CN106833922A - Cleaning agent for microwave oven and preparation method thereof - Google Patents
Cleaning agent for microwave oven and preparation method thereof Download PDFInfo
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- CN106833922A CN106833922A CN201611238202.5A CN201611238202A CN106833922A CN 106833922 A CN106833922 A CN 106833922A CN 201611238202 A CN201611238202 A CN 201611238202A CN 106833922 A CN106833922 A CN 106833922A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
- C11D1/8255—Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
Abstract
The present invention relates to cleaning agent for microwave oven and preparation method thereof.Grease on micro-wave oven inwall is more obstinate, and traditional clean method cleaning effect is undesirable.Cleaning agent for microwave oven of the present invention is made up of nonionic surfactant, safe environment protection type solvent, rheology modifier, oil rub resistance redeposition agent, acid-base modifier, conventional additives and deionized water, it is gentle non-stimulated, safety non-toxic, convenient use, environmental protection, is the product dedicated for micro-wave oven cleaning that can fully remove obstinate oil stain.Inventive formulation is gentle, and coating and device are not corroded;Addition oil rub resistance redeposition technology, it is easy to secondary cleaning;Gel state, the residence time is long, deoils fully, there is provided clean cooking environments.
Description
Technical field
The invention belongs to kitchen appliance surface and oil contaminant cleaning applications, and in particular to a kind of cleaning agent for microwave oven and its preparation side
Method.
Background technology
With the development of science and technology life of urban resident tempo increase, the machine for kitchen use of more and more fast cookings is used,
Such as micro-wave oven, electric cake shelves, electric oven etc..During micro-wave oven use, food can be volatilized a certain amount of water by heating using microwave
Point, these moisture are often attached on micro-wave oven inwall entrainment of materials such as greases.Due to heating or cooking food volatilization every time
Oil stain it is unobvious, people typically will not often wipe micro-wave oven inwall, therefore, the greasy dirt that micro-wave oven inwall is speckled with is substantially day
The tired result of the product moon, these greasy dirts become very sticky thick not easy-clear by heating repeatedly, baking.If the residual stain of these greasy dirts
Cannot thoroughly clean, can be evaporated after heating again, cause micro-wave oven peculiar smell;Can also be attached on food, food is made
Into different degrees of pollution, long-term use can influence household's health.So often cleaning micro-wave oven inwall is needed, to ensure health
The food of safety.
Because the grease on micro-wave oven inwall is more obstinate, traditional clean method is mainly and dips liquid detergent by rag
Or kitchen cleaning agent cleans micro-wave oven, also need to be cleaned again with water one time after cleaning, not only waste time and energy, and cleaning effect
It is undesirable.Commercially available pollution cleanser alkalescence of deoiling for kitchen use is larger, although the removal ability to heavy oil stain is strong, but its corrosivity
Also it is relatively strong, corrosion is caused to cleaned object surface, while causing to stimulate to user's skin;The security of its formula material is not
Height, is not suitable for the cleaning of this kind of and food directly contact electrical equipment of micro-wave oven, baking box.Though there are some special microwaves on the market
Stove cleaning agent, but declare that effect is larger, product alkalescence is not also low, and being irritating to the skin property, raw material is also safe not to the utmost, goes to degrease
Effect it is also preferable not to the utmost.
The content of the invention
It is an object of the invention to provide a kind of cleaning agent for microwave oven and preparation method thereof, can fully remove stupid in micro-wave oven
Gu oil stain.
The technical solution adopted in the present invention is:
Cleaning agent for microwave oven, it is characterised in that:
It is made up of the component of following weight portion:
The weight portion of nonionic surfactant 1~15;
The weight portion of safe environment protection type solvent 5~50;
The weight portion of rheology modifier 0.05~5;
The oil rub resistance redeposition weight portion of agent 0.05~5;
The weight portion of acid-base modifier 1~10;
The weight portion of conventional additives 0.05~2;
Deionized water surplus;
The parts by weight summation of each component is 100.
