CN113073014B - Multifunctional cleaning agent capable of efficiently removing oil and stains and preparation method thereof - Google Patents
Multifunctional cleaning agent capable of efficiently removing oil and stains and preparation method thereof Download PDFInfo
- Publication number
- CN113073014B CN113073014B CN202110351327.3A CN202110351327A CN113073014B CN 113073014 B CN113073014 B CN 113073014B CN 202110351327 A CN202110351327 A CN 202110351327A CN 113073014 B CN113073014 B CN 113073014B
- Authority
- CN
- China
- Prior art keywords
- cleaning agent
- stains
- parts
- surfactant
- multifunctional cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/185—Hydrocarbons cyclic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2048—Dihydric alcohols branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Abstract
The invention discloses a multifunctional cleaning agent for efficiently removing oil and stains and a preparation method thereof, wherein the multifunctional cleaning agent is prepared from the following raw materials in percentage by weight: 1.0-1.5% of sodium citrate, 0.5-2.0% of isohexane glycol, 3.0-6.0% of diethylene glycol ethyl ether, 3.0-4.5% of nonionic surfactant, 0.5-1.5% of cationic surfactant, 1.0-1.5% of benzyl alcohol, 2.0-2.5% of D-limonene, 1.0-1.7% of pH regulator, 0.5% of essence and the balance of water; the components are stirred and mixed at normal temperature to obtain the product. The invention adds diethylene glycol monobutyl ether as a solvent, adopts isopropanolamine as a pH regulator, uses a nonionic gemini surfactant with high permeability and high stripping property, and assists a cationic gemini surfactant to enhance the integral decontamination performance, and various raw materials are ingeniously matched and matched with each other, so that various heavy oil stains, blue-black ink stains, grass stains and the like can be quickly removed.
Description
Technical Field
The invention relates to the technical field of washing products, in particular to a multifunctional cleaning agent for efficiently removing oil and stains and a preparation method thereof.
Background
With the development of society, the requirements of people on environmental protection, energy conservation and emission reduction are continuously improved, and the requirements on cleaning agents are gradually improved. The cleaning agents in the current market mainly comprise water-based cleaning agents, semi-solvent type cleaning agents and solvent type cleaning agents, wherein the water-based cleaning agents mainly use surfactants as main materials, most of the water-based cleaning agents are added with phosphorus inorganic salts to improve the cleaning capability, but the problem of eutrophication pollution caused by the discharge of phosphorus substances into the environment is gradually revealed, the biodegradation performance of some traditional surfactants is poor, and the solvents selected by the semi-solvent type cleaning agents and the solvent type cleaning agents are mainly organic solvents such as petroleum, fluorine and fluorocarbon, and the like, so that although the decontamination efficiency is high, the organic solvents are generally low in flash point, high in toxicity, flammable and large in harm to human bodies, and the large-amount storage in the production is also a great potential safety hazard; the heavy oil stain cleaning agent with great demand in families and industry generally needs a large amount of sodium hydroxide or potassium hydroxide and needs high temperature to achieve the cleaning effect, but the cleaning agent has strong alkalinity, hurts hands and has great corrosivity on cleaned objects. In a word, most of cleaning agents in the current market have certain defects, and most of the cleaning agents can only aim at a certain specific dirt or cleaning object, and can meet the living needs by multiple cleaning agents, even a single-effect cleaning agent still has the problem of weak capability of cleaning heavy stains, such as heavy oil stain, blue-black ink, grass stains and the like, which are still worried, especially for ink cleaning agent removal, most of the cleaning agents can only well remove the blue ink which is easy to fade and oxidize, while the blue-black ink contains ferrous tannate, becomes ferric tannate after oxidation, never fades, and is extremely difficult to remove after being sold with the cleaning agents. In conclusion, the development of multifunctional efficient cleaning agents has become an industry development trend.
Disclosure of Invention
The invention aims to provide a multifunctional cleaning agent for efficiently removing oil and stains, which can remove various heavy oil stains, blue-black ink stains, grass stains, signature handwriting and the like.
