CN101255381A - Cleaning method and combination - Google Patents
Cleaning method and combination Download PDFInfo
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- CN101255381A CN101255381A CNA2007100842033A CN200710084203A CN101255381A CN 101255381 A CN101255381 A CN 101255381A CN A2007100842033 A CNA2007100842033 A CN A2007100842033A CN 200710084203 A CN200710084203 A CN 200710084203A CN 101255381 A CN101255381 A CN 101255381A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/188—Terpenes
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
A detergent composition is provided, which contains a) anionic surfactant which is 0.1%-20% of total weight of the composition, wherein the mentioned anionic surfactant is selected from fatty alcohol - polyoxyethyleneether sulfate series, dodecyl sulfate series, secondary alkane sulphonate series and group formed by their mixture; b) nonionic surfactant which is 0.1%-30% of total weight of the composition; c) citrus essential oil which is 0.01%-3% of the total weight of the composition; and d) equilibrium amount of water. The other aspect of the invention is to provides a dirt cleaning method from substrate, which includes a step of contacting substrate with mentioned detergent composition in liquid and/or gaseous phase (or putting the substrate into the composition).
Description
Technical field
The present invention relates to cleanser compositions, relate in particular to the cleanser compositions that comprises the tangerine oil component, and relate to the method for using this composition to remove crude removal from substrate surface especially crust.
Background technology
The various members of family and working space, facility, as table top, bathing pool, washbasin, wood furniture, floor etc. normally are made of crusts such as glass, pottery, polyethylene, marble, timber, porcelain in kitchen utensils microwave oven, interior oven walls, mirror, window, the bathroom.The purpose of cleaning these class article mainly is: 1) remove dirt; 2) keep the intact of crust, make the surface injury-free; 3) minimizing is to the harm and the environmental pollution of HUMAN HEALTH.
Tensio-active agent is a most important component in the washing composition.Because tensio-active agent such as widely used linear alkylbenzene sulfonate in the conventional washing agent improve its resistance to hard water because of needs make the used additives tripoly phosphate sodium STPP, and have caused the problem of global water body " eutrophication ".Enter after the seventies in 20th century, many countries have issued limit phosphorus law in succession.
In addition, owing to the biological degradability of tensio-active agent and the security of degraded product, be directly connected to the ecotope of washing composition, the tensio-active agent that therefore is difficult for degraded also has been subjected to strict restriction.At present, this is abandoned the branch-alkylbenzene sulfonate hexyl of difficult degraded, and in West Europe, distearyl dimethyl ammonium chloride also is restricted.Because the degradation production alkylphenol of alkylphenol polyoxyethylene (APEO) is difficult for being decomposed in water, can make some birds and mammiferous individuality reproductive organ occur diminishes, or make ripe individual buck the phenomenon that ovary etc. is feminized occur, so alkylphenol oneself be listed in one of 70 kinds of Environmental Hormones that restriction uses.In addition, APEO is very strong to the pungency of skin and eyes.Therefore, the use of alkylphenol polyoxyethylene has been subjected to strict restriction.
Another weakness of conventional washing agent is that skin is had pungency or toxicity, and some human consumer has anaphylaxis to washing composition.Some strong basicity washing composition have very strong corrodibility and pungency for reaching strong degreasing and purpose cheaply, can cause skin ulceration.Though many cleaning products directly do not contact with human body generally speaking,, may damage human body if spattered because of carelessness.Poisoning to the generation of children and pet often has report to the washing composition series products because eating misuse by mistake.Therefore, toxicity, pungency and the security of research washing composition are apparent more important.A kind of nontoxic sanitising agent that adopts tensio-active agent, sequestrant is disclosed in the U.S. Pat 6197738, except that containing 1% sodium phosphate, also contain 94% citric acid, 4%EDTA, 1% sodium lauryl sulphate, obtained good cleaning, hygiene effect, but the pH value of said composition is no more than 3, is tangible acidity, be unsuitable for being used for the cleaning of some metallic surfaces, and may produce certain stimulation human body skin.
