CN1087940A - A kind of multipurpose sterilizing detergent - Google Patents

A kind of multipurpose sterilizing detergent Download PDF

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Publication number
CN1087940A
CN1087940A CN 93117915 CN93117915A CN1087940A CN 1087940 A CN1087940 A CN 1087940A CN 93117915 CN93117915 CN 93117915 CN 93117915 A CN93117915 A CN 93117915A CN 1087940 A CN1087940 A CN 1087940A
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detergent composition
sterilant
composition according
starso
composition comprises
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CN 93117915
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CN1030227C (en
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柏绿山
杨秀莉
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Abstract

The invention provides a kind of efficient, nontoxic, sterilization multi-purpose washing agent composition, said composition comprises nonionogenic tenside, alkaline carbonate, alkali metal silicate, alkali metal sulfates, alkali metal percarbonate, basic metal carboxymethyl cellulose salt, alkali-metal gluconate or Citrate trianion.Said detergent composition not only can be used for laundry and also can be used for wash dining set, vegetables and fruit.

Description

A kind of multipurpose sterilizing detergent
It is clean to the present invention relates to the washing of a kind of multipurpose sterilizing, specifically, the present invention relates to nontoxic, the sterilization of nuisances such as a kind of not phosphorous, white dyes, Phenylsulfonic acid, benzene sulfonic acid sodium salt, aluminium, multiduty detergent composition.
At present commercially available washing powder be the non-phosphide detergent of one of its raw material production just like the phosphorous washing powder of producing as one of its raw material with phosphoric acid salt with the 4A zeolite, these washing powder all contain white dyes and alkane sulfonate, make sterilant with dichloro or trichlorine sodium isocyanate.
Being taken away by rinse water in environment and the deleterious chemical ingredients major part of people in the washing powder, small portion remains on the clothing.Its phosphorous rinse water inflow rivers and lakes will destroy the oxygen part in the water, and the generation that jeopardizes organism in water and microorganism brings potentially dangerous to the eubiosis.Residue in the phosphorus on the fabric, people's skin is constituted a threat to, the oxygen that their can absorptive hair lyriform pore, unfavorable in skin health.And behind the intrusion of the sodium alkyl benzene sulfonate wherein human body, amylase, pancreatin, gastric enzyme, pepsic activity are had very strong restraining effect, and in the liver accumulation, the infringement liver function.Have following harm with the 4A zeolite again as the washing powder of one of its raw material: well-known, the 4A zeolite is a kind of aluminate, make washing powder with it and must consume a large amount of aluminium every year, and be a kind of great consumption to bauxite resource undoubtedly.On the other hand, these bauxite resource major parts of consumption are taken away the inflow rivers,lakes and seas by rinse water, and the edible for a long time this aluminium water that contains of people can get numerous disease.
On the other hand, 4A zeolite itself is again a kind of water-fast material, pierces fabric fibre inside in the washing process and exists with the powder form, and these powders or micro mist grain can make clothing wash harder and harder.In addition, under charge effect, wherein a large amount of particulates will be adsorbed on the tube wall of sewage effluent, cause the powder dirt, stop up sewer line.
Because phosphoric acid salt has stronger ramollescence to water, is that other material is irreplaceable so people it is generally acknowledged this effect.We find through a large amount of experiments, there are many materials that the metal ion in the water is all had good chelating ability, Sunmorl N 60S and Trisodium Citrate then are representatives wherein, be surprisingly found out that especially in free base solution, Sunmorl N 60S has unhoped-for chelating ability, experiment shows, but 200 milligrams of lime carbonate of 10g Sunmorl N 60S chelating, and it is also extremely strong to chelated iron ionic ability, and be not subjected to the influence of pH value, hence one can see that, and Sunmorl N 60S is better than phosphoric acid salt greatly to the water softening effect.
Though the ability of Starso softening water is a little less than tripoly phosphate sodium STPP, other performances are better than the latter, owing to used Sunmorl N 60S, so the effect of softening water also is better than tripoly phosphate sodium STPP, its over-all properties is better than known phosphorous washing powder greatly.
The sterilant that uses in existing washing powder mostly is dichloro or sodium trichloro-isocyanurate, and not only sterilization effect is undesirable and polluted water also for chloride type or contain oxygen type sterilant, these sterilant.
Because known washing powder contains above-mentioned objectionable impurities, thus can not be used for wash dining set, vegetables and fruit, its rinse water are contaminate environment again.
The purpose of this invention is to provide a kind of environmentally safe, harmless efficient multi-purpose washs clean composition.
Another object of the present invention provides a kind of and is used to prepare the high effect nontoxic bactericidal washing powder and is combined in thing.
A further object of the present invention provides a kind of detergent composition that is used to prepare high effect nontoxic, disinfecting scrub tableware, vegetables, fruit etc.
The detergent composition of one of embodiment of the present invention comprises nonionogenic tenside, alkaline carbonate, alkali metal silicate, alkali metal percarbonate, alkali-metal carboxymethyl cellulose, alkali-metal gluconate or Citrate trianion, sterilant.
