KR20040019483A - The powdered cleanser and a manufacture process of powdered cleanser - Google Patents

The powdered cleanser and a manufacture process of powdered cleanser Download PDF

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Publication number
KR20040019483A
KR20040019483A KR1020020051025A KR20020051025A KR20040019483A KR 20040019483 A KR20040019483 A KR 20040019483A KR 1020020051025 A KR1020020051025 A KR 1020020051025A KR 20020051025 A KR20020051025 A KR 20020051025A KR 20040019483 A KR20040019483 A KR 20040019483A
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weight
powder
powder detergent
sodium bicarbonate
sorbitol
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KR1020020051025A
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Korean (ko)
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정근식
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정근식
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • C11D7/12Carbonates bicarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06Powder; Flakes; Free-flowing mixtures; Sheets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/261Alcohols; Phenols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/265Carboxylic acids or salts thereof

Abstract

PURPOSE: A powder detergent composition and its preparation method are provided, to reduce the generation of bubbles by containing no LAS component (emulsifier) and to reduce the harmfulness to the skin. CONSTITUTION: The powder detergent composition comprises 30 wt% of soda ash (sodium carbonate); 30 wt% of sodium hydrogen carbonate; 20 wt% of powder sorbitol; 5 wt% of glacial acetic acid; 10 wt% of a sterilizer; and 5 wt% of an aid for household articles. The method comprises the steps of mixing soda ash, sodium hydrogen carbonate and powder sorbitol; adding glacial acetic acid, a sterilizer and an aid for household articles to the mixture and mixing them; and removing the moisture from the obtained mixture to prepare a dry powder detergent.

Description

분말세제 조성물 및 그 제조방법 {The powdered cleanser and a manufacture process of powdered cleanser}Powdered detergent composition and its manufacturing method {The powdered cleanser and a manufacture process of powdered cleanser}

본 발명은 세탁용 및 주방용에 사용되는 분말세제 조성물 및 그 제조방법에 관한 것으로서, 더욱 상세하게는 일반 가정에서 의류등의 세탁시 세제에 의한 피부거침과 고급의류의 손상을 줄이고, 과일, 야채류, 식기등에 묻어있는 농약, 오염물 또는 세균들을 깨끗하게 제거시킬 수 있도록 하는 동시에, 기포가 발생되지 않아 환경오염을 유발하지 않고, 인체에 자극을 주지 않으면서 뛰어난 세척력을 가지고 있으며, 살균 소독효과를 갖는 분말세제 조성물 및 그 제조방법에 관한 것이다.The present invention relates to a powder detergent composition and a method for manufacturing the same, which are used for laundry and kitchen, and more particularly, to reduce skin roughness and damage to high-quality clothing by washing detergents when washing clothes, etc. Powder detergent with sterilizing and disinfecting effect that can remove pesticides, contaminants or germs on tableware cleanly, does not cause air pollution and does not cause environmental pollution, and does not irritate the human body. A composition and a method for producing the same.

일반적으로 세제란 오염에 대한 효율적인 세정을 도와주는 혼합물질로서, 계면활성제와 조제로 구성되며, 세척을 목적으로 사용되는 계면활성제를 세척제라고 하는등 세제의 세척작용은 주로 계면활성제의 역할에 의하는 것인데, 세제는 제조방법에 따라 비누와 합성세제로 구분되고 성분상으로 크게 나누면 음이온계 계면활성제 비누ㆍ알킬벤젠술폰산나트륨ㆍ비이온성세제등으로 나눌 수 있다.In general, detergents are mixtures that help efficient cleaning against contamination. They consist of surfactants and preparations. The detergents used for cleaning are called detergents. Detergents are divided into soaps and synthetic detergents according to the preparation method. The detergents can be broadly divided into anionic surfactant soaps, sodium alkylbenzenesulfonates, and nonionic detergents.