The invention also aims to provide a preparation method of the multifunctional cleaning agent for efficiently removing oil and stains, which has simple process and can be used for industrial production.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows: a multifunctional cleaning agent for efficiently removing oil and stains is prepared from the following raw materials in percentage by weight: 1.0-1.5% of sodium citrate, 0.5-2.0% of isohexane glycol, 3.0-6.0% of diethylene glycol ethyl ether, 3.0-4.5% of nonionic surfactant, 0.5-1.5% of cationic gemini surfactant, 1.0-1.5% of benzyl alcohol, 2.0-2.5% of D-limonene, 1.0-1.7% of pH regulator, 0.5% of essence and the balance of water; wherein the nonionic surfactant is a compound of narrow-distribution C9-11 fatty alcohol-polyoxyethylene ether and ethylene-bis (N-ethanesulfonic acid-dodecanamide) sodium salt, and the mass ratio is 1:1-2: 1; the cationic surfactant is ethylene-based bis (tetradecylpolyoxyethylene/polyoxypropylene block ammonium chloride) and dodecyl dimethyl benzyl ammonium chloride 1227, and the mass ratio is 1:1-8: 5.
Preferably, the multifunctional cleaning agent for efficiently removing oil and stains is prepared from the following raw materials in percentage by weight: 1.0% of sodium citrate, 2.0% of isohexane glycol, 5.0% of diethylene glycol ethyl ether, 4.5% of nonionic surfactant, 1.3% of cationic gemini surfactant, 1.2% of benzyl alcohol, 2.0% of D-limonene, 1.5% of pH regulator, 0.5% of essence and 81.0% of water; wherein the nonionic surfactant is a mixture of narrow-distribution C9-11 fatty alcohol-polyoxyethylene ether and ethylene-bis (N-ethanesulfonic acid-dodecanamide) sodium salt, and the mass ratio is 2: 1; the cationic surfactant is ethylene-based bis (tetradecylpolyoxyethylene/polyoxypropylene block ammonium chloride) and dodecyl dimethyl ammonium chloride 1227, and the mass ratio is 8: 5.
Preferably, the pH regulator is isopropanolamine.
The invention also provides a preparation method of the multifunctional cleaning agent for efficiently removing oil and stains, which comprises the following steps:
1) adding water with the formula amount into a stirring tank, adding sodium citrate, and stirring and dispersing for 10-15 minutes;
2) sequentially adding solvents of isohexane glycol and diethylene glycol ethyl ether, stirring for 5-8 minutes, uniformly mixing, sequentially adding a nonionic surfactant and a cationic surfactant, stirring and dispersing for 15-20 minutes, adding benzyl alcohol and D-limonene, and uniformly mixing;
3) and finally, adding a pH regulator to regulate the pH of the system to 10-11, adding essence, sampling, detecting, discharging, and packaging to obtain a finished product.
Compared with the prior art, the invention has the following beneficial effects:
1. the multifunctional cleaning agent has scientific formula, fully integrates the dissolving power of the solvent, the alkalinity of the alkaline substance and the decontamination characteristic of the gemini surfactant through the compounding of the solvent, the alkaline substance and the surfactant, enhances the penetration, emulsification and dispersion of stains, can quickly and effectively remove heavy oil stains, old blue and black ink stains, grass stains, signature handwriting and the like, and is a multifunctional household cleaning agent;
2. the multifunctional cleaning agent adopts the alcohol ether type solvent diethylene glycol ethyl ether, has no pungent smell, has high flash point, contains alcohol and ether functional groups in molecules, can be fused with different phases due to unique polarity and nonpolar solubility of the molecules, reduces the surface tension of a system, permeates and softens pollutants, and obviously improves the decontamination capability of the cleaning agent.
3. The multifunctional cleaning agent provided by the invention abandons the traditional alkaline substances of sodium hydroxide, potassium hydroxide or triethanolamine, adopts environment-friendly isopropanolamine with excellent performance to provide an alkaline environment, has little harm to skin, and simultaneously, the isopropanolamine can reduce the interfacial tension of a solvent, so that the product can exert good rapid cleaning capability at normal temperature, the effect of cleaning oil stains on hard surfaces by spraying and wiping is achieved, and the strong decontamination capability of the isopropanolamine also improves the performance of the cleaning agent.
4. The cationic surfactant ethylene-based bis (tetradecylpolyoxyethylene/polyoxypropylene block ammonium chloride) and dodecyl dimethyl ammonium chloride 1227 added in the invention are compounded with nonionic surfactant, so that the penetration and decontamination performance of the system can be improved, and the cationic surfactant has the characteristics of corrosion resistance and sterilization.