The cleaning composition of another embodiment of the present invention comprises, nonionogenic tenside, yellow soda ash, Starso, SPC-D, Xylo-Mucine, Sunmorl N 60S or Trisodium Citrate, sterilant.
The present invention again the detergent composition of an embodiment comprise, nonionogenic tenside, yellow soda ash, meta-acid sodium, SPC-D, Xylo-Mucine, Sunmorl N 60S or Trisodium Citrate, sodium bicarbonate, soap powder, spices, sterilant.
The detergent composition of the preferred embodiment of the invention comprises nonionogenic tenside 8-15%, yellow soda ash 10-25%, Starso 8-25%, SPC-D 8-15%, Xylo-Mucine 0.5-2%, Sunmorl N 60S (or Trisodium Citrate) 2-8%, sodium bicarbonate 3-10%, soap powder 2-5%, an amount of, the sterilant 0.1-1% of spices.
The present invention more preferably detergent composition of embodiment comprises nonionogenic tenside 8-15%, yellow soda ash 15-20%, Starso 15-23%, SPC-D 8-15%, sodium bicarbonate 3-10%, solvable SiO 22-3%, Trisodium Citrate or Sunmorl N 60S 5-18%, carboxymethyl cellulose sodium 1-2%, soap powder 2-5%, an amount of, the sterilant 0.1-1% of spices.It is 1.4 that the decontamination value of the washing composition that makes by the composition of the present embodiment is counted correlative value, is that under 2% the concentration, acting on 5 minutes kill ratios is 100% to the sterilization effect of intestinal bacteria, golden yellow grape bacillus, pseudomonas aeruginosa.
The detergent composition of another preferred embodiment of the present invention comprises: nonionogenic tenside 13-15%, yellow soda ash 15%, Starso 25%, SPC-D 10-15%, sodium bicarbonate 5-10%, solvable SiO 23%, an amount of, the sterilant 0.5% of Sunmorl N 60S 5%, its sodium cellulosate 2% of carboxylic first, spices, soap powder 3-5%.
The decontamination value number of the detergent compositions that makes by the composition of the present embodiment is 1.4, to the sterilization effect of intestinal bacteria, golden yellow grape bacillus, pseudomonas aeruginosa (under 2% concentration, acting on 5 minutes) sterilizing rate is 100%, is 99.6% to the killing rate in the anti-source of HBS.
Other has except the explanation, and all per-cents all are weight percentage in this specification sheets.
Term " sterilant " is a chlorine oxygen composite bactericide, notes by abridging to be chlorine oxygen type sterilant, promptly adds the preferred 48-50 of 45-52(in oronain B and/or oronain T) %NH 4Cl or (NH 4) 2SO 4Composite and get, oronain B and oronain T can buy from the market.
Term " soap powder " is preparation soap or a perfumed soap former process powder in the affiliated field.
Term " spices " is a conventional material in this area.
Employed Starso makes the PH that is in the suds very little with the material concentration variation in the present composition, so Starso is a kind of good buffer reagent; Starso has suspension and dispersive ability to dirt, and grease is had emulsifying effect, helps preventing soil redeposition; Starso can remove the middle molysite that anhydrates, and the effect of softening water is arranged, and makes throw out be difficult for precipitating on fabric, is easy to rinsing, and this is to use the washing powder laundering of textile fabrics of preparation of compositions of the present invention to wash one of white more reason more.Though the PH of Starso itself is very high, but a large amount of experiments are found unexpectedly, Starso is fragile fiber unlike other alkaline matters, the existence of Starso also makes fabric keep very high intensity, and this washing powder that also is to use composition of the present invention to make has one of good feel reason.
Chlorine oxygen type sterilant sterilization effect used in the present invention is better than usual dichloro or the trichlorine sodium isocyanate sterilant sterilizing ability that uses, and is about 50-100 times of the latter, is about 50 times of oronain type sterilant, and the fast 30-50 of its sterilization speed doubly.As add trichlorine sodium isocyanate 3% in the Fen of doing washing, and under 2% concentration, acting on golden yellow grape bacillus, pseudomonas aeruginosa, intestinal bacteria 5 minutes, killing rate is 99.6%; As in washing powder, adding " C 10" type (chlorine oxygen type sterilant) 0.3%, under 2% concentration, acting on above-mentioned bacterium 3 minutes, killing rate is 100%; As in washing powder, adding oronain B1%, under 2% concentration, act on above-mentioned same bacterium 5 minutes, killing rate is 99.8%.This shows the present invention " C 10" sterilization effect the best of type sterilant.
According to the preparation technology's of detergent composition of the present invention example as shown in the figure.
With the detergent raw material of prescription, as nonionogenic tenside, anion surfactant, spices equal the tablets press host machine part and add.Sterilant, enzyme-added powder, soap powder etc. add in little batch bin.In addition, all raw materials are sent into mixing machine through conveyor 2 after preparing burden by prescription, and thorough mixing is after lift 4 is sent into powder storehouse 5.Powder flow meter 6, main frame flat belt 7, belt elevator machine 8 are sent into little static mixer with liquid (nonionogenic tenside etc.) the atomizing granulation after 20,21 meterings through conveyor 10 after sending into tablets press 9.Little batchings such as sterilant, enzyme-added powder, soap powder enter little feed bin through lift 15, after under meter 14 batching by conveyor send into little static mixer 11 with main powder static mixing washing powder.
Those of ordinary skill in the field can carry out various changes and modification within the scope of the present invention, but these changes and revising all within the claim protection domain that application etc. is criticized.

