CN115820347B - Cleaning composition, preparation method thereof and cleaning agent - Google Patents
Cleaning composition, preparation method thereof and cleaning agent Download PDFInfo
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- CN115820347B CN115820347B CN202211637873.4A CN202211637873A CN115820347B CN 115820347 B CN115820347 B CN 115820347B CN 202211637873 A CN202211637873 A CN 202211637873A CN 115820347 B CN115820347 B CN 115820347B
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- 238000004140 cleaning Methods 0.000 title claims abstract description 88
- 239000000203 mixture Substances 0.000 title claims abstract description 78
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000012459 cleaning agent Substances 0.000 title description 6
- 150000001875 compounds Chemical class 0.000 claims abstract description 19
- 239000002904 solvent Substances 0.000 claims abstract description 17
- 229920002545 silicone oil Polymers 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 14
- 150000004676 glycans Chemical class 0.000 claims abstract description 14
- 229920000570 polyether Polymers 0.000 claims abstract description 14
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 14
- 239000005017 polysaccharide Substances 0.000 claims abstract description 14
- 239000000230 xanthan gum Substances 0.000 claims abstract description 14
- 229920001285 xanthan gum Polymers 0.000 claims abstract description 14
- 229940082509 xanthan gum Drugs 0.000 claims abstract description 14
- 235000010493 xanthan gum Nutrition 0.000 claims abstract description 14
- 239000002738 chelating agent Substances 0.000 claims abstract description 12
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 11
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- 239000003755 preservative agent Substances 0.000 claims description 7
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 claims description 6
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 6
- 239000003906 humectant Substances 0.000 claims description 5
- 230000002335 preservative effect Effects 0.000 claims description 5
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- -1 alkyl glycoside Chemical class 0.000 claims description 4
- 230000000844 anti-bacterial effect Effects 0.000 claims description 4
- 239000003899 bactericide agent Substances 0.000 claims description 4
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 3
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims description 3
- SNPLKNRPJHDVJA-ZETCQYMHSA-N D-panthenol Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCCO SNPLKNRPJHDVJA-ZETCQYMHSA-N 0.000 claims description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 3
- 239000004166 Lanolin Substances 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 3
- 229930003427 Vitamin E Natural products 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 claims description 3
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 claims description 3
- 239000000174 gluconic acid Substances 0.000 claims description 3
- 235000012208 gluconic acid Nutrition 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- 229930182470 glycoside Natural products 0.000 claims description 3
- 229940039717 lanolin Drugs 0.000 claims description 3
- 235000019388 lanolin Nutrition 0.000 claims description 3
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 claims description 3
- 229940101267 panthenol Drugs 0.000 claims description 3
- 235000020957 pantothenol Nutrition 0.000 claims description 3
- 239000011619 pantothenol Substances 0.000 claims description 3
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 claims description 3
- 229960005323 phenoxyethanol Drugs 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 239000011736 potassium bicarbonate Substances 0.000 claims description 3
- 229910000028 potassium bicarbonate Inorganic materials 0.000 claims description 3
- 235000015497 potassium bicarbonate Nutrition 0.000 claims description 3
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 3
- 235000011181 potassium carbonates Nutrition 0.000 claims description 3
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims description 3
- 235000011118 potassium hydroxide Nutrition 0.000 claims description 3
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 3
- 229940005657 pyrophosphoric acid Drugs 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- 235000017550 sodium carbonate Nutrition 0.000 claims description 3
- 229940046009 vitamin E Drugs 0.000 claims description 3
- 235000019165 vitamin E Nutrition 0.000 claims description 3
- 239000011709 vitamin E Substances 0.000 claims description 3
- 230000002070 germicidal effect Effects 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 150000003077 polyols Chemical class 0.000 claims description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 2
- 239000002304 perfume Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 9
- 238000005201 scrubbing Methods 0.000 abstract description 9
- 230000002195 synergetic effect Effects 0.000 abstract description 4
- 230000001681 protective effect Effects 0.000 abstract description 3
- 229920002521 macromolecule Polymers 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 7
- 239000011521 glass Substances 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 230000007794 irritation Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 4
