CN107384617A - Low temperature high performance surface degreasing powder and preparation method thereof - Google Patents
Low temperature high performance surface degreasing powder and preparation method thereof Download PDFInfo
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- CN107384617A CN107384617A CN201710604750.3A CN201710604750A CN107384617A CN 107384617 A CN107384617 A CN 107384617A CN 201710604750 A CN201710604750 A CN 201710604750A CN 107384617 A CN107384617 A CN 107384617A
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of low temperature high performance surface degreasing powder and preparation method thereof.The low temperature high performance surface degreasing powder includes the component of following parts by weight:25 parts of silicate, 12 18 parts of percarbonate, 15 20 parts of sodium carbonate, 8 15 parts of sodium gluconate.Beneficial effects of the present invention:In such as 25 DEG C of low temperature environment, the low temperature high performance surface degreasing powder still has good deoiling effect, without carrying out heating operation, so as to reduce the loss of the energy, increase the convenience of removal operation.
Description
Technical field
The present invention relates to degreasing powder, more particularly to a kind of low temperature high performance surface degreasing powder and preparation method thereof.
Background technology
It is one of important procedure in industry that cleaning is carried out to workpiece.Workpiece is cleaned primarily directed to some heavy oil in industry
The cleaning of stain workpiece, it directly influences the use function and aesthetic property of workpiece.Some heavy oil stain workpiece are all using organic at present
Solvent is cleaned, but due to organic solvent component, content and preparation method the defects of, easily have to health larger
Influence.
Degreasing powder is to be removed using refined low bubbles formed such as a variety of high-quality surfactants, detergent, bleeding agent, builders
Oily degreasing agent, there is the abilities such as good wetting, emulsification, there is stronger ability of deoiling.Workpiece surface after cleaning is without visible oil
Film or oil mark.It is mainly used in the cleaning of the alloy materials such as aluminium alloy, kirsite, magnesium alloy to degreaser, to workpiece not damaged
Phenomenon.
Publication No. CN104451752A Chinese patent discloses a kind of degreasing powder for cleaning heavy oil stain and its preparation side
Method.The deoiling effect of the degreasing powder is stronger, and service life is longer, improves the technological difficulties of counterweight oil stain multiple working procedure cleaning, has
Effect improves operating efficiency.
But from embodiment it was found from, the degreasing powder needs to be used in temperature is 80 DEG C or so of environment.Change
Yan Zhi, it is necessary to which the cleaning fluid that degreasing powder is configured to is heated to 80 DEG C or so when using the degreasing powder, it can reach preferable
Deoiling effect.And the loss that this undoubtedly needs to increase the energy.As common knowledge, with the rise of temperature, degreasing powder removes
Oily effect is typically stronger.Therefore, how preferable deoiling effect is maintained in such as 25 DEG C of low temperature environment, is urgently
Solve the problems, such as.
The content of the invention
It is an object of the invention to provide a kind of low temperature high performance surface degreasing powder.In such as 25 DEG C of low temperature environment, this is low
Temperature high-performance surface degreasing powder still has good deoiling effect, without carrying out heating operation, so as to reduce the loss of the energy,
Increase the convenience of removal operation.
The present invention above-mentioned technical purpose technical scheme is that:
A kind of low temperature high performance surface degreasing powder, include the component of following parts by weight:
Silicate 2-5 parts
Percarbonate 12-18 parts
Sodium carbonate 15-20 parts
Sodium gluconate 8-15 parts.
By using above-mentioned technical proposal, silicate has the distinctive property of softening, dispersiveness, suspension and inorganic emulsibility
With the strong attraction to greasy dirt.Percarbonate is the additive compound of carbonate and hydrogen peroxide, white particulate powder, water
Solution alkaline.Percarbonate can be decomposed into sodium carbonate and hydrogen peroxide in water, hydrogen peroxide continue to be decomposed into again water and
Oxygen.SODIUM PERCARBONATE is the unstable compound formed by sodium carbonate, hydrogen peroxide and water three compositions system using hydrogen bond,
Easily decompose at high temperature.Sodium carbonate has stronger alkalescence, can promote the saponification of grease.Sodium gluconate is a kind of metal
The highly effective chelating agent of surface treatment, it can be used in chelating the metal ions such as calcium, magnesium, softening of water.
The present invention is further arranged to:According to parts by weight, in addition to spaonin powder 15-20 parts.