Described nonionic surfactant is polyethenoxy alkanolamide class, fatty alcohol polyethenoxy ether class, coconut oil
The mixture of one or more in fatty acid alkanol amides class, sucrose ester, APG class.
Described safe environment protection type solvent is edible alcohol, ethylene glycol, polyethylene glycol, glycerine, propane diols, propane diols fourth
The mixture of one or more in ether, dipropylene.
Described rheology modifier is acrylic polymer.
Described oil rub resistance redeposition agent is that vinylpyrrolidone/decil acrylate copolymer or acrylic acid are common
At least one of polymers.
Described acid-base modifier is NaOH, Na2CO3, diethanol amine, triethanolamine, in citric acid one or more
Mixture.
Described conventional additives are preservative, essence, pigment.
The preparation method of cleaning agent for microwave oven, it is characterised in that:
Comprise the following steps:
Step 1:Got the raw materials ready according to following weight:
The weight portion of nonionic surfactant 1~15;
The weight portion of safe environment protection type solvent 5~50;
The weight portion of rheology modifier 0.05~5;
The oil rub resistance redeposition weight portion of agent 0.05~5;
The weight portion of acid-base modifier 1~10;
The weight portion of conventional additives 0.05~2;
Deionized water surplus;
The parts by weight summation of each component is 100;
Step 2:Under normal temperature, rheology modifier is added in deionized water, rheology modifier is at least diluted 10~20 times, stirring
After well mixed, solution A is obtained;
Step 3:Add nonionic surfactant one by one in solution A, be uniformly mixed successively, obtain solution B;
Step 4:Oil rub resistance redeposition agent is added in solution B, is stirred to being uniformly dissolved, obtain solution C;
Step 5:Add safe environment protection type solvent one by one in solution C, stir to being uniformly dissolved, obtain solution D;
Step 6:Conventional additives are added in solution D, continues to stir to being uniformly dissolved, obtain solution E;
Step 7:Acid-base modifier is added in solution E, is stirred to being uniformly dissolved, the viscosity of solution increases immediately, finally gives
Transparent viscous liquid, is made cleaning agent for microwave oven.
Described nonionic surfactant is polyethenoxy alkanolamide class, fatty alcohol polyethenoxy ether class, coconut oil
The mixture of one or more in fatty acid alkanol amides class, sucrose ester, APG class;
Described safe environment protection type solvent is edible alcohol, ethylene glycol, polyethylene glycol, glycerine, propane diols, propandiol butyl ether, two
The mixture of one or more in propandiol butyl ether;
Described rheology modifier is acrylic polymer;
Described oil rub resistance redeposition agent is vinylpyrrolidone/decil acrylate copolymer or acrylic copolymer
At least one of;
Described acid-base modifier is NaOH, Na2CO3, diethanol amine, triethanolamine, one or more mixed in citric acid
Compound;
Described conventional additives are preservative, essence, pigment.
The present invention has advantages below:
1st, the AEO and APG compounding in natural seed oil source are employed as main active matter, it is special
Hard-surface cleaning is not suitable for it, especially effective to removing kitchen oil stain, the ability for removing triglyceride is protruded;Formula is gentle,
Coating and utensil are not corroded;Gel range is narrow, good water solubility, it is easy to be formulated;Energy complete biodegradable, it is environmentally friendly;Meet
Safety non-toxic requirement to human body skin.
2nd, the rheology modifier selected is Tao Shi ACUSOL series, with strong table work tolerance;With polar solvent compatibility
It is good;There is the excellent transparency and mobility;High temperature and freeze-thaw stability are good.The modifying agent can become when system pH is weak base
The clear solution of high viscosity, and viscosity is steady.The addition of triethanolamine, not only can play synergy with surfactant, promote
Enter the removal of grease, mild alkaline conditions can also be provided, improve the viscosity of product, stop of the extension product in crust vertical direction
Time so that product is more abundant with the effect of grease, deoils more thorough.