Drawings
FIG. 1 is a diagram showing the effect of the cleaning agent of example 1 on the treatment of stainless steel sheets stained with heavy oil: (a) a stainless steel sheet stained with heavy oil stains before treatment; (b) stainless steel sheets cleaned with the cleaning agent of example 1;
FIG. 2 is a graph showing the effect of the cleaning agent of example 1 on the treatment of white cotton cloth stained with blue and black ink: (a) before treatment, the cotton cloth is stained with blue and black ink; (b) the white cotton cloth stained with blue and black ink after the cleaning agent of example 1 was sprayed for 30 seconds; (c) the white cotton cloth stained with blue and black ink after the cleaning agent treatment of example 1;
FIG. 3 is a graph showing the effect of the cleaning agent of example 1 on the treatment of the white cotton cloth stained with grass stains: (a) white cotton cloth stained with grass stains before treatment; (b) the white cotton cloth stained with grass stains was sprayed with the cleaning agent of example 1 for 30 seconds; (c) the treated white cotton cloth of example 1 was stained with grass stains.
Detailed Description
The invention is described in further detail below with reference to the figures and specific examples.
Example 1
A multifunctional cleaning agent for efficiently removing oil and stains is prepared from the following raw materials in parts by weight: 81.0 parts of water, 1.0 part of sodium citrate, 2.0 parts of isohexane glycol, 5.0 parts of diethylene glycol ethyl ether, 4.5 parts of nonionic surfactant, 1.3 parts of cationic surfactant, 1.2 parts of benzyl alcohol, 2.0 parts of D-limonene, 1.5 parts of isopropanolamine and 0.5 part of essence. Wherein the nonionic surfactant is a mixture of narrow-distribution C9-11 fatty alcohol-polyoxyethylene ether and ethylene-bis (N-ethanesulfonic acid-dodecanamide) sodium salt, and the mass ratio is 2: 1; the cationic surfactant is ethylene-based bis (tetradecylpolyoxyethylene/polyoxypropylene block ammonium chloride) and dodecyl dimethyl ammonium chloride 1227, and the mass ratio is 8: 5.
The preparation method of the multifunctional cleaning agent comprises the following specific steps:
step 1, adding 81.0 parts of water into a stirring tank, adding 1.0 part of sodium citrate, and stirring and dispersing for 10-15 minutes;
step 2, sequentially adding 2.0 parts of solvent isohexane glycol and 5.0 parts of diethylene glycol ethyl ether, stirring for 5-8 minutes, uniformly mixing, sequentially adding 3.0 parts of narrow-distribution C9-11 fatty alcohol-polyoxyethylene ether and 1.5 parts of ethylene-bis (N-ethanesulfonic acid-dodecanamide) sodium salt, uniformly stirring and dispersing, then adding 0.8 part of ethylene-based bis (tetradecylpolyoxyethylene/polyoxypropylene block ammonium chloride) and 0.5 part of dodecyl dimethyl ammonium chloride 1227, and stirring and dispersing for 15-20 minutes;
step 3, adding 1.2 parts of benzyl alcohol and 2.0 parts of D-limonene, and stirring and mixing uniformly;
and 4, adding 1.5 parts of isopropanolamine to adjust the pH of the system to 10-11, adding 0.5 part of essence, stirring and mixing uniformly, sampling, detecting and discharging after the sample is qualified, and packaging to obtain a finished product.
The physical and chemical indexes of the multifunctional cleaning agent are as follows:
example 2
A multifunctional cleaning agent for efficiently removing oil and stains is prepared from the following raw materials in parts by weight: 81.0 parts of water, 1.0 part of sodium citrate, 1.0 part of isohexane glycol, 6.0 parts of diethylene glycol ethyl ether, 4.5 parts of nonionic surfactant, 1.3 parts of cationic surfactant, 1.2 parts of benzyl alcohol, 2.0 parts of D-limonene, 1.5 parts of isopropanolamine and 0.5 part of essence. Wherein the nonionic surfactant is a mixture of narrow-distribution C9-11 fatty alcohol-polyoxyethylene ether and ethylene-bis (N-ethanesulfonic acid-dodecanamide) sodium salt, and the mass ratio is 2: 1; the cationic surfactant is ethylene-based bis (tetradecylpolyoxyethylene/polyoxypropylene block ammonium chloride) and dodecyl dimethyl ammonium chloride 1227, and the mass ratio is 8: 5.
The preparation method is the same as that of example 1.
