KR100236374B1 - Powder cleaning composition and its manufacturing method - Google Patents

Powder cleaning composition and its manufacturing method Download PDF

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Publication number
KR100236374B1
KR100236374B1 KR1019970052778A KR19970052778A KR100236374B1 KR 100236374 B1 KR100236374 B1 KR 100236374B1 KR 1019970052778 A KR1019970052778 A KR 1019970052778A KR 19970052778 A KR19970052778 A KR 19970052778A KR 100236374 B1 KR100236374 B1 KR 100236374B1
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weight
present
powder detergent
sorbitol
detergent composition
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KR1019970052778A
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Korean (ko)
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KR980002230A (en
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정근식
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정근식
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
    • C11D11/0082—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/221—Mono, di- or trisaccharides or derivatives thereof

Abstract

본 발명은 유동성 개량제인 소다회와 유화제를 주성분으로 한 후, 라스(las), 빙초산, 중조(과탄산소다)를 보조성분으로 첨가하고 특징적 성분인 솔비톨을 첨가한 혼합물로 제조된 분말세제 조성물 및 그 제조방법을 제공함으로서, 과일이나 채소류에 묻어있는 농약이나 오염물 또는 세균들을 신선도에 영향을 미치지 않으면서 깨끗히 제거시킬수 있는 동시에 의류의 세탁과정에서 세제에 의한 고급의류의 손상 및 세탁물 취급시 발생할 수 있는 피부손상을 방지하는 한편 인체에 대한 독성이 없고 사용 후 세제가 하수로 방류되어도 환경오염을 유발하지 않는 분말세제 조성물 및 그 제조방법을 제공하는데 목적이 있다.The present invention is a powder detergent composition prepared from a mixture containing a soda ash and an emulsifier as a fluid improving agent, followed by adding las, glacial acetic acid and sodium bicarbonate (sodium percarbonate) as auxiliary ingredients, and adding sorbitol as a characteristic ingredient, and a powder detergent composition thereof. By providing a method of manufacturing, it is possible to remove pesticides, contaminants or germs from fruits and vegetables without affecting its freshness, while at the same time washing the garments, damage to high-quality clothing by detergents and skin that may occur when handling laundry. It is an object of the present invention to provide a powder detergent composition and a method for manufacturing the same, which prevent damage and do not cause environmental pollution even when the detergent is discharged to sewage after use.

이를 실현하기 위하여 본 발명은 유동성 개량제인 소다회 50중량%에 유화제 30중량%를 혼합한 혼합물을 주성분으로 하고 여기에 보조성분인 라스(las) 3중량%, 빙초산 5중량%, 중조(과탄산소다) 5중량%를 첨가하고, 마지막으로 특징적 성분인 솔비톨 7중량%를 첨가한 것을 특징으로 한 것이다.In order to realize this, the present invention has a mixture of 50% by weight of soda ash, which is a fluidity improver, and 30% by weight of an emulsifier, and as a main component, 3% by weight of las, 5% by weight of glacial acetic acid, and sodium bicarbonate (sodium percarbonate). 5% by weight was added, and finally, 7% by weight of sorbitol, which is a characteristic ingredient, was added.

Description

[발명의 명칭][Name of invention]

분말세제 조성물 및 그 제조방법Powder detergent composition and preparation method thereof

[발명의 상세한 설명]Detailed description of the invention

[가) 발명이 속하는 기술분야 및 그 분야의 종래기술][A] The technical field to which the invention belongs and the prior art in that field]

본 발명은 주방용 및 세탁용에 사용되는 분말세제 조성물 및 그 제조방법에 관한 것으로서, 더욱 상세하게는 일반가정에서 과일이나 채소 또는 식기에 묻어있는 농약, 오염물 또는 세균들을 신선도에 영향을 미치지 않으면서 깨끗히 제거시킬 수 있는 동시에 의류의 세탁과정에서 세제에 의향 고급의류의 손상 및 세탁물 취급시 발생할 수 있는 피부손상을 최소화 하도록 만들어진 분말세제조성물 및 그 제조방법에 관한 것이다.The present invention relates to a powder detergent composition used in kitchen and laundry, and to a method of manufacturing the same, and more particularly, to cleansed, without affecting the freshness of pesticides, contaminants or bacteria on the fruit or vegetable or tableware in the general home The present invention relates to a powder detergent composition and a method for manufacturing the same, which can be removed to minimize the damage to high-quality clothing and skin damage that may occur when handling laundry.

