CN114606066A - Laundry detergent with color fixing and formaldehyde removing functions and preparation process thereof - Google Patents
Laundry detergent with color fixing and formaldehyde removing functions and preparation process thereof Download PDFInfo
- Publication number
- CN114606066A CN114606066A CN202110934612.8A CN202110934612A CN114606066A CN 114606066 A CN114606066 A CN 114606066A CN 202110934612 A CN202110934612 A CN 202110934612A CN 114606066 A CN114606066 A CN 114606066A
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- Prior art keywords
- parts
- extract
- coconut shell
- formaldehyde
- laundry detergent
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- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 title claims abstract description 168
- 239000003599 detergent Substances 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims description 7
- 235000013162 Cocos nucifera Nutrition 0.000 claims abstract description 41
- 244000060011 Cocos nucifera Species 0.000 claims abstract description 41
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- 239000000284 extract Substances 0.000 claims abstract description 25
- 239000000843 powder Substances 0.000 claims abstract description 24
- 108091005658 Basic proteases Proteins 0.000 claims abstract description 23
- 239000004094 surface-active agent Substances 0.000 claims abstract description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000003381 stabilizer Substances 0.000 claims abstract description 19
- 239000000419 plant extract Substances 0.000 claims abstract description 15
- 241000196324 Embryophyta Species 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 238000003756 stirring Methods 0.000 claims description 15
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- 239000001522 artemisia absinthium l. herb extract Substances 0.000 claims description 12
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 claims description 12
- 229940083980 lavender extract Drugs 0.000 claims description 12
- 235000020723 lavender extract Nutrition 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 12
- 239000011259 mixed solution Substances 0.000 claims description 12
- 229940119569 wormwood extract Drugs 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 11
- 230000004913 activation Effects 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 6
- 238000007873 sieving Methods 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- 244000063299 Bacillus subtilis Species 0.000 claims description 4
- 235000014469 Bacillus subtilis Nutrition 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- -1 magnesium hydroxide modified diatomite Chemical class 0.000 claims description 4
- 235000009051 Ambrosia paniculata var. peruviana Nutrition 0.000 claims description 3
- 235000003097 Artemisia absinthium Nutrition 0.000 claims description 3
- 240000001851 Artemisia dracunculus Species 0.000 claims description 3
- 235000017731 Artemisia dracunculus ssp. dracunculus Nutrition 0.000 claims description 3
- 235000003261 Artemisia vulgaris Nutrition 0.000 claims description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 3
- 229920001661 Chitosan Polymers 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 244000178870 Lavandula angustifolia Species 0.000 claims description 3
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 3
- 241000220317 Rosa Species 0.000 claims description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 3
- 229910021536 Zeolite Inorganic materials 0.000 claims description 3
- 230000003213 activating effect Effects 0.000 claims description 3
- 239000001138 artemisia absinthium Substances 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 230000001580 bacterial effect Effects 0.000 claims description 3
- 239000003610 charcoal Substances 0.000 claims description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 3
- 239000003546 flue gas Substances 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000001102 lavandula vera Substances 0.000 claims description 3
- 235000018219 lavender Nutrition 0.000 claims description 3
- 239000000347 magnesium hydroxide Substances 0.000 claims description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000002703 mutagenesis Methods 0.000 claims description 3
- 231100000350 mutagenesis Toxicity 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 210000001938 protoplast Anatomy 0.000 claims description 3
- 238000006479 redox reaction Methods 0.000 claims description 3
- 238000002791 soaking Methods 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000001509 sodium citrate Substances 0.000 claims description 3
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical group O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- 239000010457 zeolite Substances 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 238000003763 carbonization Methods 0.000 claims description 2
- 235000019864 coconut oil Nutrition 0.000 claims description 2
- 239000003240 coconut oil Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 10
- 231100000252 nontoxic Toxicity 0.000 abstract description 6
- 230000003000 nontoxic effect Effects 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 3
- 239000013543 active substance Substances 0.000 abstract description 3
- 150000001299 aldehydes Chemical class 0.000 abstract description 3
