CN108410596A - Multifunctional laundry liquid and its preparation process - Google Patents
Multifunctional laundry liquid and its preparation process Download PDFInfo
- Publication number
- CN108410596A CN108410596A CN201810432466.7A CN201810432466A CN108410596A CN 108410596 A CN108410596 A CN 108410596A CN 201810432466 A CN201810432466 A CN 201810432466A CN 108410596 A CN108410596 A CN 108410596A
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- China
- Prior art keywords
- parts
- multifunctional laundry
- laundry liquid
- water
- hours
- Prior art date
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- 239000007788 liquid Substances 0.000 title claims abstract description 94
- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- 102000004190 Enzymes Human genes 0.000 claims abstract description 49
- 108090000790 Enzymes Proteins 0.000 claims abstract description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 46
- 230000000694 effects Effects 0.000 claims abstract description 45
- 229940088598 enzyme Drugs 0.000 claims abstract description 45
- 239000000284 extract Substances 0.000 claims abstract description 42
- 239000003599 detergent Substances 0.000 claims abstract description 37
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 33
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 31
- 230000001012 protector Effects 0.000 claims abstract description 24
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- VHBFFQKBGNRLFZ-UHFFFAOYSA-N vitamin p Natural products O1C2=CC=CC=C2C(=O)C=C1C1=CC=CC=C1 VHBFFQKBGNRLFZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 108010059892 Cellulase Proteins 0.000 claims abstract description 15
- 229940106157 cellulase Drugs 0.000 claims abstract description 15
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 15
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 15
- 235000008109 Thuja occidentalis Nutrition 0.000 claims abstract description 12
- GAMYVSCDDLXAQW-AOIWZFSPSA-N Thermopsosid Natural products O(C)c1c(O)ccc(C=2Oc3c(c(O)cc(O[C@H]4[C@H](O)[C@@H](O)[C@H](O)[C@H](CO)O4)c3)C(=O)C=2)c1 GAMYVSCDDLXAQW-AOIWZFSPSA-N 0.000 claims abstract description 11
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- 240000003243 Thuja occidentalis Species 0.000 claims abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 44
- 235000019441 ethanol Nutrition 0.000 claims description 25
- 238000003756 stirring Methods 0.000 claims description 16
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 10
- 229920002678 cellulose Polymers 0.000 claims description 9
- 235000010980 cellulose Nutrition 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical class [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 8
- 238000005119 centrifugation Methods 0.000 claims description 8
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- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 7
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 6
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- 235000002906 tartaric acid Nutrition 0.000 claims description 6
- 239000011975 tartaric acid Substances 0.000 claims description 6
- WEEGYLXZBRQIMU-UHFFFAOYSA-N Eucalyptol Chemical compound C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 claims description 5
- 239000004202 carbamide Substances 0.000 claims description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
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- 235000011121 sodium hydroxide Nutrition 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
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- HXITXNWTGFUOAU-UHFFFAOYSA-N phenylboronic acid Chemical compound OB(O)C1=CC=CC=C1 HXITXNWTGFUOAU-UHFFFAOYSA-N 0.000 claims description 3
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- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
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- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims 1
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- 230000001139 anti-pruritic effect Effects 0.000 abstract description 5
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- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 6
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- BLILOGGUTRWFNI-UHFFFAOYSA-N Monomenthyl succinate Chemical compound CC(C)C1CCC(C)CC1OC(=O)CCC(O)=O BLILOGGUTRWFNI-UHFFFAOYSA-N 0.000 description 4
- 229930182478 glucoside Natural products 0.000 description 4
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- 238000004519 manufacturing process Methods 0.000 description 4
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- 235000017550 sodium carbonate Nutrition 0.000 description 4
- 238000010790 dilution Methods 0.000 description 3
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- -1 sodium alkyl sulfonate Chemical class 0.000 description 3
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- 244000025254 Cannabis sativa Species 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
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- XINCECQTMHSORG-UHFFFAOYSA-N Isoamyl isovalerate Chemical compound CC(C)CCOC(=O)CC(C)C XINCECQTMHSORG-UHFFFAOYSA-N 0.000 description 1
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- KXLYRTSEXNEABR-UHFFFAOYSA-N [2-(hydroxymethyl)phenoxy]boronic acid Chemical class OCC1=CC=CC=C1OB(O)O KXLYRTSEXNEABR-UHFFFAOYSA-N 0.000 description 1
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
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- HJCCZIABCSDUPE-UHFFFAOYSA-N methyl 2-[4-[[4-methyl-6-(1-methylbenzimidazol-2-yl)-2-propylbenzimidazol-1-yl]methyl]phenyl]benzoate Chemical compound CCCC1=NC2=C(C)C=C(C=3N(C4=CC=CC=C4N=3)C)C=C2N1CC(C=C1)=CC=C1C1=CC=CC=C1C(=O)OC HJCCZIABCSDUPE-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P17/00—Drugs for dermatological disorders
- A61P17/04—Antipruritics
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P17/00—Drugs for dermatological disorders
- A61P17/16—Emollients or protectives, e.g. against radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/043—Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/14—Diatomaceous earth
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
- C08J3/075—Macromolecular gels
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/166—Organic compounds containing borium
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
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- C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2383/04—Polysiloxanes
- C08J2383/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
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Abstract
The invention discloses a kind of multifunctional laundry liquid and its preparation process, the multifunctional laundry liquid includes following components：Surfactant, essence, glycerine, arbor-vitae leaf flavone extract, Herba speranskiae tuberculatae extract, cellulase, neutral proteinase, protector of enzyme activity, sodium sulphate, water.Contain protease, cellulase, protector of enzyme activity, adsorbent in the multifunctional laundry liquid of the present invention; dirt can be effectively removed; detersive efficiency is high; also having prevents different colours clothing from shuffling caused colouring problem; the freshener component contained in liquid detergent makes liquid detergent for having refrigerant, antipruritic, the effect not hurt hands when hand-washing.
