CN108410596B - Multifunctional laundry detergent and preparation process thereof - Google Patents
Multifunctional laundry detergent and preparation process thereof Download PDFInfo
- Publication number
- CN108410596B CN108410596B CN201810432466.7A CN201810432466A CN108410596B CN 108410596 B CN108410596 B CN 108410596B CN 201810432466 A CN201810432466 A CN 201810432466A CN 108410596 B CN108410596 B CN 108410596B
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- China
- Prior art keywords
- laundry detergent
- parts
- temperature
- stirring
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003599 detergent Substances 0.000 title claims abstract description 81
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 230000000694 effects Effects 0.000 claims abstract description 51
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 41
- 102000004190 Enzymes Human genes 0.000 claims abstract description 40
- 108090000790 Enzymes Proteins 0.000 claims abstract description 40
- 229940088598 enzyme Drugs 0.000 claims abstract description 40
- 239000000284 extract Substances 0.000 claims abstract description 34
- 238000005406 washing Methods 0.000 claims abstract description 34
- 239000003223 protective agent Substances 0.000 claims abstract description 24
- 239000003463 adsorbent Substances 0.000 claims abstract description 21
- 108010059892 Cellulase Proteins 0.000 claims abstract description 19
- 229940106157 cellulase Drugs 0.000 claims abstract description 19
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 18
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 17
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 17
- 239000004094 surface-active agent Substances 0.000 claims abstract description 17
- GAMYVSCDDLXAQW-AOIWZFSPSA-N Thermopsosid Natural products O(C)c1c(O)ccc(C=2Oc3c(c(O)cc(O[C@H]4[C@H](O)[C@@H](O)[C@H](O)[C@H](CO)O4)c3)C(=O)C=2)c1 GAMYVSCDDLXAQW-AOIWZFSPSA-N 0.000 claims abstract description 16
- 229930003944 flavone Natural products 0.000 claims abstract description 16
- 150000002212 flavone derivatives Chemical class 0.000 claims abstract description 16
- 235000011949 flavones Nutrition 0.000 claims abstract description 16
- VHBFFQKBGNRLFZ-UHFFFAOYSA-N vitamin p Natural products O1C2=CC=CC=C2C(=O)C=C1C1=CC=CC=C1 VHBFFQKBGNRLFZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 108090000145 Bacillolysin Proteins 0.000 claims abstract description 14
- 102000035092 Neutral proteases Human genes 0.000 claims abstract description 14
- 108091005507 Neutral proteases Proteins 0.000 claims abstract description 14
- 238000003756 stirring Methods 0.000 claims description 39
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 37
- 239000011259 mixed solution Substances 0.000 claims description 20
- 244000018716 Impatiens biflora Species 0.000 claims description 18
- 235000015912 Impatiens biflora Nutrition 0.000 claims description 18
- 235000005155 Tanacetum balsamita Nutrition 0.000 claims description 18
- 238000002156 mixing Methods 0.000 claims description 18
- 238000001035 drying Methods 0.000 claims description 17
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 16
- 238000010438 heat treatment Methods 0.000 claims description 15
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
- LMXFTMYMHGYJEI-IWSPIJDZSA-N (1R,2R,5R)-2-(1-hydroxy-1-methylethyl)-5-methylcyclohexanol Chemical compound C[C@@H]1CC[C@@H](C(C)(C)O)[C@H](O)C1 LMXFTMYMHGYJEI-IWSPIJDZSA-N 0.000 claims description 11
- 238000001816 cooling Methods 0.000 claims description 11
- 238000007873 sieving Methods 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000002244 precipitate Substances 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 7
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 7
- 229940072020 calcium borogluconate Drugs 0.000 claims description 7
- SSKRIDIHZLFJCG-UHFFFAOYSA-L calcium;2,3-dihydroxy-3-[2-hydroxy-5-(hydroxymethyl)-1,3,2-dioxaborolan-4-yl]propanoate Chemical compound [Ca+2].OCC1OB(O)OC1C(O)C(O)C([O-])=O.OCC1OB(O)OC1C(O)C(O)C([O-])=O SSKRIDIHZLFJCG-UHFFFAOYSA-L 0.000 claims description 7
- 239000001913 cellulose Substances 0.000 claims description 7
- 229920002678 cellulose Polymers 0.000 claims description 7
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims description 7
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 7
- PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical compound CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 7
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 6
- 238000005119 centrifugation Methods 0.000 claims description 6
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 6
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 5
- AFHOBSCDNXGFMO-UHFFFAOYSA-N [2-(hydroxymethyl)phenyl]boronic acid Chemical compound OCC1=CC=CC=C1B(O)O AFHOBSCDNXGFMO-UHFFFAOYSA-N 0.000 claims description 5
- 239000004202 carbamide Substances 0.000 claims description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 5
- 239000011975 tartaric acid Substances 0.000 claims description 5
- 235000002906 tartaric acid Nutrition 0.000 claims description 5
- 229910021538 borax Inorganic materials 0.000 claims description 4
- 239000012065 filter cake Substances 0.000 claims description 4
- 239000004328 sodium tetraborate Substances 0.000 claims description 4
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims description 4
- 239000000686 essence Substances 0.000 abstract description 18
- 108091005804 Peptidases Proteins 0.000 abstract description 5
- 239000004365 Protease Substances 0.000 abstract description 5
- 239000003086 colorant Substances 0.000 abstract description 5
- 238000004043 dyeing Methods 0.000 abstract description 3
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 16
- 235000005979 Citrus limon Nutrition 0.000 description 11
- 244000131522 Citrus pyriformis Species 0.000 description 11
- 238000005202 decontamination Methods 0.000 description 9
- 230000003588 decontaminative effect Effects 0.000 description 9
- 239000004744 fabric Substances 0.000 description 9
- 208000003251 Pruritus Diseases 0.000 description 8
- 239000000499 gel Substances 0.000 description 8
- 239000000843 powder Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 239000000975 dye Substances 0.000 description 5
- 239000008236 heating water Substances 0.000 description 5
- 238000005303 weighing Methods 0.000 description 5