- 125000000129 anionic group Chemical group 0.000 abstract description 3
- 150000002148 esters Chemical class 0.000 abstract description 3
- 150000002576 ketones Chemical class 0.000 abstract description 3
- 150000002894 organic compounds Chemical class 0.000 abstract description 3
- 235000017003 Cissus Nutrition 0.000 abstract description 2
- 235000017014 Cissus repens Nutrition 0.000 abstract description 2
- 244000035145 Cissus repens Species 0.000 abstract 1
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 239000004744 fabric Substances 0.000 description 16
- 239000000523 sample Substances 0.000 description 7
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 6
- 238000000855 fermentation Methods 0.000 description 4
- 230000004151 fermentation Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000004364 calculation method Methods 0.000 description 3
- 244000045483 Cissus quadrangularis Species 0.000 description 2
- 235000000470 Vitis quadrangularis Nutrition 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 230000036632 reaction speed Effects 0.000 description 2
- 238000009751 slip forming Methods 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 208000035143 Bacterial infection Diseases 0.000 description 1
- 241001355260 Cissus Species 0.000 description 1
- 206010015150 Erythema Diseases 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- 208000003251 Pruritus Diseases 0.000 description 1
- 206010042674 Swelling Diseases 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 208000022362 bacterial infectious disease Diseases 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004737 colorimetric analysis Methods 0.000 description 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000007803 itching Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000009966 trimming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a laundry detergent with color fixation and formaldehyde removal functions, which is characterized by being prepared from the following raw materials in parts by weight: 14-25 parts of plant extract, 5-10 parts of alkaline protease, 5-10 parts of diatomite powder, 20-40 parts of surfactant, 1-5 parts of stabilizer, 1-5 parts of essence, 2 parts of coconut shell carbon and 1-5 parts of film-forming agent; the beneficial effects are that: the invention has strong active substances, and the plant active groups can capture and convert formaldehyde into nontoxic reticular high molecular substances; the plants contain organic compounds such as alcohol, aldehyde, ketone, ester and the like, and the formaldehyde removing effect is good; the alkaline protease has the characteristics of nonionic and anionic surface activity, and is non-toxic and harmless; the film forming agent has strong film forming property, can promote formaldehyde removal, and can continuously form a transparent film harmless to human bodies on clothes after the clothes are cleaned and dried, so that the color of the clothes can be fixed; the extract of the cissus quadratus has prominent substantive characteristics for absorbing formaldehyde.
Description
Technical Field
The invention relates to the field of laundry detergent, in particular to a laundry detergent with color fixing and formaldehyde removing functions and a preparation process thereof.
Background
Because the materials of the existing clothes are more and more, a plurality of different raw materials are also used for manufacturing the clothes fabric in the process of manufacturing the clothes fabric. Formaldehyde is mainly used as a dyeing assistant and a resin finishing agent for improving the crease-resistant and shrink-proof effects in fiber products. In particular, the phenomenon that formaldehyde in the fabric of the children clothes and the infant clothes exceeds standard generally exists. The formaldehyde content, generally, does not exceed 20mg per kg of garment. Therefore, a large amount of formaldehyde remains on the fabric of the clothes.
The formaldehyde remained on the fabric can cause severe stimulation to the skin, and when the clothes containing the formaldehyde are worn for a long time, a series of skin disease problems can be caused to the skin, such as symptoms of redness and swelling, itching and the like, and bacterial infection can be caused if the clothes are grabbed by hands. When the clothes containing formaldehyde are worn, allergy can be caused, and even life health and safety can be threatened in serious cases, so that the purchased new clothes must be cleaned in time.
The working principle of the laundry detergent is the same as that of the traditional washing powder and soap, and the active ingredients are all surfactants. The difference lies in that: the traditional washing powder and soap adopt anionic surfactant, and have strong alkalinity. And the laundry detergent mostly adopts nonionic surfactants, so that the laundry detergent is mild. The active ingredients of the laundry detergent are mainly nonionic surfactants, and the structure of the laundry detergent comprises a hydrophilic end and an oleophilic end, wherein the oleophilic end is combined with stains, and then the stains and fabrics are separated by physical movement. Meanwhile, the surfactant reduces the tension of water, so that the water can reach the surface of the fabric, and the effective components can play a role.
