CN104130883B - A kind of cleaning agent composition and cleaning agent and its application - Google Patents
A kind of cleaning agent composition and cleaning agent and its application Download PDFInfo
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- CN104130883B CN104130883B CN201410391201.9A CN201410391201A CN104130883B CN 104130883 B CN104130883 B CN 104130883B CN 201410391201 A CN201410391201 A CN 201410391201A CN 104130883 B CN104130883 B CN 104130883B
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Abstract
The invention belongs to technical field of fine, and in particular to a kind of cleaning agent composition and its in the application cleaning various stone surfaces and oiling in stain discloses a kind of cleaning agent composition and stone material cleaning agent and its application.The cleaning agent composition contains limonene, glycol monoalkyl ether and surfactant, and the weight ratio of each component is 1:0.10~2.0:0.01~1.0, preferably 1:0.5~1.5:0.1~0.5.Cleaning agent composition of the invention meets environmentally protective requirement, the cleaning of the greasy dirt spot suitable for various quality of stone material surfaces.Cleaning agent composition of the invention is thorough with spot is removed, and does not corrode stone material, entire cleaning process is made to become simply application easy to spread.
Description
Technical field
The invention belongs to technical field of fine, it is related to a kind of cleaning agent composition and cleaning agent and its application, especially
It is related to a kind of cleaning agent composition and cleaning agent and its application on cleaning stone material in various greasy dirt spots.
Background technique
Natural marble, granite, flag and artificial stone, because of its distinctive decorative performance --- the flower of Natural
Line, the glossiness of bright analysis or the male and fomale(M&F) of texture, good friction intensity etc., are widely used in the interior of building since ancient times
It is on architectural history using earliest one of construction material in external decoration.With the progress of human history and the hair of Modern Architecture industry
Exhibition, over the past decade, decorative stone has been widely applied to various all kinds of buildings, has beautified our living environment.But
Over time with the movable influence of people, so that stone surface is constantly contaminated, wherein greasy dirt spot is the most common dirt
One of dye, such as restaurant, dining room, kitchen, passageway, the hall for putting machinery and parking lot and congregation plaza etc., wall
The stone material on face and ground often can see greasy dirt spot.Greasy dirt once pollutes the surface of this calculus material, not only seriously affects beauty,
It also pollutes the environment, makes troubles to people's lives.Often with micropore, the greasy dirt that remove in micropore has stone material
Comparable difficulty.
In terms of mainly there is following four in the source of stone surface greasy dirt: first is that stone machining equipment process bring grease；
Second is that being more common in dining room, kitchen, passageway due to the edible oil contamination of mankind's vegetable edible；Third is that due to being let out when putting mechanical or vehicle
Machine oil or lubricating grease of dew etc.；Fourth is that since ground and metope waxing and upper protection oil quality are inferior or uneven.These greases
The superficial layer for being permeated and being diffused into building decoration materials, in addition to itself will form oil mark, can also automatic absorbing dust formed
Greasy dirt spot, certain greasy dirt spots also tend to form black stain containing the organic matter of carbonization or partial carbonization.Greasy dirt once enters stone material table
Surface layer, due to the specific surface area that oil is very large in the contact angle of inorganic material surface very little and stone material micropore, these stone materials pair
The adsorption capacity and package action of greasy dirt are quite strong, therefore are difficult to clean up.
Chinese patent CN103525583A discloses a kind of silicate product greasy dirt detergent, and the weight of each component is matched
Than are as follows: sodium hypochlorite 30%~45%, calcium carbonate 5%~10%, n-Propyl Bromide 5%~10%, acetone 5%~15%, acetic acid
Ethyl ester 2%~8%, surfactant 10%~20%, surplus are deionized water.CN103103028A discloses a kind of marble
Ground cleaning agent and preparation method thereof.In parts by weight, the present invention is composed of the following components: neopelex: 5~
10, sodium bicarbonate: 2~5, ethylene glycol monobutyl ether: 10~18, sodium pyrophosphate: 2~4, sodium citrate: 1~3, ethylenediamine tetra-acetic acid
Sodium: 1~3, methacrylate: 20~30, butyl acetate: 20~30, essence: 0.2~0.4, water: 1000~2000.
