CN111979053A

CN111979053A - Household cleaning wet tissue composition without water mark during wiping and preparation method thereof

Info

Publication number: CN111979053A
Application number: CN202010777342.XA
Authority: CN
Inventors: 陈妍; 林艺青; 郑遒天; 袁小娇
Original assignee: Mingchen Health Co ltd
Current assignee: Mingchen Health Co ltd
Priority date: 2020-08-05
Filing date: 2020-08-05
Publication date: 2020-11-24

Abstract

The invention discloses a household cleaning wet tissue composition with no water mark during wiping and a preparation method thereof. The wet tissue agent composition comprises the following components in percentage by weight: 0.05 to 1 percent of chelating agent; 0.1 to 5 percent of nonionic surfactant; 0.1-3% of a solvent; 0.1-1% of brightener; 0.10-5% of a humectant; 0.2 to 1 percent of bactericide; 0.2 to 1 percent of preservative; 0.1-1% of essence; the balance being water. The household cleaning wet tissue agent provided by the invention can wipe the surface of a household without water marks, effectively shortens the drying time, improves the anti-fouling capability, and has the effects of degerming and strong detergency.

Description

Household cleaning wet tissue composition without water mark during wiping and preparation method thereof

Technical Field

The invention relates to a household cleaning wet tissue agent composition, belongs to the technical field of daily chemical washing products, and particularly relates to a household cleaning wet tissue agent composition without water mark during wiping and a preparation method thereof.

Background

With the improvement of the living standard of people, the wet tissue is continuously developed. Particularly, in recent two years, the production and market development of wet tissues are very rapid, the purposes are diversified, the wet tissues are not limited to a single variety for cleaning skin (wiping hands and faces), and household cleaning wet tissues gradually become a new favorite in the market. In particular, the new crown epidemic that has been eminent in 2020 has spread worldwide, making people aware that good hygiene practices are critical for prevention. People pay more and more attention to environmental sanitation, and the household cleaning and sterilizing wet tissue is rapidly increased.

The disadvantage of the traditional household cleaning wet tissue is as follows:

1) water marks remain after the cleaning;

2) the cleaning power is poor, only light oil stains on the surface can be cleaned, heavy oil stains can be cleaned, and repeated hard scrubbing is needed;

3) the degerming rate is low, and better sanitary protection cannot be achieved.

Therefore, it is important to develop a wet cleaning towel with no water mark after scrubbing, reduced cleaning times and quick drying effect.

Disclosure of Invention

The invention aims to provide a household cleaning wet tissue composition with wiping no water mark, which can wipe the household surface without leaving water mark, effectively shorten the drying time, improve the anti-fouling capability and simultaneously have the effects of degerming and strong detergency.

The invention also aims to provide a preparation method of the household cleaning wet tissue composition with no water mark for wiping.

The present invention is realized by the following technical means.

A household cleaning wet tissue composition with no water mark for wiping comprises the following raw material components in percentage by weight:

0.05-1% of chelating agent, 0.1-5% of surfactant, 0.1-3% of solvent, 0.1-1% of high molecular polymer film-forming brightener, 0.2-1% of bactericide, 0.2-1% of preservative, 0.10-5% of humectant and 0.1-1% of essence.

Further, in order to better realize the invention, the household cleaning wet tissue composition with no water mark for wiping consists of the following raw material components in percentage by weight:

0.1 to 0.5 percent of chelating agent;

1% -2% of nonionic surfactant;

2-3% of a solvent;

0.5-1% of high molecular polymer film-forming brightener;

0.1-1% of a humectant;

0.3 to 0.6 percent of bactericide;

0.2 to 0.5 percent of preservative;

0.1-0.5% of essence;

the balance being water.

Further, to better implement the present invention, the surfactant is a nonionic surfactant; the nonionic surfactant is one or more of fatty alcohol alkyl oxide, fatty alcohol-polyoxyethylene ether and alkyl glucoside.

Further, in order to further realize the present invention, the chelating agent is any one of tetrasodium glutamate diacetate, sodium ethylenediaminetetraacetate, or condensed phosphoric acid such as pyrophosphoric acid.

