KR100489035B1 - The powdered cleanser and the manufacture process of powdered cleanser - Google Patents
The powdered cleanser and the manufacture process of powdered cleanser Download PDFInfo
- Publication number
- KR100489035B1 KR100489035B1 KR10-2002-0067513A KR20020067513A KR100489035B1 KR 100489035 B1 KR100489035 B1 KR 100489035B1 KR 20020067513 A KR20020067513 A KR 20020067513A KR 100489035 B1 KR100489035 B1 KR 100489035B1
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- powder
- detergent
- soda ash
- acetic acid
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title description 5
- 239000003599 detergent Substances 0.000 claims abstract description 43
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 40
- 239000000843 powder Substances 0.000 claims abstract description 33
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 29
- 235000017550 sodium carbonate Nutrition 0.000 claims abstract description 18
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 18
- 239000000203 mixture Substances 0.000 claims abstract description 16
- 229960000583 acetic acid Drugs 0.000 claims abstract description 13
- 239000012362 glacial acetic acid Substances 0.000 claims abstract description 10
- 235000019502 Orange oil Nutrition 0.000 claims abstract description 9
- 239000000284 extract Substances 0.000 claims abstract description 9
- 239000010502 orange oil Substances 0.000 claims abstract description 9
- -1 polyoxyethylene nonylphenyl ether Polymers 0.000 claims abstract description 9
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims abstract description 8
- 229940045872 sodium percarbonate Drugs 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 229910001868 water Inorganic materials 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 2
- 238000001704 evaporation Methods 0.000 claims 1
- 238000005406 washing Methods 0.000 abstract description 12
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 7
- 239000000356 contaminant Substances 0.000 abstract description 5
- 239000003995 emulsifying agent Substances 0.000 abstract description 5
- 208000017520 skin disease Diseases 0.000 abstract description 5
- 239000002736 nonionic surfactant Substances 0.000 abstract description 4
- 230000003020 moisturizing effect Effects 0.000 abstract description 3
- 230000001580 bacterial effect Effects 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000007844 bleaching agent Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 238000003912 environmental pollution Methods 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 235000013311 vegetables Nutrition 0.000 description 5
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 239000000600 sorbitol Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 238000012851 eutrophication Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000000271 synthetic detergent Substances 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000004278 EU approved seasoning Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 241000282412 Homo Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 208000002193 Pain Diseases 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 208000004880 Polyuria Diseases 0.000 description 1
- 206010036790 Productive cough Diseases 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 208000003251 Pruritus Diseases 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 235000021028 berry Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 description 1
- 230000035619 diuresis Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000007803 itching Effects 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 235000013923 monosodium glutamate Nutrition 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 230000036620 skin dryness Effects 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229940073490 sodium glutamate Drugs 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/40—Products in which the composition is not well defined
- C11D7/44—Vegetable products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/12—Carbonates bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/263—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
본 발명은 분말세제 조성물 및 그 제조방법에 관한 것으로, 소다회분말 71중량%와 폴리옥시에틸렌 노닐페닐 에테르 28.4중량%가 주성분으로 되고, 과탄산소다 0.2중량%와 빙초산 0.2중량%, 탱자추출물 0.1중량%, 오렌지오일 0.1중량%의 보조성분이 혼합되며, 특히 주성분인 유화제는 비이온 계면활성제로서 때를 부드럽게 벗겨내는 역할을 하게 돼 피세척물의 오염물질이 보다 더 깨끗하게 세척되고, 보조성분인 탱자추출물은 세균증식을 억제하는 성분으로서 항균작용과 보습효과가 있기 때문에 세탁후에도 피세척물에 미세하게 남아있는 오염물로 인한 피부질환을 예방하며, 또한 상기 분말세제는 기존 세제에 주로 사용되는 성분인 솔비톨이 첨가되지 않음으로써 세제의 경화현상이 방지되도록 한 것이다. The present invention relates to a powder detergent composition and a manufacturing method thereof, wherein 71% by weight of soda ash powder and 28.4% by weight of polyoxyethylene nonylphenyl ether are the main components, 0.2% by weight of sodium percarbonate, 0.2% by weight of glacial acetic acid, and 0.1% of tanza extract. %, Orange oil 0.1% by weight of the auxiliary components are mixed, especially the main component emulsifier is a non-ionic surfactant to gently peel off the dirt to clean the contaminants of the cleansing more, tanza extract as an auxiliary component Is a component that inhibits bacterial growth, and has an antibacterial and moisturizing effect, thus preventing skin diseases caused by contaminants that remain in the cleaned product even after washing. It is to prevent the curing phenomenon of the detergent by not added.
