JPH09310091A - Cleanser composition for hard surface - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain the subject composition containing a specific glycine derivative, a surfactant and a water-soluble solvent in a specified ratio, excellent in a cleansing ability against stains on the hard surfaces of bath room units, toilet stools, kitchen units, etc., capable of reducing wiping residues after cleansing treatments, and further excellent in storage stability. SOLUTION: This cleanser composition comprises (A) 0.1-30wt.% of a compound of the formula (R is a 1-18C alkyl or alkenyl; M is H, Na, K, NH4 ), (B) 0.1-30wt.% of a surfactant, and (C) 0.1-50wt.% of a water-soluble solvent. Therein, the components B and C are contained in a B/C weight ratio of 5/1 to 1/50. The component B comprises preferably a quaternary ammonium salt type cationic surfactant or a betaine type amphoteric surfactant and, if necessary, further contains a polyoxyalkylene group-containing anionic surfactant.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cleaning composition for hard surfaces, more specifically to cleaning power on hard surfaces, particularly scum stains and sebum stains in bathrooms, etc., and inorganic stains in toilet bowls and even kitchen areas. The present invention relates to a detergent composition for hard surfaces, which has excellent detergency against various kinds of hard surface stains such as oil / inorganic composite stains, has a reduced amount of wiping residue after washing, and has excellent long-term storage stability.

[0002]

2. Description of the Related Art Conventional detergent compositions are used properly depending on the type and degree of stains. That is, surfactants and solvent systems are used for hand stains and unmodified oil stains that are relatively lightly soiled, and oil and grease stains that have been altered by the action of heat, sunlight, oxygen in the air, etc. around the kitchen. Is a detergent, a solvent, an alkaline cleaner, and a detergent, a solvent, and a sequestering agent for metal soap in the bathroom, especially calcium salts of fatty acids, and dirt in the toilet bowl. Cleaning agents are becoming mainstream. In fact, it is extremely rare for each stain to exist as a single component, and as a result of our research, it has become clear that divalent metal ions act as a binder for stains regardless of whether they are organic or inorganic stains. There is. As a result, it is extremely important to apply a sequestering agent, which acts synergistically to stains with a cleaning substrate such as an activator or a solvent, to a hard surface cleaning agent. Generally, the sequestering agent, which is the main component of the detergent, is a phosphorus compound represented by tripolyphosphate, a hydroxycarboxylate represented by citrate, from the viewpoints of detergency, cost and the like.
Chelating agents represented by ethylenediaminetetraacetate and diethylenetriaminepentaacetate have been used. However, sodium tripolyphosphate is excellent in chelating ability, but since it has phosphorus, it has contributed to the eutrophication phenomenon of rivers and lakes. Therefore, it is rarely used at present. On the other hand, a hydroxycarboxylic acid salt represented by citric acid has a relatively weak chelating ability and is rarely used alone as a hard surface cleaning agent. On the other hand, chelating agents represented by ethylenediaminetetraacetate also have very high chelating performance, but do not necessarily act synergistically with other cleaning components (for example, solvents, surfactants, etc.), At present, it cannot be said that the compound is a satisfactory compound in view of the problem that the compounded fabric is colored under a long-term storage condition and the biodegradability by microorganisms in the natural environment. In addition, as a stain on the bathroom and the like, there is a lot of stains on the human body and stains around the kitchen mainly due to oils and fats, and it is a complex stain using metal ions as a binder. It is also desired to improve the cleaning power for these stains.

[0003]

SUMMARY OF THE INVENTION Accordingly, the object of the present invention is to prevent hard surfaces, especially scum stains in bathrooms, sebum stains, inorganic stains in toilet bowls, etc., as well as oil / inorganic composite stains around the kitchen. The object is to provide a hard surface cleaner composition which has excellent cleaning power and has a small amount of wiping residue after cleaning and excellent long-term storage stability.

[0004]

[Means for Solving the Problems] As a result of intensive investigations by the present inventors in such an actual situation, a specific alkylglycine-N, N-diacetic acid or a salt thereof and a surfactant compounded in a specific ratio were used. By adding a water-soluble solvent, it has been found that a cleaning agent having excellent cleaning power against stains on various hard surfaces, having reduced uncleaned residue, and having excellent long-term storage stability can be obtained, and the present invention is completed. Came to.

