CN108774589A - A kind of refrigerator antibacterial cleanser and preparation method thereof - Google Patents

A kind of refrigerator antibacterial cleanser and preparation method thereof Download PDF

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Publication number
CN108774589A
CN108774589A CN201810652285.5A CN201810652285A CN108774589A CN 108774589 A CN108774589 A CN 108774589A CN 201810652285 A CN201810652285 A CN 201810652285A CN 108774589 A CN108774589 A CN 108774589A
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weight
parts
refrigerator
environment
solution
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CN201810652285.5A
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于文
雷敏
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Shanghai Kaimi Technology Co Ltd
XI'AN KAIMI CO Ltd
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Shanghai Kaimi Technology Co Ltd
XI'AN KAIMI CO Ltd
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Priority to CN201810652285.5A priority Critical patent/CN108774589A/en
Publication of CN108774589A publication Critical patent/CN108774589A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/825Mixtures of compounds all of which are non-ionic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776Heterocyclic compounds, e.g. lactam
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40Dyes ; Pigments
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43Solvents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention is a kind of safe and non-toxic, easy to use, environmentally protective refrigerator antibacterial cleanser and preparation method thereof dedicated for cold storage chamber of refrigerator cleaning-sterilizing, and formula is mild, does not corrode coating and device;Excellent grease emulsifying performance removes oil stain dirt;Bacterial micro-organism in refrigerating chamber can effectively be killed to grow, while going to eliminate the unusual smell;Oil rub resistance redeposition technology is assisted, secondary cleaning is easy to;The cold storage environment for providing safety clean, extends the service life of electric appliance.Detergent of the present invention is composed of the following raw materials by weight:1~15 parts by weight of nonionic surfactant, 0.05~5 parts by weight of safety-type antiseptic, 5~30 parts by weight of environment-friendly type solvent, 0.05~5 parts by weight of oil rub resistance redeposition agent, 0.05~2 parts by weight of conventional additives, deionized water surplus.

Description

A kind of refrigerator antibacterial cleanser and preparation method thereof
One, technical field:
The invention belongs to refrigerating chamber antibacterial and surface and oil contaminant cleaning technology fields, and it is clear to be specifically related to a kind of refrigerator antibacterial Clean dose and preparation method thereof.
Two, background technology:
With the raising of people's living standard and the level of consumption, in city, refrigerator is present in often as household necessity Family's each household, in rural area, refrigerator also starts to popularize as television set originally.We are desirable to eat using the purpose of refrigerator Vegetables, food to fresh and healthy, but some bacteriums in refrigerator can also flourish, contaminated food.Refrigerator preserves food The common refrigerated storage temperature of object is 0~8 DEG C, and in such a case, most of bacteria growth can slow down, but psychrophilic bacteria Such as Yersinia, listeria spp, Shigella can also breed at low ambient temperatures, if edible infected this kind of bacterium Food, nausea and vomiting can be caused, or even the diseases such as infection enteritis, dysentery.Meanwhile the process that these bacteriums are metabolized in growth In will produce many metabolism gases, such as methane, hydrogen sulfide, methyl mercaptan, methyl amine malodoring gas, a variety of odours mixing can make At peculiar smell more unpleasant in refrigerator.In addition, the antibacterial of refrigerator, degerming functions are additional health hygienic function, it is not equivalent In the disinfection cabinet of profession, it must not believe that and food is put into the thoroughly fresh-keeping degerming of antimicrobial refrigerator energy, it can be seen that, periodically use The refrigerater antibiotic detergent of profession, which carries out artificial cleaning-sterilizing work, to be very important.
Refrigerator deodorizer on the market and refrigerator detergent at present, most of is all solids package, mainly use activated carbon, The inorganic porous substance such as zeolite, sepiolite, medical stone is matrix material, impregnates chemistry or plant extraction liquid is process, merely By physical absorption, adsorbance is small, and adsorption rate is slow, and easy moisture absorption saturation, has a single function in wet environment.Also there is liquid-type production Product, using plant extraction liquid, cost is higher and function and effect are undesirable, and some liquid components even have low toxicity or biology The bad problem of degradability.
