CN103834487A - Heavy grease stain environment-friendly type water base cleaning compound - Google Patents
Heavy grease stain environment-friendly type water base cleaning compound Download PDFInfo
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- CN103834487A CN103834487A CN201410057977.7A CN201410057977A CN103834487A CN 103834487 A CN103834487 A CN 103834487A CN 201410057977 A CN201410057977 A CN 201410057977A CN 103834487 A CN103834487 A CN 103834487A
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Abstract
The invention discloses a heavy grease stain environment-friendly type water base cleaning compound comprising 10-15% of surfactant, 1-3% of additive, 1-5% of antiseptic, 3-5% of organic amine and remaining tap water; the ingredient of the surfactant comprises 4-5% of aliphatic acid methyl esters ethoxylate, 2-3.5% of APG, 1-3% of fatty alcohol polyoxyethylene ether sodium sulfate (AES), 0.5-1% of straight chain sodium alkyl benzene sulfonate (LAS) and 0.5-2% of aliphatic acid methyl esters ethoxylate; the additive is one or more from a group formed by sodium citrate, citric acid, lactic acid and DL-malic acid; the organic amine is one or more from a group formed by triethanolamine, n-butylamine, diethanolamine and N-methyl diethanolamine; the antiseptic at least is triclosan or tetrachloro isophthalonitrile; through the said method, the heavy grease stain environment-friendly type water base cleaning compound has anti bacterium, heavy grease stain cleaning and environmental protection performances.
Description
Technical field
The present invention relates to clean-out system field, particularly relate to a kind of heavy oil stain environment-friendly type water based cleaning agent.
Background technology
The main flow heavy oil stain clean-out system adopting on Vehicles Collected from Market adopts high solvent, high pH value or high-alkali formula more, causes its security and the feature of environmental protection not good enough.How, for the feature of metallic surface heavy oil stain, development is efficient, the low-cost water-based clean-out system of Environmental Safety is a great problem in civilian cleaning field.
The existing heavy oil stain environment-friendly type water based cleaning agent being re-dubbed by polyoxyethylenated alcohol sodium sulfate (AES) and alkyl glycoside (APG) etc. has adopted the solubility promoter D-limonene mandarin oil that price is relatively high, cleaning performance has certain limitation, and cost is high, action effect is limited.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of heavy oil stain environment-friendly type water based cleaning agent, be lead composite Anionic-nonionic tensio-active agent not only and between other component, there is fabulous consistency by selected fatty acid FMEE and alkyl glycoside APG, can also effectively improve the degreasing rate of nonionogenic tenside; Can effectively remove Ca2+, the Mg2+ in tap water by sequestrant Trisodium Citrate, can finely tune again the pH value of solution, improve the detergency ability of clean-out system.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: a kind of heavy oil stain environment-friendly type water based cleaning agent is provided, comprise: the tap water of tensio-active agent 10-15%, additive 1-3%, antiseptic-germicide 1-5%, organic amine 3-5% and surplus, in mass, is chemical pure.
In a preferred embodiment of the present invention, the each composite component of described tensio-active agent and the mass percent in clean-out system are: fatty acid methyl ester ethoxylate 4-5%, alkyl glycoside (APG) 2-3.5%, polyoxyethylenated alcohol sodium sulfate (AES) 1-3%, linear alkylbenzene sulphonic acid (LAS) 0.5-1% and fatty acid methyl ester ethoxylate 0.5-2%.
In a preferred embodiment of the present invention, described additive is one or more mixing of Trisodium Citrate, citric acid, lactic acid and DL-oxysuccinic acid.
In a preferred embodiment of the present invention, described organic amine is one or more mixing in trolamine, n-Butyl Amine 99, diethanolamine, N methyldiethanol amine.
In a preferred embodiment of the present invention, described antiseptic-germicide is at least one in triclosan and termil powder.
The invention has the beneficial effects as follows: heavy oil stain environment-friendly type water based cleaning agent of the present invention is lead composite Anionic-nonionic tensio-active agent not only and between other component, have fabulous consistency by selected fatty acid FMEE and alkyl glycoside APG, can also effectively improve the degreasing rate of nonionogenic tenside; Can effectively remove Ca2+, the Mg2+ in tap water by sequestrant Trisodium Citrate, can finely tune again the pH value of solution, improve the detergency ability of clean-out system; Organic bases trolamine can with grease generation saponification, grease is spun off under solution impulse action, can also stop or slow down corrosion of metal speed.
