CN103232908B - Cleaning composition and wet tissue with same - Google Patents
Cleaning composition and wet tissue with same Download PDFInfo
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- CN103232908B CN103232908B CN201310149332.1A CN201310149332A CN103232908B CN 103232908 B CN103232908 B CN 103232908B CN 201310149332 A CN201310149332 A CN 201310149332A CN 103232908 B CN103232908 B CN 103232908B
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Abstract
The invention provides a cleaning composition, which contains nano-silver particles, a dispersant, a waterproof film-forming agent, a water-soluble organic solvent and a surfactant in the mass ratio of (0.005-0.1): (0.01-5): (0.01-10): (5-85): (0.5-5). The invention also provides a wet tissue with the cleaning composition. The nano-silver particles in the cleaning composition provided by the invention are not aggregated, so that the antiseptic and anti-microbial effects of the nano-silver particles can be effectively developed; and the nano-silver particles can stick to the surface of an object so as to realize long-acting antiseptic and anti-microbial effects on the surface of the object; and besides, the cleaning composition easily removes dirt and contaminations on the surface of the object, and also can be dried quickly to form a film. The wet tissue with the cleaning composition is convenient to carry, and can be used for cleaning the surfaces of a cell phone, a screen of a computer, a keyboard, a housing and the like.
Description
Technical field
The present invention relates to a kind of cleaning compositions and apply its wet tissue.
Background technology
At present, smart mobile phone, panel computer are widely used.But the screen surface, keyboard etc. of these electronic products inevitably can be stained with greasy dirt, dust in the process used, and grow a large amount of bacteriums, threaten the health of people.Therefore need often to clean the screen surface of these electronic products, main cleaning mode comprises: (1) carries out wiping with cleaning cloth; (2) clean with the cleaning agent such as liquid detergent, washing powder.(1) plant cleaning mode usually can only dusting out class compared with the dirt of easy-clear, inadequate to obstinate soil cleaning power such as oil stains, if firmly carry out wiping, then may scratch screen, affect the discrimination power of screen; And cleaning cloth just can clean after a number of uses, the bacterial micro-organism of its glued on top can constantly increase, and brings larger threat to the health of user.(2) can remove the intractable dirts such as oil stain though plant cleaning mode, but this kind of sanitising agent foaminess is stronger, not easily do, water mark is left through surface of being everlasting after clean, need again with article such as paper handkerchiefs by its wiped clean, at pollutents such as remained on surface paper ashes, the use properties of product may be affected so again.In addition, although containing sterilant in this kind of sanitising agent, can kill the bacterial micro-organism subtracting surface after the cleaning, the timeliness of its sterilization is shorter, cannot stop bacterial micro-organism and human contact for a long time, the health of protection people.
Summary of the invention
In view of this, be necessary to provide a kind of cleaning compositions effectively solved the problem.
In addition, there is a need to provide a kind of wet tissue applying above-mentioned cleaning compositions.
A kind of cleaning compositions, it contains nano-Ag particles, dispersion agent, water-repellancy membrane-forming agent, water miscible organic solvent, tensio-active agent, and wherein the mass ratio of nano-Ag particles, dispersion agent, water-repellancy membrane-forming agent, water miscible organic solvent, tensio-active agent is 0.005 ~ 0.1:0.01 ~ 5:0.01 ~ 10:5 ~ 85:0.5 ~ 5.
Apply a wet tissue for above-mentioned cleaning compositions, this wet tissue contains base material and is adsorbed in the cleaning compositions in base material.
The present invention is by the cleaning compositions of a kind of special component of configuration, nano-Ag particles in this cleaning compositions is not reunited, effectively can play its bactericidal effect, and nano-Ag particles can adhere to body surface thus to body surface to realize long-acting bactericidal antibacterial; In addition the various dirts, dirty of this cleaning compositions easy-clear body surface, and impel cleaning compositions energy rapid drying film forming due to the volatilization of organic solvent.Apply the wet tissue of this cleaning compositions, easy to carry, can be used for surperficial the cleaning such as screen, keyboard, shell of mobile phone, computer, this wet tissue cleaning effect is good, bacterial micro-organism and human contact can be stoped for a long time, avoid the propagation of bacterial micro-organism, help people away from the threat of bacterial micro-organism.
