CN101899364B - Plant environment-friendly cleaning agent - Google Patents
Plant environment-friendly cleaning agent Download PDFInfo
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- CN101899364B CN101899364B CN2010102339549A CN201010233954A CN101899364B CN 101899364 B CN101899364 B CN 101899364B CN 2010102339549 A CN2010102339549 A CN 2010102339549A CN 201010233954 A CN201010233954 A CN 201010233954A CN 101899364 B CN101899364 B CN 101899364B
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Abstract
The present invention discloses a plant environment-friendly cleaning agent, which is characterized in that: the cleaning agent is prepared from the following raw materials in percentage by weight: 20 to 30 percent of fatty alcohol-polyoxyethylene ether, 20 to 30 percent of coconut acyl-diethanol amine essential oil, 3 to 8 percent of sodium carbonate, 8 to 13 percent of propylene glycol and the balance of softened water; and the coconut acyl-diethanol amine essential oil is prepared from the following plant raw materials in percentage by weight: 40 percent of corn starch, 20 percent of bergamot fruit and 40 percent of palm oil. The invention also discloses a specific method for preparing the plant environment-friendly cleaning agent. The cleaning agent is safe to people, animal and surrounding working environment, has no toxic or side effect, has no acrimony, and has good cleaning performance, wide application range and potential economic benefit.
Description
The application is dividing an application of " plant environment-friendly type cleaning agent and working method thereof ", and the applying date of original application is on May 14th, 2009, and application number is: 2009100985888.
Technical field
The present invention relates to a kind of plant environment-friendly type cleaning agent.
Background technology
The cleaning agent formula of present industrial use belongs to the chemical agent prescription mostly, belongs to strong acid, highly basic or leaning solvent.Have following shortcoming during use: when use (1) security not enough, liquid has corrosive nature to cleaning material surface, toxic to human body, some clean-out system is inflammable and explosive.(2) damage ratio to environment is bigger, and atmosphere, water resources are had biological accumulation.(3) cleaning performance is lower, and life cycle is short.(4) remained on surface or uniform passivation.(5) foam is higher, and rust-preventing characteristic is poor.
The aq. type clean-out system of up-to-date research and development also is, and to be that main raw material is composite with the chemical agent form, and exist drawback too: the scope of application that has is narrow, can only be applicable to a certain class field, a certain class material surface; The meeting injury human skin that has; The meeting injury clean surface material that has; The performance that has is gentle but cleaning performance is not good.
Announced " a kind of water-solubility printing ink washing agent and preparation technology thereof " patent of invention on January 26th, 2005 as Patent Office of the People's Republic of China, the patent No.: 03119639.X, the water-soluble washing agent that this technical scheme has adopted components such as polyoxyethylene octyl phenolic ether or polyoxyethylene nonylphenol ether, trolamine, ethylene glycol butyl ether (ethylene glycol monobutyl ether), soft water to make.Along with the continuous appearance of cleaning agent formula, we find that present used clean-out system adopts polyoxyethylene octyl phenolic ether or polyoxyethylene nonylphenol ether more, and these compounds have pungency to skin; And this raw material that the compound of acute toxicity is arranged as cleaning agent formula of ethylene glycol monobutyl ether, ethylene glycol butyl ether is that ethylene glycol monobutyl ether is as solublization, its solublization shows: when surfactant polyoxyethylene octyl phenolic ether or polyoxyethylene nonylphenol ether form micella in the aqueous solution after, have organic solubleness insoluble or that be slightly soluble in water is enlarged markedly.But cause murder by poisoning to human body and environment.
Summary of the invention
The object of the present invention is to provide a kind of plant environment-friendly type cleaning agent, clean-out system of the present invention all has safety to people, animal and surrounding working environment, no side effects, and nonirritant, cleaning performance is good, and is applied widely, has the potential economic benefit.