Expert prophesy will be the dominance of the sanitising agent of gentle, Sustainable development in the washing cleaning industry.Manufacturerss adapt to this development trend and have also released some successively and declare to be rich in herbal essences, the detergent product of attractions such as natural plant extraction liquid, be subjected to human consumer's concern, but the cost problem still takes extensively these ways to play restriction to people.For example, Chinese patent CN1818046A discloses a kind of natural environmental-protective sanitising agent, and it contains wooden chaff, sodium alkyl benzene sulfonate, analysis for soybean powder, tensio-active agent, whitening agent etc., and dirt clearance height does not have corrosion, and non-stimulated, cost is low; But residual many, easily secondary pollution needs to clean residue after using, and has increased the labor force and the cost of follow-up link.
In sum, be badly in need of a kind of nontoxic, low irritant, suitable, the easy degraded of pH, low residue and lower-cost sanitising agent prescription at present.
See also " tensio-active agent science " book series (Marcel Dekker press, New York, 1996) the 56th volume chapter 2 " alkylbenzene sulfonate: history, production, analysis and environmental performance ", p39-108; " tensio-active agent science " book series (Marcel Dekker press, New York, 1998) the 73rd volume; " tensio-active agent science " book series (Marcel Dekker press, New York, 1992) the 40th volume.Also referring to International Patent Application WO 97/22,683, on May 17th, 1996 submitted to; International Patent Application WO 98/40,452, on February 24th, 1998 submitted to; The open CN1702162A of Chinese patent application, on May 31st, 2005 submitted to.Above-mentioned document is whole to be introduced with the some as this specification sheets.
Summary of the invention
The present inventor is now definite, not only has gratifying comprehensive clean-up performance by being used in combination a kind of cleanser compositions that specific anion surfactant, nonionogenic tenside and tangerine oil obtain, and be surprised to find its LD50 more than or equal to 15000mg/kg, and be that not phosphorous, non-aggressive, low irritant and volatile organic compounds (VOC) content are low, belong to nontoxic product.In addition, its pH is moderate, also have low irritant, non-aggressive, low solvent odor, residual less, easy characteristics such as degraded, be fit to be used for removal to crust dirts such as demanding zone safe in utilization such as dining room, kitchen, food-processing, swimming pool, school, kindergarten, gymnasiums.Thereby the problems referred to above have been solved well.
Specifically, one aspect of the present invention provides a kind of cleanser compositions, and said composition comprises:
A) account for the anion surfactant of 0.1 weight %-20 weight % of described composition, described anion surfactant is selected from by polyoxyethylene alkyl ether sulfate salt series, dodecyl alcohol ether ammonium sulfate series, ammonium lauryl sulfate series, secondary paraffin sulfonate series, and the group formed of their mixture;
B) account for the nonionogenic tenside of 0.1 weight %-30 weight % of described composition;
C) account for the citrus essential oil of 0.01 weight %-3 weight % of described composition; With
D) water of equal amount.
Another aspect of the present invention provides and a kind ofly removes the cleaning method of crude removal from substrate surface, and described method comprises makes contact with liquid phase and/or the above-mentioned cleanser compositions of the gas phase step of (or place this composition with base material) of base material.Method of the present invention can comprise direct use detergent composition or use water or other carrier diluted composition of q.s in advance.
Above-mentioned embodiment of the present invention and others will illustrate more fully and illustrate in detailed description after this.
The per-cent that relates in this specification sheets, ratio, ratio etc. specify and all to represent with weight except that having, all temperature except that have specify all with degree centigrade (℃) represent that the relevant portion of all references file is incorporated herein by reference.
Embodiment
To be described in detail water, other optional, materials in this cleanser compositions of anion surfactant, nonionogenic tenside, tangerine oil component and equal amount as necessary component, form, preparation and the application etc. of composition (all concentration and ratio are all represented with weight specifying except that having) below.