That is, the present invention comprises (A) an alkylglycine-N, N-diacetic acid represented by the following general formula (I) or a salt thereof:
~ 30 wt%, (B) surfactant 0.1 to 30 wt%, and (C)
Contains 0.1 to 50% by weight of water-soluble solvent, and the ratio (B) / (C) of the content of component (B) and the content of component (C) is 5/1 by weight.
It is intended to provide a hard surface cleaner composition of about 1/50.

[0006]

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(In the formula, R represents an alkyl group or an alkenyl group having 1 to 18 carbon atoms, and M represents H, Na, K or NH ₄ )

[0008]

BEST MODE FOR CARRYING OUT THE INVENTION The detergent composition of the present invention will be described in detail below. The general formula of the component (A) of the present invention
The alkylglycine-N, N-diacetic acid or its salt represented by (I) is capable of binding divalent metal ions such as calcium as a binder in various stains (organic substances (fatty acid calcium, etc.) and inorganic substances) on the hard surface. It is used as a decomposition component of stains by chelating and shows higher cleaning performance than hydroxycarboxylic acid salts such as citric acid which is generally used as a chelating agent, and coloring property due to long-term storage compared to ethylenediaminetetraacetic acid salt (EDTA). Is extremely small, and the finishability after cleaning (there are few traces of unwiping) is good. Further, unlike EDTA, it has biodegradability, which is advantageous from the environmental aspect.

In the general formula (I), R is particularly preferably a straight-chain alkyl group or alkenyl group, more preferably having 1 to 18 carbon atoms, especially 1 to 10 carbon atoms from the viewpoint of solubility and detergency. These compounds are, for example, Tris manufactured by BASF.
Available as lon ES series.

The surfactant which is the component (B) of the present invention is (A)
Acts synergistically as a detergency enhancer for the ingredients. Examples of surfactants include cationic surfactants, amphoteric surfactants, nonionic surfactants, and anionic surfactants.The surfactants that act synergistically as the detergency enhancer of the component (A) are cationic surfactants. Activators and amphoteric surfactants are preferable, and cationic surfactants are particularly preferable. It is extremely rare for each stain on the hard surface of a house to exist as a single component, and as mentioned above, divalent metal ions act as a binder for stains regardless of whether they are organic or inorganic stains. It is very important to apply the agent to hard surface cleaners, and it is very important to use a surfactant that acts synergistically on the soil with the sequestering agent. Although the detailed mechanism of washing is unknown, cationic surfactants and amphoteric surfactants are preferable,
Among them, cationic surfactants are effective when compared to ordinary hydroxycarboxylic acid salts such as citric acid and ethylenediaminetetraacetate (EDTA), more effectively like a complex with component (A). It is easy to form so that the divalent metal ion is easy to act on the dirt that is the binder, or the activator itself acts on the dirt (A)
It is considered that it is susceptible to decomposition by the components.

Examples of the component (B) used in the present invention include the following.

<Cationic Surfactant> The cationic surfactant is not particularly limited, but a quaternary ammonium salt is preferable, and among them, the following general formulas (1), (2) and
One or more selected from cationic surfactants selected from the quaternary ammonium salts represented by (3) are preferable.

[0013]

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[Wherein R ¹ represents a linear or branched alkyl or alkenyl group having 6 to 20 carbon atoms, and R ² represents a methyl group or a linear or branched alkyl or alkenyl group having 6 to 20 carbon atoms. Group, R ³ represents a linear or branched alkyl or alkenyl group having 6 to 20 carbon atoms, and X represents a halogen atom or an alkylsulfate residue]

[0015]

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In the general formula (1), the linear or branched alkyl or alkenyl group represented by R ¹ or R ² preferably has a chain length of 6 to 20 from the viewpoint of detergency, and more preferably 6 to
14, more preferably 6-12, particularly preferably 6-11. Further, of the R ¹ and R ² , a linear or branched alkyl group is preferable, a linear alkyl group is particularly preferable, a linear alkyl group having 6 to 14 carbon atoms, further 6 to 12, and particularly 6 to
Eleven linear alkyl groups are preferred. Further, among the cationic surfactants represented by the general formula (1), dialkyl (or alkenyl) dimethyl group in which each of R ¹ and R ² is a linear or branched alkyl or alkenyl group having 6 to 14 carbon atoms. The quaternary ammonium salt is particularly preferably a dialkyl (or alkenyl) dimethyl quaternary ammonium salt which is a linear or branched alkyl or alkenyl group having 6 to 11 carbon atoms. Further, when R ² is a methyl group, R ¹ is preferably a linear or branched alkyltrimethyl quaternary ammonium salt having 6 to 16 carbon atoms, particularly 6 to 11 carbon atoms.

