CN108251228A

CN108251228A - A kind of detergent composition

Info

Publication number: CN108251228A
Application number: CN201810146559.3A
Authority: CN
Inventors: 蒋赞; 郑翔龙; 潘东
Original assignee: GUANGZHOU BLUEMOON INDUSTRY Co Ltd
Current assignee: GUANGZHOU BLUEMOON INDUSTRY Co Ltd
Priority date: 2018-02-12
Filing date: 2018-02-12
Publication date: 2018-07-06

Abstract

The invention discloses a kind of detergent compositions.This detergent composition includes following ingredient：(a) amine surfactants are aoxidized；(b) non-oxide amine surfactants；(c) with coordination ability and/or with metal cation salt of N → O coordinate bonds with binding ability；The mass percent that the active matter total content of ingredient (a) and (b) account for detergent composition is 1%~60%；The mass percent that the content of ingredient a accounts for active matter content in ingredient a and b is 67%~95%；Its general formula of the oxidation amine surfactants of ingredient (a) is：

Description

A kind of detergent composition

Technical field

The present invention relates to a kind of detergent compositions.

Background technology

The cleaning or washing of the surface of solids such as generally include to soak, remove, emulsify at the processes.For water-detergent solution Speech, because of the surfactant containing sufficient amount, usually with relatively low surface and interface tension, therefore there is no problem for wetting；Dirt Stripping process can also be by selecting suitable surfactant system to be realized；And emulsification can both be happened at dirt stripping It, can be to liquid greasy dirt or to solid grease even tiny particles content etc. in fact after dirt stripping can also be happened at from before Existing good emulsion dispersion, therefore the quality of emulsifiability is an important factor for influencing detergent detergency ability.In addition, for hand Dishwashing detergent, the hand oil sense when quality of emulsification can also influence to wash.Therefore it is good how to obtain emulsifiability Formula system, be that current washing field is continued for paying close attention to and it is expected to solve the problems, such as.

For detergent compositions engineer when seeking to promote emulsifiability, the selection of surfactant is most important, although literary Offer and seem to give the exploitation that a large amount of alternative surfactants are used for detergent in summary, but actually many raw materials because Its special chemical constitution and be not suitable in single wash detergent composition used in everyday at low cost.In fact, due to Considering in terms of economy, most of detergent composition still select one or more traditional EO base nonionic surfactants With sulfonic group or sulfate anion surfactant as primary surfactant, but the type surfactant can not reach Quick emulsification or the purpose of strength emulsification.Detergent compositions engineer is also challenged by various Environmental Factors, such as：Some are not The ingredient for having biodegradability cannot be considered, some ingredients with bio-toxicity are used by limitation, efficient phosphoric acid The reason of salt builder is because of body eutrophication is disabled in many countries.In addition, many surfactants are not both from The petrochemical material of regenerative resource, the type raw material is not advocated increasingly in compound composition yet, but is more considered The surfactant of biological source, such as the raw material in natural oil source, to obtain more environmentally protective composition.

Wherein amine oxide, particularly alkyl amidopropyldimethyl amine oxide are former as the one kind in source using natural oil Material arrives the patent of amine oxide at present involved in overwhelming majority detergent composition, addition is very low, by the matter of active matter Percentage is measured to represent, generally to be less than 5%, is more existed with the content for being less than 2%, frequently as Babassuamidopropylamine and foam Stabilizer exists.

At present, the oxidation amine component of high-content has only been used in only a few patent, such as the US 5698505 in the U.S..The U.S. US 5698505 be related to a kind of light duty liquid or gel detergent compositions with high bubble and automatic emulsified solid grease, It includes following components by mass percentage：

(a) 10%~70% detersive surfactant, the detersive surfactant are selected from polyhydroxy fatty acid amide, non- Ionic aliphatic poly glucoside, C8-22 alkyl sulfates, C9-15 alkylbenzenesulfonates, C8-22 alkyl sulfates, C8-22 alkene sulfonates, C8-22 paraffin sulfate, C8-22 alkyl glyceryl ether sulfonates, fatty acid ester sulfonate, secondary alcohol sulphur Hydrochlorate, amphoteric detersive surfactants and their mixture；

(b) 8%~25% C10-22 amine oxides, the range of the pH of the composition 6~9, amine oxide and decontamination table The ratio of face activating agent is about 2:1 to 1:3 range；

(c) comprising 1%~10% Babassuamidopropylamine；

(d) comprising 0.001%~5% enzyme；

(e) and 0.01%~4% magnesium ion or calcium ion or the mixture of the two.

The JP6051111B of Japan is related to a kind of liquid detergent for kitchen use, it discloses：Include (A) at least one sulfuric acid Salt form or sulfonate type anion surfactant, (B) amine oxide surfactant, (C) weight average molecular weight are 400,000-four hundred Ten thousand polyethylene glycol, (D) carbon atom number is for 2-10 and containing the water-soluble solvent of a hydroxyl, (E) water, the mass ratio D/ of each component Ranges of the C 5~150, ranges of (the A+B)/C 10~150, ranges of (the A+B)/D 1~5；(A+B) content 10~ The range of 50wt%, preferably 15-35wt%.This document is mentioned in the description, range of the A/B ratios 0.5~15, preferably 0.5~10, more preferable 0.5~5, most preferably 1~3 range.