Anion surfactant
Preferred anionic surfactants tensio-active agent of the present invention comprises polyoxyethylene alkyl ether sulfate salt (AES) series, the pure ether ammonium sulfate of dodecyl (AESA) series, ammonium lauryl sulfate (K12A) series, secondary paraffin sulfonate (SAS) series.Special preferred fat polyoxyethylenated alcohol sulfuric acid, for example Fatty Alcohol(C12-C14 and C12-C18) is C
8～C
20Natural or synthetic fatty alcohol, the ethylene oxide polymerization degree is 1～5 polyoxyethylene alkyl ether sulfate salt, more preferably Fatty Alcohol(C12-C14 and C12-C18) is C
12～C
15Natural or synthetic fatty alcohol, the ethylene oxide polymerization degree is 2～3 polyoxyethylene alkyl ether sulfate salt, as dodecanol polyoxyethylene ether sulfate (AES).The C that particularly preferred example is for example produced for Sasol company
12～C
14Fatty alcohol-polyoxyethylene ether (2EO) sodium sulfate salt AES270N.
Its content of described anion surfactant accounts for 0.1 weight %-20 weight % of described composition, and preferred range is 1-10 weight %.
Nonionogenic tenside
The ionic surfactant pack that is suitable among the present invention is drawn together but is not limited to alkyl glycoside (APG) series, glucamide (APAO) series, N-methyl glucamine (AGA) series.Preferred alkyl glucoside (APG) and their mixture, as the alkyl glycoside of 4-18 carbon, the more preferably alkyl glycoside of 4-14 carbon.Glucopon 650EC, the Glucopon 225DK that particularly preferred specific examples is for example produced for Cognis company, Plantacare 2000UP etc.
The content of described nonionogenic tenside accounts for 0.1 weight %-30 weight % of described composition, and preferred range is 0.5-15 weight %.
The alkyl glycoside of mentioning among the present invention is a kind of to non-stimulated, the very gentle plant-sourced tensio-active agent of human body skin.The raw materials for production of alkyl glycoside (APG) mainly come from natural reproducible vegetalitas resource, as starch, Fatty Alcohol(C12-C14 and C12-C18) etc.Alkyl glycoside is that the hemiacetal hydroxyl by sugar dewaters under an acidic catalyst effect with alcoholic extract hydroxyl group and the compound that generates.Industry APG product is made of single glycosides, two glycosides and three glycosides etc.From molecular structure, APG belongs to nonionogenic tenside, but has the advantage of nonionic and anion surfactant concurrently: surface tension is low, latherability is strong, foam stabilization, and wettability is good, strong detergency, compatibility is splendid, and good synergistic is arranged, solubleness is still very high under the very high situation of electrolyte concentration, anti-hard water, dispersion of calcium soap is strong, and is nontoxic, non-stimulated, biological degradation is thorough rapidly etc.The alkyl glycoside (APG) that glucose and Fatty Alcohol(C12-C14 and C12-C18) or fatty acid response form in the employing natural matter starch is the agent of the surperficial quiet property of typical mild " green ".It is ripe that the large-scale production of domestic APG has become.The biological degradability of APG is fast and thorough.Biological degradation rate has reached 80% in 5 days, and ultimate biodegradation rate (20～30 days) can surpass more than 90%.APG is little to skin irritation, toxicity is minimum, LD50 is 10000-15000mg/kg, its HLB value with use anion surfactant always and nonionogenic tenside is close, can be widely used in the raw material of washing, concise, emulsification, dispersion agent, be that ideal APEO substitutes articles for use.
Tangerine oil
Oranges and tangerines belong to the Rutaceae tangerine and belong to (Citrus) plant, mainly comprise mandarin orange class, tangerine class, orange class (comprising bitter orange, sweet orange, bigarabe etc.), lemon class, shaddock class, high orange class or other mixed citrus fruit.
The tangerine oil of mentioning among the present invention is a colourless transparent liquid, and orange fragrance is arranged.Its main component is a terpene compound, and it is actually a kind of special vegetables oil, and is insoluble or be slightly soluble in water, has aromatic odour, and its main component is terpene hydrocarbons, arene, alcohol aldehyde ether ketone ester phenols etc.Sweet orange oil, neroli bigarade oil, lemon main body of oil are limonenes.
