CN108641827A - Ultra-clean bactericidal liquid of washing machine and preparation method thereof - Google Patents
Ultra-clean bactericidal liquid of washing machine and preparation method thereof Download PDFInfo
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- CN108641827A CN108641827A CN201810388003.5A CN201810388003A CN108641827A CN 108641827 A CN108641827 A CN 108641827A CN 201810388003 A CN201810388003 A CN 201810388003A CN 108641827 A CN108641827 A CN 108641827A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
- C11D1/8255—Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
- A01N47/44—Guanidine; Derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/28—Myrtaceae [Myrtle family], e.g. teatree or clove
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/188—Terpenes
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2027—Monohydric alcohols unsaturated
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2072—Aldehydes-ketones
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/33—Amino carboxylic acids
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/36—Organic compounds containing phosphorus
- C11D3/362—Phosphates or phosphites
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Abstract
The invention discloses a kind of ultra-clean bactericidal liquids of washing machine, include the raw material components of following weight：The aroma type solvent of 38 parts by weight hexamethylenes, the eucalyptus citriodora extraction of essential oil object of 3 10 parts by weight, the organic multicomponent phosphate acid of 5 30 parts by weight, the surfactant of 45 80 parts by weight, the solubilizer of 5 15 parts by weight, the chelating agent of 3 15 parts by weight and 0.1 2 parts by weight.The present invention also provides the preparation methods of the ultra-clean bactericidal liquid of the washing machine, by the ultra-clean bactericidal liquid of washing machine made from this method the bacteriums such as Escherichia coli, staphylococcus aureus, Candida albicans, shigella flexneri, pseudomonas aeruginosa can be reached with 99.9% killing rate, and with good fungistatic effect (according to standard：There is the product of Shuai≤50 Yi Jun~90% bacteriostasis, Yi Jun Shuai≤90%, product to have stronger bacteriostasis), the ultra-clean bactericidal liquid bacteriostasis rate of washing machine in this implementations is up to 90%, with excellent sterilization effect.
Description
Technical field
The present invention relates to the preparation methods of a kind of ultra-clean bactericidal liquid of washing machine and a kind of ultra-clean bactericidal liquid of washing machine.
Background technology
Today's society washing machine generally arrives each family substantially, and the fiber of incrustation scale and clothes of the washing machine after work is residual
It stays, in addition most of washing machine is placed in the toilet in divulge information bad place or humidity and the environment of washing machine internal is temperature
Warm current is wet, after leaving unused several days, can grow a large amount of moulds.Longer using being spaced, the quantity that mould is grown in inside is more.Greatly
If family is taken using the laundry washer for having mould for a long time, it is easy for leading to cross infection, causes all kinds of skin diseases.For family
With washing machine pollution condition by washing machine dirt sample bacterial analysis display find washing machine drum, tub gap it is thin
Bacterium exceeding standard rate is 81.3%, and total coli group recall rate is 100%, and mould recall rate is 60.2%.Good cleaning is not paid attention to usually,
It is often easy to during cleaning clothing, secondary pollution is carried out to clothing.Human body wears the clothing of secondary pollution, and pole holds
Easily infected by germ.Especially as old man and infant, these specific groups of pregnant woman, since itself resistance is weaker, just more
It is easy to be invaded by germ.And to germ in washing machine to human body can caused by endanger, mould is danger close for women,
It is easy to cause the gynaecological diseases such as mycotic colpitis, bigger is endangered to the women in pregnancy period, newborn also has infected danger
Danger, while can also cause the multiple dermatosis such as the ringworm of the foot, the tinea manuum.
Invention content
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of ultra-clean bactericidal liquid of washing machine and the laundries
The preparation method of the ultra-clean bactericidal liquid of machine.
The scheme of the invention is be achieved：
A kind of ultra-clean bactericidal liquid of washing machine, includes the raw material components of following weight：
Further, the surfactant is nonionic surfactant.
Further, the nonionic surfactant includes isomery ceteth -10, fatty alcohol polyoxyethylene ether
It is one or more in aeo-9, fatty alcohol polyoxyethylene ether aeo-7, castor oil soap base, cocoanut fatty acid diethanolamide.
Further, the solubilizer includes edible alcohol, trideceth -8, tridecanol acrylic acid, 2- (4- first
Base -3- cyclohexenyl groups) -2- propyl alcohol, dimethylcarbinol, 1,3- propylene glycol, rilanit special it is one or more.