Embodiment
Cleaning compositions of the present invention contains nano-Ag particles, dispersion agent, water-repellancy membrane-forming agent, water miscible organic solvent, tensio-active agent, and wherein the mass ratio of nano-Ag particles, dispersion agent, water-repellancy membrane-forming agent, water miscible solvent, tensio-active agent is 0.005 ~ 0.1:0.01 ~ 5:0.01 ~ 10:5 ~ 85:0.5 ~ 5.
Also can containing appropriate water in this cleaning compositions.
Nano-Ag particles in this cleaning compositions has excellent sterilization antibacterial effect, various bacteria can be killed at several minutes, and to human body nonirritant, the existence of nanometer silver can kill bacterial micro-organism that is that mobile phone screen, cell phone keyboard, computor-keyboard etc. have adhered on the surface and in use new generation fast, stop bacterial micro-organism and human contact, avoid the propagation of bacterial micro-organism, help people away from the threat of bacterial micro-organism.The diameter of this nano-Ag particles is 5 ~ 100nm, is more preferably 5 ~ 25nm.
Because nano-Ag particles granularity is little, specific surface area is large, surface energy is high, it easily occurs in the solution to reunite and affects stability and the bactericidal property of cleaning compositions, therefore be added with the dispersion that dispersion agent makes nano-Ag particles uniform and stable in cleaning compositions in this cleaning compositions, wherein the mass ratio of nano-Ag particles and dispersion agent is 0.005 ~ 0.1:0.01 ~ 5.This dispersion agent is selected from least one in polyvinylpyrrolidone, cats product.Further cats product comprises Trimethyllaurylammonium bromide, cetyl trimethylammonium bromide etc.
Owing to having the shortcoming not easily adhered to when nano-Ag particles is present in body surface, namely wind, washing can depart from body surface, cause the loss of nano-Ag particles.Therefore, water-repellancy membrane-forming agent is added in this cleaning compositions, nano-Ag particles not only can be helped to be dispersed in body surface, also can increase the adhesivity of itself and object, reduce nano silver particles to run off because of the factor such as wind, washing in use procedure, improve the retention of nanometer silver at body surface, its bactericidal property of the performance making it more long-acting.
This water-repellancy membrane-forming agent is selected from least one in polyvinyl alcohol, acrylic acid or the like, polyurethanes membrane-forming agent.
Acrylic acid or the like membrane-forming agent comprises vinylformic acid (ester) class/octylacrylamido (DERMACRYL79 film-forming polymer), acrylate copolymer 5009(SYNTRAN5009), acrylate copolymer 5190(SYNTRAN5190), acrylate copolymer 5960(SYNTRAN5960), acrylate/ethylhexyl acrylate multipolymer 5000AD(DAITOSOL5000AD), acrylate/ethylhexyl acrylate multipolymer 5000SJ(DAITOSOL5000SJ), acrylate/ethylhexyl acrylate multipolymer 4000SJT(DAITOSOL4000SJT).
Polyurethanes membrane-forming agent specifically comprises PUA Series of Polyurethane modified environment-friendly membrane-forming agent, as PUA-1, PUA-2.
Further, this water-repellancy membrane-forming agent is preferably DERMACRYL79 film-forming polymer, DAITOSOL5000AD and composition thereof.
Water-miscible organic solvent in this cleaning compositions is except the effect with certain clean dirt, the more important thing is the volatility utilizing it good, can make to become dry in the body surface time shorter after wiping, and promote the drying of membrane-forming agent in cleaning compositions, make it at body surface fast filming.This solvent is selected from least one in alcohols, ketone, and wherein alcoholic solvent is selected from methyl alcohol, ethanol, propyl alcohol, Virahol and composition thereof.Ketone mainly comprises acetone, butanone and composition thereof.This solvent is preferably ethanol or Virahol, and these two kinds of solvents except having good volatility, and are more conducive to nano-Ag particles stably dispersing in the solution.
This tensio-active agent is selected from least one in nonionogenic tenside and amphoterics.Tensio-active agent in this cleaning compositions is mainly used in the intractable dirt such as dirt and grease compared with easy-clear such as dust and dirt, fingerprint etc. on clean mobile phone, the screen of computer, keyboard, shell.The nonionogenic tenside related in clean mixed solution mainly comprises at least one in alkyl glycoside, alcohol amide class.Amphoterics comprises at least one in betanin derivative, both sexes acetate, sulfo-succinic acid salt.
Alkyl glycoside is specially the alkyl glycoside of 8-16 carbon, as APG0810(carbon chain lengths 8-10), APG1214(carbon chain lengths 12-14), APG0814(carbon chain lengths 8-14), APG0816(carbon chain lengths 8-16), APG1216(carbon chain lengths 12-16) etc.Be more preferably the alkyl glycoside of 8-14 carbon, as GLUCOPON215CSUP, GLUCOPON225DK, GLUCOPON600CS UP, GLUCOPON650EC etc. of cognis company, further preferably GLUCOPON215CS UP, addition is 0.5% ~ 2%.
Alcohol amide class specifically comprises at least one in lauric monoethanolamide, lauric acid diethyl amide, cocounut oil acyl single ethanol amide, cocounut oil acyl diglycollic amide.
Betanin derivative has at least one comprised in AMONYL 380LC, octyl group/decylamidopropyl trimethyl-glycine, ricinoleic acid amide CAB, dodecyl oxyethyl group sultaine, dodecyl hydroxypropyl sultaine, dodecyl sulfobetaine, lauroyl CAB.
Both sexes Acetates specifically comprises at least one in cocounut oil both sexes sodium acetate, cocounut oil both sexes diacetic acid disodium, sweet almond oil both sexes sodium-acetate.
Sulfo-succinic acid salt specifically comprises at least one in polyoxyethylene glycol-5 lauryl citric acid disodium sulfosuccinate, lauryl alcohol disodium sulfosuccinate, ricinoleic acid amide monoethanolamine disodium sulfosuccinate, lauryl disodium sulfosuccinate.
When containing nonionogenic tenside and amphoterics in cleaning compositions simultaneously, the mass ratio between nonionogenic tenside and amphoterics is 1:0.1 ~ 1.
Further, also too much foam adheres can be produced in body surface, the smooth finish of ectocrine surface to suppress cleaning compositions containing defoamer in the process prepared and use in this cleaning compositions.This defoamer is selected from polyethers, lipid acid and derivative thereof, silicone based at least one.This defoamer is preferably silicone antifoam agent, silicone antifoam agent specifically includes the silicone antifoam agent product of dimethyl silicone oil, Y-14865(Zhong Yuan company), PEG-12 polydimethylsiloxane (XIAMETER OFX-0193FLUID, the product of Dow Corning Corporation).
Further also ancillary component can be comprised, as solubilizing agent, tinting material, pH adjusting agent, sequestrant, sanitas, sterilant, thickening material, spices, antioxidant in this cleaning compositions.
Apply a wet tissue for above-mentioned cleaning compositions, it comprises base material and is adsorbed in the cleaning compositions in base material, and in this wet tissue, the mass ratio of base material and cleaning compositions is 1:1 ~ 3.This base material is selected from the material that non-woven fabrics, cotton, gauze, wet-strength paper etc. have water suction, water retention capacity.
The present invention is by the cleaning compositions of a kind of special component of configuration, nano-Ag particles in this cleaning compositions is not reunited, effectively can play its bactericidal effect, and nano-Ag particles can adhere to body surface thus to body surface to realize long-acting bactericidal antibacterial; In addition, the various dirts of this cleaning compositions easy-clear body surface, dirty, and can rapid drying film forming.Apply the wet tissue of this cleaning compositions, easy to carry, can be used for surperficial the cleaning such as screen, keyboard, shell of mobile phone, computer, this wet tissue cleaning effect is good, bacterial micro-organism and human contact can be stoped for a long time, avoid the propagation of bacterial micro-organism, help people away from the threat of bacterial micro-organism.
Below by embodiment, the present invention is specifically described.
Embodiment 1
By the raw material shown in table one and proportional arrangement cleaning compositions, be specially: polyvinylpyrrolidone, nanometer silver, water are added in container, after stirring for some time, then in supersonic cleaning machine, carried out to powder ultrasonic disperse for some time, until form uniform and stable nano silver dispersion.Then DERMACRYL79 film-forming polymer is added in ethanol and dissolve completely, neutralize with trolamine, under agitation add in nano silver dispersion, add GLUCOPON215CS UP more successively, after Cocoalkyl amido propyl betaine, Y-14865, spices, sanitas, sequestrant, pH adjusting agent be uniformly mixed, i.e. obtained required clean mixed solution.
Wet tissue makes: be that 1.5:1 adds on base material by above-mentioned clean mixed solution according to the mass ratio of clean mixed solution and base material, then cuts into required size and can obtain required wet tissue.
Table one
Embodiment 2
By the raw material shown in table two and proportional arrangement cleaning compositions, be specially: Trimethyllaurylammonium bromide, nanometer silver, water are added in container, after stirring for some time, in supersonic cleaning machine, carried out to powder ultrasonic disperse for some time again, until form uniform and stable nano silver dispersion.Then polyvinyl alcohol is added in nano silver dispersion, and be stirred to it and dissolve completely, add cocounut oil acyl diglycollic amide more successively, after cocounut oil both sexes diacetic acid disodium, Virahol, Y-14865, antioxidant, spices, sanitas, sequestrant, pH adjusting agent be uniformly mixed, i.e. obtained required clean mixed solution.
Wet tissue makes: be that 2:1 adds on base material by above-mentioned clean mixed solution according to the mass ratio of clean mixed solution and base material, then cuts into required size and can obtain required wet tissue.
Table two
Result of use is tested: use the wet tissue wiping electronic product screen in embodiment 1 and embodiment 2, can both rapidly by screen surface wiped clean, and screen surface there will not be wearing and tearing or " flower screen " phenomenon.Bactericidal test is carried out to the screen after wiping simultaneously, after placing for some time, after such as 2 months, Bactericidal test is done again with the fritter resin of this screen, find that the screen after wiping still has good fungistatic effect, illustrate that the screen wiped across through wet tissue of the present invention has good fungistatic effect.
In addition, those skilled in the art also can make various amendments in other form and details, interpolation and replacement in the claims in the present invention scope of disclosure and spirit.Certainly, the changes such as these various amendments made according to the present invention's spirit, interpolation and replacement, all should be included within the present invention's scope required for protection.
Claims (12)
1. one kind is applied to the cleaning compositions of wet tissue, it is characterized in that: this cleaning compositions contains nano-Ag particles, dispersion agent, water-repellancy membrane-forming agent, water miscible organic solvent, tensio-active agent, wherein the mass ratio of nano-Ag particles, dispersion agent, water-repellancy membrane-forming agent, water miscible solvent, tensio-active agent is 0.005 ~ 0.1:0.01 ~ 5:0.01 ~ 10:5 ~ 40:0.5 ~ 5; Wherein, described dispersion agent is polyvinylpyrrolidone.
2. cleaning compositions as claimed in claim 1, is characterized in that: the diameter of this nano-Ag particles is 5 ~ 100nm.
3. cleaning compositions as claimed in claim 2, is characterized in that: the diameter of this nano-Ag particles is 5 ~ 25nm.
4. cleaning compositions as claimed in claim 1, is characterized in that: this water-repellancy membrane-forming agent is selected from least one in polyvinyl alcohol, acrylic acid or the like, polyurethanes membrane-forming agent; Acrylic acid or the like membrane-forming agent comprises vinylformic acid (ester) class/octylacrylamido, acrylate copolymer 5009, acrylate copolymer 5190, acrylate copolymer 5960, acrylate/ethylhexyl acrylate multipolymer 5000AD, acrylate/ethylhexyl acrylate multipolymer 5000SJ, acrylate/ethylhexyl acrylate multipolymer 4000SJT; Polyurethanes membrane-forming agent comprises PUA Series of Polyurethane modified environment-friendly membrane-forming agent.
5. cleaning compositions as claimed in claim 1, is characterized in that: this water miscible organic solvent is selected from least one in alcohols, ketone, and wherein alcoholic solvent is selected from least one in methyl alcohol, ethanol, propyl alcohol, Virahol; Ketones solvent is selected from least one in acetone, butanone.
6. cleaning compositions as claimed in claim 1, is characterized in that: this tensio-active agent is selected from least one in nonionogenic tenside and amphoterics.
7. cleaning compositions as claimed in claim 6, is characterized in that: when containing nonionogenic tenside and amphoterics in cleaning compositions simultaneously, the mass ratio between nonionogenic tenside and amphoterics is 1:0.1 ~ 1.
8. cleaning compositions as claimed in claim 1, is characterized in that: also containing defoamer in this cleaning compositions, this defoamer is selected from polyethers, lipid acid and derivative thereof, silicone based at least one.
9. cleaning compositions as claimed in claim 8, it is characterized in that: also containing water and ancillary component in this cleaning compositions, this ancillary component is selected from least one in solubilizing agent, tinting material, pH adjusting agent, sequestrant, sanitas, sterilant, thickening material, spices, antioxidant.