In order to achieve the above object, technical scheme of the present invention is:
Plant environment-friendly type cleaning agent of the present invention is removed greasy dirt mechanism: adopt the clean-out system of low surface tension, by acting on the interface that is cleaned thing surface and contact thereof, dirt removal.On the interface of surface that is cleaned and the schmutzband of being cleaned thing, contact cleaning, can on surface to be cleaned and dirt interface, soak into diffusion, play a part to peel off from being cleaned the schmutzband on thing surface.Because the surface tension of dirt generally than big many of 30N/m, adds clean-out system of the present invention, and surface tension is dropped to below the 20mN/m, the aqueous solution of clean-out system is easy to the surface removal dirt that is being cleaned.
A kind of plant environment-friendly type cleaning agent, it is formulated by following weight percentages:
Fatty alcohol-polyoxyethylene ether (polymerization degree n is 6～18) 20%～30%;
Coconut acyl diethanolamine volatile oil 20%～30%;
Yellow soda ash 3%～8%;
Propylene glycol 8%～13%;
Surplus is a softening water.
Fatty alcohol-polyoxyethylene ether is bought in Guangzhou Yue Ji chemical industry company limited, and model is a kind of among AEO7, AEO9 or the AEO37.
The weight percent of described each raw material is:
Fatty alcohol-polyoxyethylene ether 25%
Coconut acyl diethanolamine volatile oil 25%;
Yellow soda ash 5%;
Propylene glycol 10%;
Surplus is a softening water.
Described coconut acyl diethanolamine volatile oil is formulated by the plant material of following weight per-cent: juniper berry 30%, Thymus vulgaris 40%, soybean leaf 30%.
Described coconut acyl diethanolamine volatile oil is formulated by the plant material of following weight per-cent: W-Gum 40%, Citrus bergamia fruit 20%, plam oil 40%.
A kind of working method of plant environment-friendly type cleaning agent comprises the steps:
(1) plant material cleans: with weight percent: the plant material surface impurity dirt 0.5%Na of juniper berry 30%, Thymus vulgaris 40%, soybean leaf 30% or W-Gum 40%, Citrus bergamia fruit 20%, plam oil 40%
2CO
3Solution soaking is cleaned 1～3min, and it is stand-by that the clear water rinsing drains the back.
(2) plant pulverising mill oil: the plant material after will cleaning is earlier poured in the loading hopper, and the rotation by mill is constantly rotated plant on mill, and rotating speed is controlled at 60～80 rev/mins, makes to flow out vegetable slurries on the mill.Simultaneously, open spray water oil flushing is got off, flow in the Receiving bin, stir into the vegetable slurries raw material by filtration.
(3) adopt molecular distillation equipment and evaporation equipment, wherein adopt paraffin oil to add thermal distillation, distillation temperature: 30～45 ℃, the time: 2～3 hours, vacuum tightness was the 0.5-1.8 mmhg, distilled out coconut acyl diethanolamine essential oil mixture.
(4) plant environment-friendly type cleaning agent complex process
A) add softening water in mixing tank, water hardness is controlled between 10～100ppm.Temperature remains on 15～25 ℃;
B) in stainless reactor with a small amount of dissolved in distilled water fatty alcohol-polyoxyethylene ether (polymerization degree n is 6～18), fatty alcohol-polyoxyethylene ether (polymerization degree n is 6～18) after slowly will dissolving successively then, yellow soda ash, propylene glycol join in the mixing tank, slowly stir, to prevent to produce foam, fully stirred 16～26 minutes, mix, make the clean-out system intermediate liquid;
C) then the coconut acyl diethanolamine essential oil mixture of plant distillation extraction is added in the clean-out system intermediate liquid, wherein the weight percent that adds between each component is: polyoxyethylene straight-chain alcohol ethoxylate (polymerization degree n is 6～18) 20%～30%, coconut acyl diethanolamine volatile oil 20%～30%, yellow soda ash 3%～8%, propylene glycol 8%～13%, surplus are softening water; Stir mixed in 18～25 minutes after, potential of hydrogen is also regulated in test, pH is 7～10 in control, makes plant environment-friendly type cleaning agent.
