CN1102207A - High-grade specific bactericidal and detoxicating washing powder - Google Patents
High-grade specific bactericidal and detoxicating washing powder Download PDFInfo
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- CN1102207A CN1102207A CN 94116784 CN94116784A CN1102207A CN 1102207 A CN1102207 A CN 1102207A CN 94116784 CN94116784 CN 94116784 CN 94116784 A CN94116784 A CN 94116784A CN 1102207 A CN1102207 A CN 1102207A
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- sodium
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- powder
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- 238000005406 washing Methods 0.000 title claims abstract description 35
- 239000000843 powder Substances 0.000 title claims abstract description 20
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims abstract description 5
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims abstract 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 5
- 229920002472 Starch Polymers 0.000 claims description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 4
- 239000004202 carbamide Substances 0.000 claims description 4
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 238000012856 packing Methods 0.000 claims description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 4
- 235000019353 potassium silicate Nutrition 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 235000017550 sodium carbonate Nutrition 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 4
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 3
- 238000005054 agglomeration Methods 0.000 claims description 3
- 230000002776 aggregation Effects 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 229930182490 saponin Natural products 0.000 claims description 3
- 150000007949 saponins Chemical class 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- 230000003068 static effect Effects 0.000 claims description 3
- 241001122767 Theaceae Species 0.000 claims description 2
- 230000032683 aging Effects 0.000 claims description 2
- 238000007599 discharging Methods 0.000 claims description 2
- 238000005469 granulation Methods 0.000 claims description 2
- 230000003179 granulation Effects 0.000 claims description 2
- 235000011837 pasties Nutrition 0.000 claims description 2
- 238000010298 pulverizing process Methods 0.000 claims description 2
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 2
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 claims description 2
- 238000005303 weighing Methods 0.000 claims description 2
- WLYIIDKKPCXCLS-UHFFFAOYSA-N 3,4,5-tribromo-2-hydroxy-n-phenylbenzamide Chemical compound OC1=C(Br)C(Br)=C(Br)C=C1C(=O)NC1=CC=CC=C1 WLYIIDKKPCXCLS-UHFFFAOYSA-N 0.000 claims 1
- ZMUQGGLSCIDPLS-UHFFFAOYSA-N Saponin 5 Natural products COC(=O)C1(C)CCC2(CCC3(C)C(=CCC4C5(C)CCC(OC6OC(CO)C(O)C(O)C6OC7OC(CO)C(O)C(O)C7OC8OC(C)C(O)C(O)C8O)C(C)(C)C5CCC34C)C2C1)C(=O)O ZMUQGGLSCIDPLS-UHFFFAOYSA-N 0.000 claims 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims 1
- DJGAAPFSPWAYTJ-UHFFFAOYSA-M metamizole sodium Chemical compound [Na+].O=C1C(N(CS([O-])(=O)=O)C)=C(C)N(C)N1C1=CC=CC=C1 DJGAAPFSPWAYTJ-UHFFFAOYSA-M 0.000 claims 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 abstract description 7
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical class [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 abstract 1
- 238000004659 sterilization and disinfection Methods 0.000 description 16
- 230000001954 sterilising effect Effects 0.000 description 13
- 230000000694 effects Effects 0.000 description 9
- 239000013543 active substance Substances 0.000 description 8
- 239000000427 antigen Substances 0.000 description 5
- 102000036639 antigens Human genes 0.000 description 5
- 108091007433 antigens Proteins 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000002574 poison Substances 0.000 description 4
- 231100000614 poison Toxicity 0.000 description 4
- 241000700605 Viruses Species 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- 241000700721 Hepatitis B virus Species 0.000 description 2
- 241000709721 Hepatovirus A Species 0.000 description 2
- 230000009849 deactivation Effects 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 230000002147 killing effect Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 235000017709 saponins Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000003206 sterilizing agent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000271 synthetic detergent Substances 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 241000709661 Enterovirus Species 0.000 description 1