The CN 103249827B of China are related to a kind of liquid detergent composition, wherein, the liquid detergent composition Contain following (a)~(c) ingredients：(a) selected from the aliphatic acid that carbon atom number is 8~14 and its compound of one or more of salt 0.5~10wt%, and in the case of containing fatty acid salt, which is the conversion amount of aliphatic acid；(b) there is 1 carbon original Subnumber is 0.5~18wt% of amine oxide type surfactant of 8~16 hydroxyl；And (c) is 4~8 selected from carbon atom number 1 kind in alkene and styrene with 0.1~10wt% of copolymer of maleic acid；The mass ratio of a ingredients/b ingredients for 1/10~ Total content of 10/1, a ingredient and b ingredients is 4~20wt%, and the mass ratio of c ingredients/(a+b) ingredient for 1/100~ 2.5/1。

The CN 101981171A of China are related to substantially anhydrous concentrate composition, include (a) amine oxide surfactants Agent, (b) substantially water-soluble solvent, (c) alkaline source, (d) is substantially free of water；Preferably, substantially anhydrous concentration combination Object includes (a) 60-75wt% amine oxides, (b) 8-20wt% substantially water-soluble solvents, (c) 3-10wt% alkaline sources, (d) 5- 10% chelating agent, (e) 0.5-5wt% hydrotropic solvents, the water of (f) less than 10wt%；Preferably, substantially anhydrous concentration combination Object includes (a) 10-20wt% amine oxides, (b) 50-75wt% substantially water-soluble solvents, (c) 5-15wt% alkaline sources, (d) 0.1-7% chelating agents, (e) is substantially free of water；The concentrate composition is water-soluble, and available for preparing stable contain Water application solution.

As it can be seen that the prior art generally with the content of amine oxide surfactant be not higher than total surfactant content 2/3, Or not higher than 1/2 for node, to provide good foaming properties and/or grease emulsifying performance.In disclosed patent document, oxidation Why the content of amine is not directed to 2/3 range higher than total surfactant content, it may be possible to due to aoxidizing for a long time Amine is used mainly as Babassuamidopropylamine, foam stabiliser, and when as such use, amine oxide is in total surfactant Preferable amount be below 2/3 or less than 1/2, more preferably be less than 1/10 dosage add in.

In conclusion the emulsifiability of detergent composition how is improved on the basis of green, environmental protection, economy is still Detergent compositions engineer develops the key content that New-type detergent composition is studied.

Invention content

Present inventor is had found when amine oxide surfactant contains in detergent composition by long-term research When amount is higher than the 2/3 of total surfactant content, the emulsifying capacity of greasy dirt is remarkably reinforced.And then the purpose of the present invention exists In providing a kind of detergent composition, with improved emulsifying capacity, and current high oxidation amine surface-active contents are overcome Composition preparing process be not easy the problem realized, and applied in all kinds of detergent is prepared.

The technical solution used in the present invention is：

A kind of detergent composition, including following ingredient：

(a) amine surfactants are aoxidized；

(b) non-oxide amine surfactants；

(c) with coordination ability and/or with metal cation salt of N → O coordinate bonds with binding ability；

The mass percent that the active matter total content of ingredient (a) and (b) account for detergent composition is 1%~60%；Ingredient (c) mass percent that content accounts for detergent composition is 0.1%~8%；Also, the content of ingredient (a) account for ingredient (a) and (b) mass percent of active matter content is 67%~95% in；

Wherein, shown in the oxidation amine surfactants such as general formula (Ι) of ingredient (a)：

R₁It is the alkyl or hydroxyalkyl that carbon atom number is C8~C22；R₂、R₃It is C1~C4 independently to represent carbon atom number Low alkyl group or hydroxyalkyl；The value of m is 2~6.

Preferably, in detergent composition, the active matter total content of ingredient (a) and (b) account for the quality of detergent composition Percentage is 3%~45%.

Preferably, in detergent composition, the content of ingredient (a) accounts for the quality hundred of active matter content in ingredient (a) and (b) Divide than being 67%~85%.

Preferably, in the oxidation amine surfactants shown in general formula (Ι), R₁It is the alkyl that carbon atom number is C10~C18 Or hydroxyalkyl；R₂、R₃Independently represent the low alkyl group or hydroxyalkyl that carbon atom number is C1~C2；The value of m is 2~4.

Further, in detergent composition, ingredient (b) for anion surfactant, zwitterionic surfactant, At least one of nonionic surfactant.

Preferably, in detergent composition, the mass percent that the content of ingredient (c) accounts for detergent composition is 0.5% ~6%.