Description
Technical field
The present invention relates to a kind of liquid detergent and its preparation processes.
Background technology
Traditional washing powder, soap are with sodium alkyl sulfonate and odium stearate using anionic surfactant
Based on, alkalinity is stronger, and then larger to the stimulation of skin and injury when in use, and liquid detergent mostly uses non-ionic surface work
Property agent, PH is mild to skin close to neutrality, and after being discharged into nature, degradation is fast compared with washing powder, so becoming a new generation
Detergent.Another purpose of development liquid detergent is to while holding washing powder excellent scourability, powder be overcome to make
With inconvenient disadvantage.Liquid detergent can bring many facilities to the daily life of consumer, compared with powder product, liquid production
Product are more prone to dissolve, and especially at low temperatures, dust in process of production is less, and metering is easy and accurate.Laundry
The technology content higher of liquid, convenient for adding various active ingredients, washing can enable clothing fluffy, soft, smooth glossy, and has and remove
The effect of bacterium and lasting lasting.It is low using overall cost, just widely received by people.It is main about the research of liquid detergent at present
It concentrates in the protection to appearance of fabrics and color, it is desirable to which after fabric is by repeatedly washing, color and texture keep relatively good.This
Also include persistently synthesizing new macromolecule to shift (colour contamination) to reduce the dyestuff in washing process in a little technologies, is absorbed in novel enzyme
The decomposition etc. of application and reduction enzyme preparation of the preparation in liquid detergent.
Since the clean effect of traditional liquid detergent is limited, the application of enzyme preparation in liquid detergent makes the performance of liquid detergent
Have and be obviously improved, be not only directed on the substrate of enzyme preparation effect, such as the careless stain that is directed to of protease and bloodstain, simultaneously
The removal ability to conventional spot can also be improved.Because in practical spot, protein is often together with other dirts
It fixes on the fabric, the removal of protein can also help to remove other dirts mixed with protein.But it does washing
Often solution decomposes or loses activity enzyme in prolonged storage in liquid, to reduce the clean effect of the liquid detergent containing enzyme,
The activity of enzyme how is kept to become a urgent problem to be solved.
A problem is also faced with when being washed at present with washing machine：When the clothes of fugitive color washs together with other clothes
Other clothes are dyed, people generally require to carry out by color Wash Separately, and traditional liquid detergent cannot solve the above problems.
For the traditional laundry detergents of comparison, liquid detergent alkalinity is relatively low, although performance is milder, will not damaging laundry and hand,
But the ingredients such as Chinese herbal medicine extract, antiseptic, antistatic agent, softener are usually added in liquid detergent, when for hand-washing use
Still certain excitements such as itch, is scorching hot may be brought, the hand washing experience of user how is improved and is also one and need to study
Problem.
The present invention provides a kind of multifunctional laundry liquid and its processing method, contain scientific matching in liquid detergent of the invention
Surfactant, protease, cellulase, enzymatic activity retention agent, arbor-vitae leaf flavone extract, Herba speranskiae tuberculatae extract, can have
Oil stain, bloodstain, coloring agent etc. on effect removal clothing, also added the novel adsorption for adsorbing dyestuff, dirt in liquid detergent
Agent, the freshener for playing refrigerant antipruritic effect improve usage experience, the clothing after the washing of the detergent of the present invention is soft,
High resilience, comfort level are high.
Invention content
The present invention provides a kind of multifunctional laundry liquid and its processing methods.The present invention adopts the following technical scheme that：
A kind of multifunctional laundry liquid, including following components in parts by weight：10-30 parts of surfactants, 0.2-2 parts of essence,
0.3-3 parts of glycerine, 0.02-0.2 parts of arbor-vitae leaf flavone extracts, 0.04-0.4 parts of Herba speranskiae tuberculatae extracts, 0.05-0.5 parts of fibers
Plain enzyme, 0.03-0.3 part neutral proteinase, 3-9 parts of protector of enzyme activity, 0.5-5 parts of sodium sulphate, 30-60 parts of water.