Three, invention content
It is easy to use the purpose of the present invention is to provide a kind of safe and non-toxic, it is environmentally protective cold dedicated for refrigerator The refrigerator antibacterial cleanser and preparation method thereof of room cleaning-sterilizing is hidden, formula is mild, does not corrode coating and device;Excellent Grease emulsifying performance removes oil stain dirt;Bacterial micro-organism in refrigerating chamber can effectively be killed to grow, while going to eliminate the unusual smell;Auxiliary Oil rub resistance redeposition technology, is easy to secondary cleaning;The cold storage environment for providing safety clean, extends the service life of electric appliance.
To achieve the above object, the technical solution adopted by the present invention is:
A kind of refrigerator antibacterial cleanser, it is characterised in that:The detergent is composed of the following raw materials by weight:
The nonionic surfactant is polyglyceryl fatty acid ester class, fatty acid distribution of coconut oil alkanolamide class, fatty alcohol The mixture of one or more of polyethenoxy ether class, sucrose ester, alkyl glycosides.
The safety-type antiseptic is chlorhexidine gluconate, ε-poly-D-lysine, polylysine and organic acid and ammonia The mixture of one or more of the mixture of base acid, natural organic antibacterial agent A.SAP, polyhexamethylene hydrochloric acid bisguanides.
The environment-friendly type solvent is to meet European Union 1999/13/EC to discharge laws and regulations on the management, Europe about volatile organic solvent The requirement of alliance 2005/344/EC multifuctional cleaning agent environmental regulations and meet HJ 458-2009 environmental standard product technologies requirement Environment-friendly type solvent.
The environment-friendly type solvent is one or more of ethylene glycol, polyethylene glycol, propylene glycol, edible alcohol, glycerine Mixture.
The oil rub resistance redeposition agent is that vinylpyrrolidone/decil acrylate copolymer or acrylic acid are total At least one of polymers.
The conventional additives are the preservative, essence, pigment of routine.
A kind of preparation method of refrigerator antibacterial cleanser, it is characterised in that:The step of described preparation method is:
Step 1:According to above-mentioned raw materials weight, 100 parts are amounted to;
Step 2:Under room temperature, nonionic surfactant is added in deionized water, stirs, after mixing, obtains molten Liquid A;
Step 3:In solution A, environment-friendly type solvent is added, stirring obtains solution B to being uniformly mixed;
Step 4:Oil rub resistance redeposition agent is added in solution B, stirs to being uniformly dissolved, obtains solution C;
Step 5:In solution C, safety-type antiseptic is added, continues stirring to being uniformly mixed, obtains solution D;
Step 6:Conventional additives are added in solution D, stirs to being uniformly dissolved, finally obtains transparent liquid E, are made At refrigerator antibacterial cleanser.
Compared with prior art, the invention has the advantages that and effect:
1, the natural organic antibacterial agent A.SAP selected is colourless, tasteless, transparent aqua liquid, with beans and wheat etc. Cereal extract liquor is main component with cationic surfactant, is free of heavy metal;With very high safety, LD50Value is big In 5000mg/kg, skin is disposably tested, all feminine genders are tested in cutaneous sensibility experiment and allergenicity;To gram sun Property bacterium, Gram-negative bacteria have good inactivating efficacy;Antibacterial effect is notable, and sustained anti-microbial has both the performance that eliminates the unusual smell. A.SAP is widely used in each field such as oral hygiene, napkin paper, wet tissue, hand cleanser, environment disinfected.The Antibacterial Mechanism of A.SAP is The cationic surfactant contained generates obstacle to microprotein and denaturation solidifies, and makes its own that function occur and inhibits, To reach sterilization purpose.A.SAP realizes the work for reducing toxicity and enhancing sterilization by cereal extract liquor (based on amino acid) With.
(polylysine, the organic acid, amino acid) mixture selected be applied to the disinfection of food enterprise, sterilised products, Each component is food-grade, safe, harmless to people, animal;Have well to gram-positive bacteria and Gram-negative bacteria Antibacterial effect, rapid-action, noresidue.Polylysine and organic acid are compound, are mainly used for the antibacterial anti-corrosion of food, and amino acid can then increase Strong sterilization efficacy.Its mechanism of action is to act on the cell wall and cell membrane and functional protein of microorganism so that bacterium or Mold inactivation realizes antibiotic effect.