The physical and chemical indexes of the multifunctional cleaning agent are as follows:
example 3
A multifunctional cleaning agent for efficiently removing oil and stains is prepared from the following raw materials in parts by weight: 81.0 parts of water, 1.0 part of sodium citrate, 2.0 parts of isohexane glycol, 5.0 parts of diethylene glycol ethyl ether, 4.5 parts of nonionic surfactant, 1.3 parts of cationic surfactant, 1.2 parts of benzyl alcohol, 2.0 parts of D-limonene, 1.5 parts of isopropanolamine and 0.5 part of essence. Wherein the nonionic surfactant is a mixture of narrow-distribution C9-11 fatty alcohol-polyoxyethylene ether and ethylene-bis (N-ethanesulfonic acid-dodecanamide) sodium salt, and the mass ratio is 5: 4; the cationic surfactant is ethylene-based bis (tetradecylpolyoxyethylene/polyoxypropylene block ammonium chloride) and dodecyl dimethyl ammonium chloride 1227, and the mass ratio is 8: 5.
The preparation method is the same as that of example 1.
The physical and chemical indexes of the multifunctional cleaning agent are as follows:
comparative example 1
A multifunctional cleaning agent is prepared from the following raw materials in parts by weight: 82.2 parts of water, 1.0 part of sodium citrate, 2.0 parts of isohexane glycol, 5.0 parts of diethylene glycol ethyl ether, 4.5 parts of nonionic surfactant, 1.3 parts of cationic surfactant, 1.2 parts of benzyl alcohol, 2.0 parts of D-limonene, 0.3 part of sodium hydroxide and 0.5 part of essence. Wherein the nonionic surfactant is a mixture of narrow-distribution C9-11 fatty alcohol-polyoxyethylene ether and ethylene-bis (N-ethanesulfonic acid-dodecanamide) sodium salt, and the mass ratio is 2: 1; the cationic surfactant is ethylene-based bis (tetradecylpolyoxyethylene/polyoxypropylene block ammonium chloride) and dodecyl dimethyl ammonium chloride 1227, and the mass ratio is 8: 5.
The preparation method is the same as that of example 1.
The physical and chemical indexes of the multifunctional cleaning agent are as follows:
comparative example 2
A multifunctional cleaning agent is prepared from the following raw materials in parts by weight: 82.3 parts of water, 1.0 part of sodium citrate, 2.0 parts of isohexane glycol, 5.0 parts of diethylene glycol ethyl ether, 4.5 parts of nonionic surfactant, 1.5 parts of isopropanolamine, 1.2 parts of benzyl alcohol, 2.0 parts of D-limonene and 0.5 part of essence. Wherein the nonionic surfactant is a mixture of narrow-distribution C9-11 fatty alcohol-polyoxyethylene ether and ethylene-bis (N-ethanesulfonic acid-dodecanoamide) sodium salt, and the mass ratio is 2: 1.
The preparation method is the same as that of example 1.
The physical and chemical indexes of the multifunctional cleaning agent are as follows:
comparative example 3
A multifunctional cleaning agent is prepared from the following raw materials in parts by weight: 81.8 parts of water, 1.0 part of sodium citrate, 2.0 parts of isohexane glycol, 5.0 parts of diethylene glycol ethyl ether, 4.5 parts of nonionic surfactant, 0.5 part of dodecyl dimethyl ammonium chloride, 1.5 parts of isopropanolamine, 1.2 parts of benzyl alcohol, 2.0 parts of D-limonene and 0.5 part of essence. Wherein the nonionic surfactant is a mixture of narrow-distribution C9-11 fatty alcohol-polyoxyethylene ether and ethylene-bis (N-ethanesulfonic acid-dodecanoamide) sodium salt, and the mass ratio is 2: 1.
The preparation method is the same as that of example 1.
The physical and chemical indexes of the multifunctional cleaning agent are as follows:
comparative example 4
A multifunctional cleaning agent is prepared from the following raw materials in parts by weight: 81.0 parts of water, 1.0 part of sodium citrate, 7.0 parts of isohexane glycol, 4.5 parts of nonionic surfactant, 1.3 parts of cationic surfactant, 1.5 parts of isopropanolamine, 1.2 parts of benzyl alcohol, 2.0 parts of D-limonene and 0.5 part of essence. Wherein the nonionic surfactant is a mixture of narrow-distribution C9-11 fatty alcohol-polyoxyethylene ether and ethylene-bis (N-ethanesulfonic acid-dodecanamide) sodium salt, and the mass ratio is 2: 1; the cationic surfactant is ethylene-based bis (tetradecylpolyoxyethylene/polyoxypropylene block ammonium chloride) and dodecyl dimethyl ammonium chloride 1227, and the mass ratio is 8: 5.