또한 세탁조제는 세제의 세척작용을 높여줄 목적으로, 즉 계면활성제의 계면활성을 촉진시키기 위하여 세제에 배합하는 조제 또는 첨가제인데, 대개 무기염류나 유기성 호료로서 합성세제 중에 65∼80%가 배합되어 있다.In addition, laundry aids are additives or additives formulated in detergents for the purpose of enhancing the cleaning action of detergents, i.e., to promote the surfactant activity of surfactants. In general, 65 to 80% of synthetic detergents are formulated as inorganic salts or organic ingredients. have.

종래에 개발되어 있는 각종 세제들은 피부에 무해한 쪽으로 개선되어 가고 있으나, 이들 세제들은 주로 기포를 발생시키는 라스(LAS)성분등의 화학성분들을 주성분으로 하고 있어서 심각한 환경오염 유발문제가 단점으로 지적되었고, 세척 및 살균력등의 특성에 있어서는 우수하지만, 상기한 바와 같은 음이온계 계면활성제를 주성분으로 하고 있어 이들 성분의 단백 변성작용에 의해 피부염증 및 피부거침등을 유발하는 등 인체에 미치는 독성이 심하고, 이러한 독성을 약화시키기 위해 연화제 또는 피부보호제등을 별도로 첨가하여야 하는 불편함이 따르는 등의 문제점이 지적돼 왔다.Various detergents developed in the past have been improved to be harmless to the skin, but since these detergents are mainly composed of chemical components such as las (LAS) that generate air bubbles, serious environmental pollution causing problems have been pointed out as disadvantages. Although excellent in properties such as washing and disinfecting power, the anionic surfactant as described above is the main ingredient, and the toxic effects on the human body are severe, such as causing skin inflammation and skin roughness by protein denaturation of these components. Problems such as the inconvenience of having to add a softener or skin protectant, etc. separately to reduce the toxicity has been pointed out.

따라서 저자극성 계면활성제의 개발 또는 가능한 소량의 계면활성제를 사용하는 제품의 개발노력이 꾸준히 계속되고 있으며, 근래에는 세제에 천연의 추출물등을 첨가하여 자연의 신선한 향취를 부여하고 이들 추출물이 갖는 보습 및 영양공급효과를 제품에 부여하고자 하는 시도가 계속되고 있다.Therefore, efforts have been made to develop hypoallergenic surfactants or products using small amounts of surfactants. In recent years, natural extracts are added to detergents to give natural fresh flavors, moisturizing and Attempts have been made to give nutritional benefits to products.

그러나 이러한 식물 추출물들을 이용한 생분해성 세제류는 세제 본래의 세척력의 감소를 초래하고 이로 인하여 사용량에 제한을 받게됨과 동시에 가격이 비싸다는 문제점을 갖고 있었다.However, biodegradable detergents using such plant extracts have a problem that the detergent's inherent washing power is reduced, thereby limiting the amount used and the price thereof.

상기한 바와 같은 종래의 문제점을 해결하기 위한 본 발명의 목적은 의류, 식기등의 세척시에 피부에 자극을 주지 않으며, 종래 세제와는 다르게 기포를 발생시키는 유화제의 일종 라스(LAS)성분이 첨가되지 않음으로써, 기포가 전혀 발생되지않고 계면활성제의 사용량을 감소시키는 분말세제를 제공하여 폐수발생이 억제되면서 환경오염을 방지하는 동시에 살균제 성분이 함유되어 세척대상물의 살균소독이 가능하도록 하는 분말세제 및 그 제조방법을 제공하는 것이다.An object of the present invention for solving the conventional problems as described above do not irritate the skin when washing clothes, tableware, etc., unlike the conventional detergents are added a kind of las (LAS) component of the emulsifier that generates bubbles Powder detergent that does not generate bubbles at all and reduces the amount of surfactant used, thereby preventing wastewater generation while preventing wastewater generation and containing a disinfectant component to enable sterilization and disinfection of cleaning objects. It is to provide a manufacturing method.

상기한 바와 같은 목적을 달성하기 위한 본 발명의 실시예를 보다 상세히 설명하면 다음과 같다.Referring to the embodiments of the present invention for achieving the above object in more detail as follows.