Description
본 발명은 세탁용 및 주방용으로 사용되는 분말세제 조성물 및 그 제조방법에 관한 것으로서, 더욱 상세하게는 일반 가정에서 의류등의 세탁시 세제에 의한 피부거침과 고급의류의 손상을 줄이고, 항균작용과 보습효과가 있기 때문에 세탁후에도 피세척물에 미세하게 남아있는 오염물로 인한 피부질환을 예방하며, 과일, 야채류, 식기등에 묻어있는 농약, 오염물, 또는 세균들을 부드럽게 벗겨내 깨끗하게 제거시킬 수 있도록 하는 동시에, 살균소독, 섬유유연작용효과, 피부보호기능과 세제의 경화현상이 방지되도록 하는 분말세제 조성물 및 그 제조방법에 관한 것이다.The present invention relates to a powder detergent composition and a method for manufacturing the same, which are used for washing and kitchen, and more particularly, to reduce skin roughness and damage to high-quality clothing by washing detergents when washing clothes, etc. Because it is effective, it prevents skin diseases caused by contaminants that remain in the cleaned objects even after washing, and gently removes pesticides, contaminants or bacteria on fruits, vegetables, and utensils, and cleans them. It relates to a powder detergent composition and a method for producing the same so that disinfection, fiber softening effect, skin protection function and curing of the detergent are prevented.
일반적으로 세제란 오염에 대한 효율적인 세정을 도와주는 혼합물질로서, 계면활성제와 조제로 구성되며, 세척을 목적으로 사용되는 계면활성제를 세척제라고 하는 등 세제의 세척작용은 주로 계면활성제의 역할에 의하는 것인데, 세제는 제조방법에 따라 비누와 합성세제로 구분되고 성분상으로 크게 나누면 음이온계 계면활성제 비누ㆍ알킬벤젠술폰산나트륨ㆍ비이온성 세제등으로 나눌 수 있다.In general, detergents are mixtures that help efficient cleaning against contamination. They consist of surfactants and preparations. The detergents used for cleaning are called detergents. The detergent is divided into soap and synthetic detergent according to the manufacturing method, and can be divided into anionic surfactant soap, alkylbenzene sodium sulfonate, and nonionic detergent.
종래에 개발되어 있는 각종 세제들은 피부에 무해한 쪽으로 개선되어 가고 있으나, 이들 세제들은 음이온 계면활성제의 유화제가 함유돼 부영양화를 발생시킴에 따라 심각한 환경오염을 초래하고, 이들 성분의 단백 변성작용에 의해 가정주부의 손이 갈라지거나 지문이 없어지는 피부염증 및 피부거침을 유발하는 등 인체에 미치는 독성이 심하며, 항균기능을 하는 세균억제성분이 부족해 세척후에도 피세척물로 인한 피부질환이 유발되고, 주요성분으로 포함되는 솔비톨은 세제의 경화현상을 촉진시켜 세제 사용자들에게 불편과 불쾌감을 초래하는 등의 문제점이 있었다. Various detergents developed in the past have been improved to be harmless to the skin, but these detergents contain emulsifiers of anionic surfactants, causing eutrophication and causing serious environmental pollution, and are assumed to be due to protein denaturation of these components. The toxic effects on the human body are severe, such as skin irritation and skin roughness, which causes cracks or fingerprints on the housewife's hands.In addition, lack of antimicrobial functions that cause antibacterial function causes skin diseases caused by cleansing products even after washing. Sorbitol included as to promote the curing phenomenon of the detergent had a problem such as causing inconvenience and discomfort to the detergent users.