Further, in order to better realize the invention, the solvent is one or more of ethers or polyhydric alcohols.

Further, in order to better realize the invention, the high molecular polymer film-forming brightener is one or more of film-forming agents such as Kelain aristocrate Samrt, Yingchuang WE50 and the like.

Further, in order to better realize the invention, the humectant is one or more of vitamin E, lanolin and panthenol.

Further, in order to better implement the invention, the bactericide is quaternary ammonium salts, including but not limited to one or more of dodecyl dimethyl benzyl ammonium chloride, octadecyl dimethyl benzyl ammonium chloride and didecyl dimethyl ammonium chloride;

the preservative is one or more of polyalcohol, phenoxyethanol, pentanediol or ethyl hexyl glycerol.

In addition, the invention also discloses a preparation method of the household cleaning wet tissue composition with no water mark during wiping, which comprises the following steps:

1) adding 80-90 wt% of water into a stirring cylinder at room temperature, starting stirring, adding 0.05-1 wt% of chelating agent into the mixing and stirring cylinder, and uniformly stirring until the chelating agent is completely dissolved;

2) slowly adding alkyl glycoside with the weight ratio of 0.1-5% into the step 1), and uniformly stirring until the alkyl glycoside is completely dissolved;

3) slowly adding the environment-friendly solvent with the weight ratio of 0.1-3% into the step 2), and uniformly stirring until the solvent is completely dissolved;

4) slowly adding the high molecular polymer film-forming brightener with the weight ratio of 0.1-1% into the step 3), and uniformly stirring until the film-forming brightener is completely dissolved; slowly adding a humectant in an amount of 0.1-5 wt%, and uniformly stirring until the humectant is completely dissolved; slowly adding bactericide with the weight ratio of 0.2-1%, and uniformly stirring until the bactericide is completely dissolved; then adding 0.2-1% of preservative, and stirring uniformly until the preservative is completely dissolved; adding 0.1-1% of essence, and uniformly stirring until the essence is completely dissolved; standing for 2 hr, and packaging.

Compared with the prior art, the invention has the following advantages and beneficial effects:

1) no water mark after scrubbing: because of the hydrophilic structure formed on the surface of the object, no water mark is formed after the product is wiped, and the scale accumulation can be reduced by washing the surface with water for a long time.

2) The cleaning times are reduced: because the hydrophilic polymer is added, a water film is formed on the hard surface, so that dirt, product residues or water drops can be prevented from being adhered to the hard surface to cause secondary pollution to the hard surface.

3) Has the efficacy of quick drying: the cleaning wet tissue agent has the functions of cleaning, sterilizing and protecting; the range of cleaning objects is wide, the dirt removing capability is good, heavier oil stains can be cleaned, and the daily cleaning requirement of consumers is met. The cleaning objects comprise kitchen appliances, table tops, glass, toilets, toilet tiles and the like.

4) The skin lotion is added, so that the skin is not damaged: compared to other detergents that clean such surfaces, such as: kitchen oil stain remover; the multifunctional wet paper does not irritate the skin in the wiping process, and has the effect of protecting hands; no secondary rinse is required. The solvent is added as the defoaming agent, so that little foam is generated during wiping, and no rinsing water is needed.

5) The household cleaning agent can effectively remove stains on the surface of a household, and has no water mark and residue after wiping; because a hydrophilic water film is formed on the surface of the object, dust adsorption can be reduced, the cleaning times of consumers are reduced, and the drying time is shortened; has the sterilization effect, and the killing rate of common escherichia coli and staphylococcus aureus reaches 99.9 percent.

Detailed Description

The present invention will be described in further detail below with reference to specific preferred embodiments and effect test examples, but the embodiments of the present invention are not limited thereto.