2, the fatty alcohol polyoxyethylene ether and alkyl glycosides compounding for using natural seed oil source are used as main activity Object meets the safe and non-toxic requirement to human skin;Energy complete biodegradable, it is environmentally friendly;It is effective to removing kitchen greasy dirt, The ability for removing triglyceride protrudes;Formula is mild, does not corrode coating and utensil.
3, oil rub resistance redeposition technology of the invention, to greasy dirt and surfacing common in family (such as glass, stainless Steel, ceramics, granite) effectively, hard surface hydrophily can be improved, greasy dirt is made to be more easy to remove, and protective superficial layer is provided To resist following greasy dirt, realization is easy to secondary clean target.
Four, specific implementation mode
It is limited with reference to specific embodiment technical scheme of the present invention is further:
A kind of refrigerator antibacterial cleanser each group by weight of the present invention is divided into:1~15 weight of nonionic surfactant Measure part;0.05~5 parts by weight of safety-type antiseptic;5~30 parts by weight of environment-friendly type solvent;0.05~5 weight of oil rub resistance redeposition agent Measure part;0.05~2 parts by weight of conventional additives;Surplus is deionized water, amounts to 100 parts.
The nonionic surfactant is polyglyceryl fatty acid ester class, fatty acid distribution of coconut oil alkanolamide class, fatty alcohol The mixture of one or more of polyethenoxy ether class, sucrose ester, alkyl glycosides.
The safety-type antiseptic is chlorhexidine gluconate, ε-poly-D-lysine, (polylysine, organic acid, amino Acid) mixture, natural organic antibacterial agent A.SAP, one or more of polyhexamethylene hydrochloric acid bisguanides mixture.
The environment-friendly type solvent is to meet European Union 1999/13/EC to discharge laws and regulations on the management, Europe about volatile organic solvent The requirement of alliance 2005/344/EC multifuctional cleaning agent environmental regulations and meet HJ 458-2009 environmental standard product technologies requirement.
The environment-friendly type solvent is one or more of ethylene glycol, polyethylene glycol, propylene glycol, edible alcohol, glycerine Mixture.
The oil rub resistance redeposition agent is that vinylpyrrolidone/decil acrylate copolymer or acrylic acid are total At least one of polymers.
The conventional additives are the preservative, essence, pigment of routine.
The preparation method of refrigerator antibacterial cleanser of the present invention is realized by following steps by weight ratio:
Step 1:Under room temperature, nonionic surfactant is added in deionized water, stirs, after mixing, obtains molten Liquid A;
Step 2:In solution A, environment-friendly type solvent is added one by one, stirring obtains solution B to being uniformly mixed;
Step 3:Oil rub resistance redeposition agent is added in solution B, stirs to being uniformly dissolved, obtains solution C;
Step 4:In solution C, safety-type antiseptic is added, continues stirring to being uniformly mixed, obtains solution D;
Step 5:Conventional additives are added in solution D, are stirred to being uniformly dissolved, are finally obtained transparent liquid E, i.e., Refrigerator antibacterial cleanser is made.
Embodiment one:
A kind of refrigerator antibacterial cleanser each group by weight of the present invention is divided into:1 parts by weight of nonionic surfactant; 0.05 parts by weight of safety-type antiseptic;5 parts by weight of environment-friendly type solvent;0.05 parts by weight of oil rub resistance redeposition agent;Conventional additives 0.05 parts by weight;Surplus is deionized water.
The nonionic surfactant is polyglyceryl fatty acid ester class, fatty acid distribution of coconut oil alkanolamide class, fatty alcohol The mixture of one or more of polyethenoxy ether class, sucrose ester, alkyl glycosides.
The safety-type antiseptic is chlorhexidine gluconate, ε-poly-D-lysine, (polylysine, organic acid, amino Acid) mixture, natural organic antibacterial agent A.SAP, one or more of polyhexamethylene hydrochloric acid bisguanides mixture.
The environment-friendly type solvent is to meet European Union 1999/13/EC to discharge laws and regulations on the management, Europe about volatile organic solvent The requirement of alliance 2005/344/EC multifuctional cleaning agent environmental regulations and meet HJ 458-2009 environmental standard product technologies requirement.
The environment-friendly type solvent is one or more of ethylene glycol, polyethylene glycol, propylene glycol, edible alcohol, glycerine Mixture.