Preferably, in the ingredient (c) of detergent composition, the metallic element of metal cation salt is Section II A, IB, IIB, III B, at least one of IV B, V B, VI B, VII B, VIII race's element；Salt is organic salt and/or inorganic salts.

It is further preferred that in the ingredient (c) of detergent composition, the metallic element of metal cation salt is Section II A, IB, At least one of IIB, VIII race's element；Inorganic salts for chloride, bromide, iodide, nitrate, sulfate, sulphite, At least one of phosphate, dibasic alkaliine, dihydric phosphate；Organic salt is formates, acetate, citrate, toluene At least one of sulfonate.

Further, detergent composition further includes auxiliary agent, auxiliary agent is chelating agent, preservative, dyestuff, essence, builder, In dye transfer inhibitor, enzyme, enzyme stabilizers, anti redeposition agent, anti-colour contamination agent, brightening agent, carrier, pH adjusting agent, filler At least one.

A kind of detergent, including above-mentioned detergent composition.

Compared with prior art, the present invention has the advantages that：

1st, the present invention preferably amine oxide surfactant and the other surfaces activating agent in addition to amine oxide surfactant Compounding forms detergent composition, and when amine oxide, total surfactant content is higher than 67wt%, preferably 67wt% in the composition During~85wt%, there is excellent greasy dirt emulsifying capacity.

2nd, the present invention using with coordination ability and/or with alkali salt of N → O coordinate bonds with binding ability and/ Or transition metal salt overcomes the problems, such as that the detergent composition of above-mentioned high oxidation amine content is difficult to realize in technique, not only into This is cheap, it is often more important that can achieve the effect that viscosity reduction, and the low-temperature stability of composition sample can be also obviously improved.

3rd, the surfactant added in detergent composition provided by the invention, selected from easily biological-degradable, environmentally protective And natural amine oxide, the detergent composition with other surfaces activating agent compounding is in the case of high oxidation amine content With good greasy dirt emulsifying capacity, and it is more environmentally protective, fabric detergent, dishwashing detergent can be widely used in In the fields such as agent, fruits and vegetables detergent, hard surface detergent, kitchen ventilator detergent.

Specific embodiment

A kind of detergent composition, including following ingredient：

(a) amine surfactants are aoxidized；

(b) non-oxide amine surfactants；

The mass percent that the active matter total content of ingredient (a) and (b) account for detergent composition is 1%~60%；Ingredient (c) mass percent that content accounts for detergent composition is 0.1%~8%；Also, the content of ingredient (a) account for ingredient (a) and (b) mass percent of active matter content is 67%~95% in.

In the present invention, the content of all the components and the additive amount of surfactant are calculated with active matter content.

Preferably, in detergent composition, the active matter total content of ingredient (a) and (b) account for the quality of detergent composition Percentage is 3%~45%；It is further preferred that the active matter total content of ingredient (a) and (b) account for the quality of detergent composition Percentage is 15%~40%.

Preferably, in detergent composition, the content of ingredient (a) accounts for the quality hundred of active matter content in ingredient (a) and (b) Divide than being 67%~85%；It is further preferred that the content of ingredient (a) accounts for the quality hundred of active matter content in ingredient (a) and (b) Divide than being 67%~80%.

Each ingredient of each detergent composition is further detailed below：

First, the surfactant of ingredient (a)

The oxidation amine surfactants of ingredient (a) are the compound of structure shown in general formula (Ι), are typically dredged comprising different The mixture of the oxidation amine molecule of water tail chain length.The commercialized raw materials of this surfactant often with 25wt%~35wt%, It is preferred that the aqueous solution of 28wt%~32wt% solid contents exists.

General formulaIn, R₁It is the alkyl or hydroxyalkyl that carbon atom number is C8~C22, It is preferred that the alkyl of C10~C18, the alkyl of more preferable C12~C14；R₂、R₃It is the low of C1~C4 independently to represent carbon atom number Grade alkyl or hydroxyalkyl, preferably methyl or ethyl or ethoxy, more preferable methyl or ethoxy, most preferable；The value of m is 2~6, preferably 2~4, more preferably 3.

2nd, the surfactant of ingredient (b)

Non-oxide amine surfactants described in ingredient (b) are except the other surfaces activating agent of oxidation amine；Preferably, Ingredient (b) is at least one of anion surfactant, zwitterionic surfactant, nonionic surfactant；Institute It states the counter ion that anion surfactant and/or zwitterionic surfactant carry and may be selected from sodium ion, ammonium ion, alcohol Amine radical ion, magnesium ion, calcium ion and their mixture, preferably at least one of sodium ion, ammonium ion, magnesium ion.

Preferably, in ingredient (b) anion surfactant, nonionic surfactant, amphoteric surfactant The length of alkyl carbon chain is between C8~C22, more preferable C10~C18.