The invention discloses a household cleaning wet tissue composition with no water mark during wiping and a preparation method thereof. The wet tissue agent composition comprises the following components in percentage by weight:

0.05% to 1% of a chelating agent (preferably in the range of 0.1% to 0.5%); 0.1-5% of a nonionic surfactant (preferably in the range of 1-2%); 0.1-3% of solvent (preferably in the range of 2% -3%); 0.1-1% of high molecular polymer film forming brightener (the preferable range is 0.5% -1%); 0.1-5% of humectant (preferably 0.1-1%); 0.2 to 1 percent of bactericide (the preferred range is 0.3 to 0.6 percent); 0.2 to 1 percent of preservative (the preferred range is 0.2 to 0.5 percent); 0.1-1% of essence (the preferable range is 0.1% -0.5%); the balance being water.

Based on the research of the traditional cleaning wet tissue (hand wiping and face wiping), the invention improves the detergency and increases the sterilization function. The solid content is higher than that of the common wet tissue because the wet tissue has the functions of strong decontamination and degerming. High solid content, which is apt to leave water marks on the surface of the object. The present invention prevents the development of water marks when wiping hard surfaces by adding a brightener. The brightener is a hydrophilic polymer, can form a hydrophilic water film on the surface of an object, can prevent water marks when a hard surface is wiped, and can improve the anti-fouling capability and effectively shorten the drying time.

The household cleaning wet tissue composition provided by the invention can wipe the household surface without leaving water marks, effectively shortens the drying time, improves the anti-fouling capability, and has the effects of sterilization and strong detergency.

The formulation components of the household cleaning wet towel composition with no water mark for wiping of the invention are shown in the following table 1 and the contents of examples 1-4.

Examples 1 to 4

A household cleaning wet tissue composition without water mark for wiping comprises the following formula components as shown in the following table 1:

table 1 household cleaning wet towel composition formulation with no water mark for wiping (% by weight)

Components	Categories	Example 1	Example 2	Example 3	Example 4
						Water (W)	Water (W)	Balance of	Balance of	Balance of	Balance of
Glutamic acid diacetic acid tetrasodium salt	Chelating agents	0.05％	0.2％	1.0％	0.2％
						Alkyl glycosides 1214	Nonionic surfactant	1％	0.5％	5.0％	3.5％
Diethylene glycol butyl ether	Environment-friendly odorless solvent	2％	3％	2％	2％
						Smart	Brightening agent	0.2％	0.1％	1％	1.2％
Panthenol	Moisture-retaining agent	0.2％	0.5％	1％	1.2％
						Dodecyl dimethyl ammonium chloride	Bactericide	0.2％	0.3％	1.0％	0.3％
Chlorobenzene alcohol	Preservative	0.3％	0.2％	0.3％	1.0％
						Essence	Other Components	1.0％	0.2％	0.1％	0.2％

The method for preparing the household cleaning wet tissue composition with no water mark for wiping of the above examples 1-4 comprises the following steps:

1) adding 80-90 wt% of water into a stirring cylinder at room temperature, starting stirring, adding a chelating agent into the mixing stirring cylinder, and uniformly stirring until the chelating agent is completely dissolved;

2) slowly adding alkyl glycoside into the step 1), and uniformly stirring until the alkyl glycoside is completely dissolved;

3) slowly adding the environment-friendly solvent into the step 2), and uniformly stirring until the environment-friendly solvent is completely dissolved;

4) slowly adding the high molecular polymer film-forming brightener into the step 3), and uniformly stirring until the film-forming brightener is completely dissolved; slowly adding the humectant, and uniformly stirring until the humectant is completely dissolved;

5) slowly adding the bactericide, and uniformly stirring until the bactericide is completely dissolved; adding the preservative, and stirring uniformly until the preservative is completely dissolved; adding essence, and stirring to dissolve completely; standing for 2 hr, and packaging.