3rd, the oil rub resistance redeposition component of present invention addition, to greasy dirt and surfacing common in family(Such as glass, no
Rust steel, ceramics, granite)Effectively, crust hydrophily can be improved, makes greasy dirt be more easy to remove, and provide protective surface
To resist following greasy dirt, realization is easy to the target of secondary cleaning to layer.Also there is high glaze, the spy of basic noresidue vestige in addition
Point.
Specific embodiment
With reference to specific embodiment, the present invention will be described in detail.
Cleaning agent for microwave oven of the present invention, is made up of the component of following weight portion:
The weight portion of nonionic surfactant 1~15;
The weight portion of safe environment protection type solvent 5~50;
The weight portion of rheology modifier 0.05~5;
The oil rub resistance redeposition weight portion of agent 0.05~5;
The weight portion of acid-base modifier 1~10;
The weight portion of conventional additives 0.05~2;
Deionized water surplus;
The parts by weight summation of each component is 100.
Wherein:
Described nonionic surfactant is polyethenoxy alkanolamide class, fatty alcohol polyethenoxy ether class, coconut oil fat
The mixture of one or more in sour alkanolamide class, sucrose ester, APG class;
Described safe environment protection type solvent discharges laws and regulations on the management, Europe to meet European Union 1999/13/EC on volatile organic solvent
The requirement of alliance 2005/344/EC multifuctional cleaning agent environmental regulations and meet HJ 458-2009 environmental standards product technology will
Ask.From the one kind in edible alcohol, ethylene glycol, polyethylene glycol, glycerine, propane diols, propandiol butyl ether, dipropylene or
Several mixtures;
Described rheology modifier is acrylic polymer, it is desirable to raw material non-hazardous, there is comprehensive EHS number
According to support;
Described oil rub resistance redeposition agent is vinylpyrrolidone/decil acrylate copolymer or acrylic copolymer
At least one of;
Described acid-base modifier is NaOH, Na2CO3, diethanol amine, triethanolamine, one or more mixed in citric acid
Compound;
Described conventional additives are conventional preservative, essence, pigment.
The preparation method of above-mentioned cleaning agent for microwave oven, comprises the following steps:
Step 1:Got the raw materials ready according to following weight:
The weight portion of nonionic surfactant 1~15;
The weight portion of safe environment protection type solvent 5~50;
The weight portion of rheology modifier 0.05~5;
The oil rub resistance redeposition weight portion of agent 0.05~5;
The weight portion of acid-base modifier 1~10;
The weight portion of conventional additives 0.05~2;
Deionized water surplus;
The parts by weight summation of each component is 100;
Step 2:Under normal temperature, rheology modifier is added in deionized water, rheology modifier is at least diluted 10~20 times, stirring
After well mixed, solution A is obtained;
Step 3:Add nonionic surfactant one by one in solution A, be uniformly mixed successively, obtain solution B;
Step 4:Oil rub resistance redeposition agent is added in solution B, is stirred to being uniformly dissolved, obtain solution C;
Step 5:Add safe environment protection type solvent one by one in solution C, stir to being uniformly dissolved, obtain solution D;
Step 6:Conventional additives are added in solution D, continues to stir to being uniformly dissolved, obtain solution E;
Step 7:Acid-base modifier is added in solution E, is stirred to being uniformly dissolved, the viscosity of solution increases immediately, finally gives
Transparent viscous liquid, is made cleaning agent for microwave oven.
In above-mentioned steps:
Described nonionic surfactant is polyethenoxy alkanolamide class, fatty alcohol polyethenoxy ether class, coconut oil fat
The mixture of one or more in sour alkanolamide class, sucrose ester, APG class;
Described safe environment protection type solvent is edible alcohol, ethylene glycol, polyethylene glycol, glycerine, propane diols, propandiol butyl ether, two
The mixture of one or more in propandiol butyl ether;
Described rheology modifier is acrylic polymer;
Described oil rub resistance redeposition agent is vinylpyrrolidone/decil acrylate copolymer or acrylic copolymer
At least one of;
Described acid-base modifier is NaOH, Na2CO3, diethanol amine, triethanolamine, one or more mixed in citric acid
Compound;
Described conventional additives are preservative, essence, pigment.