A kind of multifunctional laundry liquid, including following components in parts by weight：10-30 parts of surfactants, 0.2-2 parts of essence,
0.3-3 parts of glycerine, 0.02-0.2 parts of arbor-vitae leaf flavone extracts, 0.04-0.4 parts of Herba speranskiae tuberculatae extracts, 0.05-0.5 parts of fibers
Plain enzyme, 0.03-0.3 part neutral proteinase, 3-9 parts of protector of enzyme activity, 2-6 parts of adsorbents, 0.5-5 parts of sodium sulphate, 30-60 parts
Water.
A kind of multifunctional laundry liquid, including following components in parts by weight：10-30 parts of surfactants, 0.2-2 parts of essence,
0.3-3 parts of glycerine, 0.02-0.2 parts of arbor-vitae leaf flavone extracts, 0.04-0.4 parts of Herba speranskiae tuberculatae extracts, 0.05-0.5 parts of fibers
Plain enzyme, 0.03-0.3 part neutral proteinase, 3-9 parts of protector of enzyme activity, 2-6 parts of adsorbents, 2-6 portions of fresheners, 0.5-5 parts of sulphur
Sour sodium, 30-60 part water.
The surface-active is made of the raw material of following mass percents：10%-30% Cocoamidopropyl betaines,
10%-30% lauryl glucosyls, 10%-30% neopelexes, surplus are laruyl alcohol sulfate ammonium salt.
The essence can be flavoring apple essence, lemon extract, lavender oil, flavoring rose essence etc..The present invention is specifically used
Essence be lemon extract.
The protector of enzyme activity is preferably one kind in caclium diborogluconate, 2- methylols phenyl boric acid, borax, further
Preferably caclium diborogluconate.
Contain a large amount of water in laundry liquid formulation, therefore for protease, cellulase, it is necessary to have stabilizer with
Prevent decomposition of the enzyme in product shelf life.It is combined, is conducive to by hydrogen bond action between the protector of enzyme activity and enzyme of the present invention
Keep enzyme stablizes survival, enzyme can be released again when liquid detergent is diluted, to reinforce decontamination washing effect.
The preparation method of heretofore described adsorbent is as follows：80-240g is added in 5-15g urea, 8-24g sodium hydroxides
It in water, is stirred 20-60 minutes at 25-35 DEG C, is cooled to -10~-5 DEG C, 3-12g celluloses are added, 2- is stirred at -10~-5 DEG C
8 hours, it is warming up to 25-35 DEG C, 0.2-2g sodium carbonate, 5-20g diatomite is added, is stirred 20-60 minutes at 25-35 DEG C, is added
The hydrochloric acid 0.5-5mL of a concentration of 0.5-5mol/L is stirred 3-8 hours at 25-35 DEG C, 100-500 mesh sieve is crossed, by filter cake 30-
100g ethyl alcohol, 30-100g water are 12-36 hours dry at 35-55 DEG C after rinsing, by dry products therefrom, tartaric acid, ethyl alcohol, water
It is in mass ratio (5-15):(1-5):(40-60):The ratio of (8-12) is uniformly mixed, and 20-60min is stirred at 25-35 DEG C,
50-80 DEG C 12-36 hours dry, obtains adsorbent.The rotating speed of the wherein described stirring is 100-500 revs/min.
Addition adsorbent is cellulose and diatomaceous composite particles in the liquid detergent of the present invention, modified by tartaric acid
Dirt, dyestuff can be more preferably adsorbed, realizes that the while of improving washing effect avoids also achieving the effect for avoiding clothes from being colored.
The preparation method of heretofore described freshener is：Under 40-70 DEG C of condition of water bath heating, by ethyl orthosilicate,
3-aminopropyltriethoxysilane, ethyl alcohol, water are (1-5) in mass ratio:(1-3):(5-7):10 are uniformly mixed, and are mixed
Liquid A, under 40-70 DEG C of condition of water bath heating, by Monomenthyl succinate, trans--to press matter to terpane -3,8- glycol and ethyl alcohol
Amount is than being (1-5)：(6-8)：60 are uniformly mixed, and obtain mixed liquid B, are 5 in mass ratio by mixed liquor A and mixed liquid B:(1-3)
It is uniformly mixed, it is then open in 25-35 DEG C, the environment that relative humidity is 85-90% to place 2-6 hours, gel is formed, will be coagulated
Glue centrifuges, 12-36 hours dry by being deposited in 35-70 DEG C obtained by centrifugation, smashes it through 20-100 mesh sieve, obtains freshener.Its
Described in centrifuge when rotating speed be 3000-10000 revs/min, centrifugation time is 20-60 minutes.
Contain freshener in liquid detergent of the present invention, scorching hot, the feeling of itching of liquid detergent when for hand wash laundry, tool can be solved
There is refrigerant, sedation, takees good care of both hands.The freshener that the present invention adds is a kind of answering containing Silica hydrogel and peppermint analog derivative
Structure is closed, there is certain absorption property, can also achieve the effect that adsorb dirt and dyestuff.