The oil rub resistance redeposition agent is that vinylpyrrolidone/decil acrylate copolymer or acrylic acid are total At least one of polymers.
The conventional additives are the preservative, essence, pigment of routine.
The preparation method of refrigerator antibacterial cleanser of the present invention is realized by following steps by weight ratio:
Step 1:Under room temperature, nonionic surfactant is added in deionized water, stirs, after mixing, obtains molten Liquid A;
Step 2:In solution A, environment-friendly type solvent is added one by one, stirring obtains solution B to being uniformly mixed;
Step 3:Oil rub resistance redeposition agent is added in solution B, stirs to being uniformly dissolved, obtains solution C;
Step 4:In solution C, safety-type antiseptic is added, continues stirring to being uniformly mixed, obtains solution D;
Step 5:Conventional additives are added in solution D, are stirred to being uniformly dissolved, are finally obtained transparent liquid E, i.e., Refrigerator antibacterial cleanser is made.
Embodiment two:
A kind of refrigerator antibacterial cleanser each group by weight of the present invention is divided into:8 parts by weight of nonionic surfactant; 3 parts by weight of safety-type antiseptic;15 parts by weight of environment-friendly type solvent;2.5 parts by weight of oil rub resistance redeposition agent;1 weight of conventional additives Measure part;Surplus is deionized water.
The nonionic surfactant is polyglyceryl fatty acid ester class, fatty acid distribution of coconut oil alkanolamide class, fatty alcohol The mixture of one or more of polyethenoxy ether class, sucrose ester, alkyl glycosides.
The safety-type antiseptic is chlorhexidine gluconate, ε-poly-D-lysine, (polylysine, organic acid, amino Acid) mixture, natural organic antibacterial agent A.SAP, one or more of polyhexamethylene hydrochloric acid bisguanides mixture.
The environment-friendly type solvent is to meet European Union 1999/13/EC to discharge laws and regulations on the management, Europe about volatile organic solvent The requirement of alliance 2005/344/EC multifuctional cleaning agent environmental regulations and meet HJ 458-2009 environmental standard product technologies requirement.
The environment-friendly type solvent is one or more of ethylene glycol, polyethylene glycol, propylene glycol, edible alcohol, glycerine Mixture.
The oil rub resistance redeposition agent is that vinylpyrrolidone/decil acrylate copolymer or acrylic acid are total At least one of polymers.
The conventional additives are the preservative, essence, pigment of routine.
The preparation method of refrigerator antibacterial cleanser of the present invention is realized by following steps by weight ratio:
Step 1:Under room temperature, nonionic surfactant is added in deionized water, stirs, after mixing, obtains molten Liquid A;
Step 2:In solution A, environment-friendly type solvent is added one by one, stirring obtains solution B to being uniformly mixed;
Step 3:Oil rub resistance redeposition agent is added in solution B, stirs to being uniformly dissolved, obtains solution C;
Step 4:In solution C, safety-type antiseptic is added, continues stirring to being uniformly mixed, obtains solution D;
Step 5:Conventional additives are added in solution D, are stirred to being uniformly dissolved, are finally obtained transparent liquid E, i.e., Refrigerator antibacterial cleanser is made.
Embodiment three:
A kind of refrigerator antibacterial cleanser each group by weight of the present invention is divided into:15 weight of nonionic surfactant Part;5 parts by weight of safety-type antiseptic;30 parts by weight of environment-friendly type solvent;5 parts by weight of oil rub resistance redeposition agent;2 weight of conventional additives Measure part;Surplus is deionized water.
The nonionic surfactant is polyglyceryl fatty acid ester class, fatty acid distribution of coconut oil alkanolamide class, fatty alcohol The mixture of one or more of polyethenoxy ether class, sucrose ester, alkyl glycosides.
The safety-type antiseptic is chlorhexidine gluconate, ε-poly-D-lysine, (polylysine, organic acid, amino Acid) mixture, natural organic antibacterial agent A.SAP, one or more of polyhexamethylene hydrochloric acid bisguanides mixture.
The environment-friendly type solvent is to meet European Union 1999/13/EC to discharge laws and regulations on the management, Europe about volatile organic solvent The requirement of alliance 2005/344/EC multifuctional cleaning agent environmental regulations and meet HJ 458-2009 environmental standard product technologies requirement.