The linear or branched alkyl or alkenyl group represented by R ³ in the general formula (2) preferably has a chain length of 6 to 20, more preferably 6 to 14, and even more preferably 6 -12, particularly preferably 6-11. Also, the relevant R ³
Of these, a linear or branched alkyl group is preferable, a linear alkyl group is particularly preferable, and a carbon number of 6 to 6 is more preferable.
A straight chain alkyl group having 14, more preferably 6 to 12 carbon atoms, and particularly 6 to 11 carbon atoms is preferable.

Further, in the general formula (3), the following general formula (3
Quaternary ammonium salts selected from a) to (3f), and especially quaternary ammonium salts selected from general formulas (3a), (3b) and (3c) are preferable.

[0019]

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[Wherein y and z are numbers 1 to 6,
R ⁴ , R ⁵ , R ⁶ and X are the same as defined above) As the alkyl or alkenyl group of R ^{4 in} the general formula (3), those having 5 to 19 carbon atoms, more preferably 5 to 15, and especially 7 to 11 are preferable. It is preferable from the viewpoint of detergency. Further, among the alkyl group and the alkenyl group, an alkyl group is preferable, and a linear alkyl group is particularly preferable.

R ⁵ represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, and examples of the alkyl group having 1 to 5 carbon atoms include methyl, ethyl, propyl, isopropyl, isobutyl and se.
Examples thereof include c-butyl, t-butyl, and pentyl groups.
A hydrogen atom is particularly preferable as R ⁵ . Examples of the alkyl or alkenyl group for R ⁶ include the same groups as those for R ⁵ , but an alkyl group having 1 to 5 carbon atoms is more preferable, and a methyl group is particularly preferable. Further, examples of the aralkyl group of R ⁶ include benzyl and phenethyl groups, and the benzyl group is particularly preferable. A phenyl group is preferred as the aryl group for R ⁶ . As l 1, l ′, n and n ′, a number of 1 to 3 is preferable, and a number of 1 to 2 is particularly preferable. Further, y is more preferably a number of 1 to 3, and particularly preferably 2.

Of X's which represent counterions of these cationic surfactants, examples of halogen atoms include bromine atom, iodine atom and chlorine atom, and examples of alkyl sulfuric acid residues include methanesulfonic acid and ethanesulfonic acid. Among these, a halogen atom, especially a bromine atom or a chlorine atom is preferable.

<Amphoteric Surfactant> The amphoteric surfactant is not particularly limited, but in the present invention, betaines represented by the following general formulas (4), (5), (6) and (7) are used. 1 type (s) or 2 or more types selected from are mentioned.

[0024]

[Chemical 6]

[In the formula, R ⁷ represents a linear or branched alkyl or alkenyl group having 8 to 22 carbon atoms, and R ⁸ and R ⁹ are the same or different and have 1 carbon atom which may be substituted with a hydroxyl group. ~ 5
It indicates an alkyl group, R ¹⁰ represents a linear or branched alkyl or alkenyl group of 7 to 21 carbon atoms, Y represents a hydrogen atom or a hydroxyl group, r, s, and t is a number from 1 to 3 , U represents a number from 1 to 5, v represents a number of 1 or more, and w
And x represent a number satisfying 0 ≦ w + x ≦ 4]. In the general formula (4), R ⁷ is preferably a saturated alkyl group having 8 to 18 carbon atoms, more preferably a saturated alkyl group having 10 to 16 carbon atoms in terms of detergency. Is preferred. For the same reason, R ⁸ and R ⁹ are preferably a methyl group, an ethyl group or a hydroxyethyl group, and r is preferably 1.

In the general formula (5), R ⁷ is preferably a saturated alkyl group having 8 to 18 carbon atoms, and more preferably a saturated alkyl group having 10 to 16 carbon atoms, from the viewpoint of detergency. For the same reason, it is preferable that R ⁸ and R ⁹ are each a methyl group, an ethyl group or a hydroxyethyl group, s is 1 and t is 1.

