CN113528247A - Heavy oil stain cleaning agent for kitchen - Google Patents
Heavy oil stain cleaning agent for kitchen Download PDFInfo
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- CN113528247A CN113528247A CN202110966010.0A CN202110966010A CN113528247A CN 113528247 A CN113528247 A CN 113528247A CN 202110966010 A CN202110966010 A CN 202110966010A CN 113528247 A CN113528247 A CN 113528247A
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- 239000000295 fuel oil Substances 0.000 title claims abstract description 35
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 32
- 239000000654 additive Substances 0.000 claims abstract description 38
- 230000000996 additive effect Effects 0.000 claims abstract description 38
- 239000003921 oil Substances 0.000 claims abstract description 37
- 238000003756 stirring Methods 0.000 claims description 92
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims description 52
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 44
- 150000001412 amines Chemical class 0.000 claims description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical group O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 37
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 30
- 238000002156 mixing Methods 0.000 claims description 30
- 239000008367 deionised water Substances 0.000 claims description 29
- 229910021641 deionized water Inorganic materials 0.000 claims description 29
- 229940087305 limonene Drugs 0.000 claims description 26
- 235000001510 limonene Nutrition 0.000 claims description 26
- AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical compound CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims description 24
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 24
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 22
- 239000003599 detergent Substances 0.000 claims description 20
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 12
- 230000000694 effects Effects 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 11
- 235000006408 oxalic acid Nutrition 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 8
- 238000011049 filling Methods 0.000 claims description 6
- 238000004806 packaging method and process Methods 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 abstract description 13
- 230000003670 easy-to-clean Effects 0.000 abstract description 3
- 239000006260 foam Substances 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 24
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 24
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 16
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 16
- 238000006243 chemical reaction Methods 0.000 description 12
- 239000003205 fragrance Substances 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 8
- 239000000376 reactant Substances 0.000 description 8
- 238000010992 reflux Methods 0.000 description 8
- 235000010265 sodium sulphite Nutrition 0.000 description 8
- PCWGTDULNUVNBN-UHFFFAOYSA-N 4-methylpentan-1-ol Chemical compound CC(C)CCCO PCWGTDULNUVNBN-UHFFFAOYSA-N 0.000 description 4
- 238000007599 discharging Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000003517 fume Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000008157 edible vegetable oil Substances 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- -1 alkyl glycoside Chemical class 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Inorganic materials [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C291/00—Compounds containing carbon and nitrogen and having functional groups not covered by groups C07C201/00 - C07C281/00
- C07C291/02—Compounds containing carbon and nitrogen and having functional groups not covered by groups C07C201/00 - C07C281/00 containing nitrogen-oxide bonds
- C07C291/04—Compounds containing carbon and nitrogen and having functional groups not covered by groups C07C201/00 - C07C281/00 containing nitrogen-oxide bonds containing amino-oxide bonds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/188—Terpenes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2048—Dihydric alcohols branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/64—Cationic compounds of unknown constitution, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
Abstract
The invention discloses a kitchen heavy oil stain cleaning agent, which has the technical scheme key points that: a kitchen heavy oil stain cleaning agent comprises the following components: the special oil removing surface active DGR added into the kitchen heavy oil stain cleaning agent has excellent cleaning and oil removing performance, the hard surface additive can increase the hydrophilicity of the hard surface, so that oil stains are more easily removed, the detergency is improved, the cleaning is easy to clean again during cleaning, and the kitchen heavy oil stain cleaning agent is sprayed on the oil stain surface in a foam or spray mode.
Description
Technical Field
The invention relates to the technical field of oil stain detergents, and particularly relates to a heavy oil stain detergent for a kitchen.
Background
The oil fume emitted by frying dishes is a large amount of thermal oxidation decomposition products generated by edible oil and food under the high-temperature condition, during cooking, the oil is heated, blue smoke decomposed in the initial stage appears when the temperature reaches the smoke point of the edible oil of 170 ℃, the decomposition speed is accelerated along with the continuous rise of the temperature, and a large amount of oil fume is generated when the temperature reaches 250 ℃, and the oil fume is accompanied with pungent smell.