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 150000007514 bases Chemical class 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 238000007665 sagging Methods 0.000 description 3
- LCTONWCANYUPML-UHFFFAOYSA-N Pyruvic acid Chemical compound CC(=O)C(O)=O LCTONWCANYUPML-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 150000001720 carbohydrates Chemical group 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 229920001477 hydrophilic polymer Polymers 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 238000004904 shortening Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- ANZUDYZHSVGBRF-UHFFFAOYSA-N 3-ethylnonane-1,2,3-triol Chemical compound CCCCCCC(O)(CC)C(O)CO ANZUDYZHSVGBRF-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- IAJILQKETJEXLJ-UHFFFAOYSA-N Galacturonsaeure Natural products O=CC(O)C(O)C(O)C(O)C(O)=O IAJILQKETJEXLJ-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 240000007263 Pinus koraiensis Species 0.000 description 1
- 235000011615 Pinus koraiensis Nutrition 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- AEMOLEFTQBMNLQ-WAXACMCWSA-N alpha-D-glucuronic acid Chemical compound O[C@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-WAXACMCWSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 description 1
- 229910000020 calcium bicarbonate Inorganic materials 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000002431 foraging effect Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 229940107700 pyruvic acid Drugs 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The application provides a cleaning composition, which comprises the following preparation raw materials in percentage by weight: 3 to 15 percent of chelating agent, 0.3 to 4 percent of inorganic alkaline compound, 2 to 8 percent of nonionic surfactant, 0.05 to 3 percent of polysaccharide macromolecular compound, 0.05 to 1.5 percent of polyether modified silicone oil, 0 to 5 percent of other auxiliary agent and 63.5 to 94.6 percent of solvent; wherein the polysaccharide high molecular compound is xanthan gum. The cleaning composition has excellent cleaning performance through the cooperation of polyether modified silicone oil and xanthan gum and the synergistic effect of the components, so that the scrubbing times can be effectively reduced, and the cleaning strength is enhanced; meanwhile, the cleaning composition has spreadability, a layer of protective film can be formed on the surface after cleaning is finished, water drops can flow down more quickly, the draining time is shorter, and then the generation of scale marks can be reduced, so that the self-cleaning effect is achieved.
Description
Technical Field
The application belongs to the technical field of daily chemical washing products, and particularly relates to a cleaning composition, a preparation method thereof and a cleaning agent.
Background
In daily life, the tap is frequently turned on and off in a bathroom and a kitchen, scale is extremely easy to be generated on the tap and glass when the operation of using hot water and the like is carried out, the appearance is influenced, and the tap is easy to rust and damage.
The cleaning composition on the market at present mainly comprises a neutral cleaning composition and an acidic cleaning composition, wherein the neutral cleaning composition mainly utilizes organic acid or inorganic acid and alkali to neutralize and generate salt to be used as a chelating agent for combining and reacting with scale, so that the defects of slow reaction and low removal efficiency exist, and the neutral cleaning composition can only wash away dirty things and cannot thoroughly remove the scale. The acidic cleaning composition mainly utilizes the reaction of hydrogen ions and scale, has the advantages of quick reaction and high removal rate, but has the defects of time and labor waste and long draining time because of the need of scrubbing for multiple times.
Disclosure of Invention
In view of the foregoing problems of the prior art, it is an object of the present application to provide a cleaning composition. The cleaning composition can effectively remove scale, effectively reduce scrubbing times, save time and labor, and shorten draining time.
In order to achieve the above purpose, the present application adopts the following technical scheme:
the application provides a cleaning composition, which comprises the following preparation raw materials in percentage by weight:
wherein the polysaccharide high molecular compound is xanthan gum.
In one embodiment, the polyether modified silicone oil is a clariant Aristocare Smart.
In one embodiment, the cleaning composition comprises the following preparation raw materials in weight percent:
in one embodiment, the nonionic surfactant comprises one or more of AEO-9, fatty alcohol alkyl oxides, fatty alcohol polyoxyethylene ethers, and alkyl glycosides.
In one embodiment, the inorganic basic compound includes one or more of sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate, and potassium bicarbonate.
In one embodiment, the chelating agent comprises one or more of ethylenediamine tetraacetic acid, phosphoric acid, pyrophosphoric acid, gluconic acid, citric acid, sodium salts of silicic acid, and potassium salts of silicic acid.