또한, 본 발명은 세척시 잔류세제에 의한 인체독성이 없고 사용후 세제가 환경오염을 유발하지 않는 분말세제조성물 및 그 제조방법에 관한 것이다.In addition, the present invention relates to a powder detergent composition and a method for producing the same, which have no human toxicity due to residual detergent upon washing and do not cause environmental pollution after use of the detergent.

종래에 개발되어 있는 각종 중성세제들은 세척 및 살균력 특성에 있어서는 우수하지만, 설폰산염 형태의 음이온계 계면활성제를 주성분으로 하고있어 이들 성분의 단백 변성작용에 의해 피부염증 및 피부거침등을 유발하는 등 인체독성이 심하고, 이러한 인체독성을 약화시키기 위하여 연화제 또는 피부보호제 등을 별도로 첨가하여야 하는 불편함이 있을 뿐 아니라 환경공해 유발 문제가 심각한 단점으로 지적되었다.Various neutral detergents developed in the past are excellent in washing and disinfecting properties, but they are mainly composed of anionic surfactants in the form of sulfonates, which cause skin inflammation and skin roughness by protein denaturation of these components. Toxicity is severe, and in order to weaken the human toxicity, it is not only inconvenient to add a softener or skin protection agent, etc., but also pointed out as a serious disadvantage.

이상의 단점을 좀더 구체적으로 설명하면 다음과 같다.The above disadvantages will be described in more detail as follows.

계면활성제로는 알킬벤젠술포네이트, 알파올레핀술페이트, 소듐 또는 암모늄라우릴술페이트, 알킬베타인, 아민옥사이드, 에톡시화알콜에테르, 알킬폴리글루코사이드, 지방산아마이드 등이 있으며, 이들은 모두 석유 또는 식물의 1성분을 출발물질로 하는 합성 계면활성제이다. 이러한 합성 계면활성제들은 경우에 따라 피부자극과 주부습진 같은 피부염을 유발하고 세척후 피세정 물질 표면에 잔류하여 이로 인한 인체독성의 원인제공이 되기도 한다.Surfactants include alkylbenzenesulfonates, alphaolefin sulfates, sodium or ammonium lauryl sulfates, alkylbetaines, amine oxides, ethoxylated alcohol ethers, alkylpolyglucosides, fatty acid amides, all of which are petroleum or plant It is a synthetic surfactant which uses one component as a starting material. These synthetic surfactants sometimes cause skin irritation and dermatitis, such as housewife eczema, and remain on the surface of the material to be cleaned after washing to provide a cause of human toxicity.

따라서 저자극성 계면활성제의 개발 또는 가능한 소량의 계면활성제를 사용하는 제품의 개발노력이 꾸준히 계속되고 있으며, 최근에는 세제에 천연의 추출물 등을 첨가하여 자연의 신선한 향취를 부여하고 이들 추출물이 갖는 보습 및 영양공급 효과를 제품에 부여하고자 하는 시도가 계속되고 있다.Therefore, efforts have been made to develop hypoallergenic surfactants or products using small amounts of surfactants. Recently, natural extracts have been added to detergents to give natural fresh odors, moisturizing and Attempts have been made to give nutritional benefits to products.

그러나 이러한 식물 추출물들을 이용한 생분해성 세제류는 세제 본래의 세척력 및 기포력의 감소를 초래하고 이로 인하여 사용량에 제한을 받게됨과 동시에 가격이 비싸다는 문제점을 갖고있다.However, biodegradable detergents using such plant extracts have a problem that the detergent's inherent washing power and foaming power are reduced, thereby limiting the amount of use and being expensive.

[나) 발명이 이루고자 하는 기술적 과제][B) Technical problem to be achieved by the invention]

본 발명은 상기한 종래기술의 문제점을 해소하기 위하여 발명된 것으로서, 본 발명은 분말세제에 함유하는 경우 피부보호효과, 보습효과를 나타내며 종래 식물 추출물들과는 달리 세척력 및 기포력을 증가시켜 합성 계면활성제의 사용량을 감소시킬 수 있는 분말세제를 제공하고자 광범위하게 연구한 결과 종래 식품 첨가제, 가용화제 등으로 사용되어온 솔비톨(D-Sorbitol ; C6H14O6)을 분말세제에 첨가시키면 세제로서의 제반 특성을 골고루 만족시킬 수 있다는 새로운 사실을 알아내어 본 발명을 완성하게 되었다.The present invention has been invented to solve the above problems of the prior art, the present invention has a skin protection effect, moisturizing effect when contained in a powder detergent and unlike the conventional plant extracts to increase the washing power and foaming power of the synthetic surfactant As a result of extensive research to provide a powder detergent that can reduce the amount of use, sorbitol (D-Sorbitol; C 6 H 14 O 6 ), which has been used as a food additive or a solubilizer, is added to the powder detergent to provide various characteristics as a detergent. The present invention has been accomplished by finding new facts that can be evenly satisfied.