The anion surfactant that 2.1 ingredients (b) are related to

Ingredient (b) anion surfactant is chosen as carboxylic acid type, sulfate type, sulfonate type surface-active Agent；Optional anion surfactant includes alcohol ether carboxylate, alkyl sulfate, alkyl ethoxylated sulfate, alkylbenzene Sulfonate, α olefin sulfonate, aliphatic alcohol sulfate, fatty alcohol sulfonate, fatty alcohol ether sulphate, fatty acid methyl ester ethyoxyl Change sulfonate etc., optimizing alkyl benzene sulfonate, alkyl ethoxylated sulfate, alkylsulfonate and α olefin sulfonate.

The nonionic surfactant that 2.2 ingredients (b) are related to

Ingredient (b) nonionic surfactant is linear or branched alkyl group nonionic surfactant, is chosen as alkane Base glucoside, alkyl ethoxylated glucoside, alkyl polyoxyethylene ether, alkyl polyoxyethylene polyethenoxy ether, polyoxygenated Allylic alkylation aliphatic ester, alkyl fatty acid alkanolamide or nitrogen-alkyl -2-Pyrrolidone etc., optimizing alkyl glucoside and nitrogen - Alkyl -2-Pyrrolidone.

The zwitterionic surfactant that 2.3 ingredients (b) are related to

Ingredient (b) zwitterionic surfactant includes fatty acid quaternary ammonium salt, phosphonate, wherein sulfonium compound, fat Fat chain part is the linear chain or branch chain of C8~C24, while comprising anionic water soluble group, preferably amphoteric surfactant is Alkyl betaine, alkyl hydroxy sulfo lycine, alkylamide propyl-betaine, alkylamide propyl hydroxy sulfo lycine, carboxylic acid Type imidazoline etc., more preferable alkylamide propyl-betaine and alkyl hydroxy sulfo lycine.

It should be pointed out that allocated by the ingredient (a) in detergent composition of the present invention and ingredient (b), even if Also the excessive problem that can not normally stir of process for preparation medium viscosity can be encountered under relatively low gross activity object content, it is steady also to encounter sample Qualitative, particularly low-temperature stability is bad, inconvenient problem with use, needs to add in other auxiliary agents and solve.In general, It can be alleviated, but must be added to a large amount of alcohols or alcohol ethers solvent by adding in alcohols solvent and alcohol ethers solvent viscosity reduction, Such as add in more than 10% ethyl alcohol, ethylene glycol, diethylene glycol monobutyl ether, diethylene glycol ether, triethylene glycol butyl ether or they Mixture, can just reach smoothly complete prepare and with good low temperature stability result.This method necessarily causes The cost of composition dramatically increases or brings the problem of low-flash or burning rank deficient.

3rd, the metal cation salt of ingredient (c)

In the present invention, by add in coordination ability and/or with metal ion of N → O coordinate bonds with binding ability Salt can obviously reduce the viscosity in process for preparation, overcome the problems, such as that stirring is fixed up.This is because, it is desirable to it is not bound by discussing limit There is system the oxygen atom in the metal ion and surfactant A of coordination ability to be coordinated, and form special construction (such as octahedral Body structure or planar structure) aggregation, so as to cause system viscosity reduce.In general, the addition of salt can compress ionic The electric double layer of surfactant (including zwitterionic surfactant), makes it arrange closer, the aggregation of surfactant Body increases, and such as forms vermiculate glues or vermiculate glues gradually increases, winds, viscosity is caused to rise.And in the present invention, have The addition of the alkali salt or transition metal salt of coordination ability is not only of low cost, it is often more important that can reach the effect of viscosity reduction Fruit, and the low-temperature stability of composition sample can be also obviously improved, and be a big important discovery and innovation.

Preferably, in detergent composition ingredient (c), the metallic element of metal cation salt is Section II A, IB, IIB, III B, At least one of IV B, V B, VI B, VII B, VIII race's element；It is further preferred that the metallic element of metal cation salt is the At least one of IIA, IB, IIB, VIII race's element；Still further preferably, the metal ion of metal cation salt for Section II A, IB, IIB, VIII race's element are in third, the 4th or period 6 corresponding metal ion；Still further preferably, metal ion selects From Zn²⁺、Cu²⁺、Ba²⁺、Ni²⁺、Mg²⁺、Co²⁺、Ca²⁺At least one of；Still more preferably, metal ion is selected from Zn²⁺、 Mg²⁺、Ca²⁺At least one of.

Preferably, in detergent composition ingredient (c), salt is organic salt and/or inorganic salts；It is further preferred that washing In agent composition components (c), salt is inorganic salts.

Further, inorganic salts for chloride, bromide, iodide, nitrate, sulfate, sulphite, phosphate, At least one of dibasic alkaliine, dihydric phosphate；Preferably, inorganic salts be chloride, nitrate, in sulfate at least It is a kind of.

Further, organic salt is at least one of formates, acetate, citrate, toluene fulfonate；Again into one Step is preferred, and organic salt is at least one of acetate, citrate.