In one embodiment, the solvent comprises one or more of water, glycerin, polyethylene glycol, and propylene carbonate.
In one embodiment, the other auxiliary agents include one or more of moisturizers, bactericides, preservatives and fragrances,
the humectant comprises one or more of vitamin E, lanolin and panthenol;
the bactericide comprises one or more of dodecyl dimethyl benzyl ammonium chloride and octadecyl dimethyl;
the preservative comprises one or more of pinus koraiensis, polyalcohol, phenoxyethanol, pentanediol and ethyl hexyl glycerol.
The application also provides a preparation method of the cleaning composition, which comprises the following steps:
and dissolving the polysaccharide high molecular compound in the solvent, adding the nonionic surfactant, the chelating agent, the inorganic alkaline compound, the polyether modified silicone oil and other auxiliary agents, and stirring to prepare the cleaning composition.
The present application also provides a cleaning composition comprising the cleaning composition of any of the embodiments described above.
The application provides a cleaning composition, which is prepared by matching polysaccharide polymer compound xanthan gum with polyether modified silicone oil, and can achieve the following beneficial effects under the synergistic effect of all components:
(1) Good hydrophilicity. The cleaning composition has good hydrophilicity, can enable oil stains to quickly slide off in cleaning, and effectively reduces scrubbing times.
(2) Shorten the draining time and have self-cleaning capability. The cleaning composition has spreadability, can form a layer of protective film on the surface after cleaning is finished, so that the surface becomes smooth, water drops and oil stains can slide on the surface very quickly, the water drops and the oil stains are not easy to adhere, the draining time can be effectively shortened, and therefore, the generation of scale marks can be reduced, and the self-cleaning effect is achieved.
Detailed Description
The cleaning composition, the method for preparing the cleaning composition, and the cleaning agent of the present application are described in further detail below with reference to specific examples. This application may be embodied in many different forms and is not limited to the embodiments described herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete. Of course, they are merely examples and are not intended to limit the present application.
When a range of values is disclosed herein, the range is considered to be continuous and includes both the minimum and maximum values for the range, as well as each value between such minimum and maximum values. Further, when a range refers to an integer, each integer between the minimum and maximum values of the range is included. Further, when multiple range description features or characteristics are provided, the ranges may be combined. In other words, unless otherwise indicated, all ranges disclosed herein are to be understood to include any and all subranges subsumed therein.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs. The terminology used herein in the description of the application is for the purpose of describing particular embodiments only and is not intended to be limiting of the application. Unless otherwise indicated or contradicted, terms or phrases used herein have the following meanings:
in the present application, reference is made to "multiple", etc., the index is greater than or equal to 2 in number, as not particularly limited. For example, "one or more" means one kind or two or more kinds.
In this application, the terms "first," "second," "third," "fourth," and the like are used for descriptive purposes only and are not to be construed as indicating or implying a relative importance or quantity, nor as implying an importance or quantity of a technical feature being indicated. Moreover, the terms "first," "second," "third," "fourth," and the like are used for non-exhaustive list description purposes only, and are not to be construed as limiting the number of closed forms.
In the present application, the technical features described in an open manner include a closed technical scheme composed of the listed features, and also include an open technical scheme including the listed features.
In this application, references to "a combination thereof", "any combination thereof", and the like include all suitable combinations of any two or more of the listed items.
In the present application, the "suitable" is referred to in "suitable combination mode", "suitable mode", "any suitable mode", etc., so as to implement the technical scheme of the present application, solve the technical problem of the present application, and achieve the technical effects expected in the present application.
In this application, references to "preferred," "better," "preferred," and "preferably" are merely descriptive of better performing embodiments or examples, and are not to be construed as limiting the scope of the application.
In this application, references to "further," "still further," "particularly," etc. are used for descriptive purposes and are intended to indicate differences in content and are not to be construed as limiting the scope of the application.
In this application, references to "optionally", "optional" refer to the presence or absence of the possibility, i.e. to any one of two juxtaposed schemes, either "with" or "without". If multiple "alternatives" occur in a technical solution, if no particular description exists and there is no contradiction or mutual constraint, then each "alternative" is independent.