The preparation method is the same as that of example 1.
The physical and chemical indexes of the multifunctional cleaning agent are as follows:
comparative example 5
A multifunctional cleaning agent is prepared from the following raw materials in parts by weight: 81.0 parts of water, 1.0 part of sodium citrate, 2.0 parts of isohexane glycol, 5.0 parts of diethylene glycol ethyl ether, 4.5 parts of narrow-distribution C9-11 fatty alcohol-polyoxyethylene ether, 1.3 parts of cationic surfactant, 1.5 parts of isopropanolamine, 1.2 parts of benzyl alcohol, 2.0 parts of D-limonene and 0.5 part of essence. The cationic surfactant is ethylene-based bis (tetradecylpolyoxyethylene/polyoxypropylene block ammonium chloride) and dodecyl dimethyl ammonium chloride 1227, and the mass ratio is 8: 5.
The preparation method is the same as that of example 1.
The physical and chemical indexes of the multifunctional cleaning agent are as follows:
comparative example 6
A multifunctional cleaning agent is prepared from the following raw materials in parts by weight: 81.0 parts of water, 1.0 part of sodium citrate, 2.0 parts of isohexane glycol, 5.0 parts of diethylene glycol ethyl ether, 4.5 parts of ethylene-bis (N-ethanesulfonic acid-dodecanamide) sodium salt, 1.3 parts of cationic surfactant, 1.45 parts of isopropanolamine, 1.2 parts of benzyl alcohol, 2.0 parts of D-limonene and 0.5 part of essence. The cationic surfactant is ethylene-based bis (tetradecylpolyoxyethylene/polyoxypropylene block ammonium chloride) and dodecyl dimethyl ammonium chloride 1227, and the mass ratio is 8: 5.
The preparation method is the same as that of example 1.
The physical and chemical indexes of the multifunctional cleaning agent are as follows:
the effect of the multifunctional cleaning agent of the present invention was verified by the following application experiments:
1. experimental samples: stainless steel oil stain pieces, white cotton cloth stained with blue and black ink, and white cotton cloth stained with grass stains.
2. The oil stain removal rate test method comprises the following steps: visual measurement, wiping and weighing. Observing whether the stainless steel sheet contains oil stains or not by looking at the stainless steel sheet with eyes and wiping the stainless steel sheet with paper, weighing the mass of the stainless steel sheet before and after removing the oil stains, and calculating the removal rate of the oil stains, wherein the removal rate of the oil stains is (the mass of the initial stainless steel sheet-the mass of the stainless steel sheet after removing the oil stains)/the mass of the initial stainless steel sheet multiplied by 100 percent.
3. The blue-black ink and grass stain removal rate test method comprises the following steps: visual inspection and whiteness. The removal degree of blue-black ink or grass stains on white cotton cloth was visually observed, and the removal rate of blue-black ink or grass stains, which is (whiteness after washing-whiteness before washing)/(whiteness before white cotton cloth-whiteness before washing) x 100%, was calculated by measuring the whiteness values of white cotton cloth, white cotton cloth containing stains, and white cotton cloth after washing stains.
The multifunctional cleaning agent prepared in the examples 1-3 and the comparative examples 1-6 is used for treating stainless steel oil stain sheets respectively, and the treatment method comprises the following steps: the prepared multifunctional cleaning agent is treated by referring to standard QB/T4348-2012 kitchen greasy dirt cleaning agent to obtain a dirty sheet (wiredrawing stainless steel) stained with kitchen heavy greasy dirt, and the steps are as follows: putting the test piece into a normal-temperature multifunctional cleaning agent, wherein the liquid level is higher than the height of the test piece, completely soaking the test piece for 1-10min, swinging and washing for 2min, taking out the test piece, drying in an oven at (120 +/-2) DEG C for 45min, and cooling in a dryer for 30 min. The oil stain removal rate of the soiled pieces was measured, and the results are shown in Table 1.
Taking example 1 as an example, comparing the stain sheets before and after treatment (fig. 1), it is known that the multifunctional cleaning agent prepared in example 1 can rapidly remove the stain on the surface of stainless steel without obvious corrosion.
