CN103694958B - Glass antifogging agent and preparation method thereof - Google Patents
Glass antifogging agent and preparation method thereof Download PDFInfo
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- CN103694958B CN103694958B CN201210368018.8A CN201210368018A CN103694958B CN 103694958 B CN103694958 B CN 103694958B CN 201210368018 A CN201210368018 A CN 201210368018A CN 103694958 B CN103694958 B CN 103694958B
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- glass antidimmer
- dipropylene glycol
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Abstract
The invention provides a glass antifogging agent. The glass antifogging agent comprises 0.1-0.5wt% of a modified acrylic polymer, 0.05-0.5wt% of highly-polymerized alkyl glycoside, 2-10wt% of propanediol ether, 50-60wt% of water, and the balance low molecular alcohol. The invention also discloses a preparation method of the glass antifogging agent. The glass antifogging agent has a good antifogging performance, a good antifogging stability and a good cleaning performance.
Description
Technical field
The present invention relates to a kind of antifogging agent, specifically, relate to a kind of glass antidimmer and preparation method thereof, belong to chemical field.
Background technology
The research of glass antidimmer is in the stage of active development at present, and each state all expands the research to antifogging agent, and particularly along with the development in automobile industry, the application of glass aspect is day by day obvious.
Along with the progress of science and technology, the development of diversification makes the research of glass antidimmer occur the situation that a hundred flowers blossom, and various diverse ways and principle have respective feature and distinctive feature.And a kind of desirable antifogging agent should have, and cost is low, the feature of good antifogging effect, lasting period length, and easy to use, to glass non-corrosiveness, to human body without harm.
Therefore, developing the antifogging agent product innovation of highly effective and promote the use of, is the key of current antifog work.
Summary of the invention
The object of the present invention is to provide a kind of glass antidimmer with good anti-fog performance, antifog stability and cleaning performance.
In order to realize the object of the invention, glass antidimmer of the present invention, it is made up of the raw material of following weight percent:
Modified acrylic polymer 0.1-0.5%,
Alkyl glycoside with high polymerization degree 0.05-0.5%,
Dipropylene glycol 2-10%,
Water 50-60%,
Low mass molecule alcohol surplus.
Wherein, preferably, it is made up of the raw material of following weight percent:
Modified acrylic polymer 0.3-0.5%,
Alkyl glycoside with high polymerization degree 0.2-0.5%,
Dipropylene glycol 4-10%,
Water 50-60%,
Low mass molecule alcohol surplus.
Described modified acrylic polymer is water-soluble acrylic copolymer, the polyquart ampho149 of such as Kening Co., Ltd.Because water-soluble acrylic copolymer's hydrophilicity is excellent, the hydrophilicity-imparting treatment of glass surface can be conducive to.
Described alkyl glycoside with high polymerization degree is nonionogenic tenside, such as TRITONBG-10 or TRITON CG-110.It belongs to a kind of environment-friendly type nonionogenic tenside of natural high surface and high biological degradability, has both been conducive to the antifog process of glass surface, is conducive to again glass surface and cleans, but also environmental protection.
Described dipropylene glycol is dipropylene, dipropylene glycol propyl ether, dimethyl ether, dipropylene glycol ethyl ether, is conducive to cleaning glass surface.
Described low mass molecule alcohol is methyl alcohol, ethanol or Virahol; Described low mass molecule alcohol is conducive to the antifreeze effect of cleaning and improving antifogging agent to glass surface.
Described water preferably adopts deionized water.
The preparation method of glass antidimmer of the present invention, its adopt first by proportioning by soluble in water to modified acrylic polymer, alkyl glycoside with high polymerization degree and propandiol butyl ether, finally add low mass molecule alcohol, mix and form.
Glass antidimmer of the present invention has good anti-fog performance, antifog stability and cleaning performance.
Embodiment
Following examples for illustration of the present invention, but are not used for limiting the scope of the invention.