The environment-friendly type solvent is one or more of ethylene glycol, polyethylene glycol, propylene glycol, edible alcohol, glycerine Mixture.
The oil rub resistance redeposition agent is that vinylpyrrolidone/decil acrylate copolymer or acrylic acid are total At least one of polymers.
The conventional additives are the preservative, essence, pigment of routine.
The preparation method of refrigerator antibacterial cleanser of the present invention is realized by following steps by weight ratio:
Step 1:Under room temperature, nonionic surfactant is added in deionized water, stirs, after mixing, obtains molten Liquid A;
Step 2:In solution A, environment-friendly type solvent is added one by one, stirring obtains solution B to being uniformly mixed;
Step 3:Oil rub resistance redeposition agent is added in solution B, stirs to being uniformly dissolved, obtains solution C;
Step 4:In solution C, safety-type antiseptic is added, continues stirring to being uniformly mixed, obtains solution D;
Step 5:Conventional additives are added in solution D, are stirred to being uniformly dissolved, are finally obtained transparent liquid E, i.e., Refrigerator antibacterial cleanser is made.
Experimental example
It is the performance test explanation of refrigerator antibacterial cleanser according to the present invention below:
Experiment 1:
The pH value of two product of testing example and commercial products compares.It is measured by GB/T 6368.Test temperature 25 DEG C, the aqueous solution of 1% sample is prepared with distilled water.
Test result is as follows:
Sample name The present invention Commercial product is 1. Commercial product is 2. Commercial product is 3.
PH value 7.62 5.04 7.61 10.27
Experiment 2:
Two product of testing example and comparison of the commercial products in terms of emulsifiability.
A. each sample to be tested is diluted with distilled water, solution concentration 1% is spare after mixing;5 band glass stoppers of preparation, Have scale mark (minimum range 1mL) teat glass, clean dry it is spare;Timer, glass bar, rack for test tube, vaseline, food It is appropriate with oil, it is spare.
B. test tube is marked respectively, pours into the prepared samples of 10mL successively, then 5mL is added into every test tube and eats Oil, with water-oil factor 2:1 carries out emulsifiability test;It smears a little vaseline on glass stopper, after stoppered test tube mouth, shakes up the mixing of water oil Liquid rocks time 3min;It shakes after stopping, test tube is disposed vertically on rack for test tube, pressing manual time-keeping immediately, observes Shui You circle Face stops timing when water yield reaches 8mL;Each sample carries out operation repetitive twice, to ensure to reappear, calculates mean time Between.
C. in addition, it is necessary to distilled water into line blank test.
Test result record is as follows:
Sample name The present invention Commercial product is 1. Commercial product is 2. Commercial product is 3.
The water-oil separation time/s 115.1 41.8 34.8 48.9
The water-oil separation time is longer, illustrates that the emulsifiability of sample is better.
Experiment 3:
The bacteriostasis property and anti-microbial property of two product of testing example.
Activity stoste, action time 5min carry out fungistatic effect test to Escherichia coli and staphylococcus aureus. It is measured according to bacteriostatic test operating procedure in disinfection technology standard 2002 editions.
Test result is as follows:
Two product sample of embodiment, to Escherichia coli bacteriostasis rate>90%;
To staphylococcus aureus bacteriostasis rate>90%.
Activity stoste, action time 5min carry out antibacterial effect test to Escherichia coli and staphylococcus aureus. It is measured according to antibacterial test operation step in disinfection technology standard 2002 editions.
Test result is as follows:
Two product sample of embodiment, to Escherichia coli sterilizing rate>99%;
To staphylococcus aureus sterilizing rate>99%.
Present disclosure is not limited to cited by embodiment, and those of ordinary skill in the art are by reading description of the invention And to any equivalent replacement that technical solution of the present invention is taken, it is that claim of the invention is covered.

Claims (8)

1. a kind of refrigerator antibacterial cleanser, it is characterised in that:The detergent is composed of the following raw materials by weight:
1~15 parts by weight of nonionic surfactant
0.05~5 parts by weight of safety-type antiseptic
5~30 parts by weight of environment-friendly type solvent
0.05~5 parts by weight of oil rub resistance redeposition agent
0.05~2 parts by weight of conventional additives
Deionized water surplus.