Unless specialize, the term that adopts among the present invention " tangerine oil " is meant the extract that partly obtains through method such as vapor distillation or squeezing, extraction or absorption via root, stem, leaf, flower, fruit, seed or the bark etc. of natural citrus.For example adopt disclosed method among FMC technology, Brown technology or the Chinese patent application publication number CN1702162A (document is introduced the part of the present invention as specification sheets of the present invention in full), or the like.General high strength tartaric acid class essence is used as the spices in food or the makeup in the extract, and remaining by product such as limonene CAS5989-27-5, terpenes CAS 68647-72-3 etc. can be used for food and chemical engineering industry as solvent or thinner because of it has the molten oiliness of superior cleaning.Objectionable impuritiess such as alternative chlorinated solvent, ethylene glycol, ether, methyl ethyl ketone, dimethylbenzene, freonll-11, chlorine oxyfluoride.Need particularly point out, non-extraction also is encompassed within the scope of " tangerine oil " of the present invention from other Bao Han limonene CAS5989-27-5, the terpenes CAS68647-72-3 of citrus or their various mixtures or the arbitrary substance be made up of limonene CAS5989-27-5, terpenes CAS 68647-72-3 or their various mixtures basically.
The content of described citrus essential oil accounts for 0.01～3 weight % of described composition, preferred 0.1～1 weight %.
Water
The surplus of cleanser compositions prescription of the present invention is the water as carrier, and water is used as the filler solvent of composition usually or constitutes concentration balance.
Except that disclosed liquid phase and solid components before this, cleanser compositions of the present invention can and preferably contain various other optional components.The optional component of this class can be the liquid or solid form.Described optional component can be dissolved in the liquid phase, perhaps can be dispersed in the liquid phase with the form of fine particle or small droplets.These optional components include but not limited to tinting material, pH regulator agent, buffer reagent, sequestrant, sanitas, sterilant, defoamer, foam agent, suds-stabilizing agent, membrane-forming agent, solubilizing agent, anti-deposition agent, thickening material, dispersion agent, enzyme, enzyme synergistic agent, spices, clay and their mixture.These that list are not meant and comprise altogether or get rid of and be suitable for material of the present invention.The suitable amounts of optional component is decided according to the actual requirements.The optional component that is preferably used in the cleanser compositions of the present invention comprises one or more conventional additives, particularly sequestrant safe in utilization with the mankind to environment (preferred sodium bicarbonate or yellow soda ash), sanitas, tinting material, spices, spices stablizer, viscosity modifier, pH regulator agent, buffer reagent etc. and their mixture.
According to a particularly preferred embodiment of the present invention, cleanser compositions of the present invention also contains washing auxiliary detergent except that above-mentioned necessary component.The washing auxiliary detergent that is suitable among the present invention includes but not limited to: organic bases, and as list, two or trolamine, coconut oil diethanolamine etc.; Washing auxiliary detergent such as ethers, alcohols is as Diethylene Glycol (list) butyl ether, propylene glycol monomethyl ether, propylene glycol butyl ether, propylene glycol propyl ether, Propylene Glycol Dimethyl Ether, butyl glycol ether etc.Preferred especially Diethylene Glycol butyl ether, butyl glycol ether.The content of washing auxiliary detergent accounts for the 0.01-10 weight % of composition total weight, preferred 0.1-5 weight %.
The form of composition and preparation method
Composition can be mixed with and have enough concentration for use, during use product is sprayed onto on the clean surface, for example cloth, paper handkerchief etc. are wiped with suitable material then.In addition, composition can be mixed with conc forms, dilute with water before using.Said composition can be packed with the packaging vessel thing, and this packaging vessel comprises the device that produces spraying, for example pump, aerosol propellants and jet valve etc.
Can prepare heavy duty type cleanser compositions of the present invention by required component is mixed and blend with required solvent.