In the amidobetaine type amphoteric surfactants (6) and (7) used in the present invention, R ¹⁰ is preferably a saturated alkyl group having 9 to 15 carbon atoms from the viewpoint of detergency. For the same reason, R ⁸ and R ⁹ are each a methyl, ethyl or hydroxyethyl group, u is 2 or 3, v is 1 and w is 1,
x is preferably 1. Specific examples of these include alkylamidopropyl-N, N-dimethylacetate betaine, alkylamidopropyl-N, N-dimethyl-2-hydroxypropylsulfobetaine, alkylamidopropyl-N, N
-Dimethyl-propylsulfobetaine, etc., but in terms of detergency and foaming power, amidopropyl laurate-N, N-dimethylacetate betaine, myristic acid amidopropyl-N, N-dimethylacetate betaine, cocamide Amidopropyl-N, N-dimethyl betaine, hydroxysulfobetaine, amide laurate-N, N-
Dimethyl-2-hydroxypropyl betaine and the like are preferable.

<Nonionic Surfactant> The nonionic surfactant used in the present invention is not particularly limited, but may be polyoxyethylene alkyl or alkenyl ethers, polyoxyethylene alkylphenyl ethers, polyoxypropylene alkyl. Or alkenyl ethers, polyoxybutylene alkyl or alkenyl ethers,
Alkylene oxide addition alkyl group or alkenyl group-containing nonionic surfactant mixture, sucrose fatty acid esters, aliphatic alkanolamides, fatty acid glycerin monoesters, amine oxides, ethylene oxide condensed surfactants and alkyl glycosides One or more selected from the above are preferable. More specific examples of such nonionic surfactants include the following (1) to (11).

(1) Polyoxyethylene alkyl or alkenyl ethers in which the alkyl group or the alkenyl group has an average carbon number of 10 to 20 and the ethylene oxide addition mole number is 1 to 30 moles on average. .

(2) Polyoxyethylene alkylphenyl ethers having an alkyl group having an average carbon number of 6 to 12
And the number of moles of ethylene oxide added is 1 to 1 on average.
What is 25 moles.

(3) Polyoxypropylene alkyl or alkenyl ethers in which the alkyl group or alkenyl group has an average carbon number of 10 to 20 and the propylene oxide addition mole number is 1 to 20 moles on average. .

(4) Polyoxybutylene alkyl or alkenyl ethers, wherein the alkyl group or alkenyl group has an average carbon number of 10 to 20, and the butylene oxide addition mole number is 1 to 20 moles on average. .

(5) having an alkyl group or an alkenyl group,
Ethylene oxide and propylene oxide (molar ratio:
0.1 / 9.9 to 9.9 / 0.1) or ethylene oxide and butylene oxide (molar ratio: 0.1 / 9.9 to 9.9 / 0.
1) is added to the nonionic surfactant mixture, wherein the alkyl group or alkenyl group has an average carbon number of 10 to
It is 20, and the number of moles of alkylene oxide added per molecule is 1 to 30 moles on average.

(6) A higher fatty acid alkanolamide represented by the following general formula (8) or an alkylene oxide adduct thereof.

[0035]

[Chemical 7]

[In the formula, R ¹¹ is an alkyl group or an alkenyl group having 10 to 20 carbon atoms, R ¹² and R ¹³ are the same or different and are H or CH ₃ , p is a number of 1 to 3, and q is Is a number from 0 to 3. (7) Sucrose fatty acid esters whose fatty acid moiety has an average carbon number of 10 to 20.

(8) Fatty acid glycerin monoesters having an average carbon number of the fatty acid portion of 10 to 20.

(9) Amine oxides. For example, carbon number 1
And alkyl or alkenylamine oxides having up to 24 linear or branched alkyl or alkenyl groups. More preferable amine oxides include alkylamine oxides represented by the following general formula (9).

[0039]

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In the above general formula (9), R ¹⁴ has 8 carbon atoms.
It is an alkyl group or alkenyl group having from 24 to 24, preferably an alkyl group having 12 to 18 carbon atoms. R ¹⁵ and R ¹⁶ are each an alkyl group having 1 to 3 carbon atoms, and a methyl group having 1 carbon atom is particularly preferable.

(10) A nonionic surfactant having a trade name of "Pluronic" (Asahi Denka Co., Ltd.) obtained by condensing ethylene oxide.

(11) Alkyl polysaccharides. For example, an alkyl polysaccharide represented by the following general formula (10).