4th, auxiliary agent

4.1 chelating agent

In the present invention, the chelating agent is selected from amino carboxylic acid compounds and/or organo-aminophosphonic acid compound and/or lemon Lemon acid sodium, the amino carboxylic acid compounds include but not limited to：Ethylenediamine tetra-acetic acid (EDTA), N- hydroxy-ethylenediamine tetrems Acid, nitrilotriacetic acid (NTA), diethylenetriamine pentaacetic acid (DEPTA)；The organo-aminophosphonic acid compound includes but not limited to： Ethylenediaminetetrakis (methylenephosphonic acid), 1- hydroxyl ethane 1,1- di 2 ethylhexyl phosphonic acids (HEDP) and amino three (methylene phosphonic acid).Such as use chela Mixture, it is usually 0.1~15wt% that the content of these chelating agents, which accounts for the detergent composition mass percentage, preferably 1~ 15wt%.

4.2 preservative

In the present invention, the preservative is selected from Kathon CG (2-methyl-4-isothiazolin-3-one and 5- chloro-2-methyls -4- The mixture of isothiazoline -3- ketone), 2-methyl-4-isothiazolin-3-one, in 5-Chloro-2-methyl-4-isothiazolin-3-one It is at least one.Such as using preservative, the content of these preservatives accounts for the detergent composition mass percentage and is usually 0.01~1wt%, preferably 0.02~0.2wt%.

4.3 dyestuff

In the present invention, the dyestuff is selected from direct dyes, and the content of the direct dyes is enough to provide coloring, suitable Dyestuff includes but not limited to：The acid dyes of a variety of colors, the basic dye of a variety of colors and 4-nitro-o-phenylenediamine, 2- Nitro p-phenylenediamine, 4- amino-3-nitro phenols, the chloro- 4- nitrophenols of 2- amino -6-, 4- nitro-phenylaminos hydantoic acid, 6- Nitro -2,5- pyridines diamines, the sodium salt of the monosulfonic acid of quinophthalone or 2- indandione rodenticides and disulphonic acid mixtures, 2- hydroxyl -1,4- naphthalenes Quinone, nail premium, indigo, alkermes and their mixture.Such as using dyestuff, the content of these dyestuffs accounts for the washing Agent composition quality percentage composition is usually 0.01~5wt%.

4.4 essence

In the present invention, the essence is selected from draft pastil, such as minty note, spearmint, rosemary, thyme, Salvia japonica With atom pine tree, dragon spruce and other trees with forest smell；Fruit pastil, as apple, almond, grape, cherry, pineapple, Pears, honey peach, mango, orange, strawberry, blueberry, citrus；Fragrance of a flower agent, such as rose sample, lavender sample, carnation sample；It is and fragrant Grass, cape jasmine, hawthorn, chypre, honeysuckle, cyclamen, hyacinth, fiddlehead, cloves, jasmine, lily, sensitive plant, magnolia, orchid Flower, daffodil, flores aurantii, Radix Glycyrrhizae, reseda green, clover, violet, Lathyrus odoratus, English wallflower etc. (" Perfumes The Cosmetics and Soaps " second editions, nineteen fifty-nine are published by W.A.Poucher).The content of these essence accounts for the washing Agent composition quality percentage composition is usually 0.01~5wt%, preferably 0.05~2wt%.

4.5 builder

In the present invention, the builder is selected from organic polycarboxylic acid, propionic acid copolymer, type A zeolite, sodium carbonate, silicic acid At least one of sodium, sodium metasilicate.Such as using builder, the content of these builders accounts for the detergent composition quality hundred Point content is usually 0.01~30wt%, preferably 0.1~28wt%.

4.6 dye transfer inhibitor

In the present invention, the dye transfer inhibitor is selected from polyvinylpyrrolidone, polyamine N-oxide, N- ethylene pyrroles Copolymer, polyvinyl imidazole, Ju Yi Xi oxazolidones and their mixture of pyrrolidone-N- vinyl imidazols.Such as using dye Expect transfer inhibitor, it is usually 0.01 that the content of these dye transfer inhibitors, which accounts for the detergent composition mass percentage, ~10wt%, preferably 0.1~5wt%.

4.7 enzyme

In the present invention, the enzyme is selected from protease, cellulase, lipase, amylase, pectase, zytase, oxygen Change enzyme, reductase, peroxidase and their mixture, be preferably typically combined as protease, cellulase, starch One or more kinds of mixtures in enzyme, lipase.Such as using enzyme, the content of these enzymes accounts for the detergent composition matter It is usually 0.01~15wt% to measure percentage composition, preferably 0.1~10wt%.

4.8 enzyme stabilizers

In the present invention, the enzyme stabilizers are selected from calcium chloride, calcium formate, calcium gluconate and their mixture. Such as using enzyme stabilizers, the contents of these enzyme stabilizers account for the detergent composition mass percentage be usually 0.001~ 5wt%, preferably 0.005~3wt%.