For example, chinese patent No. CN108004051A, which discloses a heavy greasy dirt cleaner for kitchen, comprising: disodium ethylene diamine tetraacetate, sodium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether, coco dimethyl benzyl ammonium chloride, alkyl glycoside, sodium fatty alcohol-polyoxyethylene ether sulfate, sodium chloride and deionized water.
The kitchen heavy oil stain cleaning agent has the characteristics of neutrality, low irritation and no odor; however, the above-mentioned heavy oil stain detergent for kitchens still has some disadvantages, such as: the cleaning efficiency of the oil stain is low, the hydrophilicity of the cleaning agent is poor, and the brightness after cleaning is low.
Disclosure of Invention
The invention aims to provide a kitchen heavy oil stain cleaning agent to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme:
a kitchen heavy oil stain cleaning agent comprises the following components: the mass percent of the special oil removal surface active DGR is 1-4%, the mass percent of amine oxide is 5-8%, the mass percent of hard surface additive is 0.7-1%, the mass percent of sodium carbonate is 1-4%, the mass percent of isohexane glycol is 2-5%, the mass percent of limonene is 0.6-0.9%, the mass percent of BIT20 is 0.09-0.12%, the mass percent of brightener is 1-2%, the mass percent of oxalic acid is 2-4%, the mass percent of essence is 0.1-0.6%, and the balance is deionized water.
Preferably, the heavy oil stain cleaning agent comprises the following components in percentage by mass: 2-3% of special oil removal surface active DGR, 6-7% of amine oxide, 0.8-0.9% of hard surface additive, 2-3% of sodium carbonate, 3-4% of isohexane glycol, 0.7-0.8% of limonene, 0.1-0.11% of BIT20, 1.1-1.8% of brightener, 2.5-3.5% of oxalic acid, 0.2-0.5% of essence and the balance of deionized water.
Preferably, the heavy oil stain cleaning agent comprises the following components in percentage by mass: the mass percent of the special oil removal surface active DGR is 2%, the mass percent of the amine oxide is 6%, the mass percent of the hard surface additive is 0.8%, the mass percent of the sodium carbonate is 2%, the mass percent of the isohexane glycol is 3%, the mass percent of the limonene is 0.7%, the mass percent of the BIT20 is 0.101%, the mass percent of the brightener is 1.2%, the mass percent of the oxalic acid is 2.6%, the mass percent of the essence is 0.3%, and the balance is deionized water.
Preferably, the hard surface additive is a modisturflift hard surface additive.
Preferably, the amine oxide is a 30% concentration amine oxide solution.
Preferably, the stirring time in the step S2 is 20-30min, and the stirring speed is 400-500 r/min.
Preferably, the preparation method of the kitchen heavy oil stain cleaning agent comprises the following steps:
the method comprises the following steps: preparing materials: taking the special oil removal surface active DGR, the amine oxide, the hard surface additive, the sodium carbonate, the isohexane glycol, the limonene, the BIT20 and the deionized water for standby according to percentage;
step two: stirring: adding the deionized water into a batching tank provided with a stirrer, starting the stirrer, and stirring the deionized water;
step three: primary mixing and stirring: adding the special oil removal surface activity DGR and the amine oxide into a batching tank in sequence, stirring for 5-8min by a stirrer, then adding the hard surface additive, and fully stirring;
step four: and (3) secondary mixing and stirring: after fully stirring in the third step, adding the sodium carbonate into a mixing tank, and stirring for 10-15min by a stirrer;
step five: mixing and stirring for the third time: and after fully stirring in the fourth step, adding the isohexide, the limonene and the BIT20 into the blending tank at one time, and increasing the revolution number of the stirrer for 15-30 min.
Step six: and (4) checking: inspecting the prepared detergent;
step seven: packaging: and filling the qualified detergent.
Preferably, the stirring time in the first step is 5-8min, and the stirring speed is 100-160 r/min.
Compared with the prior art, the invention has the beneficial effects that:
the special oil removal surface active DGR added in the kitchen heavy oil stain cleaning agent has excellent cleaning and oil removal performance, can even replace solvent type cleaning agents in many applications, has high-efficiency oil removal efficiency, can increase the hydrophilicity of a hard surface by using a modisurf Lift hard surface additive, enables the oil stains to be removed more easily, provides a protective surface layer to resist future oil stains, is effective on common oil stains and surface materials in families, can be prepared into an acidic, neutral or alkaline cleaning product, improves the dirt removal capability, is easy to clean again, enables the cleaning agent to be convenient to use, and improves the brightness of kitchenware through a brightener.