R ¹⁷ (OR ¹⁸ ) _x G _y (10) [wherein R ¹⁷ represents a linear or branched alkyl group having 8 to 18 carbon atoms, an alkenyl group or an alkylphenyl group, and R ¹⁸ Represents an alkylene group having 2 to 4 carbon atoms, G
Is a residue derived from a reducing sugar having 5 to 6 carbon atoms.
x (average value) is 0 to 5 and y (average value) is 1 to 5. The alkyl glycoside represented by the general formula (10) will be further described. In the formula, the average value of x is from 0 to 5, but by changing this value, the cleaning for hard surfaces used in the present invention can be performed. The water solubility and crystallinity of the agent composition can be adjusted. That is, the larger the value of x, the higher the water solubility and the lower the crystallinity. The preferred value of x is 0
To 2, and particularly preferably 0. On the other hand, when the average value of y is greater than 1, that is, when a sugar chain of two or more saccharides is used as a hydrophilic group, the bonding mode of sugar chains is 1-2, 1-
It is possible to include any mixture having 3, 1-4, 1-6 linkages, as well as α-, β-pyranoside linkages or furanoside linkages and mixed modes of binding thereof.
Further, the average value of y in the general formula (10) is 1 to 5, preferably 1 to 1.5, and more preferably 1.1 to 1.4. The measured value of y is based on the proton NMR method. Further, R ¹⁷ in the formula is preferably an alkyl group having 10 to 14 carbon atoms from the viewpoint of solubility and detergency. R ¹⁸ is preferably an alkylene group having 2 to 3 carbon atoms from the viewpoint of water solubility. Further, the structure of G is determined by a raw material of monosaccharide or disaccharide or more. Examples of the raw material of G include glucose, fructose, galactose, xylose, mannose, lyxose, arabinose, and mixtures thereof in monosaccharides. Examples of disaccharides include maltose, xylobiose, isomaltose, cellobiose, gentibiose, lactose, sucrose, nigerose, turanose, raffinose, gentianose, melezitose, and mixtures thereof. Among these, preferred raw materials are, in view of their availability and cost,
Monosaccharides are glucose and fructose, and disaccharides and more are maltose and sucrose. Of these, glucose is particularly preferable from the viewpoint of easy availability. Furthermore,
1 mol adduct of pentaerythritol / isostearyl glycidyl ether, 1 mol adduct of sorbitol / isostearyl glycidyl ether, mannitol 2-
1 mol adduct of octyldodecylglycidyl ether,
1 mol adduct of methyl glucoside / isostearyl glycidyl ether, 1 mol adduct of diglycerin / isostearyl glycidyl ether, at least one long-chain branched alkyl group or alkenyl group and at least 3 Non-ionic surfactants having a single hydroxyl group. Among these nonionic surfactants, (1), (6), (9) and (11) are preferable, and (9) and (11) are particularly preferable.

<Anionic Surfactant> The anionic surfactant used in the present invention is not particularly limited but includes the following.

(1) Alkylbenzene sulfonates having a straight or branched chain alkyl group having an average carbon number of the alkyl group of 8-18.

(2) Anionic surfactants having a polyoxyalkylene group, which are polyoxyalkylene alkyl ether sulfates, polyoxyalkylene alkenyl ether sulfates, polyoxyalkylene alkylaryl ether sulfates, polyoxyalkylene alkenyl aryls. Ether sulfate, polyoxyalkylene mono- or di-alkyl ether phosphate, polyoxyalkylene mono- or di-alkenyl ether phosphate, polyoxyalkylene mono- or diphenyl ether phosphate,
Polyoxyalkylene alkyl ether carboxylate,
Polyoxyalkylene alkenyl ether carboxylate, polyoxyalkylene alkyl ether acetate, polyoxyalkylene alkenyl ether acetate, polyoxyalkylene alkyl amide ether carboxylate,
Polyoxyalkylene alkenyl amide ether carboxylate, etc.

The alkyl or alkenyl group in these anionic surfactants preferably has 4 to 26 carbon atoms, more preferably 8 to 24 carbon atoms. Further, these alkyl or alkenyl groups may be linear or branched. Further, examples of the polyoxyalkylene group in the anionic surfactant include polyoxyethylene, polyoxypropylene, and polyoxybutylene groups, and polyoxyethylene group and / or polyoxypropylene group are particularly preferable. Further, the number of added moles of the polyoxyalkylene group is preferably 1 to 20, particularly preferably 1 to 10. Furthermore,
Examples of the salt in the anionic surfactant include alkali metal salts such as sodium and potassium, alkaline earth metal salts such as calcium and magnesium, ammonium salts, and alkanolamine salts such as mono-, di- or tri-ethanolamine. To be

(3) An alkyl or alkenyl sulfate having an average carbon number of 8 to 20 in the alkyl or alkenyl group.
Stuff. (4) Olefin sulfonates having an average of 10 to 20 carbon atoms. (5) Alkanesulfonates having an average of 10 to 20 carbon atoms. (6) Saturated or unsaturated fatty acid salts having an average of 10 to 24 carbon atoms.