The present invention also provides the preparation processes of above-mentioned multifunctional laundry liquid：Liquid detergent each component is weighed by weight, by water
Be heated to 50-80 DEG C, at 50-80 DEG C, with 100-500 revs/min of rotating speed stirring condition under be added surfactant, enzymatic activity
Then protective agent, sodium sulphate, glycerine are stirred 1-3 hours at 50-80 DEG C, with 300-800 revs/min of rotating speed, are cooled to 30-
40 DEG C, remaining ingredient is added, is stirred 20-60 minutes at 30-40 DEG C, with 300-500 revs/min of rotating speed, obtains multifunctional laundry
Liquid.
It, can be effective containing protease, cellulase, protector of enzyme activity, adsorbent in the multifunctional laundry liquid of the present invention
Dirt is removed, detersive efficiency is high, and also having prevents different colours clothing from shuffling caused colouring problem, and what is contained in liquid detergent is clear
Cool dose of component makes liquid detergent for having refrigerant, antipruritic, the effect not hurt hands when hand-washing.
On the basis of common knowledge of the art, above-mentioned each optimum condition, can be each preferably to get the present invention in any combination
Embodiment.
Specific implementation mode
It is further illustrated the present invention below by the mode of embodiment, but does not therefore limit the present invention to the reality
It applies among a range.In the following examples, the experimental methods for specific conditions are not specified, according to conventional methods and conditions, or according to quotient
Product specification selects.
In following embodiments, primary raw material and instrument used are as follows：
Cellulase, No. CAS：9012-54-8 is to use trichoderma reesei (Classification system：Trichodermareesei it) passes through
Highly effective cellulose enzyme preparation made of the processes such as liquid deep layer fermenting, ultrafiltration are refined, specifically used model full constituent type 7000
Cellulase, enzyme activity：7000u/g is purchased from Ningxia Sunson Industrial Group Co., Ltd..
Neutral proteinase, No. CAS：9068-59-1.Enzyme activity：50u/mg.It buys from Shanghai Aladdin biochemical technology share
Co., Ltd, product identification：D195752.
Glycerine, No. CAS：56-81-5.
Sodium sulphate, i.e. thenardite, No. CAS：7757-82-6.
Caclium diborogluconate, No. CAS：5743-34-0.
2- methylol phenyl boric acids, No. CAS：87199-14-2.
Borax, No. CAS：1303-96-4, grain size：80 mesh, Grade A execute standard：GB537-97 is bought from Yingkou City
Xing Dong Chemical Co., Ltd.s.
Lemon extract, the production of Guangzhou all sorts of flowers spices limited liability company, model 6133.
Arbor-vitae leaf flavone extract, can be by buying or being prepared.Cacumen biotae is cupressaceae plant arbor-vitae (Latin
Name：PLatycladus orientalis (L.) Franco) branch and leaf, the cacumen biotae (place of production Shandong) that uses in the present invention
Chromocor extract is according to application No. is the methods of embodiment in 201410785394.6 4 to be prepared.
Herba speranskiae tuberculatae extract, can be by buying or being prepared, and the Herba speranskiae tuberculatae extract in the present invention passes through with lower section
Method is prepared：Take lopseed (Classification system：Phryma leptostachya L.subsp.asiatica(Hara)
Kitamura) complete stool 150g, it is 12 hours dry at 40 DEG C, 50 mesh sieve is then crushed, deep grass meal is obtained, takes deep grass meal
95g is added in 700g water, is kept the temperature 10 hours at 30 DEG C, 72 DEG C is then heated to, at 72 DEG C, with 200 revs/min of rotating speed
Stirring 2 hours, sieves with 100 mesh sieve, and filtrate is concentrated by evaporation to 30 DEG C and measures the thick paste that relative density is 1.27, by thick paste in temperature
It is 12 hours dry under conditions of being 0.04MPa for 50 DEG C, vacuum degree, obtain Herba speranskiae tuberculatae extract.
Dodecyl Polyglucosides, No. CAS：110615-47-9.
Cocoamidopropyl betaine, No. CAS：86438-79-1.
Laruyl alcohol sulfate ammonium salt, No. CAS：2235-54-3.
Neopelex, No. CAS：25155-30-0.
Urea, No. CAS：57-13-6.
Sodium hydroxide, No. CAS：1310-73-2.
Cellulose, model PH102, brand CEOLUS, producer：Asahi Kasei Corporation.
Sodium carbonate, CAS：497-19-8.
Diatomite, two oxygen silicone content≤85%, model RS1280, producer：Guangzhou Yikang new material Science and Technology Ltd..
Ethyl alcohol, CAS：64-17-5, purity 99.9%, Hua Chang Chemical Co., Ltd.s of Shenzhen provide.
Tartaric acid, No. CAS：526-83-0.
Ethyl orthosilicate, CAS：78-10-4.
3-aminopropyltriethoxysilane, No. CAS:919-30-2.
Monomenthyl succinate, No. CAS：77341-67-4.