나아가 본 발명은 상기한 솔비톨을 유동성 개량제인 소다회에 소량만 첨가하여도 필요한 제반 특성을 골고루 만족시키는 세제를 얻을수 있다는 사실을 확인하였다.Furthermore, the present invention confirmed that even if only a small amount of sorbitol was added to soda ash, which is a fluidity improver, a detergent that satisfies all the necessary properties could be obtained.

또한, 상기한 솔비톨과 소다회의 혼합물이 유화제나 라스(las) 또는 이들의 혼합물과 혼합되면 더욱 뛰어난 세정효과를 나타낸다는 사실도 확인되었다.In addition, it was also confirmed that the above-described mixture of sorbitol and soda ash exhibited an excellent cleaning effect when mixed with an emulsifier, las, or a mixture thereof.

따라서 본 발명의 목적은 소다회와 유화제를 주성분으로 한후, 라스(las), 빙초산, 중조(과탄산소다)를 소량 첨가한 보조성분에 특징적 성분인 솔비톨을 소량 첨가한 이들의 혼합물을 건조분말화 시킨 분말세제 및 그 제조방법을 제공하는데 있다.Accordingly, an object of the present invention is to dry powderize a mixture of these powders containing soda ash and emulsifier as a main component, and then a small amount of sorbitol, which is a characteristic ingredient in the auxiliary component containing small amounts of las, glacial acetic acid and sodium bicarbonate (sodium percarbonate). The present invention provides a powder detergent and a method of manufacturing the same.

본 발명의 다른 목적은 과일이나 채소류에 묻어있는 농약이나 오염물 또는 세균들을 신선도에 영향을 미치지 않으면서 깨끗히 제거시킬 수 있는 동시에 의류의 세탁과정에서 세제에 의한 고급의류의 손상 및 세탁물 취급시 발생할 수 있는 피부 손상을 방지할수 있는 분말세제 조성물을 제공하는데에 있다.It is another object of the present invention to remove pesticides, contaminants or bacteria on fruits and vegetables without affecting the freshness, and at the same time may cause damage to high-quality clothing by detergents during laundry washing and handling of laundry. It is to provide a powder detergent composition that can prevent skin damage.

본 발명의 또다른 목적은 인체에 대한 독성이 없으며 사용후 세제가 환경오염을 유발하지 않는 분말세제 조성물을 제공하는데에 있다.It is another object of the present invention to provide a powder detergent composition which is not toxic to the human body and the detergent after use does not cause environmental pollution.

[다) 본 발명의 실시예 및 작용][C) Embodiments and Functions of the Invention]

상기한 바와같은 목적을 달성하기 위하여 본 발명의 실시예에 의하면 유동성 개량제인 소다회 50중량%에 유화제 30중량%를 혼합한 혼합물을 주성분으로 하는 분말세제가 제공된다.In order to achieve the above object, according to an embodiment of the present invention, there is provided a powder detergent mainly containing a mixture of 30% by weight of an emulsifier and 50% by weight of soda ash, which is a fluidity improver.

또한 본 발명의 실시예2에 의하면 소다회 50중량%에 유화제 30중량%를 혼합한 혼합물에 보조성분인 라스(las) 3중량%, 빙초산 5중량%, 중조(과탄산소다) 5중량%를 첨가하는 것을 특징으로 하는 분말세제가 제공된다.In addition, according to Example 2 of the present invention, 3% by weight of las, 5% by weight of glacial acetic acid, and 5% by weight of sodium bicarbonate (sodium percarbonate) were added to a mixture of 50% by weight of soda ash and 30% by weight of an emulsifier. A powder detergent is provided, which is characterized by the above-mentioned.