Embodiment
To the technical scheme in the embodiment of the present invention be clearly and completely described below, obviously, described embodiment is only a part of embodiment of the present invention, instead of whole embodiment.Based on the embodiment in the present invention, those of ordinary skill in the art, not making all other embodiment that obtain under creative work prerequisite, belong to the scope of protection of the invention.
The embodiment of the present invention comprises:
A kind of heavy oil stain environment-friendly type water based cleaning agent, comprising: the tap water of tensio-active agent 10-15%, additive 1-3%, antiseptic-germicide 1-5%, organic amine 3-5% and surplus, in mass, is chemical pure.
The each composite component of described tensio-active agent and the mass percent in clean-out system are: fatty acid methyl ester ethoxylate 4-5%, alkyl glycoside (APG) 2-3.5%, polyoxyethylenated alcohol sodium sulfate (AES) 1-3%, linear alkylbenzene sulphonic acid (LAS) 0.5-1% and fatty acid methyl ester ethoxylate 0.5-2%.
In the present invention, described alkyl glycoside APG for short, synthetic by renewable resources natural fat alcohol and glucose, it is the more comprehensive new non-ionic surfactants of a kind of performance, have the characteristic of common nonionic and anion surfactant concurrently, having high surface, good ecological security and intermiscibility, is internationally recognized first-selection " green " functional surface promoting agent;
Polyoxyethylenated alcohol sodium sulfate (AES), suitable with edible salt and sodium bicarbonate, belong to non-toxic substance.Soluble in water, there is good decontamination, emulsification, foam performance and anti-performance of hard water, gentle washing character can injured skin.Be widely used in the washing cosmetic articles for use such as shampoo, body lotion, dish washing detergent, compound soap; For textile industry wetting agent, sanitising agent etc.;
Linear alkylbenzene sulphonic acid (LAS) is the industrial general designation to alkyl benzene sulphonate (ABS) and salt thereof, belongs to fatty acid and salt, and for the production of tensio-active agent, such as washing composition etc., without dangerous.
In the present invention, select industrial goods green surfactant non-ionic type APG, polyoxyethylenated alcohol sodium sulfate (AES) and fatty acid methyl ester ethoxylate, linear alkylbenzene sulphonic acid (LAS) combination, not only temperature applicable range is wide for clean-out system through making with organic bases trolamine, without phosphorus sequestrant Trisodium Citrate and tap water organic complex, and the detersive power after diluting 10 times is still higher than 90%.
In the present invention, fatty acid methyl ester ethoxylate (FMEE) is a kind of typical nonionogenic tenside, be with fatty acid methyl ester under corresponding catalyst effect, there is addition and make in direct and oxyethane (EO), compared with traditional fatty alcohol ethoxylate (AEO), there is low foam, high cloud point, the feature that the molten speed of cold water is fast and removing oil-removing wax is effective, still there is in the winter time good mobility, FMEE in various performances close to the TX that contains APEO, NP and OP series, under the background of abroad environmental protection being strict with, the toy that uses FMEE to replace TX or NP to process, floor, textile garment etc., adopt fatty acid methyl ester ethoxylate as tensio-active agent, having outside the performance close with TX-10 with traditional OP, environmental protection more, health,
Above-mentioned APEO comprises polyoxyethylene nonylphenol ether (NPEO), polyoxyethylene octylphenol ether (OPEO), dodecyl phenol polyethenoxy ether (DPEO) and Dinonylphenol Polyoxyethylene Ether (DNPEO), wherein widely used polyoxyethylene nonylphenol ether is also the one in APEO, APEO can cause more serious hazardness to ecotope, harmful side product that comprises that toxicity is large, biological degradation is difficult, produce in environmental hormone effect and production process etc., people look for gradually its substitute and carry out the configuration of soldering flux.
Described additive is one or more mixing of Trisodium Citrate, citric acid, lactic acid and DL-oxysuccinic acid.