- 241000710198 Foot-and-mouth disease virus Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000295644 Staphylococcaceae Species 0.000 description 1
- 108010067390 Viral Proteins Proteins 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000000539 amino acid group Chemical group 0.000 description 1
- 230000036592 analgesia Effects 0.000 description 1
- 230000001093 anti-cancer Effects 0.000 description 1
- 230000003110 anti-inflammatory effect Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 244000144987 brood Species 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- SQEDZTDNVYVPQL-UHFFFAOYSA-N dodecylbenzene;sodium Chemical compound [Na].CCCCCCCCCCCCC1=CC=CC=C1 SQEDZTDNVYVPQL-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 208000005252 hepatitis A Diseases 0.000 description 1
- 208000002672 hepatitis B Diseases 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000000968 intestinal effect Effects 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- -1 polyoxyethylene nonylphenol Polymers 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 230000003612 virological effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Detergent Compositions (AREA)
Abstract
The washing powder is compounded with five-element surfactant, such as sodium dodecyl benzene sulfonate, etc. and seven kinds of detergency builder, such as chlorinated trisodium phosphate, etc. these twelve kinds of material have excellent detergency and bactericidal and detoxicating functions. The invention has simple production flow, energy saving, low production cost and simple equipment, and is convenient for common township enterprises to implement.
Description
The present invention relates to the daily chemical industry product, particularly have the washing powder and the preparation method thereof of washing and sterilization and disinfection effect concurrently.
Along with popularizing of washing machine, the washing powder consumption increases day by day.But heavy smeary collar, cuff, the dirt of the head of a quilt does not wash clean with general washing powder, and special-purpose sprays is arranged in recent years, but it contains organic solvent human body is had certain toxicity, and the cost height.People expect to have a kind of washing powder of energy strong dirt-removing.Frequent along with human communication on the other hand, various bacteriums, virus disseminating is savage day by day, hospital, hotel, the restaurant, the sterilization of resident's clothing, quilt, article, the requirement of the poison that goes out is more and more urgent, generally adopts high-temperature sterilization or uses sterilizing agent, this sterilizing agent function singleness, people expect to have a kind of washing powder of the poison that can strong dirt-removing again can efficient sterilizing goes out.ZL90105201 " concentrated high-effective P-free sterilization washing powder and manufacture method thereof " replaces phosphoric acid salt with Starso, with the sterilization of muriate sterilant, which kind of tensio-active agent is this patent do not point out to adopt, in CN1065881A " concentrated sterilization washing powder prescription and technology ", adopt Efficacious Disinfeitant to make disinfectant, adopt Witco 1298 Soft Acid and polyoxyethylene nonylphenol ether to make tensio-active agent, these two kinds of washing powder can be had any problem when the washing heavy oil dirt.
The objective of the invention is to solve the difficulty that prior art exists, develop a kind of malicious washing powder that can strong dirt-removing again can efficient sterilizing goes out, and its preparation method is provided.
For finishing task of the present invention, the inventor is to the detersive power of various tensio-active agents, sterilizing ability, and the malicious ability of going out, scourability is studied, and therefrom filters out five kinds of tensio-active agents, and these five kinds of surfactivitys are carried out the compatibility test; Help washing composition to help to seven kinds and wash test and sterilization and disinfection test.