The clothes are cleaned by using cleaning products such as traditional laundry detergent and the like, and harmful substances such as residual formaldehyde and the like in the clothes cannot be well removed. At present, a laundry detergent which can achieve a good formaldehyde removal effect is not available.
Disclosure of Invention
The invention aims to provide a laundry detergent with functions of color fixation and formaldehyde removal and a preparation process thereof, aiming at the defects of the prior art.
In order to achieve the above object, the present invention is achieved by the following technical solutions.
A laundry detergent with color fixation and formaldehyde removal functions is characterized in that: the medicine is prepared from the following raw materials in parts by weight: 14-25 parts of plant extract, 5-10 parts of alkaline protease, 5-10 parts of diatomite powder, 20-40 parts of surfactant, 1-5 parts of stabilizer, 1-5 parts of essence, 2 parts of coconut shell carbon, 1-5 parts of film-forming agent and the balance of water.
Further, the plant extracting solution comprises the following components in parts by mass: 3-5 parts of lavender extract, 3-5 parts of wormwood extract, 0-10 parts of tetragonal vine extract and 3-5 parts of orange peel extract.
Further, the alkaline protease is bacillus subtilis bred by bacterial protoplast mutagenesis, fermentation and extraction of bacillus subtilis strain are carried out to obtain fermentation liquor, and the alkaline protease is obtained after centrifugation and filtration.
Further, the diatomite is magnesium hydroxide modified diatomite and powder with the granularity of more than 400 meshes.
Further, the surfactant comprises the following components in parts by mass: 5-10 parts of fatty alcohol-polyoxyethylene ether sodium sulfate, 5-10 parts of alpha-alkenyl sodium sulfonate and fatty acid potassium, 5-10 parts of fatty alcohol-polyoxyethylene ether and 5-10 parts of coconut oil fatty acid diethanolamide.
Further, the stabilizing agent is sodium citrate, and the essence is rose essence.
Further, the particle size of the coconut shell carbon is 400 meshes.
Furthermore, the film forming agent is chitosan, the strong film forming property of the film forming agent is mainly utilized, the reaction speed of formaldehyde removing components and formaldehyde can be promoted, and after clothes are cleaned and dried, a transparent film harmless to a human body can be continuously formed on the clothes, so that the color fixing effect on the clothes is realized.
Further, the balance of water is deionized water.
Further, 3 parts of lavender extract, 3 parts of wormwood extract, 5 parts of tetragonal vine extract, 3 parts of orange peel extract, 6 parts of alkaline protease, 5 parts of diatomite powder, 30 parts of surfactant, 1 part of stabilizer, 1 part of essence, 2 parts of coconut shell carbon and 3 parts of film-forming agent.
Further, 3 parts of lavender extract, 3 parts of wormwood extract, 3 parts of orange peel extract, 6 parts of alkaline protease, 5 parts of diatomite powder, 30 parts of surfactant, 1 part of stabilizer, 1 part of essence, 2 parts of coconut shell carbon and 3 parts of film-forming agent.
Further, 4 parts of lavender extract, 5 parts of wormwood extract, 8 parts of tetragonal vine extract, 5 parts of orange peel extract, 6 parts of alkaline protease, 8 parts of diatomite powder, 35 parts of surfactant, 1 part of stabilizer, 2 parts of essence, 2 parts of coconut shell carbon and 3 parts of film-forming agent.
A process for preparing a formaldehyde-removing laundry detergent according to claim 1, characterized in that: the preparation process comprises the following steps:
1) the plant extract is obtained by mechanically crushing the lavender, the wormwood, the tetragonal vine and the orange peel in parts by weight, and soaking the crushed plant extract in 500L of deionized water with the pH value of 5-7 at the temperature of 10-30 ℃ for 1-48 hours to obtain the plant extract for later use.