2. a kind of refrigerator antibacterial cleanser according to claim 1, it is characterised in that:The non-ionic surface active Agent is polyglyceryl fatty acid ester class, fatty acid distribution of coconut oil alkanolamide class, fatty alcohol polyethenoxy ether class, sucrose ester, alkyl sugar The mixture of one or more of glycoside.
3. a kind of refrigerator antibacterial cleanser according to claim 1 or 2, it is characterised in that:The safety-type antibacterial Agent is chlorhexidine gluconate, ε-poly-D-lysine, polylysine and the mixture of organic acid and amino acid, natural organic anti-bacterial The mixture of one or more of agent A.SAP, polyhexamethylene hydrochloric acid bisguanides.
4. a kind of refrigerator antibacterial cleanser according to claim 3, it is characterised in that:The environment-friendly type solvent is symbol European Union 1999/13/EC is closed about volatile organic solvent discharge laws and regulations on the management, European Union 2005/344/EC multifuctional cleaning agent rings It protects the requirement of regulation and meets the environment-friendly type solvent of HJ 458-2009 environmental standard product technologies requirement.
5. a kind of refrigerator antibacterial cleanser according to claim 4, it is characterised in that:The environment-friendly type solvent is second The mixture of one or more of glycol, polyethylene glycol, propylene glycol, edible alcohol, glycerine.
6. a kind of refrigerator antibacterial cleanser according to claim 5, it is characterised in that:The oil rub resistance redeposition agent For vinylpyrrolidone/at least one of decil acrylate copolymer or acrylic copolymer.
7. a kind of refrigerator antibacterial cleanser according to claim 6, it is characterised in that:The conventional additives are normal Preservative, essence, the pigment of rule.
8. a kind of preparation method of refrigerator antibacterial cleanser according to claim 1, it is characterised in that:The preparation The step of method is:
Step 1:According to above-mentioned raw materials weight, 100 parts are amounted to;
Step 2:Under room temperature, nonionic surfactant is added in deionized water, stirs, after mixing, obtains solution A;
Step 3:In solution A, environment-friendly type solvent is added, stirring obtains solution B to being uniformly mixed;
Step 4:Oil rub resistance redeposition agent is added in solution B, stirs to being uniformly dissolved, obtains solution C;
Step 5:In solution C, safety-type antiseptic is added, continues stirring to being uniformly mixed, obtains solution D;
Step 6:Conventional additives are added in solution D, are stirred to being uniformly dissolved, are finally obtained transparent liquid E, electricity is made Refrigerater antibiotic detergent.
CN201810652285.5A 2018-06-22 2018-06-22 A kind of refrigerator antibacterial cleanser and preparation method thereof Pending CN108774589A (en)

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CN109735394A (en) * 2019-02-15 2019-05-10 王喆 A kind of refrigerator sealing ring antibacterial and deodouring detergent and preparation method thereof

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CN102002444A (en) * 2009-08-31 2011-04-06 上海家化联合股份有限公司 Refrigerator degerming smell-removing cleansing fluid and refrigerator degerming smell-removing cleansing cloth
CN102408951A (en) * 2011-09-23 2012-04-11 石家庄菠莉亚日用化工有限公司 Disinfecting and deodorizing cleaning agent for refrigerator and preparation process thereof
CN102851145A (en) * 2012-08-14 2013-01-02 青岛叁鼎卫生制品有限公司 Disinfectant cleaning spray and preparation method thereof
CN103103032A (en) * 2012-12-10 2013-05-15 苏州丰儒软件有限公司 Refrigerator cleaner and preparation method of same
CN106833922A (en) * 2016-12-28 2017-06-13 于文 Cleaning agent for microwave oven and preparation method thereof
CN107550818A (en) * 2017-09-26 2018-01-09 广西达庆生物科技股份有限公司 A kind of washing-free antibacterial liquid and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109370804A (en) * 2018-11-28 2019-02-22 广州市番禺区协运来化工用品有限公司 A kind of bad smell removal detergent agent and preparation method thereof
CN109735394A (en) * 2019-02-15 2019-05-10 王喆 A kind of refrigerator sealing ring antibacterial and deodouring detergent and preparation method thereof

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Application publication date: 20181109