By using above-mentioned technical proposal, spaonin powder is gleditsia sinensis grinds.Gleditsia sinensis is the peculiar hungry Caesalpiniaceae Chinese honey locust in China
Belong to one of seeds.The main chemical compositions of gleditsia sinensis are Gleditschiasaponin, palmitic acid, stearic acid, oleic acid.Spaonin powder is a kind of plant table
Face activating agent.Metal deoiling after spaonin powder is handled, blast is polished after plating.Using spaonin powder to metal surface without appoint
What corrodes.
The present invention is further arranged to:According to parts by weight, in addition to ethylenediamine oleate 15-20 parts.
By using above-mentioned technical proposal, ethylenediamine oleate belongs to nonionic surfactant, with other surfaces activity
Agent compatibility is good, and dissolving power is strong, does not produce oil slick, has certain deoiling effect, more preferably, persistence is longer for rust-proof effect.
The present invention is further arranged to:The silicate selects sodium metasilicate.
By using above-mentioned technical proposal, because the cation in sodium carbonate, grape grape acid sodium is sodium ion, therefore select
Bringing into for variety classes cation can be reduced with sodium metasilicate.It is water-soluble preferable meanwhile the ionic radius of sodium ion is smaller.
The present invention is further arranged to:The percarbonate selects SODIUM PERCARBONATE.
By using above-mentioned technical proposal, because the cation in sodium carbonate, grape grape acid sodium is sodium ion, therefore select
Bringing into for variety classes cation can be reduced with SODIUM PERCARBONATE.It is water-soluble preferable meanwhile the ionic radius of sodium ion is smaller.
Another goal of the invention of the present invention is to provide a kind of preparation method of low temperature high performance surface degreasing powder, including as follows
Step:According to parts by weight, silicate 2-5 parts, percarbonate 12-18 parts, sodium carbonate 15-20 parts, sodium gluconate 8-15 are weighed
Part, spaonin powder 15-20 parts, ethylenediamine oleate 15-20 parts, it is well mixed.
By using above-mentioned technical proposal, each component is sufficiently mixed, the low temperature with good deoiling effect is prepared
High performance surface degreasing powder.
In summary, the invention has the advantages that:
1st, the present invention can have good deoiling effect under such as 25 DEG C of low temperature environment, without carrying out heating operation, so as to
The loss of the energy is reduced, increases the convenience of removal operation;
2nd, SODIUM PERCARBONATE can produce oxygen in water, so as to realize the oxidation Decomposition to grease, promote the dissolving of grease;
3rd, spaonin powder and ethylenediamine oleate are used in conjunction with, and can cooperate with enhancing deoiling effect.
Embodiment
Embodiment 1
A kind of low temperature high performance surface degreasing powder, include the component of following parts by weight:
2 parts of sodium metasilicate, 18 parts of SODIUM PERCARBONATE, 20 parts of sodium carbonate, 8 parts of sodium gluconate, 16 parts of spaonin powder, ethylenediamine oleate 20
Part.
A kind of preparation method of low temperature high performance surface degreasing powder, comprises the following steps:
According to parts by weight, 2 parts of sodium metasilicate, 18 parts of SODIUM PERCARBONATE, 20 parts of sodium carbonate, 8 parts of sodium gluconate, spaonin powder 16 are weighed
Part, 20 parts of ethylenediamine oleate, it is well mixed.
Embodiment 2
A kind of low temperature high performance surface degreasing powder, include the component of following parts by weight:
4 parts of sodium metasilicate, 17 parts of SODIUM PERCARBONATE, 19 parts of sodium carbonate, 10 parts of sodium gluconate, 17 parts of spaonin powder, ethylenediamine oleate
15 parts.
A kind of preparation method of low temperature high performance surface degreasing powder, comprises the following steps:
According to parts by weight, 4 parts of sodium metasilicate, 17 parts of SODIUM PERCARBONATE, 19 parts of sodium carbonate, 10 parts of sodium gluconate, spaonin powder 17 are weighed
Part, 15 parts of ethylenediamine oleate, it is well mixed.
Embodiment 3
A kind of low temperature high performance surface degreasing powder, include the component of following parts by weight:
3 parts of sodium metasilicate, 16 parts of SODIUM PERCARBONATE, 15 parts of sodium carbonate, 12 parts of sodium gluconate, 18 parts of spaonin powder, ethylenediamine oleate
16 parts.