Embodiment 1
The glass antidimmer of the present embodiment adopts and is first dissolved completely in the deionized water of 6000 grams by 10 grams of modified acrylic polymers (the polyquart ampho149 of Kening Co., Ltd), 10 grams of alkyl glycoside with high polymerization degree (TRITON BG-10), 200 grams of dipropylene, finally adds 3780 grams of dehydrated alcohols and makes.
Embodiment 2
The glass antidimmer of the present embodiment adopts and is first dissolved completely in the deionized water of 6000 grams by 20 grams of modified acrylic polymers (the polyquart ampho149 of Kening Co., Ltd), 5 grams of alkyl glycoside with high polymerization degree (TRITON CG-110), 500 grams of dipropylene glycol ethyl ether, finally adds 3485 grams of dehydrated alcohols and makes.
Embodiment 3
The glass antidimmer of the present embodiment adopts and is first dissolved completely in the deionized water of 6000 grams by 50 grams of modified acrylic polymers (the polyquart ampho149 of Kening Co., Ltd), 20 grams of alkyl glycoside with high polymerization degree (TRITON BG-10), 1000 grams of dipropylene glycol propyl ether, finally adds 2930 grams of anhydrous methanols and makes.
Embodiment 4
The glass antidimmer of the present embodiment adopts and is first dissolved completely in the deionized water of 5000 grams by 30 grams of modified acrylic polymers (the polyquart ampho149 of Kening Co., Ltd), 50 grams of alkyl glycoside with high polymerization degree (TRITONCG-110), 400 grams of dipropylene, finally adds 4520 grams of anhydrous isopropyl alcohols and makes.
Test example 1
This test example adopts to carry out respectively by the glass antidimmer of embodiment 1-4 and comparative sample 1,2 that high temperature anti-fogging property can be tested, low temperature anti-fog performance is tested and long period anti-fog performance is tested.Comparative sample 1 is purchased from the glass antidimmer of Guangzhou Bao Chi-Li Chemical Co., Ltd; Comparative sample 2 is purchased from Shenzhen Kuai Meite company.
1.1 high temperature anti-fogging property can be tested:
This experiment is the method for a kind of research anti-fog performance of antifogging agent in high temperature (40 DEG C).At the one side coating antifogging agent of sheet glass, this face is made to contact water vapour 3min each time.Judge with " number of occurrence " before about having the glass sheet surface of 10% to amass to nebulize.Within initial 3min, (for the first time) just hazes, and the number of occurrence is as 0 time, and secondary occasion, the number of occurrence is as once, and the occasion of third time, the number of occurrence is as secondary.Concrete detected result is in table 1.
Table 1 antifogging agent of the present invention and comparative sample high temperature anti-fogging property can be tested
Conclusion: high temperature anti-fogging property can be tested has larger performance advantage compared with comparative sample 1,2.
1.2 low temperature anti-fog performance tests:
This experiment is the method for the anti-fog performance of (0 DEG C) antifogging agent under research low temperature.At sheet glass both sides coating antifogging agent, and keep 30min in the refrigerator of 0 DEG C, take out and put at ambient temperature, by sheet glass observation experiment card, according to its state, judge.Repeatedly be for three times and pass through.Concrete detected result is in table 2.
Table 2 antifogging agent of the present invention and comparative sample low temperature anti-fog performance are tested
1.3 long period anti-fog performance tests:
This experiment is the one side coating antifogging agent of method at sheet glass of the antifogging film stability of research antifogging agent, leave standstill in laboratory environment and carry out the antifog test of high temperature after 240 hours, at the one side coating antifogging agent of sheet glass in high temperature (40 DEG C), this face is made to contact water vapour 3min each time.Judge with " number of occurrence " before about having the glass sheet surface of 10% to amass to nebulize.Within initial 3min, (for the first time) just hazes, and the number of occurrence is as 0 time, and secondary occasion, the number of occurrence is as once, and the occasion of third time, the number of occurrence is as secondary.Repeatedly be for three times and pass through.Concrete detected result is in table 3.
