CN110184133A - A kind of liquid detergent that can allow clothing long-acting bacteriostatic - Google Patents

A kind of liquid detergent that can allow clothing long-acting bacteriostatic Download PDF

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Publication number
CN110184133A
CN110184133A CN201910539044.4A CN201910539044A CN110184133A CN 110184133 A CN110184133 A CN 110184133A CN 201910539044 A CN201910539044 A CN 201910539044A CN 110184133 A CN110184133 A CN 110184133A
Authority
CN
China
Prior art keywords
long
liquid detergent
acting bacteriostatic
acting
clothing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910539044.4A
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Chinese (zh)
Inventor
林兴
陈梅
代灿
周国鹏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangzhou Yingfuke Chemical Co Ltd
Original Assignee
Guangzhou Yingfuke Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangzhou Yingfuke Chemical Co Ltd filed Critical Guangzhou Yingfuke Chemical Co Ltd
Priority to CN201910539044.4A priority Critical patent/CN110184133A/en
Publication of CN110184133A publication Critical patent/CN110184133A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/825Mixtures of compounds all of which are non-ionic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/662Carbohydrates or derivatives
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols

Abstract

The invention discloses a kind of liquid detergents that can allow clothing long-acting bacteriostatic, and wherein the liquid detergent includes principal surfactant, antipathogenic composition and other components.Principal surfactant includes the alkyl glycosides of the fatty alcohol polyoxyethylene ether AEO-9 and 3-15% of the fatty alcohol polyoxyethylene ether AEO-7 and 3-20% of 3-20% and the cocoanut fatty acid diethanolamide of 2-10%.Antipathogenic composition includes the long-acting bacteriostatic agent of 0.1-3%, and long-acting bacteriostatic agent is cation quaternary ammonium salt.Other components include the deionized water of the citric acid of 0.05-0.1% and the essence of 0.3-0.6% and 0.1-0.2% preservative and 70-80%.The present invention, which has, can allow the liquid detergent of clothing long-acting bacteriostatic, and clothing can be made still to keep excellent fungistatic effect after washing.