Discover, five yuan of compound surfactants in the present invention's prescription, sodium dodecylbenzene belongs to the high aniorfic surfactant of inexpensive matter, its hydrophilic group makes hydrophobic group because of outwardly because of combining with bacterium surface, is combined into a water-based particles settling to aqueous solution lower floor, then break off oxygen death, therefore it not only has good scourability, foam performance, still a kind of good sterilant.Tea saponin is a kind of natural nonionic surface active agent of excellent property, and is existing wetting, foaming, emulsification, performances such as dispersion and washing, and have impervious, anti-inflammatory, analgesia, anticancer physiologically active is with its composite synthetic detergent, fairly good to cotton, woolen clean effect, and sterilization, the poison that goes out, efficiency of preservation is strong.Fatty alcohol-polyoxyethylene ether is a kind of nonionic surface active agent, and best detersive power is arranged, and especially the hydrophobic synthetic fibre washing is effective especially.The itself nontoxicity, to bacterium, virus has good killing action.Alkylol amide is a nonionic surface active agent, foam performance is good, strong detergency, can prevent that calcium ion adheres on the cotton goods, the compound compatibility of three kinds of nonionic surface active agent in the prescription, improved the detersive power and the sterilization and disinfection ability of synthetic detergent powder greatly, better to the hepatitis B virus effect especially.The 5th kind of surfactivity is the empgen BB with amphoteric ion type of good sterilization and disinfection ability and high-effective cleansing power in the prescription, and direct sterilization and disinfection ability is arranged.These five kinds of tensio-active agents have obvious synergistic effect after compound compatibility of the present invention is handled, its net effect has been strengthened decontamination separately, sterilization, the effect of the poison that goes out.
Selection for washing assistant, the contriver requires them not only to help and washes work in order to improve the detersive power of prescription, require them that sterilization is arranged simultaneously, toxic action goes out: Efficacious Disinfeitant is main washing assistant, because it is to hepatitis A virus (HAV) antigen, hepatitis B surface antigen, intestinal bacteria, cured sample 4001 brood cells, paying comma bacillus and gold-coloured staphylococci has killing action completely.All the other washing assistants are medical bactericide as Sodium peroxoborate.Hydrochlorinate sodium, yellow soda ash, water glass are the alkaline auxiliary lotions, and stronger sterilization and disinfection ability is all arranged.Urea has the effect that separates the soluble complement conjugated antigen in virus particle, and can hit the hydrophobicity key between the non-polar sidechain on hydrogen bond and the amino-acid residue, and makes the multiple sex change of viral protein.These seven kinds of washing assistants not only itself have soil removability.And play synergy with tensio-active agent, and the further decontamination of five yuan of tensio-active agents of synergy, sterilization, toxic action goes out.And washing assistant can chelating or the sedimentation meeting consume the hardness ions of tensio-active agent and washing assistant itself, adjusting water hardness, and adjusting and stable pH value are in a reasonable range.
Allocate the moisture absorption agglomeration problems that toluenesulfonic acid sodium salt solves washing powder in this external prescription into.Allocate polyacrylic ester into, help the agglomeration of solid and material, when washing, can increase the negative charge quantity of whole washing system again, thereby reduce soil redeposition.Carboxymethyl starch has good bonding, thickening, and performances such as suspension and dispersion play anti-soil dirt resedimentation, make product have good powder granule structure simultaneously.Fluorescent bleaches increases the total amount of material reflected light spoke brightness, thereby produces whitening effect.3,4, the 5-tribromosalicylanilide is the sanitas of weight, it increases the antiseptic property of this product.Essence makes this product fragrance tempting.
According to above-mentioned thinking, the comprehensively performance of each component and effect, the design end formulation is listed in table 1.
Further specify preparation method of the present invention and effect below in conjunction with embodiment.
