CN107955743A - A kind of high-effect liquid laundry detergent and preparation method thereof - Google Patents
A kind of high-effect liquid laundry detergent and preparation method thereof Download PDFInfo
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- CN107955743A CN107955743A CN201711071725.XA CN201711071725A CN107955743A CN 107955743 A CN107955743 A CN 107955743A CN 201711071725 A CN201711071725 A CN 201711071725A CN 107955743 A CN107955743 A CN 107955743A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Abstract
The invention belongs to daily chemicals field, and in particular to a kind of high-effect liquid laundry detergent and preparation method thereof.High-effect liquid laundry detergent provided by the invention includes following components and its mass percent：Mass concentration is 70% sodium sulfate of polyethenoxy ether of fatty alcohol 5~20%, linear alkyl benzene sulfonic acid 3~15%, fatty alcohol polyoxyethylene ether 3~6%, mass concentration is 35% cocamidopropyl betaine 3~8%, mass concentration is 17% potassium laurate aqueous solution 3~10%, mass concentration is 5% oleic acid aqueous solutions of potassium 3~10%, sodium hydroxide 1~10%, complex enzyme 0.1~2%, preservative 0.05~0.2%, disodium ethylene diamine tetraacetate 0.1~0.5%, citric acid 0.05~0.5%, sodium chloride 0.5~3%, essence 0.15~0.5%, surplus is deionized water.High-effect liquid laundry detergent that the present invention supplies is antibacterial, dirt-removing power is strong, energy- and time-economizing, and low bubble water-saving is environmentally friendly.
Description
Technical field
The invention belongs to daily chemicals field, and in particular to a kind of high-effect liquid laundry detergent and preparation method thereof.
Background technology
Wear the clothes, be the big fundamental of human lives, from ancient times to the present, the cleaning of clothing is always that people's daily life is non-
An often important part.With the raising of modern life quality, laundry is also constantly being carried with the performance requirement of daily chemicals
Rise, the most commonly used laundry in the past is washing powder with daily chemicals, and washing powder has preferable decontamination cleaning effect, but does washing
Powder frequently appears in insufficient situation is dissolved in water when in use, one that clothing can be influenced as a kind of powder detergent
Washing effect, two washing powder to fail fully to dissolve in part can cause washing powder concentration in regional area excessive so that should
The alkalescence in region is very big, and clothing can be caused to damage, and three carry out washing powder since the easily redeposition containing many solid additives is on clothing
Fabric is set to harden, meanwhile, washing powder is stronger to the irritation of skin, easily injures the skin of washer's hand.In China, with
The raising of living standards of the people, consumer are increasingly favored in using the good liquid detergent of dissolubility.Relative to washing powder, liquid detergent
There is gentle, soluble, low energy consumption.Liquid detergent is started late in China, and the shared market share is also very low, but liquid detergent
Market is always maintained at growing at top speed recent years.
Chinese patent application CN103805367A discloses a kind of high-efficiency bactericidal liquid detergent, includes the group of following parts by weight
Point：0.5~6 part of traditional Chinese medicine bactericide, 6~31 parts of anion surfactant, 12~43 parts of nonionic surfactant, thickener
And 0.06~1 part of other auxiliary agents, 40~60 parts of deionized water；The preparation method of the traditional Chinese medicine bactericide is as follows：The Chinese mugwort of weight will be waited
Leaf, sweet wormwood, scutellaria, granatum, perilla leaf mixing decoct, and filtering, filtrate is concentrated into 1~1.5g/mL, autoclaving, to obtain the final product.Should
Invention contains traditional Chinese medicine bactericide, and it is needed through decocting, concentration step, and preparation process is more complicated, and is needed when preparing liquid detergent
Heat.
Chinese patent application CN104479893A discloses a kind of high-effective cleansing liquid detergent, its composition weight proportioning is：15
~20% surfactant, 2~5% acid additive, 0.2~0.6% piece alkali, 0.3~0.5% fungicide, 0.3~
0.5% chelating agent, 0.4~0.6% fluorescent whitening agent, 0.2~0.4% preservative, 1~2% thickener, 1~2%
Anti redeposition agent, 0.2~0.4% Rosemary Oil, 0.5~1% fixastive, 2~4% Tea Saponin, surplus is goes
Ionized water.Contain triclosan in fungicide in the invention, long-time service may be unfavorable to health, for example causes more resistance to
Medicine bacterium, or cause hormone disturbance.
At present, with the diversification of people life style, the spot encountered in life also becomes increasingly complex, existing common
Liquid detergent be increasingly difficult to meet consumer demand.Secondly, environmental problem increasingly attracts attention, and saves, is environmentally friendly, efficiently
Gradually the theme of Green Home life is become.And still lack a kind of do not adding the situation of extra fungicide in the prior art
Under, still with good restraining and sterilizing bacteria and dirt-removing functions, preparation process is simple, reduces production cost, is environmental-friendly, efficiently washing
Clothing liquid.