Further, the chelating agent includes EDETATE SODIUM, tetrasodium ethylenediamine tetraacetate, sodium citrate, ethoxy second two
It is one or more in amine triacetic acid.
Further, the aroma type solvent includes one kind or more in limonene, lemon extract, butylbenzene ylmethyl propionic aldehyde
Kind.
A kind of preparation method of the ultra-clean bactericidal liquid of washing machine, includes the following steps：
The surfactant of 45-80 parts by weight is mixed with the hexamethylene of 3-8 parts by weight, is stirred
Mixed liquor A；
The eucalyptus citriodora extraction of essential oil object of 3-10 parts by weight is mixed with the solubilizer of 5-15 parts by weight, stirs to obtain mixed liquid B；
Mixed liquor A is mixed with mixed liquid B, stirs to obtain mixed liquor C；
The chelating agent of 3-15 parts by weight is added in mixed liquor C, mixed liquor D is stirred to obtain；
Mixed liquor D is added in the organic multicomponent phosphate acid of 5-30 parts by weight and the aroma type solvent of 0.1-2 parts by weight
In, stir to obtain the ultra-clean bactericidal liquid of washing machine.
The beneficial effects of the invention are as follows：
In the ultra-clean bactericidal liquid of washing machine of the present invention, hexamethylene and eucalyptus citriodora extraction of essential oil object are made
For main sterilizing ingredient, wherein hexamethylene can kill mould and some fungi, but cannot be effective
Kill the fungi for causing skin disease, and eucalyptus citriodora oil extract then pair skin disease related with insect, fungi, bacterium totally ten two
A disease all has different degrees of effect, especially more notable with scabies and tinea versicolor, both sterilizing ingredients are answered
Match so that increase sterilization type while ultra-clean bactericidal liquid enhancing bactericidal effect, reach more preferable wider array of sterilization, antibacterial effect
Fruit can more effectively reduce infection risk.Meanwhile the surfactant of addition can more good dissolving, the softening spots such as incrustation scale, add
Strong cleaning effect so that the ultra-clean bactericidal liquid of washing machine is by a variety of disinfection ingredients comprehensively to be cleaned.
The ultra-clean bactericidal liquid of washing machine produced by the present invention is to Escherichia coli, staphylococcus aureus, Candida albicans, Fu Shi
The bacteriums such as shigella dysenteriae, pseudomonas aeruginosa can reach 99.9% killing rate, and with good fungistatic effect (according to mark
It is accurate：There is 50~90% product of bacteriostasis rate bacteriostasis, bacteriostasis rate 90%, product to have stronger bacteriostasis), washing in this implementation
The ultra-clean bactericidal liquid bacteriostasis rate of clothing machine is up to 90%, has excellent sterilization effect.
Description of the drawings
The invention will be further described with embodiment below in conjunction with the accompanying drawings.
Fig. 1 is the preparation method flow diagram of the ultra-clean bactericidal liquid of washing machine in one embodiment of the invention.
Specific implementation mode
It should be noted that in the absence of conflict, the feature in embodiment and embodiment in the present invention can phase
Mutually combination.Below with reference to the attached drawing of the embodiment of the present invention, technical scheme of the present invention is described further, the present invention is not only
It is limited to detailed description below.