Trans--to terpane -3,8- glycol, No. CAS：3564-98-5.
In following embodiments, used test method is as follows：
Test 1：Clean effect is tested
It is washed before washing and with multifunctional laundry liquid to JB-02 soiled cottons according to GB/T13174-2008 test JB-02 soiled cottons
Whiteness value difference after washing.By multifunctional laundry liquid the whiteness difference result divided by standard front and back to JB-02 soiled cotton decontaminations washing
The liquid detergent whiteness difference front and back to JB-02 soiled cotton decontaminations washing evaluates clean effect as a result, as decontamination index, with this.
Experiment condition is：Multifunctional laundry liquid (is contained in i.e. every 1L water using 250ppm hard water, a concentration of 2g/L of multifunctional laundry liquid
2g), wash time is 20 minutes, temperature is 30 DEG C, uses defined RQHL types vertical washing machine, rotating speed for 60 revs/min.
Test 2：Antipruritic effect is tested
It will be sufficiently stirred after 25 DEG C of the water dilution of the multifunctional laundry liquid of the present invention, obtain the multi-functional of a concentration of 2g/L
Then liquid detergent dilution stretches into the hand of volunteer in the basin equipped with above-mentioned multifunctional laundry liquid dilution, impregnate 30 seconds, ask
20 volunteers carry out feel testing evaluation,>2 Qie≤3 point Fen indicate not itch completely,>1 Qie≤2 point Fen indicate slightly to itch,>0
Qie≤1 point Fen indicate obviously itch, contrast sample (containing mass fraction be 50% soda ash and mass fraction be 50% sulfuric acid
The aqueous solution of sodium) it is 0 point, expression is seriously itched.The test result of each group embodiment and comparative example compares, P<0.05.
Test 3：Anti- dyeing measure of merit
White cotton (meeting GB/T7568.2-2008) is tested before washing according to GB/T13174-2008 and uses this hair
Whiteness value after bright multifunctional laundry liquid washing.Whiteness value is higher, indicates that anti-coloring is better.Experiment condition is：It is to be washed
After clothing machine water filling, the Reactive Brilliant Blue KN-R solution that the mass fraction of 4mL is 1% is added, then according to the experiment item of test 1
Part is tested.
It is further illustrated the present invention below by the mode of embodiment, unless otherwise specified, used number is attached most importance to
Measure number.
Embodiment 1
Multifunctional laundry liquid, including following components in parts by weight：25 parts of surfactants, 0.5 part of lemon extract, 1.5 parts
Glycerine, 0.15 part of arbor-vitae leaf flavone extract, 0.08 part of Herba speranskiae tuberculatae extract, 0.25 part of cellulase, 0.15 part of neutral protein
Enzyme, 5.5 parts of protector of enzyme activity, 0.5 part of sodium sulphate, 40 parts of water.
The surface-active is made of the raw material of following mass percents：25% Cocoamidopropyl betaine, 3,0%0
Dialkyl group glucoside, 15% neopelex, surplus are laruyl alcohol sulfate ammonium salt.
The protector of enzyme activity is caclium diborogluconate.
The preparation process of the multifunctional laundry liquid is：Liquid detergent each component is weighed by weight, heats water to 70 DEG C,
At 70 DEG C, with 300 revs/min of rotating speed stirring condition under be added surfactant, protector of enzyme activity, sodium sulphate, glycerine, so
It is stirred 1 hour at 70 DEG C, with 500 revs/min of rotating speed afterwards, is cooled to 35 DEG C, cacumen biotae chromocor extract is added, lopseed carries
Object, cellulase, neutral proteinase, lemon extract are taken, is stirred 30 minutes at 35 DEG C, with 300 revs/min of rotating speeds, obtains this hair
Bright multifunctional laundry liquid.
Embodiment 2
It is substantially the same manner as Example 1, it differs only in：In the present embodiment 2, the protector of enzyme activity is 2- hydroxyl first
Base phenyl boric acid.
Embodiment 3
It is substantially the same manner as Example 1, it differs only in：In the present embodiment 3, the protector of enzyme activity is borax.
Embodiment 4
Multifunctional laundry liquid, including following components in parts by weight：25 parts of surfactants, 0.5 part of lemon extract, 1.5 parts
Glycerine, 0.15 part of arbor-vitae leaf flavone extract, 0.08 part of Herba speranskiae tuberculatae extract, 0.25 part of cellulase, 0.15 part of neutral protein
Enzyme, 5.5 parts of protector of enzyme activity, 0.5 part of sodium sulphate, 2.5 parts of adsorbents, 40 parts of water.
The surface-active is made of the raw material of following mass percents：25% Cocoamidopropyl betaine, 3,0%0
Dialkyl group glucoside, 15% neopelex, surplus are laruyl alcohol sulfate ammonium salt.
The protector of enzyme activity is caclium diborogluconate.