The content of the invention
In view of the deficiencies of the prior art, it is an object of the invention to provide a kind of high-effect liquid laundry detergent and preparation method thereof.This
The high-effect liquid laundry detergent that invention supplies uses a variety of surfactant compounds, in the case where not adding extra fungicide, reaches and removes
Bacterium effect, has good restraining and sterilizing bacteria and dirt-removing functions, easily biological-degradable is safe, pollution-free.In production, the present invention is high
When imitating liquid detergent, it need to only compound at room temperature, so as to enormously simplify liquid detergent production technology, energy- and time-economizing, saves life
Produce cost.In addition, the low bubble water-saving of high-effect liquid laundry detergent that the present invention supplies, environmentally friendly, it is a kind of laundry of efficiently friendly health
Product.
The technical scheme is that：
A kind of high-effect liquid laundry detergent, including following components and its mass percent：
Mass concentration be 70% sodium sulfate of polyethenoxy ether of fatty alcohol 5~20%, linear alkyl benzene sulfonic acid 3~15%,
Fatty alcohol polyoxyethylene ether 3~6%, mass concentration are 35% cocamidopropyl betaine 3~8%, and mass concentration is
17% potassium laurate aqueous solution 3~10%, mass concentration be 5% oleic acid aqueous solutions of potassium 3~10%, sodium hydroxide 1~
10%, complex enzyme 0.1~2%, preservative 0.05~0.2%, disodium ethylene diamine tetraacetate 0.1~0.5%, citric acid 0.05~
0.5%, sodium chloride 0.5~3%, essence 0.15~0.5%, surplus is deionized water.
Further, the high-effect liquid laundry detergent is made of following components and its mass percent：
Mass concentration be 70% sodium sulfate of polyethenoxy ether of fatty alcohol 10%, linear alkyl benzene sulfonic acid 5%, poly alkyl alcohol
Ethylene oxide ether 4%, mass concentration are 35% cocamidopropyl betaine 5%, and mass concentration is 17% potassium laurate
Aqueous solution 6%, mass concentration be 5% oleic acid aqueous solutions of potassium 6%, sodium hydroxide 2%, complex enzyme 0.5%, preservative 0.1%,
Disodium ethylene diamine tetraacetate 0.1%, citric acid 0.1%, sodium chloride 1.5%, essence 0.35% and deionized water 59.35%.
Further, the complex enzyme is by protease, lipase, amylase and cellulase 4-7 in mass ratio:2-4:4-
6:1-3 is formed.
Further, the complex enzyme is by protease, lipase, amylase and cellulase in mass ratio 5:3:5:2
Composition.
Further, the protease is microencapsulation protease.
Further, the preparation method of the microencapsulation protease is：
(1) the Arabic gum aqueous solution that mass concentration is 2%, Arabic gum aqueous solution and protease are added into protease
Mass ratio be 5:1, obtain Arabic gum-protein enzyme solution；
(2) chitosan is dissolved in the acetic acid aqueous solution that mass concentration is 6%, is configured to the shell that mass concentration is 1.2%
Glycan acetic acid solution, adds calcium chloride, and the addition of calcium chloride is the 1/10 of above-mentioned chitosan mass, stirring to being completely dissolved,
Obtain chitosan-calcium chloride solution；
(3) chitosan obtained by step (2)-calcium chloride solution is added into Arabic gum-protein enzyme solution obtained by step (1)
In, the mass ratio of chitosan calcium chloride solution and Arabic gum-protein enzyme solution is 1:5, stir evenly, obtain mixed liquor；
(4) mixed liquor obtained by step (3) dry, pulverize, to obtain the final product.
Further, the preservative by 5-Chloro-2-methyl-4-isothiazolin-3-one and 2- methyl -4- isothiazolines -
3- ketone 3-5 in mass ratio:8-10 is formed.
Further, the preservative is by 5-Chloro-2-methyl-4-isothiazolin-3-one and 2- methyl -4- isothiazole
Quinoline -3- ketone in mass ratio 4:9 compositions.
In addition, present invention also offers the preparation method of the high-effect liquid laundry detergent, comprise the following steps：
S1 takes the deionized water of gross mass 95%, adds linear alkyl benzene sulfonic acid and sodium hydroxide is pre-neutralized, question response
Disodium ethylene diamine tetraacetate, sodium sulfate of polyethenoxy ether of fatty alcohol, fatty alcohol polyoxyethylene ether, coconut oleoyl amine are sequentially added completely
Base propyl betaine, potassium laurate aqueous solution, oleic acid aqueous solutions of potassium, stir to being completely dissolved, obtain homogeneous system；
Complex enzyme, preservative, citric acid, sodium chloride, essence are added in homogeneous system obtained by S2 to step S1, is stirred to body
System is uniform, adds the ionized water of surplus, stirs evenly and adjusts pH to 7.5~8.5, to obtain the final product.
Further, the step S2, which is stirred evenly, adjusts pH to 8.0.