- 102000035195 Peptidases Human genes 0.000 description 4
- 230000007803 itching Effects 0.000 description 4
- 239000011246 composite particle Substances 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 238000010186 staining Methods 0.000 description 3
- 239000005909 Kieselgur Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 2
- 230000001139 anti-pruritic effect Effects 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 229940079919 digestives enzyme preparation Drugs 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- -1 sodium alkyl sulfonate Chemical class 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 230000004083 survival effect Effects 0.000 description 2
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- 206010006784 Burning sensation Diseases 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 108010084185 Cellulases Proteins 0.000 description 1
- 102000005575 Cellulases Human genes 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- XINCECQTMHSORG-UHFFFAOYSA-N Isoamyl isovalerate Chemical compound CC(C)CCOC(=O)CC(C)C XINCECQTMHSORG-UHFFFAOYSA-N 0.000 description 1
- 244000178870 Lavandula angustifolia Species 0.000 description 1
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 1
- 235000006679 Mentha X verticillata Nutrition 0.000 description 1
- 235000002899 Mentha suaveolens Nutrition 0.000 description 1
- 235000001636 Mentha x rotundifolia Nutrition 0.000 description 1
- BLILOGGUTRWFNI-UHFFFAOYSA-N Monomenthyl succinate Chemical compound CC(C)C1CCC(C)CC1OC(=O)CCC(O)=O BLILOGGUTRWFNI-UHFFFAOYSA-N 0.000 description 1
- 241000132171 Phryma leptostachya Species 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 241000434639 Speranskia tuberculata Species 0.000 description 1
- 240000003243 Thuja occidentalis Species 0.000 description 1
- 235000008109 Thuja occidentalis Nutrition 0.000 description 1
- 241000499912 Trichoderma reesei Species 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001914 calming effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
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- 238000006731 degradation reaction Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
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- 239000000706 filtrate Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 241000411851 herbal medicine Species 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000001102 lavandula vera Substances 0.000 description 1
- 235000018219 lavender Nutrition 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-N sodium;sulfuric acid Chemical compound [H+].[H+].[Na+].[O-]S([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-N 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
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- 239000003381 stabilizer Substances 0.000 description 1
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- 239000000126 substance Substances 0.000 description 1
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- 238000003786 synthesis reaction Methods 0.000 description 1
- 150000003892 tartrate salts Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P17/00—Drugs for dermatological disorders
- A61P17/04—Antipruritics
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P17/00—Drugs for dermatological disorders
- A61P17/16—Emollients or protectives, e.g. against radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/043—Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/14—Diatomaceous earth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
- C08J3/075—Macromolecular gels
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/166—Organic compounds containing borium
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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Abstract
The invention discloses a multifunctional laundry detergent and a preparation process thereof, wherein the multifunctional laundry detergent comprises the following components: surfactant, essence, glycerol, folium Platycladi flavone extract, caulis et folium Gaultheriae Yunnanensis extract, cellulase, neutral protease, enzyme activity protectant, sodium sulfate, and water. The multifunctional laundry detergent contains protease, cellulase, an enzyme activity protective agent and an adsorbent, can effectively remove dirt, has high washing efficiency, and also has the function of preventing the dyeing problem caused by the shuffling of clothes with different colors.
Description
Technical Field
The invention relates to a laundry detergent and a preparation process thereof.
Background
The traditional washing powder and soap adopt anionic surfactants which mainly comprise sodium alkyl sulfonate and sodium stearate and have strong alkalinity, so that the soap has large irritation and damage to skin when in use, while the washing liquid mostly adopts nonionic surfactants, the pH value is close to neutral, the washing liquid is mild to skin, and after being discharged into the nature, the washing liquid is degraded faster than the washing powder, so the soap becomes a new generation of detergent. The other purpose of developing the laundry detergent is to overcome the defect of inconvenient powder use while maintaining the excellent washing performance of the washing powder. The laundry detergent can bring convenience to daily life of consumers, compared with powder products, the liquid products are easier to dissolve, especially under the condition of low temperature, dust is less in the production process, and metering is easy and accurate. The technical content of the laundry detergent is higher, various active ingredients are convenient to add, clothes are fluffy, soft, smooth and bright when being washed, and the laundry detergent has the effects of sterilization and lasting fragrance. The comprehensive use cost is low, and the method is widely accepted by people. The current research on laundry detergents is mainly focused on the protection of fabric appearance and color, and it is expected that the color and texture of the fabric can be kept better after the fabric is washed for a plurality of times. These techniques also include the continuous synthesis of new macromolecules to reduce dye transfer (cross-staining) during washing, the focus on the use of new enzyme preparations in laundry detergents and to reduce the breakdown of enzyme preparations, among others.
Due to the fact that the conventional laundry detergent is limited in decontamination effect, the application of the enzyme preparation in the laundry detergent obviously improves the use performance of the laundry detergent, not only on substrates acted by the enzyme preparation, such as grass stains and blood stains targeted by protease, but also improves the removal capacity of conventional stains. Since in actual stains the protein is often immobilized on the fabric along with other soils, removal of the protein may also help remove other soils mixed with the protein. However, the enzyme in the laundry detergent is often decomposed or inactivated in the process of long-term storage, so that the decontamination effect of the laundry detergent containing the enzyme is reduced, and how to maintain the activity of the enzyme becomes a problem to be solved urgently.
The current washing machine also faces a problem: when the clothes which are easy to fade are washed together with other clothes, other clothes are dyed, people often need to wash the clothes separately according to colors, and the traditional laundry detergent cannot solve the problems.
Compared with the traditional laundry detergent, the laundry detergent is low in alkalinity, mild in performance and free of damage to clothes and hands, but the laundry detergent is often added with Chinese herbal medicine extracts, antibacterial agents, antistatic agents, softening agents and other components, so that certain irritation such as itching and burning can be brought when the laundry detergent is used for hand washing, and how to improve the hand washing experience of a user is a problem needing to be researched.
The multifunctional laundry detergent contains a surfactant, protease, cellulase, an enzyme activity maintaining agent, a cacumen biotae flavone extract and a garden balsam stem extract which are scientifically proportioned, can effectively remove oil stains, blood stains, coloring agents and the like on clothes, is added with a novel adsorbent for adsorbing dyes and dirt and a freshener with a cooling and itching relieving effect, improves the use experience, and is soft, elastic and high in comfort level after being washed by the detergent.
Disclosure of Invention
The invention provides a multifunctional laundry detergent and a processing method thereof. The invention adopts the following technical scheme:
a multifunctional laundry detergent comprises the following components in parts by weight: 10-30 parts of surfactant, 0.2-2 parts of essence, 0.3-3 parts of glycerol, 0.02-0.2 part of cacumen biotae flavone extract, 0.04-0.4 part of garden balsam stem extract, 0.05-0.5 part of cellulase, 0.03-0.3 part of neutral protease, 3-9 parts of enzyme activity protective agent, 0.5-5 parts of sodium sulfate and 30-60 parts of water.
A multifunctional laundry detergent comprises the following components in parts by weight: 10-30 parts of surfactant, 0.2-2 parts of essence, 0.3-3 parts of glycerol, 0.02-0.2 part of cacumen biotae flavone extract, 0.04-0.4 part of garden balsam stem extract, 0.05-0.5 part of cellulase, 0.03-0.3 part of neutral protease, 3-9 parts of enzyme activity protective agent, 2-6 parts of adsorbent, 0.5-5 parts of sodium sulfate and 30-60 parts of water.
A multifunctional laundry detergent comprises the following components in parts by weight: 10-30 parts of surfactant, 0.2-2 parts of essence, 0.3-3 parts of glycerol, 0.02-0.2 part of cacumen biotae flavone extract, 0.04-0.4 part of garden balsam stem extract, 0.05-0.5 part of cellulase, 0.03-0.3 part of neutral protease, 3-9 parts of enzyme activity protective agent, 2-6 parts of adsorbent, 2-6 parts of freshener, 0.5-5 parts of sodium sulfate and 30-60 parts of water.
The surface activity is composed of the following raw materials in percentage by mass: 10 to 30 percent of cocamidopropyl betaine, 10 to 30 percent of dodecyl glucoside, 10 to 30 percent of sodium dodecyl benzene sulfonate and the balance of lauryl alcohol sulfate ammonium salt.
The essence can be apple essence, lemon essence, lavender essence, rose essence, etc. The essence specifically used in the invention is lemon essence.
The enzyme activity protective agent is preferably one of calcium borogluconate, 2-hydroxymethyl phenylboronic acid and borax, and is further preferably calcium borogluconate.
Laundry detergent formulations contain large amounts of water and therefore, for proteases, cellulases, stabilizers are necessary to prevent enzyme degradation during product storage. The enzyme activity protective agent and the enzyme are combined through hydrogen bond action, so that the stable survival of the enzyme is favorably kept, and the enzyme can be released when the laundry detergent is diluted, so that the decontamination washing effect is enhanced.
The preparation method of the adsorbent comprises the following steps: adding 5-15g of urea and 8-24g of sodium hydroxide into 80-240g of water, stirring for 20-60 minutes at the temperature of 25-35 ℃, cooling to the temperature of-10 to-5 ℃, adding 3-12g of cellulose, stirring for 2-8 hours at the temperature of-10 to-5 ℃, heating to the temperature of 25-35 ℃, adding 0.2-2g of sodium carbonate and 5-20g of diatomite, stirring for 20-60 minutes at the temperature of 25-35 ℃, adding 0.5-5mL of hydrochloric acid with the concentration of 0.5-5mol/L, stirring for 3-8 hours at the temperature of 25-35 ℃, sieving with a 500-mesh sieve of 100 meshes, washing a filter cake with 30-100g of ethanol and 30-100g of water, drying for 12-36 hours at the temperature of 35-55 ℃, drying the obtained product, tartaric acid, ethanol and water according to the mass ratio of (5-15): (1-5): (40-60): (8-12) Mixing, stirring at 25-35 deg.C for 20-60min, and drying at 50-80 deg.C for 12-36 hr to obtain adsorbent. Wherein the rotation speed of the stirring is 100-500 r/min.
The adsorbent added into the laundry detergent is composite particles of cellulose and diatomite, and the composite particles can better adsorb dirt and dye after being modified by tartaric acid, so that the effect of preventing clothes from being dyed is avoided while the washing effect is improved.
The preparation method of the freshener comprises the following steps: under the water bath heating condition of 40-70 ℃, uniformly mixing ethyl orthosilicate, 3-aminopropyltriethoxysilane, ethanol and water according to the mass ratio of (1-5) to (1-3) to (5-7) to obtain a mixed solution A, and under the water bath heating condition of 40-70 ℃, uniformly mixing menthyl monosuccinate, trans-p-menthane-3, 8-diol and ethanol according to the mass ratio of (1-5): (6-8): 60 to obtain a mixed solution B, uniformly mixing the mixed solution A and the mixed solution B according to the mass ratio of 5 (1-3), then placing the mixture in an open environment with the temperature of 25-35 ℃ and the relative humidity of 85-90% for 2-6 hours to form gel, centrifuging the gel, drying the precipitate obtained by centrifugation at the temperature of 35-70 ℃ for 12-36 hours, crushing the precipitate and sieving the precipitate with a 20-100-mesh sieve to obtain the freshener. Wherein the rotation speed during centrifugation is 3000-10000 r/min, and the centrifugation time is 20-60 min.
The laundry detergent contains the freshener, can solve the burning and itching feeling of the laundry detergent when being used for washing clothes by hands, has the cooling and calming effects, and can care hands. The added freshener is a composite structure containing silica gel and mint derivatives, has certain adsorption performance, and can also achieve the effect of adsorbing dirt and dye.
The invention also provides a preparation process of the multifunctional laundry detergent, which comprises the following steps: weighing the components of the laundry detergent according to the parts by weight, heating water to 50-80 ℃, adding the surfactant, the enzyme activity protective agent, the sodium sulfate and the glycerol under the stirring condition of the temperature of 50-80 ℃ and the rotating speed of 500 turns/min, then stirring for 1-3 hours at the temperature of 50-80 ℃ and the rotating speed of 800 turns/min, cooling to 30-40 ℃, adding the rest components, and stirring for 20-60 minutes at the temperature of 30-40 ℃ and the rotating speed of 500 turns/min to obtain the multifunctional laundry detergent.
The multifunctional laundry detergent contains protease, cellulase, an enzyme activity protective agent and an adsorbent, can effectively remove dirt, has high washing efficiency, and also has the function of preventing the dyeing problem caused by the shuffling of clothes with different colors.
On the basis of the common knowledge in the field, the above preferred conditions can be combined randomly to obtain the preferred embodiments of the invention.
Detailed Description
The invention is further illustrated by the following examples, which are not intended to limit the scope of the invention. The experimental methods without specifying specific conditions in the following examples were selected according to the conventional methods and conditions, or according to the commercial instructions.
In the following examples, the main raw materials and equipment used were as follows:
cellulase, CAS number: 9012-54-8, which is a high-efficiency cellulase preparation prepared by refining trichoderma reesei (Latin chemical name: Trichodermaresei) through procedures of liquid submerged fermentation, ultrafiltration and the like, and specifically uses cellulase with the type of 7000 full-component type, and the enzyme activity is as follows: 7000u/g, purchased from Ningxia Xiesheng industry group Co.
Neutral protease, CAS No.: 9068-59-1. Enzyme activity: 50 u/mg. Purchased from Shanghai Aladdin Biotechnology, Inc., product number: D195752.
glycerol, CAS number: 56-81-5.
Sodium sulfate, i.e., thenardite, CAS number: 7757-82-6.
Calcium borogluconate, CAS No.: 5743-34-0.
2-hydroxymethylphenylboronic acid, CAS No.: 87199-14-2.
Borax, CAS No.: 1303-96-4, particle size: 80 mesh, first grade, performance criteria: GB537-97, purchased from Xindong chemical Co., Ltd, Yingkou City.
Lemon flavor, model 6133, manufactured by Guangzhou Baihua spices GmbH.
The arborvitae tops flavone extract can be purchased or prepared. The cacumen Platycladi is the branch tip and leaf of cacumen Platycladi (Latin scientific name: Platychaeta orientalis (L.). Franco), and the flavone extract of cacumen Platycladi (Shandong, produced in Shandong province) used in the present invention is prepared according to the method of example 4 in application No. 201410785394.6.
The garden balsam stem extract can be purchased or prepared, and the garden balsam stem extract is prepared by the following method: taking 150g of whole plant of garden balsam stem (the Latin scientific name: Phryma leptostachya L.subsp.asitica (Hara) Kitamura), drying at 40 ℃ for 12 hours, then crushing and sieving with a 50-mesh sieve to obtain garden balsam stem powder, taking 95g of garden balsam stem powder, adding into 700g of water, preserving the heat at 30 ℃ for 10 hours, then heating to 72 ℃, stirring at 72 ℃ for 2 hours at a rotating speed of 200 revolutions per minute, sieving with a 100-mesh sieve, evaporating and concentrating the filtrate to a thick paste with a relative density of 1.27 measured at 30 ℃, drying the thick paste at 50 ℃ and a vacuum degree of 0.04MPa for 12 hours to obtain the garden balsam stem extract.
Dodecyl glucoside, CAS number: 110615-47-9.
Cocamidopropyl betaine, CAS No.: 86438-79-1.
Ammonium lauryl sulfate, CAS No.: 2235-54-3.
Sodium dodecylbenzenesulfonate, CAS No.: 25155-30-0.
Urea, CAS No.: 57-13-6.
Sodium hydroxide, CAS No.: 1310-73-2.
Cellulose, model PH102, brand CEOLUS, manufacturer: asahi Kabushiki Kaisha.
Sodium carbonate, CAS: 497-19-8.
Diatomaceous earth, silica content ≧ 85%, type RS1280, manufacturer: guangzhou Yikang New Material science and technology, Inc.
Ethanol, CAS: 64-17-5 percent and the purity of 99.9 percent, which is provided by Huachang chemical Co., Ltd, Shenzhen city.
Tartaric acid, CAS number: 526-83-0.
Tetraethoxysilane, CAS: 78-10-4.
3-aminopropyltriethoxysilane, CAS number 919-30-2.
Menthyl monosuccinate, CAS No.: 77341-67-4.
Trans-p-menthane-3, 8-diol, CAS No.: 3564-98-5.
In the following examples, the test methods used are as follows:
test 1: stain removal test
And testing the difference value of the whiteness values of the JB-02 dirty cloth before washing and the JB-02 dirty cloth after washing by using the multifunctional laundry detergent according to GB/T13174-2008. And (3) dividing the whiteness difference result of the multifunctional laundry detergent before and after decontamination and washing of the JB-02 dirty cloth by the whiteness difference result of the standard laundry detergent before and after decontamination and washing of the JB-02 dirty cloth to obtain a decontamination index, and evaluating the decontamination effect. The experimental conditions were: the method adopts 250ppm hard water, the concentration of the multifunctional laundry detergent is 2g/L (namely 2g of the multifunctional laundry detergent is contained in every 1L of water), the washing time is 20 minutes, the temperature is 30 ℃, a specified RQHL vertical washing machine is adopted, and the rotating speed is 60 revolutions per minute.
And (3) testing 2: test for antipruritic Effect
Diluting the multifunctional laundry detergent with water at 25 ℃, fully stirring to obtain the multifunctional laundry detergent diluent with the concentration of 2g/L, then extending the hands of volunteers into a basin containing the multifunctional laundry detergent diluent, soaking for 30 seconds, and taking 20 volunteers to perform hand feeling test and scoring, wherein the hand feeling test and scoring are carried out for more than 2 minutes and less than 3 minutes to indicate that the laundry detergent is not itchy completely, the hand feeling test and scoring are carried out for more than 1 minute and less than 2 minutes to indicate that the laundry detergent is slightly itchy, the hand feeling test and scoring are carried out for more than 0 minute and less than 1 minute to indicate that the laundry detergent is obviously itchy, and a comparison sample (aqueous solution containing 50% of soda and 50% of sodium sulfate) is 0 minute to indicate that the laundry detergent is severely itchy. Compared with the test results of each group of examples and comparative examples, P is less than 0.05.
And (3) testing: test of anti-staining Effect
The whiteness values of white cotton cloth (according to GB/T7568.2-2008) before washing and after washing with the multifunctional laundry detergent of the invention were tested according to GB/T13174-2008. The higher the whiteness value, the better the stain-proofing effect. The experimental conditions were: after the washing machine is filled with water, 4mL of 1% by mass reactive brilliant blue KN-R solution is added, and then the test is carried out according to the experimental conditions of the test 1.
The invention is further illustrated by the following examples, in which the parts are by weight unless otherwise specified.
Example 1
The multifunctional laundry detergent comprises the following components in parts by weight: 25 parts of surfactant, 0.5 part of lemon essence, 1.5 parts of glycerol, 0.15 part of cacumen biotae flavone extract, 0.08 part of garden balsam stem extract, 0.25 part of cellulase, 0.15 part of neutral protease, 5.5 parts of enzyme activity protective agent, 0.5 part of sodium sulfate and 40 parts of water.
The surface activity is composed of the following raw materials in percentage by mass: 25% of cocamidopropyl betaine, 30% of dodecyl glucoside, 15% of sodium dodecyl benzene sulfonate and the balance of lauryl alcohol sulfate ammonium salt.
The enzyme activity protective agent is calcium borogluconate.
The preparation process of the multifunctional laundry detergent comprises the following steps: weighing the components of the laundry detergent according to parts by weight, heating water to 70 ℃, adding the surfactant, the enzyme activity protective agent, the sodium sulfate and the glycerol under the condition of stirring at the temperature of 70 ℃ and the rotating speed of 300 revolutions per minute, then stirring at the temperature of 70 ℃ and the rotating speed of 500 revolutions per minute for 1 hour, cooling to 35 ℃, adding the cacumen biotae flavone extract, the garden balsam stem extract, the cellulase, the neutral protease and the lemon essence, and stirring at the temperature of 35 ℃ and the rotating speed of 300 revolutions per minute for 30 minutes to obtain the multifunctional laundry detergent.
Example 2
Essentially the same as example 1, except that: in this example 2, the enzyme activity protecting agent is 2-hydroxymethylphenylboronic acid.
Example 3
Essentially the same as example 1, except that: in this example 3, the enzyme activity protecting agent is borax.
Example 4
The multifunctional laundry detergent comprises the following components in parts by weight: 25 parts of surfactant, 0.5 part of lemon essence, 1.5 parts of glycerol, 0.15 part of cacumen biotae flavone extract, 0.08 part of garden balsam stem extract, 0.25 part of cellulase, 0.15 part of neutral protease, 5.5 parts of enzyme activity protective agent, 0.5 part of sodium sulfate, 2.5 parts of adsorbent and 40 parts of water.
The surface activity is composed of the following raw materials in percentage by mass: 25% of cocamidopropyl betaine, 30% of dodecyl glucoside, 15% of sodium dodecyl benzene sulfonate and the balance of lauryl alcohol sulfate ammonium salt.
The enzyme activity protective agent is calcium borogluconate.
The preparation method of the adsorbent comprises the following steps: adding 7.5g urea and 13g sodium hydroxide into 100g water, stirring at 30 deg.C and 200 r/min for 40min, cooling to-8 deg.C, adding 6g cellulose, stirring at-8 deg.C and 150 rpm for 5 hr, heating to 30 deg.C, adding 1g sodium carbonate and 10g diatomaceous earth, stirring at 30 ℃ and 150 rpm for 40 minutes, adding 2mL of hydrochloric acid with the concentration of 1mol/L, stirring for 5 hours at the rotating speed of 150 rpm at the temperature of 30 ℃, sieving by a 300-mesh sieve, washing a filter cake by 50g of ethanol and 50g of water, drying for 24 hours at the temperature of 40 ℃, uniformly mixing a product obtained by drying, tartaric acid, ethanol and water according to the mass ratio of 10:3:50:10, stirring at 30 deg.C and 200 rpm for 40min, and drying at 60 deg.C for 24 hr to obtain adsorbent.
The preparation process of the multifunctional laundry detergent comprises the following steps: weighing the components of the laundry detergent according to parts by weight, heating water to 70 ℃, adding the surfactant, the enzyme activity protective agent, the sodium sulfate and the glycerol under the condition of stirring at the temperature of 70 ℃ at the rotating speed of 300 revolutions per minute, then stirring at the temperature of 70 ℃ at the rotating speed of 500 revolutions per minute for 1 hour, cooling to 35 ℃, adding the cacumen biotae flavone extract, the garden balsam stem extract, the cellulase, the neutral protease, the adsorbent and the lemon essence, and stirring at the temperature of 35 ℃ at the rotating speed of 300 revolutions per minute for 30 minutes to obtain the multifunctional laundry detergent.
Example 5
The multifunctional laundry detergent comprises the following components in parts by weight: 25 parts of surfactant, 0.5 part of lemon essence, 1.5 parts of glycerol, 0.15 part of cacumen biotae flavone extract, 0.08 part of garden balsam stem extract, 0.25 part of cellulase, 0.15 part of neutral protease, 5.5 parts of enzyme activity protective agent, 0.5 part of sodium sulfate, 2.5 parts of adsorbent, 2 parts of freshener and 40 parts of water.
The surface activity is composed of the following raw materials in percentage by mass: 25% of cocamidopropyl betaine, 30% of dodecyl glucoside, 15% of sodium dodecyl benzene sulfonate and the balance of lauryl alcohol sulfate ammonium salt.
The enzyme activity protective agent is calcium borogluconate.
The preparation method of the adsorbent is the same as that of example 4.
The preparation method of the freshener comprises the following steps: under the water bath heating condition of 50 ℃, uniformly mixing ethyl orthosilicate, 3-aminopropyltriethoxysilane, ethanol and water according to the mass ratio of 3:2:6:10 to obtain a mixed solution A, and under the water bath heating condition of 50 ℃, mixing mono-menthyl succinate, trans-p-menthane-3, 8-diol and ethanol according to the mass ratio of 3: 7: 60 to obtain a mixed solution B, uniformly mixing the mixed solution A and the mixed solution B according to the mass ratio of 5:1, then placing the mixture in an open environment with the temperature of 25 ℃ and the relative humidity of 85% for 3 hours to form gel, centrifuging the gel at the rotating speed of 5000 r/min for 40 minutes, drying the precipitate obtained by centrifuging at the temperature of 45 ℃ for 24 hours, crushing and sieving by a 50-mesh sieve to obtain the freshener.
The preparation process of the multifunctional laundry detergent comprises the following steps: weighing the components of the laundry detergent according to the parts by weight, heating water to 70 ℃, adding the surfactant, the enzyme activity protective agent, the sodium sulfate and the glycerol under the condition of stirring at the temperature of 70 ℃ at the rotating speed of 300 revolutions per minute, then stirring at the temperature of 70 ℃ for 1 hour at the rotating speed of 500 revolutions per minute, cooling to 35 ℃, adding the cacumen biotae flavone extract, the garden balsam stem extract, the cellulase, the neutral protease, the adsorbent, the freshener and the lemon essence, and stirring at the temperature of 35 ℃ at the rotating speed of 300 revolutions per minute for 30 minutes to obtain the multifunctional laundry detergent.
Comparative example 1
The multifunctional laundry detergent comprises the following components in parts by weight: 25 parts of surfactant, 0.5 part of lemon essence, 1.5 parts of glycerol, 0.15 part of cacumen biotae flavone extract, 0.08 part of garden balsam stem extract, 0.25 part of cellulase, 0.15 part of neutral protease, 0.5 part of sodium sulfate and 40 parts of water.
The surface activity is composed of the following raw materials in percentage by mass: 25% of cocamidopropyl betaine, 30% of dodecyl glucoside, 15% of sodium dodecyl benzene sulfonate and the balance of lauryl alcohol sulfate ammonium salt.
The preparation process of the multifunctional laundry detergent comprises the following steps: weighing the components of the laundry detergent according to parts by weight, heating water to 70 ℃, adding the surfactant, the sodium sulfate and the glycerol under the condition of stirring at 70 ℃ and the rotating speed of 300 revolutions per minute, then stirring at 70 ℃ and the rotating speed of 500 revolutions per minute for 1 hour, cooling to 35 ℃, adding the cacumen platycladi flavone extract, the speranskia tuberculata extract, the cellulase, the neutral protease and the lemon essence, and stirring at 35 ℃ and the rotating speed of 300 revolutions per minute for 30 minutes to obtain the multifunctional laundry detergent.
Comparative example 2
Substantially the same as example 4 except that, in comparative example 2, the adsorbent was prepared by: adding 7.5g of urea and 13g of sodium hydroxide into 100g of water, stirring at 30 ℃ and 200 rpm for 40 minutes, cooling to-8 ℃, adding 6g of cellulose, stirring at-8 ℃ and 150 rpm for 5 hours, heating to 30 ℃, adding 1g of sodium carbonate and 10g of diatomite, stirring at 30 ℃ and 150 rpm for 40 minutes, adding 2mL of hydrochloric acid with the concentration of 1mol/L, stirring at 30 ℃ and 150 rpm for 5 hours, sieving with a 300-mesh sieve, washing a filter cake with 50g of ethanol and 50g of water, and drying at 40 ℃ for 24 hours to obtain the adsorbent.
Comparative example 3
Substantially the same as example 5 except that, in this comparative example 3, the cooling agent was prepared by: under the water bath heating condition of 50 ℃, uniformly mixing ethyl orthosilicate, 3-aminopropyltriethoxysilane, ethanol and water according to the mass ratio of 3:2:6:10 to obtain a mixed solution A, and under the water bath heating condition of 50 ℃, mixing menthyl monosuccinate and ethanol according to the mass ratio of 10: 60 to obtain a mixed solution B, uniformly mixing the mixed solution A and the mixed solution B according to the mass ratio of 5:1, then placing the mixture in an open environment with the temperature of 25 ℃ and the relative humidity of 85% for 3 hours to form gel, centrifuging the gel at the rotating speed of 5000 r/min for 40 minutes, drying the precipitate obtained by centrifuging at the temperature of 45 ℃ for 24 hours, crushing and sieving by a 50-mesh sieve to obtain the freshener.
Comparative example 4
Substantially the same as example 5 except that, in comparative example 4, the cooling agent was prepared by: under the water bath heating condition of 50 ℃, uniformly mixing ethyl orthosilicate, 3-aminopropyltriethoxysilane, ethanol and water according to the mass ratio of 3:2:6:10 to obtain a mixed solution A, and under the water bath heating condition of 50 ℃, mixing trans-p-menthane-3, 8-diol and ethanol according to the mass ratio of 10: 60 to obtain a mixed solution B, uniformly mixing the mixed solution A and the mixed solution B according to the mass ratio of 5:1, then placing the mixture in an open environment with the temperature of 25 ℃ and the relative humidity of 85% for 3 hours to form gel, centrifuging the gel at the rotating speed of 5000 r/min for 40 minutes, drying the precipitate obtained by centrifuging at the temperature of 45 ℃ for 24 hours, crushing and sieving by a 50-mesh sieve to obtain the freshener.
Effect testing
Table 1: decontamination effect test result table
| Index of stain removal | |
| Example 1 | 3.42 |
| Example 2 | 3.33 |
| Example 3 | 3.29 |
| Example 4 | 3.64 |
| Example 5 | 3.75 |
| Comparative example 1 | 3.20 |
| Comparative example 2 | 3.53 |
| Comparative example 3 | 3.66 |
| Comparative example 4 | 3.69 |
Table 2: anti-staining effect test result table
| Whiteness value before washing | Whiteness value after washing | |
| Example 1 | 88.4 | 85.6 |
| Example 2 | 88.5 | 85.4 |
| Example 3 | 88.3 | 85.1 |
| Example 4 | 88.4 | 87.3 |
| Example 5 | 88.3 | 88.2 |
| Comparative example 1 | 88.5 | 83.5 |
| Comparative example 2 | 88.4 | 86.8 |
| Comparative example 3 | 88.5 | 87.5 |
| Comparative example 4 | 88.4 | 87.7 |
Table 3: test result table for antipruritic effect
The liquid laundry detergent contains an enzyme activity protective agent, the enzyme activity protective agent and the enzyme are combined through hydrogen bond action, so that the stable survival of the enzyme is favorably kept, and the enzyme can be released when the liquid laundry detergent is diluted, so that the decontamination washing effect is enhanced. The adsorbent added into the laundry detergent is composite particles of cellulose and diatomite, and the modified tartaric acid has better effect of adsorbing dirt and dye, improves the washing effect and can prevent the dyeing problem caused by the shuffling of clothes with different colors. The freshener added into the laundry detergent can solve the problems of itching and burning sensation of the laundry detergent when the laundry detergent is used for washing clothes by hands, does not hurt hands, and improves user experience.