4.9 clays and dirt removal/anti redeposition agent

In the present invention, the clay and dirt removal/anti redeposition agent are selected from maleic-acrylic acid polymer, carboxylic first Base cellulose, hydroxyethyl cellulose and their mixture.Such as using clay and dirt removal/anti redeposition agent, these are viscous It is usually 0.1~15wt% that the content of soil and dirt removal/anti redeposition agent, which accounts for the detergent composition mass percentage, It is preferred that 0.2~10wt%.

4.10 anti-colour contamination agent

In the present invention, the anti-colour contamination agent is selected from aliphatic poly amine derivative, polyvinylpyrrolidone, N- ethylene pyrroles Copolymer, polyvinyl imidazole, Ju Yi Xi oxazolidones and their mixture of alkanone-N- vinyl imidazols.Such as use anti-string Toner, it is usually 0.5~2wt% that the content of these anti-colour contamination agent, which accounts for the detergent composition mass percentage, and preferably 0.4 ~1.5wt%.

4.11 brightening agent

In the present invention, the brightening agent is selected from fluorescent whitening agent, preferably CBS-X.Such as using brightening agent, these brightening agents Content to account for the detergent composition mass percentage be usually 0.01~10wt%, preferably 0.1~3wt%.

4.12 carrier

In the present invention, the carrier is selected from polar solvent, including but not limited to water, ethylene glycol, propylene glycol, poly- second two Alcohol, glycerine and/or nonpolar solvent, including but not limited to mineral oil, silicone oil, paraffin oil and their mixture.Such as make With carrier, it is usually 0.1~15wt% that the content of these carriers, which accounts for the detergent composition mass percent, preferably 1~ 15wt%.

4.13pH conditioning agent

In the present invention, the pH adjusting agent is selected from citric acid, hydrochloric acid, sulfamic acid, sodium hydroxide, sodium carbonate, Dan Yi It is one or more in hydramine, triethanolamine.

4.14 filler

In the present invention, the filler is water, in polyalcohol, Disodium sulfate decahydrate, sodium carbonate, sodium metasilicate, 4A zeolites It is one or more.

The present invention also provides a kind of detergent, this detergent includes above-mentioned detergent composition.

This detergent is fabric detergent, the washing of dish washing detergent, fruits and vegetables detergent, hard surface detergent, kitchen ventilator At least one of agent, but it is not limited only to this.

Preferably, the additive amount of detergent composition is 1~60wt% in this detergent.

This detergent can be various forms, preferably liquid.

Further, when this detergent is liquid, the surplus ingredient in the detergent is solvent, is for example, gone Ionized water.

Further, when this detergent is solid-like, the surplus ingredient in the detergent is for making its molding Filler.

Further, the pH of this detergent is 5~13；When detergent is liquid, pH is preferably 5~9；Work as washing When agent is solid-like, pH is preferably 9~13.

In the present invention, the detergent has the effect of decontamination and greasy dirt emulsification in the range of wider pH；But detergent The skin or hard surface of the too strong easy stimulation user of alkalinity, damages skin and hard surface, it is possible to according to reality Using reasonably selecting within the above range.

The preparation method of this detergent is as follows：

When detergent is liquid detergent, the preparation method of this liquid detergent is：By detergent composition In each component mix and be dissolved in solvent, adjust the pH to 5~9 or 10~13 of mixed liquor, add solvent to 100wt%, After stirring evenly, liquid detergent is obtained.

When detergent is solid-like washing agent, the preparation method of this solid-like washing agent is：By detergent composition In surfactant and filler and other auxiliary agents mixing, grind and be configured to solid content be 50~60wt% slurry, It is diluted with water and adjusts pH to 9~11, re-dry, sieving are to get to solid-like washing agent after turbid sieving；The grinding is such as It is ground in colloid mill, it is dry for spray drying.

Present disclosure is described in further detail below by way of specific embodiment.It is former used in embodiment Material unless otherwise specified, can be obtained from routine business approach.In example, the content of all the components and adding for surfactant Dosage is in terms of active matter content.

Embodiment：

The detergent composition raw material composition ratio of embodiment and comparative example is shown in Table 1~6.Amine oxide accounts for total surface in each example The content of agent/compositions solid content is also found in table 1~6.Solid content, total surfactant content and combination in composition The test method difference that amine content is aoxidized in object is as follows：

First, solid content is tested

Solid content refer to sample dry under prescribed conditions after remainder account for the mass percent of total amount.Its test process For：1) the 250mL beakers of clean dried are put into 105 DEG C of baking ovens after constant temperature 1.5h, taking-up is weighed, record quality m1；2) it is accurate Really weigh 2g (being accurate to 0.0001g) homogeneous sample, record quality m, be put in the beaker of constant weight, make sample evenly laid out in Bottom of bottle；3) beaker for filling sample is put into constant temperature 3h in 105 DEG C of baking ovens, taking-up is weighed, record quality m2；4) solid content is calculated =(m2-m1)/m, unit %.