Embodiment 1:
Step 1:Got the raw materials ready according to following weight:
The weight portion of nonionic surfactant 1;
The weight portion of safe environment protection type solvent 50;
The weight portion of rheology modifier 0.05;
The oil rub resistance redeposition weight portion of agent 5;
The weight portion of acid-base modifier 1;
The weight portion of conventional additives 2;
Deionized water surplus;
The parts by weight summation of each component is 100;
Step 2:Under normal temperature, rheology modifier is added in deionized water, rheology modifier is at least diluted 10 times, stirring mixing
After uniform, solution A is obtained;
Step 3:Add nonionic surfactant one by one in solution A, be uniformly mixed successively, obtain solution B;
Step 4:Oil rub resistance redeposition agent is added in solution B, is stirred to being uniformly dissolved, obtain solution C;
Step 5:Add safe environment protection type solvent one by one in solution C, stir to being uniformly dissolved, obtain solution D;
Step 6:Conventional additives are added in solution D, continues to stir to being uniformly dissolved, obtain solution E;
Step 7:Acid-base modifier is added in solution E, is stirred to being uniformly dissolved, the viscosity of solution increases immediately, finally gives
Transparent viscous liquid, is made cleaning agent for microwave oven.
In above-mentioned steps:
Described nonionic surfactant is polyethenoxy alkanolamide class, the mixture of fatty alcohol polyethenoxy ether class(Such as
Mixed in equal amounts);
Described safe environment protection type solvent is edible alcohol, ethylene glycol, the mixture of polyethylene glycol(Such as mixed in equal amounts);
Described rheology modifier is acrylic polymer;
Described oil rub resistance redeposition agent is vinylpyrrolidone/decil acrylate copolymer;
Described acid-base modifier is NaOH, Na2CO3Mixture(Such as mixed in equal amounts);
Described conventional additives are preservative, essence, pigment(Such as mixed in equal amounts).
Embodiment 2:
Step 1:Got the raw materials ready according to following weight:
The weight portion of nonionic surfactant 7;
The weight portion of safe environment protection type solvent 30;
The weight portion of rheology modifier 2.5;
The oil rub resistance redeposition weight portion of agent 2.5;
The weight portion of acid-base modifier 5;
The weight portion of conventional additives 1;
Deionized water surplus;
The parts by weight summation of each component is 100;
Step 2:Under normal temperature, rheology modifier is added in deionized water, rheology modifier is at least diluted 15 times, stirring mixing
After uniform, solution A is obtained;
Step 3:Add nonionic surfactant one by one in solution A, be uniformly mixed successively, obtain solution B;
Step 4:Oil rub resistance redeposition agent is added in solution B, is stirred to being uniformly dissolved, obtain solution C;
Step 5:Add safe environment protection type solvent one by one in solution C, stir to being uniformly dissolved, obtain solution D;
Step 6:Conventional additives are added in solution D, continues to stir to being uniformly dissolved, obtain solution E;
Step 7:Acid-base modifier is added in solution E, is stirred to being uniformly dissolved, the viscosity of solution increases immediately, finally gives
Transparent viscous liquid, is made cleaning agent for microwave oven.
In above-mentioned steps:
Described nonionic surfactant is coco-nut oil fatty acid alkanolamide class, the mixture of sucrose ester(As equivalent is mixed
Close);
Described safe environment protection type solvent is glycerine, propane diols, the mixture of propandiol butyl ether(Such as mixed in equal amounts);
Described rheology modifier is acrylic polymer;
Described oil rub resistance redeposition agent is vinylpyrrolidone/decil acrylate copolymer;
Described acid-base modifier is diethanol amine, the mixture of triethanolamine(Such as mixed in equal amounts);
Described conventional additives are preservative, essence, pigment(Such as mixed in equal amounts).
