TW318865B - - Google Patents

Description

A7 A7 Printed by the Employees ’Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economics _____B7 V. Description of the invention (y. Background of the invention The present invention relates to a detergent composition for hard surfaces, and in particular to scum or dirt on bathroom hard surfaces Traces and other cleaning compositions for hard surfaces with aggressive detergency. Description of background art Regarding hard surfaces, especially baths and bathtubs, the cleaning agents are generally used mainly by nonionic surfactants , Anionic surfactant, organic acid and solvent composed of acidic cleaner; including neutral cleaner combined with nonionic surfactant and anionic surfactant; mainly composed of nonionic surfactant, anionic It is an experimental cleanser composed of surfactant and miscellaneous agent. However, the dirt in the bathroom and the bathtub is different from the components in the house from other dirt, and it is mainly composed of metal soaps, especially calcium salts of fatty acids. Composition, which is bound to proteins, nucleic acids, and oils such as lipids. Although the metal soap suds cannot be decomposed by traditional neutral and alkaline detergents, but It can be decomposed by acidic detergents. However, acidic detergents have the problem of difficulty in rinsing, because dirt will re-deposit after cleaning, causing damage to bathtubs and the like and causing rough hands. From this point of view, generally try to develop metal soaps A cleaning agent with excellent detergency for the foam. As a result, it is reported that there is a neutral detergent containing a combination of cationic surfactants and nonionic surfactants (Japanese Published Patent Application No. 283696/1986), which contains a combination of cationic Surfactants, non-ionic surfactants and water-soluble solvent cleaners (Japanese Patent Application No. 283697/1986), containing combined cationic surfactants, non-ionic Caiguanjia Standard (CNS) A4M ^ · (21G X297 Gongdong)-: ----. 1 installed ------ ordered ------ in (please read the notes on the back before filling in (This page) 318365 A7 ___B7___ of the consumer cooperation of the Central Standards Bureau of the Ministry of Economic Affairs. 5. Description of the invention (2) Interface legal agent and maleic acid cleaner (Japanese Patent Application No. 283700/1986) for Bathroom cleaners, including cations Surfactants, non-ionic surfactants, and combinations of aminocarboxylic acids and solvents (Japanese Patent Application No. 221497/1989), cleaning agents for bathrooms, including barrier agents and glycol ethers Combination (Japanese Patent Application No. 22397/1 98 1), etc. However, it is not known that these detergents have completely satisfactory detergency for metal soap scum. Therefore, 'use this detergent Cleaning the bathroom, etc. requires sponges, etc. ^ Wipe the surface to be cleaned. In addition, the traditional cleaning agents mixed with dagger-grade ammonium salts involve a problem because they are irritating to the skin. SUMMARY Therefore, the object of the present invention is to provide a cleansing composition that can easily remove dirt or stains mainly composed of metal soap scum on hard surfaces such as Luo room, and does not irritate the skin. The inventors of the present case have conducted various studies on the detergency of soils combined with metal soap scum and oils and the chemical structure of cationic surfactants. As a result, it was found that quaternary monoalkyl (or monoalkenyl) trimethylammonium or dialkyl (or dialkenyl) dimethyl salt, or quaternary monoalkyl (or alkenyl) fluorenyl dimethyl The ammonium salt, whose alkyl or alkenyl part has a relatively short chain length of one carbon atom, and the barrier agent and water-soluble solvent can provide superior detergency compared to the case of using any other cationic surfactant in combination , It will not irritate the skin, so towards the completion of the present invention. It is also shown that the combination of the above components and anionic surfactants with polyoxyalkylene can not only further improve the detergency of metal soap scum, but also apply the Chinese National Standard (CNS) ) A4 specification (210X2974 ^:-I n ^ " Binding n — .. ^ (please read the precautions on the back and then fill in this page) V. Invention description (3) A7 B7 can improve the sebum Detergency. It was also found that when nonionic surfactants and / or amphoteric surfactants are mixed in addition to the above components, the detergency for metal scum and sebum stains can still be improved again. Moreover, the storage stability is also improved. According to the present invention, a cleaner composition for hard surfaces is thus provided, comprising the following components ⑻, ⑸ and (C): ⑻0.1-30% by weight in the general formula ⑴ or ⑵ Represented cationic surfactant: R2 R ^ N-CH; CH〇Γ (1) R3- ^ CH2 ^ ©> CH〇; X- (2) -------- 1 ^ --- --- ir ------. 4- (Please read the precautions on the back before filling in this page) Printed by the Consumer Cooperative, a member of the Central Bureau of Standards of the Ministry of Economic Affairs, of which R1 has 6.11 Atomic linear or branched chain alkyl or alkyl, R2 represents methyl or linear or branched alkyl or alkenyl with 6-11 carbon atoms' R3 represents linear or branched alkyl with 6-11 carbon atoms Radical or alkenyl group, and is a residue of _ atom or alkyl sulfuric acid; (b) 0. 1-2 0% by weight of a barrier agent; and (C) 0.1-20% by weight of a water-soluble solvent, The composition has a pH value of 3-12. According to the present invention, a detergent composition for hard surfaces is also provided, further -6- This paper size is applicable to China) M specifications (21〇x297 employees of the Ministry of Economic Affairs Central Standards Bureau Printed by the consumer cooperative A7 B7 V. Description of the invention (4) Contains i part ⑻, except (b) and (C), ⑹ anionic surfactant with polyoxyalkylene, the composition has 3 · i 2 The pH value. According to the present invention, a cleaner composition for hard surfaces is further provided, further comprising components ⑻, ⑸, (c) and (d) except ⑹ nonionic surfactant and / or zwitterionic interface activity The composition has a value of 3-i 2. Due to the decomposition and dissolution of the cleaning composition for hard surfaces according to the present invention The ability to dissolve the metal soap scum and sebum is superior, so the dirt on the bath red in the bathroom can be removed quickly and easily. Furthermore, it has good long-term storage stability. Other objects, features and advantages will be easily understood by the preferred embodiments of the present invention, and will be described in detail later. The detailed description of the present invention and the preferred embodiments of the cationic surfactant of component ⑻ are right and wrong It can be used to decompose and dissolve metal soap when it is used together. In the present invention, it is important for this surfactant to have a structure represented by the general formula (1) or (2). More specifically, the linear or branched