At present, with people life style diversification, the spot encountered in life also becomes increasingly complex, and goes stain
Difficulty is also increasing, and existing common liquid detergent is increasingly difficult to meet consumer demand.Complexity based on spot, this hair
It is bright that overall detergency is lifted using complex enzyme.Complex enzyme is pressed by four kinds of protease, lipase, amylase and cellulase enzymes
Certain mass is formed than compounding, achievees the purpose that a variety of enzyme components act on the different substrates of spot at the same time, and can produce more
Efficient excellent collaboration clean effect.Complex enzyme in the present invention can effectively remove protide, starch, grease type spot,
Cotton fiber is acted at the same time, has the redeposition of anti-stain, removes ball top, safeguards the functions such as fabric color.It is in addition, of the invention by albumen
Enzyme has carried out microencapsulation, is allowed to isolate with other enzymes, and has good compatibility, keeps the stability of compound enzyme system,
To ensure the vigor of complex enzyme, while making products obtained therefrom that there is excellent dirt-removing power, and make product efficient stable.
At present, the liquid detergent kind with sterilizing function is more, still, adds the components such as triclosan, triclocarban mostly,
Long-time service may be unfavorable to health, for example causes more drug-fast bacterias, or causes hormone disturbance etc..The present inventor is unexpected
Discovery, by using a variety of surfactant compounds, compatibility is good, and has good synergistic function, not only
System surface tension can be significantly reduced, strengthens the dirt-removing power of complex enzyme, while the sterilizing ability of higher can be inspired,
In the case of not adding extra fungicide, reach degerming effect, while low bubble water-saving, it is environmentally friendly, it is a kind of efficiently friend
The laundry product of good health.
Compared with prior art, the present invention has the advantage that：
(1) the low bubble water-saving of high-effect liquid laundry detergent provided by the invention, it is environmentally friendly, it is a kind of laundry of efficiently friendly health
Product.
(2) high-effect liquid laundry detergent that the present invention supplies uses a variety of surfactant compounds, is not adding extra fungicide
In the case of, reach degerming effect, there is good restraining and sterilizing bacteria and dirt-removing functions, easily biological-degradable is safe, pollution-free.
(3) the preparation method technological operation for the high-effect liquid laundry detergent that the present invention supplies is simple, it is easy to accomplish industrialized production.
(4) high-effect liquid laundry detergent that the present invention supplies is non-stimulated, will not leave behind basic residual after washing, will not cause skin allergy etc.
Symptom, there will not be fabric damage.
(5) when producing high-effect liquid laundry detergent of the present invention, need to only compound at room temperature, so as to enormously simplify liquid detergent
Production technology, energy- and time-economizing, saves production cost.
Embodiment
Below by way of the description of embodiment, the invention will be further described, but this is not the limit to the present invention
System, those skilled in the art's basic thought according to the present invention, various modifications may be made or improves, but without departing from this
The basic thought of invention, within the scope of the present invention.
In the present invention, the mass concentration of sodium sulfate of polyethenoxy ether of fatty alcohol is 70%, No. CAS：9004-82-4；Straight chain
Alkyl benzene sulphonate：No. CAS：42615-29-2；Fatty alcohol polyoxyethylene ether：No. CAS：68131-39-5；Cocamidopropyl
The mass concentration of glycine betaine be 35%, No. CAS：61789-40-0；Protease is purchased from the limited public affairs of Shanghai Dan Niyue biotechnologies
Department, model：DENYCLEAN PRO-03L；Lipase is purchased from Shanghai Dan Niyue bio tech ltd, model：
DENYCLEAN LIP-1A；Amylase is purchased from Shanghai Dan Niyue bio tech ltd, model：DENYCLEAN AMSL；
Cellulase is purchased from Shanghai Dan Niyue bio tech ltd, model：DENYCLEAN 80L.
Embodiment 1, a kind of high-effect liquid laundry detergent
The high-effect liquid laundry detergent is made of following components and its mass percent：
Mass concentration be 70% sodium sulfate of polyethenoxy ether of fatty alcohol 5%, linear alkyl benzene sulfonic acid 3%, poly alkyl alcohol
Ethylene oxide ether 3%, mass concentration are 35% cocamidopropyl betaine 3%, and mass concentration is 17% potassium laurate
Aqueous solution 3%, mass concentration be 5% oleic acid aqueous solutions of potassium 3%, sodium hydroxide 1%, complex enzyme 0.1%, preservative
0.05%, disodium ethylene diamine tetraacetate 0.1%, citric acid 0.05%, sodium chloride 0.5%, essence 0.15% and deionized water
78.05%；The preservative presses quality by 5-Chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one
Than 3:10 compositions.
The complex enzyme is by protease, lipase, amylase and cellulase in mass ratio 4:4:6:3 compositions.
The protease is microencapsulation protease.