Description

A kind of liquid detergent that can allow clothing long-acting bacteriostatic
Technical field
It is the invention belongs to wash clean field, in particular to a kind of applied to can allow clothing long-acting bacteriostatic in household clothes washing Liquid detergent.
Background technique
Liquid detergent has the characteristic and ease of use mild to skin and is widely used.With consumer to health, Health, cleaning are increasingly paid attention to, and liquid detergent is also higher and higher in addition to having the additional function of washing to require.And for antibacterial The liquid detergent of bacteria resistance function is one of important development direction, it is desirable that liquid detergent not only can achieve the purpose of fabric cleaning, but also Various bacteriums, fungi and fungus growth can be effectively inhibited within the regular hour and under moist hot environment.Currently, city The many enterprises in face all fall over each other to release antibacterial bacteriostatic liquid detergent, but the lacking there is the following with regard to its existing formula or method Fall into: (1) the antibacterial bacteriostatic liquid detergent of commercial type is using addition triclosan or to chloro-m-xylene mostly at present The broad spectrum antimicrobial agents such as phenol carry out antibacterial bacteriostatic, however for triclosan and parachlorometaxylenol because having irritation gas Taste has certain toxicity, unfriendly to environment and human body and eliminated gradually by industry.(2) commercial type is washed at present Clothing liquid is the sterilizing ability emphasized in laundering process, however is dried in the air in the environment of hot humid after having ignored clothes washing Whether there is bacteriostasis during dry and placement, this is only what consumer to be really concerned about in fact.If one clean Clothes dry be easy to grow bacterium in placement process if, even if being washed in washing process clean again, sterilize it is thorough again, Also antibacterial purpose is not achieved.But the effect detection of general bacteriostasis antibiosis liquid detergent is also quantitative using conventional suspension Method, this method under certain effect concentration and action time, mix, then take mixed liquor primarily directed to liquid detergent with test bacteria suspension Bacteria Culture is carried out, obtains antibiotic rate or bacteriostasis rate by counting clump count.Specifically see the disinfection technology standard (Ministry of Public Health Version in 2002) second part (2.1.1.9) suspension quantitative method.Therefore suspension quantitative method can only confirm the sterilization energy in washing process Power can not confirm clothing drying and in placement process, keep good antibacterial or fungistatic effect after washing.Therefore one is found A liquid detergent that can make to have good antibacterial and fungistatic effect in the placement process of clothing after washing, and experiment can be used Method is confirmed that this is only the current technical issues that need to address in this field.
Summary of the invention
In view of the above problems, the purpose of the present invention is to provide a kind of liquid detergent that can allow clothing long-acting bacteriostatic, can make Clothing still keeps excellent fungistatic effect after washing.
To achieve the above object, a kind of liquid detergent that can allow clothing long-acting bacteriostatic provided by the invention, the wherein liquid detergent Including principal surfactant, antipathogenic composition and other components;Principal surfactant includes 9% fatty alcohol polyoxyethylene ether (AEO-7) and 6% fatty alcohol polyoxyethylene ether (AEO-9) and 5% alkyl glycosides and 3% coco-nut oil fatty acid diethyl Alkylolamides;Antipathogenic composition includes 0.5% long-acting bacteriostatic agent;Long-acting bacteriostatic agent is cation quaternary ammonium salt;Other components include 0.1% citric acid and 0.3% essence and 0.2% preservative and 75.9% deionized water.
Another object is to provide a kind of manufacture craft of liquid detergent that can allow clothing long-acting bacteriostatic, wherein the manufacture craft Specific step is as follows: Step 1: injecting the deionized water of 70-80% in a mixing bowl, primary surfactant rouge being added later Fat alcohol polyoxyethylene ether, alkyl glycosides, cocoanut fatty acid diethanolamide, are sufficiently stirred dispersion;Step 2: by cationic season Ammonium salt long-acting bacteriostatic agent is added in the cylinder after above-mentioned steps one are sufficiently stirred, and continues to stir evenly;Step 3: other components are added In a mixing bowl for entering above-mentioned steps two, got product after adjusting PH=7-8.
The invention has the advantages that due to primary surfactant formula with fatty alcohol polyoxyethylene ether, alkyl glycosides and Based on cocoanut fatty acid diethanolamide, such liquid detergent can satisfy the requirement of decontamination.In addition, long-acting bacteriostatic agent be sun from Sub- quaternary ammonium salt, it is not only very friendly to environment, it is non-toxic to humans, meet pursuit of the consumer for health;And sun from Sub- quaternary ammonium salt has wide fungicidal spectrum, is in gram-positive bacterium and negative bacteria, mould, fungi saccharomycete, algae etc. Existing brilliant antibacterial effect;Namely cation quaternary ammonium salt can be in conjunction with clothing, and clothing stores under sunning or wet condition When be also able to suppress bacteria breed, realize the purpose of long-term effect antibacterial bacteriostatic.
Specific embodiment
Invention is described in further detail below.
Embodiment 1
A kind of liquid detergent that can allow clothing long-acting bacteriostatic, wherein the liquid detergent includes principal surfactant, antipathogenic composition With other components;Principal surfactant includes 9% fatty alcohol polyoxyethylene ether (AEO-7) and 6% fatty alcohol polyoxy second Alkene ether (AEO-9) and 5% alkyl glycosides and 3% cocoanut fatty acid diethanolamide;Antipathogenic composition includes 0.5% Long-acting bacteriostatic agent;Long-acting bacteriostatic agent is cation quaternary ammonium salt;Other components include 0.1% citric acid and 0.3% essence, and 0.2% preservative and 75.9% deionized water.
A kind of manufacture craft for the liquid detergent that can allow clothing long-acting bacteriostatic, which is characterized in that the specific step of the manufacture craft It is rapid as follows: Step 1: injecting the deionized water of 70-80% in a mixing bowl, primary surfactant fatty alcohol polyoxy being added later Dispersion is sufficiently stirred in vinethene, alkyl glycosides, cocoanut fatty acid diethanolamide;Step 2: cation quaternary ammonium salt is long-acting Bacteriostatic agent is added in the cylinder after above-mentioned steps one are sufficiently stirred, and continues to stir evenly;Step 3: above-mentioned step is added in other components In rapid two a mixing bowl, got product after adjusting PH=7-8.
This effect has passed through the detection certification of microbiological analysis inspection center, Guangdong Province, please refers to the 6th point of test result. This formula can detect the effect of antibacterial bacteriostatic with simulation.Simulation is to be washed by simulating the laundry processes of washing machine to detect The antibacterial or fungistatic effect of the dry goods cleaning product such as clothing liquid.Simulation is that microbiological contamination is made in a part of cotton after sterilizing to carry Body, then together with remaining cloth, using being washed under the activity of sample liquid detergent and action time, by bacterial carrier after washing It takes out, produces dilution under prescribed conditions, take out dilution inoculation TSB plate and carry out Bacteria Culture, finally observation culture Clump count on ware, to obtain antibacterial or bacteriostasis rate.Specifically see professional standard QB/T2738-2012/7.4 antibacterial or suppression Bacterial type dry goods detergent antibacterial or the fungistatic effect method of inspection (simulation).
Embodiment 2
A kind of liquid detergent that can allow clothing long-acting bacteriostatic, wherein the liquid detergent includes principal surfactant, antipathogenic composition With other components;Principal surfactant includes 9% fatty alcohol polyoxyethylene ether (AEO-7) and 6% fatty alcohol polyoxy second Alkene ether (AEO-9) and 5% alkyl glycosides and 3% cocoanut fatty acid diethanolamide;Antipathogenic composition includes 2% length Imitate bacteriostatic agent;Long-acting bacteriostatic agent is cation quaternary ammonium salt;Other components include 0.1% citric acid and 0.3% essence, and 0.2% preservative and 74.4% deionized water.
A kind of manufacture craft for the liquid detergent that can allow clothing long-acting bacteriostatic, which is characterized in that the specific step of the manufacture craft It is rapid as follows: Step 1: injecting the deionized water of 70-80% in a mixing bowl, primary surfactant fatty alcohol polyoxy being added later Dispersion is sufficiently stirred in vinethene, alkyl glycosides, cocoanut fatty acid diethanolamide;Step 2: cation quaternary ammonium salt is long-acting Bacteriostatic agent is added in the cylinder after above-mentioned steps one are sufficiently stirred, and continues to stir evenly;Step 3: above-mentioned step is added in other components In rapid two a mixing bowl, got product after adjusting PH=7-8.
To prove long-acting bacteriostatic effect of this formula on clothing, this liquid detergent sample being formulated is given to Guangdong Province microorganism Analysis detection Spot detection, detection method are washed according to professional standard QB/T2738-2012/7.4 antibacterial or antibacterial type dry goods Agent antibacterial or the fungistatic effect method of inspection (simulation) are tested, activity 1:100, action time 20m i n.
1 detection data of example:
2 detection data of example:
Data summary table:
Above two different laundry liquid formulation, is knitted according to professional standard QB/T2738-2012/7.4 antibacterial or antibacterial type The test result of species detergent antibacterial or the fungistatic effect method of inspection (simulation) all shows to have good antibacterial and antibacterial Ability.
Above-described is only some embodiments of the present invention.For those of ordinary skill in the art, not Under the premise of being detached from the invention design, various modifications and improvements can be made, these belong to the protection scope of invention.