alkyl or alkenyl group represented by R1 or R2 in the general formula (1) has a chain It is 6 carbon atoms in length, preferably 8-10 carbon atoms, and most preferably 8 carbon atoms β. The R1 and R2 groups are preferably linear or branched alkyl groups, with 8-10 carbon atoms Linear alkyl, especially octyl is the best. The preferred general formula (1) is a quaternary dialkyl dimethyl ammonium salt, in which both R2 and R2 are linear or branched alkyl or alkenyl groups having 6 to 11 carbon atoms. On the other hand, in the general formula ⑵, the linear or branched alkyl group represented by R3 or the size of this paper is applicable to the Chinese National Standard (CNS) Α4 specification (210Χ297mm -------- seed coat --- --- 、 玎 ------ ^ (Please read the precautions on the back before filling in this page) A7 _____B7___ printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Invention description (5) The base has a chain length of 6 -11 carbon atoms, preferably 8-10 carbon atoms, and most preferably 8 carbon atoms. Such R3 group is preferably a linear or branched alkyl group, especially a linear alkyl group having 8 carbon atoms It is the best one. Among them, any one of Ri_Rs having 12 or more carbon atoms of formula I or formula II cationic surfactant is strongly irritating to the skin, so it is not suitable for cleaning agents for hard surfaces such as bathrooms. Examples of the relative ion X in these cationic surfactants include bromine atom, iodine atom and gas atom when X is a halogen atom, and methanesulfonic acid and ethanesulfonic acid when x is a residual i of alkyl sulfuric acid 1 wherein halogen atoms, especially bromine or gas atoms are preferred. According to the present invention, component ⑻ is preferably 0.1. -30% by weight, particularly preferably 0.3-15% by weight, most preferably incorporated into the composition at a ratio of 0.5% to 10% by weight. Any ratio below 0.1% by weight will make the detergent composition The defoaming power of the foam is insufficient. On the other hand, if the component ⑻ is incorporated in any proportion exceeding 30%, the effect of the present invention will not be improved any more. Therefore, the component ⑻ is incorporated in such a high proportion It is not economical to enter. As long as the component (b) staggering agent has the ability to pinch and stagger metal ions, it does not impose any special restrictions on it. However, examples thereof include hydroxychiric acid and its salts, And aminocarboxylic acids and their salts. Among them, ethylenediaminetetraacetic acid, hydroxyethylethylenediaminetriacetic acid, citric acid, and salts of these compounds are particularly preferred. According to the present invention, component (b ) Preferably 0 _ 1-2 0% by weight, particularly preferably 0.5 _ 1 〇% by weight, most preferably incorporated in the composition at a ratio of 1-5 weight 〇 / 〇. Any lower than 0.1 weight The ratio of 5% will make the detergent composition's detergency to float -8 * This paper scale uses the Chinese National Standard (CNS) A4 specification (210X297 % Ί '^-Binding Brigade (please read the precautions on the back before filling in this page) A7 B7 V. Description of the invention (6) Wooden feet. On the other hand, if the component (b) is in any proportion exceeding 2 〇 When incorporated, the effect of the present invention will not be further improved. No particular restrictions are imposed on the component (c) water-soluble solvent suitable for the practice of the present invention. However, it may preferably contain one or more water Soluble solvents, selected from compounds represented by the following general formulas ⑶ to ⑸ and mono-alcohols with 1.5 carbon atoms: R4〇 (C2Ii40) m (C3H6〇) nR5 ⑶ 12? Η r6-n nr \ / c 2 7 (4) (Please read the precautions on the back before filling in this education) • Pack. 0 R8〇C (CH3) 2ch2ch2oh (5 Order where R4 and R5 are each hydrogen atoms, each with a carbon atom Burning group, phenyl group or benzyl group, the restriction is that both R4 and R5 cannot be gas atoms at the same time, m and η each represent an integer of 0-10, the restriction is that both 111 and 11 cannot be an integer at the same time, R «and R7 are each an alkyl group having i_3 carbon atoms, and R * is an alkyl group having i_3 carbon atoms. In the water-soluble solvent represented by the general formula (3), for R 4 and R ί, when they are burnt groups, it is particularly preferable that they have i_4 carbon atoms. In formula (3), 111 and η respectively represent the average number of moles of ethylene oxide (Ε.Ο.) and propylene oxide (ρ · 〇_), and each may be individually 〇β1〇 ^ these oxides There are no specific restrictions on the order of addition. Therefore, this addition can be carried out at will. From the point of view of the detergency and tactility of the resulting detergent composition, the compound of formula ⑶- This paper scale is applicable to the Chinese National Standard (CNS) 八四 界 格Printed by employee consumer cooperatives A7 B7 Printed by employee consumer cooperatives of the Central Bureau of Standards of the Ministry of Economy V. Description of invention (7) Preferred examples include propylene glycol monomethyl squint, diethylene glycol monobutyl ether, and propylene glycol monobutyl Ether, dipropylene glycol monobutyl ether and polyoxyethylene glycol (p = 1 -4) phenyl ether. Preferred examples of compounds represented by general formula ⑷ include 1,3-dimethyl-2-oxazolidinone And 1,3-diethyl-2-imidazolidinone. On the other hand, 3-methoxy-3 · methylbutanol, 3-ethoxy-3-methylbutanol, etc. are preferred as The compound represented by the general formula ⑸. Examples of the dihydroxy alcohol having 4 to 12 carbon atoms include isoprene diol, 2,2,1-trimethyl-1,3-pentanediol, etc. Examples of monohydric alcohols of 1 to 5 carbon atoms include methanol, ethanol, isopropanol, etc. When these lower carbon alcohols are mixed, the low-temperature stability of the resulting composition is improved According to the present invention, component (c) is preferably from 0.1 to 20% by weight, particularly preferably from 1 to 0.15% by weight, and most preferably is incorporated into the composition at a ratio of 5 to 10% by weight, any low At a ratio of 0.1 weight ° / 〇, the detergency of the detergent composition to non-floating dirt will be insufficient. On the other hand, if the component ⑹ is incorporated in any proportion exceeding 20%, The effect will not be further improved. In the cleaner composition for hard surfaces according to the present invention, in addition to the above components ⑻, (b) and (c), an anionic surfactant having polyoxyalkylene ( d) The detergency of oil and lipid stains, especially sebum stains, can be further improved. Particularly preferred examples of anionic surfactant component (d) having polyoxyalkylene include polyoxygen Alkyl alkyl ether sulfates, polyoxyalkylene alkenyl ether sulfates, polyoxyalkylene alkyl ether acetates and polyoxyalkylene alkenyl carp acetates. -10- This paper size applies to Chinese national standards (CNS) A4 specification (210X297mm) (Please read the precautions on the back before filling this page),-· 0 < ·· 7

I Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs: A7 --------- B7_ V. Description of the invention (8) The alkyl or alkenyl group in these anionic surfactants preferably has 4 · 26 atoms, especially S-24 carbon atoms. These alkyl or alkenyl groups may be linear or branched. Examples of the polyoxyalkylene in the anionic surfactant include polyoxyethylidene, polyoxypropylene and polyoxypropylene. The average mole number of the polyoxygen extension pit foundation after addition is preferably 1-20, particularly preferably uo. Examples of the anionic surfactant salts include salts containing alkali metals (such as sodium and potassium) 'salts containing residual earth metals (such as magnesium and magnesium), saddle salts, and alcohol amines (such as monoethanolamine, diethanolamine and Triethanolamine). Specific preferred examples of anions ~ surfactants include polyoxyethylene (E.〇. = I_10) C8 · 24 alkyl ether sulfate and polyoxyethylidene (E〇 == 1-10) C8- 24 alkyl ether acetate. From the viewpoint of the detergency to sebum stains and storage stability, the composition (d) of the composition according to the present invention is preferably 0.1 to 20% by weight, particularly preferably 0.3 to 1. 5% by weight, preferably incorporated at a ratio of 〇5_i 〇% by weight. From the viewpoint of the detergency of the resulting composition on sebum stains, the blending ratio of the component ⑻ to the component ⑻ in the molar ratio is preferably 3/7 to 7/3, and particularly preferably 4/6 To 6/4. Usually, the combined use of a cationic surfactant and an anionic surfactant will lead to the formation of a complex. Therefore, from the viewpoint of storage stability, the easy formation of precipitates seems to constitute a problem. However, the use of an anionic surfactant having a polyoxyalkylene group can reduce the complex formation ability and thus contribute to storage stability. In the cleaner composition for hard surfaces according to the present invention, in order to still further improve the detergency to sebum stains and prevent the I paper scale during long-term storage at high temperature, the Chinese National Standard (21〇: 7 · ^ ----:----------- ^ ------ lsτ ------ .., 1 (please read the precautions on the back before filling this page) A7

Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. The performance deterioration is preferably combined with non-ionic interface active fresh / or amphoteric interface activator as a component⑹. Preferred examples of such nonionic surfactants include the following compounds (i) to (iv), with compound (iv) being particularly preferred. ; (0 where the burned or alkenyl group has an average of 10 to 20 carbon atoms, and the added polyoxyethylidene has a molar number of an average of idO, polyoxypropylene hexyl alkyl ether or polyoxygenated Ethyl alkenyl silver carp. (Ii) Higher fatty acid alcohol amines represented by the following general formula, or their iL addition products of oxidizing oxides: R10 I '

(CHCH2〇) pH

R9C0N \

(CHCH20) gH in 'wherein R9 is an alkyl or alkenyl group having 10 to 20 carbon atoms, R1. R11 and R11 may be the same or different from each other and each is H or CH3, and p and q are integers of 1-3 and 0-3, respectively. (Hi) amine oxides, exemplified by alkylamine oxides or alkenylamine oxides having linear or branched alkyl or alkenyl groups of 1 to 24 carbon atoms. Preferred examples of amine oxides include alkylamine oxides represented by the following general formula ⑻: R13

”I R12- (D) a- (E) b_V—0 (R14 -12- — This paper scale is applicable to China National Standard (CNS) A4 specification (210X297mm) --------- 1 ^. ------, 玎 ------ A (please read the notes on the back before filling in this page) «1 Α7 Β7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy V. Invention Instructions (1 of which R12 Is an alkyl or alkenyl group having 8 to 24 carbon atoms, R13 and R14 are the same as or different from each other, each is an alkyl group having 1 to 3 carbon atoms, D is • NH < ^ or · ΪΝΗ ·, and E is having An alkylene group of 1-5 carbon atoms, and a and b are relative to each other, representing 0 or 1. In the general formula ⑻, R 12 may be an alkyl or alkenyl group having 8 to 24 carbon atoms. However, it has 12 An alkyl group of -18 carbon atoms is preferred. Rh and R " can be individually alkyl groups with 1-3 carbon atoms. However, a methyl group is preferred. The chemical formula is represented by the following general formula: R15 (OR16) xGy where R15 means a linear or branched alkyl, alkenyl or alkylphenyl group with a total of 8-18 carbon atoms, R16 represents a group with 2-4 The secondary alkyl group of carbon atoms, G is derived from 5-6 atoms Sugar residues, and \ and ya represent the average value, the number of 0-5 and 1-5. From the viewpoint of solubility and crystallinity in water, the X value is preferably, and 0 is particularly preferred. Another On the other hand, when the average value of y is greater than 1, the nonionic surfactant contains a sugar chain composed of a disaccharide or higher oligosaccharide as a hydrophilic group. The bonding form of the sugar chain may be 1-2, 1-3, 1-4 or 1-6 bonds, or Alpha-pyranose or furanose bonds. It may also contain sugar chains with these bonding combinations. The average value of y in the general formula can be 1-5, compared It is preferably 1-1.5, particularly preferably 1-1.4. Incidentally, y is determined according to the proton NMR method. Furthermore, from the viewpoint of solubility and detergency, R15 in the general formula preferably has 10-14 Alkyl group of carbon atom. In addition, from the point of view of solubility in water, 13-reference paper scale is applicable to the Chinese National Standard (CNS> A4 specification (210X297 mm) ----------- # ----- -? τ ------., 1. (Please read the notes on the back before filling out this page) A7 A7

