CN106833946A - Tableware biological enzyme cleaning fluid and its preparation method and application - Google Patents
Tableware biological enzyme cleaning fluid and its preparation method and application Download PDFInfo
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Abstract
The invention discloses a kind of tableware biological enzyme cleaning fluid, by weight, it is made up of following component：Nonionic surfactant 18% ~ 20%, amphoteric surfactant 14% ~ 16%, enzyme preparation 2% ~ 3%, enzyme stabilizers 0.6% ~ 1.0%, chelating agent 0.2% ~ 0.4%, preservative 0.2% ~ 0.3%, essence 0.1% ~ 0.2%, balance of deionized water.Various components in tableware biological enzyme cleaning fluid of the invention are all food grade ingredients, it is nontoxic degradable, for cleaning during tableware, various component synergies, the especially synergy between various biology enzymes and nonionic surfactant, amphoteric surfactant, energy fast decoupled simultaneously removes the various spots on tableware, with excellent dirt-removing power, simultaneously, the addition of biology enzyme also greatly reduces the consumption of surfactant, residual of the surfactant on tableware is greatly reduced, stimulation of the cleaning fluid to skin of hand is also reduced.
Description
Technical field
The present invention relates to detergent technical field, more particularly to a kind of tableware biological enzyme cleaning fluid and its preparation method and application.
Background technology
It is traditionally used for cleaning the chemical of tableware, to reach clean effect, often adds substantial amounts of surfactant, and conventional main component is anionic detergent（Main component dodecyl sodium sulfate）It is a kind of low toxicity material, has chronic toxic action to skin, liver, hematological system etc..The eating habit and eating habit of China have the particularity of national conditions, the tableware various shapes for such as using, not only dishes, also there is shape, the spoon of different sizes, chopsticks etc.；The tableware material variation for using, there is ceramics, glass, plastics, metal etc..Dirt on tableware does not only have animal and plant fat, various edible proteins, and has the starchy food high such as rice, only is difficult to clean up with the strong surfactant of ability of cleaning greasy dirt.Therefore, addition can reduce fat, the biology enzyme of protein and starch dirt, the purpose of quick thoroughly cleaning can be reached, while helping to reduce the usage amount of surfactant, save cleaning water, environmental protection.It is that the protease being extract from Pancreas Bovis seu Bubali is used in laundry detergent compositions by German Rohn companies it is reported that enzyme was applied to the research Patent Publication for washing industry in 1913 earliest.By after development for many years, protease is applied to clothes washing industry by ripe, but is mostly that, with single enzyme and solid form application, because enzyme mutability inactivation in a liquid, and various enzyme compounding uses have technical barrier.Tableware needs to wash everyday, and unlike clothing can be washed once with several days, and tableware is the container for filling food, wash dishes are clean and to health be very important without hazard residue.Therefore, while cleaning agent for dinnerware is using nonhazardous material composition but also with good cleaning capacity be people research emphasis.
The content of the invention
The present invention solves the technical problem of a kind of tableware biological enzyme cleaning fluid of offer, various components in the tableware biological enzyme cleaning fluid are all food grade ingredients, it is nontoxic degradable, for cleaning during tableware, various components synergy in tableware biological enzyme cleaning fluid, especially various biology enzymes and nonionic surfactant, synergy between amphoteric surfactant, energy fast decoupled simultaneously removes the various spots on tableware, with excellent dirt-removing power, simultaneously, the addition of biology enzyme not only greatly reduces the consumption of surfactant, greatly reduce residual of the surfactant on tableware, and decrease stimulation of the cleaning fluid to skin of hand.
In order to solve the above technical problems, one aspect of the present invention is：A kind of tableware biological enzyme cleaning fluid is provided, by weight, the tableware biological enzyme cleaning fluid is made up of following component：
Nonionic surfactant 18% ~ 20%；
Amphoteric surfactant 14% ~ 16%；
Enzyme preparation 2% ~ 3%；
Enzyme stabilizers 0.6% ~ 1.0%；
Chelating agent 0.2% ~ 0.4%；
Preservative 0.2% ~ 0.3%；
Essence 0.1% ~ 0.2%；
Balance of deionized water.