10. application rights requires a wet tissue for cleaning compositions described in any one in 1-9, and this wet tissue contains base material and is adsorbed in the cleaning compositions in base material.
11. wet tissues as claimed in claim 10, is characterized in that: in this wet tissue, the mass ratio of base material and cleaning compositions is 1:1 ~ 3.
12. wet tissues as claimed in claim 10, is characterized in that: this base material is non-woven fabrics, cotton, gauze or wet-strength paper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310149332.1A CN103232908B (en) | 2013-04-25 | 2013-04-25 | Cleaning composition and wet tissue with same |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310149332.1A CN103232908B (en) | 2013-04-25 | 2013-04-25 | Cleaning composition and wet tissue with same |
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| CN103232908B true CN103232908B (en) | 2015-04-01 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111979053A (en) * | 2020-08-05 | 2020-11-24 | 名臣健康用品股份有限公司 | Household cleaning wet tissue composition without water mark during wiping and preparation method thereof |
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| TW201544128A (en) * | 2014-05-30 | 2015-12-01 | Cloudtain Internat Biotech Co Ltd | Film-forming composition and kit containing the same |
| CN105199880A (en) * | 2014-11-13 | 2015-12-30 | 深圳市合明科技有限公司 | Cleaning agent, and preparation method and application thereof |
| CN105286705B (en) * | 2015-10-27 | 2018-04-10 | 诸暨双林电脑防护用品有限公司 | The seamless moisture paper tissue papers of electronic curtain wood-fibred |
| CN105476530A (en) * | 2015-11-03 | 2016-04-13 | 河北氏氏美卫生用品有限责任公司 | Degreasing wet tissue for kitchens |
| CN106753847A (en) * | 2016-11-17 | 2017-05-31 | 维尼健康（深圳）股份有限公司 | A kind of wiping optical lenses wet tissue |
| CN106753822A (en) * | 2016-12-15 | 2017-05-31 | 成都锦汇科技有限公司 | Multi-Function Keyboard cleaning fluid |
| CN106590987A (en) * | 2016-12-28 | 2017-04-26 | 于文 | Household screen cleanser and preparation method thereof |
| CN107189878A (en) * | 2017-07-09 | 2017-09-22 | 马爱连 | A kind of computer and accessory rapid cleaning agent and preparation method thereof and application method |
| CN107338132A (en) * | 2017-07-14 | 2017-11-10 | 马爱连 | A kind of keyboard cleaning method and the cleaning suit used |
| CN109810809A (en) * | 2019-03-04 | 2019-05-28 | 广东欧蝶兰高新科技日用品有限公司 | A kind of screen antibacterial cleansing composition |
| CN110527602A (en) * | 2019-08-30 | 2019-12-03 | 合肥学院 | A kind of portable computer impregnated wipe |
| CN110951551A (en) * | 2019-11-22 | 2020-04-03 | 常福林 | Preparation method of environment-friendly cleaning agent |
| CN112545923A (en) * | 2020-12-31 | 2021-03-26 | 杭州柘大飞秒检测技术有限公司 | Stock solution of pet wet tissue and preparation method thereof |
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| US20040261196A1 (en) * | 2003-06-27 | 2004-12-30 | The Procter & Gamble Company | Fabric care compositions for lipophilic fluid systems incorporating an antimicrobial agent |
| CN101956027B (en) * | 2010-10-13 | 2013-06-05 | 四川大学 | Sheep fur with nanometer antibacterial function and preparation method thereof |
| CN102041207A (en) * | 2010-12-08 | 2011-05-04 | 芜湖耀华玻璃园艺有限公司 | Glass detergent |
| CN102600496B (en) * | 2012-01-30 | 2014-06-04 | 施耐克江苏生物制药有限公司 | I, II and III medical equipment products acting on skin, mucosa and wound for inactivating virus |
| CN102860927B (en) * | 2012-10-12 | 2014-01-15 | 金红叶纸业集团有限公司 | Emulsion composition and wet tissue utilizing same |
| CN102965223B (en) * | 2012-11-26 | 2014-01-08 | 吴金龙 | Nano-multifunctional washing sheet |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111979053A (en) * | 2020-08-05 | 2020-11-24 | 名臣健康用品股份有限公司 | Household cleaning wet tissue composition without water mark during wiping and preparation method thereof |
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