Beneficial effect of the present invention is: the present invention is to be host with the volatile oil of plant extract and non-ionic type polyoxyethylene straight-chain alcohol ethoxylate (polymerization degree n is 6～18) tensio-active agent, at the auxilliary aq. type clean-out system that adds activation permeate agent and solubilizing agent.Mainly utilize the amphipathic characteristic of polyoxyethylene straight-chain alcohol ethoxylate (polymerization degree n is 6～18) nonionogenic tenside, promptly in the plant type surfactant molecule, there are hydrophilic group and hydrophobic group simultaneously, has adsorption, in solution, play micelle and turn usefulness into, reduce surface tension, thereby have very strong penetrating power, have functions such as emulsification, wetting, diffusion, directly being penetrated into the contact surface of greasy dirt and clean surface, is the actives of clean-out system.
Coconut acyl diethanolamine among the present invention belongs to nonionogenic tenside, water soluble, have stronger latherability, detersive power and soak into ability, make clean-out system of the present invention have stronger cleansing power, also have dispersiveness preferably in addition, make that greasy dirt can be good at coming off from scavenger surface.It also has certain antirust power, after the metallic surface is cleaned, has antirust function.
Plant environment-friendly type cleaning agent of the present invention does not contain ethylene glycol monobutyl ether class toxic compounds, or this class of polyoxyethylene nonylphenol ether has pungent to skin.
Plant environment-friendly type cleaning agent of the present invention has following characteristics:
(1) pure plant extract clean-out system main component does not contain strong acid, highly basic, etching reagent, phosphoric acid salt, oranges and tangerines derivative, muriate, petroleum distillate, the butyl-like compound.
(2) nontoxic to environment, fully biodegradable.
(3) nontoxic, do not contain cancer-causing chemicals, not carcinogenic.
(4) content of volatile organic compound is almost nil.
(5) ozone depletion potential is zero.
(6) do not contain the alkylphenol polyoxyethylene compounds, aromatic solvent, organic chloride, butyl cellosolve etc. in the prescription.
(7) harmless to surfaces such as rubber, plastics and paint.
(8) human body skin there is not any pungency.
(9) cleaning performance is good, and noresidue after the metallic surface is cleaned, has antirust function.
In sum: clean-out system of the present invention all has safety to people, animal and surrounding working environment, no side effects, and nonirritant, cleaning performance is good, and is applied widely, has the potential economic benefit.The present invention can be used for the clean-out operation in fields such as automobile, aviation, oil mining, communications and transportation, electric power, government, medical treatment.
Embodiment
Embodiment 1
A kind of plant environment-friendly type cleaning agent of present embodiment indication comprises the steps:
(1) plant material cleans: with weight percent: the plant material of juniper berry 30%, Thymus vulgaris 40%, soybean leaf 30%, surface impurity dirt 0.5%Na
2CO
3Solution soaking is cleaned 1～3min, and it is stand-by that the clear water rinsing drains the back.
(2) plant pulverising mill oil: the plant material after will cleaning is earlier poured in the loading hopper, and the rotation by mill is constantly rotated plant on mill, and rotating speed is controlled at 60～80 rev/mins, makes to flow out vegetable slurries on the mill.Simultaneously, open spray water oil flushing is got off, flow in the Receiving bin, stir into the vegetable slurries raw material by filtration.
(3) adopt U.S. Pope molecular distillation equipment and evaporation equipment, wherein adopt paraffin oil to add thermal distillation, distillation temperature: 30～45 ℃, the time: 2～3 hours, vacuum tightness was the 0.5-1.8 mmhg, distilled out coconut acyl diethanolamine essential oil mixture.
Vegetable slurries enters in the distiller under vacuum state, and is launched into film rapidly, down to water surface of evaporation.
Heated wall and high vacuum are ordered about more volatile composition (volatile oil) to approaching built-in condenser, and not volatile composition (residue) continues to flow back to matrass along distillation column simultaneously.
The fraction of separating like this exports out by independent discharging.According to the application of volatile oil, required product or distillment, remaining fraction give over to distillation next time, reuse.Thermal Release Technology is isolated the plant essence oil production, and this fractionation by distillation efficient height can reach more than 20～30%.
