CN110016390A - A kind of liquid detergent and preparation method thereof removing formaldehyde - Google Patents
A kind of liquid detergent and preparation method thereof removing formaldehyde Download PDFInfo
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- CN110016390A CN110016390A CN201910453769.1A CN201910453769A CN110016390A CN 110016390 A CN110016390 A CN 110016390A CN 201910453769 A CN201910453769 A CN 201910453769A CN 110016390 A CN110016390 A CN 110016390A
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- liquid detergent
- extracting solution
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to a kind of liquid detergents and preparation method thereof for removing formaldehyde, it is prepared by the raw material of weights score: alkali protease: 10 to 15 parts, 10 to 20 parts of zeolite powder, and diatomite in powder: 5 to 10 parts, 1 to 5 part of stabilizer, 10 to 20 parts of asparagus juice, 1 to 5 part of essence, 10 to 20 parts of gleditsia sinensis extracting solution, 20 to 30 parts of orange peel extracting solution, 1 to 5 part of preservative, 10 to 15 parts of sodium alkyl benzene sulfonate, surplus is water；Product formula is mildly non-stimulated, can not only play the role of preferable cleaning effect, can also play preferable sterilization, except formaldehyde, alkali protease is used in product formula, has the characteristic of nonionic and anion surface active concurrently, is easily rinsed, anti- dilution capacity is strong, has an antibacterial, the multi-efficiencies such as submissive, bleaching, strong detergency being capable of deep layer cleaning substrate, both there is good environment-friendly and green ecological safety activity, there is multifunction surface active again, safe green is environmentally friendly, will not pollute environment.
Description
Technical field
The present invention relates to chemical fields, and in particular to a kind of liquid detergent and preparation method thereof for removing formaldehyde.
Background technique
The working principle of liquid detergent and traditional washing powder, soap kind is same, and effective component is all surfactant.Difference exists
In traditional washing powder, soap using anionic surfactant, be based on the sodium alkyl sulfonate and odium stearate,
Alkalinity is stronger, and then larger to the stimulation of skin and injury when in use.And liquid detergent mostly uses nonionic surface active agent,
PH is mild to skin close to neutrality, and after being discharged into nature, degrades fast compared with washing powder, so becoming the washing of a new generation
Agent.The effective component of liquid detergent is mainly nonionic surface active agent, and structure includes water-wet side and hydrophobic end, wherein oleophylic
Then end separates spot and fabric by physical motion in conjunction with spot.Surfactant reduces the tension of water simultaneously, makes water
Fabric surface can be reached, effective component is made to play a role.
Formaldehyde is a kind of slow poisoning drug, and the textile containing formaldehyde can be released gradually during wearing,
By with human respiratory tract and skin contact, the inflammation of respiratory tract and skin can be caused, can also to eyes generate stimulation.In clothes
Contained formaldehyde is to the very harmful of human body.Formaldehyde is mainly used for dyeing assistant in fibre and improves wrinkle resistant anti-
The resin finishing agent of contracting effect.Especially formaldehyde phenomenon is generally existing in children's garment and infant clothing fabric.Formaldehyde contains
Amount, general per kilogram clothes are no more than 20 milligrams.Expert points out that the harmful substance in textile is mainly formaldehyde, it is mainly deposited
It is in the programs such as the processing to pure cotton textile, processing and dyeing.If the clothes that the textile for wearing formaldehyde is made into,
Respiratory tract and skin will be damaged, induce respiratory inflammation and skin disease.Using cleaning supplies such as traditional liquid detergents
Clothing is cleaned, the harmful substances such as formaldehyde remaining in clothing can not be removed well.At present still lack one kind can play compared with
Good sterilization, except the liquid detergent of formaldehyde effect.
Therefore, developing a kind of be formulated does not stimulate mildly, and cleaning effect is good, and bactericidal effect is good, effectively removes first contained by clothes
Aldehyde does not have secondary injury to human body, and the liquid detergent and preparation method thereof of preparation method removal formaldehyde simple to operation has wide
General market prospects.