5. Description of the Invention (Η) R 16 is preferably an alkylene group having 2-3 carbon atoms. Also, the decision of the G structure depends on the raw materials used, which are monosaccharides or di- or higher oligosaccharides. In terms of 〇, preferred examples of the raw materials include monosaccharide glucose and fructose, di-or meta-oligosaccharide maltose and sucrose, due to their excellent availability and low cost. Among them, glucose is particularly preferred from the viewpoint of availability. The amphoteric surfactants suitable for the practice of the present invention do not have any special restrictions. However, alkyl amide amino carboxy sugar beet and alkyl amide amino hydroxy sulf sugar beet are preferred. Among these amphoteric surfactants, it is preferable to include a linear or branched chain group having 8 to 24 carbon atoms as a hydrophobic group. Among the component ⑹ surfactants, amphoteric surfactants are preferred for improving the storage stability of the composition according to the present invention, while nonionic surfactants are preferred for improving the cleaning effect on sebum stains. Therefore, the combination of amphoteric and nonionic surfactants is particularly preferred in the present invention. From the viewpoint of the detergency to sebum stains and storage stability, the component ⑹ is preferably mixed in a ratio of 0 1-2 0% by weight, particularly preferably in a ratio of 〇J · 1 〇weight 〇 / 0 according to the present invention. Of the composition. The cleaning agent composition according to the present invention may contain, for example, an alkalizing agent (5% by weight, such as an alcohol amine), a thickener, a pigment, a coloring agent, a perfume base, a bactericide, a preservative, and an amount sufficient to make Water β with a total composition weight of 100% by weight The detergent composition according to the present invention can be prepared by a method known in the industry by using the above components. The pH of the composition is preferably 3 _ i 2, particularly preferably 5-10, most preferably 6-8. With any pH falling outside the above-mentioned range ____ -14- This paper scale is applicable _ China National Standard (CNS) Α4 · (21 () χ297 Public)---- ----------- ^ ------ 1T ------ A (Please read the precautions on the back before filling in this page) Printed by the Ministry of Economic Affairs Central Counseling Bureau Employee Consumer Cooperative V. Description of invention (】 2) Group of grains For the poor, yang. Because it will cause problems such as rough hands

According to the present invention, the combination mine mine pumps mA. I * ^ ^ is used as a hard surface (such as ceramic tiles, Kunming soil, expanders, reinforced hard ποτ>, ”glue (? 卩), stainless steel, wood Bodhi, the cleaning agent used. However, it is better to use it especially for cleaning the bathroom and heating the bathroom, that is, as a cleaning agent for the bathroom. As for the cleaning method using the composition according to the present invention, any conventional method can be used. For example, 'just use the composition to impregnate the material, etc., and wipe the hard surface to be cleaned in (iv) and bath red; or use the composition to spray wine on the surface to be cleaned'. Leave the surface as it is for a while, and then rinse with water The surface. When cleaning the inner surface of the bath, it is also allowed to add the composition according to the present invention to the remaining water in the bathtub after bathing and let it stay for a period of time, preferably at least 1 hour, and then drain the water. Afterwards, if necessary, the bathtub surface can be rinsed with water. In this case, the concentration of the composition of the present invention in terms of cationic surfactant is 〇5_i 〇〇ppm, preferably 10_80 p p m 〇 The present invention will be described in more detail in the following examples. However, it should be borne in mind that the present invention is not limited to these examples or is limited by the example of the consumer cooperation cooperation printing of the Central Bureau of Standards of the Ministry of Economy. Example 1 · 8 and Comparative Examples 1-3: The detergent compositions shown in Tables 1 and 2 having their corresponding formulations were prepared to evaluate the detergency. The results are shown in Table 1 and Table 2. The numbers of the corresponding components in the table represent% by weight. [Evaluation method of detergency] 15 This paper scale is applicable to China National Standard (CNS) Μ specifications (210X297mm)

328565 V. Description of the invention (13) Evaluation of the decontamination power in the form of τ. After bathing and staining the basin made of polypropylene and the bath to the extent that it is not easy to remove by rubbing, put the two in close contact with the cloth soaking the detergent composition to be tested for a few seconds, or use the The detergent composition is sprayed, rinsed slightly with water, and when the dirt has been removed, it is visually observed and divided into 5 grades according to the following standards (in the table, represented by the average value of n = 5): 5: Removal reaches a very good level; 4: Removal of dirt reaches a good level; 3: Removal of dirt is uneven; '2: Removal of dirt is slightly removed; and 1: Removal of dirt is not removed. (Please read the precautions on the back before filling in this page) Binding-Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs _____ -16- This paper scale is applicable to the Chinese National Standard (CNs) Μ specifications (210X297 mm) 5 6 3 8 i 3