Claims (8)

1, a kind of high effect nontoxic desinfactant detergent composition, it is characterized in that said composition comprises nonionogenic tenside, alkaline carbonate, alkali metal silicate, alkali metal percarbonate, alkali-metal carboxymethyl cellulose, alkali-metal gluconate or Citrate trianion, sterilant.
2, a kind of detergent composition according to claim 1, it is characterized in that: said cleaning composition comprises, nonionogenic tenside, yellow soda ash, Starso, SPC-D, Xylo-Mucine, Sunmorl N 60S or Trisodium Citrate, sterilant.
3, a kind of detergent composition according to claim 2 is characterized in that: said detergent composition comprises, sodium bicarbonate, soap powder, spices.
4, a kind of detergent composition according to claim 1 is characterized in that said sterilant is that oronain B and/or oronain T add 45-52% ammonium chloride or ammonium sulfate is composite and forms.
5, a kind of detergent composition according to claim 4 is characterized in that: to be that oronain B or oronain T add 48-50% ammonium chloride or ammonium sulfate is composite form said sterilant.
6, a kind of detergent composition according to claim 4 or 5, it is characterized in that: said detergent composition comprises nonionogenic tenside 8-15%, yellow soda ash 10-25%, Starso 8-25%, SPC-D 8-15%, Xylo-Mucine 0.5-2%, Sunmorl N 60S (or Trisodium Citrate) 2-8%, sodium bicarbonate 3-10%, soap powder 2-5%, an amount of, the sterilant 0.1-1% of spices.
7, a kind of detergent composition according to claim 6 is characterized in that: said detergent composition comprises, yellow soda ash 15-20%, Starso 15-23%, sodium bicarbonate 3-10%, solvable SiO 22-3%, Trisodium Citrate 5-18%, carboxymethyl cellulose sodium 1-2%, soap powder 2-5%, an amount of, the sterilant 0.1-1% of spices.
8, a kind of detergent composition according to claim 4 or 5, it is characterized in that: said detergent composition comprises: nonionogenic tenside 13-15%, yellow soda ash 15%, Starso 25%, SPC-D 10-15%, sodium bicarbonate 10-15%, solvable SiO 23%, Sunmorl N 60S 5%, Xylo-Mucine 2%, an amount of, the sterilant 0.5% of spices.Soap powder 3-5%.
CN 93117915 1993-10-07 1993-10-07 Multipurpose sterilizing detergent Expired - Fee Related CN1030227C (en)