(7) α-sulfo fatty acid salts or α-sulfo fatty acid esters represented by the following general formula (11)

[0050]

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[In the formula, Y is an alkyl group having 1 to 3 carbon atoms or a counter ion, and Z is a counter ion. R ¹⁹ has 10 to 20 carbon atoms
Represents an alkyl group or an alkenyl group. Examples of the counter ion of the anionic surfactant include alkali metal ions such as sodium and potassium.

(8) A diphenyl ether disulfonic acid type anionic surfactant represented by the general formula (12).

[0053]

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[In the formula, R ²⁰ and R ²¹ represent a linear or branched alkyl or alkenyl group having 6 to 22 carbon atoms or a hydrogen atom (provided that both R ²⁰ and R ²¹ are hydrogen atoms). , M and M'are hydrogen atom, alkali metal,
An ammonium group or an alkanol-substituted ammonium group is shown. ].

Among these anionic surfactants (2)
And (8) are preferred in terms of cleaning performance. As described above, the surfactant which is the component (B) of the present invention acts synergistically as a detergency enhancer for the component (A), and among them, a cationic surfactant and an amphoteric surfactant were used. In some cases, the synergistic effect is great. Further, in the present invention, when a cationic surfactant and an amphoteric surfactant are used, by further blending an anionic surfactant, an organic / inorganic composite soil represented by various fats and oils in a house is further reduced. Significant detergency can be provided. The molar ratio of one or more selected from cationic surfactants and amphoteric surfactants to anionic surfactants is from 1/9 to
9/1, preferably 3/7 to 7/3,
More preferably, it is set to 4/6 to 6/4.

Usually, when a cationic surfactant and an anionic surfactant are used in combination, a complex is formed, so that precipitation is likely to occur and there is a problem in storage stability, but a polyoxyalkylene group is contained as an anionic surfactant. The use of a compound having a plurality of hydrophilic groups weakens the formation of the complex and improves the solubility of the complex, which is advantageous not only in storage stability but also in cleaning power and finish after cleaning. It is advantageous in terms of (less traces of wiping).

Specifically, (2) and (8) in the above examples of the anionic surfactant are preferable, and (2) is particularly preferable.

Among (2), polyoxyalkylene alkyl ether sulfate, polyoxyalkylene alkenyl ether sulfate, polyoxyalkylene alkyl ether acetate, polyoxyalkylene alkenyl ether acetate, polyoxyalkylene alkyl amide ether carboxylate And polyoxyalkylene alkenyl amide ether carboxylates are particularly preferred.

Examples of the polyoxyalkylene alkyl amide ether carboxylate or polyoxyalkylene alkenyl amide ether carboxylate include the amide ether carboxylates represented by the following general formula (13).

[0060]

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[Wherein, R ²² represents a linear or branched alkyl group or alkenyl group having 5 to 21 carbon atoms, and x and y each have an average degree of polymerization of 0 to 20 satisfying 1 ≦ x + y ≦ 20. Where A is (C ₂ H ₄ O) _k (C ₃ H ₅ O) _j CH ₂ COOM ^' , (C ₂ H ₄ O) _k (C
₃ H ₆ O) _j CH ₂ CH ₂ OH, a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, k and j each represent an average degree of polymerization of 0 to 20 satisfying 0 ≦ k + j ≦ 20, and M And M'represents an alkali metal, alkaline earth metal, ammonium or alkanolammonium. In addition, the amide ether carboxylate may contain a small amount of a compound not having -CH ₂ COOM added to the general formula (13), which is a production intermediate. Mixtures may be used.

Specific examples of more preferable anionic surfactants include polyoxyethylene (EO = 1 to 10) C ₈ to ₂₄
Alkyl ether sulfate, polyoxyethylene (EO =
1~10) C ₈ ~ ₂₄ alkyl ether acetates, polyoxyethylene _{(EO = 1~10) C 8 ~} 24 alkyl ether carboxylic acid salts.

The water-soluble solvent which is the component (C) of the present invention is
It becomes a detergency enhancer for components (A) and (B), and (A)
By including it as a component, it is possible to reduce the residue of wiping residue after cleaning with the cleaning composition.

The component (C) used in the present invention is not particularly limited as long as it is a water-soluble solvent, but the following (1) to (5)
One or more compounds selected from the above compounds are preferable.