The present invention adopts static cyclone agglomerator production, and its technical process is:
Take by weighing 10 kilograms of Sodium dodecylbenzene sulfonatees respectively by prescription, 5 kilograms of tea saponins, 4 kilograms of fatty alcohol-polyoxyethylene ether, 6 kilograms in yellow soda ash, 10 kilograms of sodium bicarbonates, 25 kilograms of Efficacious Disinfeitants, 3 kilograms in sodium hydroxide, 4 kilograms of water glass, 3 kilograms in urea, 6 kilograms of anhydrous sodium sulphate, 2 kilograms of novalgins, 2 kilograms of polyacrylic ester, 3,4,9.5 kilograms of 5-Temasepts are through pulverizing, cross 80 mesh sieves, be mixed into solid powder and pack in the cyclone agglomerator, 0.3 kilogram of carboxymethyl starch is dissolved in furnishing pasty state in 4 kilograms of clear water, 0.1 kilogram of fluorescent bleaches, essence dissolves in wherein back the input in the cyclone agglomerator for 0.1 kilogram, again 2 kilograms of liquid empgen BBs and alkylol amide feed liquid are injected static cyclone agglomerator for 2 kilograms, make it to mix with the solid powder of packing into wherein, granulation adds 15 kilograms of Sodium peroxoborate to make in the discharging process again and mixes thoroughly, aging through spilling material, drying is crossed 20 orders, 18 orders, 16 orders, 14 mesh sieves, branch granularity packing.
Washing machine with specific bactericidal function of the present invention.
Product of the present invention detects through product technology supervision and inspection station, the light industry Room, Jiangxi Province, and its physical and chemical index is listed in table 2.
The heavy dirty clothing of washing in washing machine, no matter collar, coat-sleeve and the head of a quilt can both washes clean.
This product is made bactericidal assay: concentration is that the test-results of 0.5% detergent solution of the present invention is listed in table 3.
The malicious test-results of going out of product of the present invention is: 1.5% concentration water-detergent solution effect can make the hepatitis A viral antigen deactivation in 5 minutes; 3% mass action can make the whole deactivations of hepatitis B virus antigen HBSAS in 5 minutes, killed rhinovirus simultaneously, foot and mouth disease virus.
Experiment showed, washing composition of the present invention can strong dirt-removing again can efficient sterilization, reach task of the present invention.Technical process of producing washing composition of the present invention is simple, energy-conservation, production cost is low, equipment is simple, be convenient to general township and village enterprises implements.
Annotate: A-is excellent, and B-is good, and C-is qualified, D-a little less than, a little less than the E-.
Claims (2)
1, a kind of washing machine with specific bactericidal function, its prescription (weight percentage) is:
Sodium dodecylbenzene sulfonate 10%
Tea saponin 5%
Fatty alcohol-polyoxyethylene ether 4%
Alkylol amide 2%
Empgen BB 2%
Efficacious Disinfeitant 25%
Sodium peroxoborate 15%
Sodium hydroxide 3%
Yellow soda ash 6%
Water glass 4%
Sodium bicarbonate 10%
Urea 3%
Anhydrous sodium sulphate 6%
Novalgin 2%
Polyacrylic ester 2%
Carboxymethyl starch 0.3%
Fluorescent bleaches 0.1%
3,4,5-tribromosalicylanilide 0.5%
Essence 0.1%
2, the manufacture method of the washing powder of claim 1 is characterized by:
Adopt agglomeration technique: by after the prescription weighing Sodium dodecylbenzene sulfonate, tea saponin, fatty alcohol-polyoxyethylene ether, yellow soda ash, sodium bicarbonate, Efficacious Disinfeitant, sodium hydroxide, water glass, urea, anhydrous sodium sulphate, toluenesulfonic acid sodium salt, polyacrylic ester, 3,4, the 5-tribromosalicylanilide is crossed 80 mesh sieves through pulverizing, and is mixed into solid powder and packs in the cyclone agglomerator, carboxymethyl starch is dissolved in furnishing pasty state in 4% clear water, with fluorescent bleaches, after dissolving in wherein, drops in the cyclone agglomerator by essence, again liquid empgen BB and alkylol amide are injected static cyclone agglomerator, make it to mix with the solid powder of packing into wherein, granulation adds Sodium peroxoborate in the discharging process and mixes thoroughly, and is aging through spilling material, dry, cross 20 orders, 18 orders, 16 orders, 14 mesh sieves, divide the granularity packing washing powder of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94116784 CN1102207A (en) | 1994-10-08 | 1994-10-08 | High-grade specific bactericidal and detoxicating washing powder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94116784 CN1102207A (en) | 1994-10-08 | 1994-10-08 | High-grade specific bactericidal and detoxicating washing powder |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1102207A true CN1102207A (en) | 1995-05-03 |
Family
ID=5038083
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 94116784 Pending CN1102207A (en) | 1994-10-08 | 1994-10-08 | High-grade specific bactericidal and detoxicating washing powder |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1102207A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1052751C (en) * | 1995-06-16 | 2000-05-24 | 杨国林 | Muslim washing powder |
| CN1086199C (en) * | 1997-10-14 | 2002-06-12 | 成都市瑞泰技术研究所 | Fabric mildew spot eliminating detergent |
| CN100393936C (en) * | 2005-08-24 | 2008-06-11 | 西北大学 | Antibacterial fabric finishing agent and its preparation method |
| CN101768530A (en) * | 2010-03-17 | 2010-07-07 | 天津鎏虹科技发展有限公司 | Natural plant cleaning agent |
| CN103789103A (en) * | 2012-12-28 | 2014-05-14 | 王镭 | Special washing agent for hospital washing and production method thereof |
| CN103820235A (en) * | 2014-02-20 | 2014-05-28 | 苏州龙腾万里化工科技有限公司 | Washing agent for dishes |
| CN104837974A (en) * | 2012-12-13 | 2015-08-12 | 宝洁公司 | Anti-microbial laundry detergent product |
| CN106244352A (en) * | 2016-08-11 | 2016-12-21 | 李金新 | Antibacterial low foam laundry liquid and preparation method thereof |
| CN107674791A (en) * | 2017-09-15 | 2018-02-09 | 安徽科技学院 | A kind of solid-state sustained release Bactericidal cleaner and preparation method thereof |
| CN108587824A (en) * | 2018-06-07 | 2018-09-28 | 界首市亚鑫塑业有限公司 | A kind of cleaning waste plastic bottle cleaning agent and preparation method thereof |
| CN108865503A (en) * | 2018-06-29 | 2018-11-23 | 广西浙缘农业科技有限公司 | A kind of Tea Saponin washing powder and preparation method thereof |
| US20220132857A1 (en) * | 2020-11-04 | 2022-05-05 | Arash Mirzaei | Disinfecting Composition and Related Methods |
-
1994
- 1994-10-08 CN CN 94116784 patent/CN1102207A/en active Pending
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1052751C (en) * | 1995-06-16 | 2000-05-24 | 杨国林 | Muslim washing powder |
| CN1086199C (en) * | 1997-10-14 | 2002-06-12 | 成都市瑞泰技术研究所 | Fabric mildew spot eliminating detergent |
| CN100393936C (en) * | 2005-08-24 | 2008-06-11 | 西北大学 | Antibacterial fabric finishing agent and its preparation method |
| CN101768530A (en) * | 2010-03-17 | 2010-07-07 | 天津鎏虹科技发展有限公司 | Natural plant cleaning agent |
| CN104837974A (en) * | 2012-12-13 | 2015-08-12 | 宝洁公司 | Anti-microbial laundry detergent product |
| CN103789103A (en) * | 2012-12-28 | 2014-05-14 | 王镭 | Special washing agent for hospital washing and production method thereof |
| CN103789103B (en) * | 2012-12-28 | 2016-02-03 | 王镭 | Special washing composition and production method thereof are washed by hospital |
| CN103820235A (en) * | 2014-02-20 | 2014-05-28 | 苏州龙腾万里化工科技有限公司 | Washing agent for dishes |
| CN106244352A (en) * | 2016-08-11 | 2016-12-21 | 李金新 | Antibacterial low foam laundry liquid and preparation method thereof |
| CN107674791A (en) * | 2017-09-15 | 2018-02-09 | 安徽科技学院 | A kind of solid-state sustained release Bactericidal cleaner and preparation method thereof |
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