상기한 바와 같은 종래의 문제점을 해결하기 위한 본 발명의 목적은 의류, 식기등의 세척시에 피부에 자극을 주지 않고, 항균작용과 보습효과가 있기 때문에세척후에도 피세척물에 미세하게 남아있는 오염물, 세균등으로 인한 피부질환을 예방하며, 기존세제와는 다르게 비이온 계면활성제의 유화제성분이 함유돼 오염물질을 부드럽게 벗겨내는 역할을 하는 동시에 음이온 계면활성제가 첨가된 기존세제와는 달리 환경오염을 유발시키지 않으며, 또한 솔비톨이 함유되지 않음으로써, 세제의 경화현상이 방지되도록 하는 분말세제 및 그 제조방법을 제공하는 것이다.An object of the present invention for solving the conventional problems as described above is that the stains remain fine in the washes even after washing because they do not irritate the skin during washing of clothes, tableware, etc., and have an antibacterial and moisturizing effect. It prevents skin diseases caused by germs, bacteria, etc. Unlike conventional detergents, it contains emulsifiers of nonionic surfactants, which gently removes contaminants and prevents environmental pollution unlike conventional detergents with anionic surfactants. It does not cause, and also does not contain sorbitol, to provide a powder detergent and a manufacturing method for preventing the curing phenomenon of the detergent.
상기한 목적을 달성하기 위한 본 발명의 실시예를 보다 상세히 설명하면 다음과 같다.When explaining the embodiment of the present invention to achieve the above object in more detail.
본 발명에 따른 분말세제 조성물은 유동성 개량제인 소다회분말 71중량%와 폴리옥시에틸렌 노닐페닐 에테르(Polyoxyethylene Nonylphenyl Ether, 이하 NP라 함) 28.4중량%를 주성분으로 하고, 보조성분으로 과탄산소다 0.2중량%와 빙초산 0.2중량%, 탱자추출물 0.1중량%, 오렌지오일 0.1중량%를 첨가하여 제조되며, 본 발명의 주성분인 소다회분말과 폴리옥시에틸렌 노닐페닐 에테르는 7:3의 비율로 혼합되는 것이 바람직하다. The powder detergent composition according to the present invention contains 71 wt% of soda ash powder, which is a fluidity improver, and 28.4 wt% of polyoxyethylene nonylphenyl ether (hereinafter referred to as NP) as a main component, and 0.2 wt% of sodium percarbonate as an auxiliary component. And 0.2% by weight glacial acetic acid, 0.1% by weight of tanza extract, 0.1% by weight of orange oil, soda ash powder and polyoxyethylene nonylphenyl ether, the main component of the present invention is preferably mixed in a ratio of 7: 3.
상기한 본 발명 분말세제의 총중량을 140.8kg으로 가정하여 본 발명의 바람직한 실시예를 살펴보면, 소다회분말 100kg , NP 40kg, 과탄산소다 0.25kg, 빙초산 0.25kg, 탱자추출물 0.15kg, 오렌지오일 0.15kg으로 구성된다.Looking at a preferred embodiment of the present invention assuming the total weight of the powder detergent of the present invention 140.8kg, soda ash powder 100kg, NP 40kg, sodium percarbonate 0.25kg, glacial acetic acid 0.25kg, tanza extract 0.15kg, orange oil 0.15kg It is composed.
상기한 세제 성분중에서 소다회(soda ash)는 탄산나트륨 무수물의 일반명칭으로 수산화나트륨(가성소다)과 함께 소다공업의 2대제품중 하나이고, 시판되고 있는 것은 2% 전후의 탄산수소나트륨ㆍ염화나트륨ㆍ물등을 함유하고 있으며, 하소로(瑕燒爐)에서 제조된 그대로의 소다회를 라이트회(light ash)또는 경회(輕灰)라고 하고 이것에 물을 끼얹어 다시 하소한 소다회를 덴스회(dense ash)또는 중회(重灰)라 한다. 본 발명의 소다회분말은 경회(輕灰)성분이며, 이와같은 소다회는 암모니아-소다법에 의하여 만들어진 탄산수소나트륨을 노(爐)에서 하소하여 이산화탄소와 물을 제거하면 생긴다. Among the above detergent components, soda ash is one of the two major products of soda industry together with sodium hydroxide (caustic soda) as a generic name of sodium carbonate anhydride, and commercially available products such as sodium bicarbonate, sodium chloride, water, etc. around 2% Containing soda ash, which is produced in a calcining furnace, is called light ash or light ash, and the soda ash calcined by pouring water on it is dense ash or It is called middle weight. Soda ash powder of the present invention is a light component, such a soda ash is produced by calcination of sodium hydrogen carbonate produced by the ammonia-soda method in the furnace to remove carbon dioxide and water.