Summary of the invention
In view of the deficiencies of the prior art, the present invention provides a kind of be formulated and does not stimulate mildly, and cleaning effect is good, bactericidal effect
It is good, formaldehyde contained by clothes is effectively removed, does not have secondary injury, the laundry of preparation method removal formaldehyde simple to operation to human body
Liquid and preparation method thereof, for overcoming defect in the prior art.
The technical scheme of the present invention is realized as follows: a kind of liquid detergent for removing formaldehyde, it is by weights score
Raw material be prepared: alkali protease: 10 to 15 parts, 10 to 20 parts of zeolite powder, diatomite in powder: 5 to 10 parts, stabilizer 1
To 5 parts, 10 to 20 parts of asparagus juice, 1 to 5 part of essence, 10 to 20 parts of gleditsia sinensis extracting solution, 20 to 30 parts of orange peel extracting solution, preservative 1
To 5 parts, 10 to 15 parts of sodium alkyl benzene sulfonate, surplus is water.
The alkali protease is the Bacillus licheniformis2709 gone out by bacterial protoplast mutagenic and breeding, is sent out through deep layer
Made of ferment extracts, the enzyme activity range of alkali protease is 800,000 u/g.
The zeolite powder is natural zeolite powder, and granularity is the powder of 500 mesh or more, and the excess water is deionization
Water.
The diatomite is magnesium hydroxide modification infusorial earth, and granularity is the powder of 500 mesh or more, the alkyl
Benzene sulfonic acid sodium salt is neopelex.
The stabilizer is sodium citrate, and the asparagus juice is natural aloe juice, and the essence is tea tree essence.
The orange peel extracting solution is added to made from boiling water distillation extraction using dry orange peel.
A kind of preparation method of the liquid detergent of removal formaldehyde as described above, preparation method are as follows:
1) alkali protease of above-mentioned parts by weight is mixed first with zeolite powder and diatomite in powder, water is then added, and stir
It mixes uniformly, and is warming up to 50 degrees Celsius, be stirred continuously during heating, mixing time is 30 minutes, and mixing speed is every point
500 turns of clock, 500 meshes are crossed after static in then natural cooling 30 minutes, mixed liquor A；
2) successively added in mixed liquor A obtained in step 1) the gleditsia sinensis extracting solutions of above-mentioned parts by weight, sodium alkyl benzene sulfonate,
Stabilizer, essence and preservative, it is static after then heating to 50 degrees Celsius, stirring 30 minutes, obtain mixed liquid B:
3) asparagus juice and orange peel extracting solution of above-mentioned parts by weight are added in the mixed liquid B obtained in step 2, stirs
Worth finished product after uniformly.
The present invention has following good effect: the product formula is mildly non-stimulated, can not only play preferable cleaning effect
Fruit can also play the role of preferably sterilizing, except formaldehyde, use alkali protease in product formula, have concurrently nonionic and it is negative from
The active characteristic in sublist face easily rinses, and anti-dilution capacity is strong, has antibacterial, the multi-efficiencies such as submissive, bleaching, strong detergency, energy
Enough deep layer cleaning substrates had not only had good environment-friendly and green ecological safety activity, but also have had multifunction surface activity, nontoxic, nothing
Harmful, non-stimulated to skin, safe green environmental protection will not pollute environment.The present invention uses zeolite powder raw material, and zeolite powder is day
Right Zeolite Rock is levigate to be formed, and color is light green color, white.It can remove ammonia nitrogen 95% in water, purify water, alleviation turns water phenomenon.
Zeolite is in neutrality pH between 7 to 7.5, and natural zeolite powder has the function of friction, promotes the removal effect of spot.The present invention adopts
With diatomite in powder, pH value is neutral, nontoxic, and suspendability is good, and absorption property is strong, and bulk density is light, and oil absorbency 115%, fineness is in 325 mesh
To 500 mesh, mixing uniformity is good, and adsorbable activity red material can replace the surfactant of a part, greatly reduce
The additive amount of surfactant, to reduce influence of the surfactant to alkaline protease activity, it is ensured that alkali protease
Super-active is kept without stabilizer in liquid environment, diatomite has good suction-operated, can be good by its
Suction-operated adsorbs the spot of the difficult removal on clothing, so as to further improve the clean-up performance to clothing, another party
Face, it enables to clothing soft fluffy, non-stimulated to human skin.Asparagus juice can make the clothing after washing in inventive formulation
Clothes reduce the stimulation to skin, are provided simultaneously with the effect of certain elimination peculiar smell.The present invention uses the conduct of orange peel extracting solution
One of formula has the effect of fragrance, cooperates tea tree essence, natural harmless instead of traditional essence and aromatic props.