Preferably, the nonionic watch active agent be APG, lauryl glucoside, sucrose fatty ester, fatty acid methyl ester ethoxylate in one or more.
APG（APG）Be a kind of novel green functional surfactant, it be obtained by natural fatty alcohol and natural carbohydrate, no matter at aspects such as ecotoxicologicals, or is all safe in terms of dermatology.
It is highly preferred that the carbon number of the alkyl of the APG is 12 ~ 14（C12~C14）, being processed with the other glucose of medical grade by the other palm oil of food grade or coconut oil, moderate performance, foam appropriateness, dirt-removing power are strong, with outstanding skin-friendliness.
Lauryl glucoside is also known as Dodecyl Glucoside, it is a kind of new, nontoxic, biodegradable nonionic surfactant, raw materials of glucose, fatty alcohol used by it is both from natural reproducible raw material, production process and product not generation environment public hazards, therefore the product belongs to natural, gentle green product, can be used in the daily use chemicals manization industry such as various fruits and vegetables cleaning agents, cleaning agent for dinnerware.The surface-active of Plantacare APG 1200G is strong, surface tension is low, strong detergency, without cloud point, foaming power be good, foam it is fine and smooth it is abundant, wetability is good and skin-friendliness is good；Nontoxic, non-stimulated, easily biological-degradable, can significantly improve the mildness of formula；Resistance to highly basic and electrolyte, there is good thickening capabilities.
Sucrose fatty ester maximum feature is harmless, is had no stimulation of the skin, and with excellent biological degradability, is highly suitable for the preparation that tableware washes agent by liquid, and sucrose ester composition may also operate as conserving the effect of ceramic material tableware.
Fatty acid methyl ester ethoxylate is a new safe efficient, environment-friendly type nonionic surfactant, with low bubble, emulsifiability is strong, oil removing ability is strong, it is alkaline-resisting many advantages, such as, be widely used in the products such as detergent, cleaning agent.Fatty acid methyl ester ethoxylate has good alkali resistance, low spumescence, excellent emulsifiability and dispersive property, excellent deoiling function, cloud point high, temperature in use scope relatively wide and the features such as all types of surfactant compatibilities are good, it is a kind of environment-friendly type nonionic surfactant, while there is excellent biological degradability.
Preferably, the both sexes table activating agent be lauroylamidopropyl betaine, imidazoline amophoteric surface active agent in one or two.
Lauroylamidopropyl betaine is a kind of new amphoteric surfactant, it has good cleaning, conditioning and antistatic property, it is non-stimulated to skin, eye mucous membrane, without allergic reaction, transparent liquid or colloid can be obtained with nonionic surfactant compatibility, its foam stabilization, exquisiteness.
Imidazoline amophoteric surface active agent have it is nontoxic, to eyes and skin safe, coordinate that compatibility is good, have good polishing, thickening, foam enhancing, it is hard water resistance by force, biological degradability it is good, can with various surfactant compatibilities the features such as.
The surfactant used in tableware biological enzyme cleaning fluid of the invention has the characteristics that：1st, it is excellent except oiliness, emulsibility, wetability；2nd, to skin action temperature and；3rd, good foaming power；4th, biological degradability is good；5th, of light color, free from extraneous odour；6th, solution viscosity can easily be accommodated；7th, it is nontoxic to human body.These characteristics cause that tableware biological enzyme cleaning fluid of the invention has excellent detergency.
Preferably, the enzyme preparation is made up of lipase, protease, amylase and mannase.Lipase can effectively remove various grease type dirts, the peanut oil of vegetable oil such as cooking, soybean oil and rapeseed oil etc.；Fat, the grease in meat soup in animal tallow such as chafing dish butter bed material, dairy produce.Amylase can remove starch spot, such as rice, noodles starch food products.In numerous food product sauce, starch is also main component, such as catsup, barbecue sauce, thick chilli sauce, mayonnaise, and amylase can help remove these obstinate spots.Protease can effectively remove the protein stain of the food source such as eggs, dairy products or gravy, vegetable juice.Mannase can effectively decompose mannanses spot, and mannosan such as guar gum, konjac glucomannan etc., are the thickeners in food additives, are commonly used in ice cream, mayonnaise, instant noodles.The residual of food often leaves behind one layer of dirt film of starch-containing/protein, if this film is not removed, a period of time is spent, these film dirts will be accumulated in tableware surface, the harden dirt of exsiccation of bulk can be also remained on tableware, such as dirt of egg and rice, enzyme can effectively remove these tough stains.