As shown in hereinafter example, described degreasing composition is mainly by the synergistic effect of anion surfactant, nonionogenic tenside, washing auxiliary detergent and citrus extract, has that clean effect is good, low irritant, non-aggressive, low solvent odor, residual less, easily degraded, LD50 be more than or equal to characteristics such as 15000mg/kg.Be fit to be used for removal to crust dirts such as demanding zone safe in utilization such as dining room, kitchen, food-processing, swimming pool, school, kindergarten, gymnasiums.
The pH scope of said composition stoste in the time of 20 ℃ is 7-11.5, is preferably 8.5-10.5 (with reference to GB7919-1987 " safety evaluation of cosmetics program and method ").Therefore, the cleanser compositions among the present invention as mild as a dove.
Further set forth the compositions and methods of the invention below in conjunction with embodiment and test method.Embodiment is only in order to play illustrative effect, and do not mean that the scope that will limit accessory claim.Unless otherwise mentioned, all umbers wherein and percentage ratio etc. are all calculated in mass.Except as otherwise noted, all reagent that use among the embodiment are all buied from common chemical supplier.
Embodiment
The acute oral toxicity testing experiment
LD50 medium lethal dose (median lethal dose) is meant and causes the required dosage of a group study subject 50% individual death.Precise definition refers to obtain on the statistics, estimates to cause the single dose of animal half death.The unit of LD50 is the mg/kg body weight, and the numerical value of LD50 is more little, and the toxicity of expression poisonous substance is strong more; Otherwise LD50 numerical value is big more, and the toxicity of poisonous substance is low more.Among the present invention LD50 test reference method and judgement criteria be ministry of Health of China 2003 version " toxicological evaluation of food safety procedure and method " (GB15193-2003).With embodiment 1 is example, and the chmice acute per os toxicity test LD50 value that records through Shanghai City product toxicity quality surveillance measuring station is judged as nontoxic greater than 15000mg/kg.
The detergency test test
Dirt grease preparation: with lard: the ratio preparation of vegetables oil=1: 1, and add its total mass 5% glyceryl monostearate, 1-2 spoon carbon black is formulated as the artificial greasy dirt of black.Wherein lard is refining, and vegetables oil is Jin Longyu.This artificial greasy dirt is placed on the mid-electric furnace of beaker is heated to 180 ℃, stir and keep this temperature 10min, naturally cool to temperature required 80 ℃ standby, this moment, room temperature was 25 ℃.
3 slide glasss are cleaned with ethanol, and hot blast drying places moisture eliminator stand-by.With stand-by test piece weighing on balance, accurately to 0.1mg.Coat fused dirt grease for 1/3rd sections in the middle of the test piece of weighing got, naturally cool to room temperature, at room temperature place weighing behind the 48hr.
Prepare test solution to be measured, get the 150ml test solution in the 250ml Erlenmeyer flask, again the greasy dirt sheet is sandwiched (liquid just is dipped into greasy dirt) in the Erlenmeyer flask gently with tweezers, seal bottleneck with plastic fresh-keeping membrane, and carry out mark.This Erlenmeyer flask is put into the desk-top constant temperature oscillator of THZ-312 type, adjust the temperature to 30 degree, hunting speed 120r/min, vibrating stopped powered-down after 30 minutes.Greasy dirt sheet in the Erlenmeyer flask is taken out with tweezers, again with test piece in the normal-temperature distilled water of 200ml gently pendulum wash 5 times, use the hot blast drying of blower after the taking-up immediately, place weighing behind the moisture eliminator 30min.
Soil removal efficiency uses following formula to calculate:
Soil removal efficiency (%)=(m1-m2)/(m1-m0) * 100
M1-is with the quality of oily test piece, g in the formula;
M2-cleans the quality of back test piece, g;
The quality of the stand-by test piece of m0-, g.