The preparation method of the microencapsulation protease is：
(1) the Arabic gum aqueous solution that mass concentration is 2%, Arabic gum aqueous solution and protease are added into protease
Mass ratio be 5:1, obtain Arabic gum-protein enzyme solution；
(2) chitosan is dissolved in the acetic acid aqueous solution that mass concentration is 6%, is configured to the shell that mass concentration is 1.2%
Glycan acetic acid solution, adds calcium chloride, and the addition of calcium chloride is the 1/10 of above-mentioned chitosan mass, stirring to being completely dissolved,
Obtain chitosan-calcium chloride solution；
(3) chitosan obtained by step (2)-calcium chloride solution is added into Arabic gum-protein enzyme solution obtained by step (1)
In, the mass ratio of chitosan calcium chloride solution and Arabic gum-protein enzyme solution is 1:5, stir evenly, obtain mixed liquor；
(4) mixed liquor obtained by step (3) dry, pulverize, to obtain the final product.
The preparation method of the high-effect liquid laundry detergent, comprises the following steps：
S1 takes the deionized water of gross mass 95%, adds linear alkyl benzene sulfonic acid and sodium hydroxide is pre-neutralized, question response
Disodium ethylene diamine tetraacetate, sodium sulfate of polyethenoxy ether of fatty alcohol, fatty alcohol polyoxyethylene ether, coconut oleoyl amine are sequentially added completely
Base propyl betaine, potassium laurate aqueous solution, oleic acid aqueous solutions of potassium, stir to being completely dissolved, obtain homogeneous system；
Complex enzyme, preservative, citric acid, sodium chloride, essence are added in homogeneous system obtained by S2 to step S1, is stirred to body
System is uniform, adds the ionized water of surplus, stirs evenly and adjusts pH to 7.5, to obtain the final product.
Embodiment 2, a kind of high-effect liquid laundry detergent
The high-effect liquid laundry detergent is made of following components and its mass percent：
Mass concentration be 70% sodium sulfate of polyethenoxy ether of fatty alcohol 20%, linear alkyl benzene sulfonic acid 15%, fatty alcohol
Polyoxyethylene ether 6%, mass concentration are 35% cocamidopropyl betaine 8%, and mass concentration is 17% laurate
Aqueous solutions of potassium 10%, mass concentration be 5% oleic acid aqueous solutions of potassium 10%, sodium hydroxide 10%, complex enzyme 2%, preservative
0.2%, disodium ethylene diamine tetraacetate 0.5%, citric acid 0.5%, sodium chloride 3%, essence 0.5% and deionized water 14.3%；
The preservative is by 5-Chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one 3-5 in mass ratio:8-
10 compositions.
The complex enzyme is by protease, lipase, amylase and cellulase in mass ratio 7:2:4:1 composition.
The protease is microencapsulation protease.
The preparation method of the microencapsulation protease is：
(1) the Arabic gum aqueous solution that mass concentration is 2%, Arabic gum aqueous solution and protease are added into protease
Mass ratio be 5:1, obtain Arabic gum-protein enzyme solution；
(2) chitosan is dissolved in the acetic acid aqueous solution that mass concentration is 6%, is configured to the shell that mass concentration is 1.2%
Glycan acetic acid solution, adds calcium chloride, and the addition of calcium chloride is the 1/10 of above-mentioned chitosan mass, stirring to being completely dissolved,
Obtain chitosan-calcium chloride solution；
(3) chitosan obtained by step (2)-calcium chloride solution is added into Arabic gum-protein enzyme solution obtained by step (1)
In, the mass ratio of chitosan calcium chloride solution and Arabic gum-protein enzyme solution is 1:5, stir evenly, obtain mixed liquor；
(4) mixed liquor obtained by step (3) dry, pulverize, to obtain the final product.
The preparation method of the high-effect liquid laundry detergent, comprises the following steps：
S1 takes the deionized water of gross mass 95%, adds linear alkyl benzene sulfonic acid and sodium hydroxide is pre-neutralized, question response
Disodium ethylene diamine tetraacetate, sodium sulfate of polyethenoxy ether of fatty alcohol, fatty alcohol polyoxyethylene ether, coconut oleoyl amine are sequentially added completely
Base propyl betaine, potassium laurate aqueous solution, oleic acid aqueous solutions of potassium, stir to being completely dissolved, obtain homogeneous system；
Complex enzyme, preservative, citric acid, sodium chloride, essence are added in homogeneous system obtained by S2 to step S1, is stirred to body
System is uniform, adds the ionized water of surplus, stirs evenly and adjusts pH to 8.5, to obtain the final product.