Preferably, the enzyme stabilizers be ethanol, sodium formate, citric acid in one or more.
It is highly preferred that the enzyme stabilizers are made up of ethanol and citric acid.Citric acid is a kind of organic acid, can keep stability of the enzyme in water as enzyme stabilizers, and the performance of surfactant as builder, can be improved again, improves the performance of cleaning product, is alternatively arranged as pH adjusting agent, keeps the necessary acid-base property of cleaning fluid.
Preferably, the chelating agent is sodium glucoheptonate.Sodium glucoheptonate is efficient, safe chelating agent, the product being modified through Killiani-Fischer by natural glucose, can be 100% biodegradable, environmentally safe, can be used under conditions of more than 90 DEG C, is adapted to HIGH TEMPERATURE PURGE.
There is the problem of environmental pollution of potential security and protrusion in metal ion chelation agent such as EDTA, the NTA and phosphate derivative commonly used in existing wash dishes liquid.EDTA, NTA are non-biodegradable products, and its chelate products is difficult effectively to be decomposed, and phosphate and phosphate are easily enriched with water body, cause body eutrophication, severe contamination environment.Sodium glucoheptonate chelating agent is not only safe and easily-degradable, also contributes to keep the limpid transparent organoleptic attribute of tableware biological enzyme cleaning fluid of the invention.
Preferably, the preservative be parabens, organic acid and its esters in one or more.
It is highly preferred that the preservative is made up of methyl hydroxybenzoate and propylben.The preservative of methyl hydroxybenzoate and propylben composition can significantly extend the period of storage of tableware biological enzyme cleaning fluid of the present invention.
The essence is edible orange odor type, and the selection of essence can select to meet as needed《GB30616-2014》Essence for food standard requirement, appropriate perfume ingredient can play fresh air effect, can also increase sense organ pleasure.
In order to solve the above technical problems, another technical solution used in the present invention is：A kind of preparation method of described tableware biological enzyme cleaning fluid is provided, is comprised the following steps：
A, to addition deionized water gross mass in ingredients pot 60% ~ 70%；
B, input chelating agent, stirring is to being completely dissolved；
C, input amphoteric surfactant, are heated to 50 DEG C, and stirring puts into nonionic surfactant to after dissolving, and stirring is to being completely dissolved；
D, input preservative, stirring is to being completely dissolved；
E, the remaining deionized water of addition；
F, regulation pH；
G, input enzyme preparation and enzyme stabilizers, stir；
H, input essence, stir, and obtain the tableware biological enzyme cleaning fluid.
Present invention also offers the application of described tableware biological enzyme cleaning fluid, when directly cleaning, take a small amount of tableware biological enzyme cleaning fluid of the invention and be placed on implement, such as on sponge or a dishcloth, gently wipe after being rinsed well with clear water after wash up；Tableware biological enzyme cleaning fluid of the invention is suitably diluted with clear water first during soaking and washing, such as generally 300 times or so of dilution, wash up washing by soaking will be treated, then rinsed well with clear water.Proper extension soak time is needed to the tableware that spot has dried up or reduces extension rate, and aid in cleaning by Cleaning tool, optimal clean temperature is 35 ~ 45 DEG C.