더욱 구체적인 본 발명 실시예3에 의하면 제1실시예와 제2실시예의 혼합분말에 특징적 성분인 솔비톨 7중량%를 첨가하는 것을 특징으로 하는 분말세제가 제공된다.According to a third embodiment of the present invention, a powder detergent is provided, wherein 7 wt% of sorbitol, which is a characteristic ingredient, is added to the mixed powder of the first and second embodiments.

이하 본 발명의 실시예를 설명하면 다음과 같다.Hereinafter, an embodiment of the present invention will be described.

[실시예 1]Example 1

본 발명 주성분의 조성물은 다음과 같다.The composition of the main component of the present invention is as follows.

Figure kpo00001
Figure kpo00001

[실시예 2]Example 2

본 발명 보조성분의 조성물은 다음과 같다.The composition of the auxiliary ingredient of the present invention is as follows.

Figure kpo00002
Figure kpo00002

[실시예 3]Example 3

본 발명 분말세제의 조성물은 다음과 같다.The composition of the powder detergent of the present invention is as follows.

Figure kpo00003
Figure kpo00003

본 발명의 주성분인 유동성개량제인 소다회와 유화제의 비율은 5 : 3의 비율(중량비)로 혼합되는 것이 가장 바람직하며, 또한 본 발명에 있어서는 상기한 주성분 이외에 필요에 따라 라스(las), 빙초산, 중조(과탄산소다)를 보조성분으로 함유할 수 있다.It is most preferable that the ratio of the soda ash and the emulsifier, the fluidity improving agent, which is the main component of the present invention, is mixed in a ratio (weight ratio) of 5: 3, and in the present invention, in addition to the above-mentioned main components, las, glacial acetic acid, sodium bicarbonate, etc. as necessary. (Soda percarbonate) may be included as an auxiliary component.

이들 보조성분은 분말세제 등에 사용되는 공지의 재료들로써 인체에 무해한 것 중에서 선택하여 사용하는 것이 바람직하며 이들 보조성분은 본발명 세제조성물의 세제 특성에 영향을 미치지 않는 범위내에서 첨가하는 것이 바람직하고 전체 세제조성물에 대해 라스(las) 0.03중량%, 빙초산 0.05중량%, 중조(과탄산소다) 0.05중량%가 바람직하나 상기 중량비율이 꼭 한정적인 것은 아니다.These auxiliary ingredients are well-known materials used in powder detergents, and are preferably selected from those which are harmless to the human body. These auxiliary ingredients are preferably added within a range that does not affect the detergent properties of the detergent composition of the present invention. The detergent composition is preferably 0.03% by weight las, 0.05% by weight glacial acetic acid, 0.05% by weight sodium bicarbonate, but the weight ratio is not necessarily limited.

이들 보조성분의 첨가량이 너무적은 경우에는 각각 보조성분의 역할을 수행하기 곤란하게 되고 반대로 첨가량이 너무 많은 경우에는 본 발명 분말세제 조성물의 특성을 오히려 저하시키거나, 또는 부작용을 일으킬 염려가 있게된다.When the addition amount of these auxiliary ingredients is too small, it becomes difficult to perform the role of each auxiliary component, on the contrary, when the addition amount is too large, the characteristics of the powder detergent composition of the present invention may rather deteriorate or cause side effects.

또 본 발명 특징적 보조성분 솔비톨은 물에 매우 잘 용해되는 순수 솔비틀이 바람직하며 분말 솔비톨이면 더욱 바람직하다. 또한 첨가비율은 전체 세제 조성물에 대해 0.07중량%가 가장 바람직 하나 이 또한 꼭 한정적인 것은 아니다.In addition, the characteristic auxiliary component sorbitol of the present invention is preferably pure sorbitol, which is very soluble in water, and more preferably powder sorbitol. In addition, the addition ratio is most preferably 0.07% by weight based on the total detergent composition, but is not necessarily limited.

한편, 상기한 바의 보조성분 중에서 빙초산을 첨가하는 것은 본 발명 분말세제의 침투력을 높임과 동시에 살균소독 효과를 높이기 위함이며, 중조(과탄산소다)를 첨가하는 것은 표백효과를 향상시키기 위함이고, 솔비톨을 첨가하는 것은 세제로서의 제반 특성을 골고루 만족시킬 뿐 아니라 피부보호제 역할을 하기 때문이다.On the other hand, the addition of glacial acetic acid among the auxiliary components as described above to increase the penetration power of the powder detergent of the present invention and at the same time to increase the disinfectant disinfection effect, the addition of sodium bicarbonate (sodium percarbonate) is to improve the bleaching effect, The addition of sorbitol not only satisfies all the properties as a detergent, but also acts as a skin protectant.