Embodiment 3, a kind of high-effect liquid laundry detergent
The high-effect liquid laundry detergent is made of following components and its mass percent：
Mass concentration be 70% sodium sulfate of polyethenoxy ether of fatty alcohol 10%, linear alkyl benzene sulfonic acid 5%, poly alkyl alcohol
Ethylene oxide ether 4%, mass concentration are 35% cocamidopropyl betaine 5%, and mass concentration is 17% potassium laurate
Aqueous solution 6%, mass concentration be 5% oleic acid aqueous solutions of potassium 6%, sodium hydroxide 2%, complex enzyme 0.5%, preservative 0.1%,
Disodium ethylene diamine tetraacetate 0.1%, citric acid 0.1%, sodium chloride 1.5%, essence 0.35% and deionized water 59.35%；Institute
Preservative is stated by 5-Chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one in mass ratio 4:9 compositions.
The complex enzyme is by protease, lipase, amylase and cellulase in mass ratio 5:3:5:2 compositions.
The protease is microencapsulation protease.
The preparation method of the microencapsulation protease is：
(1) the Arabic gum aqueous solution that mass concentration is 2%, Arabic gum aqueous solution and protease are added into protease
Mass ratio be 5:1, obtain Arabic gum-protein enzyme solution；
(2) chitosan is dissolved in the acetic acid aqueous solution that mass concentration is 6%, is configured to the shell that mass concentration is 1.2%
Glycan acetic acid solution, adds calcium chloride, and the addition of calcium chloride is the 1/10 of above-mentioned chitosan mass, stirring to being completely dissolved,
Obtain chitosan-calcium chloride solution；
(3) chitosan obtained by step (2)-calcium chloride solution is added into Arabic gum-protein enzyme solution obtained by step (1)
In, the mass ratio of chitosan calcium chloride solution and Arabic gum-protein enzyme solution is 1:5, stir evenly, obtain mixed liquor；
(4) mixed liquor obtained by step (3) dry, pulverize, to obtain the final product.
The preparation method of the high-effect liquid laundry detergent, comprises the following steps：
S1 takes the deionized water of gross mass 95%, adds linear alkyl benzene sulfonic acid and sodium hydroxide is pre-neutralized, question response
Disodium ethylene diamine tetraacetate, sodium sulfate of polyethenoxy ether of fatty alcohol, fatty alcohol polyoxyethylene ether, coconut oleoyl amine are sequentially added completely
Base propyl betaine, potassium laurate aqueous solution, oleic acid aqueous solutions of potassium, stir to being completely dissolved, obtain homogeneous system；
Complex enzyme, preservative, citric acid, sodium chloride, essence are added in homogeneous system obtained by S2 to step S1, is stirred to body
System is uniform, adds the ionized water of surplus, stirs evenly and adjusts pH to 8.0, to obtain the final product.
Comparative example 1, a kind of high-effect liquid laundry detergent
The high-effect liquid laundry detergent is made of following components and its mass percent：
Mass concentration be 70% sodium sulfate of polyethenoxy ether of fatty alcohol 10%, linear alkyl benzene sulfonic acid 5%, poly alkyl alcohol
Ethylene oxide ether 4%, mass concentration are 35% cocamidopropyl betaine 5%, and mass concentration is 17% potassium laurate
Aqueous solution 12%, sodium hydroxide 2%, complex enzyme 0.5%, preservative 0.1%, disodium ethylene diamine tetraacetate 0.1%, citric acid
0.1%, sodium chloride 1.5%, essence 0.35% and deionized water 59.35%；The preservative is by the different thiophenes of 5- chloro-2-methyls -4-
Oxazoline -3- ketone and 2-methyl-4-isothiazolin-3-one in mass ratio 4:9 compositions.
The complex enzyme is by protease, lipase, amylase and cellulase in mass ratio 5:3:5:2 compositions.
The protease is microencapsulation protease.
The microencapsulation protease, the preparation method of high-effect liquid laundry detergent are similar to Example 3.
Difference lies in become the mass percent for the oleic acid aqueous solutions of potassium that mass concentration is 5% by 6% with embodiment 3
For 0, the mass percent for the potassium laurate aqueous solution that mass concentration is 17% is changed into 12% from 6%.
Comparative example 2, a kind of high-effect liquid laundry detergent
The high-effect liquid laundry detergent is made of following components and its mass percent：
Mass concentration be 70% sodium sulfate of polyethenoxy ether of fatty alcohol 10%, linear alkyl benzene sulfonic acid 5%, poly alkyl alcohol
Ethylene oxide ether 4%, mass concentration are 35% cocamidopropyl betaine 5%, and mass concentration is 17% potassium stearate
Aqueous solution 6%, mass concentration be 5% oleic acid aqueous solutions of potassium 6%, sodium hydroxide 2%, complex enzyme 0.5%, preservative 0.1%,
Disodium ethylene diamine tetraacetate 0.1%, citric acid 0.1%, sodium chloride 1.5%, essence 0.35% and deionized water 59.35%；Institute
Preservative is stated by 5-Chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one in mass ratio 4:9 compositions.
The complex enzyme is by protease, lipase, amylase and cellulase in mass ratio 5:3:5:2 compositions.
The protease is microencapsulation protease.
The microencapsulation protease, the preparation method of high-effect liquid laundry detergent are similar to Example 3.