7 B V. Description of the invention (14) Example of component-1 1 2 3 4 5 6 7 8 Dioctyl dimethyl ammonium gasification 5 5 (a) Didecyl dimethyl ammonium gasification 5 5 decyl tri 5 5 (c) Diethylene glycol monobutyl ether 5 5 5. Diethanoldiol monobutyl ether: 5 '5 5 5 (b) EDTA 2 2 2 2 2 2 2 2 Other components:-Water Bal Bal Bal Bal Bal Bal Bal Eyelid Reagent One (MaOH) QS QS QS QS QS QS QS QS QS Detergency Evaluation 5.0 5.0 4 · 0 5, 0 5.0 5-0 4.2 I 5.0 Ba 1: balance; QS: enough to maintain the pH at 7. The amount of table 2 I ---: ---- batch approval-- (please read the precautions on the back first (Fill in this page) Comparison example of the printed components of the Employees ’Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 1 2.3 Sodium alkyl benzoate (0 = 13) 5-Distearyl Dimethyl Ammonium Vapor 5 Diethylene Dioxide Alcohol monobutyl ether 5 EDTA 2 2 2 Citric acid 2 2 2 Water Bal Bal Bal Alkalinization reagent (Nk〇H) QS QS QS Detergency evaluation 3.5 2.5 2.3 Bal: balance; QS: sufficient to maintain pH 7 Consumption; · -17- brigade The paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) A7 A7 Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 4 3 2 V. Description of the invention (1 5) Understand by Ϊ1 and Table 2 The detergent composition has superior detergency when compared to the case of using a quaternary ammonium salt having a long-chain alkyl group in which the number of carbon atoms is at least 12. When using the detergent composition according to the present invention, The cleaned surface was not damaged, and almost no irritation to the skin was observed. Examples 9-17 and Comparative Examples 4-7: Prepare detergent compositions with their corresponding formulations shown in Tables 3 and 4 and Evaluate its detergency and storage stability. The results are shown in Tables 3 to 5. The numbers of the corresponding components in these tables represent the weight% [the detergency of the dirt and sebum stains of the metal-coated float Evaluation method] (Decontamination power of metal-bubble contaminants) The decontamination power is evaluated in the following manner. After bathing and staining the bathtub made of polypropylene and the bathroom area to a degree that is not easy to remove by wiping, the two And the cleaning agent to be tested The cloth of the compound is in close contact for a few seconds, or it can be sprayed with the detergent composition, wipe it gently with this cloth, and visually observe the dirt after it has been removed and divide it into 5 grades according to the following standards (in the table , Expressed as an average value of η = 5): 5: The removal of dirt reaches a very good level; the removal of dirt reaches a good level; the dirt is removed unevenly; the dirt is slightly removed; and the dirt is almost dead Not cleared. (The detergency of sebum stains) After five adults bathe in a bathtub made of stainless steel, make the bathtub dimension I ^ Binding line (please read the notes on the back before filling this page)

A7 A7 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs ____B7____ 5. Description of the invention (16) " Keep the original overnight, drain the water in the bathtub, and dry the bathtub. The dirt adhering to Yuhong was used in this assessment operation. Use a commercially available sprayer to spray the detergent composition to be tested on the dirt on the bathtub, and then wipe the sprayed area with sponge. Rinse the treated red with water, and when the dirt has been removed, visually observe and divide it into 5 grades according to the following standards (in the table, expressed as the average value of n = 5): 5: Very good level; 4: The dirt is removed to a good degree; 3: The dirt is removed unevenly; · 2: The dirt is slightly removed; and 1: The dirt is not removed. [Storage stability] The storage stability is graded according to the following criteria: A: Even after storage at 40eC for 1 month, no turbidity, separation and precipitation have been observed; B: After storage at 40 ° C for 1 month Slight contamination was observed; however, neither separation nor precipitation was observed; C: no precipitation occurred immediately after the composition was prepared at room temperature, but after storage at 40 ° C for 1 month Then precipitation is observed; and D: Fouling and precipitation are observed immediately after the composition is made at room temperature. ___ -19- This paper scale is applicable to the Chinese National Standard (CNS) A4 (210X 297mm) Binding (please read the precautions on the back before filling in this page) A7 5. Description of the invention (! 7) 'Table-3 Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

Component Example 9 10 11 12 13 14 15 16 17. Octylbenzyl gasified carp 3 3 3 3 1 .----(a) .decylphenyl gasified carp-1-1-3 3 Dioctyl dimethyl ammonium monoxide-1-3 3 3--(d) Compounds of the formula * I 4-4 5 mono-5 5-Compounds of the formula # 2-4-A 4 5 mono- 5 Alkyl * 3.--2 mono-1 1 1-compound of the formula * 4--mono one-1---(e) compound of the formula * 5 mono--2 mono one-1-r Compounds of the following formula *,---one by one 1-2 (b) Four sodium EDTA 3 2 2 2 3 3 3 2 2 2 Citric acid 2 2 2 3 2 2 — 2 2 Diethyldioxygenated monobutyl ether 7 —-7-7 7 5 10 (C) 1,3-Dif-2-ylimidazolinone----5-.3-methoxy-3-methylbutanol-7 11----3-methyl-1,3-butanediol----7----Bal Bal Bal Bal Bal Bal Bal Bal pH (adjusted with NaOH or HC1) 6 7 7 8 6 7 8 7 7 Detergency to soap scum dirt 4.5 4 · 5 4.6 4.6 4.6 4.6 4.5 4.5 4.5 4.5 'Stress against sebum> Detergency 4.5 4.5 4.9 4.7 4.5 4.9 4.8 4-8 4.8 Storage stability (40 &quot; CU months) BBAABAAAA -20- This paper scale is applicable to the Chinese National Standard (CNS) Α4 specification (210X 297 mm) -------- batch clothing ------ lτ ------ # (Please read the precautions on the back before filling in this page), V. Description of the invention (18) A7 B7 * 1: ChHuO ^^ s / ohsc ^ Na, * 2: C12H2 50P \ / 〇 )-? CH2c02Na '* 3: C12H25G1.3 <G: grape graft residue), * 4: C12H25〇 ^ X / 〇) ^ H / 0 CHo II 1 * 5: C11H23CN / V \ N® AC〇2 ®, Η 1 0 CH〇II 1 J ★ 6: C1: LH23CN / V \ N® S03e H 1 I 'ch3 ch3 oh Bal: margin .. Table 4 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