The multifunctional cleaning agent prepared in the examples 1-3 and the comparative examples 1-6 is used for respectively treating white cotton cloth stained with blue-black ink or grass stains, and the specific treatment method is as follows: fixing the dirty cloth on a bracket, spraying a cleaning agent, standing for 30s-10min, then spraying clear water, naturally drying, measuring the whiteness of the white cotton cloth, and further calculating the removal rate of blue-black ink or grass stains, wherein the results are shown in table 1.
By taking the example 1 as an example, the pictures (fig. 2 and 3) of the cotton cloth before and after the treatment and the pictures after spraying the cleaning agent for 30s show that the multifunctional cleaning agent prepared in the example 1 can completely remove the blue-black ink and the grass marks on the surface of the cotton cloth.
TABLE 1 treatment Effect of different multifunctional detergents
Note: ND is the stain remained on the surface of the stainless steel or the surface of the white cotton cloth after 10min of treatment.
From table 1, it can be seen from the comparative data of the examples and comparative examples that: 1) comparative example 1 after the isopropanolamine is replaced by sodium hydroxide, the oil stain removal rate of the stainless steel surface, the reduction of the removal rate of blue-black ink and grass stains are greatly reduced, which shows that the isopropanolamine not only can play a role in adjusting the pH, but also has a great synergistic effect on the stain removal effect; 2) in comparative example 2, cationic surfactant ethylene-based bis (tetradecylpolyoxyethylene/polyoxypropylene block ammonium chloride) and dodecyl dimethyl benzyl ammonium chloride 1227 were not added, and the obtained cleaning agent was an unstable milky liquid, in comparative example 3, no cationic surfactant ethylene-based bis (tetradecylpolyoxyethylene/polyoxypropylene block ammonium chloride) was added, and the obtained cleaning agent was a stable milky liquid, and the removal rate of the oil stain, the blue-black ink and the grass stain on the surface of the stainless steel is reduced in the comparative examples 2 and 3, these phenomena show that the cationic surfactant can increase the solubility of each component in water and increase the stability of the product, and the ethylene-based bis (tetradecylpolyoxyethylene/polyoxypropylene block ammonium chloride) and dodecyl dimethyl benzyl ammonium chloride 1227 are compounded and added according to a certain proportion to greatly increase the decontamination performance of the product; 3) in the formula of the comparative example 4, the oil stain on the surface of the stainless steel can be effectively removed only by using the solvent isohexane glycol, but the ideal effect can be achieved only by compounding the diethylene glycol ethyl ether for removing the blue-black ink and the grass stains, which shows that the diethylene glycol ethyl ether has a good effect on removing the blue-black ink and the grass stains; 4) in comparative example 5 and comparative example 6, when only single nonionic surfactant narrow-distribution C9-11 fatty alcohol-polyoxyethylene ether and ethylene-bis (N-ethanesulfonic acid-dodecanoamide) sodium salt are used respectively, oil stains on the surface of stainless steel, blue-black ink and grass stains on white cotton cloth can be completely removed, but the removal time is greatly increased, which shows that after the narrow-distribution C9-11 fatty alcohol-polyoxyethylene ether and the ethylene-bis (N-ethanesulfonic acid-dodecanoamide) sodium salt are compounded, the removal efficiency of the oil stains, the blue-black ink and the grass stains can be well accelerated, and also shows that the surfactant ethylene-bis (N-ethanesulfonic acid-dodecanoamide) sodium salt has good capacity of solubilizing the stains. On the other hand, through many experiments, the inventor finds that all the raw materials must be added according to the steps, and if the raw materials are directly mixed, the problems of the occurrence of degeneration, the failure of dissolution or unstable delamination of the product of individual raw materials can be caused.
The multifunctional cleaning agent provided by the invention can remove various heavy oil stains, blue-black ink stains, grass stains, signature handwriting and the like, can be used as a household multifunctional cleaning agent, and is a multifunctional efficient cleaning agent integrating kitchen heavy oil stain cleaning agent, floor cleaning agent, small white shoe cleaning agent, glass cleaning agent, down coat stain removing dry cleaning agent, clothes collar cleaning agent and household appliance cleaning agent. The cleaning agent does not contain phosphorus, is added with mild, green and high-safety solvents of isohexane glycol and diethylene glycol butyl ether, has less total surfactant and solvent consumption in the formula, has no damage to cleaning substrates, high cleaning speed, normal-temperature cleaning, little environmental pollution and good application prospect.
