CN105273857A - Multifunctional green water-based cleaning agent and preparation method for multifunctional green water-based cleaning agent - Google Patents
Multifunctional green water-based cleaning agent and preparation method for multifunctional green water-based cleaning agent Download PDFInfo
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- CN105273857A CN105273857A CN201510717930.3A CN201510717930A CN105273857A CN 105273857 A CN105273857 A CN 105273857A CN 201510717930 A CN201510717930 A CN 201510717930A CN 105273857 A CN105273857 A CN 105273857A
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Abstract
The invention discloses a multifunctional green water-based cleaning agent and a preparation method for the multifunctional green water-based cleaning agent. A formula comprises: 0.5 to 10.0 percent of octyl/decyl glucoside (APG0810), 0.5 to 8.0 percent of fatty acid methyl ester ethoxylate (FMEE), 1.0 to 4.0 percent of coconut oil diethanol amide (6501) and the balance of running water. The preparation method for the cleaning agent comprises the following steps: sequentially adding the running water, the APG0810, the FMEE and the 6501 into a mixing kettle according to the mass percent, and performing moderate-intensity stirring until a transparent solution is formed. The cleaning agent integrates functions of a household cleaning agent and an industrial cleaning agent, can effectively remove vegetable oil dirt, animal oil dirt, mixed dirt, industrial polishing paste dirt and mineral oil dirt, and is applicable to removal of heavy oil dirt on kitchenware, polishing paste on a metal workpiece, mineral oil dirt on the metal workpiece and the like. In addition to the running water, the cleaning agent only contains three easily-degradable nonionic surfactant raw materials namely the APG0810, the FMEE and the 6501, the formula is simple, green and environmentally-friendly, the preparation operation is simple and convenient, and the application prospect is greater.
Description
Technical field
The present invention relates to a kind of clean-out system, be specifically related to a kind of multifunctional green aqueous cleaning agent and preparation method thereof, this clean-out system can remove the surface blots such as the mineral oil spot on the heavy oil stain on kitchen appliance, the buffing wax on metal works and metal works efficiently, both be applicable to daily cleaning field, be also applicable to industry cleaning link field.
Background technology
Due to the aspect such as food habits and cooking method, not only oil smoke weight in China's residential kitchen, and grease on kitchen and periphery article surface is very heavy, especially lampblack absorber surface and impeller to stick a thick layer of viscous crude dirty.The formation of the viscous crude dirt vegetables oil mainly in cooking process, animal oil are carried secretly after at high temperature evaporating, grease wherein containing unsaturated double-bond is at high temperature oxidized, polyreaction, and form the grease of " paint " shape with strong tack with carbon distribution, dust etc., more and more sticky even dry and hard after long time integration, be difficult to cleaning.The clean-out system for kitchen use that Vehicles Collected from Market adopts not only is filled a prescription complexity, and adds alkaline assistant more, has certain stimulation to the skin of people, security and the feature of environmental protection not good enough.Such as, CN104293498A discloses " a kind of preparation method of clean-out system for kitchen use ", the detergency ability of this clean-out system is good, but the complicated process of preparation of its starch base tensio-active agent, containing the alkaline assistant such as tripoly phosphate sodium STPP and sodium carbonate in formula, the phosphorus-containing wastewater of rear generation is used also to pollute the environment.CN102807925B discloses one " road surface grease environment-friendly type water based cleaning agent and preparation method thereof ", this clean-out system is excellent to the cleaning performance of kitchen oil stain, but its formula composition relative complex, containing the 8 kinds of components comprising the poor alkylphenol polyoxyethylene of biological degradability and weak organic bases trolamine.
In addition, metallic element can leave various residue on its surface in the processes such as processing and manufacturing, transport and maintenance, therefore, metal cleaning is the requisite link of mechanical workout production process, and cleaning quality directly affects the work-ing life of metallic element.Most metallic substance is before processing, and surface exists the slushing oil of one deck based on mineral oil and mechanical workout greasy dirt usually; Some workpiece need sanding and polishing before processing, and part workpiece, except attachment mineral grease, also adheres to wax dirt, also needs process before following process.But clean-out system specificity on sale is at present comparatively strong, the more complicated and metal cleaner is filled a prescription usually, or in certain alkalescence or acidity, or contain the disagreeableness component of environment.Such as, CN103469224A discloses " a kind of high pressure resistant low-foam antirust clean-out system ", this clean-out system contains the Starso of alkalescence and can cause totally 6 kinds of components such as sodium phosphate of body eutrophication, can be used for cleaning the dirt on automobile, engineering machinery and farm machinery metal parts.CN104264167A discloses " a kind of water base metal cleaning agent ", this clean-out system is for the surface degreasing before and after intermetallic composite coating, scale removal, and soil removability is strong, rust-preventing characteristic is good, but its formula is complicated, and deionizing water is outward also containing hydrophilic polyol, sodium carbonate and sodium bicarbonate 9 kinds of components.CN104313608A discloses " a kind of environment-friendly type aluminum material cleaning agent ", and this clean-out system, for cleaning the oxide skin of aluminium workpiece surface, has good degreasing and antirust ability, but this clean-out system contains 8 kinds of components, and in stronger acidity, pH value is 2.1 ~ 5.6.
The research of multifuctional cleaning agent also has report.Such as, CN104388210A discloses one " multifuctional cleaning agent ", this clean-out system contains acid vinegar, hydrogen peroxide and citric acid, the sodium carbonate of alkalescence, totally 8 kinds of material compositions such as organic solvent ethanol, can also be used for cleaning ceramic utensil, fabric and furniture and for fruit crust sterilization etc.CN102154068A discloses one " multifuctional cleaning agent and preparation method ", and this cleaning agent formula is very complicated, containing 12 kinds of material compositions such as acid citric acids, for removing protein stain, starch spot, carbon black spot and greasy dirt stain etc.CN103343356A discloses one " multi-function metal aqueous rustproof and clean-out system and its preparation method and application ", this clean-out system is applicable to metal rust preventing, the cleaning of intermetallic composite coating and machine industry and uses as rust-inhibiting additive, but its preparation technology's more complicated, relate to multiple heat-processed, energy consumption is higher.
But also rarely have so far clean-out system can high-efficient cleaning except kitchen grease, again can high-efficient cleaning except the report of the buffing wax on metal works and mineral oil spot.
Summary of the invention
The object of the invention is the deficiency existed for existing clean-out system, a kind of composition environmental friendliness of filling a prescription, cheapness and multifunctional green aqueous cleaning agent not producing secondary pollution and preparation method thereof after use are provided, this clean-out system not only has good cleaning performance to the viscous crude dirt of family kitchen, and also has good cleaning performance to buffing wax residual on metal works and mineral oil spot.
The object of the invention is to be realized by following technique means:
Multifunctional green aqueous cleaning agent provided by the invention, it is made up of the composition of following mass percent: 6501 of the FMEE of the APG0810 of 0.5-10.0%, 0.5-8.0%, 1.0-4.0%, and surplus is tap water.
Described clean-out system is replaced by the composition of following mass percent: 6501 of the FMEE of the APG0810 of 5.0-10.0%, 0.5-3.0%, 1.0-2.0%, and surplus is tap water.
Above-mentioned multifunctional green aqueous cleaning agent provided by the invention, it adopts the method for following steps to make: joined by tap water in stirring tank, under medium tenacity stirs, slowly add APG0810, FMEE and 6501 successively, until form the solution of transparence.
Multifunctional green aqueous cleaning agent prepared by the inventive method, its purposes is: the heavy oil stain of this multifunctional green aqueous cleaning agent on cleaning daily necessities surface, or buffing wax on cleaning industrial goods surface and application in mineral oil spot.
Described daily necessities refer to kitchen appliance.
Described industrial goods refer to metal works.
It is tap water and other commercially available industrial raw material cheap and easy to get that the present invention prepares the raw material that clean-out system adopts, wherein, nonionogenic tenside APG0810 is synthesized by renewable resources natural fat alcohol and glucose, have the characteristic of conventional nonionic and anion surfactant concurrently, having that biological degradation is complete, detersive power good and the remarkable advantage such as wetting power is strong, is internationally recognized first-selection " green " functional surfactant; Nonionogenic tenside FMEE is the nonionogenic tenside of the low foam of a class ether-ester type, have excellent cleaning performance, and production cost is lower, particularly dispersive ability is very strong, effectively can prevent the anti-contamination of dirt in cleaning process, be applicable to the cleaning of grease and wax.Nonionogenic tenside 6501 is with low cost, and foaminess is good, can strengthen cleaning performance with kinds of surface active ingredient.This clean-out system utilizes the good APG0810 of consistency, FMEE, 6501 and the synergy of water, through infiltration, emulsification, dispersion and solvency action, surface tension between realization reduction grease and clean-out system, emulsification dissolve grease and wax, thus reach the efficient effect removing viscous crude dirt, mineral oil and buffing wax.
Multifunctional green aqueous cleaning agent provided by the invention has the following advantages:
(1) formula is simple, and except tap water, raw material only has cheap harmless APG0810, FMEE and 6501 totally 3 kinds, and wherein, APG0810 and FMEE is the tensio-active agent of environmental protection, and readily biodegradable, does not pollute the environment.
(2) suitability is wide, can not only remove the heavy oil stain on kitchen appliance surface fast and effectively, and also has good elimination effect to buffing wax residual on surface of workpiece in industrial production and mineral oil spot.
Embodiment
Below in conjunction with embodiment, the invention will be further described, and these embodiments are only the descriptions to better embodiment of the present invention, but be not limited to described content below.
Embodiment 1:
Multifunctional green aqueous cleaning agent prepared by the present embodiment is made up of the component of following mass percent: APG0810 is 0.5%, FMEE be 5.0%, 6501 is 4.0%, and surplus is tap water, and its preparation and application comprises the following steps:
(1) join in mixing kettle by the tap water of 90.5%, medium tenacity adds APG0810, the FMEE of 5.0%, 4.0% 6501 of 0.5% successively slowly under stirring, obtain clean-out system finished product, record the pH ≈ 8.0 of prepared clean-out system after stirring.
(2) standard kitchen viscous crude dirt is prepared with reference to national standard QB/T4348-2014 " kitchen oil scale washing agent ", also it carries out cleaning experiment to make the dirty sheet of viscous crude dirt, wherein the aging condition of greasy dirt is elder generation aging 10min in the thermostat container of 200 DEG C, aging 3h in the thermostat container of 45 DEG C again, after the dirty sheet of cleaning viscous crude dirt, recording its detersive power is 93.9%.
(3) steel disc is cleaned with reference to " water base metal cleaning agent test method ", weigh (claiming accurate to 0.002g) after successively cooling 30min in dry 1h, moisture eliminator in the baking oven of (120 ± 2) DEG C.With glass stick at test piece one side predetermined portion coating mineral oil.Dirt quality control at 0.24-0.26g/ sheet, dry 10min in the baking oven of (200 ± 2) DEG C.Put into the constant temperature oven of (45 ± 2) DEG C after test piece being taken out cooling 20min, aging 3h, after cleaning mineral greasy dirt sheet, recording its detersive power is 92.4%.
(4) with reference to " test method of water base metal cleaning agent ", will to clean and steel disc at 120 DEG C after dry 1h is placed in moisture eliminator, weigh after being cooled to room temperature.Again steel disc is placed in baking oven and is heated to 60-65 DEG C, at once at the predetermined portion even application buffing wax 0.24 ± 0.02g of steel disc.Then, the steel disc scribbling buffing wax is taken out after aging 10min at 200 DEG C, under room temperature in moisture eliminator ageing 20-22h, after the dirty sheet of cleaning polishing wax, recording its detersive power is 95.3%.