In this application, reference is made to a numerical interval (i.e., a numerical range), where the optional numerical distribution is considered continuous, and includes two numerical endpoints (i.e., a minimum value and a maximum value) of the numerical range, and each numerical value between the two numerical endpoints, unless otherwise indicated. Where a numerical range merely refers to integers within the numerical range, including both end integers of the numerical range, and each integer between the two ends, unless otherwise indicated, each integer is recited herein as directly, such as where t is an integer selected from 1 to 10, and where t is any integer selected from the group of integers consisting of 1, 2, 3, 4, 5, 6, 7, 8, 9, and 10. Further, when a plurality of range description features or characteristics are provided, these ranges may be combined. In other words, unless otherwise indicated, the ranges disclosed herein are to be understood to include any and all subranges subsumed therein.
The temperature parameter in the present application is not particularly limited, and may be a constant temperature treatment or may vary within a predetermined temperature range. It should be appreciated that the constant temperature process described allows the temperature to fluctuate within the accuracy of the instrument control. Allows for fluctuations within a range such as + -5 ℃, + -4 ℃, + -3 ℃, + -2 ℃, + -1 ℃.
In the present application, the term "percentage content" refers to mass percentage for both solid-liquid and solid-solid phase mixtures and volume percentage for liquid-liquid phase mixtures unless otherwise specified.
In this application, reference to percent concentration, unless otherwise indicated, refers to the final concentration. The final concentration refers to the ratio of the additive component in the system after the component is added.
The application provides a cleaning composition, which comprises the following preparation raw materials in percentage by weight:
wherein the polysaccharide high molecular compound is xanthan gum.
In one example, the polyether-modified silicone oil is clariant Aristocare Smart.
The principle and advantages of the above cleaning composition are as follows:
according to the cleaning composition, the polysaccharide polymer compound xanthan gum is matched with polyether modified silicone oil, and meanwhile, under the synergistic effect of all components, the scrubbing times can be effectively reduced and the cleaning force can be enhanced in actual use; meanwhile, the cleaning composition has spreadability, a layer of protective film can be formed on the surface after cleaning is finished, water drops can flow down more quickly, the draining time is shorter, and then the generation of scale marks can be reduced, so that the self-cleaning effect is achieved. The principle can be summarized as follows:
on the one hand, the cleaning composition has good pseudoplasticity, namely the viscosity of the cleaning composition is reduced along with the increase of the shear rate or the shear stress, so that the viscosity of a solution with pseudoplasticity is reduced along with the action of external force when the cleaning composition is extruded, and the cleaning composition is easy to be sprayed out due to the lower viscosity; meanwhile, the sprayed solution is subjected to smaller external force action, so that the viscosity is higher, the sprayed solution can be better attached to an object to be cleaned, the reaction time is prolonged, and the scrubbing times are reduced;
meanwhile, the structure of xanthan gum can be expressed as follows:xanthan gum is a polysaccharide polymer, and is a polymer with a pentasaccharide repeating unit structure composed of D-glucose, D-mannose, D-glucuronic acid, acetic acid and pyruvic acid. The interaction of the xanthan gum and the solvent enables hydroxyl groups in saccharide units of the xanthan gum to interact with the solvent to form a three-dimensional network structure, so that the solution forms a certain consistency; thereby can prolongLong reaction time with scale, effectively reducing scrubbing times;
on the other hand, after the cleaning is finished, the spreadability of the cleaning composition can enable the cleaning composition to form a layer of hydrophilic polymer film on the surface of a cleaned object, the hydrophilic polymer film can ensure the surface of the cleaned object to be smooth, water drops, stains and the like slide on the surface, the draining time is shortened, meanwhile, the generation of scale marks can be reduced, and the self-cleaning effect is achieved.
The cleaning composition provided herein comprises, by weight, 3% to 15% chelating agent. Specifically, the weight ratio of chelating agents includes, but is not limited to: 3%, 4%, 5%, 6%, 8%, 8.5%, 8.6%, 8.7%, 9%, 9.8%, 9.9%, 10%, 10.1%, 10.2%, 11%, 12%, 13%, 14% or 15%.