Drawings
FIG. 1 is a flow chart of the present invention;
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The kitchen heavy oil stain cleaning agent comprises the following components: the mass percent of the special oil removal surface active DGR is 1%, the mass percent of the amine oxide is 5%, the mass percent of the hard surface additive is 0.7%, the mass percent of the sodium carbonate is 1%, the mass percent of the isohexane glycol is 2%, the mass percent of the limonene is 0.6%, the mass percent of the BIT20 is 0.09%, the mass percent of the brightener is 1.1%, the mass percent of the oxalic acid is 2.5%, the mass percent of the essence is 0.2%, and the balance is deionized water.
In order to increase the hydrophilicity of the hard surface, the greasy dirt is removed more easily. In this embodiment, the hard surface additive is preferably a ModisurfLift hard surface additive.
In order to enhance the fragrance of the greasy cleanser, in this example, it is preferred that limonene be extracted from natural orange peel, have good cleaning performance, and provide a pleasant fragrance.
In this embodiment, preferably, the amine oxide is a 30% amine oxide solution prepared by the following steps;
s1: taking a proper amount of dodecyl dimethylamine, citric acid, 30% hydrogen peroxide, water, isopropanol and sodium sulfite;
s2: adding dodecyl dimethyl amine and citric acid into a reaction kettle provided with a stirrer, a reflux condenser pipe, a thermometer and a control feeding device, adding 30% of hydrogen peroxide into the feeding device, and then stirring;
s3: heating to 60 ℃, uniformly injecting hydrogen peroxide into the reaction kettle within a specified time, heating the reactant to 80 ℃, and carrying out reflux reaction for about 4 hours;
s4: the mixture of water and isopropanol was added and stirred well. And when the temperature of the reactant is reduced to 40 ℃, adding sodium sulfite, uniformly stirring, and discharging to obtain 30% of amine oxide.
In this embodiment, the stirring time in step S2 is preferably 20min, and the stirring speed is preferably 400 r/min.
In this embodiment, preferably, the preparation method of the kitchen heavy oil stain cleaning agent includes the following steps:
the method comprises the following steps: preparing materials: according to the percentage, taking special oil removal surface activity DGR, amine oxide, hard surface additive, sodium carbonate, isohexanol, limonene, BIT20 and deionized water for later use;
step two: stirring: adding deionized water into a batching tank provided with a stirrer, starting the stirrer, and stirring the deionized water;
step three: primary mixing and stirring: adding the special deoiling surface activity DGR and the amine oxide into the batching tank in sequence, stirring for 5min by using a stirrer, adding the hard surface additive ModisurfLift, and fully stirring;
step four: and (3) secondary mixing and stirring: after fully stirring in the third step, adding sodium carbonate into the material mixing tank, and stirring for 10min by using a stirrer;
step five: mixing and stirring for the third time: and after fully stirring in the fourth step, adding the isohexide, the limonene and the BIT20 into the mixing tank at one time, and increasing the revolution number of the stirrer for 15 min.
Step six: and (4) checking: inspecting the prepared detergent;
step seven: packaging: and filling the qualified detergent.
In this embodiment, the stirring time in the first step is preferably 5min, and the stirring speed is preferably 100 r/min.
Example 2
The kitchen heavy oil stain cleaning agent comprises the following components in percentage by mass: the mass percent of the special oil removal surface active DGR is 2%, the mass percent of the amine oxide is 6%, the mass percent of the hard surface additive is 0.8%, the mass percent of the sodium carbonate is 2%, the mass percent of the isohexane glycol is 3%, the mass percent of the limonene is 0.7%, the mass percent of the BIT20 is 0.1%, the mass percent of the brightener is 1.3%, the mass percent of the oxalic acid is 2.7%, the mass percent of the essence is 0.3%, and the balance is deionized water.
In order to increase the hydrophilicity of the hard surface, the greasy dirt is removed more easily. In this embodiment, the hard surface additive is preferably a ModisurfLift hard surface additive.
In order to enhance the fragrance of the greasy cleanser, in this example, it is preferred that limonene be extracted from natural orange peel, have good cleaning performance, and provide a pleasant fragrance.
In this embodiment, preferably, the amine oxide is a 30% amine oxide solution prepared by the following steps;
s1: taking a proper amount of dodecyl dimethylamine, citric acid, 30% hydrogen peroxide, water, isopropanol and sodium sulfite;
s2: adding dodecyl dimethyl amine and citric acid into a reaction kettle provided with a stirrer, a reflux condenser pipe, a thermometer and a control feeding device, adding 30% of hydrogen peroxide into the feeding device, and then stirring;
s3: heating to 60 ℃, uniformly injecting hydrogen peroxide into the reaction kettle within a specified time, heating the reactant to 80 ℃, and carrying out reflux reaction for about 4 hours;
s4: the mixture of water and isopropanol was added and stirred well. And when the temperature of the reactant is reduced to 40 ℃, adding sodium sulfite, uniformly stirring, and discharging to obtain 30% of amine oxide.
In this embodiment, the stirring time in step S2 is preferably 23min, and the stirring speed is preferably 440 r/min.
In this embodiment, preferably, the preparation method of the kitchen heavy oil stain cleaning agent includes the following steps:
the method comprises the following steps: preparing materials: according to the percentage, taking special oil removal surface activity DGR, amine oxide, hard surface additive, sodium carbonate, isohexanol, limonene, BIT20 and deionized water for later use;
step two: stirring: adding deionized water into a batching tank provided with a stirrer, starting the stirrer, and stirring the deionized water;
step three: primary mixing and stirring: adding the special deoiling surface activity DGR and the amine oxide into the batching tank in sequence, stirring for 6min by using a stirrer, adding the hard surface additive ModisurfLift, and fully stirring;
step four: and (3) secondary mixing and stirring: after fully stirring in the third step, adding sodium carbonate into the material mixing tank, and stirring for 12min by using a stirrer;
step five: mixing and stirring for the third time: and after fully stirring in the fourth step, adding the isohexide, the limonene and the BIT20 into the mixing tank at one time, and increasing the revolution number of the stirrer for 20 min.
Step six: and (4) checking: inspecting the prepared detergent;
step seven: packaging: and filling the qualified detergent.
In this embodiment, the stirring time in the first step is preferably 6min, and the stirring speed is preferably 120 r/min.
Example 3
The kitchen heavy oil stain cleaning agent comprises the following components: the mass percent of the special oil removal surface active DGR is 3%, the mass percent of the amine oxide is 7%, the mass percent of the hard surface additive is 0.9%, the mass percent of the sodium carbonate is 3%, the mass percent of the isohexane glycol is 4%, the mass percent of the limonene is 0.8%, the mass percent of the BIT20 is 0.11%, the mass percent of the brightener is 1.5%, the mass percent of the oxalic acid is 3%, and the mass percent of the essence is 0.5%. The balance of deionized water.
In order to increase the hydrophilicity of the hard surface, the greasy dirt is removed more easily. In this embodiment, the hard surface additive is preferably a ModisurfLift hard surface additive.
In order to enhance the fragrance of the greasy cleanser, in this example, it is preferred that limonene be extracted from natural orange peel, have good cleaning performance, and provide a pleasant fragrance.
In this embodiment, preferably, the amine oxide is a 30% amine oxide solution prepared by the following steps;
s1: taking a proper amount of dodecyl dimethylamine, citric acid, 30% hydrogen peroxide, water, isopropanol and sodium sulfite;
s2: adding dodecyl dimethyl amine and citric acid into a reaction kettle provided with a stirrer, a reflux condenser pipe, a thermometer and a control feeding device, adding 30% of hydrogen peroxide into the feeding device, and then stirring;
s3: heating to 60 ℃, uniformly injecting hydrogen peroxide into the reaction kettle within a specified time, heating the reactant to 80 ℃, and carrying out reflux reaction for about 4 hours;
s4: the mixture of water and isopropanol was added and stirred well. And when the temperature of the reactant is reduced to 40 ℃, adding sodium sulfite, uniformly stirring, and discharging to obtain 30% of amine oxide.
In this embodiment, it is preferable that the stirring time in step S2 is 26 and the stirring speed is 470 r/min.