Difference lies in the potassium laurate aqueous solution that mass concentration is 17% is changed to mass concentration is with embodiment 3
17% potassium stearate aqueous solution, mass percent 6%.
Comparative example 3, a kind of high-effect liquid laundry detergent
The high-effect liquid laundry detergent is made of following components and its mass percent：
Mass concentration be 70% sodium sulfate of polyethenoxy ether of fatty alcohol 10%, linear alkyl benzene sulfonic acid 5%, poly alkyl alcohol
Ethylene oxide ether 4%, mass concentration are 35% cocamidopropyl betaine 5%, and mass concentration is 17% potassium laurate
Aqueous solution 6%, mass concentration be 5% oleic acid aqueous solutions of potassium 6%, sodium hydroxide 2%, complex enzyme 0.5%, preservative 0.1%,
Disodium ethylene diamine tetraacetate 0.1%, citric acid 0.1%, sodium chloride 1.5%, essence 0.35% and deionized water 59.35%；Institute
Preservative is stated by 5-Chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one in mass ratio 4:9 compositions.
The complex enzyme is by protease, lipase, amylase and cellulase in mass ratio 1:1:1:1 composition.
The protease is microencapsulation protease.
The microencapsulation protease, the preparation method of high-effect liquid laundry detergent are similar to Example 3.
Difference lies in the mixed enzyme presses quality by protease, lipase, amylase and cellulase with embodiment 3
Than 1:1:1:1 composition.
Comparative example 4, a kind of high-effect liquid laundry detergent
The high-effect liquid laundry detergent is made of following components and its mass percent：
Mass concentration be 70% sodium sulfate of polyethenoxy ether of fatty alcohol 10%, linear alkyl benzene sulfonic acid 5%, poly alkyl alcohol
Ethylene oxide ether 4%, mass concentration are 35% cocamidopropyl betaine 5%, and mass concentration is 17% potassium laurate
Aqueous solution 6%, mass concentration be 5% oleic acid aqueous solutions of potassium 6%, sodium hydroxide 2%, complex enzyme 0.5%, preservative 0.1%,
Disodium ethylene diamine tetraacetate 0.1%, citric acid 0.1%, sodium chloride 1.5%, essence 0.35% and deionized water 59.35%；Institute
Preservative is stated by 5-Chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one in mass ratio 4:9 compositions.
The complex enzyme is by protease, lipase, amylase and cellulase in mass ratio 5:3:5:2 compositions.
The preparation method of the high-effect liquid laundry detergent is similar to Example 3.
Difference lies in the complex enzyme presses quality by protease, lipase, amylase and cellulase with embodiment 3
Than 5:3:5:2 compositions.
Comparative example 5, a kind of high-effect liquid laundry detergent
The high-effect liquid laundry detergent is made of following components and its mass percent：
Mass concentration be 70% sodium sulfate of polyethenoxy ether of fatty alcohol 10%, linear alkyl benzene sulfonic acid 5%, poly alkyl alcohol
Ethylene oxide ether 4%, mass concentration are 35% cocamidopropyl betaine 5%, and mass concentration is 17% potassium laurate
Aqueous solution 6%, mass concentration be 5% oleic acid aqueous solutions of potassium 6%, sodium hydroxide 2%, complex enzyme 0.5%, preservative 0.1%,
Disodium ethylene diamine tetraacetate 0.1%, citric acid 0.1%, sodium chloride 1.5%, essence 0.35% and deionized water 59.35%；Institute
Preservative is stated by 5-Chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one in mass ratio 4:9 compositions.
The complex enzyme is by protease, lipase, amylase and cellulase in mass ratio 5:3:5:2 compositions.
The protease is microencapsulation protease.
The microencapsulation protease, the preparation method of high-effect liquid laundry detergent are similar to Example 3.
Difference lies in the preparation of microencapsulation protease, step (2) does not add calcium chloride with embodiment 3.
Comparative example 6, a kind of high-effect liquid laundry detergent
The high-effect liquid laundry detergent is made of following components and its mass percent：
Mass concentration be 70% sodium sulfate of polyethenoxy ether of fatty alcohol 12%, linear alkyl benzene sulfonic acid 6%, mass concentration
For 35% cocamidopropyl betaine 6%, mass concentration is 17% potassium laurate aqueous solution 6%, and mass concentration is
5% oleic acid aqueous solutions of potassium 6%, sodium hydroxide 2%, complex enzyme 0.5%, preservative 0.1%, disodium ethylene diamine tetraacetate
0.1%, citric acid 0.1%, sodium chloride 1.5%, essence 0.35% and deionized water 59.35%；The preservative is by the chloro- 2- of 5-
Methyl -4- isothiazoline -3- ketone and 2-methyl-4-isothiazolin-3-one in mass ratio 4:9 compositions.
The complex enzyme is by protease, lipase, amylase and cellulase in mass ratio 5:3:5:2 compositions.
The protease is microencapsulation protease.