Table 3 antifogging agent of the present invention and comparative sample long period anti-fog performance are tested
Conclusion: the test of long period anti-fog performance has larger performance advantage compared with comparative sample 1,2, illustrates that antifogging agent of the present invention has fabulous long period stability in use.
Although above the present invention is described in detail with a general description of the specific embodiments, on basis of the present invention, can make some modifications or improvements it, this will be apparent to those skilled in the art.Therefore, these modifications or improvements without departing from theon the basis of the spirit of the present invention, all belong to the scope of protection of present invention.
Claims (6)
1. a glass antidimmer, is characterized in that, it is made up of the raw material of following weight percent:
Described alkyl glycoside with high polymerization degree is TRITON BG-10 or TRITON CG-110;
Described low mass molecule alcohol is ethanol, methyl alcohol or Virahol.
2. glass antidimmer according to claim 1, is characterized in that, it is made up of the raw material of following weight percent:
3. glass antidimmer according to claim 1 and 2, is characterized in that, described modified acrylic polymer is water-soluble acrylic copolymer.
4. glass antidimmer according to claim 1 and 2, is characterized in that, described dipropylene glycol is dipropylene, dipropylene glycol propyl ether, dimethyl ether or dipropylene glycol ethyl ether.
5. glass antidimmer according to claim 1 and 2, is characterized in that, described hydromining deionized water.
6. prepare the method for the glass antidimmer described in claim 1-5 any one, it is characterized in that, its adopt first by proportioning by soluble in water to modified acrylic polymer, alkyl glycoside with high polymerization degree and dipropylene glycol, finally add low mass molecule alcohol, mix and form.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210368018.8A CN103694958B (en) | 2012-09-28 | 2012-09-28 | Glass antifogging agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210368018.8A CN103694958B (en) | 2012-09-28 | 2012-09-28 | Glass antifogging agent and preparation method thereof |
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| CN103694958A CN103694958A (en) | 2014-04-02 |
| CN103694958B true CN103694958B (en) | 2015-03-04 |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104877480A (en) * | 2015-06-23 | 2015-09-02 | 宣乐 | Antifogging agents for outdoor lamp box |
| CN104893387A (en) * | 2015-06-23 | 2015-09-09 | 宣乐 | Antifogging agent for outdoor advertising boards |
| CN110373154A (en) * | 2019-07-25 | 2019-10-25 | 广州佳伲斯防霉抗菌科技有限公司 | A kind of antifog spray and preparation method thereof |
| CN111574960A (en) * | 2020-05-12 | 2020-08-25 | 浙江优亿医疗器械有限公司 | Formula and preparation method of antifogging liquid |
| CN112760175A (en) * | 2020-12-31 | 2021-05-07 | 茂名张氏科技发展有限公司 | Antifogging wet tissue for glass and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1749348A (en) * | 2005-10-14 | 2006-03-22 | 浙江大学 | Glass fog-proof agent and its preparing method |
| CN101255381A (en) * | 2007-02-27 | 2008-09-03 | 3M创新有限公司 | Cleaning method and combination |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58217578A (en) * | 1982-06-10 | 1983-12-17 | Hoya Corp | Antifogging agent |
| JP2931938B2 (en) * | 1992-05-29 | 1999-08-09 | 花王株式会社 | Anti-fog agent |
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- 2012-09-28 CN CN201210368018.8A patent/CN103694958B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1749348A (en) * | 2005-10-14 | 2006-03-22 | 浙江大学 | Glass fog-proof agent and its preparing method |
| CN101255381A (en) * | 2007-02-27 | 2008-09-03 | 3M创新有限公司 | Cleaning method and combination |
Non-Patent Citations (1)
| Title |
|---|
| 肖进新,等.表面活性剂应用原理.《表面活性剂应用原理》.化学工业出版社,2003,第410-411页. * |
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