In the present invention, described Trisodium Citrate, citric acid, lactic acid and DL-oxysuccinic acid are alcohol acid, alcohol acid is because contain hydroxyl and carboxyl Liang Zhong functional group in molecule, there is the general aspects of hydroxyl and carboxyl, and because hydroxyl in alcohol acid molecule is to inhale electric base, there is electrophilic inductive effect, the dissociation degree of carboxyl is increased, acid stronger than corresponding carboxylic acid, because these organic acid boiling points and decomposition temperature have certain difference, multiple organic acid activator is used in combination, can make the boiling point of soldering flux and the decomposition temperature of promoting agent present a larger interval distributes, keep soldering flux in whole welding process all to there is higher activity, obtain good welding effect, because the fusing point of the activation temperature of soldering flux and leadless welding alloy adapts, improve lead-free solder wettability so can play, the effect of anti-oxidation and raising welding property.
Described organic amine is one or more mixing in trolamine, n-Butyl Amine 99, diethanolamine, N methyldiethanol amine.
In the present invention, described trolamine is colourless to faint yellow transparent thick liquid, and micro-have an ammonia taste, becomes colourless to faint yellow isometric system crystal when low temperature.Soluble in water, ethanol, acetone, glycerine and ethylene glycol etc., be strong basicity, and tool water absorbability, has larger corrodibility to copper, aluminium and alloy thereof, flammable, low toxicity;
Described n-Butyl Amine 99 is generally used for system medicine, pesticide herbicide, dyestuff, tensio-active agent, rubber processing aids etc.For the production of the speciality plasticizer of sterilant, medicine, tackiness agent, polymeric amide;
Diethanolamine is colorless viscous liquid or crystallization, has alkalescence, can absorb the gases such as airborne carbonic acid gas and hydrogen sulfide; As analytical reagent, acid gas absorbent, for the purification of the industry such as coke gas, and can be recycled; Also for washing composition processed, polish, lubricant, tenderizer, tensio-active agent etc., also can be used for organic synthesis; In shampoo and light-duty washing agent, as thickening material lather modifier, in synthon and leather production, be used as softening agent;
N methyldiethanol amine contains two hydroxyls and an amino, and hydroxyl reduces vapour pressure, increases solubleness, is conducive to the absorption of sour gas, can improve concentration, reduces internal circulating load, reduces energy consumption; The existence of methyl in amino, has reduced amino alkalescence, activity, and the specific absorptioies such as CO2 are reduced; N methyldiethanol amine is colourless or micro-yellow viscous liquid, 247 DEG C of boiling points, soluble in water and alcohol, be slightly soluble in ether, flammable, nontoxic,, be a kind of selective desulfurization, decarburization novel dissolvent of excellent property, there is the advantages such as selectivity is high, solvent consumption is few, energy-saving effect is remarkable, difficult degraded.
Described antiseptic-germicide is at least one in triclosan and termil powder.
In the present invention, described triclosan formal name used at school " triclosan ", chemical molecular formula is C12H7Cl3O2, has another name called " triclosan ", " Triclosan " etc., triclosan normality is white or the crystalline powder of canescence, slightly phenol stink.Water insoluble, be soluble in alkali lye and organic solvent.Triclosan is a kind of broad spectrum antimicrobicide, is widely used among the household chemicals such as soap, toothpaste.
Described termil powder is pale powder, and common name is m-tetrachlorophthalodinitrile, and odorlessness is stable under storage at normal temperature condition, stable to illumination, stable in weak acid, weak base medium, decomposes non-corrosiveness in highly basic medium.The antioxidant effect of termil powder is very good, stronger 5～7 times than BHA, BHT, PG.Being applicable to animals and plants fat and fat-rich food, being specially adapted in vegetables oil, is that salad oil, mixed oil, height are cooked the first-selected antioxidant of oil.Can effectively delay Oxidation of Fat and Oils, improve the stability of food, extend significantly the shelf-lives of grease and fat-rich food.It is also high temperature resistant, can be used for instant noodles, cake and other fried food product, and the highest withstand temp can reach more than 230 DEG C.And it goes back potion multipotency, effectively anti-bacteria and mould-growth.Adding in range of application, can suppress nearly all bacterium and Yeast Growth, the mould that flavus etc. is detrimental to health has good restraining effect.