The beneficial effects of the invention are as follows：For the situation that the surfactant component in existing dish washing detergent is poisonous, not degradable and cleaning performance is poor, the various components in tableware biological enzyme cleaning fluid of the invention are all food grade ingredients, nontoxic, degradable；When tableware biological enzyme cleaning fluid is used to clean tableware, various component synergies, the especially synergy between various biology enzymes and nonionic surfactant, amphoteric surfactant, can fast decoupled simultaneously remove the various spots on tableware, with excellent dirt-removing power；Meanwhile, the addition of biology enzyme also greatly reduces the consumption of surfactant, greatly reduces residual of the surfactant on tableware, decreases stimulation of the cleaning fluid to skin of hand.In addition, the technical barrier of the stability this invention also solves various biology enzymes in liquid environment, the biology enzyme in tableware biological enzyme cleaning fluid of the invention can in a long time keep activity.
Tableware biological enzyme cleaning fluid of the invention has further the advantage that：
1st, without any pigment；
2nd, neutral formula, washes rear skin gentle；
3rd, easily flushing, noresidue, corrosion-free, has defencive function to top grade tableware.
Specific embodiment
With reference to embodiment, the present invention is described in detail.
Surfactant, enzyme preparation in embodiment, enzyme stabilizers, chelating agent, preservative, essence are commercially available, and for example enzyme preparation can be bought from Shenzhen Leveking Biology Engineering Co., Ltd.
Embodiment 1
The formula of tableware biological enzyme cleaning fluid is as follows：
Nonionic surfactant 20%（Alkyl-glucoside 6%, fatty acid methyl ester ethoxylate 8%, sucrose ester 6%）, amphoteric surfactant 14%（Lauroylamidopropyl betaine 6%, imidazoline amophoteric surface active agent 8%）, enzyme 3%（Amylase 0.8%, lipase 1%, proteinase-10 .6%, mannase 0.6%）, essence 0.1%, preservative 0.3%（Methyl hydroxybenzoate 0.2%, propylben 0.1%）, sodium glucoheptonate 0.2%, enzyme stabilizers 1%（Ethanol 0.4%, citric acid 0.6%）Deionized water 61.4%.
The preparation method of tableware biological enzyme cleaning fluid：
Each component is weighed by above-mentioned formula, it is standby.Prepare according to the following steps：
A, to addition deionized water gross mass in ingredients pot 60% ~ 70%；
B, input chelating agent, stirring is to being completely dissolved；
C, input amphoteric surfactant, are heated to 50 DEG C, and stirring puts into nonionic surfactant to after dissolving, and stirring is to being completely dissolved；
D, input preservative, stirring is to being completely dissolved；
E, the remaining deionized water of addition；
F, regulation pH；
G, input enzyme preparation and enzyme stabilizers, stir；
H, addition essence, stir, and obtain the tableware biological enzyme cleaning fluid.
Embodiment 2
The formula of tableware biological enzyme cleaning fluid is as follows：
Nonionic surfactant 18%（Alkyl-glucoside 8%, Plantacare APG 1200G 6%, sucrose ester 4%）, amphoteric surfactant 16%（Lauroylamidopropyl betaine 10%, imidazoline amophoteric surface active agent 6%）, enzyme 2%（Amylase 0.6%, lipase 0.6%, proteinase-10 .4%, mannase 0.4%）, essence 0.2%, preservative 0.2%（Methyl hydroxybenzoate 0.1%, propylben 0.1%）, sodium glucoheptonate 0.4%, enzyme stabilizers 0.6%（Ethanol 0.2%, citric acid 0.4%）, deionized water 62.6%.
The preparation method of tableware biological enzyme cleaning fluid is same as Example 1.
Embodiment 3
The Performance comparision of the performance of tableware biological enzyme cleaning fluid of the invention and wash dishes liquid both domestic and external.
Choose the wash dishes liquid both domestic and external respectively standard dish washing detergent that market has been sold（Preparation method is shown in GB 9985）, Amway Amway concentration liquid detergent（China）, flower Wang Qingliang Natural cleanser essences（Japan）, Frosch efficient concentration liquid detergents（Germany）, stand white liquid detergent（China）, than sub- enzyme decontamination shield tableware it is net（China）.