Claims (3)
1. The multifunctional cleaning agent for removing oil and stains is characterized by being prepared from the following raw materials in percentage by weight: 1.0-1.5% of sodium citrate, 0.5-2.0% of isohexane glycol, 3.0-6.0% of diethylene glycol ethyl ether, 3.0-4.5% of nonionic surfactant, 0.5-1.5% of cationic surfactant, 1.0-1.5% of benzyl alcohol, 2.0-2.5% of D-limonene, 1.0-1.7% of pH regulator, 0.5% of essence and the balance of water; wherein the nonionic surfactant is a compound of narrow-distribution C9-11 fatty alcohol-polyoxyethylene ether and ethylene-bis (N-ethanesulfonic acid-dodecanamide) sodium salt, and the mass ratio is 1:1-2: 1; the cationic surfactant is ethylene-based bis (tetradecylpolyoxyethylene/polyoxypropylene block ammonium chloride) and dodecyl dimethyl benzyl ammonium chloride 1227, the mass ratio is 1:1-8:5, and the pH regulator is isopropanolamine.
2. The multifunctional cleaning agent for removing oil and stains according to claim 1, which is characterized by being prepared from the following raw materials in percentage by weight: 1.0% of sodium citrate, 2.0% of isohexane glycol, 5.0% of diethylene glycol ethyl ether, 4.5% of nonionic surfactant, 1.3% of cationic surfactant, 1.2% of benzyl alcohol, 2.0% of D-limonene, 1.5% of pH regulator, 0.5% of essence and 81.0% of water; wherein the nonionic surfactant is a mixture of narrow-distribution C9-11 fatty alcohol-polyoxyethylene ether and ethylene-bis (N-ethanesulfonic acid-dodecanamide) sodium salt, and the mass ratio is 2: 1; the cationic surfactant is ethylene-based bis (tetradecylpolyoxyethylene/polyoxypropylene block ammonium chloride) and dodecyl dimethyl ammonium chloride 1227, and the mass ratio is 8: 5.
3. The preparation method of the multifunctional cleaning agent for removing oil and stains as claimed in any one of claims 1 to 2, characterized by comprising the following steps: 1) adding water with the formula amount into a stirring tank, adding sodium citrate, and stirring and dispersing for 10-15 minutes; 2) sequentially adding solvents of isohexane glycol and diethylene glycol ethyl ether, stirring for 5-8 minutes, uniformly mixing, sequentially adding a nonionic surfactant and a cationic surfactant, stirring and dispersing for 15-20 minutes, adding benzyl alcohol and D-limonene, and uniformly mixing; 3) and finally, adding a pH regulator to regulate the pH of the system to 10-11, adding essence, sampling, detecting, discharging, and packaging to obtain a finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110351327.3A CN113073014B (en) | 2021-03-31 | 2021-03-31 | Multifunctional cleaning agent capable of efficiently removing oil and stains and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110351327.3A CN113073014B (en) | 2021-03-31 | 2021-03-31 | Multifunctional cleaning agent capable of efficiently removing oil and stains and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN113073014A CN113073014A (en) | 2021-07-06 |
| CN113073014B true CN113073014B (en) | 2022-02-01 |
Family
ID=76614495
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110351327.3A Active CN113073014B (en) | 2021-03-31 | 2021-03-31 | Multifunctional cleaning agent capable of efficiently removing oil and stains and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113073014B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113528247A (en) * | 2021-08-23 | 2021-10-22 | 上海畅帆生物科技有限公司 | Heavy oil stain cleaning agent for kitchen |
| CN113667550A (en) * | 2021-09-22 | 2021-11-19 | 东莞市四辉表面处理科技有限公司 | PET plastic board cleaning agent and preparation method and use method thereof |
| CN114149875A (en) * | 2021-12-06 | 2022-03-08 | 广东舒洁环境科技有限公司 | Neutral environment-friendly cleaning agent and preparation method thereof |
| CN115386889A (en) * | 2022-08-05 | 2022-11-25 | 沈阳瑞驰表面技术有限公司 | Water-based crude oil efficient cleaning agent |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101942364A (en) * | 2010-01-15 | 2011-01-12 | 中山榄菊日化实业有限公司 | Cleaning agent composition and preparation method thereof |
| CN103525581A (en) * | 2013-09-23 | 2014-01-22 | 南通信一服饰有限公司 | Colored stain cleanser for textiles |