Embodiment 2:
Multifunctional green aqueous cleaning agent prepared by the present embodiment is made up of the component of following mass percent: APG0810 is 3.0%, FMEE be 4.0%, 6501 is 2.5%, and surplus is tap water, and its preparation and application comprises the following steps:
(1) preparation process of this clean-out system is with embodiment 1, records the pH ≈ 7.5 of prepared clean-out system.
(2) standard kitchen viscous crude dirt is prepared with reference to national standard QB/T4348-2014 " kitchen oil scale washing agent ", make the viscous crude dirty sheet of dirt and cleaning experiment is carried out to it, wherein the aging condition of greasy dirt is elder generation aging 10min in 200 DEG C of thermostat containers, aging 3h in the thermostat container of 45 DEG C again, after the dirty sheet of cleaning viscous crude dirt, recording its detersive power is 92.3%.
(3) with reference to " water base metal cleaning agent test method ", steel disc is cleaned, weigh successively cool 30min successively in (120 ± 2) DEG C dry in an oven 1h, moisture eliminator after (claiming accurate to 0.002g).With glass stick at test piece one side predetermined portion coating mineral oil.Dirt quality control at 0.24-0.26g/ sheet, dry 10min in the baking oven of (200 ± 2) DEG C.Put into the constant temperature oven of (45 ± 2) DEG C after test piece being cooled 20min, aging 3h, after cleaning mineral greasy dirt sheet, recording its detersive power is 90.2%.
(4) with reference to " test method of water base metal cleaning agent ", will to clean and steel disc at 120 DEG C after dry 1h is placed in moisture eliminator, weigh after being cooled to room temperature.Again steel disc is placed in baking oven and is heated to 60-65 DEG C, at once at the predetermined portion even application buffing wax 0.24 ± 0.02g of steel disc.Then, the steel disc scribbling buffing wax is taken out after aging 10min at 200 DEG C, under room temperature in moisture eliminator ageing 20-22h, after the dirty sheet of cleaning polishing wax, recording its detersive power is 94.9%.
Embodiment 3:
Multifunctional green aqueous cleaning agent prepared by the present embodiment is made up of the component of following mass percent: APG0810 is 4.0%, FMEE be 8.0%, 6501 is 1.5%, and surplus is tap water, and its preparation and application comprises the following steps:
(1) preparation process of this clean-out system is with embodiment 1, records the pH ≈ 7.5 of prepared clean-out system.
(2) standard kitchen viscous crude dirt is prepared with reference to national standard QB/T4348-2014 " kitchen oil scale washing agent ", make the viscous crude dirty sheet of dirt and cleaning experiment is carried out to it, wherein the aging condition of greasy dirt is elder generation aging 10min in the thermostat container of 200 DEG C, aging 3h in the thermostat container of 45 DEG C again, after the dirty sheet of cleaning viscous crude dirt, recording its detersive power is 92.9%.
(3) with reference to " water base metal cleaning agent test method ", steel disc is cleaned, weigh (claiming accurate to 0.002g) after successively cooling 30min in dry 1h, moisture eliminator in the baking oven of (120 ± 2) DEG C.With glass stick at test piece one side predetermined portion coating mineral oil.Dirt quality control at 0.24-0.26g/ sheet, dry 10min in the baking oven of (200 ± 2) DEG C.Put into the constant temperature oven of (45 ± 2) DEG C after test piece being cooled 20min, aging 3h, after cleaning mineral greasy dirt sheet, recording its detersive power is 90.1%.
(4) will to clean with reference to " test method of water base metal cleaning agent " and steel disc at 120 DEG C after dry 1h is placed in moisture eliminator, to weigh after being cooled to room temperature.Again steel disc is placed into baking oven for heating to 60-65 DEG C, at once at position even application buffing wax 0.24 ± 0.02g that steel disc specifies.Then, the steel disc scribbling buffing wax is taken out after aging 10min at 200 DEG C, under room temperature in moisture eliminator ageing 20-22h, after the dirty sheet of cleaning polishing wax, recording its detersive power is 92.7%.