또한 판유리ㆍ유리제품의 제조, 탄산나트륨ㆍ물유리등의 나트륨염 제조, 탄산마그네슘등의 탄산염 제조, 글루탐산나트륨등의 조미료 제조, 염료ㆍ향료ㆍ의약품ㆍ농약등 유기화합물 합성용, 양모등의 세척, 비누의 제조, 세제의 배합용, 종이ㆍ펄프제조, 고무의 재생등 용도가 대단히 넓은 것으로 알려져 있으며, 특히 반응이 완결된 세탁비누에 직접 추가됨으로써 때가 잘 빠지게 하는 비누혼합제 즉 Builder(소다회, 가성소다, 규산나트륨등)의 역할을 하게 돼 세제의 세척기능을 증진시키거나, 또는 합성세제의 혼합제로서 사용되고 있다.In addition, the production of plate glass and glass products, the production of sodium salts such as sodium carbonate and water glass, the production of carbonates such as magnesium carbonate, the preparation of seasonings such as sodium glutamate, the synthesis of organic compounds such as dyes, flavors, pharmaceuticals, pesticides, washing of wool, soap It is known to have a wide range of uses, such as the preparation of detergents, the formulation of detergents, the manufacture of paper and pulp, and the regeneration of rubber.In particular, soap mixtures, such as builders (soda ash, caustic soda, Sodium silicate, etc.) to enhance the cleaning function of the detergent, or is used as a mixture of synthetic detergents.
유화제는 비이온 계면활성제의 일종으로서 적어도 하나이상의 활성수소를 가지고 있는 지방알콜, 지방산, 알킬페놀, 알킬아민 또는 다른 화합물에 에틸렌 옥사이드 또는 프로필렌 옥사이드를 부가함으로 얻어지는 계면활성제이고, 일반적으로 계면활성제로 가장 널리 사용되는 알콜류는 탄소사슬이 C8 - C18범위의 알콜류인데, 그중 가장 널리 사용되고 있는 알킬페놀류중 범용적인 것으로는 상기한 노닐페놀과 옥틸페놀이 있으며 NP시리즈와 OP시리즈로 구분된다.Emulsifiers are a type of nonionic surfactants and are surfactants obtained by adding ethylene oxide or propylene oxide to fatty alcohols, fatty acids, alkylphenols, alkylamines or other compounds having at least one active hydrogen. Alcohols widely used are alcohols having a carbon chain in the range of C8 to C18. Among the most widely used alkylphenols are nonylphenol and octylphenol described above, and are classified into NP series and OP series.
비이온 계면활성제는 음이온 계면활성제와 달리 부영양화를 발생시키는 환경오염을 유발하지 않는데, 알콜의 일반적인 성질을 그대로 유지할 뿐만 아니라 말단그룹의 폴리에테르 사슬이 반응성을 가지고 있으므로 고몰수 부가반응, 황산염(sulfate), 술폰산염(sulfonate), 인산염(phosphate), 카르복시산염(carboxylate) 등이 가능하며 EO/PO코폴리머, 폴리에틸렌 글리콜(Polyethylene glycol)시리즈 등의 다양한 계면활성제들이 생산되고 있다.본 발명에서는 특히 비이온 계면활성제 중 NP를 사용하여 유화제로서 작용토록 함으로써, 최대의 세척효과와 피부보호 효과를 얻도록 한다.Nonionic surfactants, unlike anionic surfactants, do not cause environmental pollution, which causes eutrophication. They maintain high properties of alcohol as well as the polyether chains of the end groups, so that high molar addition reactions and sulfates , Sulfonates, phosphates, carboxylates, and the like, and various surfactants such as EO / PO copolymers and polyethylene glycol series have been produced. NP is used in the surfactant to act as an emulsifier, thereby obtaining the maximum washing effect and skin protection effect.
