CN102807932B - Grease cleaning agent and preparation method thereof - Google Patents
Grease cleaning agent and preparation method thereof Download PDFInfo
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- CN102807932B CN102807932B CN2012103041362A CN201210304136A CN102807932B CN 102807932 B CN102807932 B CN 102807932B CN 2012103041362 A CN2012103041362 A CN 2012103041362A CN 201210304136 A CN201210304136 A CN 201210304136A CN 102807932 B CN102807932 B CN 102807932B
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- mixed
- ether
- group
- acid ester
- fatty acid
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Links
- 239000004519 grease Substances 0.000 title claims description 23
- 239000012459 cleaning agent Substances 0.000 title abstract 3
- 238000002360 preparation method Methods 0.000 title description 6
- 238000002156 mixing Methods 0.000 claims abstract description 17
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 16
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 16
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 15
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 15
- 239000000194 fatty acid Substances 0.000 claims abstract description 15
- 229930195729 fatty acid Natural products 0.000 claims abstract description 15
- -1 sorbitan fatty acid ester Chemical class 0.000 claims abstract description 15
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims abstract description 13
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 36
- 239000011259 mixed solution Substances 0.000 claims description 24
- 238000006243 chemical reaction Methods 0.000 claims description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 230000000873 masking effect Effects 0.000 claims description 14
- 229930195733 hydrocarbon Natural products 0.000 claims description 13
- 150000002430 hydrocarbons Chemical class 0.000 claims description 13
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 6
- 238000001556 precipitation Methods 0.000 claims description 6
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 5
- 235000005956 Cosmos caudatus Nutrition 0.000 claims description 4
- 244000293323 Cosmos caudatus Species 0.000 claims description 4
- 230000006353 environmental stress Effects 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 238000005755 formation reaction Methods 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 238000000746 purification Methods 0.000 claims description 4
- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 abstract 1
- QCAHUFWKIQLBNB-UHFFFAOYSA-N 3-(3-methoxypropoxy)propan-1-ol Chemical compound COCCCOCCCO QCAHUFWKIQLBNB-UHFFFAOYSA-N 0.000 abstract 1
- 239000002781 deodorant agent Substances 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 description 5
- 238000005238 degreasing Methods 0.000 description 4
- 239000002085 irritant Substances 0.000 description 4
- 231100000021 irritant Toxicity 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 206010065954 Stubbornness Diseases 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000006837 decompression Effects 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 239000002516 radical scavenger Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000013268 sustained release Methods 0.000 description 2
- 239000012730 sustained-release form Substances 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000011538 cleaning material Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000003137 locomotive effect Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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- Detergent Compositions (AREA)
Abstract
The invention relates to a cleaning agent. The cleaning agent is formed by mixing and reacting 5 to 10 mass percent of dipropylene glycol monomethyl ether, 30 to 40 mass percent of isomeric alkane, 1 to 2 mass percent of fatty alcohol-polyoxyethylene ether, 3 to 5 mass percent of sorbitan fatty acid ester, 5 to 10 mass percent of butyl cellosolve, 5 to 10 mass percent of propylene glycol ether, 40 to 50 mass percent of alkane and 0.2 to 1 mass percent of deodorant.
Description
Technical field
The present invention relates to a kind of clean-out system, especially a kind of efficient degreasing, seepage force is strong, degradable, smell is light, without skin irritant grease clean-out system and preparation method thereof.
Background technology
The high development of whole world modern industry, the maintenance of mechanical means, the cleaning of the upper grease of especially outmoded mechanical means component (comprising aviation facility, steamer, locomotive, automobile equipment) is continued to use harmful stupid class I liquid I cleaning in order to clean above-mentioned grease at present always.Therefore, be badly in need of a kind of efficient degreasing of research and development, seepage force is strong, degradable, smell is light, without skin irritant novel detergent.
Summary of the invention
The present invention is directed to above-mentioned grease and propose that a kind of technical problem provides a kind of efficient degreasing, seepage force is strong, degradable, smell is light, without skin irritant grease clean-out system and preparation method thereof.
This grease clean-out system is to carry out hybrid reaction by dipropylene glycol methyl ether, isomeric alkane, fatty alcohol-polyoxyethylene ether, sorbitan fatty acid ester, butyl glycol ether, propylene glycol, paraffinic hydrocarbons and taste masking deodovization agent with the ratio of following quality percentage composition to make:
Dipropylene glycol methyl ether 5-10%;
Isomeric alkane 30-40%;
Fatty alcohol-polyoxyethylene ether 1-2%;
Sorbitan fatty acid ester 3-5%;
Butyl glycol ether 5-10%;
Propylene glycol 5-10%;
Paraffinic hydrocarbons 40-50%;
Taste masking deodovization agent 0.2-1%.