Embodiment 3:
Step 1:Got the raw materials ready according to following weight:
The weight portion of nonionic surfactant 15;
The weight portion of safe environment protection type solvent 5;
The weight portion of rheology modifier 5;
The oil rub resistance redeposition weight portion of agent 0.05;
The weight portion of acid-base modifier 10;
The weight portion of conventional additives 0.05;
Deionized water surplus;
The parts by weight summation of each component is 100;
Step 2:Under normal temperature, rheology modifier is added in deionized water, rheology modifier is at least diluted 20 times, stirring mixing
After uniform, solution A is obtained;
Step 3:Add nonionic surfactant one by one in solution A, be uniformly mixed successively, obtain solution B;
Step 4:Oil rub resistance redeposition agent is added in solution B, is stirred to being uniformly dissolved, obtain solution C;
Step 5:Add safe environment protection type solvent one by one in solution C, stir to being uniformly dissolved, obtain solution D;
Step 6:Conventional additives are added in solution D, continues to stir to being uniformly dissolved, obtain solution E;
Step 7:Acid-base modifier is added in solution E, is stirred to being uniformly dissolved, the viscosity of solution increases immediately, finally gives
Transparent viscous liquid, is made cleaning agent for microwave oven.
In above-mentioned steps:
Described nonionic surfactant is coco-nut oil fatty acid alkanolamide class, sucrose ester, the mixing of APG class
Thing(Such as mixed in equal amounts);
Described safe environment protection type solvent is the mixture in propandiol butyl ether, dipropylene(Such as mixed in equal amounts);
Described rheology modifier is acrylic polymer;
Described oil rub resistance redeposition agent is acrylic copolymer;
Described acid-base modifier is citric acid;
Described conventional additives are preservative, essence, pigment(Such as mixed in equal amounts).
It is below the performance test explanation of cleaning agent for microwave oven involved in the present invention:
Experiment 1:
The contrivance is tested to be contrasted with the pH value of commercial products.It is measured by GB/T 6368.25 DEG C of test temperature, with steaming
Distilled water prepares the aqueous solution of 1 % samples.
Test result is as follows:
Experiment 2:
Test the contrivance and performance comparison of the commercial products in terms of degreasing power.
Dirt is selected from 6 Oil stain mixtures of different family kitchen smoke exhaust ventilators.Dirty piece is without purple in experimentation
Outside line treatment with irradiation.Test piece model:Stainless steel 1Cr18Ni9Ti, 50 mm × 25 mm ×(3~6)mm.
It is cold in drier by stainless steel test piece according to the method polishing in QB/T 2117-1995, after clean, drying
But, weigh(Accurate extremely ± 0.2 mg).Greasy dirt is uniformly coated on test piece predetermined portion, the control of greasy dirt coated weight exists(0.15~
0.25), then together with test piece be placed on dirty piece by g/piece(105±2)30 min are dried in DEG C baking oven, cooling is taken out, in drying
22~24 h are aged in device.Dirty piece is weighed(Accurate extremely ± 0.2mg)Afterwards, it is hooked on the rocker of pendulum washing machine with " S " type, is used
The test method of QB/T 4348-2012 carry out pendulum wash, dried process, calculate degreasing power.
Result of calculation is as follows:
Experiment 3:
Test the contrivance and performance comparison of the commercial products in terms of oil rub resistance redeposition.
Dirt is selected from 6 Oil stain mixtures of different family kitchen smoke exhaust ventilators.Test piece model:Stainless steel
1Cr18Ni9Ti, 50 mm × 50 mm ×(3~6)mm.Dirty piece non-irradiated with ultraviolet radiation treatment, only room temperature ageing in experimentation
Treatment.