As shown in Figure 1, it is the ultra-clean bactericidal liquid of washing machine of an embodiment, include the raw material group of following weight
Point：
A kind of ultra-clean bactericidal liquid of washing machine of the offer of the present invention is used to carry out sterilizing to washing machine internal, by poly- six
Di-2-ethylhexylphosphine oxide guanidine hydrochloride, eucalyptus citriodora extraction of essential oil object, organic multicomponent phosphate acid, surfactant, solubilizer, chelating agent and
Aroma type solvent mixes, specifically, in the ultra-clean sterilization formula of liquid of washing machine of the present invention, hexamethylene
Main component be polyhexamethylene guanide, chemical formula be (C8H17N5)nXHCl is a kind of environmental protection with broad spectrum antibacterial activity
Type fungicide, hexamethylene have colorless and odorless, antibacterial effective concentration is low, wide spectrum is less toxic, work fast,
The good characteristics such as foam volume is low, soluble easily in water, property is stablized, and can be when article surface one layer of cation of formation continues long
Between it is antibacterial, can be long-term antibacterial, and be not in asking for bacterial drug resistance since sterilization process is a kind of physical action
Topic will not cause to generate antibacterial bacteria characteristic.The mechanism of action of the sterilization of hexamethylene is：Polyhexamethylene
Guanidine radicals in biguanide hydrochloride has very high activity, and polymer can be made at electropositive, be easy by electronegative all kinds of bacteriums, disease
Poison is adsorbed, and to inhibit the splitting function of bacterial virus, it is made to lose fecundity, in addition the film that polymer is formed blocks
The respiration channel of microorganism, makes the rapid death by suffocation of microorganism.Using hexamethylene with disinfection, nothing
Side effect generates, and its corrosivity is extremely low, is used for a long time under common dosage also corrosion-free to equipment and materials.Also, poly- six
The bactericidal effect of di-2-ethylhexylphosphine oxide guanidine hydrochloride is by environment temperature, pH (hydrogen ion concentration, hydrogen ion concentration
Index) and the influence of organic matter etc. it is smaller, lot of experiments shows poly hexamethylene biguanide in extremely low concentration (10ppm)
Under can kill cotton fabric bacterial catalase and fungi, Acanthamoeba Keratitis pathogen, Escherichia coli of going out, golden yellow Portugal
Grape coccus and Candida albicans, skin natural bacteria, inactivation of viruses, bacterial spore, bacterial propagule etc., especially for generally killing
The microbial inoculum peculiar effect of Gram-negative bacteria all difficult to deal with, has food pathogen and pollutant high activity.Poly- six methylene
Base biguanide hydrochloride plays important sterilization in the present invention.
Eucalyptus citriodora extraction of essential oil object is derived from the natural extract of the plants essential oils such as eucalyptus citriodora essential oil, and eucalyptus citriodora essential oil
A kind of plants essential oil extracted from eucalyptus citriodora megaphanerophyte leaf, eucalyptus citriodora extraction of essential oil object it is biologically active effectively at
Part, there is good bacteriostasis to staphylococcus aureus, Escherichia coli, shigella flexneri and beta hemolytic streptococcus,
Have hay bacillus with certain effect, has certain bacteriostasis to 10 kinds of fungies and 12 kinds of actinomyces, especially with to stone lamb sample
The effects that trichophyta, Trichophyton rubrum and oidium schoenleinii, is stronger.Wherein, comparative test result, the effect to griseofulvin
Effect is strong, weaker to the function and effect of nystatin.Experimental results demonstrate the related skins caused for insect, fungi, bacterium
(including fiber crops are sought in the life of scabies, tinea versicolor, stock stern tinea, tinea pedis, the tinea manuum, ringworm of the body, cutaneous candidiasis, papule to disease for totally ten two diseases
Rash, acne, impetigo, underarm odor disease etc.) all there is different degrees of effect.
In the above-mentioned ultra-clean sterilization formula of liquid of washing machine, the organic multicomponent phosphoric acid resin acid is for derusting, going calcium and magnesium dirty, its energy
Enough it is attached to the surface of incrustation scale so that bactericidal liquid being capable of more good dissolving, the softening spots such as incrustation scale；The surfactant is for adding
Strong cleaning effect, the surfactant have good foaming, foam stabilizing, infiltration decontamination, hard water resistance performance, reinforce cleaning effect
Fruit, the solubilizer are used to improve the compatibility of hexamethylene and eucalyptus citriodora extraction of essential oil object so that the two
It can mix more uniform.