Comparative examples 1 to 4

A household cleaning wet tissue agent composition comprises the following formula components shown in the following table 2:

TABLE 2 household cleaning wet towel composition formula (wt%)

Components	Categories	Comparative example 1	Comparative example 2	Comparative example 3	Comparative example 4
						Water (W)	Water (W)	Balance of	Balance of	Balance of	Balance of
Glutamic acidTetrasodium diacetate	Chelating agents	0.2％	0.2％	0.2％	0.2％
						Alkyl glycosides 1214	Nonionic surfactant	0.5％	0.5％	0.5％	0.5％
Diethylene glycol butyl ether	Environment-friendly odorless solvent	2％	0.1％	/	2％
						Smart	Brightening agent	/	0.2％	1％	1％
Panthenol	Moisture-retaining agent	0.2％	0.2％	0.2％	0.2％
						Dodecyl dimethyl ammonium chloride	Bactericide	0.3％	0.2％	0.3％	/
Chlorobenzene alcohol	Preservative	0.3％	0.3％	0.3％	0.3％
						Essence	Other Components	0.2％	1.0％	0.2％	0.2％

The process for preparing the household cleaning wet towel composition of comparative examples 1-4 was the same as that of examples 1-4 above.

The following are contents of the effect test examples.

Effect test example 1 (efficacy test)

The functional test effect of the household cleaning wet tissue agent with no water mark for wiping is shown in the following table 3:

table 3 efficacy testing of the household cleaning wet wipes of examples 1-4 and comparative example 1

Sample name	Evaluation of surface Brightness of glass	Evaluation of quick drying on glass surface
			Example 1	No water mark	About 40 seconds
Example 2	No water mark	About 15 seconds
			Example 3	No water mark	About 10 seconds
Example 4	No water mark	About 10 seconds
			Comparative example 1	Has water mark	About 1 minute

The results in Table 3 show that: tests on the brightness and the drying time of the glass surface show that when the addition amount of the brightener Smart is 0.2-1%, the brightener has the effects of wiping the surface without water marks and shortening the drying time; when the addition amount is 1%, the effect is more excellent.

Effect test example 2 (detergency test)

The household cleaning wet tissue agent with wiping no water mark of examples 1-4 and comparative examples 2 and 3 has the following detergency test effect:

pretreatment: firstly, wiping clean glass sheets with absolute ethyl alcohol;

oiling: coating 0.2 g of engine oil on the glass sheet;

soaking: adding 50 ml of solution into a 50 ml beaker, soaking the glass sheet coated with the oil stain in the solution for 10 minutes, and observing the oil stain stripping process;

swinging and washing: then the glass sheet is put in a beaker and washed for 10 times;

and (4) observation: taking out and observing the oil stain separation state on the glass sheet;

evaluation: the detergency of the detergent was evaluated by the amount of oil stain peeled off from the glass sheet, as shown in table 4 below:

table 4 comparison of detergency of household cleaning wet towel agents of examples 1 to 4 and comparative examples 2 and 3

Sample name	Residual amount of oil stain on glass sheet
		Example 1	Removing most of oil stains
Example 2	Removing most of oil stains
		Example 3	Removing most of oil stains
Example 4	Removing most of oil stains
		Example 5	Removing most of oil stains
Comparative example 2	Removing small part of oil stain
		Comparative example 3	Removing small part of oil stain

From the results of table 4 above, it can be seen that: comparative examples 2 and 3 were inferior in detergency to examples 1 to 4 in evaluation of the degree of removal of stains from the glass sheets. In addition, the nonionic surfactant alkyl glycoside 1214 and solvent diethylene glycol butyl ether have a synergistic detersive effect, and detergency will decrease when the amount of diethylene glycol butyl ether used is reduced.

Effect test example 3 (foam test)

The foam test results of the household cleaning wet towel agent with wiping dry marks of examples 1-4 and comparative example 3 are shown in the following table 5: the amount of foam during the wiping process was evaluated by wiping a foraminous household surface.

TABLE 5 foam test of household cleaning wet wipes with wiping dry stains from examples 1-4 and comparative example 3

The results in Table 5 show that: by scrubbing the foraminous household surface, comparative example 3 had more lather than examples 1-4 and required a second rinse.

Effect test example 4 (Sterilization Effect test)

The degerming effect of the household cleaning wet tissue agent with wiping anhydrous mark of examples 1-4 and comparative example 4 is shown in the following table 6.