, A component 丨 Comparative Example 4 5 6 7 (a) Fourteen pits. Phenylphenyl gasification alkane 3 3 --di-tetradecyl dimethyl ammonium gasification-3 3 (d,) 12 Glycerol alkylbenzenesulfonate 5 5--Sodium dodecyl sulfate--5 5 (e) Alkyl 3J-1-3 Compounds of the following chemical formula--2 3 (b) Tetrasodium EDTA 2 2- 2 2 Citric acid 3 3. 3 3 (c) Diethylene glycol monobutyl silver carp 7-5 5 3-methoxy-3-methylbutyric acid 7 5 5 Water Bal Bal Bal Bal PH (using NaOH or HC1 adjustment): 7 7 6 8 Detergency for soap scum dirt 2.0 2 · 0 2.3 2 * 8 Detergency for sebum dirt standard 1.2 1.2 1 * 1 2.0 Storage stability (4〇 * C, 1 month) DDD CD * 3: C12H25G13 (G: Residue of Glucose), * 4: C12H25〇 _ ^^ 〇 ^ H, Bal: balance ______________,-21 -_ This paper size is suitable for Chinese national flags Standard (CNS) A4 specification (210X297mm) --------- ¾ ------, 玎 -------. 4. (Please read the precautions on the back before filling in this Page) A7 B7 5. Description of the invention (1 9) It is understood from Tables 3 and 4 that the detergent composition according to the present invention should have an anionic interface with the polypyrene secondary burning group Where the agent is incorporated having excellent detergency to sebum stains compared. When the detergent composition according to the present invention is used, the cleaned surface is not damaged and hardly has any irritation to the skin. Example 1 8-2 0 Prepare a detergent composition that does not have its equivalent formulation in Table 5 and evaluate its detergency and storage stability. Incidentally, the evaluation of the defrosting force and storage stability of the metal soap suds was performed in the same manner as the above box. The results are shown in Table 5. The numbers of the corresponding components in these tables represent the weight%. --------- Guyi -------- Ιτ ------ ^ (Please read the precautions on the back before filling out this page) Printed by the Employees Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs _- 22- The size of this paper is printed by the staff consumer cooperative of the Central Standards Bureau of the Ministry of Economy j.8365 A7 B7 V. Description of invention (2 Q) Table 5

Component Example 18 19 20 Ammonium octylbenzene gasification * 3--(a) Ammonium decylbenzene gasification dioctyl dimethyl ammonium gasification 3 3 • Alkyl--2 (e) Compounds of the formula * 4_. Compound of the following formula * 5 Compound of the following formula * 6 2 2 2 (b) Si Na DTA '2 2 2 citric acid. Acid 2 2 2 Diethylene glycol monobutyl ether--7 (η) 1,3-Dimethyl-2-imidazolinone-one \ ^ y 3-methoxy-3-methylbutyryl 3-methyl-1,3-butanedioxan 7 one-one water •- Bal Bal Bal pH (adjusted with NaOH or HC1) 7 6 8 Detergency to soap float-end dirt. 4.7 4 *. 7 4.7 Storage stability (40 ° C, 1 month) AAA 5 ★

Bal: margin --------- ¾ ------ lsτ ------- d (please read the notes on the back before filling this page)

3 \ 3 Η φ Η C — Ν — C

θ 2ο C 6 *

C 1Η Ν Ηonnc 3 2

3 Η φ C — Ν——C τ θ 3ο s Ηο 3 Η -23- This paper scale is applicable to the Chinese National Standard (CNS) A4 specifications (210X297 mm) A7 _B7_ 5. Description of the invention (29. Know from Table 5, The cleansing composition according to the present invention has superior detergency against metal scum. When the cleansing composition according to the present invention is used, the surface after washing is not damaged, and almost no damage to the skin is observed. Irritation. It is equivalent to storage stability and superior. --------- Approved clothing ------ 1T ------- (Please read the precautions on the back before filling in this Page) DuPont Printing by Staff Consumption Cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs-24- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm)