The cleaning composition provided by the application comprises 0.3-4% of inorganic alkaline compound by weight percent. Specifically, the weight ratio of the inorganic basic compounds includes, but is not limited to: 0.3%, 0.4%, 0.45%, 0.46%, 0.47%, 0.48%, 0.49%, 0.5%, 0.51%, 0.52%, 0.53%, 0.54%, 0.55%, 0.6%, 0.7%, 0.8%, 0.9%, 1.0%, 2%, 3% or 4%.
The cleaning composition provided by the application comprises 2-8% of nonionic surfactant by weight percent. Specifically, the weight ratio of nonionic surfactants includes, but is not limited to: 2%, 2.3%, 2.4%, 2.5%, 2.6%, 2.7%, 2.8%, 2.9%, 3%, 3.1%, 3.2%, 3.3%, 3.4%, 3.5%, 4%, 5%, 6%, 7% or 8%.
The cleaning composition provided by the application comprises 0.05-3% of polysaccharide high molecular compound by weight percent. Specifically, the weight ratio of the polysaccharide polymer compound includes, but is not limited to: 0.05%, 0.1%, 0.2%, 0.3%, 0.4%, 0.46%, 0.47%, 0.48%, 0.49%, 0.5%, 0.51%, 0.52%, 0.55%, 0.56%, 0.57%, 0.58%, 0.59%, 0.6%, 0.61%, 0.62%, 0.63%, 0.64%, 0.65%, 0.7%, 0.75%, 0.78%, 0.79%, 0.8%, 1.0%, 1.5%, 2%, 2.5%, 2.9% or 3%.
The cleaning composition provided by the application comprises 0.05-1.5% of polyether modified silicone oil by weight percent. Specifically, the weight ratio of polyether modified silicone oils includes, but is not limited to: 0.05%, 0.1%, 0.15%, 0.2%, 0.28%, 0.29%, 0.3%, 0.31%, 0.32%, 0.33%, 0.34%, 0.4%, 0.5%, 0.55%, 0.56%, 0.57%, 0.58%, 0.59% or 0.6%.
The cleaning composition provided by the application comprises 0-5% of other auxiliary agents by weight percent. Specifically, the weight ratio of other auxiliary agents includes, but is not limited to: 0%, 0.08%, 0.09%, 0.1%, 0.11%, 0.12%, 0.13%, 0.15%, 0.2%, 0.5%, 1%, 1.5%, 2%, 2.5%, 3%, 3.5%, 4%, 4.5% or 5%.
The cleaning composition provided herein comprises, by weight, 63.5% to 94.6% solvent. Specifically, the content of the solvent includes, but is not limited to: 63.5%, 65%, 70%, 75%, 76%, 77%, 77.6%, 78%, 79%, 80%, 81%, 82%, 83%, 84%, 84.9%, 85%, 85.1%, 85.2%, 85.3%, 85.4%, 85.5%, 86%, 87%, 88%, 88.4%, 88.5%, 88.6%, 88.7%, 88.8%, 89%, 90%, 91%, 92%, 93%, 94%, 94.5% or 94.6%.
In one example, the cleaning composition is a household cleaning composition.
Preferably, the cleaning composition comprises the following preparation raw materials in percentage by weight:
in one embodiment, the cleaning composition comprises the following preparation raw materials in weight percent:
through adjusting the proportion of each component, under the synergistic effect of each component, the interaction of xanthan gum and solvent can lead hydroxyl in saccharide units of the xanthan gum and the solvent to interact with the solvent to form a three-dimensional network structure, so that solvent molecules form an ordered arrangement structure from disordered ordering, and further atomized fine liquid drops can be gathered into larger liquid drops when the household cleaning composition is sprayed out, the atomization effect is weakened, the household cleaning composition can not enter respiratory tract or eyes, and the irritation is reduced. Meanwhile, the cleaning composition has good pseudoplasticity and good viscosity, can enhance the adhesive force with the cleaned object, and solves the sagging problem.
In one example, the nonionic surfactant includes one or more of AEO-9, fatty alcohol alkyl oxide, fatty alcohol polyoxyethylene ether, and alkyl glycoside.