In this embodiment, preferably, the preparation method of the kitchen heavy oil stain cleaning agent includes the following steps:
the method comprises the following steps: preparing materials: according to the percentage, taking special oil removal surface activity DGR, amine oxide, hard surface additive, sodium carbonate, isohexanol, limonene, BIT20 and deionized water for later use;
step two: stirring: adding deionized water into a batching tank provided with a stirrer, starting the stirrer, and stirring the deionized water;
step three: primary mixing and stirring: adding the special deoiling surface activity DGR and the amine oxide into the batching tank in sequence, stirring for 7min by using a stirrer, adding the hard surface additive ModisurfLift, and fully stirring;
step four: and (3) secondary mixing and stirring: after fully stirring in the third step, adding sodium carbonate into the material mixing tank, and stirring for 13min by using a stirrer;
step five: mixing and stirring for the third time: and after fully stirring in the fourth step, adding the isohexide, the limonene and the BIT20 into the mixing tank at one time, and increasing the revolution number of the stirrer for 25 min.
Step six: and (4) checking: inspecting the prepared detergent;
step seven: packaging: and filling the qualified detergent.
In this embodiment, the stirring time in the first step is preferably 7min, and the stirring speed is preferably 140 r/min.
Example 4
The kitchen heavy oil stain cleaning agent comprises the following components: the mass percent of the special oil removal surface active DGR is 4%, the mass percent of the amine oxide is 8%, the mass percent of the hard surface additive is 1%, the mass percent of the sodium carbonate is 4%, the mass percent of the isohexane glycol is 5%, the mass percent of the limonene is 0.9%, the mass percent of the BIT20 is 0.12%, the mass percent of the brightener is 1.8%, the mass percent of the oxalic acid is 3.5%, the mass percent of the essence is 0.5%, and the balance is deionized water.
In order to increase the hydrophilicity of the hard surface, the greasy dirt is removed more easily. In this embodiment, the hard surface additive is preferably a ModisurfLift hard surface additive.
In order to enhance the fragrance of the greasy cleanser, in this example, it is preferred that limonene be extracted from natural orange peel, have good cleaning performance, and provide a pleasant fragrance.
In this embodiment, preferably, the amine oxide is a 30% amine oxide solution prepared by the following steps;
s1: taking a proper amount of dodecyl dimethylamine, citric acid, 30% hydrogen peroxide, water, isopropanol and sodium sulfite;
s2: adding dodecyl dimethyl amine and citric acid into a reaction kettle provided with a stirrer, a reflux condenser pipe, a thermometer and a control feeding device, adding 30% of hydrogen peroxide into the feeding device, and then stirring;
s3: heating to 60 ℃, uniformly injecting hydrogen peroxide into the reaction kettle within a specified time, heating the reactant to 80 ℃, and carrying out reflux reaction for about 4 hours;
s4: the mixture of water and isopropanol was added and stirred well. And when the temperature of the reactant is reduced to 40 ℃, adding sodium sulfite, uniformly stirring, and discharging to obtain 30% of amine oxide.
In this embodiment, the stirring time in step S2 is preferably 30min, and the stirring speed is preferably 500 r/min.
In this embodiment, preferably, the preparation method of the kitchen heavy oil stain cleaning agent includes the following steps:
the method comprises the following steps: preparing materials: according to the percentage, taking special oil removal surface activity DGR, amine oxide, hard surface additive, sodium carbonate, isohexanol, limonene, BIT20 and deionized water for later use;
step two: stirring: adding deionized water into a batching tank provided with a stirrer, starting the stirrer, and stirring the deionized water;
step three: primary mixing and stirring: adding the special deoiling surface activity DGR and the amine oxide into the batching tank in sequence, stirring for 8min by using a stirrer, adding the hard surface additive ModisurfLift, and fully stirring;
step four: and (3) secondary mixing and stirring: after fully stirring in the third step, adding sodium carbonate into the material mixing tank, and stirring for 15min by using a stirrer;
step five: mixing and stirring for the third time: and after fully stirring in the fourth step, adding the isohexide, the limonene and the BIT20 into the mixing tank at one time, and increasing the revolution number of the stirrer for 30 min.
Step six: and (4) checking: inspecting the prepared detergent;
step seven: packaging: and filling the qualified detergent.