| CN105039007A (en) * | 2015-07-13 | 2015-11-11 | 于文 | Efficient de-oiling and bacteria-inhibiting detergent for kitchen and preparation method for efficient de-oiling and bacteria-inhibiting detergent for kitchen |
| US9670433B1 (en) * | 2015-12-28 | 2017-06-06 | Ecolab Usa Inc. | Hard surface cleaning compositions |
| CN107761123A (en) * | 2017-10-13 | 2018-03-06 | 广州迪奕科环保科技有限公司 | A kind of environmentally friendly oil pipeline cleaning agent |
| CN112662490A (en) * | 2020-12-25 | 2021-04-16 | 广东自由能科技股份有限公司 | Kitchen heavy oil stain cleaning agent, preparation method thereof and application thereof in aerosol |
-
2021
- 2021-03-31 CN CN202110351327.3A patent/CN113073014B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101942364A (en) * | 2010-01-15 | 2011-01-12 | 中山榄菊日化实业有限公司 | Cleaning agent composition and preparation method thereof |
| CN103525581A (en) * | 2013-09-23 | 2014-01-22 | 南通信一服饰有限公司 | Colored stain cleanser for textiles |
| CN105039007A (en) * | 2015-07-13 | 2015-11-11 | 于文 | Efficient de-oiling and bacteria-inhibiting detergent for kitchen and preparation method for efficient de-oiling and bacteria-inhibiting detergent for kitchen |
| US9670433B1 (en) * | 2015-12-28 | 2017-06-06 | Ecolab Usa Inc. | Hard surface cleaning compositions |
| CN107761123A (en) * | 2017-10-13 | 2018-03-06 | 广州迪奕科环保科技有限公司 | A kind of environmentally friendly oil pipeline cleaning agent |
| CN112662490A (en) * | 2020-12-25 | 2021-04-16 | 广东自由能科技股份有限公司 | Kitchen heavy oil stain cleaning agent, preparation method thereof and application thereof in aerosol |
Also Published As
| Publication number | Publication date |
|---|---|
| CN113073014A (en) | 2021-07-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN113073014B (en) | Multifunctional cleaning agent capable of efficiently removing oil and stains and preparation method thereof | |
| CN110067001B (en) | Metal cleaning agent and preparation method thereof | |
| JP5753113B2 (en) | Microemulsion cleaning composition and method for removing hydrophobic soils from articles | |
| US3839234A (en) | Multi-purpose cleaning concentrate | |
| CN106318686B (en) | Efficient environment-friendly concentrated hard surface cleaning agent | |
| CN107418771B (en) | Stripping type water-based optical glass cleaning agent | |
| CN105713740A (en) | Cleaning agent for cleaning animal oil and fat in food industry | |
| US3723330A (en) | Detergent composition | |
| CN109576067A (en) | A kind of high-efficiency heavy oil dirt cleaning agent and preparation method thereof and heavy oil dirt cleaning method | |
| CN107937168A (en) | A kind of production method of environment-friendly type degreasing cleaning agent | |
| CN104130883B (en) | A kind of cleaning agent composition and cleaning agent and its application | |
| CN102191140A (en) | Electronic circuit board detergent | |
| CN102703261B (en) | Cleaning agent for processing of precision part | |
| EP1846517A1 (en) | Agent to remove paint, lacquer, glue, plastic or similar from objects and the use of it | |
| CN109370812B (en) | Low-volatility high-performance water-based cleaning agent and cleaning method | |
| CN111286418A (en) | Plane grinding cleaning agent and preparation method thereof | |
| CN104152296A (en) | Composition for cleaning agent, cleaning agent and use of cleaning agent | |
| CN109181894A (en) | A kind of hyperconcetration dish washing liquid and preparation method | |
| CN108753485A (en) | Ozone laundry composition and preparation method thereof | |
| CN108301008A (en) | A kind of high-efficiency environment friendly Degreasant composition and preparation method thereof and application method | |
| CN105419957B (en) | A kind of glass cleaner composition of addition cationic polymer | |
| US5837667A (en) | Environmentally safe detergent composition and method of use | |
| CN113105781A (en) | Efficient environment-friendly water-based ink cleaning agent and preparation method thereof | |
| CN112322399B (en) | Cleaning agent and preparation method and application thereof | |
| KR20030009500A (en) | Cleaning Surfaces |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |