CN104152307B - A kind of cleaning agent composition and cleaning agent and its application - Google Patents
A kind of cleaning agent composition and cleaning agent and its application Download PDFInfo
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- CN104152307B CN104152307B CN201410390563.6A CN201410390563A CN104152307B CN 104152307 B CN104152307 B CN 104152307B CN 201410390563 A CN201410390563 A CN 201410390563A CN 104152307 B CN104152307 B CN 104152307B
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Abstract
The invention belongs to technical field of fine, and in particular to a kind of cleaning agent composition and cleaning agent and its application on cleaning stone material in various greasy dirt spots.The cleaning agent composition contains amide compound, glycol monoalkyl ether and surfactant, and the weight ratio of each component is 1：0.50~4.0：0.1~4.0, preferably 1：1.0~2.0：0.5~2.0.The cleaning agent composition of the present invention meets green requirement, the cleaning suitable for the greasy dirt spot on various quality of stone material surfaces.The cleaning agent composition of the present invention is thorough with spot is removed, and does not corrode stone material, whole cleaning process is become simple, application easy to spread.
Description
Technical field
The invention belongs to technical field of fine, is related to a kind of cleaning agent composition and cleaning agent and its application, especially
It is related to a kind of cleaning agent composition and cleaning agent and its application on cleaning stone material in various greasy dirt spots.
Background technology
Natural marble, granite, flag and artificial stone, because of its distinctive decoration performance --- the flower of Natural
Line, the glossiness of bright analysis or the male and fomale(M＆F) of texture, good friction intensity etc., are widely used in the interior of building since ancient times
It is using one of earliest construction material on architectural history in external decoration.Progress and the hair of Modern Architecture industry with human history
Exhibition, closely during the last ten years, TERRAZZO has been widely applied to various all kinds of buildings, has beautified our living environment.But
The influence movable with people over time so that stone surface is constantly contaminated, and wherein greasy dirt spot is most common dirt
One of dye, such as restaurant, dining room, kitchen, passageway, the hall for putting machinery and parking lot and congregation plaza etc., its wall
The stone material on face and ground often can see greasy dirt spot.Greasy dirt once pollutes the surface of this calculus material, not only have a strong impact on it is attractive in appearance,
Also pollute the environment, the life to people is made troubles.Often with micropore, the greasy dirt that remove in micropore has stone material
Suitable difficulty.
In terms of mainly there is following four in the source of stone surface greasy dirt：First, the grease that stone machining equipment process is brought；
Two be due to the edible oil contamination of mankind's vegetable edible, is more common in dining room, kitchen, passageway；Three let out when being due to and putting machinery or vehicle
Machine oil or lubricating grease of dew etc.；Four be due to that ground and metope waxing and upper protection oil quality are inferior or uneven.These greases
Through permeating and diffusing into the superficial layer of building and ornament materials, in addition to itself can form oil mark, can also automatic absorbing dust formed
Greasy dirt spot, some greasy dirt spots also tend to the organic matter containing carbonization or partial carbonization and form black stain.Greasy dirt once enters stone material table
Surface layer, because oil is in the contact angle of inorganic material surface very little, and the specific surface area that stone material micropore is very large, these stone materials pair
The absorption affinity and package action of greasy dirt are quite strong, therefore are difficult to clean up.
It is more perfect for the cleaning technique of the greasy dirt on glass-hard surface at present, but it is micro- for stone material, cement products etc.
The material in space, the cleaning problem of greasy dirt spot are not still well solved.
Chinese patent CN103525583A discloses a kind of silicate product greasy dirt detergent, and the weight of each component is matched somebody with somebody
Than for：Sodium hypochlorite 30%~45%, calcium carbonate 5%~10%, n-Propyl Bromide 5%~10%, acetone 5%~15%, acetic acid
Ethyl ester 2%~8%, surfactant 10%~20%, surplus are deionized water.CN103103028A discloses a kind of marble
Ground cleaning agent and preparation method thereof.In parts by weight, the present invention is composed of the following components：Neopelex：5~
10, sodium acid carbonate：2~5, ethylene glycol monobutyl ether：10~18, sodium pyrophosphate：2~4, sodium citrate：1~3, ethylenediamine tetra-acetic acid
Sodium：1~3, methacrylate：20~30, butyl acetate：20~30, essence：0.2~0.4, water：1000~2000.
CN101225347A discloses a kind of stone special-purpose cleaning agent, its constituent component and weight proportion be respectively sodium hypochlorite 40~
60%th, trichloro ethylene 8~12%, acetone 10~20%, surfactant 15~25%, butyl ester 2~7%.CN102994288A
A kind of marble floorings cleaning agent is disclosed, the marble floorings cleaning agent is made up of the raw material of following each component：Citric acid
6-8 parts, palm wax 7-9 parts, triethanolamine 8-10 parts, lac 2-4 parts, ammonium hydroxide 6-8 parts, water 40-50 parts, sodium chloride 6-10
Part.CN103387893A discloses a kind of cement flooring scavenger specially, and its constituent has：Sodium phosphate, SODIUM PERCARBONATE, hydrogen-oxygen
Change sodium, neopelex, ethylene glycol monobutyl ether, pure plant spices.
Japan Patent JPH03182596 A disclose a kind of liquid ground cleaner.The cleaning agent include 1~5% it is cloudy from
Sub- surfactant (such as sodium n-alkylbenzenesulfonate), 2~10% nonionic surfactants (such as ethoxylated dodecyl alcohol),
0.1~2% hydroxy alkyl cellulose and 1~5% low-carbon alcohols, pH9~12.JPH06322398 (A) discloses a kind of crust
Cleaning agent.The cleaning agent includes 0.1~30% amphoteric surfactant, 0.1~5% soap containing 8-22 carbon, 0.1~
50% solvent, 0.1~50% metal ion chelation agent.
Korean Patent KR101005656 B1 disclose a kind of stone material cleaning agent.The cleaning agent include sodium metasilicate 11~
14%, sodium hydroxide 1.1~2%, butyl cellosolve 4~6%, nonyl phenol 0.2~0.4%, monoethanolamine 1~5%, the nitrogen of benzo three
Azoles 2~4%, nitric acid 2~6% and water 65~75%.
The current following shortcoming of stone material cleaning agent generally existing is found by studying：1st, detergency is low, corrodes stone material, due to
The characteristic and performance of stone material itself, make the cleaning performance of this kind of greasy dirt spot cleaned in the microvoids such as stone material, cement products low；2、
Cost is high, and the main component and auxiliary materials, cost of these formulas are higher；3rd, the feature of environmental protection is poor, due to having used highly basic in formula
And n-Propyl Bromide, the solvent of trichloro ethylene high volatile or chloride conduct solvent have preferable dissolution to greasy dirt, but easily
Volatilization and toxicity height, it is long-term use of, it is very big to human body and environmental hazard.
The content of the invention
It is a primary object of the present invention to for above-mentioned deficiency of the prior art, there is provided a kind of cleaning agent composition
Application with cleaning agent and its on various stone materials are cleaned in various greasy dirt spots.
To achieve these goals, on the one hand, the invention provides a kind of cleaning agent composition, said composition contains acyl
Amines, glycol monoalkyl ether and surfactant, the weight ratio of each component is 1：0.50~4.0：0.1~4.0, be preferably
1：1.0~2.0：0.5~2.0.
Preferably, the amide compound is selected from 1-METHYLPYRROLIDONE, N- ethyl pyrrolidones, N, N- dimethyl formyls
At least one of amine.
Preferably, the glycol in the glycol monoalkyl ether is selected from ethylene glycol, diethylene glycol, propane diols and DPG
At least one of.
Preferably, the alkyl in the glycol monoalkyl ether is selected from methyl, ethyl, n-propyl, normal-butyl and n-hexyl
At least one of.
Preferably, the surfactant is selected from diisooctyl succinate sodium sulfonate, C8-C18APG, C8-C18Alkanol
Acid amides, the straight or branched AEO and APES that hydrophilic lipophilic balance (HLB) is 8-15
At least one of.
Preferably, also containing solvent and adsorbent, solvent is selected from ethanol, at least one of isopropanol, and adsorbent is selected from gas
At least one of aerosil, diatomite, bentonite, Emathlite and winnofil.
On the other hand, the invention provides a kind of cleaning agent, the cleaning agent contains above-mentioned cleaning agent composition and water.
Preferably, the content of the cleaning agent composition is 5~80 weight %, preferably 20~50 weight %.
Another further aspect, it is special the invention provides application of the above-mentioned cleaning agent in various stone surface supernatant washing oil stains
It is not suitable for natural marble, the cleaning of granitic greasy dirt spot.
Pass through above-mentioned technical proposal, cleaning agent chemical property of the invention is stable, is combined for environment-friendly cleaning agent
Thing, meet green requirement；The cleaning agent of the present invention can be used in various stone surfaces oil stain cleaning process, had
There is excellent cleaning performance, dosage is few, and processing procedure is simple and positive effect, application easy to spread.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Embodiment
The embodiment of the present invention is described in detail below.It is it should be appreciated that described herein specific
Embodiment is merely to illustrate and explain the present invention, and is not intended to limit the invention.
Cleaning agent composition provided by the invention, said composition contain amide compound, glycol monoalkyl ether and surface
Activating agent, the weight ratio of each component is 1：0.50~4.0：0.1~4.0, preferably 1：1.0~2.0：0.5~2.0.
Wherein, the amide compound is the important composition composition in cleaning agent composition, to the various dirts of stone surface
Dirt has outstanding cleaning performance, energy rapid osmotic stone material micropore, removes deep layer oil mark, and have and the nonreactive spy of stone material
Property, it ensure that the integrality of stone material.Under preferable case, the amide compound is selected from 1-METHYLPYRROLIDONE, N- N-ethyl pyrrole Ns
At least one of alkanone, DMF.
The glycol monoalkyl ether is the important component of cleaning agent composition, can promote the cleaning of oil foulant,
And there is infiltration function, the speed and effect of cleaning are improved, removes deep layer oil mark.Under preferable case, wherein, the glycol can be with
For at least one of ethylene glycol, diethylene glycol, propane diols, DPG；Wherein, the alkyl can be methyl, ethyl, just
Propyl group, one kind in normal-butyl and n-hexyl.Under the conditions of more preferably, the glycol monoalkyl ether is selected from glycol monoethyl ether, second
2-ethoxyethanol, ethylene glycol monobutyl ether, ethylene glycol monohexylether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol list
Butyl ether, propylene glycol monomethyl ether, dihydroxypropane single-ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, dipropylene glycol monomethyl ether, dipropyl
At least one of 2-ethoxyethanol, Dipropylene glycol mono-n-butyl Ether.
The surfactant is the constituent in cleaning agent composition, can improve speed and the cleaning of cleaning
Completeness, oil emulsion stain, can be at least one of any kind of surfactant.As alkyl or aryl sulfuric acid,
Sodium sulfonate, potassium sulfonate, ichthyodin, alkyl phosphate salt, alkyl carboxylate, alkyl sulfonyl amine salt, AEO, alkane
Base glucosides, alkanolamide, alkyl quaternary ammonium salts or Fixanol etc..Under preferable case, described surfactant is selected from
Diisooctyl succinate sodium sulfonate, C8-C18 APGs, C8-C18 alkanolamides, hydrophilic lipophilic balance (HLB) are 8-15
AEO or at least one of NPE or OPEO.
The other cleansing composition can also contain solvent and adsorbent, and it is clear that its solvent is mainly used in shortening stone surface
Drying time after washing.The oil mark cleaned out is mainly adsorbed onto surface by adsorbent, is advantageous to preferably remove oil mark.Institute
At least one of ethanol, isopropanol can be selected from by stating solvent.The adsorbent can be selected from aerosil, diatomite,
At least one of bentonite, Emathlite and winnofil.
The cleaning agent of the present invention contains above-mentioned cleaning agent composition and water.
According to the present invention, cleaning agent can be selected in relative broad range as needed with the content of composition in the cleaning agent
Select, under preferable case, the content of the cleaning agent composition is 5~80 weight %, more preferably 20~50 weight %.
According to the present invention, the cleaning agent can be obtained by existing various methods, such as will can be formed described clear
The step of raw material of lotion is well mixed according to foregoing required ratio and is made, therefore the present invention is to the mixing and condition are without spy
It is different to require.
Application in greasy dirt spot of the cleaning agent of the present invention on various stone materials are cleaned, it is characterised in that the cleaning agent
For above-mentioned cleaning agent.
The present invention will be described in detail by way of examples below.Embodiment 1-6 is used for illustrating cleaning agent composition
And preparation method thereof.The reagent used in embodiment is as follows：1-METHYLPYRROLIDONE, N- ethyl pyrrolidones, N, N- bis-
NMF, aerosil, diatomite, bentonite, Emathlite, winnofil, ethanol and isopropanol are point
Analyse pure (Chemical Reagent Co., Ltd., Sinopharm Group)；Glycol monoethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol
Monohexyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether and diethylene glycol monobutyl ether, which are that analysis is pure, (is purchased from Tokyo chemistry work
Industry Co., Ltd)；Propylene glycol monomethyl ether, dihydroxypropane single-ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, DPG list first
Ether, DPE and Dipropylene glycol mono-n-butyl Ether are to analyze pure (being purchased from Sigma-Aldrich)；Succinic acid di-isooctyl
Sodium sulfonate, C8-C18 APGs, alkanolamide, TX-7, OP-10, TX-15, MOA-7, MOA-9 and O-8 are that technical grade is (equal
Purchased from Jiangsu Hai'an petrochemical plant).
Embodiment 1
Weigh 5.0 grams of 1-METHYLPYRROLIDONEs, 5.0 grams of DMFs, 5.0 grams of ethylene glycol monobutyl ethers, 5.0 grams
Glycol monoethyl ether, 5.0 grams of propylene glycol monomethyl ethers, 5.0 grams of alkanolamides, 5.0 grams of OP-10,5.0 grams of MOA-7,10 grams of isopropyls
Alcohol, 80% content solution is finally diluted with water to, is stirred.
Embodiment 2
Weigh 5.0 grams of 1-METHYLPYRROLIDONEs, 5.0 grams of N- ethyl pyrrolidones, 2.0 grams of diethylene glycol monobutyl ethers, 4.0 grams
Ethylene glycol monoethyl ether, 4.0 grams of dihydroxypropane single-ethers, 5.0 grams of diisooctyl succinate sodium sulfonates, 5.0 grams of C8-C18APG,
10.0 grams of TX-7,10.0 grams of ethanol, 10.0 grams of aerosils, 50% content solution is finally diluted with water to, is stirred.
Embodiment 3
Weigh 10.0 grams of 1-METHYLPYRROLIDONEs, 2.0 grams of ethylene glycol monohexylethers, 5.0 grams of diethylene glycol monomethyl ethers, 5.0 grams
Propylene glycol monobutyl ether, 5.0 grams of dipropylene glycol monomethyl ethers, 2.5 grams of TX-7,2.5 grams of MOA-7,3.0 grams of DPEs, 10
Gram diatomite, is finally diluted with water to 30% content solution, stirs.
Embodiment 4
Weigh 10.0 grams of DMFs, 2.5 grams of diethylene glycol monoethyl ethers, 2.5 grams of Dipropylene glycol mono-n-butyl Ethers,
10.0 grams of TX-15,10.0 grams of O-8,10.0 grams of MOA-9,10.0 grams of bentonites, 30% content solution is finally diluted with water to, is stirred
Mix uniformly.
Embodiment 5
Weigh 10.0 grams of 1-METHYLPYRROLIDONEs, 25.0 grams of ethylene glycol monobutyl ethers, 15.0 grams of diethylene glycol monobutyl ethers, 1.0
Gram MOA-9,10 grams of Emathlites, is finally diluted with water to 50% content solution, stirs.
Embodiment 6
Weigh 10.0 grams of 1-METHYLPYRROLIDONEs, 1.0 grams of ethylene glycol monohexylethers, 3.0 grams of Dipropylene glycol mono-n-butyl Ethers, 3.0 grams
Diethylene glycol monobutyl ether, 20.0 grams of MOA-7,20.0 grams of alkanolamides, 10.0 grams of isopropanols, 10.0 grams of winnofils, finally
20% content solution is diluted with water to, is stirred.
Comparative example 1
Cleaning agent is prepared according to CN103525583A embodiments 1.
Comparative example 2
Cleaning agent is prepared according to CN103103028A embodiments 1.
Test case 1
Marble/granite test piece specification：50×25×2mm.
Cleaning agent oil removing performance：Test piece is dipped into miscella (diesel oil：Salad oil=1：1) taken after (room temperature) within 2 hours in
Go out, after drying, cleaned with cleaning agent, test cleaning oil mark performance.With reference to DB11/T512-2007《Building decoration engineering stone material should
Use technical regulation》And GB/T25146-2010《Industrial equipment Chemical cleaning inspection of quality specification》, respectively to embodiment 1-6 and right
Stone material cleaning agent obtained by ratio 1-2 is evaluated with the cleaning performance of composition.
Table 1
| Embodiment | Mass concentration/% | Clean rate/the % of removing oil mark/ | Effect assessment |
| Embodiment 1 | 50 | 99 | It is excellent |
| Embodiment 1 | 5 | 95 | It is excellent |
| Embodiment 2 | 5 | 95 | It is excellent |
| Embodiment 3 | 30 | 98 | It is excellent |
| Embodiment 4 | 20 | 96 | It is excellent |
| Embodiment 5 | 25 | 98 | It is excellent |
| Embodiment 6 | 20 | 98 | It is excellent |
| Comparative example 1 | - | 85 | It is good |
| Contrast row 2 | - | 90 | It is good |
The cleaning agent composition that can be seen that the present invention from the evaluation experimental result of table 1 has good cleaning performance,
The cleaning agent after the composition for cleaning of the present invention is added, oil mark cleans rate >=95%, therefore, cleaning agent of the invention combination
Thing can meet that stone material oils the cleaning requirement of stain.
The preferred embodiment of the present invention described in detail above, still, the present invention are not limited in above-mentioned embodiment
Detail, in the range of the technology design of the present invention, a variety of simple variants can be carried out to technical scheme, this
A little simple variants belong to protection scope of the present invention.
It is further to note that each particular technique feature described in above-mentioned embodiment, in not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to it is various can
The combination of energy no longer separately illustrates.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally
The thought of invention, it should equally be considered as content disclosed in this invention.
Claims (5)
1. various greasy dirt spot cleaning agents on one kind cleaning stone material, it is characterised in that the cleaning agent contains cleaning agent composition
And water, said composition contain amide compound, glycol monoalkyl ether and surfactant；The amide compound, glycol list alkane
The weight of base ether and surfactant ratio is 1：0.50~4.0：0.1~4.0；
The surfactant is selected from diisooctyl succinate sodium sulfonate, C8-C18APG, hydrophilic lipophilic balance (HLB)
For at least one of 8-15 straight or branched AEO and APES；
The cleaning agent also contains solvent and adsorbent, and solvent is selected from ethanol, at least one of isopropanol, and adsorbent is selected from gas phase
At least one of silica, diatomite, bentonite, Emathlite and winnofil；
2. various greasy dirt spot cleaning agents on cleaning stone material according to claim 1, it is characterised in that the amide compound
Selected from least one of 1-METHYLPYRROLIDONE, N- ethyl pyrrolidones, DMF.
3. various greasy dirt spot cleaning agents on cleaning stone material according to claim 1, it is characterised in that the glycol monoalkyl
Glycol in ether is selected from ethylene glycol, diethylene glycol, at least one of propane diols and DPG.
4. various greasy dirt spot cleaning agents on cleaning stone material according to claim 1, it is characterised in that the glycol monoalkyl
Alkyl in ether is selected from methyl, ethyl, n-propyl, at least one of normal-butyl and n-hexyl.
5. various greasy dirt spot cleaning agents on cleaning stone material according to claim 1, it is characterised in that the cleaning agent group
The content of compound is 5~80 weight %.
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| CN105695127A (en) * | 2016-03-16 | 2016-06-22 | 安徽海德石油化工有限公司 | High-viscosity petroleum product conveying pipeline cleaning agent |
| CN107118857A (en) * | 2017-05-31 | 2017-09-01 | 苏州龙腾万里化工科技有限公司 | A kind of nontoxic corrosion-free derusting cleaning agent |
| CN107843648B (en) * | 2017-09-21 | 2020-11-27 | 中国石油天然气集团公司管材研究所 | Nondestructive testing method |
| WO2021240665A1 (en) * | 2020-05-27 | 2021-12-02 | 光貴スペーステクノロジーズ株式会社 | Carbon-cleaning agent and cleaning method using said carbon-cleaning agent |
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| US5006279A (en) * | 1988-08-24 | 1991-04-09 | Grobbel William J | Water-based coating removers |
| US6090765A (en) * | 1997-12-12 | 2000-07-18 | Church & Dwight Co., Inc. | Composition for cleaning hard surfaces |
| CN1256415C (en) * | 2004-09-30 | 2006-05-17 | 武汉理工大学 | Cleaning agent pinene containing solvent |
| BE1020269A5 (en) * | 2012-01-17 | 2013-07-02 | Taminco | USE OF REPLACEMENT SOLVENTS FOR N-METHYLPYRROLIDONE (NMP). |
| CN103937628A (en) * | 2014-05-12 | 2014-07-23 | 苏州禾川化学技术服务有限公司 | High-alkalinity non-foaming spraying cleaning agent |
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