CN101225347A discloses a kind of stone special-purpose cleaning agent, constituent component and weight proportion be respectively sodium hypochlorite 40~
60%, trichloro ethylene 8~12%, acetone 10~20%, surfactant 15~25%, butyl ester 2~7%.
Japan Patent JPH03182596A discloses a kind of liquid ground cleaner.The detergent includes 1~5% anion
Surfactant (such as sodium n-alkylbenzenesulfonate), 2~10% nonionic surfactants (such as ethoxylated dodecyl alcohol),
0.1~2% hydroxy alkyl cellulose and 1~5% low-carbon alcohols, pH9~12.JPH06322398 (A) discloses a kind of hard surface
Cleaning agent.The detergent include 0.1~30% amphoteric surfactant, 0.1~5% fatty acid salt containing 8-22 carbon, 0.1~
50% solvent, 0.1~50% metal ion chelation agent.
Korean Patent KR101005656B1 discloses a kind of stone material cleaning agent.The cleaning agent include sodium metasilicate 11~
14%, sodium hydroxide 1.1~2%, butyl cellosolve 4~6%, nonyl phenol 0.2~0.4%, ethanol amine 1~5%, three nitrogen of benzo
Azoles 2~4%, nitric acid 2~6% and water 65~75%.
German patent DE 102005034604A1 discloses a kind of cleaning for handling hard surface and antiscuffing paste, the formula
By at least 0.05 part of sweet orange terpenes, 1000~1500 parts of glycerol, 1000 parts of whiting compositions.
The current generally existing following disadvantage of stone material cleaning agent is found by research: 1, detergency is low, corrodes stone material, due to
The characteristic and performance of stone material itself keep the cleaning effect of the greasy dirt spot in the microvoids such as this kind of cleaning stone material, cement products low；2,
It is at high cost, the main component and auxiliary materials of these formulas, higher cost；3, the feature of environmental protection is poor, due to having used highly basic in formula
And n-Propyl Bromide, the solvent of trichloro ethylene high volatile or as solvent there is preferable dissolution to greasy dirt containing chlorine, but easy
Volatilization and toxicity height, are used for a long time, very big to human body and environmental hazard.
Summary of the invention
It is a primary object of the present invention in view of the deficiency of the prior art, provide a kind of cleaning agent composition
With cleaning agent and its application on cleaning various stone materials in various greasy dirt spots.
To achieve the goals above, on the one hand, the present invention provides a kind of cleaning agent composition, the composition contains lemon
Lemon alkene, glycol monoalkyl ether and surfactant, the weight ratio of each component are 1:0.10~2.0:0.01~1.0, preferably 1:
0.5~1.5:0.1~0.5.
Preferably, the glycol in the glycol monoalkyl ether is selected from ethylene glycol, diethylene glycol, propylene glycol and dipropylene glycol
At least one of.
Preferably, the alkyl in the glycol monoalkyl ether is selected from methyl, ethyl, n-propyl, normal-butyl and n-hexyl
At least one of.
Preferably, the surfactant is selected from diisooctyl succinate sodium sulfonate, C8-C18Alkyl glycosides, C8-C18Alkanol
Amide, the linear chain or branched chain fatty alcohol polyoxyethylene ether and alkyl phenol polyoxyethylene ether that hydrophilic lipophilic balance (HLB) is 8-15
At least one of.
Preferably, also contain solvent, solvent is selected from ethyl alcohol, at least one of isopropanol.
On the other hand, the present invention provides a kind of cleaning agent, which contains above-mentioned cleaning agent composition and water.
Preferably, the content of the cleaning agent composition is 5~80 weight %, preferably 20~50 weight %.
In another aspect, the application the present invention provides above-mentioned cleaning agent in various stone surface supernatant washing oil stains, special
It is not suitable for natural marble, the cleaning of the greasy dirt spot on granite.