The preparation of clean-out system:
Two reactors are labeled as to A and B, a certain amount of alkyl glycoside (APG) and tap water are joined in A, change at 50 DEG C even; By required fatty acid methyl ester ethoxylate, polyoxyethylenated alcohol sodium sulfate (AES), linear alkylbenzene sulphonic acid (LAS), fatty acid methyl ester ethoxylate with join in B, solution in B is added in A and is stirred, form solution, and add successively organic amine and additive, until formation solution adds the tap water of antiseptic-germicide and surplus to 100mL.
Cleaning experiment:
Clean test piece is weighed after cooling 30 min in dry 30 min, moisture eliminator at 120 DEG C.With hairbrush, at test piece regulation position coating grease, its quality control, at (0.24 ± 0.02) g, after being transferred in dry culture dish, being dried successively 10 min, in moisture eliminator, after ageing 20～22 h, test piece being weighed at 200 DEG C; Test piece is placed in to 500 mL beakers, adds after 50 mL clean-out systems, beaker is positioned over to 10 min that vibrate in 25 DEG C, the constant temperature oscillation case of certain rotating speed, take out test piece, at 120 DEG C, in dry 20 min, moisture eliminator, after cooling 30 min, weigh.
Embodiment:
Alkyl glycoside (APG) 3% and appropriate tap water are joined in reactor A, change at 50 DEG C even; By required fatty acid methyl ester ethoxylate 4%, polyoxyethylenated alcohol sodium sulfate (AES) 3%, linear alkylbenzene sulphonic acid (LAS) 1%, fatty acid methyl ester ethoxylate 2% with join in B, solution in B is added in A and is stirred, form solution, and add successively organic amine 4% and additive 3%, until formation solution, add the tap water of antiseptic-germicide 4% and surplus to 100mL, in mass.Carry out cleaning action according to above-mentioned cleaning experiment step.
Comparative example:
Commercially available certain multiplex clean-out system in brand kitchen carries out cleaning action according to above-mentioned cleaning experiment step.
Comparative analysis:
With reference to national standard, the indexs such as outward appearance, smell, stability, basicity, pH value and the corrodibility to self-control clean-out system and commercially available certain multiplex clean-out system in brand kitchen compare test, and result is as follows:
Clean-out system sample of the present invention:
Outward appearance: shallow yellow transparent solution
Smell: without special odor
Stability: good, in the insulation can of (40 ± 2) DEG C or (5 ± 2) DEG C, place 24 h, or at room temperature place 1 month, without special odor, without layering, without research of chaotic phenomenon;
Basicity (Na2O)/%: 1.045;
PH value (25 DEG C, 1% solution): 8.3;
Corrodibility [outward appearance, etching extent (LY12)]/mg:Grade 0,3.9.
Commercially available brand clean-out system:
Outward appearance: orange clear solution;
Smell: without the light aromatising flavour of special odor;
Stability: stability: good, in the insulation can of (40 ± 2) DEG C or (5 ± 2) DEG C, place 24 h, or at room temperature place 1 month, without special odor, without layering, without research of chaotic phenomenon;
Basicity (Na2O)/%: 1.482;
PH value (25 DEG C, 1% solution): 9.5;
Corrodibility [outward appearance, etching extent (LY12)]/mg: Grade 2,3.3.
As from the foregoing, self-control clean-out system be light yellow transparent liquid, without special odor, good stability, and basicity, pH value and to corrosion of metal rate all lower than commercially available certain multiplex clean-out system in brand kitchen, detersive power is better than the latter, has realized the high efficiency of cleaning performance under nearly neutral pH value.
In the present invention, clean-out system cleaning performance excellence former because: the organic complex taking fatty acid methyl ester ethoxylate and alkyl glycoside APG as main Anionic-nonionic tensio-active agent, not only and between other component, have fabulous consistency, can also effectively improve the degreasing rate of nonionogenic tenside; Sequestrant Trisodium Citrate can be removed Ca2+, the Mg2+ in tap water effectively, can finely tune again the pH value of solution, improves the detergency ability of clean-out system; Organic bases trolamine can with grease generation saponification, grease is spun off under solution impulse action, can also stop or slow down corrosion of metal speed.