Carry out other assessment of detersive power level according to following table 1:
Table 1
| Rank | Soil removal efficiency |
| Excellent | ＞90％ |
| Very | 80-90％ |
| Generally | 61-79％ |
| Relatively poor | 25-60％ |
| Difference | ＜25％ |
The source of the raw material that adopts among the embodiment is as follows:
AES270N is selected from the chemical company limited of husky rope (China)
Hostapar SAS60 is selected from Clariant chemical industry (China) company limited
MES (fatty alcohol-ether sulfonated ester) is selected from Shanghai GaoWei Chemical Co., Ltd
GLUCOPON 650EC, GLUCOPON 225DK are selected from peaceful grease chemical article limit company of Shanghai section
Dehypon LS45 is available from Shanghai Henkel sufacing company limited
D-limonene and Orange Terpenes (OTP2000) are selected from the Florida chemical Company that the U.S. two trade Co., Ltds in Shanghai are acted on behalf of
Dowanol EB Dowanol DB be selected from DOW Chemical (China) company limited
Embodiment preparation technology (1000 gram):
Embodiment 1: under the normal temperature and pressure, in reactor, add 600 gram water, add AES270N 120 grams successively, Glucopon650EC 30 grams, it is even to be stirred to material, add Dowanol DB 15 grams then, D-limonene 5 grams stir 30 minutes (but accelerating dissolving about mildly heating to 40 degree), and are even to material.The water polishing of surplus, it is even to be stirred to material at last.
Embodiment 2: under the normal temperature and pressure, in reactor, add 600 gram water, add AES270N 200 grams successively, Glucopon650EC 1 gram, it is even to be stirred to material, add Dowanol DB 15 grams then, D-limonene 5 grams stir 30 minutes (but accelerating dissolving about mildly heating to 40 degree), and are even to material.The water polishing of surplus, it is even to be stirred to material at last.
Embodiment 3: under the normal temperature and pressure, in reactor, add 600 gram water, add AES270N 1 gram successively, Glucopon650EC 300 grams, it is even to be stirred to material, add Dowanol DB 15 grams then, D-limonene 5 grams stir 30 minutes (but accelerating dissolving about mildly heating to 40 degree), and are even to material.The water polishing of surplus, it is even to be stirred to material at last.
Embodiment 4: under the normal temperature and pressure, in reactor, add 600 gram water, add AES270N 80 grams successively, Glucopon650EC 30 grams, it is even to be stirred to material, add Dowanol DB 40 grams then, D-limonene 30 grams stirred 30 minutes, accelerate dissolving about mildly heating to 40 degree, even to material.The water polishing of surplus, it is even to be stirred to material at last.
Embodiment 5: under the normal temperature and pressure, in reactor, add AES270N 120 grams successively, Glucopon225DK 30 grams, it is even to be stirred to material, adds Dowanol DB 15 grams then, D-limonene 5 grams stir 30 minutes (but accelerating dissolving about mildly heating to 40 degree), and are even to material.The water polishing of surplus, it is even to be stirred to material at last.
Embodiment 6: under the normal temperature and pressure, in reactor, add 600 gram water, add the HostaparSAS60120 gram successively, Glucopon650EC 30 grams, it is even to be stirred to material, add DowanolDB 40 grams then, D-limonene 10 grams stir 30 minutes (but accelerating dissolving about mildly heating to 40 degree), and are even to material.The water polishing of surplus, it is even to be stirred to material at last.
Embodiment 7: under the normal temperature and pressure, in reactor, add 600 gram water, add AES270N 120 grams successively, Glucopon650EC 30 grams, it is even to be stirred to material, add Dowanol DB 15 grams then, Orange Terpenes (OTP2000) 5 grams stir 30 minutes (but accelerating dissolving about mildly heating to 40 degree), and are even to material.The water polishing of surplus, it is even to be stirred to material at last.
Embodiment 8: under the normal temperature and pressure, in reactor, add 600 gram water, add AES270N 120 grams successively, Glucopon650EC 30 grams, it is even to be stirred to material, add Dowanol EB 15 grams then, D-limonene 5 grams stir 30 minutes (but accelerating dissolving about mildly heating to 40 degree), and are even to material.The water polishing of surplus, it is even to be stirred to material at last.