Claims (2)

1. a kind of liquid detergent that can allow clothing long-acting bacteriostatic, wherein the liquid detergent include principal surfactant, antipathogenic composition and Other components;
The principal surfactant includes the fatty alcohol polyoxy of the fatty alcohol polyoxyethylene ether AEO-7 and 3-20% of 3-20% The alkyl glycosides of vinethene AEO-9 and 3-15% and the cocoanut fatty acid diethanolamide of 2-10%;
The antipathogenic composition includes the long-acting bacteriostatic agent of 0.1-3%;The long-acting bacteriostatic agent is cation quaternary ammonium salt;
Other components include the citric acid of 0.05-0.1% and the essence of 0.3-0.6% and 0.1-0.2% preservative and The deionized water of 70-80%.
2. a kind of manufacture craft of liquid detergent that can allow clothing long-acting bacteriostatic according to claim 1, which is characterized in that should Specific step is as follows for manufacture craft:
Step 1: injecting the deionized water of 70-80% in a mixing bowl, primary surfactant aliphatic alcohol polyethenoxy is added later Dispersion is sufficiently stirred in ether, alkyl glycosides, cocoanut fatty acid diethanolamide;
Step 2: cation quaternary ammonium salt long-acting bacteriostatic agent is added in the cylinder after above-mentioned steps one are sufficiently stirred, it is equal to continue stirring It is even;
Step 3: other components are added in a mixing bowl of above-mentioned steps two, got product after adjusting PH=7-8.
CN201910539044.4A 2019-06-20 2019-06-20 A kind of liquid detergent that can allow clothing long-acting bacteriostatic Pending CN110184133A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112753708A (en) * 2020-12-25 2021-05-07 宁波子沐新材料科技有限公司 Long-acting antibacterial composition and application thereof in laundry detergent
CN113528250A (en) * 2021-07-23 2021-10-22 孟庆峰 Antibacterial laundry detergent and preparation method thereof
CN114085719A (en) * 2021-11-29 2022-02-25 烟台三生生物科技有限公司 Lasting antibacterial laundry detergent and preparation method thereof
CN114958491A (en) * 2022-06-22 2022-08-30 浙江工业大学 Detergent with antibacterial effect

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109706000A (en) * 2018-12-26 2019-05-03 深圳市北岳海威化工有限公司 A kind of long acting antibiotic liquid detergent and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109706000A (en) * 2018-12-26 2019-05-03 深圳市北岳海威化工有限公司 A kind of long acting antibiotic liquid detergent and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112753708A (en) * 2020-12-25 2021-05-07 宁波子沐新材料科技有限公司 Long-acting antibacterial composition and application thereof in laundry detergent
CN113528250A (en) * 2021-07-23 2021-10-22 孟庆峰 Antibacterial laundry detergent and preparation method thereof
CN113528250B (en) * 2021-07-23 2022-08-12 孟庆峰 Antibacterial laundry detergent and preparation method thereof
CN114085719A (en) * 2021-11-29 2022-02-25 烟台三生生物科技有限公司 Lasting antibacterial laundry detergent and preparation method thereof
CN114958491A (en) * 2022-06-22 2022-08-30 浙江工业大学 Detergent with antibacterial effect

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Application publication date: 20190830

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