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Application Number Priority Date Filing Date Title
CN 93117915 CN1030227C (en) 1993-10-07 1993-10-07 Multipurpose sterilizing detergent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 93117915 CN1030227C (en) 1993-10-07 1993-10-07 Multipurpose sterilizing detergent

Publications (2)

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CN1087940A true CN1087940A (en) 1994-06-15
CN1030227C CN1030227C (en) 1995-11-08

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CN 93117915 Expired - Fee Related CN1030227C (en) 1993-10-07 1993-10-07 Multipurpose sterilizing detergent

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102965205A (en) * 2012-10-19 2013-03-13 大连碧城环保科技有限公司 Cleaning agent for seafood meshes
CN104962403A (en) * 2015-06-08 2015-10-07 苏州东辰林达检测技术有限公司 Food cleaning compound and preparation method thereof
CN106190671A (en) * 2016-07-04 2016-12-07 李汉辉 Tableware dipping powder
CN106381247A (en) * 2015-12-07 2017-02-08 蒋宏凯 Cleaning agent and preparation method thereof
CN106833914A (en) * 2017-01-25 2017-06-13 王敏芳 A kind of stain removal bactericidal agent based on small-micelle water
CN107216953A (en) * 2017-05-25 2017-09-29 曹平 A kind of antistatic laundry care agent
CN107384617A (en) * 2017-07-22 2017-11-24 温州裕辉新材料科技有限公司 Low temperature high performance surface degreasing powder and preparation method thereof
CN111655832A (en) * 2018-03-02 2020-09-11 花王株式会社 Mildew-removing cleaning agent composition for hard surface

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101597547B (en) * 2009-05-21 2012-07-04 陈安友 Phosphate-free environment-friendly cleaning agent

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102965205A (en) * 2012-10-19 2013-03-13 大连碧城环保科技有限公司 Cleaning agent for seafood meshes
CN104962403A (en) * 2015-06-08 2015-10-07 苏州东辰林达检测技术有限公司 Food cleaning compound and preparation method thereof
CN106381247A (en) * 2015-12-07 2017-02-08 蒋宏凯 Cleaning agent and preparation method thereof
CN106190671A (en) * 2016-07-04 2016-12-07 李汉辉 Tableware dipping powder
CN106833914A (en) * 2017-01-25 2017-06-13 王敏芳 A kind of stain removal bactericidal agent based on small-micelle water
CN107216953A (en) * 2017-05-25 2017-09-29 曹平 A kind of antistatic laundry care agent
CN107384617A (en) * 2017-07-22 2017-11-24 温州裕辉新材料科技有限公司 Low temperature high performance surface degreasing powder and preparation method thereof
CN111655832A (en) * 2018-03-02 2020-09-11 花王株式会社 Mildew-removing cleaning agent composition for hard surface

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