The beneficial effect of heavy oil stain environment-friendly type water based cleaning agent of the present invention is:
One, can effectively clean for the heavy oil stain of metallic surface by the organic complex of fatty acid methyl ester ethoxylate and alkyl glycoside APG, and the main formula of this aqueous cleaning agent has compatible good, substantially non-stimulated, degradable, eco-friendly feature, adapt to clean-out system industry progressively to the trend of environmental protection, efficient future development;
Two, there is the wide feature of temperature applicable range compared with common heavy oil stain environment-friendly type water based cleaning agent, and after diluting 10 times detersive power still higher than 90%, in addition, tensio-active agent and auxiliary agent that formula adopts are cheap industrial raw material, solvent is tap water, and cost is low, and preparation technology is simple, having application value widely, is a kind of new and effective and green tensio-active agent;
Three, heavy oil stain environment-friendly type water based cleaning agent of the present invention has the heavy oil stain broad application temperature range of removal, speed is fast, efficiency is high, resistance to hard water and the remarkable advantage such as raw materials cost is lower, and the wide advantage of use range.
The foregoing is only embodiments of the invention; not thereby limit the scope of the claims of the present invention; every equivalent structure or conversion of equivalent flow process that utilizes description of the present invention to do; or be directly or indirectly used in other relevant technical field, be all in like manner included in scope of patent protection of the present invention.
Claims (5)
1. a heavy oil stain environment-friendly type water based cleaning agent, is characterized in that, comprising: the tap water of tensio-active agent 10-15%, additive 1-3%, antiseptic-germicide 1-5%, organic amine 3-5% and surplus, in mass, is chemical pure.
2. heavy oil stain environment-friendly type water based cleaning agent according to claim 1, it is characterized in that, the each composite component of described tensio-active agent and the mass percent in clean-out system are: fatty acid methyl ester ethoxylate 4-5%, alkyl glycoside (APG) 2-3.5%, polyoxyethylenated alcohol sodium sulfate (AES) 1-3%, linear alkylbenzene sulphonic acid (LAS) 0.5-1% and fatty acid methyl ester ethoxylate 0.5-2%.
3. heavy oil stain environment-friendly type water based cleaning agent according to claim 1, is characterized in that, described additive is one or more mixing of Trisodium Citrate, citric acid, lactic acid and DL-oxysuccinic acid.
4. heavy oil stain environment-friendly type water based cleaning agent according to claim 1, is characterized in that, described organic amine is one or more mixing in trolamine, n-Butyl Amine 99, diethanolamine, N methyldiethanol amine.
5. heavy oil stain environment-friendly type water based cleaning agent according to claim 1, is characterized in that, described antiseptic-germicide is at least one in triclosan and termil powder.
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Cited By (14)
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| CN104263542A (en) * | 2014-10-24 | 2015-01-07 | 无棣华信石油技术服务有限公司 | Degradable severe oil pollution cleaning agent and preparation method thereof |
| CN105062708A (en) * | 2015-08-10 | 2015-11-18 | 兰州瑞普科技实业有限责任公司 | Cleaning agent for water-oil heat exchange plate type heat exchanger |
| CN105273857A (en) * | 2015-10-30 | 2016-01-27 | 武汉理工大学 | Multifunctional green water-based cleaning agent and preparation method for multifunctional green water-based cleaning agent |
| CN105727657A (en) * | 2016-03-08 | 2016-07-06 | 张征北 | Purifying auxiliary for smoke particles and application in power plant production |
| CN105821419A (en) * | 2016-04-29 | 2016-08-03 | 大连碧城环保科技股份有限公司 | Water-based metal cleaning agent and preparation method thereof |
| CN105985869A (en) * | 2015-02-02 | 2016-10-05 | 上海净安化工科技有限公司 | Concentrated multifunctional detergent |