A kind of preparation method of low temperature high performance surface degreasing powder, comprises the following steps:
According to parts by weight, 3 parts of sodium metasilicate, 16 parts of SODIUM PERCARBONATE, 15 parts of sodium carbonate, 12 parts of sodium gluconate, spaonin powder 18 are weighed
Part, 16 parts of ethylenediamine oleate, it is well mixed.
Embodiment 4
A kind of low temperature high performance surface degreasing powder, include the component of following parts by weight:
5 parts of sodium metasilicate, 15 parts of SODIUM PERCARBONATE, 16 parts of sodium carbonate, 15 parts of sodium gluconate, 15 parts of spaonin powder, ethylenediamine oleate
18 parts.
A kind of preparation method of low temperature high performance surface degreasing powder, comprises the following steps:
According to parts by weight, 5 parts of sodium metasilicate, 15 parts of SODIUM PERCARBONATE, 16 parts of sodium carbonate, 15 parts of sodium gluconate, spaonin powder 15 are weighed
Part, 18 parts of ethylenediamine oleate, it is well mixed.
Embodiment 5
A kind of low temperature high performance surface degreasing powder, include the component of following parts by weight:
3 parts of sodium metasilicate, 18 parts of SODIUM PERCARBONATE, 17 parts of sodium carbonate, 11 parts of sodium gluconate, 20 parts of spaonin powder, ethylenediamine oleate
19 parts.
A kind of preparation method of low temperature high performance surface degreasing powder, comprises the following steps:
According to parts by weight, 3 parts of sodium metasilicate, 18 parts of SODIUM PERCARBONATE, 17 parts of sodium carbonate, 11 parts of sodium gluconate, spaonin powder 20 are weighed
Part, 19 parts of ethylenediamine oleate, it is well mixed.
Embodiment 6
A kind of low temperature high performance surface degreasing powder, include the component of following parts by weight:
3 parts of sodium metasilicate, 16 parts of SODIUM PERCARBONATE, 15 parts of sodium carbonate, 12 parts of sodium gluconate.
A kind of preparation method of low temperature high performance surface degreasing powder, comprises the following steps:
According to parts by weight, 3 parts of sodium metasilicate, 16 parts of SODIUM PERCARBONATE, 15 parts of sodium carbonate, 12 parts of sodium gluconate are weighed, is well mixed
.
Comparative example 1
From the embodiment 1 as a comparison case 1 of Publication No. CN104451752A Chinese patent.
Comparative example 2
Difference with embodiment 3 is, changes ethylenediamine oleate into trihydroxy ethylamine oleate soap, other are same as Example 3.
Comparative example 3
Difference with embodiment 3 is, removes spaonin powder, other are same as Example 3.
Comparative example 4
Difference with embodiment 3 is, changes ethylenediamine oleate into trihydroxy ethylamine oleate soap and removes spaonin powder, other with
Embodiment 3 is identical.
Except oil test
By ready stainless steel test piece, hung up properly, be placed in constant temperature oven with hook, control temperature as 130 ± 2 DEG C of baking 20min
Cooling is weighed afterwards, the degree of accuracy to 0.0001g, and the test piece after weighing is absorbed into artificial greasy dirt with small pieces uniformly coats, and will coat
The test piece of oil is hung up properly with hook, is put into constant temperature oven, and temperature control is dried 2 hours at 130 ± 2 DEG C, is weighed after taking out cooling 8h.
In 500mL beakers, the degreasing powder according to embodiment 1-6 and comparative example 1-4 preparations is configured to 3wt% concentration
The cleaning fluid of (15g → 500ml).It is 25 DEG C to control temperature, and the test piece for coating oil is placed in cleaning fluid, and then pendulum is washed 5 minutes,
Pendulum takes out after washing and rinsed well, is put into 130 ± 2 DEG C of thermostatic drying chamber and dries 20 minutes, is weighed after cooling, calculates oil removing
Rate.
Calculate:X1=(m1-m2)/(m1-m0) × 100%
In formula:X1- is oil removal rate/%;M0- is quality/g of test piece;M1- is test piece quality/g after oiling;After m2- is cleaning
Test piece quality/g.
The embodiment 1-6 of table 1 and comparative example 1-4 oil removal rate record sheets
It can be drawn from table 1 to draw a conclusion:
Oil removal rate/% | |
Embodiment 1 | 93.21 |
Embodiment 2 | 95.54 |
Embodiment 3 | 97.64 |
Embodiment 4 | 93.21 |
Embodiment 5 | 92.16 |
Embodiment 6 | 75.34 |
Comparative example 1 | 67.34 |
Comparative example 2 | 83.42 |
Comparative example 3 | 80.14 |
Comparative example 4 | 80.17 |
Comparative example 1-6 and comparative example 1 understand that embodiment 1-6 oil removal rate is all higher than comparative example 1, it is seen that the present invention is right
In being superior to comparative example 1 on the removal capacity of greasy dirt.