Specific embodiment
Embodiment 1: a kind of liquid detergent removing formaldehyde, it is prepared by the raw material of weights score: alkalinity
Protease: 10 parts, 10 parts of zeolite powder, diatomite in powder: 5 parts, 1 part of stabilizer, 10 parts of asparagus juice, 1 part of essence, gleditsia sinensis extracting solution 10
Part, 20 parts of orange peel extracting solution, 1 part of preservative, 10 parts of sodium alkyl benzene sulfonate, surplus is water.
The alkali protease is the Bacillus licheniformis2709 gone out by bacterial protoplast mutagenic and breeding, is sent out through deep layer
Made of ferment extracts, the enzyme activity range of alkali protease is 800,000 u/g.The zeolite powder is natural zeolite powder, and granularity is
Powders more than 500 mesh, the excess water are deionized water.The diatomite is magnesium hydroxide modification infusorial earth, grain
Degree is the powder of 500 mesh or more, and the sodium alkyl benzene sulfonate is neopelex.The stabilizer is lemon
Sour sodium, the asparagus juice are natural aloe juice, and the essence is tea tree essence.The orange peel extracting solution is using dry tangerine
Skin is added to made from boiling water distillation extraction.
A kind of preparation method of the liquid detergent of removal formaldehyde as described above, preparation method are as follows:
1) alkali protease of above-mentioned parts by weight is mixed first with zeolite powder and diatomite in powder, water is then added, and stir
It mixes uniformly, and is warming up to 50 degrees Celsius, be stirred continuously during heating, mixing time is 30 minutes, and mixing speed is every point
500 turns of clock, 500 meshes are crossed after static in then natural cooling 30 minutes, mixed liquor A；
2) successively added in mixed liquor A obtained in step 1) the gleditsia sinensis extracting solutions of above-mentioned parts by weight, sodium alkyl benzene sulfonate,
Stabilizer, essence and preservative, it is static after then heating to 50 degrees Celsius, stirring 30 minutes, obtain mixed liquid B:
3) asparagus juice and orange peel extracting solution of above-mentioned parts by weight are added in the mixed liquid B obtained in step 2, stirs
Worth finished product after uniformly.
Embodiment 2: a kind of liquid detergent removing formaldehyde, it is prepared by the raw material of weights score: alkalinity
Protease: 15 parts, 20 parts of zeolite powder, diatomite in powder: 10 parts, 5 parts of stabilizer, 20 parts of asparagus juice, 5 parts of essence, gleditsia sinensis extracts
20 parts of liquid, 30 parts of orange peel extracting solution, 5 parts of preservative, 15 parts of sodium alkyl benzene sulfonate, surplus is water.
The alkali protease is the Bacillus licheniformis2709 gone out by bacterial protoplast mutagenic and breeding, is sent out through deep layer
Made of ferment extracts, the enzyme activity range of alkali protease is 800,000 u/g.The zeolite powder is natural zeolite powder, and granularity is
Powders more than 500 mesh, the excess water are deionized water.The diatomite is magnesium hydroxide modification infusorial earth, grain
Degree is the powder of 500 mesh or more, and the sodium alkyl benzene sulfonate is neopelex.The stabilizer is lemon
Sour sodium, the asparagus juice are natural aloe juice, and the essence is tea tree essence.The orange peel extracting solution is using dry tangerine
Skin is added to made from boiling water distillation extraction.