In the ultra-clean sterilization formula of liquid of the present invention, the surfactant is nonionic surfactant, in a reality
It applies in example, the nonionic surfactant includes isomery ceteth -10, fatty alcohol polyoxyethylene ether aeo-9, fatty alcohol
It is one or more in polyoxyethylene ether aeo-7, castor oil soap base, cocoanut fatty acid diethanolamide, use isomery spermaceti
Alcohol polyethers -10, fatty alcohol polyoxyethylene ether aeo-9, fatty alcohol polyoxyethylene ether aeo-7, castor oil soap base, coco-nut oil fatty acid
When surfactant as an embodiment of a variety of in diglycollic amide, which is uniformly mixed mixture,
For example, the surfactant is the mixture of isomery ceteth -10 and fatty alcohol polyoxyethylene ether aeo-9；The solubilising
Agent includes edible alcohol, trideceth -8, tridecanol acrylic acid, 2- (4- methyl -3- cyclohexenyl groups) -2- propyl alcohol, diformazan
It is one or more in base methanol, 1,3-PD, rilanit special, use edible alcohol, trideceth -8, tridecanol
It is a variety of in acrylic acid, 2- (4- methyl -3- cyclohexenyl groups) -2- propyl alcohol, dimethylcarbinol, 1,3- propylene glycol, rilanit special
When solubilizer as an embodiment, which is uniformly mixed mixture, for example, the solubilizer is 2- (4- methyl -3-
Cyclohexenyl group) -2- propyl alcohol and tridecanol acrylic acid mixture；The chelating agent includes EDTA
(Ethylenediaminetetraacetic acid, ethylenediamine tetra-acetic acid) disodium, tetrasodium ethylenediamine tetraacetate, citric acid
It is one or more in sodium, hydroxyethylethylene diamine tri-acetic acid, use EDETATE SODIUM, tetrasodium ethylenediamine tetraacetate, sodium citrate, hydroxyl
When chelating agent as an embodiment of a variety of in ethyl-3-acetic acid ethylenediamine, which is uniformly mixed mixture, example
Such as, which is the mixture of EDETATE SODIUM and tetrasodium ethylenediamine tetraacetate；The aroma type solvent includes limonene, lemon
It is one or more in essence, butylbenzene ylmethyl propionic aldehyde, using a variety of in limonene, lemon extract, butylbenzene ylmethyl propionic aldehyde
When aroma type solvent as an embodiment, which is uniformly mixed mixture, for example, the aroma type solvent is
The mixture of limonene and lemon extract.
The present invention also provides a kind of preparation methods of the ultra-clean bactericidal liquid of washing machine, with the ultra-clean sterilization of washing machine described above
A kind of ultra-clean bactericidal liquid of washing machine can be made to prepare, with the preparation method in the composition of raw materials of the weight of liquid, one
In a embodiment, include the following steps：
Step 100：
The surfactant of 45-80 parts by weight is mixed with the hexamethylene of 3-8 parts by weight, stirring is extremely
It is completely dissolved, obtains mixed liquor A.
The eucalyptus citriodora extraction of essential oil object of 3-10 parts by weight is mixed with the solubilizer of 5-15 parts by weight, is stirred to completely molten
Solution, obtains mixed liquid B.
Step 200：
Mixed liquor A is mixed with mixed liquid B, stirs to being completely dissolved, obtains mixed liquor C.
The surfactant is nonionic surfactant, in one embodiment, the nonionic surfactant
Including isomery ceteth -10, fatty alcohol polyoxyethylene ether aeo-9, fatty alcohol polyoxyethylene ether aeo-7, monopol soap
It is one or more in base, cocoanut fatty acid diethanolamide.
The solubilizer includes edible alcohol, trideceth -8, tridecanol acrylic acid, 2- (4- methyl -3- hexamethylenes
Alkenyl) it is -2- propyl alcohol, dimethylcarbinol, 1,3- propylene glycol, one or more in rilanit special.
In the ultra-clean bactericidal liquid of washing machine of the present invention, hexamethylene and eucalyptus citriodora extraction of essential oil object are made
For main sterilizing ingredient, wherein hexamethylene can kill mould and some fungi, but cannot be effective
Kill the fungi for causing skin disease, and eucalyptus citriodora oil extract then pair skin disease related with insect, fungi, bacterium totally ten two
A disease (including scabies, tinea versicolor, stock stern tinea, tinea pedis, the tinea manuum, ringworm of the body, cutaneous candidiasis, papule life urticaria, acne,
Impetigo, underarm odor disease etc.) all there is different degrees of effect, it is especially more notable with scabies and tinea versicolor, by both sterilizings
Ingredient is compounded so that is increased sterilization type while ultra-clean bactericidal liquid enhancing bactericidal effect, is reached more preferably wider array of and kill
Bacterium, fungistatic effect can more effectively reduce infection risk.In order to improve the compatibility of both sterilizing ingredients, make it mutually
It mixing uniformly, the hexamethylene is good with nonionic surfactant compatibility, and and anionic surface
The limited compatibility of activating agent, alkali, composite phosphate and strong oxidizer, the eucalyptus citriodora extraction of essential oil object are derived from eucalyptus citriodora
The natural extract of the plants essential oils such as essential oil, main component are citral, and citral is dissolved in oils, propylene glycol and ethyl alcohol, because
Hexamethylene is first mixed respectively with surfactant in an embodiment of the present invention, eucalyptus citriodora is smart by this
Oil extract is mixed with solubilizer, so that hexamethylene can more preferably, more with eucalyptus citriodora extraction of essential oil object
Be sufficiently mixed, meanwhile, surfactant can more good dissolving, the softening spots such as incrustation scale, reinforce cleaning effect so that the present invention
The ultra-clean bactericidal liquid of washing machine by a variety of disinfections, sterilization, decontamination ingredient to be comprehensively to be cleaned.