Comparative example 1:Under the normal temperature and pressure, in reactor, add 600 gram water, add the MES120 gram successively, Glucopon650EC 30 grams, it is even to be stirred to material, adds Dowanol DB15 gram then, D-limonene 5 grams stir 30 minutes (but accelerating dissolving about mildly heating to 40 degree), and are even to material.The water polishing of surplus, it is even to be stirred to material at last.
Comparative example 2:Under the normal temperature and pressure, in reactor, add 600 gram water, add AES270N 120 grams successively, Dehypon LS45 30 grams, it is even to be stirred to material, add Dowanol DB 15 grams then, D-limonene 5 grams stir 30 minutes (but accelerating dissolving about mildly heating to 40 degree), and are even to material.The water polishing of surplus, it is even to be stirred to material at last.
Comparative example 3:Under the normal temperature and pressure, in reactor, add 600 gram water, add Glucopon650EC 30 grams, it is even to be stirred to material, adds Dowanol DB 15 grams then, D-limonene 5 grams stir 30 minutes (but accelerating dissolving about mildly heating to 40 degree), and are even to material.The water polishing of surplus, it is even to be stirred to material at last.
Comparative example 4:Under the normal temperature and pressure, in reactor, add 600 gram water, add the AES270N80 gram, it is even to be stirred to material, adds Dowanol DB 15 grams then, and D-limonene 5 grams stir 30 minutes (but accelerating dissolving about mildly heating to 40 degree), and are even to material.The water polishing of surplus, it is even to be stirred to material at last.
Comparative example 5:Under the normal temperature and pressure, in reactor, add 600 gram water, add AES270N 80 grams successively, Glucopon650EC 60 grams stir 30 minutes (but accelerating dissolving about mildly heating to 40 degree), and are even to material.The water polishing of surplus, it is even to be stirred to material at last.
Prescription, the soil removal efficiency rank of each cleanser compositions among embodiment 1-8 and the comparative example 1-5 (numerical value is weight hundred umbers in the table) as shown in table 2 below:
Although the present invention is described in some embodiment and embodiment, those skilled in the art should be understood to the present invention and prolong and to other alternative embodiment and/or purposes of the present invention and conspicuous improvement and content of equal value from concrete disclosed embodiment.In addition, the present invention is not subjected to the restriction of the concrete disclosure of preferred embodiment herein.But the applicant means the restriction that scope of the present invention only is subjected to appended claim, and method disclosed herein and material are that conspicuous variation all will drop in applicant's the scope of invention for those skilled in the art.
Claims (26)
1. cleanser compositions comprises:
A) account for the anion surfactant of 0.1 weight %-20 weight % of described composition, described anion surfactant is selected from by polyoxyethylene alkyl ether sulfate salt series, dodecyl alcohol ether ammonium sulfate series, ammonium lauryl sulfate series, secondary paraffin sulfonate series, and the group formed of their mixture;
B) account for the nonionogenic tenside of 0.1 weight %-30 weight % of described composition;
C) account for the citrus essential oil of 0.01 weight %-3 weight % of described composition; With
D) water of equal amount.
2. cleanser compositions as claimed in claim 1, wherein, described anion surfactant is selected from polyoxyethylene alkyl ether sulfate salt.
3. cleanser compositions as claimed in claim 2, wherein, in the described polyoxyethylene alkyl ether sulfate salt, Fatty Alcohol(C12-C14 and C12-C18) is C
8～C
20Natural or synthetic fatty alcohol, the ethylene oxide polymerization degree is 1～5.
4. cleanser compositions as claimed in claim 3, wherein, in the described polyoxyethylene alkyl ether sulfate salt, Fatty Alcohol(C12-C14 and C12-C18) is C
12～C
15Natural or synthetic fatty alcohol, the ethylene oxide polymerization degree is 2～3.
5. cleanser compositions as claimed in claim 3, wherein, described polyoxyethylene alkyl ether sulfate salt is dodecanol polyoxyethylene ether sulfate (AES).