In one specific example, the nonionic surfactant is AEO-9.
In one example, the inorganic basic compound includes one or more of sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate, and potassium bicarbonate.
In one specific example, the inorganic alkaline substance is sodium hydroxide.
In one example, the chelating agent includes one or more of ethylenediamine tetraacetic acid, phosphoric acid, pyrophosphoric acid, gluconic acid, citric acid, sodium salt of silicic acid, and potassium salt of silicic acid.
In one specific example, the chelating agent is citric acid.
In one example, the solvent includes one or more of water, glycerin, polyethylene glycol, and propylene carbonate.
In one specific example, the solvent is water.
In one example, the other adjuvants include one or more of humectants, bactericides, preservatives, and fragrances.
In one example, the humectant includes one or more of vitamin E, lanolin, and panthenol.
In one example, the germicide includes one or more of dodecyl dimethyl benzyl ammonium chloride and octadecyl dimethyl.
In one example, the preservative includes one or more of kathon, a polyol, phenoxyethanol, pentanediol, and ethylcycloglycerol.
In one specific example, the preservative is pinocembrane.
The application also provides a preparation method of the cleaning composition, which comprises the following steps:
and dissolving the polysaccharide high molecular compound in the solvent, adding the nonionic surfactant, the chelating agent, the inorganic alkaline compound, the polyether modified silicone oil and other auxiliary agents, and stirring to prepare the cleaning composition.
In one example, the process parameters of the agitation include: the rotating speed is set to 300 r/min-700 r/min, and the stirring time is set to 10 min-20 min.
The present application also provides a cleaning composition comprising any of the above examples.
In one example, the cleaning agent is a household cleaning agent.
In order to make the objects and advantages of the present invention more apparent, the cleaning compositions of the present invention and the effects thereof will be described in further detail with reference to the following examples, which are to be construed as merely illustrative and not limitative of the present invention. The following examples are not specifically described but do not include other components than the unavoidable impurities. The drugs and apparatus used in the examples are all routine choices in the art, unless specifically indicated. The experimental methods without specific conditions noted in the examples were carried out according to conventional conditions, such as those described in the literature, books, or recommended by the manufacturer.
The polyether modified silicone oil model in the examples is Craien Aristocare Smart.
Example 1
The cleaning composition of example 1 was prepared as follows:
dissolving xanthan gum in water completely, sequentially adding AEO-9, citric acid, sodium hydroxide, polyether modified silicone oil and kathon, setting the rotation speed at 700r/min, stirring for 15min to prepare cleaning composition, filling the cleaning composition into PET bottle, and covering with spray nozzle.
The components and amounts (in weight percent) of the cleaning compositions prepared in example 1 are shown in table 1.
The cleaning composition of example 1 was used as follows:
selecting an object to be cleaned, keeping the distance from the surface of the object to be cleaned to 20cm, pressing down a spray head to spray, waiting for 3 minutes, and wiping the object to be cleaned with a towel.
Examples 2 to 11
The cleaning compositions of examples 2-11 were prepared and used in a similar manner to example 1, except that the amounts (in weight percent) of the components were varied, as shown in Table 1.
Comparative examples 1 to 2
The cleaning compositions of comparative examples 1-2 were prepared and used in a manner similar to example 1, except that the components and amounts (in weight percent) were varied, as shown in Table 2.
TABLE 1
TABLE 2
The method for testing the effect performance comprises the following steps:
(1) Irritation test: the cleaning compositions to be tested in advance were each placed in 300mL PET bottles and pressed 6 by a spray gun next to a laboratory sink, then brought close to a hand sink, and continuously fired with the right hand into the nose, and the irritation of each sample was evaluated.
(2) Sag test:
1. calcium bicarbonate was dissolved in water to prepare a 10% calcium scale solution. 3g of calcium scale solution is dripped on a glass slide, and the glass slide is put into an oven for aging and drying for 24 hours, so as to prepare a test piece.
2. Five cleaning compositions were sprayed at a distance of 20cm from the test piece, after waiting for 3min, the sagging property of the sample was checked, and then the test piece was scrubbed in a single direction with a towel, and the number of scrubbing times to remove calcium scale was recorded.