본 발명에 따른 분말세제 조성물은 유동성 개량제인 소다회 30중량%에 중조(탄산수소나트륨) 30중량%, 분말솔비톨 20중량%를 혼합한 혼합물을 주성분으로 하고 보조성분으로 빙초산 5중량%, 살균제 10중량%, 가정용품 조제 5중량%를 첨가하여 제조되며, 본 발명의 주성분인 소다회와, 중조(탄산수소나트륨), 분말솔비톨의 비율은 3:3:2의 비율(중량비)로 혼합되는 것이 가장 바람직하다.Powder detergent composition according to the present invention is a mixture of 30% by weight of sodium hydroxide (sodium bicarbonate), 20% by weight of powder sorbitol as a main component, 5% by weight of glacial acetic acid, 10% by weight of disinfectant %, And prepared by adding 5% by weight of the preparation of household goods, the ratio of soda ash, sodium bicarbonate (sodium bicarbonate) and powder sorbitol, which are the main components of the present invention, is most preferably mixed in the ratio (weight ratio) of 3: 3: 2. Do.

이상의 세제 성분중에서 소다회는 무수탄산나트륨(Na2CO3)의 일반명칭으로 탄산나트륨을 99% 이상 함유하는 백색무수분말 또는 입상물질로서, 가성소다와 함께 알칼리부분의 대표적인 화학산업의 기초원료로 사용되고 있으며,Among the above detergent components, soda ash is a white anhydrous powder or granular material containing more than 99% of sodium carbonate in the general name of anhydrous sodium carbonate (Na 2 CO 3 ).

또한 소다회는 반응이 완결된 세탁비누에 직접 추가됨으로써 때가 잘 빠지게 하는 비누혼합제 즉 Builder(소다회, 가성소다, 규산나트륨등)의 역할을 하게 돼 세제의 세척기능을 증진시키거나, 또는 합성세제의 혼합제로서 사용되며 근래에는 무공해 산소계 표백제인 과탄산소다의 제조에도 사용되고 있다.In addition, the soda ash is directly added to the complete washing soap to act as a soap admixture that is good at removing time, such as Builder (soda ash, caustic soda, sodium silicate) to enhance the cleaning function of the detergent, or a mixture of synthetic detergents In recent years, it is also used in the production of sodium percarbonate, an oxygen-free bleach.

그리고 솔비톨은 분자량이 182.18인 6가 당알콜로서 D-Sorbitol 또는 D-Glucitol 이라고도 불려지며, 포도당을 환원하여 얻어지는 식물성 첨가제로서 물에 쉽게 용해되므로 액체나 고체 형태로 이용할 수 있고, 화학적으로도 매우 안정성이 있다. 그리고 상기 솔비톨은 수분을 강하게 흡수하는 성질이 있어서 신선도와 유연성을 유지시키고, 건조, 균열, 중량손실을 방지하므로, 습윤조정제 또는 보습제 이외에 가소제, 유연제, 광택제로서도 사용되며, 단백질의 변성을 촉진하는 Fe2+, Fe3+, Cu2+를 봉쇄하여 변성을 방지하는 역할을 하며, 효소에 의해 공격받지 않고 효소와 곰팡이의 성장에 대한 세균발육 저지력을 가지고 있다.Sorbitol is a hexavalent sugar alcohol having a molecular weight of 182.18, also called D-Sorbitol or D-Glucitol. As a vegetable additive obtained by reducing glucose, it is easily dissolved in water and can be used in liquid or solid form. have. In addition, the sorbitol has a property of strongly absorbing moisture to maintain freshness and flexibility, and prevents drying, cracking, and weight loss. Therefore, sorbitol is also used as a plasticizer, softening agent, and brightening agent in addition to a wetting or moisturizing agent. Blocks 2+ , Fe 3+ , Cu 2+ to prevent denaturation and is resistant to bacterial growth against the growth of enzymes and fungi without being attacked by enzymes.