Step 300：The chelating agent of 3-15 parts by weight is added in mixed liquor C, uniform stirring obtains mixed liquor to being completely dissolved
D。
Step 400：The organic multicomponent phosphate acid of 5-30 parts by weight and the aroma type solvent of 0.1-2 parts by weight are added mixed
It closes in liquid D, stirs to being completely dissolved, obtain the ultra-clean bactericidal liquid of washing machine.
The chelating agent includes in EDETATE SODIUM, tetrasodium ethylenediamine tetraacetate, sodium citrate, hydroxyethylethylene diamine tri-acetic acid
It is one or more.
The aroma type solvent includes one or more in limonene, lemon extract, butylbenzene ylmethyl propionic aldehyde.
The chelating agent is with aroma type solvent for having dispersion while so that various composition is more preferably mixed, resisting and sink again
Product function, can more preferably disperse incrustation scale, spot etc., prevent incrustation scale, grime and adhere to again, reach more preferable, more thoroughly go
The cleaning effect of dirt.
The dirt of washing machine interlayer attachment, such as incrustation scale, laundry detergents educt, clothes fiber and other organic matters, merely
It can not preferably penetrate into inside the spots such as incrustation scale and be cleaned by surfactant, cause sterilization component that can only kill dirt
The bacterium of upper surface can not more preferably penetrate into inside spot and be sterilized, and be unable to reach the effective spots such as scale removal and more of going
Well more fully bactericidal effect, and organic multicomponent phosphoric acid resin acid can effectively dissolve, soften the spots such as incrustation scale, organic multicomponent phosphoric acid
Resin acid dissolving is attached to washing machine tank incrustation scale surface so that there is the surfactant of infiltration decontamination can more preferably permeate and go deep into spot
Internal layer enables sterilization component more effectively to go deep into being killed inside spot, reaches better de-sludging, goes stain with sterilizing, is antibacterial
Effect.
Below the present invention is further described with embodiment.
Embodiment 1
By the isomery ceteth -10 of 50 parts by weight, the fatty alcohol polyoxyethylene ether aeo-7 of 7 parts by weight and 10 weight
The fatty alcohol polyoxyethylene ether aeo-9 of part is added in stirred tank, and the polyhexamethylene of 3 parts by weight is added to being completely dissolved in stirring
Biguanide hydrochloride after uniform stirring, obtains transparent mixed liquor A.
The eucalyptus citriodora oil extract of 3 parts by weight and the trideceth -8 of 10 parts by weight are added in another stirred tank,
Uniform stirring obtains transparent mixed liquid B to being completely dissolved.
Mixed liquid B is added in mixed liquor A again and is stirred, uniform stirring obtains transparent mixed liquor C to being completely dissolved.
The sodium citrates of 1 parts by weight is added in mixed liquor C, uniform stirring is to being completely dissolved to obtain mixed liquor D.
The organic multicomponent phosphate acid of 15 parts by weight and the limonene of 1 parts by weight are added in mixed liquor D, uniform stirring is extremely
Dissolving, obtains the ultra-clean bactericidal liquid of washing machine.
It is the test experiments data of the ultra-clean bactericidal liquid of washing machine made from the present embodiment below：
Table 1
Table 2
As can be known from the table data, in the present embodiment the ultra-clean bactericidal liquid of washing machine obtained to Escherichia coli, golden yellow grape
The bacteriums such as coccus, Candida albicans, shigella flexneri, pseudomonas aeruginosa can reach 99.9% killing rate, and have
Good fungistatic effect is (according to standard：There is 50~90% product of bacteriostasis rate bacteriostasis, bacteriostasis rate 90%, product to have relatively strong
Bacteriostasis), the ultra-clean bactericidal liquid bacteriostasis rate of washing machine in this implementation is up to 90%, has excellent sterilization effect.