Preferably, described taste masking deodovization agent is by parts such as the flower of scented plants, leaf, root, skin, stem, branch, fruit, seeds, the oily mater with characteristic perfume that take to distill, the method such as squeezing, extraction, absorption makes, in order to extend its work-ing life, allow its effect keep for a long time, the long-acting natural phant lasting agent with sustained release performance that can also prepare by advanced person's high molecular nanometer microencapsulation technology at present.
Preferably, this clean-out system is to be that 5% dipropylene glycol methyl ether, 35% isomeric alkane, 2% fatty alcohol-polyoxyethylene ether, 5% sorbitan fatty acid ester, 5% butyl glycol ether, 6% propylene glycol, 41% paraffinic hydrocarbons, 1% taste masking deodovization agent carry out hybrid reaction and make by the quality percentage composition.
Preferably, the nanometer Margarita powder that adds 0.01-0.05% in described taste masking deodovization agent.
The present invention also provides a kind of method for preparing above-mentioned grease clean-out system, and it comprises the steps:
The first step, taking in proportion fatty alcohol-polyoxyethylene ether and sorbitan fatty acid ester packs in airtight mixing vessel, be uniformly mixed under 25-35 ℃ of normal pressure and form first group's mixed solution, take in proportion dipropylene glycol methyl ether, isomeric alkane, butyl glycol ether, propylene glycol, paraffinic hydrocarbons and taste masking deodovization agent, any two kinds are mixed and join respectively in airtight mixing vessel, stirred 30 minutes under 25-35 ℃ of normal pressure, be mixed to form second, third and the 4th group's mixed solution;
Second step joins described second, third in first group's mixed solution that is mixed to form by fatty alcohol-polyoxyethylene ether and sorbitan fatty acid ester with the 4th group's mixed solution in batches, and every batch adds rear the stirring under 25-35 ℃ of normal pressure to mix in 30 minutes;
In the 3rd step, mix and be uniformly mixed after complete standingly until four group's mixed solutions, then filters precipitation and form reaction solution;
The 4th step, then with this reaction solution stirring reaction under the environmental stress of 2-5MPa, until carry out after mixing forming product after filtration, purification.
Preferably, described the 3rd step is uniformly mixed after complete standingly for until four group's mixed solutions, mixing, and then with 400 order strainers, filters precipitation formation reaction solution.
This technical scheme compared with prior art has following beneficial effect:
This clean-out system is a kind of efficient degreasing, and seepage force is strong, and is degradable, and smell is light, without skin irritant novel detergent.
Specific embodiment
This grease clean-out system provided by the present invention, it is by fatty alcohol-polyoxyethylene ether and sorbitan fatty acid ester, dipropylene glycol methyl ether and isomeric alkane, butyl glycol ether and propylene glycol, paraffinic hydrocarbons and taste masking deodovization agent are mixed to form respectively four group's mixed solutions with the ratio of following quality percentage composition, and then four group's mixed solutions are carried out hybrid reaction and make:
Dipropylene glycol methyl ether 5-10%; Isomeric alkane 30-40%; Fatty alcohol-polyoxyethylene ether 1-2%; Sorbitan fatty acid ester 3-5%; Butyl glycol ether 5-10%; Propylene glycol 5-10%; Paraffinic hydrocarbons 40-50%; Taste masking deodovization agent 0.2-1%.
Wherein, isomeric alkane is the oil-based solvent of 10-18 carbon atom; Fatty alcohol-polyoxyethylene ether, its general formula is: R-O-(CH2CH2O)
n-H, R are the alkyl of saturated or unsaturated C12～18, can be straight-chain alkyls, can be also branched alkyl, n=6～8, and the preferred fat polyoxyethylenated alcohol is the AEO series of surfactants; Paraffinic hydrocarbons is the straight-chain paraffin of 2-8 carbon; The taste masking deodovization agent is by parts such as the flower of scented plants, leaf, root, skin, stem, branch, fruit, seeds, the oily mater with characteristic perfume that take to distill, the method such as squeezing, extraction, absorption makes, in order to extend its work-ing life, allow its effect keep for a long time, the long-acting natural phant lasting agent with sustained release performance that can also prepare by advanced person's high molecular nanometer microencapsulation technology at present, industrial essence namely, mask agent commonly used in a kind of heavy chemicals field.
Below with the preparation 100KG the grease clean-out system describe in detail this grease clean-out system provided by the present invention with and concrete preparation method.