2nd, total surfactant content is tested

With reference to gross activity object content assaying method in national standard GB 9985-2000, activity is obtained using chloroform extraction method Object content, deduct urea content after be gross activity object content.In chloroform energy dissolved composition all surface activating agent and Other organic matters and insoluble inorganic salts, sample extract repeatedly after drying and dehydrating, with chloroform, collect extract, removal Chloroform dries, weighs, and calculates active matter content.But if it can be also partly solubilized, therefore must containing urea in composition Urea content must be measured with quantitative dissolved matter, and the side of being deducted is real gross activity object content.In addition, chloroform is molten It solves in object, solvent or oil components that may be comprising no surface-active can be with Japanese JIS K3362-2008《Home-use conjunction Into detergent test method》In further deduct the content of petroleum ether dissolution object, acquired results are total surfactant content. Therefore total surfactant content (%)=chloroform dissolved matter content (%)-urea content (%)-petroleum ether in composition Dissolved matter content (%).

3rd, amine oxide assay in composition

The oxidation amine content in chemical analysis method or chromatography determination composition may be used, it is preferred to use efficient liquid phase The content of amine oxide surfactant in chromatography determination composition.Optimize chromatographic condition first, make amine oxide surfactant, The amphoteric surfactantes such as beet alkali surface activator, amino acid surfactant have distinction on appearance time；Then Add in lauryl amidopropyl dimethyl amine, cocamide dimethylamine oxide, dodecyl dimethyl oxidation Amine, tetradecyldimethylamine oxide, lauryl amidopropyl betaine, cocamide propyl betaine, cocoyl base two Ethoxy glycine betaine, coco alkyl azochlorosulfonate propyl lycine, coco alkyl Hydroxypropyl phosphate ester glycine betaine, cocoyl glutamate The amphoteric surfactantes such as sodium, cocoyl Sodium Glycinate obtain the guarantor under its each comfortable chromatography optimal conditions as reference substance Stay the time；By the solid content sample in composition take it is a certain amount of be made into deionized water 10% solution, then sampling carries out high Effect liquid phase chromatogram is analyzed, and the surfactant types of component are obtained by retention time, and containing for each component is obtained by peak area How much is amount, while calculates the content of amine oxide surfactant in the composition.

Table 1

Table 2

Table 3

Table 4

Table 5

Table 6

Physics and chemistry and application performance compare：

The detergent composition of above-described embodiment and comparative example is tested for the property.The concrete operation method of dependence test It is as follows：1st, greasy dirt emulsification experiment

1) 200 milliliters of the 250ppm hard water solutions of 2% detergent composition are added in 250 milliliters of beakers, are dripped with dropper Add 1mL rapeseed oils；2) using 500 turns of magnetic agitations 2 minutes, then 2 minutes is stood and is observed；3) by differentiating the turbidity of solution With the mode for measuring the light transmittance of beaker central liquid at 550 nm, comparison detergent composition is to the emulsifying capacity of greasy dirt.Breast It is low to change the good then light transmittance of effect, then light transmittance is high for emulsifying effectiveness difference.Emulsifying effectiveness is divided into four grades, respectively：Good, preferable, It is bad, poor.

2nd, the clean level of a dishcloth

1) 1 gram of detergent composition is taken to be dissolved in the hard water of 495 milliliters of 250ppm, is stirred evenly, is made into 0.2% solution； 2) 5 grams of rapeseed oils are added in detergent composition solution, is stirred with magnetic stirring apparatus with 250 revs/min of speed, mixes grease It closes uniform；3) a dishcloth is cut into 15cm × 15cm sizes, be put into above-mentioned mixed solution, after stirring 3 minutes, take out pieces of cloth； 4) it lifts 5 times, is rinsed in 500 milliliters of tap water；5) 10 professionals are chosen as volunteer, to the cloth after rinsing Piece scores, and clean level is divided into five grades, respectively：It is very clean, clean, dirtier, dirty, very dirty, respectively correspond to 5 points, 4 Divide, 3 points, 2 points, 1 point, take the average mark of this 10 people's scorings as final scoring.

3rd, hand oil sense

1) 4 grams of detergent compositions is taken to be dissolved in the hard water of 2 liters of 250ppm, are stirred evenly, are made into 0.2% solution；2) 20 grams of rapeseed oils are added in the detergent composition solution, is stirred with magnetic stirring apparatus with 250 revs/min of speed, makes grease It is uniformly mixed；3) 10 professionals are chosen as volunteer, after above-mentioned solution stops stirring, by the five fingers and hand of a hand The palm is fully immersed in water oil mixing with water solution hands at the back, is impregnated 1 minute；4) hand is taken out, hand is gently put into other 2L and is done It is impregnated half a minute in net tap water (similar rinsing)；5) hand is taken out, whether observation hand there are greasy residues；6) to hand oil Sense is scored, and is pressed：5 points, 4 points, 3 points, 2 points, 1 point correspond to this very clean, clean, dirtier, dirty, very dirty 5 differences etc. respectively The scoring of grade takes the average mark of this 10 people's scorings as final scoring.