The preparation method of the adsorbent is：By 7.5g urea, 13g sodium hydroxides be added 100g water in, 30 DEG C, with
200 revs/min of rotating speed stirs 40 minutes, is cooled to -8 DEG C, 6g celluloses is added, at -8 DEG C, with 150 revs/min of rotating speed
Stirring 5 hours is warming up to 30 DEG C, and 1g sodium carbonate, 10g diatomite is added, and 40 points are stirred at 30 DEG C, with 150 revs/min of rotating speeds
The hydrochloric acid 2mL of a concentration of 1mol/L is added in clock, is stirred 5 hours at 30 DEG C, with 150 revs/min of rotating speeds, crosses 300 mesh sieve, will filter
Cake 50g ethyl alcohol, 50g water are 24 hours dry at 40 DEG C after rinsing, in mass ratio by dry products therefrom, tartaric acid, ethyl alcohol, water
It is 10:3:50:10 ratio is uniformly mixed, and 40min is stirred at 30 DEG C, with 200 revs/min of rotating speed, and at 60 DEG C, dry 24 is small
When, obtain adsorbent.
The preparation process of the multifunctional laundry liquid is：Liquid detergent each component is weighed by weight, heats water to 70 DEG C,
At 70 DEG C, with 300 revs/min of rotating speed stirring condition under be added surfactant, protector of enzyme activity, sodium sulphate, glycerine, so
It is stirred 1 hour at 70 DEG C, with 500 revs/min of rotating speed afterwards, is cooled to 35 DEG C, cacumen biotae chromocor extract is added, lopseed carries
Object, cellulase, neutral proteinase, adsorbent, lemon extract are taken, stirs 30 minutes, obtains at 35 DEG C, with 300 revs/min of rotating speeds
To the multifunctional laundry liquid of the present invention.
Embodiment 5
Multifunctional laundry liquid, including following components in parts by weight：25 parts of surfactants, 0.5 part of lemon extract, 1.5 parts
Glycerine, 0.15 part of arbor-vitae leaf flavone extract, 0.08 part of Herba speranskiae tuberculatae extract, 0.25 part of cellulase, 0.15 part of neutral protein
Enzyme, 5.5 parts of protector of enzyme activity, 0.5 part of sodium sulphate, 2.5 parts of adsorbents, 2 portions of fresheners, 40 parts of water.
The surface-active is made of the raw material of following mass percents：25% Cocoamidopropyl betaine, 3,0%0
Dialkyl group glucoside, 15% neopelex, surplus are laruyl alcohol sulfate ammonium salt.
The protector of enzyme activity is caclium diborogluconate.
The preparation method of the adsorbent is the same as embodiment 4.
The preparation method of the freshener is：Under 50 DEG C of condition of water bath heating, by ethyl orthosilicate, 3- aminopropyls three
Ethoxysilane, ethyl alcohol, water are 3 in mass ratio:2:6:10 are uniformly mixed, and mixed liquor A are obtained, in 50 DEG C of condition of water bath heating
Under, by Monomenthyl succinate, it is trans--be 3 in mass ratio to terpane -3,8- glycol and ethyl alcohol：7：60 are uniformly mixed, and obtain
Mixed liquor A and mixed liquid B are 5 in mass ratio by mixed liquid B:1 is uniformly mixed, then in 25 DEG C, the ring that relative humidity is 85%
It is open in border to place 3 hours, gel is formed, gel is centrifuged 40 minutes with 5000 revs/min of rotating speed, by centrifugation gained precipitation
It is 24 hours dry at 45 DEG C, 50 mesh sieve is smashed it through, freshener is obtained.
The preparation process of the multifunctional laundry liquid is：Liquid detergent each component is weighed by weight, heats water to 70 DEG C,
At 70 DEG C, with 300 revs/min of rotating speed stirring condition under be added surfactant, protector of enzyme activity, sodium sulphate, glycerine, so
It is stirred 1 hour at 70 DEG C, with 500 revs/min of rotating speed afterwards, is cooled to 35 DEG C, cacumen biotae chromocor extract is added, lopseed carries
Object, cellulase, neutral proteinase, adsorbent, freshener, lemon extract are taken, 30 are stirred at 35 DEG C, with 300 revs/min of rotating speeds
Minute, obtain the multifunctional laundry liquid of the present invention.
Comparative example 1
Multifunctional laundry liquid, including following components in parts by weight：25 parts of surfactants, 0.5 part of lemon extract, 1.5 parts
Glycerine, 0.15 part of arbor-vitae leaf flavone extract, 0.08 part of Herba speranskiae tuberculatae extract, 0.25 part of cellulase, 0.15 part of neutral protein
Enzyme, 0.5 part of sodium sulphate, 40 parts of water.
The surface-active is made of the raw material of following mass percents：25% Cocoamidopropyl betaine, 3,0%0
Dialkyl group glucoside, 15% neopelex, surplus are laruyl alcohol sulfate ammonium salt.