First, pH value detection：
Regulation of the experimental technique with reference to GB/T6368.Test temperature is 25 DEG C, 1% sample solution concentration.Testing result is shown in Table 1：
The pH value comparative result of table 1
According to the regulation of standard GB/T 9985-2000, it is desirable to which the pH value for cleaning the product of tableware should be between 4.0 ~ 10.5.If reagent solution pH is in strong basicity, too big to eyes and skin irritation when using.As shown in Table 1, tableware biological enzyme cleaning fluid of the invention is gentle non-stimulated in neutral or faintly acid, does not hurt hands safely.
2nd, the detection of gross activity thing content：
Regulation of the experimental technique with reference to 5.3.1 methods one " ethanol extraction " in QB1994-1994.
The comparative result of the gross activity thing content of table 2
Gross activity thing content is the index that generally acknowledged in the world one weighs cleaning product quality quality.Standard GB/T 9985 requires that the gross activity thing content of dish washing detergent is more than or equal to 15.As shown in Table 2, gross activity content in tableware biological enzyme cleaning fluid of the invention has reached national standard, standard dish washing detergent, flower Wang Qingliang Natural cleanser essences and Li Bai liquid detergents are exceeded, liquid detergent and Frosch efficient concentration liquid detergents are concentrated less than Amway Amway, is worked as with than sub- enzyme decontamination shield tableware net phase.
4th, detergency detection
Regulation of the experimental technique with reference to the Appendix B methods one " going oil cut rate method " of GB 9985.
Having sold product and standard dish washing detergent with market by tableware biological enzyme cleaning fluid of the invention carries out detergency Experimental comparison, experimental result such as table 3：
The detergency comparative result of table 3
Tableware is cleaned up and is highly desirable to as the container that can all contact entrance food daily.Dirt in experiment is mainly the miscella thing of butter, lard and vegetable oil.As shown in Table 3, the oil cut rate of going of tableware biological enzyme cleaning fluid of the invention is up to 26.13%, be that standard dish washing detergent goes oil cut rate 3 times, and oil cut rate is gone also above what product had been sold in market.Conventional cutlery detergent is all that greasy dirt is dispersed into countless tiny drops by emulsification by surfactant; form it into emulsion; again as water floats; hand can usually be made in cleaning greasy feeling; the cutlery box of the materials such as plastics is difficult cleaning, cold oil standing time too also very difficult wash clean at normal temperatures long.Tableware biological enzyme cleaning fluid of the invention is cut grease rapidly dirt, protide dirt and amyloid dirt at room temperature by bioenzyme activity composition, these dirts after being hydrolyzed, and other stick dirt particles can quick wetting by surfactant, solubilising, emulsification remove, cooperate with clean effect so as to reach biology enzyme and surfactant.
Can show that tableware biological enzyme cleaning fluid of the invention and the units activity thing of wash dishes liquid both domestic and external go oil cut rate by table 2 and table 3, as a result such as table 4.
The units activity thing of table 4 removes oil cut rate comparative result
As shown in Table 4, the units activity thing of tableware biological enzyme cleaning fluid of the invention goes oil cut rate to be up to 1.24 ~ 1.26, the units activity thing for having sold product more than market goes oil cut rate, this is due to adding compound biological enzyme in tableware biological enzyme cleaning fluid of the invention, compound biological enzyme and the decontamination that cooperates with of surfactant, just cause that the units activity thing of tableware biological enzyme cleaning fluid of the invention goes oil cut rate to be significantly higher than market and sold product.Complex enzyme in tableware biological enzyme cleaning fluid of the invention can not only substitute the specific dirt of removal of surfactant, can also strengthen the detergency of surfactant, thus can reduce the addition of surfactant, while superior clean effect can also be reached.
In addition, tableware biological enzyme cleaning fluid selection of the invention is all the biodegradable surfactant of environmental protection, human body will not be damaged, will not also pollute natural environment.Meanwhile, tableware biological enzyme cleaning fluid of the invention has fabulous cleaning performance to the tableware of the various materials such as glass, plastics, metal, ceramics.
Through Chinese daily chemical industry institute check, tableware biological enzyme cleaning fluid of the invention with standard dish washing detergent the number result such as table 5 that washes dishes：
The dishwashing number comparative result of table 5
As shown in Table 5, the dishwashing number of tableware biological enzyme cleaning fluid of the invention is significantly greater than standard tableware cleaning fluid, illustrates that tableware biological enzyme cleaning fluid of the invention is significantly superior to the dirt-removing power of tableware.