Embodiment 4:
Multifunctional green aqueous cleaning agent prepared by the present embodiment is made up of the component of following mass percent: APG0810 is 4.0%, FMEE be 5.0%, 6501 is 3.0%, and surplus is tap water, and its preparation and application comprises the following steps:
(1) preparation process of this clean-out system is with embodiment 1, records the pH ≈ 8.0 of prepared clean-out system.
(2) standard kitchen viscous crude dirt is prepared with reference to national standard QB/T4348-2014 " kitchen oil scale washing agent ", make the viscous crude dirty sheet of dirt and cleaning experiment is carried out to it, wherein the aging condition of greasy dirt is aging 10min in the thermostat container of 200 DEG C, aging 3h in the thermostat container of 45 DEG C again, after the dirty sheet of cleaning viscous crude dirt, recording its detersive power is 94.8%.
(3) steel disc is cleaned with reference to " water base metal cleaning agent test method ", weigh (claiming accurate to 0.002g) after successively cooling 30min in dry 1h, moisture eliminator in the baking oven of (120 ± 2) DEG C.With glass stick at test piece one side predetermined portion coating mineral oil.Dirt quality control at 0.24-0.26g/ sheet, dry 10min in the baking oven of (200 ± 2) DEG C.Put into the constant temperature oven of (45 ± 2) DEG C after test piece being taken out cooling 20min, aging 3h, after cleaning mineral greasy dirt sheet, recording its detersive power is 91.7%.
(4) with reference to " test method of water base metal cleaning agent ", will to clean and steel disc at 120 DEG C after dry 1h is placed in moisture eliminator, weigh after being cooled to room temperature.Again steel disc is placed into baking oven for heating to 60-65 DEG C, at once at position even application buffing wax 0.24 ± 0.02g that steel disc specifies.Then, the steel disc scribbling buffing wax is taken out after aging 10min at 200 DEG C, under room temperature in moisture eliminator ageing 20-22h, after the dirty sheet of cleaning polishing wax, recording its detersive power is 96.5%.
Embodiment 5:
Multifunctional green aqueous cleaning agent prepared by the present embodiment is made up of the component of following mass percent: APG0810 is 5.0%, FMEE be 3.5%, 6501 is 3.5%, and surplus is tap water, and its preparation and application comprises the following steps:
(1) preparation process of this clean-out system is with embodiment 1, records the pH ≈ 8.0 of prepared clean-out system.
(2) standard kitchen viscous crude dirt is prepared with reference to national standard QB/T4348-2014 " kitchen oil scale washing agent ", also it carries out cleaning experiment to make the dirty sheet of viscous crude dirt, wherein the aging of greasy dirt is aging 10min, more aging 3h in the thermostat container of 45 DEG C in the thermostat container of 200 DEG C, after the dirty sheet of cleaning viscous crude dirt, recording its detersive power is 96.0%.
(3) steel disc is cleaned with reference to " water base metal cleaning agent test method ", weigh (claiming accurate to 0.002g) after successively cooling 30min in dry 1h, moisture eliminator in the baking oven of (120 ± 2) DEG C.With glass stick at test piece one side predetermined portion coating mineral oil.Dirt quality control at 0.24-0.26g/ sheet, dry 10min in the baking oven of (200 ± 2) DEG C.Put into the constant temperature oven of (45 ± 2) DEG C after test piece being taken out cooling 20min, aging 3h, after cleaning mineral greasy dirt sheet, recording its detersive power is 94.0%.