또한, 중조(탄산수소나트륨)는 가열하면 이산화탄소를 내는 약 염기성 물질이며 피부활성화 효과가 있고 표백효과를 향상시키며,In addition, sodium bicarbonate (sodium bicarbonate) is a weak basic substance that emits carbon dioxide when heated, has skin activation effect and improves bleaching effect,

빙초산은 강산성이고 본 발명 분말세제의 침투력을 높임과 동시에 살균소독 효과를 높이는 역할을 하는 한편, 살균제는 BENZALKONIUM CHLORIDE형 살균제로서 일반 사용농도내에서는 인체에 대한 독성이 없어 세제사용시 피부접촉에 따른 부작용이 없다. 끝으로 가정용품 조제는 세정제, 보습제로서 인체에 무해하며, 특히 생분해도가 우수하여 하천오염을 방지할 수 있다.Glacial acetic acid is strongly acidic and increases the penetration of the powder detergent of the present invention and at the same time increases the disinfectant disinfecting effect, while the disinfectant is a BENZALKONIUM CHLORIDE type disinfectant, which is not toxic to the human body in general use concentration, so the side effects of skin contact when using detergent none. Finally, home appliance preparations are harmless to humans as detergents and moisturizers. Especially, they can prevent river pollution due to their excellent biodegradability.

상기한 바와 같이 본 발명의 분말세제는 세척력이 강한 소다회와 피부보호력이 있는 중조(탄산수소나트륨), 피세정체에 빠르게 침투하여 세척력을 높이는 빙초산등 대부분 식물성 원료이므로 세척시 피부를 손상시키지 않는다.As described above, the powder detergent of the present invention is a vegetable raw material such as soda ash, which has strong washing power, sodium bicarbonate (sodium bicarbonate) having strong skin protection, and glacial acetic acid, which quickly penetrates into the object to be washed, and thus does not damage the skin during washing.

이상과 같은 조성물질로 이루어지는 분말세제의 제조방법을 살펴보면,Looking at the manufacturing method of the powder detergent consisting of the composition as described above,

우선 소다회 분말과 중조(탄산수소나트륨), 분말솔비톨을 각각 3:3:2의 중량비율로 혼합하는데, 상기 혼합비율은 최대의 세척효과와 피부보호 효과를 얻을 수 있는 비율이다.First, soda ash powder, sodium bicarbonate (sodium bicarbonate), and powder sorbitol are mixed in a weight ratio of 3: 3: 2, respectively, and the mixing ratio is a ratio that can obtain the maximum washing effect and skin protection effect.

이후에 상기 혼합물에 빙초산과 살균제, 가정용품 조제를 넣고 다시 혼합하는데, 이와 같이 혼합된 분말은 소정의 수분건조 공정을 거침으로써, 대부분 순식물성인 재료로 제조된 상기 분말세제가 수분에 의하여 변질되는 것을 방지한다.Thereafter, the mixture is mixed with glacial acetic acid, a disinfectant, and a household product preparation, and the mixed powder is subjected to a predetermined moisture drying process, whereby the powder detergent, which is mostly made of pure vegetable materials, is deteriorated by moisture. prevent.

또한 상기한 제조방법에 의하면 최종적으로 분말에 포함된 수분을 미생물이 번식되지 않을 정도로 건조시키는 공정만을 거치면 되므로, 혼합조성물을 분말로 제조하는 별도의 공정이 필요치 않아, 제조시간이 단축된다.In addition, according to the above-described manufacturing method, only a step of drying the moisture contained in the powder to the extent that the microorganisms are not multiplied is not required, so that a separate process of manufacturing the mixed composition into powder is not necessary, and the manufacturing time is shortened.

그리고 기포를 유발시키는 유화제인 라스(LAS)가 첨가되지 않음으로써 세척시 기포가 전혀 발생되지 않고, 상기 조성물의 원료가 대부분 식물성이므로 전체 환경오염의 70%를 차지하는 가정폐수에 의한 환경오염이 대폭 감소된다.In addition, since no las (LAS), which is a bubble-inducing emulsifier, is not generated at the time of washing, no bubbles are generated at all, and since the raw material of the composition is mostly vegetable, the environmental pollution by home wastewater, which accounts for 70% of the total environmental pollution, is greatly reduced. do.