It is cold in drier by stainless steel test piece according to the method polishing in QB/T 2117-1995, after clean, drying
But, number, weigh(Accurate extremely ± 0.2 mg).Sample is applied to test piece predetermined portion according to numbering correspondence, it is quiet in drier
2 h are put, then is wiped sample with filter paper, sample residual quantity≤0.01 g.After greasy dirt then is uniformly coated on into sample effect
Same area, greasy dirt coated weight control exist(0.30~0.40), then be placed on dirty piece on clean filter paper, in room by g/piece
Temperature 2 h of lower ageing, dirty piece is weighed(Accurate extremely ± 0.2mg)Afterwards, it is hooked on the rocker of pendulum washing machine with " S " type, dirty piece directly soaks
Bubble in distilled water, using the test method of QB/T 4348-2012 carry out pendulum wash, dried process, calculate degreasing power.This goes
Greasy dirt power is oil rub resistance redeposition rate.
Result of calculation is as follows:
Experiment 4:
Test the contrivance and contrast of the commercial products in terms of residence time, remaining trace, reflecting feel.
(1) the white porcelain plate of a block specifications 35cm × 50cm has been prepared, has cleaned, with distilled water, alcohol rinse three times, hot blast
Drying.Four 8cm × 40cm, area identical regions are divided on white porcelain plate surface(The reserved about 5cm blank of area top), compile
Number, it is standby.White porcelain plate side long is placed perpendicular to horizontal experimental bench again.
(2) contrivance and commercial products are poured into model, specification identical spray bottle respectively, consumption 30ml, respectively
It is numbered record.The numbering of spray bottle is corresponding with whiteboard area numbering, is recorded in order to phenomenon.
(3) the spray bottle of (2) middle dress sample is pressed into shower nozzle for several times in advance, it is uniform to spraying.Then pressing shower nozzle three times, sprays
To the reserved blank space on blank corresponding region top, when sample flows to upper line, stopwatch is pressed immediately, until sample flow to
During underscore, stop timing.4 groups of samples are according to said method carried out, every group of sample testing 2 times, are averaged.
Test result record is as follows:
(4) in the defined area of white porcelain plate, sample is thoroughly wiped with filter paper, and after hanging 2h at lucifuge, ask 10 people to evaluate
Blank is observed from different directions by group, evaluates the light sense of the trace situation and porcelain plate of sample.
Vestige evaluation criterion:It is clearly 5 points, hence it is evident that 4 points, more apparent 3 points, less obvious 2 points, unobvious 1 point.
Light sense evaluation criterion:Become clear 5 points very much, become clear 4 points, relatively become clear 3 points, do not become clear 2 points, do not become clear 1 point very much.
The evaluation that 10 staff are given after conscientiously examining is basically identical, and its result is as follows:
Present disclosure is not limited to cited by embodiment, and those of ordinary skill in the art are right by reading description of the invention
Any equivalent conversion that technical solution of the present invention is taken, is claim of the invention and is covered.
Claims (9)
1. cleaning agent for microwave oven, it is characterised in that:
It is made up of the component of following weight portion:
The weight portion of nonionic surfactant 1~15;
The weight portion of safe environment protection type solvent 5~50;
The weight portion of rheology modifier 0.05~5;
The oil rub resistance redeposition weight portion of agent 0.05~5;
The weight portion of acid-base modifier 1~10;
The weight portion of conventional additives 0.05~2;
Deionized water surplus;
The parts by weight summation of each component is 100.
2. cleaning agent for microwave oven according to claim 1, it is characterised in that:
Described nonionic surfactant is polyethenoxy alkanolamide class, fatty alcohol polyethenoxy ether class, coconut oil fat
The mixture of one or more in sour alkanolamide class, sucrose ester, APG class.
3. cleaning agent for microwave oven according to claim 1, it is characterised in that:
Described safe environment protection type solvent is edible alcohol, ethylene glycol, polyethylene glycol, glycerine, propane diols, propandiol butyl ether, two
The mixture of one or more in propandiol butyl ether.