2) Mixing the alkaline protease, zeolite powder and diatomite powder in parts by weight, adding water, uniformly stirring until the temperature rises to 50 ℃, stirring for 30 minutes at a stirring speed of 300 revolutions per minute, naturally cooling for 10 minutes, standing, and sieving with a 500-mesh sieve to obtain a mixed solution A;
3) sequentially adding the surfactant, the stabilizer, the essence and the film-forming agent in parts by weight into the mixed solution A prepared in the step 2), heating to 80 ℃, stirring for 30 minutes, and standing to obtain a mixed solution B:
4) charring coconut shellThe equipment is treated for 8 hours at the high temperature of 120-180 ℃; immersing the carbonized coconut shell carbon in a hydrochloric acid solution with the equal volume concentration of 0.2mol/L for 10 hours; placing the coconut shell carbon soaked with hydrochloric acid into an activation furnace to make water vapor and flue gas (the main component is CO)2) The oxygen-containing gas is used as an activating agent and is contacted with coconut shell carbon at the temperature of 60-80 ℃ to generate oxidation-reduction reaction for activation; and (4) crushing the activated coconut shell carbon, and sieving the crushed coconut shell carbon with a 400-mesh sieve to obtain the coconut shell carbon for later use.
5) Adding the coconut shell charcoal and the plant extracting solution in parts by weight into the prepared mixed solution B in the step 3), and uniformly stirring to obtain a finished product.
The invention has strong active substances, and the plant active groups can capture and convert formaldehyde into nontoxic reticular high molecular substances. The plants contain organic compounds such as alcohol, aldehyde, ketone, ester and the like, and the formaldehyde removing effect is good; the alkaline protease has the characteristics of nonionic and anionic surface activity, and is non-toxic and harmless; the film forming agent has strong film forming property, can promote formaldehyde removal, and can continuously form a transparent film harmless to human bodies on clothes after the clothes are cleaned and dried, so that the color of the clothes can be fixed; the SPSS difference analysis shows that the extract of the cissus quadrangularis has prominent substantive characteristics for absorbing formaldehyde.
Detailed Description
The present invention is further illustrated by the following examples, but is not limited to the details of the description.
A laundry detergent with color fixation and formaldehyde removal functions is characterized in that: the medicine is prepared from the following raw materials in parts by weight: 14-25 parts of plant extract, 5-10 parts of alkaline protease, 5-10 parts of diatomite powder, 20-40 parts of surfactant, 1-5 parts of stabilizer, 1-5 parts of essence, 2 parts of coconut shell carbon, 1-5 parts of film-forming agent and the balance of water.
The plant extract consists of the following components in parts by mass: 3-5 parts of lavender extract, 3-5 parts of wormwood extract, 0-10 parts of tetragonal vine extract and 3-5 parts of orange peel extract.
The alkaline protease is obtained by fermenting and extracting bacillus subtilis strain which is bred by bacterial protoplast mutagenesis to obtain fermentation liquor, and centrifuging and filtering the fermentation liquor.
The diatomite is magnesium hydroxide modified diatomite and powder with the granularity of more than 400 meshes.
The surfactant comprises the following components in parts by mass: 5-10 parts of fatty alcohol-polyoxyethylene ether sodium sulfate, 5-10 parts of alpha-alkenyl sodium sulfonate and potassium fatty acid, 5-10 parts of fatty alcohol-polyoxyethylene ether and 5-10 parts of coconut fatty acid diethanolamide.
The stabilizing agent is sodium citrate, and the essence is rose essence.
The particle size of the coconut shell carbon is 400 meshes.
The film forming agent is chitosan, the strong film forming property of the film forming agent is mainly utilized, the reaction speed of formaldehyde removing components and formaldehyde can be promoted, and after clothes are cleaned and dried, a transparent film harmless to human bodies can be continuously formed on the clothes, so that the color fixing effect on the clothes is realized.
The balance of water is deionized water.
Specific example 1:
a liquid laundry detergent with color fixing and formaldehyde removing functions is prepared from the following raw materials in parts by weight: 3 parts of lavender extract, 3 parts of wormwood extract, 5 parts of tetragonal vine extract, 3 parts of orange peel extract, 6 parts of alkaline protease, 5 parts of diatomite powder, 30 parts of surfactant, 1 part of stabilizer, 1 part of essence, 2 parts of coconut shell carbon and 3 parts of film-forming agent.