The preparation process of the multifunctional laundry liquid is：Liquid detergent each component is weighed by weight, heats water to 70 DEG C,
At 70 DEG C, with 300 revs/min of rotating speed stirring condition under be added surfactant, sodium sulphate, glycerine, then 70 DEG C, with
500 revs/min of rotating speed stirs 1 hour, is cooled to 35 DEG C, and cacumen biotae chromocor extract, Herba speranskiae tuberculatae extract, cellulose is added
Enzyme, neutral proteinase, lemon extract are stirred 30 minutes at 35 DEG C, with 300 revs/min of rotating speeds, obtain the Multifunctional washing of the present invention
Clothing liquid.
Comparative example 2
It is substantially the same manner as Example 4, it differs only in, in this comparative example 2, the preparation method of the adsorbent is：
7.5g urea, 13g sodium hydroxides are added in 100g water, stirred 40 minutes at 30 DEG C, with 200 revs/min of rotating speed, it is cooling
To -8 DEG C, 6g celluloses are added, is stirred 5 hours at -8 DEG C, with 150 revs/min of rotating speed, is warming up to 30 DEG C, 1g carbonic acid is added
Sodium, 10g diatomite are stirred 40 minutes at 30 DEG C, with 150 revs/min of rotating speeds, the hydrochloric acid 2mL of a concentration of 1mol/L are added, 30
DEG C, stirred 5 hours with 150 revs/min of rotating speeds, 300 mesh sieve is crossed, in 40 DEG C of dryings after filter cake 50g ethyl alcohol, 50g water are rinsed
24 hours, obtain adsorbent.
Comparative example 3
It is substantially the same manner as Example 5, it differs only in, in this comparative example 3, the preparation method of the freshener is：
It is 3 in mass ratio by ethyl orthosilicate, 3-aminopropyltriethoxysilane, ethyl alcohol, water under 50 DEG C of condition of water bath heating:2:
6:10 are uniformly mixed, and obtain mixed liquor A, under 50 DEG C of condition of water bath heating, in mass ratio with ethyl alcohol by Monomenthyl succinate
It is 10：60 are uniformly mixed, and obtain mixed liquid B, are 5 in mass ratio by mixed liquor A and mixed liquid B:1 is uniformly mixed, then 25
DEG C, it is open in the environment that relative humidity is 85% place 3 hours, form gel, gel centrifuged with 5000 revs/min of rotating speed
40 minutes, centrifugation gained is deposited in 45 DEG C of drying 24 hours, 50 mesh is smashed it through and sieves, obtain freshener.
Comparative example 4
It is substantially the same manner as Example 5, it differs only in, in this comparative example 4, the preparation method of the freshener is：
It is 3 in mass ratio by ethyl orthosilicate, 3-aminopropyltriethoxysilane, ethyl alcohol, water under 50 DEG C of condition of water bath heating:2:
6:10 be uniformly mixed, obtain mixed liquor A, under 50 DEG C of condition of water bath heating, by it is trans--to terpane -3,8- glycol and ethyl alcohol
It is 10 in mass ratio：60 are uniformly mixed, and obtain mixed liquid B, are 5 in mass ratio by mixed liquor A and mixed liquid B:1 is uniformly mixed,
Then open in 25 DEG C, the environment that relative humidity is 85% to place 3 hours, gel is formed, by gel with 5000 revs/min
Rotating speed centrifuges 40 minutes, and centrifugation gained is deposited in 45 DEG C of drying 24 hours, 50 mesh is smashed it through and sieves, obtain freshener.
Measure of merit
Table 1：Clean effect test result table
| Decontamination index | |
| Embodiment 1 | 3.42 |
| Embodiment 2 | 3.33 |
| Embodiment 3 | 3.29 |
| Embodiment 4 | 3.64 |
| Embodiment 5 | 3.75 |
| Comparative example 1 | 3.20 |
| Comparative example 2 | 3.53 |
| Comparative example 3 | 3.66 |
| Comparative example 4 | 3.69 |
Table 2：Anti-dye measure of merit result table
| Whiteness value before washing | Whiteness value after washing | |
| Embodiment 1 | 88.4 | 85.6 |
| Embodiment 2 | 88.5 | 85.4 |
| Embodiment 3 | 88.3 | 85.1 |
| Embodiment 4 | 88.4 | 87.3 |
| Embodiment 5 | 88.3 | 88.2 |
| Comparative example 1 | 88.5 | 83.5 |
| Comparative example 2 | 88.4 | 86.8 |
| Comparative example 3 | 88.5 | 87.5 |
| Comparative example 4 | 88.4 | 87.7 |
Table 3：Antipruritic effect test result table
Contain protector of enzyme activity in the liquid detergent of the present invention, passes through hydrogen bond action knot between protector of enzyme activity and enzyme
It closes, is conducive to that stablizing for enzyme is kept to survive, enzyme can be released again when liquid detergent is diluted, to reinforce decontamination washing effect.It washes
The adsorbent added in clothing liquid is cellulose and diatomaceous composite particles, has more preferable absorption dirt by tartaric acid is modified
With the effect of dyestuff, it can prevent different colours clothes from shuffling the colouring problem brought while improving washing effect.The present invention washes
The itching of liquid detergent, scorching hot feeling, do not hurt hands when the freshener added in clothing liquid can be solved for hand wash laundry, improve user's body
It tests.