4th, the clean level of wash bowl

With reference to foam level method in national standard GB 9985-2000, dirt is prepared, cleans dirty disk, the clean journey for evaluating wash bowl Degree.Specifically：1) national standard dirt (butter are prepared:Lard:Vegetable oil=0.5:0.5:1, and add the list of total oil mass 0.5% Sweet ester), and dirt is coated on plate；2) it is 0.2% detergent composition solution 2L with 250ppm hard water compound concentration, is used in combination 0.2% solution cleans the porcelain dish of 10 national standard dirts；3) cleaning finishes, and soiling solution is stood after five minutes again to fall washing solution Fall；4) 10 professionals are chosen as volunteer, wash bowl side wall and the clean level of bottom is observed, and score, presses：5 points, 4 points, 3 points, 2 points, 1 point of this corresponding very clean, clean, dirtier, dirty, very dirty 5 different grades of scoring respectively, take this 10 people The average mark of scoring is as final scoring.

The physics and chemistry and application performance result of embodiment and comparative example are as shown in table 7~12.

Table 7

Table 8

Table 9

Table 10

Table 11

Table 12

The present invention is based on a unexpected discovery, i.e., when the content of amine oxide surfactant is higher than total surface activity Agent content 2/3 when, preferably in 2/3~4/5 range, the emulsifying capacity of greasy dirt is remarkably reinforced.And the present invention passes through The mode that amine oxide surfactant and metal cation salt are applied in combination overcomes the table of high oxidation amine surface-active contents Face activating agent is not easy to prepare the problem realized in technique.The detergent composition that the present invention obtains can be widely used in and knit In the fields such as object detergent, dish washing detergent, fruits and vegetables detergent, hard surface detergent.

More than, embodiments of the present invention are illustrated.But the present invention is not limited to the above embodiments.It is all Within the spirit and principles in the present invention, any modification, equivalent substitution, improvement and etc. done should be included in the guarantor of the present invention Within the scope of shield.

Claims

1. a kind of detergent composition, including following ingredient：(a) amine surfactants are aoxidized；(b) non-oxide amine surface Activating agent；(c) with coordination ability and/or with metal cation salt of N → O coordinate bonds with binding ability；It is characterized in that：

The mass percent that the active matter total content of ingredient (a) and (b) account for detergent composition is 1%~60%；

The mass percent that the content of ingredient (c) accounts for detergent composition is 0.1%~8%；

Also, the mass percent that the content of ingredient (a) accounts for active matter content in ingredient (a) and (b) is 67%~95%；

R₁It is the alkyl or hydroxyalkyl that carbon atom number is C8~C22；R₂、R₃It is the low of C1~C4 independently to represent carbon atom number Grade alkyl or hydroxyalkyl；The value of m is 2~6.

2. a kind of detergent composition according to claim 1, it is characterised in that：The active matter of ingredient (a) and (b) always contain The mass percent that amount accounts for detergent composition is 3%~45%.

3. a kind of detergent composition according to claim 2, it is characterised in that：The content of ingredient (a) account for ingredient (a) and (b) mass percent of active matter content is 67%~85% in.

4. a kind of detergent composition according to claim 3, it is characterised in that：Oxidation amine table shown in general formula (Ι) In the activating agent of face, R₁It is the alkyl or hydroxyalkyl that carbon atom number is C10~C18；R₂、R₃It is C1 independently to represent carbon atom number The low alkyl group or hydroxyalkyl of~C2；The value of m is 2~4.

5. a kind of detergent composition according to claim 3, it is characterised in that：Ingredient (b) is anion surface active At least one of agent, zwitterionic surfactant, nonionic surfactant.

6. a kind of detergent composition according to claim 1, it is characterised in that：The content of ingredient (c) accounts for detergent group The mass percent for closing object is 0.5%~6%.

7. a kind of detergent composition according to claim 6, it is characterised in that：In ingredient (c), the gold of metal cation salt Category element is at least one of Section II A, IB, IIB, III B, IV B, V B, VI B, VII B, VIII race's element；Salt for organic salt and/or Inorganic salts.

8. a kind of detergent composition according to claim 7, it is characterised in that：In ingredient (c), the gold of metal cation salt Category element is at least one of Section II A, IB, IIB, VIII race's element；Inorganic salts are chloride, bromide, iodide, nitric acid At least one of salt, sulfate, sulphite, phosphate, dibasic alkaliine, dihydric phosphate；Organic salt is formates, second At least one of hydrochlorate, citrate, toluene fulfonate.

9. according to a kind of detergent composition of claim 1~8 any one of them, it is characterised in that：The detergent combination Object further includes auxiliary agent, auxiliary agent is chelating agent, preservative, dyestuff, essence, builder, dye transfer inhibitor, enzyme, enzyme stabilizers, At least one of anti redeposition agent, anti-colour contamination agent, brightening agent, carrier, pH adjusting agent, filler.

10. a kind of detergent, including the detergent composition described in claim 9.