Specific example 2:
a liquid laundry detergent with color fixing and formaldehyde removing functions is prepared from the following raw materials in parts by weight: 3 parts of lavender extract, 3 parts of wormwood extract, 3 parts of orange peel extract, 6 parts of alkaline protease, 5 parts of diatomite powder, 30 parts of surfactant, 1 part of stabilizer, 1 part of essence, 2 parts of coconut shell carbon and 3 parts of film-forming agent.
Specific example 3:
a liquid laundry detergent with color fixing and formaldehyde removing functions is prepared from the following raw materials in parts by weight: 4 parts of lavender extract, 5 parts of wormwood extract, 8 parts of tetragonal vine extract, 5 parts of orange peel extract, 6 parts of alkaline protease, 8 parts of diatomite powder, 35 parts of surfactant, 1 part of stabilizer, 2 parts of essence, 2 parts of coconut shell carbon and 3 parts of film-forming agent.
A process for preparing a formaldehyde-removing laundry detergent according to claim 1, characterized in that: the preparation process comprises the following steps:
1) the plant extract is obtained by mechanically crushing the lavender, the wormwood, the tetragonal vine and the orange peel in parts by weight, and soaking the crushed plant extract in 500L of deionized water with the pH value of 5-7 at the temperature of 10-30 ℃ for 1-48 hours to obtain the plant extract for later use.
2) Mixing the alkaline protease, zeolite powder and diatomite powder in parts by weight, adding water, uniformly stirring until the temperature rises to 50 ℃, stirring for 30 minutes at a stirring speed of 300 revolutions per minute, naturally cooling for 10 minutes, standing, and sieving with a 500-mesh sieve to obtain a mixed solution A;
3) sequentially adding the surfactant, the stabilizer, the essence and the film-forming agent in parts by weight into the mixed solution A prepared in the step 2), heating to 80 ℃, stirring for 30 minutes, and standing to obtain a mixed solution B:
4) placing the coconut shell into carbonization equipment, and treating for 8 hours at the high temperature of 180 ℃ under the temperature of 120-; immersing the carbonized coconut shell carbon in a hydrochloric acid solution with the equal volume concentration of 0.2mol/L for 10 hours; placing the coconut shell carbon soaked with hydrochloric acid into an activation furnace to make water vapor and flue gas (the main component is CO)2) The oxygen-containing gas is used as an activating agent and is contacted with coconut shell carbon at the temperature of 60-80 ℃ to generate oxidation-reduction reaction for activation; and (4) crushing the activated coconut shell carbon, and sieving the crushed coconut shell carbon with a 400-mesh sieve to obtain the coconut shell carbon for later use.
5) Adding the coconut shell charcoal and the plant extracting solution in parts by weight into the prepared mixed solution B in the step 3), and uniformly stirring to obtain a finished product.
The formaldehyde removal test before and after the fabric washing comprises the following steps and calculation formula:
1. the content of formaldehyde in the textile was determined by steam absorption.
The method comprises the following steps of (1) respectively measuring the formaldehyde content of the fabric samples before and after washing by using a steam absorption method, wherein the method specifically comprises the following steps: a certain mass of fabric sample is hung on the water surface in a sealed bottle, placed in a box with constant temperature for a certain time, the released formaldehyde is absorbed by water, and after the color development of acetylacetone, the absorbance in the color development liquid is measured by a spectrophotometer colorimetric method. And (5) calculating the content of the released formaldehyde in the sample by contrasting with a standard A working curve.
The specific operation steps are as follows:
1) adding 50mL of water into each test bottle, placing the sample on a hook hung at the top of a bottle cap (to avoid the contact of the sample with the water), tightly covering the bottle cap, carefully placing the bottle in an oven at (49 +/-2) DEG C for 20h +/-15 min, taking out the test bottle, cooling for (30 +/-5) min, taking out the sample from the bottle, tightly covering the bottle cap again, and shaking up.