Through the above technical solutions, cleaning agent chemical property of the invention is stablized, combined for environmental-friendly cleaning agent
Object meets environmentally protective requirement；Cleaning agent of the invention can use in the cleaning process that various stone surfaces oil stain,
With excellent cleaning performance, dosage is few, and treatment process is simple and effect is obvious, application easy to spread.
Other features and advantages of the present invention will the following detailed description will be given in the detailed implementation section.
Specific embodiment
Detailed description of the preferred embodiments below.It should be understood that described herein specific
Embodiment is merely to illustrate and explain the present invention, and is not intended to restrict the invention.
Cleaning agent composition provided by the invention, the composition contain limonene, glycol monoalkyl ether and surface-active
Agent, the weight ratio of each component are 1:0.10~2.0:0.01~1.0, preferably 1:0.5~1.5:0.1~0.5.
Wherein, the limonene is the important composition ingredient in cleaning agent composition, to the various greasy dirt spots of stone surface
With outstanding cleaning performance, energy rapid osmotic stone material micropore understands deep layer oil mark, smell faint scent, safety and environmental protection, and have
With the nonreactive characteristic of stone material, the integrality of stone material ensure that.The limonene can choose from pure natural citrus
Pericarp extraction of essential oil object (such as Bergamot, sweet orange oil, grapefruit essential oil, lime essential oil, lemon) or chemistry close
At.
The glycol monoalkyl ether is the important component of cleaning agent composition, can promote the cleaning of oil foulant,
And there is infiltration function, the speed and effect of cleaning are improved, deep layer oil mark is removed.Under preferable case, wherein the glycol can be with
For ethylene glycol, diethylene glycol, propylene glycol, at least one of dipropylene glycol；Wherein, the alkyl can be methyl, ethyl, just
Propyl, one of normal-butyl and n-hexyl.Under the conditions of more preferably, the glycol monoalkyl ether is selected from glycol monoethyl ether, second
2-ethoxyethanol, ethylene glycol monobutyl ether, ethylene glycol monohexylether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol list
Butyl ether, propylene glycol monomethyl ether, dihydroxypropane single-ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, dipropylene glycol monomethyl ether, dipropyl
2-ethoxyethanol, at least one of Dipropylene glycol mono-n-butyl Ether.
The surfactant is the constituent in cleaning agent composition, and the speed and cleaning of cleaning can be improved
Completeness, oil emulsion stain can be at least one of any kind of surfactant.As alkyl or aryl sulfuric acid,
Sodium sulfonate, potassium sulfonate, ichthyodin, alkyl phosphate salt, alkyl carboxylate, alkyl sulfonyl amine salt, fatty alcohol polyoxyethylene ether, alkane
Base glucosides, alkanolamide, alkyl quaternary ammonium salts or Fixanol etc..Under preferable case, the surfactant is selected from
Diisooctyl succinate sodium sulfonate, C8-C18 alkyl glycosides, C8-C18 alkanolamide, hydrophilic lipophilic balance (HLB) are 8~15
Fatty alcohol polyoxyethylene ether or at least one of nonylphenol polyoxyethylene ether or octyl phenol polyoxyethylene ether.
In addition the cleansing composition can also contain solvent, and solvent is mainly used for shortening dry after stone surface cleans
The dry time.The solvent can be selected from ethyl alcohol, at least one of isopropanol.
Cleaning agent of the invention contains above-mentioned cleaning agent composition and water.
According to the present invention, the content of cleaning agent composition can according to need and select in a wider range in the cleaning agent
It selects, under preferable case, the content of the cleaning agent composition is 5~80 weight %, further preferably 20~50 weight %.
According to the present invention, the cleaning agent can be obtained by existing various methods, such as can will be formed described clear
The raw material of lotion is uniformly mixed according to aforementioned required ratio and is made, therefore the step of present invention is to the mixing and condition are without spy
It is different to require.
The application of cleaning agent of the invention in the greasy dirt spot cleaned on various stone materials, which is characterized in that the cleaning agent
For above-mentioned cleaning agent.