Embodiment 2
The fatty alcohol polyoxyethylene ether aeo-9 additions of the isomery ceteth -10 of 55 parts by weight and 9 parts by weight are stirred
It mixes in kettle, the hexamethylene of 4.5 parts by weight is added to being completely dissolved in stirring, after uniform stirring, obtains transparent
Mixed liquor A.
The eucalyptus citriodora oil extract of 3 parts by weight and the edible alcohol of 9 parts by weight are added in another stirred tank, uniform stirring
To being completely dissolved, transparent mixed liquid B is obtained.
Mixed liquid B is added in mixed liquor A again and is stirred, uniform stirring obtains transparent mixed liquor C to being completely dissolved.
The EDETATE SODIUMs of 2 parts by weight is added in mixed liquor C, uniform stirring is to being completely dissolved to obtain mixed liquor D.
The organic multicomponent phosphate acid of 16 parts by weight and the butylbenzene ylmethyl propionic aldehyde of 1.5 parts by weight are added in mixed liquor D,
Uniform stirring obtains the ultra-clean bactericidal liquid of washing machine to dissolving.
It is the test experiments data of the ultra-clean bactericidal liquid of washing machine made from the present embodiment below：
Table 3
Table 4
As can be known from the table data, in the present embodiment the ultra-clean bactericidal liquid of washing machine obtained to Escherichia coli, golden yellow grape
The bacteriums such as coccus, Candida albicans, shigella flexneri, pseudomonas aeruginosa can reach 99.9% killing rate, and have
Good fungistatic effect is (according to standard：There is 50~90% product of bacteriostasis rate bacteriostasis, bacteriostasis rate 90%, product to have relatively strong
Bacteriostasis), the ultra-clean bactericidal liquid bacteriostasis rate of washing machine in this implementation is up to 90%, has excellent sterilization effect.
Embodiment 3
The fatty alcohol polyoxyethylene ether aeo-9 additions of the isomery ceteth -10 of 56 parts by weight and 10 parts by weight are stirred
It mixes in kettle, the hexamethylene of 3.5 parts by weight is added to being completely dissolved in stirring, after uniform stirring, obtains transparent
Mixed liquor A.
2- (4- methyl -3- cyclohexenyl groups) -2- propyl alcohol of the eucalyptus citriodora oil extract of 3 parts by weight and 9.5 parts by weight is added
Enter in another stirred tank, uniform stirring obtains transparent mixed liquid B to being completely dissolved.
Mixed liquid B is added in mixed liquor A again and is stirred, uniform stirring obtains transparent mixed liquor C to being completely dissolved.
The ethyl-3-acetic acid ethylenediamines of 2 parts by weight is added in mixed liquor C, uniform stirring is to being completely dissolved to obtain mixed liquor D.
The organic multicomponent phosphate acid of 15 parts by weight and the limonene of 1 parts by weight are added in mixed liquor D, uniform stirring is extremely
Dissolving, obtains the ultra-clean bactericidal liquid of washing machine.
It is the test experiments data of the ultra-clean bactericidal liquid of washing machine made from the present embodiment below：
Table 5
Table 6
As can be known from the table data, in the present embodiment the ultra-clean bactericidal liquid of washing machine obtained to Escherichia coli, golden yellow grape
The bacteriums such as coccus, Candida albicans, shigella flexneri, pseudomonas aeruginosa can reach 99.9% killing rate, and have
Good fungistatic effect is (according to standard：There is 50~90% product of bacteriostasis rate bacteriostasis, bacteriostasis rate 90%, product to have relatively strong
Bacteriostasis), the ultra-clean bactericidal liquid bacteriostasis rate of washing machine in this implementation is up to 90%, has excellent sterilization effect.