(4) plant environment-friendly type cleaning agent complex process
A) add softening water in mixing tank, water hardness is controlled between 10～100ppm.Temperature remains on 15～25 ℃;
B) in stainless reactor with a small amount of dissolved in distilled water fatty alcohol-polyoxyethylene ether (polymerization degree n is 6～18), fatty alcohol-polyoxyethylene ether (polymerization degree n is 6～18) after slowly will dissolving successively then, yellow soda ash, propylene glycol join in the mixing tank, slowly stir, to prevent to produce foam, fully stirred 16～26 minutes, mix, make the clean-out system intermediate liquid;
C) then the coconut acyl diethanolamine essential oil mixture of plant distillation extraction is added in the clean-out system intermediate liquid, wherein the weight percent that adds between each component is: fatty alcohol-polyoxyethylene ether, model is AEO7, buy in Guangzhou Yue Ji chemical industry company limited, 20%, coconut acyl diethanolamine volatile oil 30%, yellow soda ash 3%, propylene glycol 13%, surplus are softening water; Stir mixed in 18～25 minutes after, potential of hydrogen is also regulated in test, pH is 7～10 in control, makes plant environment-friendly type cleaning agent.
Embodiment 2
A kind of plant environment-friendly type cleaning agent of present embodiment indication comprises the steps:
(1) plant material cleans: with weight percent: the plant material of W-Gum 40%, Citrus bergamia fruit 20%, plam oil 40%, surface impurity dirt 0.5%Na
2CO
3Solution soaking is cleaned 1～3min, and it is stand-by that the clear water rinsing drains the back.
(2) plant pulverising mill oil: the plant material after will cleaning is earlier poured in the loading hopper, and the rotation by mill is constantly rotated plant on mill, and rotating speed is controlled at 60～80 rev/mins, makes to flow out vegetable slurries on the mill.Simultaneously, open spray water oil flushing is got off, flow in the Receiving bin, stir into the vegetable slurries raw material by filtration.
(3) adopt U.S. Pope molecular distillation equipment and evaporation equipment, wherein adopt paraffin oil to add thermal distillation, distillation temperature: 30～45 ℃, the time: 2～3 hours, vacuum tightness was the 0.5-1.8 mmhg, distilled out coconut acyl diethanolamine essential oil mixture.Vegetable slurries enters in the distiller under vacuum state, and is launched into film rapidly, down to water surface of evaporation.
Heated wall and high vacuum are ordered about more volatile composition (volatile oil) to approaching built-in condenser, and not volatile composition (residue) continues to flow back to matrass along distillation column simultaneously.
The fraction of separating like this exports out by independent discharging.According to the application of volatile oil, required product or distillment, remaining fraction give over to distillation next time, reuse.Thermal Release Technology is isolated the plant essence oil production, and this fractionation by distillation efficient height can reach more than 20～30%.
(4) plant environment-friendly type cleaning agent complex process
A) add softening water in mixing tank, water hardness is controlled between 10～100ppm.Temperature remains on 15～25 ℃;
B) in stainless reactor with a small amount of dissolved in distilled water fatty alcohol-polyoxyethylene ether (polymerization degree n is 6～18), fatty alcohol-polyoxyethylene ether (polymerization degree n is 6～18) after slowly will dissolving successively then, yellow soda ash, propylene glycol join in the mixing tank, slowly stir, to prevent to produce foam, fully stirred 16～26 minutes, mix, make the clean-out system intermediate liquid;
C) then the coconut acyl diethanolamine essential oil mixture of plant distillation extraction is added in the clean-out system intermediate liquid, wherein the weight percent that adds between each component is: fatty alcohol-polyoxyethylene ether, model is AEO9, buy in Guangzhou Yue Ji chemical industry company limited, 30%, coconut acyl diethanolamine volatile oil 20%, yellow soda ash 8%, propylene glycol 8%, surplus are softening water; Stir mixed in 18～25 minutes after, potential of hydrogen is also regulated in test, pH is 7～10 in control, makes plant environment-friendly type cleaning agent.
Embodiment 3
A kind of plant environment-friendly type cleaning agent of present embodiment indication comprises the steps:
(1) plant material cleans: with weight percent: the plant material of juniper berry 30%, Thymus vulgaris 40%, soybean leaf 30%, surface impurity dirt 0.5%Na
2CO
3Solution soaking is cleaned 1～3min, and it is stand-by that the clear water rinsing drains the back.