Embodiment 1:
The sorbitan fatty acid ester that takes respectively the fatty alcohol-polyoxyethylene ether of 2Kg and 5Kg is packed in airtight mixing vessel, stirs 30 minutes under 25-35 ℃ of normal pressure, is mixed to form first group's mixed solution; Take respectively the butyl glycol ether of 5Kg dipropylene glycol methyl ether, 35Kg isomeric alkane, 5KG, the propylene glycol of 6KG, the paraffinic hydrocarbons of 41KG, the nanometer natural essential oil (containing the 0.005Kg nanometer Margarita powder) of 1KG, any two kinds are mixed and join respectively in airtight mixing vessel, stirred 30 minutes under 25 ℃ of normal pressures, be mixed to form second, third and the 4th group's mixed solution.
with above-mentioned second, third and fourth group's mixed solution joins in above-mentioned first group's mixed solution in batches, use the every batch of stirring under 25 ℃ of normal pressures of mixing tank or similar variable-ratio machine (with the suitable general mixing of thruster and kneading operation) to mix in 30 minutes, until four group's mixed solutions mix be uniformly mixed after complete standing, then cross elimination with 400 orders and filter precipitation formation reaction solution, again this reaction solution is continued under the environmental stress of 2MPa stirring and completed reaction in 30 minutes, then reaction solution is carried out filtration, purification, carry out packing and form the grease rinse product after filtrate constant temperature (20 ℃ of left and right).
Embodiment 2:
The sorbitan fatty acid ester that takes respectively the fatty alcohol-polyoxyethylene ether of 1Kg and 3Kg is packed in airtight mixing vessel, stirs 30 minutes under 35 ℃ of normal pressures, is mixed to form first group's mixed solution; Take respectively the butyl glycol ether of 10Kg dipropylene glycol methyl ether, 31Kg isomeric alkane, 6KG, the propylene glycol of 7KG, the paraffinic hydrocarbons of 41KG, the nanometer natural essential oil (containing the 0.005Kg nanometer Margarita powder) of 1KG, any two kinds are mixed and join respectively in airtight mixing vessel, stirred 30 minutes under 35 ℃ of normal pressures, be mixed to form second, third and the 4th group's mixed solution.
with above-mentioned second, third and fourth group's mixed solution joins in above-mentioned first group's mixed solution in batches, use the every batch of stirring under 35 ℃ of normal pressures of mixing tank or similar variable-ratio machine (with the suitable general mixing of thruster and kneading operation) to mix in 30 minutes, until four group's mixed solutions mix be uniformly mixed after complete standing, then cross elimination with 400 orders and filter precipitation formation reaction solution, again this reaction solution is continued under the environmental stress of 5MPa stirring and completed reaction in 30 minutes, then reaction solution is carried out filtration, purification, carry out packing and form the grease rinse product after filtrate constant temperature (20 ℃ of left and right).
Below the using method of this grease clean-out system described:
This grease clean-out system adopts metal inhalator jar splendid attire, on the spray cans mouth, injection spray pipe is installed, and makes injection spray pipe in cleaning materials 10-15CM scope, and on cleaned material, pressure is more than 20kg/cm2 with the clean-out system spray attachment, and spraying is cleaned.Clean-out system stops 5-7 at scavenger surface and permeates decomposition second, then with wet towel, wipes residual dirt, and clean as new scavenger surface will come into view.Run into the serious color dirty print of stubbornness, adopt dipping adding spraying and clean and can prove effective fast, can add the extension shower nozzle to the place, gap and clean.
This product also is used for the jet combined type cleaning of ultrasonic wave decompression, obstinate cleaning objects is put into the rinse bath that the high-efficiency grease clean-out system is housed, and ultrasonic oscillator is installed in groove, produces ultrasonic energy (thousands of atmospheric shockwave), and substrate is all cleaned.Give simultaneously in groove and produce negative pressure, due to decompression, washing composition can be penetrated between the gap of substrate preferably, both carries out simultaneously, and cleaning performance will increase greatly, at the grease of stubbornness, can clean up, and gets final product with jet drying up finally.
Above disclosed is only some preferred embodiments of the present invention, certainly can not limit with this interest field of the present invention, and the equivalent variations of therefore according to the present patent application the scope of the claims, doing, still belong to the scope that the present invention is contained.