6. cleanser compositions as claimed in claim 1, wherein, the content of described anion surfactant is 1-10 weight %.
7. cleanser compositions as claimed in claim 1, wherein, described citrus essential oil is material: limonene CAS5989-27-5, the terpenes CAS 68647-72-3 that comprises at least a following compound or be made up of at least a following compound basically.
8. cleanser compositions as claimed in claim 1, wherein, the content of described citrus essential oil is 0.1-1 weight %.
9. cleanser compositions as claimed in claim 1, wherein, described nonionogenic tenside is selected from by alkyl glycoside series, glucamide series, N-methyl glucamine series, and the group formed of their mixture.
10. cleanser compositions as claimed in claim 9, wherein, described nonionogenic tenside is selected from alkyl-glucoside series and their mixture.
11. cleanser compositions as claimed in claim 10, wherein, described nonionogenic tenside is the alkyl glycoside with 4-18 carbon.
12. cleanser compositions as claimed in claim 11, wherein, described nonionogenic tenside is the alkyl glycoside with 4-14 carbon.
13. cleanser compositions as claimed in claim 1, wherein, the content of described nonionogenic tenside accounts for the 0.5-15 weight % of described composition.
14. cleanser compositions as claimed in claim 1, it also contains the washing auxiliary detergent of the 0.01 weight %-10 weight % that accounts for described composition.
15. cleanser compositions as claimed in claim 14, wherein, described washing auxiliary detergent is selected from the group of being made up of organic bases, ethers, alcohols.
16. cleanser compositions as claimed in claim 15, wherein, described washing auxiliary detergent is selected from list, two or trolamine, coconut oil diethanolamine.
17. cleanser compositions as claimed in claim 15, wherein, described washing auxiliary detergent is selected from the group of being made up of Diethylene Glycol (list) butyl ether, propylene glycol monomethyl ether, propylene glycol butyl ether, propylene glycol propyl ether, Propylene Glycol Dimethyl Ether and butyl glycol ether.
18. cleanser compositions as claimed in claim 17, wherein, described washing auxiliary detergent is selected from Diethylene Glycol butyl ether and butyl glycol ether.
19. cleanser compositions as claimed in claim 14, wherein, the content of described washing auxiliary detergent accounts for the 0.1-5 weight % of described composition.
20. composition as claimed in claim 1, wherein, the content of volatile organic compounds in described composition is less than 6 weight %.
21. cleanser compositions as claimed in claim 1, wherein, the pH scope of described composition stoste in the time of 20 ℃ is 7-11.5, is preferably 8.5-10.5.
22. cleanser compositions as claimed in claim 21, wherein, the pH scope of described composition stoste in the time of 20 ℃ is 8.5-10.5.
23. cleanser compositions as claimed in claim 1, wherein, described composition LD50 is more than or equal to 5000mg/kg.
24. cleanser compositions as claimed in claim 23, wherein, described composition LD50 is more than or equal to 15000mg/kg.
25. composition as claimed in claim 1, it also contains one or more additives that are selected from the group of being made up of sequestrant, sanitas, tinting material, spices, spices stablizer, viscosity modifier, pH regulator agent, buffer reagent and their mixture.
26. one kind is removed the cleaning method of crude removal from substrate surface, described method comprise make base material with as each the contacted step of cleanser compositions among the claim 1-25.
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|---|---|---|---|
| CN2007100842033A CN101255381B (en) | 2007-02-27 | 2007-02-27 | Cleaning method and combination |
| PCT/US2008/053427 WO2008106290A1 (en) | 2007-02-27 | 2008-02-08 | Cleaning compositions and methods using the same |
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|---|---|---|---|
| CN2007100842033A CN101255381B (en) | 2007-02-27 | 2007-02-27 | Cleaning method and combination |
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| CN101255381B CN101255381B (en) | 2012-03-21 |
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| WO (1) | WO2008106290A1 (en) |
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| WO2008106290A1 (en) | 2008-09-04 |
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