[라. 본 발명의 효과][la. Effect of the present invention

이상과 같은 본 발명 분말세제 조성물은 인체에 무해하고, 피부자극성 등이 없기 때문에 식생활에 관계되는 모든 분야, 예를 들어 식기류 세척, 과일 또는 채소류 세척 등에 사용 가능하지만, 특히 의류세척에 더욱 적합하다.Since the powder detergent composition of the present invention is harmless to the human body and does not have skin irritation, it can be used in all fields related to eating habits, for example, dish washing, fruit or vegetable washing, etc., but is particularly suitable for washing clothes.

더욱이 본 발명의 분말세제 조성물은 생분해성이 뛰어나기 때문에 사용후 폐기되어 하수등에 방류되더라도 환경오염 등의 문제를 전혀 야기시키지 않는 효과가 있는 것이다.Furthermore, since the powder detergent composition of the present invention has excellent biodegradability, even after being disposed of and discharged into sewage after use, it does not cause any problems such as environmental pollution.

Claims (2)

조성물중 총중량을 기준으로 소다회 50중량%, 유화제 30중량%, 라스(las) 3중량%, 빙초산 5중량%, 중조(과탄산소다) 5중량%, 솔비틀 (D-sorbitol)7중량%를 혼합한 것을 특징으로 하는 분말세제 조성물.50% by weight of soda ash, 30% by weight of emulsifier, 3% by weight of las, 5% by weight of glacial acetic acid, 5% by weight of sodium bicarbonate and 7% by weight of D-sorbitol in the composition Powder detergent composition, characterized in that mixed. 소다회 50중량%에 유화제 30중량%를 혼합하여 기본분말세제를 준비하는 단계와, 상기 기본분말세제에 라스(las) 3중량%, 빙초산 5중량% 그리고 중조(과탄산소다) 5중량%의 보조분말세제를 첨가하는 단계, 그리고 상기 기본분말과 보조분말을 모두 혼합한후 특징적 성분인 솔비톨(D-sorbitol) 7중량%를 첨가하여 건조분말화 시킴을 특징으로 하는 분말세제 조성물의 제조방법.Preparing a basic powder detergent by mixing 30% by weight of an emulsifier with 50% by weight of soda ash, and 3% by weight of las, 5% by weight of glacial acetic acid and 5% by weight of sodium bicarbonate (soda). Adding a powder detergent, and after mixing both the main powder and the auxiliary powder 7% by weight of the sorbitol (D-sorbitol) as a characteristic component to dry powdered manufacturing method characterized in that the powder.
KR1019970052778A 1997-10-10 1997-10-10 Powder cleaning composition and its manufacturing method KR100236374B1 (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040013683A (en) * 2002-08-08 2004-02-14 주식회사 쉘그린 Powdered cleanser
KR20040019483A (en) * 2002-08-28 2004-03-06 정근식 The powdered cleanser and a manufacture process of powdered cleanser
KR100489035B1 (en) * 2002-11-01 2005-05-11 김선호 The powdered cleanser and the manufacture process of powdered cleanser
KR100489034B1 (en) * 2002-10-09 2005-05-11 김선호 The powdered cleanser and the manufacture process of powdered cleanser
KR100728474B1 (en) * 2005-11-24 2007-06-13 주식회사 엘지생활건강 Vegetable and fruit cleaner

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100638004B1 (en) * 1999-04-27 2006-10-23 주식회사 엘지생활건강 Compositions of detergent for washing vegetable and fruit

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040013683A (en) * 2002-08-08 2004-02-14 주식회사 쉘그린 Powdered cleanser
KR20040019483A (en) * 2002-08-28 2004-03-06 정근식 The powdered cleanser and a manufacture process of powdered cleanser
KR100489034B1 (en) * 2002-10-09 2005-05-11 김선호 The powdered cleanser and the manufacture process of powdered cleanser
KR100489035B1 (en) * 2002-11-01 2005-05-11 김선호 The powdered cleanser and the manufacture process of powdered cleanser
KR100728474B1 (en) * 2005-11-24 2007-06-13 주식회사 엘지생활건강 Vegetable and fruit cleaner

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