The microencapsulation protease, the preparation method of high-effect liquid laundry detergent are similar to Example 3.
With embodiment 3 difference lies in, the mass percent of fatty alcohol polyoxyethylene ether is changed into 0 from 4%, quality is dense
The mass percent for spending the sodium sulfate of polyethenoxy ether of fatty alcohol for 70% is changed into 12% from 10%, by linear alkyl benzene sulfonic acid
Mass percent is changed into 6% from 5%, by mass concentration be 35% cocamidopropyl betaine mass percent by
5% is changed into 6%.
Comparative example 7, a kind of high-effect liquid laundry detergent
The high-effect liquid laundry detergent is made of following components and its mass percent：
Mass concentration be 70% sodium sulfate of polyethenoxy ether of fatty alcohol 10%, alkyl glycosides 5%, aliphatic alcohol polyethenoxy
Ether 4%, mass concentration are 35% cocamidopropyl betaine 5%, and mass concentration is 30% potassium laurate aqueous solution
6%, mass concentration be 5% oleic acid aqueous solutions of potassium 6%, sodium hydroxide 2%, complex enzyme 0.5%, preservative 0.1%, ethylenediamine
Tetraacethyl disodium 0.1%, citric acid 0.1%, sodium chloride 1.5%, essence 0.35% and deionized water 59.35%；The anti-corrosion
Agent is by 5-Chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one in mass ratio 4:9 compositions.
The complex enzyme is by protease, lipase, amylase and cellulase in mass ratio 5:3:5:2 compositions.
The protease is microencapsulation protease.
The microencapsulation protease, the preparation method of high-effect liquid laundry detergent are similar to Example 3.
Difference lies in be changed to alkyl glycosides, mass percent 5% by linear alkyl benzene sulfonic acid with embodiment 3.
The test of test example one, foaming properties
1st, test material：High-effect liquid laundry detergent prepared by embodiment 1, embodiment 2, embodiment 3, comparative example 1 and comparative example 2.
2nd, test method：With reference to standard GB/T/T13173.6-1991《Measure (the Ross-Miles of detergent foaming power
Method)》Carry out foam test.Using Roche foam meter, record initial foam height and stand foam height after five minutes.
3rd, result of the test
Result of the test is as shown in table 1.
Table 1：The foaming properties of high-effect liquid laundry detergent
| Sample | Initial foam height/mm | Foam height/mm after five minutes |
| Embodiment 1 | 97 | 28 |
| Embodiment 2 | 100 | 32 |
| Embodiment 3 | 95 | 25 |
| Comparative example 1 | 112 | 95 |
| Comparative example 2 | 110 | 88 |
| Standard liquid detergent | 120 | 115 |
As shown in Table 1, compared with standard liquid detergent, high-effect liquid laundry detergent foam height produced by the present invention is low, and defoams soon,
The foam height of wherein embodiment 3 is minimum, is highly preferred embodiment of the present invention；Compared with comparative example 1, comparative example 2, embodiment 3
Performance it is more superior.
Test example two, detergency experiment
1st, test specimen：High-effect liquid laundry detergent prepared by embodiment 3, comparative example 3, comparative example 4, comparative example 5 and comparative example 6.
2nd, test method：With reference to standard GB/T/T13174-2008《Dress material detergent detergency and circulation washing performance
The measure of energy》Detergency test is carried out, wherein EMPA117 is bloodstain, milk stain, the mixing soiled cotton of sweat stain, and CFTC-S-28 is rice
Starch soiled cotton.Sample 2 for 37 DEG C place 4 weeks after sample.
3rd, result of the test
Result of the test is as shown in table 2.
Table 2：The detergency test result of high-effect liquid laundry detergent
The test result of table 2 is shown, compared with comparative example 3, comparative example 4, comparative example 5 and comparative example 6, the embodiment of the present invention
High-effect liquid laundry detergent made from 3 has good go to carbon black soiled cotton, albumen soiled cotton, sebum soiled cotton, EMPA117 and CFTC-S-28
Dirty effect, and 37 DEG C place 4 weeks after sample still there is good clean effect, this illustrates product produced by the present invention with excellent
Different dirt-removing power, and product efficient stable.
Test example three, bacteriostatic test
1st, test material：High-effect liquid laundry detergent prepared by embodiment 3, comparative example 6 and comparative example 7.
2nd, test method：According to QB/T2738-2012《The evaluation method of daily chemical products antibacterial bacteriostatic effect》Carry out antibacterial
Experiment, experimental strain are staphylococcus aureus, extension rate 1：100, test action time is 20 minutes.
3rd, result of the test：
Result of the test is as shown in table 3.
Table 3：The bacteriostasis rate of high-effect liquid laundry detergent
| Test material | Bacteriostasis rate (%) |
| Embodiment 3 | 99.99 |
| Comparative example 6 | 90.72 |
| Comparative example 7 | 92.46 |
As shown in Table 3, compared with comparative example 6 and comparative example 7, high-effect liquid laundry detergent foam made from the embodiment of the present invention 3 has
There is more superior fungistatic effect.