The preferred embodiment of the present invention has been described in detail above.It should be appreciated that those skilled in the art without
It needs creative work according to the present invention can conceive and makes many modifications and variations.Therefore, all technologies in the art
Personnel are available by logical analysis, reasoning, or a limited experiment on the basis of existing technology under this invention's idea
Technical solution, all should be in the protection domain being defined in the patent claims.
Claims (10)
1. a kind of multifunctional laundry liquid, which is characterized in that including following components in parts by weight：10-30 parts of surfactants, 0.2-
2 parts of essence, 0.3-3 parts of glycerine, 0.02-0.2 parts of arbor-vitae leaf flavone extracts, 0.04-0.4 parts of Herba speranskiae tuberculatae extracts, 0.05-
0.5 part of cellulase, 0.03-0.3 parts of neutral proteinases, 3-9 parts of protector of enzyme activity, 0.5-5 parts of sodium sulphate, 30-60 parts of water.
2. multifunctional laundry liquid according to claim 1, which is characterized in that further include the adsorbent of 2-6 parts by weight.
3. multifunctional laundry liquid according to claim 1 or 2, which is characterized in that further include the freshener of 2-6 parts by weight.
4. multifunctional laundry liquid according to claim 1, which is characterized in that the surface-active is by following mass percents
Raw material composition：10%-30% Cocoamidopropyl betaines, 10%-30% lauryl glucosyls, 10%-30% ten
Dialkyl benzene sulfonic acids sodium, surplus are laruyl alcohol sulfate ammonium salt.
5. multifunctional laundry liquid according to claim 1, which is characterized in that the protector of enzyme activity is boron gluconic acid
One kind in calcium, 2- methylols phenyl boric acid, borax.
6. multifunctional laundry liquid according to claim 2, which is characterized in that the preparation method of the adsorbent is as follows：It will
5-15g urea, 8-24g sodium hydroxides are added in 80-240g water, are stirred 20-60 minutes at 25-35 DEG C, are cooled to -10~-5
DEG C, 3-12g celluloses are added, are stirred 2-8 hours at -10~-5 DEG C, are warming up to 25-35 DEG C, 0.2-2g sodium carbonate, 5- is added
20g diatomite stirs 20-60 minutes at 25-35 DEG C, the hydrochloric acid 0.5-5mL of a concentration of 0.5-5mol/L is added, at 25-35 DEG C
100-500 mesh sieve is crossed in stirring 3-8 hours, in 35-55 DEG C of dry 12- after filter cake 30-100g ethyl alcohol, 30-100g water are rinsed
36 hours, be (5-15) in mass ratio by dry products therefrom, tartaric acid, ethyl alcohol, water:(1-5):(40-60):The ratio of (8-12)
Example is uniformly mixed, and 20-60min is stirred at 25-35 DEG C, 12-36 hours dry at 50-80 DEG C, obtains adsorbent.
7. multifunctional laundry liquid according to claim 3, which is characterized in that the preparation method of the freshener is：In 40-
It is (1- in mass ratio by ethyl orthosilicate, 3-aminopropyltriethoxysilane, ethyl alcohol, water under 70 DEG C of condition of water bath heating
5):(1-3):(5-7):10 are uniformly mixed, and mixed liquor A are obtained, under 40-70 DEG C of condition of water bath heating, by monosuccinic acid peppermint
Ester, it is trans--be (1-5) in mass ratio to terpane -3,8- glycol and ethyl alcohol：(6-8)：60 are uniformly mixed, and obtain mixed liquid B,
It is 5 in mass ratio by mixed liquor A and mixed liquid B:(1-3) is uniformly mixed, and is then 85-90%'s in 25-35 DEG C, relative humidity
It is open in environment to place 2-6 hours, gel is formed, by gel centrifugal, it is small that centrifugation gained is deposited in 35-70 DEG C of dry 12-36
When, 20-100 mesh sieve is smashed it through, freshener is obtained.
8. multifunctional laundry liquid according to claim 6, which is characterized in that the rotating speed of the stirring be 100-500 turn/
Minute.
9. multifunctional laundry liquid according to claim 7, which is characterized in that the rotating speed when centrifugation is 3000-10000
Rev/min, centrifugation time be 20-60 minutes.
10. the preparation process of the multifunctional laundry liquid according to claim any one of 1-3, which is characterized in that by weight
Part weighs liquid detergent each component, 50-80 DEG C is heated water to, at 50-80 DEG C, with 100-500 revs/min of rotating speed stirring condition
Lower addition surfactant, protector of enzyme activity, sodium sulphate, glycerine, then at 50-80 DEG C, with 300-800 revs/min of turn
Speed stirring 1-3 hours, is cooled to 30-40 DEG C, and remaining ingredient is added, and is stirred at 30-40 DEG C, with 300-500 revs/min of rotating speed
20-60 minutes to get multifunctional laundry liquid.
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