4. cleaning agent for microwave oven according to claim 1, it is characterised in that:
Described rheology modifier is acrylic polymer.
5. cleaning agent for microwave oven according to claim 1, it is characterised in that:
Described oil rub resistance redeposition agent is vinylpyrrolidone/decil acrylate copolymer or acrylic copolymer
At least one of.
6. cleaning agent for microwave oven according to claim 1, it is characterised in that:
Described acid-base modifier is NaOH, Na2CO3, diethanol amine, triethanolamine, the mixing of one or more in citric acid
Thing.
7. cleaning agent for microwave oven according to claim 1, it is characterised in that:
Described conventional additives are preservative, essence, pigment.
8. the preparation method of cleaning agent for microwave oven, it is characterised in that:
Comprise the following steps:
Step 1:Got the raw materials ready according to following weight:
The weight portion of nonionic surfactant 1~15;
The weight portion of safe environment protection type solvent 5~50;
The weight portion of rheology modifier 0.05~5;
The oil rub resistance redeposition weight portion of agent 0.05~5;
The weight portion of acid-base modifier 1~10;
The weight portion of conventional additives 0.05~2;
Deionized water surplus;
The parts by weight summation of each component is 100;
Step 2:Under normal temperature, rheology modifier is added in deionized water, rheology modifier is at least diluted 10~20 times, stirring
After well mixed, solution A is obtained;
Step 3:Add nonionic surfactant one by one in solution A, be uniformly mixed successively, obtain solution B;
Step 4:Oil rub resistance redeposition agent is added in solution B, is stirred to being uniformly dissolved, obtain solution C;
Step 5:Add safe environment protection type solvent one by one in solution C, stir to being uniformly dissolved, obtain solution D;
Step 6:Conventional additives are added in solution D, continues to stir to being uniformly dissolved, obtain solution E;
Step 7:Acid-base modifier is added in solution E, is stirred to being uniformly dissolved, the viscosity of solution increases immediately, finally gives
Transparent viscous liquid, is made cleaning agent for microwave oven.
9. the preparation method of cleaning agent for microwave oven according to claim 8, it is characterised in that:
Described nonionic surfactant is polyethenoxy alkanolamide class, fatty alcohol polyethenoxy ether class, coconut oil fat
The mixture of one or more in sour alkanolamide class, sucrose ester, APG class;
Described safe environment protection type solvent is edible alcohol, ethylene glycol, polyethylene glycol, glycerine, propane diols, propandiol butyl ether, two
The mixture of one or more in propandiol butyl ether;
Described rheology modifier is acrylic polymer;
Described oil rub resistance redeposition agent is vinylpyrrolidone/decil acrylate copolymer or acrylic copolymer
At least one of;
Described acid-base modifier is NaOH, Na2CO3, diethanol amine, triethanolamine, the mixing of one or more in citric acid
Thing;
Described conventional additives are preservative, essence, pigment.
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CN108774589A (en) * | 2018-06-22 | 2018-11-09 | 西安开米股份有限公司 | A kind of refrigerator antibacterial cleanser and preparation method thereof |
CN110184132A (en) * | 2019-04-29 | 2019-08-30 | 南京点元环境科技有限公司 | A kind of preparation method of glyceryl green cleaning agent |
CN112662490A (en) * | 2020-12-25 | 2021-04-16 | 广东自由能科技股份有限公司 | Kitchen heavy oil stain cleaning agent, preparation method thereof and application thereof in aerosol |
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CN110184132A (en) * | 2019-04-29 | 2019-08-30 | 南京点元环境科技有限公司 | A kind of preparation method of glyceryl green cleaning agent |
CN112662490A (en) * | 2020-12-25 | 2021-04-16 | 广东自由能科技股份有限公司 | Kitchen heavy oil stain cleaning agent, preparation method thereof and application thereof in aerosol |
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