상기한 바와 같은 본 발명의 분말세제 조성물은 인체에 무해하고, 보습효과와 세척력이 우수하며, 구성성분이 대부분 식물성이므로 피부자극성이 적어, 식생활에 관계되는 모든 분야 즉, 식기류 세척, 야채류 세척등에도 사용가능하며, 특히 의류세척에 적합하다.The powder detergent composition of the present invention as described above is harmless to the human body, excellent moisturizing effect and washing power, and since most of the components are vegetable, skin irritation is low, even in all fields related to eating habits, ie, washing dishes, washing vegetables, etc. Can be used, especially suitable for washing clothes.

특히 본 발명의 분말세제는 기포발생이 전혀 없고, 생분해성이 뛰어나기 때문에 사용후 하수등에 방류되더라도 환경오염을 유발하지 않는 효과가 있다.In particular, the powder detergent of the present invention has no bubble generation, and because of its excellent biodegradability, even when discharged into sewage after use, it does not cause environmental pollution.

Claims (2)

분말세제에 있어서,In powder detergent, 분말세제 조성물중 총중량을 기준으로 소다회 30중량%, 중조(탄산수소나트륨) 30중량%, 분말솔비톨 20중량%, 빙초산 5중량%, 살균제 10중량%, 가정용품 조제 5중량%를 혼합한 것을 특징으로 하는 분말세제 조성물.30% by weight of soda ash, 30% by weight of sodium bicarbonate (sodium bicarbonate), 20% by weight of powder sorbitol, 5% by weight of glacial acetic acid, 10% by weight of disinfectant, and 5% by weight of household preparations Powder detergent composition. 분말세제의 제조방법에 있어서,In the manufacturing method of the powder detergent, 소다회 30중량%와 중조(탄산수소나트륨)30중량%, 분말솔비톨 20중량%의 주성분을 혼합하는 1단계와, 상기 1단계의 혼합물에 빙초산 5중량%, 살균제 10중량%, 그리고 가정용품 조제 5중량%의 보조성분을 첨가하여 혼합하는 2단계와, 상기 2단계에서 생성된 혼합조성물의 수분을 증발시켜 건조분말화 하는 3단계로 이뤄지는 것을 특징으로 하는 분말세제 조성물의 제조방법.Step 1 of mixing 30% by weight of soda ash with 30% by weight of sodium bicarbonate (sodium bicarbonate), 20% by weight of powder sorbitol, 5% by weight of glacial acetic acid, 10% by weight of disinfectant, and household goods preparation 5 Method for producing a powder detergent composition comprising the two steps of adding by weight of the auxiliary component and mixing, and three steps of evaporating the dry powder by evaporating the moisture of the mixed composition produced in the second step.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR870003188A (en) * 1985-09-12 1987-04-15 에이취. 반 발렌 Manufacturing method of detergent powder
KR930007223A (en) * 1991-09-13 1993-04-22 강진구 Camcorder with LCD screen
KR100236374B1 (en) * 1997-10-10 1999-12-15 정근식 Powder cleaning composition and its manufacturing method
KR20010071058A (en) * 1998-07-31 2001-07-28 프랭크 제이. 윌리엄 삼세 Method of reducing fines in a powdered product and fabric cleaner produced therefrom

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR870003188A (en) * 1985-09-12 1987-04-15 에이취. 반 발렌 Manufacturing method of detergent powder
KR930007223A (en) * 1991-09-13 1993-04-22 강진구 Camcorder with LCD screen
KR100236374B1 (en) * 1997-10-10 1999-12-15 정근식 Powder cleaning composition and its manufacturing method
KR20010071058A (en) * 1998-07-31 2001-07-28 프랭크 제이. 윌리엄 삼세 Method of reducing fines in a powdered product and fabric cleaner produced therefrom

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