(3) Hydrophilic performance test: and (3) taking glass with one clean surface, spraying the cleaning composition at a distance of 20cm for five times, uniformly wiping the glass with sponge, washing with water, and then spraying water with a spray can to detect the hydrophilic effect. And the time for the water to drain naturally was recorded.
The test results are shown in table 3:
TABLE 3 Table 3
At the same time, physicochemical examination was carried out on the cleaning compositions in the examples, which were colorless transparent liquids in appearance and had a density of 1.03g/cm 3 ～1.05g/cm 3 The method comprises the steps of carrying out a first treatment on the surface of the The stability is good, no precipitation and no color change phenomenon exists after the room temperature is restored at 50+/-2 ℃, and no precipitation and no color change phenomenon exists after the room temperature is restored at-5+/-2 ℃; meanwhile, under the condition of 1% aqueous solution, the pH is 1.5-3.0.
As is clear from table 3, the cleaning compositions of examples 1 to 10 were effective in removing scale, had hydrophilicity, and were effective in shortening the drain time. Meanwhile, the cleaning compositions of examples 5, 6, and 10 exhibited a lighter irritation, an excellent sagging resistance, a smaller number of scrubbing times, and at the same time had a good hydrophilicity and were capable of effectively shortening the drain time.
The technical features of the above-described embodiments may be arbitrarily combined, and all possible combinations of the technical features in the above-described embodiments are not described for brevity of description, however, as long as there is no contradiction between the combinations of the technical features, they should be considered as the scope of the description.
The above examples merely represent a few embodiments of the present application, which facilitate a specific and detailed understanding of the technical solutions of the present application, but are not to be construed as limiting the scope of the invention. It should be noted that it would be apparent to those skilled in the art that various modifications and improvements could be made without departing from the spirit of the present application, which would be within the scope of the present application. It should be understood that those skilled in the art, based on the technical solutions provided in the present application, can obtain technical solutions through logical analysis, reasoning or limited experiments, all fall within the protection scope of the claims attached to the present application. The scope of the patent application is therefore intended to be indicated by the appended claims, and the description may be used to interpret the contents of the claims.
Claims (9)
1. The cleaning composition is characterized by comprising the following preparation raw materials in percentage by weight:
8.5-11% of chelating agent,
0.3-1% of inorganic alkaline compound,
2-4% of nonionic surfactant,
0.5 to 0.8 percent of polysaccharide polymer compound,
0.2 to 0.6 percent of polyether modified silicone oil,
0% -5% of other auxiliary agents
77.6% -88.5% of solvent;
wherein the polysaccharide high molecular compound is xanthan gum; the polyether modified silicone oil is Craien Aristocare Smart;
the nonionic surfactant comprises one or more of fatty alcohol polyoxyethylene ether and alkyl glycoside;
the chelating agent comprises one or more of ethylenediamine tetraacetic acid, phosphoric acid, pyrophosphoric acid, gluconic acid and citric acid.
2. The cleaning composition of claim 1, wherein the inorganic alkaline compound comprises one or more of sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate, and potassium bicarbonate.
3. The cleaning composition of claim 1 or 2, wherein the solvent comprises one or more of water, glycerin, polyethylene glycol, and propylene carbonate.
4. A cleaning composition according to claim 1 or claim 2, wherein the further adjunct comprises one or more of a humectant, a bactericide, a preservative and a perfume.
5. The cleansing composition of claim 4 wherein the humectant comprises one or more of vitamin E, lanolin, and panthenol.
6. The cleaning composition of claim 4, wherein the germicide comprises one or more of dodecyldimethylbenzyl ammonium chloride and octadecyl dimethyl.
7. The cleaning composition of claim 4, wherein the preservative comprises one or more of kathon, a polyol, phenoxyethanol, pentanediol, and ethylcycloglycerol.
8. A method of preparing a cleaning composition according to any one of claims 1 to 7, comprising the steps of:
and dissolving the polysaccharide high molecular compound in the solvent, adding the nonionic surfactant, the chelating agent, the inorganic alkaline compound, the polyether modified silicone oil and other auxiliary agents, and stirring to prepare the cleaning composition.
9. A cleaning composition according to any one of claims 1 to 7.
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