Claims (1)

318865 A8 B8 C8 D8 六 、 Apply for patent Fan Garden i • A cleaner composition for hard surfaces, including the following components ⑻, (b) and ⑹: ⑻〇 1-3 0% by weight in the general formula ⑴ The cationic surfactant represented by or ⑵: R2 RUn-ch,; CH, X- (1) ch3 r (2) Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs where R1 has 6; -11 carbon atoms Linear or branched alkyl group, R2 is methyl or a linear or branched alkyl or alkenyl group with 6-11 carbon atoms, R3 is a linear or branched alkyl group with 6-11 carbon atoms or Associative group, and X is a residue from an atom or an alkyl sulfuric acid; (b) 〇. 1-2〇% by weight of a spacer agent; and (C) 0.1-20% by weight of a water-soluble solvent, the combination The substance has a pH value of 3-12. 2. The composition according to item 1 of the patent application scope, wherein component (a) is the cationic surfactant represented by the general formula (2). 3_ The composition according to item 2 of the scope of patent application, wherein component (a) is the cationic surfactant represented by the general formula ⑵, where R3 is 8 to -25 pieces of paper and uses the Chinese national standard ( cNS) A4 specification (210x297 mm) -------- 1 ^ .------ 'order ------ ^ (please read the notes on the back before filling this page) A8 B8 C8 D8 318865 VI. Patent application · alkyl group with one carbon atom ° 4. The composition according to item 1 of the patent application, wherein component (b) is at least one selected from the group consisting of light carboxylic acids, amino-based acids and The salts of the wrong agent. 5. The composition according to item 1 of the patent application scope, wherein component (b) is at least one selected from the group consisting of ethylidene diamine tetraacetic acid, ethyl ethylidene diamine triacetic acid, citric acid and salts thereof The partition agent. 6. The composition according to item 1 of the scope of patent application, wherein component (c) is at least one water-soluble solvent selected from the compounds represented by the following general formulas ⑶ to ⑸., With 2 to 4 carbon atoms Alkyl alcohols and monohydric alcohols with one carbon atom: R 4 O (C 2 Η 4 O) m (C 3 Η 6 O) nR5 ⑶ h2c (4) C II o r8〇C (CH3) 2CH2CH2〇H where Each of R4 and R5 is an argon atom, an alkyl group, a phenyl group or a fluorenyl group with 1 · 8 carbon atoms, with the restriction that the two cannot be both hydrogen atoms, m and η each represent an integer of 0-10, The restriction is that both m and η cannot be an integer 0 at the same time, each of R6 and R7 is a pit group with 1-3 carbon atoms, and R8 is a pit group with one complete atom. 7. The composition according to item 1 of the patent application model, in which the component (c) is at least (please read the precautions on the back before filling in this page). Pack · CH〇, I r6_N '/ NR? (5) Order Printed by the Employees Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 26-Printed by the Consumer Consumer Cooperatives of the Bureau of the Central Standard Bureau of the Ministry of Economic Affairs-27 〇1δδ65 Part C8 D8 *, patent application scope. Propylene glycol monomethyl ether, propylene glycol monobutyl ether, dipropylene glycol monobutyl ether, polyoxyethylene glycol (P = Bu 4) phenyl bond, 1,3 · dimethyl-2_imidazoline, I, 3-diethyl-2-imidazolidinone, 3-methoxy-3-methylbutanol, 3-ethoxy-3-methylbutanol, isoprenediol, 2,2,4 -Trimethyl_1,3-pentanediol, methanol, ethanol and isopropanol. 8. The composition according to claim 1 of the patent application, further comprising an anionic surfactant having a polyoxyalkylene group. 9. The composition according to item 7 of the patent application scope, wherein the anionic surfactant having polyalkylene oxide is at least one compound selected from the group consisting of polyoxyalkylene alkyl ether sulfate, polyoxyalkylene Burning group mycosulfate, polyoxyalkylene alkyl ether acetate and polyoxyalkylene alkenyl acetate. 10. The composition according to item 7 of the patent application park further contains a nonionic surfactant and / or amphoteric surfactant. 11. The composition according to claim 9 of the patent application, wherein the nonionic surfactant and / or amphoteric surfactant is at least one compound selected from the group consisting of polyoxyethylene alkyl ether, polyoxyethylene Examination of ethyl styrene ether, higher fatty acid alkanolamide, amine oxide, alkyl glycoside, burned amino carboxyl beet fiber and alkyl amide hydroxy sulfose beet. 12. The composition according to item 1 of the scope of the patent application is suitable as a detergent composition for the Luo room. ΜΛ 張 徇 threat from the nation of it (210 &gt; &lt; 297 public bumps ^ 1Τ ------ ^ (please read the precautions on the back before filling this page)