과탄산소다는 염소계 표백제가 주류이던 표백제 시장에 산소계 표백제로 개발된 제품으로, 일반적으로 과탄산소다(또는 PC)라 불리는데 이는 유럽시장에서 널리 사용되는 붕소를 함유한 과붕산나트륨을 줄여 PB로 부르는데 연유한다. 과탄산소다는 소다회와 과산화수소를 원료로 사용하여 제조되는 백색과립상의 제품으로 상온에서 안정한 알칼리성의 산소계 표백제이고, 가정용 의류표백제, 업소용 표백제, 세정제등에 광범위하게 사용할 수 있도록 만들어 지고 있으며, 과탄산소다의 무공해특성은 환경오염이 심각한 사회문제로 대두되고 있는 오늘날에 분말표백제의 주요원료로 주목받고 있다. Sodium percarbonate was developed as an oxygen-based bleach in the bleach market where chlorine bleach was the mainstream. It is commonly called sodium percarbonate (or PC), which is called PB by reducing boron-containing sodium perborate that is widely used in the European market. Concatenate. Sodium percarbonate is a white granular product manufactured using soda ash and hydrogen peroxide as raw materials. It is an alkaline oxygen-based bleach that is stable at room temperature, and is made to be widely used in household clothing bleach, commercial bleach, and detergent. The pollution-free property is attracting attention as the main raw material of powder bleach in today when environmental pollution is a serious social problem.
화학식 C2H4O2인 빙초산은 수분이 적고 순도가 높은 아세트산으로 아세트산은 순도가 높을 수록 녹는점이 높아지는데, 98%인 것은 13.3℃이고 순수한 것은 16.6℃이다. 따라서 순도가 높은 아세트산은 낮은 실온에서 얼음상태인 고체가 되므로 빙초산이라고 이름이 붙었으며, 빙초산은 아세틸렌과 물의 반응 또는 알코올의 공기산화에 의하여 아세트알데히드를 얻고 이것을 다시 산화시켜 얻는 무색의 액체로서 물과 대부분의 유기용매에 용해되고 수용액은 산성을 나타낸다.Glacial acetic acid of formula C 2 H 4 O 2 is acetic acid with low moisture and high purity, and acetic acid has a higher melting point with higher purity. Therefore, high-purity acetic acid is named glacial acetic acid because it becomes an ice solid at low room temperature. Glacial acetic acid is a colorless liquid obtained by acetaldehyde by oxidation of acetylene and water or by air oxidation of alcohol. Soluble in most organic solvents and aqueous solutions are acidic.
또한 용매 또는 유기화합물의 합성원료로서 약산계이고 본 발명 분말세제의 침투력을 높임과 동시에 살균소독효과를 높이는 역할을 하는데, 공업분야에 광범위하게 사용되고 있는 빙초산은 유기화합물로 초산에스터, 합성고무, 초산비닐, 정밀화학과 의약품제조의 원료등에 사용되는 물질로서 자극성의 냄새가 나며 상온(15∼16℃)에서 결빙이 되고, 물 또는 알콜, 에테르 혹은 유기물과 자유로이 혼합된다. In addition, as a synthetic raw material of a solvent or an organic compound, it is a weak acid type and increases the penetration power of the powder detergent of the present invention and at the same time plays a role of sterilizing and disinfecting effect. It is a substance used in vinyl, fine chemicals and raw materials of pharmaceutical manufacture. It has a pungent odor and freezes at room temperature (15 ~ 16 ℃), and is freely mixed with water or alcohol, ether or organic matter.