A kind of preparation method of the liquid detergent of removal formaldehyde as described above, preparation method are as follows:
1) alkali protease of above-mentioned parts by weight is mixed first with zeolite powder and diatomite in powder, water is then added, and stir
It mixes uniformly, and is warming up to 50 degrees Celsius, be stirred continuously during heating, mixing time is 30 minutes, and mixing speed is every point
500 turns of clock, 500 meshes are crossed after static in then natural cooling 30 minutes, mixed liquor A；
2) successively added in mixed liquor A obtained in step 1) the gleditsia sinensis extracting solutions of above-mentioned parts by weight, sodium alkyl benzene sulfonate,
Stabilizer, essence and preservative, it is static after then heating to 50 degrees Celsius, stirring 30 minutes, obtain mixed liquid B:
3) asparagus juice and orange peel extracting solution of above-mentioned parts by weight are added in the mixed liquid B obtained in step 2, stirs
Worth finished product after uniformly.
Embodiment 3: a kind of liquid detergent removing formaldehyde, it is prepared by the raw material of weights score: alkalinity
Protease: 12 parts, 15 parts of zeolite powder, diatomite in powder: 8 parts, 2 parts of stabilizer, 15 parts of asparagus juice, 2 parts of essence, gleditsia sinensis extracting solution 15
Part, 25 parts of orange peel extracting solution, 2 parts of preservative, 12 parts of sodium alkyl benzene sulfonate, surplus is water.
The alkali protease is the Bacillus licheniformis2709 gone out by bacterial protoplast mutagenic and breeding, is sent out through deep layer
Made of ferment extracts, the enzyme activity range of alkali protease is 800,000 u/g.The zeolite powder is natural zeolite powder, and granularity is
Powders more than 500 mesh, the excess water are deionized water.The diatomite is magnesium hydroxide modification infusorial earth, grain
Degree is the powder of 500 mesh or more, and the sodium alkyl benzene sulfonate is neopelex.The stabilizer is lemon
Sour sodium, the asparagus juice are natural aloe juice, and the essence is tea tree essence.The orange peel extracting solution is using dry tangerine
Skin is added to made from boiling water distillation extraction.
A kind of preparation method of the liquid detergent of removal formaldehyde as described above, preparation method are as follows:
1) alkali protease of above-mentioned parts by weight is mixed first with zeolite powder and diatomite in powder, water is then added, and stir
It mixes uniformly, and is warming up to 50 degrees Celsius, be stirred continuously during heating, mixing time is 30 minutes, and mixing speed is every point
500 turns of clock, 500 meshes are crossed after static in then natural cooling 30 minutes, mixed liquor A；
2) successively added in mixed liquor A obtained in step 1) the gleditsia sinensis extracting solutions of above-mentioned parts by weight, sodium alkyl benzene sulfonate,
Stabilizer, essence and preservative, it is static after then heating to 50 degrees Celsius, stirring 30 minutes, obtain mixed liquid B:
3) asparagus juice and orange peel extracting solution of above-mentioned parts by weight are added in the mixed liquid B obtained in step 2, stirs
Worth finished product after uniformly.
The present invention have extremely strong active material, product it can destroy the various lifes in bacterium and various microbial cells
Object macromolecule and film make its loss of activity, and energy PARA FORMALDEHYDE PRILLS(91,95) plays the role of good removal, while alkalescent is presented, and helps
In the kill of bacterium.Formula is mild non-stimulated, can not only play preferable cleaning effect, can also play and preferably sterilize, remove
Formaldehyde acts on, and uses alkali protease in product formula, has the characteristic of nonionic and anion surface active concurrently, easily rinses, and resists
Dilution capacity is strong, has an antibacterial, the multi-efficiencies such as submissive, bleaching, strong detergency, can deep layer cleaning substrate, both had good
Good environment-friendly and green ecological safety activity, and have multifunction surface activity, nontoxic, harmless, non-stimulated to skin, safe green ring
It protects, environment will not be polluted.
Claims (7)
1. a kind of liquid detergent for removing formaldehyde, which is characterized in that it is prepared by the raw material of weights score: alkalinity
Protease: 10 to 15 parts, 10 to 20 parts of zeolite powder, diatomite in powder: 5 to 10 parts, 1 to 5 part of stabilizer, 10 to 20 parts of asparagus juice,
1 to 5 part of essence, 10 to 20 parts of gleditsia sinensis extracting solution, 20 to 30 parts of orange peel extracting solution, 1 to 5 part of preservative, sodium alkyl benzene sulfonate 10
To 15 parts, surplus is water.