(2) plant pulverising mill oil: the plant material after will cleaning is earlier poured in the loading hopper, and the rotation by mill is constantly rotated plant on mill, and rotating speed is controlled at 60～80 rev/mins, makes to flow out vegetable slurries on the mill.Simultaneously, open spray water oil flushing is got off, flow in the Receiving bin, stir into the vegetable slurries raw material by filtration.
(3) adopt U.S. Pope molecular distillation equipment and evaporation equipment, wherein adopt paraffin oil to add thermal distillation, distillation temperature: 30～45 ℃, the time: 2～3 hours, vacuum tightness was the 0.5-1.8 mmhg, distilled out coconut acyl diethanolamine essential oil mixture.
Vegetable slurries enters in the distiller under vacuum state, and is launched into film rapidly, down to water surface of evaporation.
Heated wall and high vacuum are ordered about more volatile composition (volatile oil) to approaching built-in condenser, and not volatile composition (residue) continues to flow back to matrass along distillation column simultaneously.
The fraction of separating like this exports out by independent discharging.According to the application of volatile oil, required product or distillment, remaining fraction give over to distillation next time, reuse.Thermal Release Technology is isolated the plant essence oil production, and this fractionation by distillation efficient height can reach more than 20～30%.
(4) plant environment-friendly type cleaning agent complex process
A) add softening water in mixing tank, water hardness is controlled between 10～100ppm.Temperature remains on 15～25 ℃;
B) in stainless reactor with a small amount of dissolved in distilled water fatty alcohol-polyoxyethylene ether (polymerization degree n is 6～18), fatty alcohol-polyoxyethylene ether (polymerization degree n is 6～18) after slowly will dissolving successively then, yellow soda ash, propylene glycol join in the mixing tank, slowly stir, to prevent to produce foam, fully stirred 16～26 minutes, mix, make the clean-out system intermediate liquid;
C) then the coconut acyl diethanolamine essential oil mixture of plant distillation extraction is added in the clean-out system intermediate liquid, wherein the weight percent that adds between each component is: fatty alcohol-polyoxyethylene ether, model is AEO37, buy in Guangzhou Yue Ji chemical industry company limited, 25%, coconut acyl diethanolamine volatile oil 25%, yellow soda ash 5%, propylene glycol 10%, surplus are softening water; Stir mixed in 18～25 minutes after, potential of hydrogen is also regulated in test, pH is 7～10 in control, makes plant environment-friendly type cleaning agent.
Claims (2)
1. a plant environment-friendly type cleaning agent is characterized in that, it is formulated by following weight percentages:
Fatty alcohol-polyoxyethylene ether 20%～30%;
Coconut acyl diethanolamine volatile oil 20%～30%;
Yellow soda ash 3%～8%;
Propylene glycol 8%～13%;
Surplus is a softening water;
Described coconut acyl diethanolamine volatile oil is formulated by the plant material of following weight per-cent: W-Gum 40%, Citrus bergamia fruit 20%, plam oil 40%; The working method of described a kind of plant environment-friendly type cleaning agent comprises the steps:
(1) plant material cleans: with weight percent: the plant material surface impurity dirt 0.5%Na of W-Gum 40%, Citrus bergamia fruit 20%, plam oil 40%
2CO
3Solution soaking is cleaned 1～3min, and it is stand-by that the clear water rinsing drains the back;
(2) plant pulverising mill oil: the plant material after will cleaning is earlier poured in the loading hopper, and the rotation by mill is constantly rotated plant on mill, and rotating speed is controlled at 60～80 rev/mins, makes to flow out vegetable slurries on the mill; Simultaneously, open spray water oil flushing is got off, flow in the Receiving bin, stir into the vegetable slurries raw material by filtration;
(3) adopt molecular distillation equipment and evaporation equipment, wherein adopt paraffin oil to add thermal distillation, distillation temperature: 30～45 ℃, the time: 2～3 hours, vacuum tightness was the 0.5-1.8 mmhg, distilled out coconut acyl diethanolamine essential oil mixture;
(4) plant environment-friendly type cleaning agent complex process:
A) add softening water in mixing filling, water hardness is controlled between 10～100ppm, and temperature remains on 15～25 ℃;
B) with a small amount of dissolved in distilled water polymerization degree n be 6～18 fatty alcohol-polyoxyethylene ether in stainless reactor, described polymerization degree n after slowly will dissolving successively then is 6～18 fatty alcohol-polyoxyethylene ether, yellow soda ash, propylene glycol joins in the mixing tank, slowly stir,, fully stirred 16～26 minutes to prevent to produce foam, mix, make the clean-out system intermediate liquid;
C) then the coconut acyl diethanolamine essential oil mixture of plant distillation extraction is added in the clean-out system intermediate liquid, wherein the weight percent that adds between each component is: polymerization degree n is 6～18 fatty alcohol-polyoxyethylene ether 20%～30%, coconut acyl diethanolamine volatile oil 20%～30%, yellow soda ash 3%～8%, propylene glycol 8%～13%, surplus are softening water; Stir mixed in 18～25 minutes after, potential of hydrogen is also regulated in test, pH is 7～10 in control, makes plant environment-friendly type cleaning agent.