탱자열매는 장과로서 둥글고 노란색이며 9월에 익는데, 향기는 좋으나 먹지 못한다. 건위ㆍ이뇨ㆍ거담ㆍ진통 등에 약으로 쓰고, 종자는 10여개가 있으며 달걀모양이고 10월에 익는데, 중국이 원산지이고 한국(경기도 이남)에 분포한다.Tangerberry is a berry that is round and yellow and ripens in September. It smells good but cannot be eaten. It is used as medicine for dry stomach, diuresis, expectoration, pain, etc .. There are about 10 seeds, egg-shaped and ripen in October. It is native to China and distributed in Korea (South Gyeonggi Province).
상기 탱자열매로부터 추출된 탱자추출물 성분은 천연식물 추출물로서 살균작용과 항균기능이 있어 피부 가려움증을 방지하는 데 뛰어난 효과가 있으며, 또한 보습효과가 좋아 피부자극을 줄이는 동시에 피부건조, 피부거침등의 각종 피부질환을 예방할 수 있다. Tanga extract extracted from the tangja fruit is a natural plant extract has a bactericidal action and antibacterial function has an excellent effect to prevent skin itching, and also has a good moisturizing effect, while reducing the skin irritation and various skin dryness, rough skin, etc. It can prevent skin diseases.
오렌지오일은 오렌지에서 추출된 천연오렌지 오일로서 인체와 환경에 무해한 중성타입으로 기름때, 찌든때, 묵은때, 얼룩등을 빠르고 손쉽게 제거하여 산뜻한 고유색상을 재현시켜주는 식물성 세정성분인 동시에 향료 성분으로 콜라겐의 생성을 촉진시키고, 식물성오일을 이용한 것이므로 세척능력이 뛰어나며 환경친화적 세제성분으로 천연향이어서 신선하다.Orange oil is a natural orange oil extracted from orange. It is a neutral type that is harmless to humans and the environment. It is a vegetable cleansing ingredient that regenerates fresh and unique colors quickly and easily by removing oil, steam, old and stains. It promotes the production of vegetable oils, and because it uses vegetable oil, it has excellent washing ability and is a natural fragrance with an environmentally friendly detergent.
상기한 바와 같이 본 발명의 분말세제는 세척력이 강한 소다회분말과 항균작용을 하는 탱자추출물, 피부보호력이 있는 과탄산소다와 오렌지오일, 그리고 피세정체에 빠르게 침투하여 세척력을 높이는 빙초산등 대부분 식물성원료이므로 세척시 피부를 손상시키지 않는다.As described above, the powder detergent of the present invention is a vegetable raw material such as strong soda ash powder and a tanza extract having antibacterial action, soda percarbonate and orange oil having skin protection, and glacial acetic acid that quickly penetrates into the object to be cleaned. Does not damage the skin when washed.
이상과 같은 조성물질로 이루어지는 분말세제의 제조방법을 살펴보면,Looking at the manufacturing method of the powder detergent consisting of the composition as described above,
NP에 빙초산과 탱자추출물, 오렌지오일을 혼합한 후 상기 혼합된 액상에 소다회분말과 과탄산소다를 혼합시키며, 이때 소다회분말과 NP는 각각 7:3의 중량비율로 혼합되는데, 상기 혼합비율은 최대의 세척효과와 피부보호 효과를 얻을 수 있는 비율이다.After mixing glacial acetic acid, tanza extract and orange oil in NP, soda ash powder and soda percarbonate are mixed in the mixed liquid, wherein soda ash powder and NP are mixed in a weight ratio of 7: 3, respectively, and the mixing ratio is maximum. It is the ratio to get the cleaning effect and skin protection effect of.
이와같이 혼합하여 제조된 분말은 소정의 수분건조 공정을 거침으로써, 대부분 식물성 성분으로 제조된 상기 분말세제가 수분에 의하여 변질되는 것을 방지하고 최종적으로 분말에 포함된 수분을 미생물이 번식되지 않을 정도로 건조시키는 공정만을 거치면 되므로, 혼합조성물을 분말로 제조하는 별도의 공정이 필요치 않아 제조시간이 단축된다.The powder prepared by mixing in this way is subjected to a predetermined moisture drying process to prevent the powder detergent, which is mostly made of vegetable ingredients, from being deteriorated by moisture, and finally to dry the moisture contained in the powder to the extent that microorganisms do not propagate. Since only a process is required, a separate process of preparing the mixed composition as a powder is not required, thereby shortening the manufacturing time.