(4) with reference to " test method of water base metal cleaning agent ", will to clean and steel disc at 120 DEG C after dry 1h is placed in moisture eliminator, weigh after being cooled to room temperature.Again steel disc is placed into baking oven for heating to 60-65 DEG C, at once at steel disc predetermined portion even application buffing wax 0.24 ± 0.02g.Then, the steel disc scribbling buffing wax is taken out after aging 10min at 200 DEG C, under room temperature in moisture eliminator ageing 20-22h, after the dirty sheet of cleaning polishing wax, recording its detersive power is 96.1%.
Embodiment 6:
Multifunctional green aqueous cleaning agent prepared by the present embodiment is made up of the component of following mass percent: APG0810 is 8.0%, FMEE be 0.5%, 6501 is 2.0%, and surplus is tap water, and its preparation and application comprises the following steps:
(1) preparation process of this clean-out system is with embodiment 1, records the pH ≈ 8.5 of prepared clean-out system.
(2) standard kitchen viscous crude dirt is prepared with reference to national standard QB/T4348-2014 " kitchen oil scale washing agent ", also it carries out cleaning experiment to make the dirty sheet of viscous crude dirt, wherein the aging of greasy dirt is aging 10min, more aging 3h in the thermostat container of 45 DEG C in the thermostat container of 200 DEG C, after the dirty sheet of cleaning viscous crude dirt, recording its detersive power is 98.7%.
(3) with reference to " water base metal cleaning agent test method ", steel disc is cleaned, weigh (claiming accurate to 0.002g) cool 30min in dry 1h, moisture eliminator in the baking oven of (120 ± 2) DEG C after.With glass stick at test piece one side predetermined portion coating mineral oil.Dirt quality control at 0.24-0.26g/ sheet, dry 10min in the baking oven of (200 ± 2) DEG C.Put into the constant temperature oven of (45 ± 2) DEG C after test piece being taken out cooling 20min, aging 3h, after cleaning mineral greasy dirt sheet, recording its detersive power is 91.3%.
(4) with reference to " test method of water base metal cleaning agent ", will to clean and steel disc at 120 DEG C after dry 1h is placed in moisture eliminator, weigh after being cooled to room temperature.Again steel disc is placed into baking oven for heating to 60-65 DEG C, at once at steel disc predetermined portion even application buffing wax 0.24 ± 0.02g.Then, the steel disc scribbling buffing wax is taken out after aging 10min at 200 DEG C, under room temperature in moisture eliminator ageing 20-22h, after the dirty sheet of cleaning polishing wax, recording its detersive power is 97.5%.
Embodiment 7:
Multifunctional green aqueous cleaning agent prepared by the present embodiment is made up of the component of following mass percent: APG0810 is 10.0%, FMEE be 3.0%, 6501 is 1.0%, and surplus is tap water, and its preparation and application comprises the following steps:
(1) preparation process of this clean-out system is with embodiment 1, records the pH ≈ 8.0 of prepared clean-out system.
(2) standard kitchen viscous crude dirt is prepared with reference to national standard QB/T4348-2014 " kitchen oil scale washing agent ", also it carries out cleaning experiment to make the dirty sheet of viscous crude dirt, wherein the aging of greasy dirt is aging 10min, more aging 3h in 45 DEG C of thermostat containers in the thermostat container of 200 DEG C, after the dirty sheet of cleaning viscous crude dirt, recording its detersive power is 98.1%.
(3) with reference to " water base metal cleaning agent test method ", steel disc is cleaned, weigh (claiming accurate to 0.002g) cool 30min in dry 1h, moisture eliminator in the baking oven of (120 ± 2) DEG C after.With glass stick at test piece one side predetermined portion coating mineral oil.Dirt quality control at 0.24-0.26g/ sheet, dry 10min in the baking oven of (200 ± 2) DEG C.Put into the constant temperature oven of (45 ± 2) DEG C after test piece being taken out cooling 20min, aging 3h, after cleaning mineral greasy dirt sheet, recording its detersive power is 92.1%.