2. the liquid detergent of removal formaldehyde according to claim 1, it is characterised in that: the alkali protease is by bacterium
The Bacillus licheniformis2709 that Protoplasts Mutagenesis goes out, made of being extracted through submerged fermentation, the enzyme activity model of alkali protease
It encloses for 800,000 u/g.
3. the liquid detergent of removal formaldehyde according to claim 1, it is characterised in that: the zeolite powder is natural zeolite
Powder, granularity are the powder of 500 mesh or more, and the excess water is deionized water.
4. the liquid detergent of removal formaldehyde according to claim 1, it is characterised in that: the diatomite changes for magnesium hydroxide
Property diatomite, granularity is the powder of 500 mesh or more, the sodium alkyl benzene sulfonate be neopelex.
5. the liquid detergent of removal formaldehyde according to claim 1, it is characterised in that: the stabilizer is sodium citrate,
The asparagus juice is natural aloe juice, and the essence is tea tree essence.
6. the liquid detergent of removal formaldehyde according to claim 1, it is characterised in that: the orange peel extracting solution is using dry
Orange peel is added to made from boiling water distillation extraction.
7. a kind of preparation method of the liquid detergent of removal formaldehyde as described in claim 1, it is characterised in that: preparation method is such as
Under:
1) alkali protease of above-mentioned parts by weight is mixed first with zeolite powder and diatomite in powder, water is then added, and stir
It mixes uniformly, and is warming up to 50 degrees Celsius, be stirred continuously during heating, mixing time is 30 minutes, and mixing speed is every point
500 turns of clock, 500 meshes are crossed after static in then natural cooling 30 minutes, mixed liquor A；
2) successively added in mixed liquor A obtained in step 1) the gleditsia sinensis extracting solutions of above-mentioned parts by weight, sodium alkyl benzene sulfonate,
Stabilizer, essence and preservative, it is static after then heating to 50 degrees Celsius, stirring 30 minutes, obtain mixed liquid B:
3) asparagus juice and orange peel extracting solution of above-mentioned parts by weight are added in the mixed liquid B obtained in step 2, stirs
Worth finished product after uniformly.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910453769.1A CN110016390A (en) | 2019-05-28 | 2019-05-28 | A kind of liquid detergent and preparation method thereof removing formaldehyde |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910453769.1A CN110016390A (en) | 2019-05-28 | 2019-05-28 | A kind of liquid detergent and preparation method thereof removing formaldehyde |
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| Publication Number | Publication Date |
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| CN110016390A true CN110016390A (en) | 2019-07-16 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910453769.1A Pending CN110016390A (en) | 2019-05-28 | 2019-05-28 | A kind of liquid detergent and preparation method thereof removing formaldehyde |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022100011A1 (en) * | 2020-11-14 | 2022-05-19 | 山西大学 | 2709 alkaline protease mutant modified on the basis of molecular dynamics calculation and use thereof |
| CN114606066A (en) * | 2021-08-16 | 2022-06-10 | 浙江水星生物科技有限公司 | Laundry detergent with color fixing and formaldehyde removing functions and preparation process thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108504461A (en) * | 2018-03-21 | 2018-09-07 | 桂林良物造日用品有限公司 | One kind containing diatomaceous antimicrobial laundry liquid and preparation method thereof |
-
2019
- 2019-05-28 CN CN201910453769.1A patent/CN110016390A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108504461A (en) * | 2018-03-21 | 2018-09-07 | 桂林良物造日用品有限公司 | One kind containing diatomaceous antimicrobial laundry liquid and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022100011A1 (en) * | 2020-11-14 | 2022-05-19 | 山西大学 | 2709 alkaline protease mutant modified on the basis of molecular dynamics calculation and use thereof |
| CN114606066A (en) * | 2021-08-16 | 2022-06-10 | 浙江水星生物科技有限公司 | Laundry detergent with color fixing and formaldehyde removing functions and preparation process thereof |
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Application publication date: 20190716 |