Comparative example 3 and comparative example 2-4 understand that, compared to embodiment 3, comparative example 2-4 oil removal rate is smaller.Its
In, the oil removal rate of comparative example 2 is more than comparative example 3 and comparative example 4, and comparative example 3 is equal with the oil removal rate of comparative example 4.Therefore, it is single
Solely change trihydroxy ethylamine oleate soap into ethylenediamine oleate, the oil removing performance of degreasing powder is constant.Individually increase spaonin powder, degreasing powder
Oil removing performance increase.But when changing trihydroxy ethylamine oleate soap into ethylenediamine oleate simultaneously and increasing spaonin powder, oil removing
Performance can further enhance.As can be seen here, ethylenediamine oleate and spaonin powder be used in conjunction with can further lift oil removing
Performance.
This specific embodiment is only explanation of the invention, and it is not limitation of the present invention, people in the art
Member can make the modification of no creative contribution to the present embodiment as needed after this specification is read, but as long as at this
All protected in the right of invention by Patent Law.
Claims (6)
1. a kind of low temperature high performance surface degreasing powder, it is characterized in that:Include the component of following parts by weight:
Silicate 2-5 parts
Percarbonate 12-18 parts
Sodium carbonate 15-20 parts
Sodium gluconate 8-15 parts.
2. low temperature high performance surface degreasing powder according to claim 1, it is characterized in that:According to parts by weight, in addition to gleditsia sinensis
Powder 15-20 parts.
3. low temperature high performance surface degreasing powder according to claim 1, it is characterized in that:According to parts by weight, in addition to second two
Amine oleate 15-20 parts.
4. low temperature high performance surface degreasing powder according to claim 1, it is characterized in that:The silicate selects sodium metasilicate.
5. low temperature high performance surface degreasing powder according to claim 1, it is characterized in that:The percarbonate selects percarbonic acid
Sodium.
6. a kind of preparation method of low temperature high performance surface degreasing powder, it is characterized in that:Comprise the following steps:According to parts by weight, claim
Take silicate 2-5 parts, percarbonate 12-18 parts, sodium carbonate 15-20 parts, sodium gluconate 8-15 parts, spaonin powder 15-20 parts, second
Diamines oleate 15-20 parts, it is well mixed.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107815691A (en) * | 2017-12-20 | 2018-03-20 | 苏州德菱化学品有限公司 | A kind of aluminium workpiece surface nano aperture processing method for nanometer injection |
CN108485847A (en) * | 2018-05-05 | 2018-09-04 | 深圳市竑鎏电子表面处理科技有限公司 | A kind of room temperature degreasing powder |
CN111057619A (en) * | 2019-12-16 | 2020-04-24 | 青岛中科润美润滑材料技术有限公司 | Cleaning agent for needle threading, coking and carbon deposition of artificial board equipment |
CN112143576A (en) * | 2020-10-21 | 2020-12-29 | 湖南澳美佳健康科技有限公司 | Production process of sodium bicarbonate cleanser without damaging skin |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107815691A (en) * | 2017-12-20 | 2018-03-20 | 苏州德菱化学品有限公司 | A kind of aluminium workpiece surface nano aperture processing method for nanometer injection |
CN108485847A (en) * | 2018-05-05 | 2018-09-04 | 深圳市竑鎏电子表面处理科技有限公司 | A kind of room temperature degreasing powder |
CN108485847B (en) * | 2018-05-05 | 2020-10-20 | 深圳市竑鎏电子表面处理科技有限公司 | Normal-temperature oil removing powder |
CN111057619A (en) * | 2019-12-16 | 2020-04-24 | 青岛中科润美润滑材料技术有限公司 | Cleaning agent for needle threading, coking and carbon deposition of artificial board equipment |
CN111057619B (en) * | 2019-12-16 | 2021-07-30 | 青岛中科润美润滑材料技术有限公司 | Cleaning agent for needle threading, coking and carbon deposition of artificial board equipment |
CN112143576A (en) * | 2020-10-21 | 2020-12-29 | 湖南澳美佳健康科技有限公司 | Production process of sodium bicarbonate cleanser without damaging skin |
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Application publication date: 20171124 |