Those skilled in the art do not depart from essence of the invention and spirit, there can be various deformation scheme to realize the present invention, the foregoing is only preferably feasible embodiment of the invention, not thereby interest field of the invention is limited to, the equivalent structure change that all utilization description of the invention are made, is both contained within interest field of the invention.
Claims (10)
1. a kind of tableware biological enzyme cleaning fluid, it is characterised in that by weight, the tableware biological enzyme cleaning fluid is made up of following component：
Nonionic surfactant
18%~20%；
Amphoteric surfactant 14% ~ 16%；
Enzyme preparation 2% ~ 3%；
Enzyme stabilizers 0.6% ~ 1.0%；
Chelating agent 0.2% ~ 0.4%；
Preservative 0.2% ~ 0.3%；
Essence 0.1% ~ 0.2%；
Balance of deionized water.
2. tableware biological enzyme cleaning fluid according to claim 1, it is characterised in that the nonionic watch active agent is one or more in APG, lauryl glucoside, sucrose fatty ester, fatty acid methyl ester ethoxylate.
3. tableware biological enzyme cleaning fluid according to claim 1, it is characterised in that the both sexes table activating agent is one or two in lauroylamidopropyl betaine, imidazoline amophoteric surface active agent.
4. tableware biological enzyme cleaning fluid according to claim 1, it is characterised in that the enzyme preparation is made up of lipase, protease, amylase and mannase.
5. tableware biological enzyme cleaning fluid according to claim 1, it is characterised in that the enzyme stabilizers are one or more in ethanol, sodium formate, citric acid.
6. tableware biological enzyme cleaning fluid according to claim 1, it is characterised in that the chelating agent is sodium glucoheptonate.
7. tableware biological enzyme cleaning fluid according to claim 1, it is characterised in that the preservative is one or more in parabens, organic acid and its esters.
8. tableware biological enzyme cleaning fluid according to claim 7, it is characterised in that the preservative is made up of methyl hydroxybenzoate and propylben.
9. the preparation method of the tableware biological enzyme cleaning fluid described in any one of claim 1 ~ 8, it is characterised in that comprise the following steps：
A, to addition deionized water gross mass in ingredients pot 60% ~ 70%；
B, input chelating agent, stirring is to being completely dissolved；
C, input amphoteric surfactant, are heated to 50 DEG C, and stirring puts into nonionic surfactant to after dissolving, and stirring is to being completely dissolved；
D, input preservative, stirring is to being completely dissolved；
E, the remaining deionized water of addition；
F, regulation pH；
G, input enzyme preparation and enzyme stabilizers, stir；
H, input essence, stir, and obtain the tableware biological enzyme cleaning fluid.
10. wash up backlash wash clean is treated in the application of the tableware biological enzyme cleaning fluid described in any one of claim 1 ~ 8, it is characterised in that when directly cleaning, the tableware biological enzyme cleaning fluid is placed on implement, wiping；During soaking and washing, first tableware biological enzyme cleaning fluid is suitably diluted, will be rinsed well after after wash up washing by soaking.
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| CN107267322A (en) * | 2017-07-09 | 2017-10-20 | 深圳市美益洁生物科技有限公司 | Degerming cleaning effervescent tablet of feeding bottle biology enzyme and its preparation method and application |
| CN109735398A (en) * | 2018-12-28 | 2019-05-10 | 北京绿伞化学股份有限公司 | Low bubble cleaning solution of a kind of household dishwasher dedicated liquid and preparation method thereof |
| CN112430509A (en) * | 2020-11-20 | 2021-03-02 | 仇晓锋 | Cleaning solution for removing pesticide residues and heavy metal pollution of fruits and vegetables |
| CN113265304A (en) * | 2021-04-30 | 2021-08-17 | 湖北美拓日化科技有限公司 | Liquid detergent and preparation method thereof |
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Application publication date: 20170613 |
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