Claims (9)
1. a kind of high-effect liquid laundry detergent, it is characterised in that including following components and its mass percent：
Mass concentration is 70% sodium sulfate of polyethenoxy ether of fatty alcohol 5~20%, and linear alkyl benzene sulfonic acid 3~15% is fatty
Alcohol polyoxyethylene ether 3~6%, mass concentration be 35% cocamidopropyl betaine 3~8%, mass concentration 17%
Potassium laurate aqueous solution 3~10%, mass concentration is 5% oleic acid aqueous solutions of potassium 3~10%, and sodium hydroxide 1~10% is multiple
Synthase 0.1~2%, preservative 0.05~0.2%, disodium ethylene diamine tetraacetate 0.1~0.5%, citric acid 0.05~0.5%,
Sodium chloride 0.5~3%, essence 0.15~0.5%, surplus are deionized water.
2. high-effect liquid laundry detergent according to claim 1, it is characterised in that be made of following components and its mass percent：
Mass concentration be 70% sodium sulfate of polyethenoxy ether of fatty alcohol 10%, linear alkyl benzene sulfonic acid 5%, fatty alcohol polyoxy second
Alkene ether 4%, mass concentration are 35% cocamidopropyl betaine 5%, and the potassium laurate that mass concentration is 17% is water-soluble
Liquid 6%, mass concentration be 5% oleic acid aqueous solutions of potassium 6%, sodium hydroxide 2%, complex enzyme 0.5%, preservative 0.1%, second two
Amine tetraacethyl disodium 0.1%, citric acid 0.1%, sodium chloride 1.5%, essence 0.35% and deionized water 59.35%.
3. high-effect liquid laundry detergent according to claim 1 or 2, it is characterised in that the complex enzyme by protease, lipase,
Amylase and cellulase 4-7 in mass ratio:2-4:4-6:1-3 is formed.
4. high-effect liquid laundry detergent according to claim 3, it is characterised in that the complex enzyme is by protease, lipase, starch
Enzyme and cellulase in mass ratio 5:3:5:2 compositions.
5. high-effect liquid laundry detergent according to claim 3, it is characterised in that the protease is microencapsulation protease.
6. high-effect liquid laundry detergent according to claim 5, it is characterised in that the preparation method of the microencapsulation protease
For：
(1) matter of the Arabic gum aqueous solution that mass concentration is 2%, Arabic gum aqueous solution and protease is added into protease
Amount is than being 5:1, obtain Arabic gum-protein enzyme solution；
(2) chitosan is dissolved in the acetic acid aqueous solution that mass concentration is 6%, is configured to the chitosan that mass concentration is 1.2%
Acetic acid solution, adds calcium chloride, and the addition of calcium chloride is the 1/10 of above-mentioned chitosan mass, stirs to being completely dissolved, obtains shell
Glycan-calcium chloride solution；
(3) chitosan obtained by step (2)-calcium chloride solution is added in Arabic gum-protein enzyme solution obtained by step (1), shell
The mass ratio of glycan calcium chloride solution and Arabic gum-protein enzyme solution is 1:5, stir evenly, obtain mixed liquor；
(4) mixed liquor obtained by step (3) dry, pulverize, to obtain the final product.
7. high-effect liquid laundry detergent according to claim 1 or 2, it is characterised in that the preservative is by 5- chloro-2-methyls -4-
Isothiazoline -3- ketone and 2-methyl-4-isothiazolin-3-one 3-5 in mass ratio:8-10 is formed.
8. high-effect liquid laundry detergent according to claim 7, it is characterised in that the preservative is by the different thiophenes of 5- chloro-2-methyls -4-
Oxazoline -3- ketone and 2-methyl-4-isothiazolin-3-one in mass ratio 4:9 compositions.
9. according to the preparation method of claim 1-8 any one of them high-effect liquid laundry detergents, it is characterised in that including following step
Suddenly：
S1 takes the deionized water of gross mass 95%, adds linear alkyl benzene sulfonic acid and sodium hydroxide is pre-neutralized, question response is complete
Sequentially add disodium ethylene diamine tetraacetate, sodium sulfate of polyethenoxy ether of fatty alcohol, fatty alcohol polyoxyethylene ether, cocamidopropyl third
Base glycine betaine, potassium laurate aqueous solution, oleic acid aqueous solutions of potassium, stir to being completely dissolved, obtain homogeneous system；
Complex enzyme, preservative, citric acid, sodium chloride, essence are added in homogeneous system obtained by S2 to step S1, is stirred equal to system
It is even, add the ionized water of surplus, stir evenly and adjust pH to 7.5~8.5, to obtain the final product.
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| CN114292712A (en) * | 2021-12-22 | 2022-04-08 | 上海中溶科技有限公司 | Detergent with antibacterial, odor-resistant and softening functions and preparation method thereof |
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