The present invention will be described in detail by way of examples below.Embodiment 1-6 is used to illustrate cleaning agent composition
And preparation method thereof.The reagent used in embodiment is as follows: ethyl alcohol and isopropanol are pure (the Chinese medicines group chemistry examination of analysis
Agent Co., Ltd)；Limonene, glycol monoethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol monohexylether, diethyl two
Alcohol monomethyl ether, diethylene glycol monoethyl ether and diethylene glycol monobutyl ether are that analysis is pure (purchased from Tokyo chemical industry Co., Ltd)；
Propylene glycol monomethyl ether, dihydroxypropane single-ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, dipropylene glycol monomethyl ether, dipropylene glycol list
Ether and Dipropylene glycol mono-n-butyl Ether are that analysis is pure (purchased from Sigma-Aldrich)；Diisooctyl succinate sodium sulfonate, C8-C18
Alkyl glycosides, alkanolamide, TX-7, OP-10, TX-15, MOA-7, MOA-9 and O-8 are that technical grade (is purchased from Jiangsu Hai'an
Petrochemical plant).
Embodiment 1
Weigh 10.0 grams of limonenes, 2.0 grams of propylene glycol monomethyl ethers, 3.0 grams of glycol monoethyl ethers, 5.0 grams of ethylene glycol only son
Ether, 1.0 grams of alkanolamides, 1.0 grams of OP-10,1.0 grams of MOA-7,10 grams of isopropanols are finally diluted with water to 80% content solution,
It stirs evenly.
Embodiment 2
Weigh 10.0 grams of limonenes, 1.0 grams of diethylene glycol monobutyl ethers, 2.0 grams of ethylene glycol monoethyl ethers, 2.0 grams of propylene glycol lists
Ether, 2.0 grams of diisooctyl succinate sodium sulfonates, 1.0 grams of TX-7,2.0 grams of C8-C18 alkyl glycosides, 20.0 grams of ethyl alcohol, finally
It is diluted with water to 50% content solution, is stirred evenly.
Embodiment 3
Weigh 10.0 grams of limonenes, 1.0 grams of ethylene glycol monohexylethers, 2.0 grams of diethylene glycol monomethyl ethers, 3.0 grams of dipropylene glycol
Single ether, 4.0 grams of dipropylene glycol monomethyl ethers, 5.0 grams of propylene glycol monobutyl ethers, 0.5 gram of TX-7,0.5 gram of MOA-7 are finally dilute with water
It is interpreted into 30% content solution, is stirred evenly.
Embodiment 4
Weigh 10.0 grams of limonenes, 0.5 gram of diethylene glycol monoethyl ether, 0.5 gram of Dipropylene glycol mono-n-butyl Ether, 2.0 grams of TX-15,
2.0 grams of O-8,6.0 grams of MOA-9, are finally diluted with water to 30% content solution, stir evenly.
Embodiment 5
Weigh 10.0 grams of limonenes, 10.0 grams of ethylene glycol monobutyl ethers, 10.0 grams of diethylene glycol monobutyl ethers, 0.1 gram of MOA-9,
It is finally diluted with water to 50% content solution, is stirred evenly.
Embodiment 6
Weigh 10.0 grams of limonenes, 2.0 grams of ethylene glycol monohexylethers, 6.0 grams of Dipropylene glycol mono-n-butyl Ethers, 10.0 grams of diethylene glycols
Monobutyl ether, 2.5 grams of alkanolamides, 5.0 grams of MOA-7,10.0 grams of isopropanols are finally diluted with water to 20% content solution, stirring
Uniformly.
Comparative example 1
Cleaning agent is prepared according to CN103525583A embodiment 1.
Comparative example 2
Cleaning agent is prepared according to CN103103028A embodiment 1.
Test case 1
Marble/granite testing piece specification: 50 × 25 × 2mm.
Cleaning agent oil removing performance: test piece is dipped into miscella (diesel oil: salad oil=1:1) and is taken after (room temperature) within 2 hours
Out, it after dry, is cleaned with cleaning agent, test cleaning oil mark performance.Referring to DB11/T512-2007, " building decoration engineering stone material is answered
With technical regulation " and GB/T25146-2010 " industrial equipment chemical cleaning inspection of quality specification ", respectively to embodiment 1-6 and right
The cleaning performance of the resulting stone material cleaning agent composition of ratio 1-2 is evaluated.