(1) Monohydric alcohol having 1 to 5 carbon atoms (2) Polyhydric alcohol having 4 to 12 carbon atoms (3) Compound represented by the following general formula (14) (4) The following general formula ( Compound represented by 15) (5) Compound represented by the following general formula (16)

[0066]

[Chemical 12]

[In the formula, R ²³ and R ²⁴ each represent a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, a phenyl group or a benzyl group, and when both R ²³ and R ²⁴ are hydrogen atoms, except. m represents a number from 0 to 10 and n represents a number from 0 to 10, except when both m and n are 0. R ²⁵ and R
²⁶ represents an alkyl group having 1 to 3 carbon atoms. R ²⁷ represents an alkyl group having 1 to 3 carbon atoms. The monohydric alcohol having 2 to 5 carbon atoms of (1) generally includes ethanol, propyl alcohol and isopropyl alcohol. By blending these lower alcohols, the stability of the system at low temperatures can be further improved.

Examples of the polyhydric alcohol having 2 to 12 carbon atoms of (2) include isoprene glycol, 2,2,4-trimethyl-1,
3-pentanediol, 1,8-octanediol, 1,9
-Nonanediol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, glycerin and the like.

The compound of the formula (3) is the compound of the formula (14)
^{When 23} and R ²⁴ are alkyl groups, the number of carbon atoms is particularly preferably 1 to 4. Further, in the general formula (14), m and n of the average addition mole number of ethylene oxide (EO) and propylene oxide (PO) are each a number of 0 to 10, and the addition order of these is particularly It is not limited and may be randomly added. Specific examples of the compound of (3), ethylene glycol monobutyl ether,
Dipropylene glycol dimethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, propylene glycol monomethyl ether, propylene glycol monobutyl ether,
Propylene glycol monoethyl ether, propylene glycol dimethyl ether, polyoxyethylene (p
= 2 to 3) polyoxypropylene (p = 2 to 3) glycol dimethyl ether (p represents the average number of moles added),
Examples thereof include polyoxyethylene (p = 3) glycol phenyl ether, phenyl carbitol, phenyl cellosolve, and benzyl carbitol. Of these, from the viewpoints of detergency and feeling of use, propylene glycol monomethyl ether, diethylene glycol monobutyl ether,
Polyoxyethylene (p = 1-4) glycol phenyl ether is preferred.

Further, as the compound of (4), 1,3-dimethyl-2-imidazolidinone and 1,3-diethyl-2-imidazolidinone are exemplified as preferable compounds, and as the compound of (5), Is 3-methoxy-3-methylbutanol, 3
-Ethoxy-3-methylbutanol and the like are preferable.

Considering the damage to a plastic substrate such as ABS in the interior of a house, ethanol, isopropyl alcohol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, glycerin, isoprene glycol, propylene are used. A water-soluble solvent having a high affinity with water and a high vapor pressure, such as glycol monomethyl ether or propylene glycol monoethyl ether, is used.

The detergent composition for hard surfaces of the present invention has the above-mentioned composition.
It is composed of the components (A), (B) and (C), and satisfies all of the detergency, finishability (there are few traces of wiping off after washing) and long-term storage stability. It is not possible to achieve all of these effects even if only one component is removed. Further, the hard surface cleaner composition of the present invention further comprises (A)
The effects of the present invention can be improved by blending the components, the component (B) and the component (C) in specific proportions.

The component (A) is 0.1 to 30% by weight, preferably 0.5 to 20% by weight, particularly preferably 1 to 20% by weight based on the total amount of the composition.
It is contained by weight%. If the content of the component (A) is less than 0.1% by weight, sufficient detergency cannot be obtained, and even if it exceeds 30% by weight, detergency and finish are better (less wiping traces after cleaning). It cannot be expected to improve.

The component (B) is 0.1 to 30% by weight, preferably 0.5 to 20% by weight, particularly preferably 1 to 20% by weight based on the total amount of the composition.
It is contained by weight%. If the content of component (B) is less than 0.1% by weight, sufficient detergency cannot be obtained, and if it exceeds 30% by weight, no further improvement in detergency can be expected, and conversely finishability (Less wiping trace after cleaning) is impaired, which is not preferable.