Claims (5)
1. grease clean-out system, it carries out hybrid reaction by dipropylene glycol methyl ether, isomeric alkane, fatty alcohol-polyoxyethylene ether, sorbitan fatty acid ester, butyl glycol ether, propylene glycol, paraffinic hydrocarbons and taste masking deodovization agent with the ratio of following quality percentage composition and makes:
Dipropylene glycol methyl ether 5-10%;
Isomeric alkane 30-40%;
Fatty alcohol-polyoxyethylene ether 1-2%;
Sorbitan fatty acid ester 3-5%;
Butyl glycol ether 5-10%;
Propylene glycol 5-10%;
Paraffinic hydrocarbons 40-50%;
Taste masking deodovization agent 0.2-1%.
2. grease clean-out system as claimed in claim 1, it is characterized in that, it is that 5% dipropylene glycol methyl ether, 35% isomeric alkane, 2% fatty alcohol-polyoxyethylene ether, 5% sorbitan fatty acid ester, 5% butyl glycol ether, 6% propylene glycol, 41% paraffinic hydrocarbons, 1% taste masking deodovization agent carry out hybrid reaction and make by the quality percentage composition.
3. grease clean-out system as claimed in claim 2, is characterized in that, adds the nanometer Margarita powder of 0.01-0.05% in described taste masking deodovization agent.
One kind prepare as arbitrary in claims 1 to 3 as described in the method for grease clean-out system, it comprises the steps:
The first step, taking in proportion fatty alcohol-polyoxyethylene ether and sorbitan fatty acid ester packs in airtight mixing vessel, be uniformly mixed under 25-35 ℃ of normal pressure and form first group's mixed solution, take in proportion dipropylene glycol methyl ether, isomeric alkane, butyl glycol ether, propylene glycol, paraffinic hydrocarbons and taste masking deodovization agent, any two kinds are mixed and join respectively in airtight mixing vessel, stirred 30 minutes under 25-35 ℃ of normal pressure, be mixed to form second, third and the 4th group's mixed solution;
Second step joins described second, third in first group's mixed solution that is mixed to form by fatty alcohol-polyoxyethylene ether and sorbitan fatty acid ester with the 4th group's mixed solution in batches, and every batch adds rear the stirring under 25-35 ℃ of normal pressure to mix in 30 minutes;
In the 3rd step, mix and be uniformly mixed after complete standingly until four group's mixed solutions, then filters precipitation and form reaction solution;
The 4th step, then with this reaction solution stirring reaction under the environmental stress of 2-5MPa, until carry out after mixing forming product after filtration, purification.
5. the method for grease clean-out system as claimed in claim 4, is characterized in that, described the 3rd step is uniformly mixed after complete standingly for until four group's mixed solutions, mixing, and then with 400 order strainers, filters precipitation formation reaction solution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103041362A CN102807932B (en) | 2012-08-24 | 2012-08-24 | Grease cleaning agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103041362A CN102807932B (en) | 2012-08-24 | 2012-08-24 | Grease cleaning agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102807932A CN102807932A (en) | 2012-12-05 |
| CN102807932B true CN102807932B (en) | 2013-11-13 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012103041362A Expired - Fee Related CN102807932B (en) | 2012-08-24 | 2012-08-24 | Grease cleaning agent and preparation method thereof |
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| Country | Link |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103614687B (en) * | 2013-11-22 | 2016-04-27 | 西峡龙成特种材料有限公司 | A kind of preparation technology of continuous casting crystallizer copper plate surface cermet coating |
| CN109967467A (en) * | 2019-03-04 | 2019-07-05 | 扬州中天利新材料股份有限公司 | The Hand scarf method of tank body oil-soluble deposition oil |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1159478A (en) * | 1995-11-13 | 1997-09-17 | 株式会社日本能源 | Lowly corrosive cleaner composition |
| CN101748003A (en) * | 2009-12-23 | 2010-06-23 | 深圳市唯特偶化工开发实业有限公司 | Halogen free environment-friendly cleaning agent |
| CN102191141A (en) * | 2010-03-17 | 2011-09-21 | 东莞市新球防锈有限公司 | Modified hydrocarbon cleaning agent |
-
2012
- 2012-08-24 CN CN2012103041362A patent/CN102807932B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1159478A (en) * | 1995-11-13 | 1997-09-17 | 株式会社日本能源 | Lowly corrosive cleaner composition |
| CN101748003A (en) * | 2009-12-23 | 2010-06-23 | 深圳市唯特偶化工开发实业有限公司 | Halogen free environment-friendly cleaning agent |
| CN102191141A (en) * | 2010-03-17 | 2011-09-21 | 东莞市新球防锈有限公司 | Modified hydrocarbon cleaning agent |
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| Publication number | Publication date |
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| CN102807932A (en) | 2012-12-05 |
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