2. a kind of plant environment-friendly type cleaning agent according to claim 1 is characterized in that, the weight percent of described each raw material is:
Fatty alcohol-polyoxyethylene ether 25%;
Coconut acyl diethanolamine volatile oil 25%;
Yellow soda ash 5%;
Propylene glycol 10%;
Surplus is a softening water.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102339549A CN101899364B (en) | 2009-05-14 | 2009-05-14 | Plant environment-friendly cleaning agent |
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| CN2010102339549A CN101899364B (en) | 2009-05-14 | 2009-05-14 | Plant environment-friendly cleaning agent |
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| CN2009100985888A Division CN101550379B (en) | 2009-05-14 | 2009-05-14 | Plant environment-friendly type cleaning agent and processing method thereof |
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| CN101899364A CN101899364A (en) | 2010-12-01 |
| CN101899364B true CN101899364B (en) | 2011-07-20 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111218691A (en) * | 2018-11-26 | 2020-06-02 | 中国石油天然气股份有限公司 | Cleaning agent for scrapped oil pipelines and preparation method thereof |
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| CN102010804B (en) * | 2010-12-08 | 2011-11-09 | 胡志焕 | Method for producing washing products with towel gourd as raw material |
| CN103275821A (en) * | 2013-02-25 | 2013-09-04 | 冯俏琼 | Automobile dry cleaning agent and preparation method thereof |
| CN105985677A (en) * | 2016-07-11 | 2016-10-05 | 赵艳丽 | Plant-type ink quick cleaning agent and preparation method thereof |
| CN106637254A (en) * | 2016-12-30 | 2017-05-10 | 内蒙古河西航天科技发展有限公司 | Stainless steel surface finishing agent for food processing and preparation method thereof |
| CN106753937A (en) * | 2017-03-04 | 2017-05-31 | 黄胜华 | Antibacterial laundry soap and its production method |
| CN110157560B (en) * | 2019-05-10 | 2021-02-26 | 珠海东方盛隆科技有限公司 | Detergent for hard stains of automobile |
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| WO2004009752A1 (en) * | 2002-07-20 | 2004-01-29 | Cj Corporation | Alkaline liquid detergent composition |
| CN101255381A (en) * | 2007-02-27 | 2008-09-03 | 3M创新有限公司 | Cleaning method and combination |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1405288A (en) * | 2001-08-20 | 2003-03-26 | 潘灿平 | Detergent composition |
| WO2004009752A1 (en) * | 2002-07-20 | 2004-01-29 | Cj Corporation | Alkaline liquid detergent composition |
| CN101255381A (en) * | 2007-02-27 | 2008-09-03 | 3M创新有限公司 | Cleaning method and combination |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111218691A (en) * | 2018-11-26 | 2020-06-02 | 中国石油天然气股份有限公司 | Cleaning agent for scrapped oil pipelines and preparation method thereof |
| CN111218691B (en) * | 2018-11-26 | 2022-03-01 | 中国石油天然气股份有限公司 | Cleaning agent for scrapped oil pipelines and preparation method thereof |
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