Further, the component (C) is contained in an amount of 0.1 to 50 in the total amount of the composition.
% By weight, preferably 1 to 30% by weight, particularly preferably 1 to
If the content of the component (C) is less than 0.1% by weight and the content of the component (C) is less than 0.1% by weight, sufficient detergency cannot be obtained. Even if the content of the component (C) exceeds 50% by weight, further detergency cannot be expected.

Further, the combination of the component (B) and the component (C) (B) / (C)
Is 5/1 to 1/50 by weight ratio, but is preferably 3/1 to 1/15. If this ratio exceeds 5/1 or less than 1/50, a synergistic cleaning effect with the component (A) cannot be sufficiently obtained, which is not preferable.

In addition to the above components, the hard surface cleaner composition of the present invention may further contain an alkali agent (0.1 to 15% by weight) such as an alkanolamine, a thickener, a pigment, a colorant, and a fragrance, if necessary. , Bactericides, preservatives and the like can be added within a range that does not impair the effects of the present invention.

The hard surface cleaning composition of the present invention is produced by mixing the above-mentioned components according to a conventional method.
H is preferably in the range of 3 to 12, more preferably in the range of 5 to 12, and particularly preferably in the range of 6 to 11. The composition of the present invention is suitable as a cleaning agent for various stains on various hard surfaces around a house made of tile, ceramic, enamel, reinforced plastic (FRP), stainless steel, wood and the like.

[0079]

The present invention will be described in more detail with reference to the following examples, which should not be construed as limiting the invention thereto.

Examples 1 to 35 and Comparative Examples 1 to 4 Cleaning composition containing the components shown in Tables 1 to 4
The test shown below was performed. The results are shown in Tables 1 to 4.

Soap residue stain detergency test The detergency of an unwashed polypropylene bath tub used under the same conditions for half a year was evaluated as follows. The cloth containing the detergent composition was brought into close contact with the stain for 5 minutes, and the state of removal of the stain after rubbing with a sponge was visually evaluated according to the following 5 grades. The numbers shown in the table are average values of 5 times. 5: Very good stain removal 4: Good stain removal 3: Uneven stain removal 2: Slight stain removal 1: Almost no stain removal

Test for Detergency of Toilet Inside Toilet The cleaning power to the inorganic / organic composite stain inside the flush toilet bowl which is not removed by rubbing with a brush was evaluated as follows. A certain amount of the detergent composition was sprinkled on the stain, and the state of removal of the stain after rubbing with a brush was visually evaluated as follows. ◎ Good ○ Somewhat good △ Somewhat bad × Bad

Storage stability test (colorability) The cleaning composition was placed in a polypropylene container and sealed,
Stored at 40 ° C for 3 months. The appearance after storage was judged by comparing with the appearance before storage. ◯: No problem in appearance Coloring: Coloring is clearly observed compared to before storage.

Compounds 1 to 11 in Tables 1 to 4 are as follows. Compound 1 In the general formula (I), R is CH ₃ and M
Alkylglycine-N, N-diacetic acid or a salt thereof in which is Na Compound 2 In the general formula (I), R is C ₂ H ₅ and M is
Alkylglycine-N, N-diacetic acid or a salt thereof in which is Na In the general formula (I), R is C ₉ H ₁₉ ,
Alkylglycine-N, N-diacetic acid or a salt thereof in which M is Na

[0085]

Embedded image

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[Table 1]

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[Table 2]

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[Table 3]

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[Table 4]

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Claims (5)

[Claims] 1. (A) 0.1-30% by weight of alkylglycine-N, N-diacetic acid represented by the following general formula (I) or a salt thereof, (B) 0.1-30% by weight of a surfactant, and (C) Contains 0.1 to 50% by weight of water-soluble solvent, the ratio of the content of component (B) and the content of component (C)
A cleaning composition for hard surfaces, wherein the weight ratio of (B) / (C) is 5/1 to 1/50. Embedded image (In the formula, R represents an alkyl group or an alkenyl group having 1 to 18 carbon atoms, and M represents H, Na, K or NH ₄ ) 2. The cleaning composition for hard surfaces according to claim 1, wherein the component (B) is one or more selected from cationic surfactants and amphoteric surfactants. 3. The hard surface cleaning agent according to claim 2, wherein the cationic surfactant is a quaternary ammonium salt type cationic surfactant, and the amphoteric surfactant is an amphoteric surfactant selected from betaines. Composition. 4. The hard surface cleaner composition according to claim 2, further comprising an anionic surfactant as the component (B). 5. The detergent composition for hard surfaces according to claim 4, wherein the anionic surfactant is an anionic surfactant having a polyoxyalkylene group.