In addition, by comparing other existing disinfection sanitizers on the market, below table is obtained：
Endangering bigger bacterium to the mankind has a Candida albicans and some other bacterium class, in two lives often in contact with to
Bacterium have Escherichia coli, staphylococcus aureus and other kinds bacterium, mould etc..It, can if they are attached on clothes
It can cause skin allergy because of fungal infection；It is serious also to cause the gynaecology such as colpomycosis disease if it is underwear
Disease.By sterilizing contrast experiment, hence it is evident that as can be seen that the ultra-clean bactericidal liquid of washing machine that the present invention is prepared can carry out it
Effective specific aim processing.The ultra-clean bactericidal liquid of washing machine that the present invention is prepared has good disinfection effect, can
It kills all kinds of strains common in life and causes various bacteriums, the mould of evil to human body, and there is long-acting bacteriostatic effect, this is washed
The ultra-clean bactericidal liquid of clothing machine is harmless, not can cause environmental pollution, safety and environmental protection.
Each technical characteristic of embodiment described above can be combined arbitrarily, to keep description succinct, not to above-mentioned reality
It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, it is all considered to be the range of this specification record.
Several embodiments of the invention above described embodiment only expresses, the description thereof is more specific and detailed, but simultaneously
It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art
It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention
Range.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (7)
1. a kind of ultra-clean bactericidal liquid of washing machine, which is characterized in that include the raw material components of following weight：
2. the ultra-clean bactericidal liquid of washing machine according to claim 1, which is characterized in that the surfactant is nonionic table
Face activating agent.
3. the ultra-clean bactericidal liquid of washing machine according to claim 2, which is characterized in that the nonionic surfactant includes
Isomery ceteth -10, fatty alcohol polyoxyethylene ether aeo-9, fatty alcohol polyoxyethylene ether aeo-7, castor oil soap base, coconut
It is one or more in fatty acid oil diglycollic amide.
4. the ultra-clean bactericidal liquid of washing machine according to claim 1, which is characterized in that the solubilizer include edible alcohol,
Trideceth -8, tridecanol acrylic acid, 2- (4- methyl -3- cyclohexenyl groups) -2- propyl alcohol, dimethylcarbinol, 1,3- the third two
Alcohol, rilanit special it is one or more.
5. the ultra-clean bactericidal liquid of washing machine according to claim 1, which is characterized in that the chelating agent include EDETATE SODIUM,
It is one or more in tetrasodium ethylenediamine tetraacetate, sodium citrate, hydroxyethylethylene diamine tri-acetic acid.
6. the ultra-clean bactericidal liquid of washing machine according to claim 1, which is characterized in that the aroma type solvent includes lemon
It is one or more in alkene, lemon extract, butylbenzene ylmethyl propionic aldehyde.
7. a kind of preparation method of the ultra-clean bactericidal liquid of washing machine, which is characterized in that include the following steps：
The surfactant of 45-80 parts by weight is mixed with the hexamethylene of 3-8 parts by weight, stirs to obtain mixing
Liquid A；
The eucalyptus citriodora extraction of essential oil object of 3-10 parts by weight is mixed with the solubilizer of 5-15 parts by weight, stirs to obtain mixed liquid B；
Mixed liquor A is mixed with mixed liquid B, stirs to obtain mixed liquor C；
The chelating agent of 3-15 parts by weight is added in mixed liquor C, mixed liquor D is stirred to obtain；
The organic multicomponent phosphate acid of 5-30 parts by weight and the aroma type solvent of 0.1-2 parts by weight are added in mixed liquor D, stirring
Obtain the ultra-clean bactericidal liquid of washing machine.
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| CN111592945A (en) * | 2020-06-05 | 2020-08-28 | 上海和黄白猫有限公司 | Antibacterial clothes cleaning spray and preparation method thereof |
| CN113416612A (en) * | 2021-07-13 | 2021-09-21 | 詹卫浩 | Antibacterial laundry fragrance retaining bead and preparation method thereof |
| CN114960196A (en) * | 2022-06-07 | 2022-08-30 | 高梵(浙江)信息技术有限公司 | Detachable warm-keeping down jacket convenient to clean and preparation method thereof |
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| CN109837147A (en) * | 2019-01-09 | 2019-06-04 | 王鹏鹤 | A kind of door of washing machine sealing rubber ring mildew cleaning agent and preparation method thereof |
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| CN115350317A (en) * | 2022-08-30 | 2022-11-18 | 振德医疗用品股份有限公司 | Wound dressing composition and preparation method thereof |
| CN115350317B (en) * | 2022-08-30 | 2024-04-02 | 振德医疗用品股份有限公司 | Wound dressing composition and preparation method thereof |
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