In this embodiment, the stirring time in the first step is preferably 8min, and the stirring speed is preferably 160 r/min.
The working principle and the using process of the invention are as follows:
the special oil removal surface activity DGR added in the kitchen heavy oil stain cleaning agent has very good cleaning and oil removal performance, the ModisurfLift hard surface additive has an additive with affinity, the hydrophilicity of a hard surface can be increased, oil stains can be removed more easily, the detergency is improved, the cleaning agent is easy to clean again during cleaning, and the antirust function is realized.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (8)
1. A heavy oil stain cleaning agent for kitchens is characterized in that: the method comprises the following components: the mass percent of the special oil removal surface active DGR is 1-4%, the mass percent of amine oxide is 5-8%, the mass percent of hard surface additive is 0.7-1%, the mass percent of sodium carbonate is 1-4%, the mass percent of isohexane glycol is 2-5%, the mass percent of limonene is 0.6-0.9%, the mass percent of BIT20 is 0.09-0.12%, the mass percent of brightener is 1-2%, the mass percent of oxalic acid is 2-4%, the mass percent of essence is 0.1-0.6%, and the balance is deionized water.
2. The kitchen heavy oil stain detergent as set forth in claim 1, characterized in that: the heavy oil stain cleaning agent comprises the following components in percentage by mass: 2-3% of special oil removal surface active DGR, 6-7% of amine oxide, 0.8-0.9% of hard surface additive, 2-3% of sodium carbonate, 3-4% of isohexane glycol, 0.7-0.8% of limonene, 0.1-0.11% of BIT20, 1.1-1.8% of brightener, 2.5-3.5% of oxalic acid, 0.2-0.5% of essence and the balance of deionized water.
3. The kitchen heavy oil stain detergent as set forth in claim 3, wherein: the heavy oil stain cleaning agent comprises the following components in percentage by mass: the mass percent of the special oil removal surface active DGR is 2%, the mass percent of the amine oxide is 6%, the mass percent of the hard surface additive is 0.8%, the mass percent of the sodium carbonate is 2%, the mass percent of the isohexane glycol is 3%, the mass percent of the limonene is 0.7%, the mass percent of the BIT20 is 0.101%, the mass percent of the brightener is 1.2%, the mass percent of the oxalic acid is 2.6%, the mass percent of the essence is 0.3%, and the balance is deionized water.
4. The kitchen heavy oil stain detergent as set forth in claim 1, characterized in that: the hard surface additive is a ModisurfLift hard surface additive.
5. The kitchen heavy oil stain detergent as set forth in claim 4, wherein: the amine oxide is a 30% concentration amine oxide solution.
6. The kitchen heavy oil stain cleaning agent according to claim 5, characterized in that: in the step S2, the stirring time is 20-30min, and the stirring speed is 400-500 r/min.
7. The kitchen heavy oil stain cleaning agent according to claim 2, characterized in that: the preparation method of the kitchen heavy oil stain cleaning agent comprises the following steps:
the method comprises the following steps: preparing materials: taking the special oil removal surface active DGR, the amine oxide, the hard surface additive, the sodium carbonate, the isohexane glycol, the limonene, the BIT20 and the deionized water for standby according to percentage;
step two: stirring: adding the deionized water into a batching tank provided with a stirrer, starting the stirrer, and stirring the deionized water;
step three: primary mixing and stirring: adding the special oil removal surface activity DGR and the amine oxide into a batching tank in sequence, stirring for 5-8min by a stirrer, then adding the hard surface additive, and fully stirring;
step four: and (3) secondary mixing and stirring: after fully stirring in the third step, adding the sodium carbonate into a mixing tank, and stirring for 10-15min by a stirrer;
step five: mixing and stirring for the third time: and after fully stirring in the fourth step, adding the isohexide, the limonene and the BIT20 into the blending tank at one time, and increasing the revolution number of the stirrer for 15-30 min.
Step six: and (4) checking: inspecting the prepared detergent;
step seven: packaging: and filling the qualified detergent.
8. The kitchen heavy oil stain detergent as set forth in claim 7, wherein: the stirring time in the first step is 5-8min, and the stirring speed is 160 r/min.
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Application publication date: 20211022 |