(4) with reference to " test method of water base metal cleaning agent ", will to clean and steel disc at 120 DEG C after dry 1h is placed in moisture eliminator, weigh after being cooled to room temperature.Again steel disc is placed into baking oven for heating to 60-65 DEG C, at once at steel disc predetermined portion even application buffing wax 0.24 ± 0.02g.Then, the steel disc scribbling buffing wax is taken out after aging 10min at 200 DEG C, under room temperature in moisture eliminator ageing 20-22h, after the dirty sheet of cleaning polishing wax, recording its detersive power is 96.6%.
Formula composition and the corresponding detersive power data thereof of clean-out system prepared by embodiment 1-7 see attached list 1.
Subordinate list:
The mass percent of each component and detersive power data thereof in table 1 Example formulations
Claims (6)
1. a multifunctional green aqueous cleaning agent, is characterized in that described clean-out system is made up of the composition of following mass percent: 6501 of the FMEE of the APG0810 of 0.5-10.0%, 0.5-8.0%, 1.0-4.0%, and surplus is tap water.
2. multifunctional green aqueous cleaning agent according to claim 1, is characterized in that described clean-out system is replaced by the composition of following mass percent: 6501 of the FMEE of the APG0810 of 5.0-10.0%, 0.5-3.0%, 1.0-2.0%, surplus is tap water.
3. the preparation method of a multifunctional green aqueous cleaning agent, it is characterized in that the method for employing following steps prepares the multifunctional green aqueous cleaning agent described in claim 1 or 2: joined by tap water in stirring tank, slowly APG0810, FMEE and 6501 are added successively, until form the solution of transparence under medium tenacity stirs.
4. the purposes of multifunctional green aqueous cleaning agent prepared of method according to claim 3, it is characterized in that the heavy oil stain of this multifunctional green aqueous cleaning agent on cleaning daily necessities surface, or buffing wax on cleaning industrial goods surface and application in mineral oil spot.
5. the purposes of multifunctional green aqueous cleaning agent according to claim 4, is characterized in that described daily necessities refer to kitchen appliance.
6. the purposes of multifunctional green aqueous cleaning agent according to claim 4, is characterized in that described industrial goods refer to metal works.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105623883A (en) * | 2016-02-24 | 2016-06-01 | 苏州龙腾万里化工科技有限公司 | High-performance composite water-based cleaning agent |
| CN114933936A (en) * | 2022-06-27 | 2022-08-23 | 陕西师范大学 | Cleaning agent for removing oil stains on surfaces of paper cultural relics and preparation method thereof |
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| WO1999057234A1 (en) * | 1998-05-05 | 1999-11-11 | Amway Corporation | Hydrotrope and skin conditioning agents for use in liquid detergent compositions |
| CN103242971A (en) * | 2013-05-03 | 2013-08-14 | 武汉理工大学 | Green efficient thick oil dirt nearly-neutral water-based cleaning agent without adding any acid-base |
| CN103834487A (en) * | 2014-02-20 | 2014-06-04 | 苏州龙腾万里化工科技有限公司 | Heavy grease stain environment-friendly type water base cleaning compound |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| WO1999057234A1 (en) * | 1998-05-05 | 1999-11-11 | Amway Corporation | Hydrotrope and skin conditioning agents for use in liquid detergent compositions |
| CN103242971A (en) * | 2013-05-03 | 2013-08-14 | 武汉理工大学 | Green efficient thick oil dirt nearly-neutral water-based cleaning agent without adding any acid-base |
| CN103834487A (en) * | 2014-02-20 | 2014-06-04 | 苏州龙腾万里化工科技有限公司 | Heavy grease stain environment-friendly type water base cleaning compound |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105623883A (en) * | 2016-02-24 | 2016-06-01 | 苏州龙腾万里化工科技有限公司 | High-performance composite water-based cleaning agent |
| CN114933936A (en) * | 2022-06-27 | 2022-08-23 | 陕西师范大学 | Cleaning agent for removing oil stains on surfaces of paper cultural relics and preparation method thereof |
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| CN105273857B (en) | 2018-05-01 |
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