Table 1
| Embodiment | Mass concentration/% | Clean rate/the % of removing oil mark/ | Effect assessment |
| Embodiment 1 | 80 | 100 | It is excellent |
| Embodiment 1 | 50 | 100 | It is excellent |
| Embodiment 1 | 5 | 95 | It is excellent |
| Embodiment 2 | 50 | 99 | It is excellent |
| Embodiment 2 | 10 | 96 | It is excellent |
| Embodiment 3 | 30 | 98 | It is excellent |
| Embodiment 4 | 30 | 98 | It is excellent |
| Embodiment 5 | 50 | 99 | It is excellent |
| Embodiment 5 | 10 | 95 | It is excellent |
| Embodiment 6 | 20 | 98 | It is excellent |
| Comparative example 1 | - | 85 | It is good |
| Comparative example 2 | - | 90 | It is good |
Can be seen that cleaning agent of the invention composition from the evaluation experimental result of table 1 has good cleaning performance,
Cleaning agent after adding composition for cleaning of the invention, oil mark clean rate >=95%, therefore, cleaning agent group of the invention
It closes object and can meet stone material and oil the cleaning requirement of stain.
The preferred embodiment of the present invention has been described above in detail, still, during present invention is not limited to the embodiments described above
Detail within the scope of the technical concept of the present invention can be with various simple variants of the technical solution of the present invention are made, this
A little simple variants all belong to the scope of protection of the present invention.
It is further to note that specific technical features described in the above specific embodiments, in not lance
In the case where shield, can be combined in any appropriate way, in order to avoid unnecessary repetition, the present invention to it is various can
No further explanation will be given for the combination of energy.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally
The thought of invention, it should also be regarded as the disclosure of the present invention.
Claims (4)
1. various greasy dirt spot cleaning agents on a kind of cleaning stone material, which is characterized in that the cleaning agent contains cleaning agent composition
And water, the cleaning agent are made of with composition limonene, glycol monoalkyl ether and surfactant, the weight ratio of each component is 1:
0.10~2.0:0.01~1.0；
The surfactant is selected from C8-C18Alkanolamide, the linear chain or branched chain that hydrophilic lipophilic balance (HLB) is 8-15 fat
At least one of alcohol polyoxyethylene ether and alkyl phenol polyoxyethylene ether；
Also contain solvent, solvent is selected from at least one of ethyl alcohol, isopropanol.
2. cleaning agent according to claim 1, which is characterized in that the glycol in the glycol monoalkyl ether is selected from second two
At least one of alcohol, diethylene glycol, propylene glycol and dipropylene glycol.
3. cleaning agent according to claim 1, which is characterized in that the alkyl in the glycol monoalkyl ether is selected from first
At least one of base, ethyl, n-propyl, normal-butyl and n-hexyl.
4. cleaning agent according to claim 1, which is characterized in that the content of the cleaning agent composition is 5~80 weights
Measure %.
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106235934A (en) * | 2015-06-11 | 2016-12-21 | 天津市地文高科技发展有限公司 | A kind of bathroom cleaning wet tissue |
| CN106593005B (en) * | 2016-12-26 | 2019-02-15 | 怀宁县三禾保洁服务有限公司 | A kind of lintel renovation technology |
| CN110158105A (en) * | 2019-05-31 | 2019-08-23 | 广东润和新材料科技有限公司 | A kind of detergent of environment protection multifunctional aircraft maintenance |
| CN110777010A (en) * | 2019-11-29 | 2020-02-11 | 陕西速源节能科技有限公司 | Bathroom cleaning agent and preparation method thereof |
| IT202100019082A1 (en) | 2021-07-19 | 2023-01-19 | Univ Degli Studi Di Palermo | Composition for cleaning artifacts |
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| US5281354A (en) * | 1991-10-24 | 1994-01-25 | Amway Corporation | Liquid cleanser composition |
| CN101230310A (en) * | 2007-01-25 | 2008-07-30 | 3M创新有限公司 | Cleaning method and combination |
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