그리고 분말세제에 일반적으로 함유되며 경화현상을 촉진시키는 성분인 솔비톨이 첨가되지 않음으로써 분말세제의 경화현상이 방지되며, 상기 분말조성물의 원료가 대부분 식물성이므로 전체 환경오염의 70%를 차지하는 가정폐수에 의한 환경오염이 대폭 감소된다. In addition, since sorbitol, which is generally contained in powder detergent and promotes hardening, is not added, hardening of powder detergent is prevented, and since the raw material of the powder composition is mostly vegetable, it is applied to household wastewater which accounts for 70% of total environmental pollution. Environmental pollution by drastically reduced.
상기한 바와 같은 분말세제를 사용시 별도의 제제를 사용하지 않아도 세척,세균제거등 살균효과가 우수하고 항균기능이 있어 피부를 보호하며, 기존세제의 주성분인 솔비톨성분이 첨가되지 않음으로써 분말세제의 경화현상을 방지할 수 있다.When using powdered detergent as described above, it does not need to use a separate formulation, it has excellent sterilization effect such as washing and removing bacteria and protects skin with antibacterial function, and hardening of powder detergent by not adding sorbitol component which is the main ingredient of existing detergent The phenomenon can be prevented.
또한 의류세탁시 의류의 색상보존 및 선명도를 유지시키고 의류에 세제찌꺼기를 남기지 않으며, 기존세제에 함유된 발암물질인 형광증백제를 사용치 않으므로 인체에 나쁜 영향을 주지 않게 되는 효과가 있다.In addition, it preserves the color and clarity of clothing during laundry and does not leave detergent residues on clothing, and does not use a fluorescent whitening agent, a carcinogen contained in the existing detergent, so that it does not adversely affect the human body.
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| KR101064570B1 (en) * | 2010-07-15 | 2011-09-14 | 주식회사 바이오랜드 | Composition for anti-irritancy comprising the extract of sophora flavescens, cinnamomum cassia blume, saururus chinensis and poncirus trifoliata |
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| KR102536422B1 (en) * | 2020-12-17 | 2023-05-26 | 주식회사 아이엠 | Detergent Composition Having Enhanced Antibacterial Activity and Activity to Remove odors Ingrained in Fabric |
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| KR19980043149A (en) * | 1998-05-30 | 1998-08-17 | 정근식 | Facial cleanser and bath powder detergent composition and preparation method thereof |
| KR100236374B1 (en) * | 1997-10-10 | 1999-12-15 | 정근식 | Powder cleaning composition and its manufacturing method |
| JP2000096096A (en) * | 1998-07-22 | 2000-04-04 | Saniida:Kk | Environmental protection type granular washing composition |
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| KR20020028718A (en) * | 2000-10-11 | 2002-04-17 | 우강융 | Pollution-free detergent using citron and process for preparation thereof |
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| KR100236374B1 (en) * | 1997-10-10 | 1999-12-15 | 정근식 | Powder cleaning composition and its manufacturing method |
| KR19980043149A (en) * | 1998-05-30 | 1998-08-17 | 정근식 | Facial cleanser and bath powder detergent composition and preparation method thereof |
| JP2000096096A (en) * | 1998-07-22 | 2000-04-04 | Saniida:Kk | Environmental protection type granular washing composition |
| KR20010018805A (en) * | 1999-08-23 | 2001-03-15 | 성재갑 | Cosmetic compositions for anti-inflammation and anti-irritation containing ponciri fructus extracts as effective ingredients |
| KR20020028718A (en) * | 2000-10-11 | 2002-04-17 | 우강융 | Pollution-free detergent using citron and process for preparation thereof |
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| KR101064570B1 (en) * | 2010-07-15 | 2011-09-14 | 주식회사 바이오랜드 | Composition for anti-irritancy comprising the extract of sophora flavescens, cinnamomum cassia blume, saururus chinensis and poncirus trifoliata |
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