2) Using a single-label pipette to suck 5mL of the acetylacetone solution and put the acetylacetone solution into another test tube, and adding 5mL of distilled water as a blank reagent.
3) The tube is placed in a water bath at 40 + -2 deg.C for developing color (30 + -5) min, then taken out, cooled at room temperature in the dark for (30 + -5) min, and the absorbance is measured at 412nm wavelength of spectrophotometer with 10mm absorption cell. The formaldehyde content (μ g/mL) in the samples was calculated by formaldehyde standard working curve.
2. Calculation and representation of the formaldehyde content in the fabric samples:
F＝c×50/m
in the formula:
f: formaldehyde content in the fabric sample, mg/kg;
c: reading from the formaldehyde content in the sample solution on the working curve, μ g/mL;
m: mass of sample, g.
Taking the average value of two parallel tests as the detection result, and trimming the calculation result to integer number. If the result is less than 20mg/kg, the test result reports "not detected".
3. The cleaning steps of the fabric are as follows:
s1: placing three fabrics cut from the same cloth in three test tubes respectively, marking as a group I, a group II and a group III, additionally preparing a group of blank comparison groups, and placing water with the same temperature in the test tubes;
s2: the solutions prepared in the examples were added to the test tubes of group one, group two, and group three, respectively, centrifuged at 600r/min for 30 minutes at 40 degrees, the fabric was taken out and air-dried, and then formaldehyde content was measured, and finally comparative analysis was performed to obtain experimental results, as shown in the table below.
After the differences are analyzed by SPSS software, some indexes of the three groups of specific embodiments show obvious differences compared with other treatments, and some differences are not obvious, but the indexes have a trend superior to other treatments when compared with the values. Example 3 is a relatively preferred formulation. The outstanding substantive characteristics of the extract of the cissus quadrata for absorbing formaldehyde can be seen through the comparison of the formula.
The invention has strong active substances, and the plant active groups can capture and convert formaldehyde into nontoxic reticular high molecular substances. The plants contain organic compounds such as alcohol, aldehyde, ketone, ester and the like, and the formaldehyde removing effect is good; the alkaline protease has the characteristics of nonionic and anionic surface activity, and is non-toxic and harmless; the film forming agent has strong film forming property, can promote formaldehyde removal, and can continuously form a transparent film harmless to human bodies on clothes after the clothes are cleaned and dried, so that the color of the clothes can be fixed; the SPSS difference analysis shows that the extract of the cissus quadrangularis has prominent substantive characteristics for absorbing formaldehyde.
The above embodiments of the present invention are merely examples for clearly illustrating the present invention, and are not intended to limit the embodiments of the present invention. Other variations and modifications will be apparent to persons skilled in the art in light of the above description. Not all embodiments are exhaustive. All obvious changes and modifications which are obvious to the technical scheme of the invention are covered by the protection scope of the invention.
Claims (9)
1. The liquid laundry detergent with the functions of color fixation and formaldehyde removal is characterized by being prepared from the following raw materials in parts by weight: 14-25 parts of plant extract, 5-10 parts of alkaline protease, 5-10 parts of diatomite powder, 20-40 parts of surfactant, 1-5 parts of stabilizer, 1-5 parts of essence, 2 parts of coconut shell carbon, 1-5 parts of film-forming agent and the balance of water.
2. The liquid laundry detergent with color fixing and formaldehyde removing functions as claimed in claim 1, characterized in that: the plant extract comprises the following components in parts by mass: 3-5 parts of lavender extract, 3-5 parts of wormwood extract, 0-10 parts of tetragonal vine extract and 3-5 parts of orange peel extract.
3. The liquid laundry detergent with color fixing and formaldehyde removing functions as claimed in claim 1, characterized in that: the alkaline protease is bacillus subtilis bred by bacterial protoplast mutagenesis.
4. The liquid laundry detergent with color fixing and formaldehyde removing functions as claimed in claim 1, characterized in that: the diatomite is magnesium hydroxide modified diatomite and powder with the granularity of more than 400 meshes; the stabilizing agent is sodium citrate; the essence is rose essence; the particle size of the coconut shell carbon is 400 meshes; the film forming agent is chitosan; the balance of water is deionized water.