The foregoing detailed description of the preferred embodiments of the invention has been presented. It should be understood that numerous modifications and variations could be devised by those skilled in the art in light of the present teachings without departing from the inventive concepts. Therefore, the technical solutions available to those skilled in the art through logic analysis, reasoning and limited experiments based on the prior art according to the concept of the present invention should be within the scope of protection defined by the claims.
Claims (7)
1. The multifunctional laundry detergent is characterized by comprising the following components in parts by weight: 10-30 parts of surfactant, 0.2-2 parts of essence, 0.3-3 parts of glycerol, 0.02-0.2 part of cacumen biotae flavone extract, 0.04-0.4 part of garden balsam stem extract, 0.05-0.5 part of cellulase, 0.03-0.3 part of neutral protease, 3-9 parts of enzyme activity protective agent, 0.5-5 parts of sodium sulfate, 30-60 parts of water, 2-6 parts of adsorbent and 2-6 parts of freshener;
the preparation method of the freshener comprises the following steps: under the water bath heating condition of 40-70 ℃, uniformly mixing ethyl orthosilicate, 3-aminopropyltriethoxysilane, ethanol and water according to the mass ratio of (1-5) to (1-3) to (5-7) to obtain a mixed solution A, and under the water bath heating condition of 40-70 ℃, uniformly mixing menthyl monosuccinate, trans-p-menthane-3, 8-diol and ethanol according to the mass ratio of (1-5): (6-8): 60 to obtain a mixed solution B, uniformly mixing the mixed solution A and the mixed solution B according to the mass ratio of 5 (1-3), then placing the mixture in an open environment with the temperature of 25-35 ℃ and the relative humidity of 85-90% for 2-6 hours to form gel, centrifuging the gel, drying the precipitate obtained by centrifugation at the temperature of 35-70 ℃ for 12-36 hours, crushing the precipitate and sieving the crushed precipitate by a 20-100-mesh sieve to obtain the freshener.
2. The multifunctional laundry detergent of claim 1, wherein the adsorbent is prepared by the following method: adding 5-15g of urea and 8-24g of sodium hydroxide into 80-240g of water, stirring for 20-60 minutes at the temperature of 25-35 ℃, cooling to the temperature of-10 to-5 ℃, adding 3-12g of cellulose, stirring for 2-8 hours at the temperature of-10 to-5 ℃, heating to the temperature of 25-35 ℃, adding 0.2-2g of sodium carbonate and 5-20g of diatomite, stirring for 20-60 minutes at the temperature of 25-35 ℃, adding 0.5-5mL of hydrochloric acid with the concentration of 0.5-5mol/L, stirring for 3-8 hours at the temperature of 25-35 ℃, sieving with a 500-mesh sieve of 100 meshes, washing a filter cake with 30-100g of ethanol and 30-100g of water, drying for 12-36 hours at the temperature of 35-55 ℃, drying the obtained product, tartaric acid, ethanol and water according to the mass ratio of (5-15): (1-5): (40-60): (8-12) The adsorbent is obtained by uniformly mixing, stirring at 25-35 deg.C for 20-60min, and drying at 50-80 deg.C for 12-36 hr.
3. The multifunctional laundry detergent of claim 1, wherein the surfactant comprises the following raw materials in percentage by mass: 10 to 30 percent of cocamidopropyl betaine, 10 to 30 percent of dodecyl glucoside, 10 to 30 percent of sodium dodecyl benzene sulfonate and the balance of lauryl alcohol sulfate ammonium salt.
4. The multifunctional laundry detergent of claim 1, wherein the enzyme activity protecting agent is one of calcium borogluconate, 2-hydroxymethylphenylboronic acid and borax.
5. The multifunctional laundry detergent of claim 2, wherein the stirring speed is 100-500 rpm.
6. The multifunctional laundry detergent as claimed in claim 1, wherein the rotation speed during centrifugation is 3000-10000 rpm, and the centrifugation time is 20-60 minutes.
7. The preparation process of the multifunctional laundry detergent as claimed in any one of claims 1-2, wherein the components of the laundry detergent are weighed according to the parts by weight, water is heated to 50-80 ℃, the surfactant, the enzyme activity protective agent, the sodium sulfate and the glycerol are added under the stirring condition of 50-80 ℃ and the rotation speed of 500 revolutions per minute of 100-.
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| CN107922882A (en) * | 2015-09-08 | 2018-04-17 | 西姆莱斯股份公司 | spice mixture |
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| CN103468429B (en) * | 2013-09-29 | 2015-10-21 | 浙江海洋学院 | A kind of for the natural liquid laundry detergent in ultraviolet washing machine and preparation method |
| CN103991872B (en) * | 2014-05-09 | 2015-11-25 | 山东大学 | The method of a kind of Organic Alcohol/sour low-temperature growth height oxygen-containing functional group gac |
| US10494330B2 (en) * | 2015-03-25 | 2019-12-03 | Takasago International Corporation | Methyl menthol derivative and cooling agent composition containing same |
| CN104893847A (en) * | 2015-05-11 | 2015-09-09 | 潘海峰 | Special washing liquid for lady panties |
| CN105733827B (en) * | 2016-01-20 | 2017-11-03 | 广州立白企业集团有限公司 | A kind of not hot laundry powder composition |
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| CN107922882A (en) * | 2015-09-08 | 2018-04-17 | 西姆莱斯股份公司 | spice mixture |
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