According to the 'disinfection technical specification' 2002 edition, the disinfection effect of the household cleaning wet tissue agent with wiping water mark-free function is shown in the following table 6:

TABLE 6 degerming Effect of examples 1-4 and comparative example 4 for household cleaning wet towel agent with wiping waterless mark

Sample name	Killing rate of colibacillus	Kill rate of staphylococcus aureus
			Example 1	＞99.99％	＞99.99％
Example 2	＞99.99％	＞99.99％
			Example 3	＞99.99％	＞99.99％
Example 4	＞99.99％	＞99.99％
			Comparative example 4	＜40％	＜40％

The results in Table 6 show that: the sterilization performance evaluation shows that the sterilization rate of the comparative example 4 to the large intestine and the gold is lower than that of the examples 1 to 4.

Effect test example 5 (Corrosion test)

The wet wipe formulations for household cleaning with scrub no water mark of examples 1-4 were tested for corrosion as shown in table 7 below.

According to the evaluation method of the national standard GB/27728, the corrosive force test effect of the wiping non-water mark household cleaning wet tissue agent is as follows 7:

table 7 examples 1-4 wet wipe formulation corrosion test with dry scratch free household cleaning

The results in Table 7 show that: examples 1 to 4 have no corrosive force on both metals and ceramics by the corrosive force test.

In conclusion, when the brightener Smart is added in an amount of 0.2-1.2%, the polishing agent has the effects of no water mark on the surface and shortening the drying time. When the addition amount is 1%, the effect is best and the cost is lowest.

The above description is only a preferred embodiment of the present invention, and is not intended to limit the present invention in any way, so that any simple modification, equivalent change and modification made to the above embodiment according to the technical spirit of the present invention are within the scope of the technical solution of the present invention.

Claims

1. The household cleaning wet tissue composition with no water mark for wiping is characterized by comprising the following raw material components in percentage by weight:

0.05 to 1 percent of chelating agent;

0.1 to 5 percent of nonionic surfactant;

0.1-3% of a solvent;

0.1-1% of high molecular polymer film-forming brightener;

0.1-5% of a humectant;

0.2 to 1 percent of bactericide;

0.2 to 1 percent of preservative;

0.1-1% of essence;

the balance being water.

2. The household cleaning wet tissue composition with wiping non-water mark as claimed in claim 1, which is characterized by comprising the following raw material components in percentage by weight:

0.1 to 0.5 percent of chelating agent;

1% -2% of nonionic surfactant;

2-3% of a solvent;

0.5-1% of high molecular polymer film-forming brightener;

0.1-1% of a humectant;

0.3 to 0.6 percent of bactericide;

0.2 to 0.5 percent of preservative;

0.1-0.5% of essence;

the balance being water.

3. The household cleaning wet towel composition with no water mark for wiping according to claim 1 or 2, which is characterized in that:

the chelating agent is any one of condensed phosphoric acids such as glutamic acid diacetic acid tetrasodium, sodium ethylene diamine tetracetate or pyrophosphoric acid and the like;

the nonionic surfactant is one or more of fatty alcohol alkyl oxide, fatty alcohol-polyoxyethylene ether and alkyl glycoside;

the solvent is one or more of ethers or polyhydric alcohols.

4. The household cleaning wet towel composition with no water mark for wiping according to claim 1 or 2, which is characterized in that: the high molecular polymer film-forming brightener is one or more of Kelain Aristocare Samrt and Yingchuang WE50 film-forming agents.

5. The household cleaning wet towel composition with no water mark for wiping according to claim 1 or 2, which is characterized in that: the humectant is one or more of vitamin E, lanolin and panthenol.

6. The household cleaning wet towel composition with no water mark for wiping according to claim 1 or 2, which is characterized in that:

the bactericide is quaternary ammonium salt, including but not limited to one or more of dodecyl dimethyl benzyl ammonium chloride, octadecyl dimethyl benzyl ammonium chloride and didecyl dimethyl ammonium chloride;

7. The method for preparing the household cleaning wet tissue composition without water mark for wiping as claimed in any one of the claims 1 or 2, is characterized by comprising the following steps:

3) slowly adding an environment-friendly solvent with the weight ratio of 0.1-3% into the step 2), and uniformly stirring until the solvent is completely dissolved;