5. The liquid laundry detergent with color fixing and formaldehyde removing functions as claimed in claim 1, characterized in that: the surfactant comprises the following components in parts by mass: 5-10 parts of fatty alcohol-polyoxyethylene ether sodium sulfate, 5-10 parts of alpha-alkenyl sodium sulfonate and fatty acid potassium, 5-10 parts of fatty alcohol-polyoxyethylene ether and 5-10 parts of coconut oil fatty acid diethanolamide.
6. The liquid laundry detergent with color fixing and formaldehyde removing functions as claimed in claim 1, characterized in that: 3 parts of lavender extract, 3 parts of wormwood extract, 5 parts of tetragonal vine extract, 3 parts of orange peel extract, 6 parts of alkaline protease, 5 parts of diatomite powder, 30 parts of surfactant, 1 part of stabilizer, 1 part of essence, 2 parts of coconut shell carbon and 3 parts of film-forming agent.
7. The liquid laundry detergent with color fixing and formaldehyde removing functions as claimed in claim 1, characterized in that: 3 parts of lavender extract, 3 parts of wormwood extract, 3 parts of orange peel extract, 6 parts of alkaline protease, 5 parts of diatomite powder, 30 parts of surfactant, 1 part of stabilizer, 1 part of essence, 2 parts of coconut shell carbon and 3 parts of film-forming agent.
8. The liquid laundry detergent with color fixing and formaldehyde removing functions as claimed in claim 1, characterized in that: 4 parts of lavender extract, 5 parts of wormwood extract, 8 parts of tetragonal vine extract, 5 parts of orange peel extract, 6 parts of alkaline protease, 8 parts of diatomite powder, 35 parts of surfactant, 1 part of stabilizer, 2 parts of essence, 2 parts of coconut shell carbon and 3 parts of film-forming agent.
9. The preparation process of the laundry detergent with the functions of color fixation and formaldehyde removal as claimed in claim 1, is characterized by comprising the following steps:
1) the plant extract is obtained by mechanically crushing the lavender, the wormwood, the tetragonal vine and the orange peel in parts by weight, and soaking the crushed plant extract in 500L of deionized water with the pH value of 5-7 at the temperature of 10-30 ℃ for 1-48 hours to obtain the plant extract for later use.
2) Mixing the alkaline protease, zeolite powder and diatomite powder in parts by weight, adding water, uniformly stirring until the temperature rises to 50 ℃, stirring for 30 minutes at a stirring speed of 300 revolutions per minute, naturally cooling for 10 minutes, standing, and sieving with a 500-mesh sieve to obtain a mixed solution A;
3) sequentially adding the surfactant, the stabilizer, the essence and the film-forming agent in parts by weight into the mixed solution A prepared in the step 2), heating to 80 ℃, stirring for 30 minutes, and standing to obtain a mixed solution B:
4) placing the coconut shell into carbonization equipment, and treating for 8 hours at the high temperature of 180 ℃ under the temperature of 120-; immersing the carbonized coconut shell carbon in a hydrochloric acid solution with the equal volume concentration of 0.2mol/L for 10 hours; placing the coconut shell carbon soaked with hydrochloric acid into an activation furnace to make water vapor and flue gas (the main component is CO)2) The oxygen-containing gas is used as an activating agent and is contacted with coconut shell carbon at the temperature of 60-80 ℃ to generate oxidation-reduction reaction for activation; and (4) crushing the activated coconut shell carbon, and sieving the crushed coconut shell carbon with a 400-mesh sieve to obtain the coconut shell carbon for later use.
5) Adding the coconut shell charcoal and the plant extracting solution in parts by weight into the prepared mixed solution B in the step 3), and uniformly stirring to obtain a finished product.
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| CN115463538A (en) * | 2022-08-16 | 2022-12-13 | 成都柴多多商贸有限公司 | Formaldehyde-removing odor-removing composition and preparation method and application thereof |
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