| CN106318686A (en) * | 2016-08-16 | 2017-01-11 | 中轻日化科技有限公司 | Efficient and environment-friendly concentrated hard surface cleaning agent |
| CN107012004A (en) * | 2017-06-14 | 2017-08-04 | 苏州永创达电子有限公司 | A kind of cleaning agent of fragrant strong detergency |
| CN107828529A (en) * | 2017-10-30 | 2018-03-23 | 无锡中科苏惠自动化技术有限公司 | A kind of water base complex cleaning and washing agent of efficient quick-drying for automation equipment |
| CN107937171A (en) * | 2017-11-29 | 2018-04-20 | 黑龙江省科学院高技术研究院 | A kind of low bubble green CIP sterilization concentrated type cleaning agents |
| CN108641830A (en) * | 2018-05-09 | 2018-10-12 | 苏州捷德瑞精密机械有限公司 | A kind of mechanical apparatus surface cleaner and preparation method thereof |
| CN112481045A (en) * | 2020-06-19 | 2021-03-12 | 新安洁环境卫生股份有限公司 | Low-foam cleaning agent and preparation method and application thereof |
| CN112481046A (en) * | 2020-11-26 | 2021-03-12 | 广东一芙化妆品有限公司 | Antibacterial kitchen detergent |
| CN112745992A (en) * | 2020-12-31 | 2021-05-04 | 广东好顺欧迪斯科技股份有限公司 | Water-based cleaning agent, and preparation method and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103045401A (en) * | 2013-01-19 | 2013-04-17 | 重庆暄洁环保产业（集团）股份有限公司 | Water-base oil dirt cleaning agent and preparation method thereof |
-
2014
- 2014-02-20 CN CN201410057977.7A patent/CN103834487A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103045401A (en) * | 2013-01-19 | 2013-04-17 | 重庆暄洁环保产业（集团）股份有限公司 | Water-base oil dirt cleaning agent and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 王慎敏: "《日用化学品》", 30 June 2005, 化学工业出版社 * |
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| CN104263542A (en) * | 2014-10-24 | 2015-01-07 | 无棣华信石油技术服务有限公司 | Degradable severe oil pollution cleaning agent and preparation method thereof |
| CN105985869A (en) * | 2015-02-02 | 2016-10-05 | 上海净安化工科技有限公司 | Concentrated multifunctional detergent |
| CN105062708A (en) * | 2015-08-10 | 2015-11-18 | 兰州瑞普科技实业有限责任公司 | Cleaning agent for water-oil heat exchange plate type heat exchanger |
| CN105273857B (en) * | 2015-10-30 | 2018-05-01 | 武汉理工大学 | A kind of multifunctional green aqueous cleaning agent and preparation method thereof |
| CN105273857A (en) * | 2015-10-30 | 2016-01-27 | 武汉理工大学 | Multifunctional green water-based cleaning agent and preparation method for multifunctional green water-based cleaning agent |
| CN105727657A (en) * | 2016-03-08 | 2016-07-06 | 张征北 | Purifying auxiliary for smoke particles and application in power plant production |
| CN105821419A (en) * | 2016-04-29 | 2016-08-03 | 大连碧城环保科技股份有限公司 | Water-based metal cleaning agent and preparation method thereof |
| CN106318686A (en) * | 2016-08-16 | 2017-01-11 | 中轻日化科技有限公司 | Efficient and environment-friendly concentrated hard surface cleaning agent |
| CN106318686B (en) * | 2016-08-16 | 2020-06-05 | 中轻日化科技有限公司 | Efficient environment-friendly concentrated hard surface cleaning agent |
| CN107012004A (en) * | 2017-06-14 | 2017-08-04 | 苏州永创达电子有限公司 | A kind of cleaning agent of fragrant strong detergency |
| CN107828529A (en) * | 2017-10-30 | 2018-03-23 | 无锡中科苏惠自动化技术有限公司 | A kind of water base complex cleaning and washing agent of efficient quick-drying for automation equipment |
| CN107937171B (en) * | 2017-11-29 | 2020-02-04 | 黑龙江省科学院高技术研究院 | Low-foam green CIP (CIP) sterilization concentrated cleaning agent |
| CN107937171A (en) * | 2017-11-29 | 2018-04-20 | 黑龙江省科学院高技术研究院 | A kind of low bubble green CIP sterilization concentrated type cleaning agents |
| CN108641830A (en) * | 2018-05-09 | 2018-10-12 | 苏州捷德瑞精密机械有限公司 | A kind of mechanical apparatus surface cleaner and preparation method thereof |
| CN112481045A (en) * | 2020-06-19 | 2021-03-12 | 新安洁环境卫生股份有限公司 | Low-foam cleaning agent and preparation method and application thereof |
| CN112481046A (en) * | 2020-11-26 | 2021-03-12 | 广东一芙化妆品有限公司 | Antibacterial kitchen detergent |
| CN112745992A (en) * | 2020-12-31 | 2021-05-04 | 广东好顺欧迪斯科技股份有限公司 | Water-based cleaning agent, and preparation method and application thereof |
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Application publication date: 20140604 |