CN103805351A - Foamless detergent and preparation method thereof - Google Patents

Foamless detergent and preparation method thereof Download PDF

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Publication number
CN103805351A
CN103805351A CN201210448205.7A CN201210448205A CN103805351A CN 103805351 A CN103805351 A CN 103805351A CN 201210448205 A CN201210448205 A CN 201210448205A CN 103805351 A CN103805351 A CN 103805351A
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sodium
foaming detergent
citric acid
detergent
minutes
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CN201210448205.7A
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陈树锋
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Chen Shufeng
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Newer World International Co Ltd
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Abstract

The invention discloses a foamless detergent, which includes: sodium alginate, starch, sodium silicate, citric acid, sodium citrate, sea salt, sodium perborate, tetraacetylethylenediamine and borax, and also includes: sodium bicarbonate and soapnut saponin. The preparation method comprises the steps of: mixing sodium silicate with sodium perborate, mixing sapindus saponin, sodium alginate, starch, citric acid, sodium citrate, sea salt, sodium bicarbonate, tetraacetylethylenediamine and borax, then mixing the two mixtures, adding citric acid and conducting mixing again. The detergent has the characteristics of compatible raw materials, good water solubility, strong activity under a low temperature condition, high detergency, complete stain removal ability, and no foam or odor, and the water discharged after washing can be effectively biodegradable. The washing process has no harm to fabrics and human skin, Staphylococcus aureus, Escherichia coli, Candida albicans and the like can be effectively inhibited, odor can be eliminated, water and power can be saved, the foamless detergent is in line with energy-saving and emission reduction, environmental protection and low carbon.

Description

A kind of non-foaming detergent and preparation method thereof
Technical field
The present invention relates to non-foaming detergent, relate in particular to a kind of non-foaming detergent and preparation method thereof.
Background technology
Existing washing composition is mainly made up of raw materials such as tensio-active agent, washing assistant, white dyes, enzyme, chloride sterilant, essence.Sodium alkyl benzene sulfonate in tensio-active agent is difficult for being biodegradable, some country has stopped producing, the sewage that is dissolved with washing composition enters rivers, aquatic organism especially fish is had to serious harm, its foam coverage water surface, reduces oxygen in water, also can destroy the taste bud tissue of fish, make its amblygeustia, lose and look for food and the ability of avoiding poisonous substance.In water, detergent concentration fish in the time that 10mg/L is above are difficult to existence; Concentration is in the time of 45mg/L, and paddy growth is had a strong impact on, even dead.Rare washing composition can be absorbed and cause irritated eczema by parts of skin.Animal experiment shows there is teratogenesis, is also a kind of cocarcinogen matter.As washing assistant, the extensive application in washing composition is an important discovery of synthetic detergent industry to tripoly phosphate sodium STPP.But phosphoric acid salt, along with wash water enters rivers and lakes, causes Water Eutrophication, promote algae class Fast-propagation, anoxic in water, endangers the existence of hydrocoles, thereby becomes a large problem of environmental protection.From 20 century 70s, the developed countries such as America and Europe have just proposed the limit phosphorus problem of washing composition, and successively its content have been made to regulation.In China, due to each side reason, particularly price factor, the past does not cause enough attention to the problems referred to above.After white dyes is absorbed by the body, can make cell produce variability, excessively may have potential carcinogenic factor if contacted.Enzyme can damage the protein of skin surface, causes the allergic phenomena such as fash, eczema.Essence is harmful, can cause chronic poisoning, even can teratogenesis, carcinogenic.
Summary of the invention
The present invention is intended to overcome above-mentioned phenomenon, provide a kind of safe, nontoxic, nuisanceless, have no side effect, there are sterilization, antibacterial, taste removal, decontamination, whitening and brightening, can extend fabric life, washing process water saving power saving, save energy, is turned to non-foaming detergent of hommization and preparation method thereof by functionalization.
The technical problem to be solved in the present invention is achieved by the following technical programs: a kind of non-foaming detergent, comprise the sodium alginate of the raw material of following weight percent: 1-10%, the starch of 1-11%, the water glass of 3-15%, the sodium perborate of 8-21%, the Trisodium Citrate of 13-25%, the citric acid of 15-30%, the sea salt of 10-25%, the borax of 1-17%, the tetraacetyl ethylene diamine of 1-9%, also comprise the sodium bicarbonate of 13-25% and the sapindoside of 3-17%.
In above-mentioned non-foaming detergent, described non-foaming detergent is containing the raw material of following weight percent: 3% sodium alginate, 2% starch, 9% water glass, 15% sodium perborate, 15% Trisodium Citrate, 17% citric acid, 12% sea salt, 5% borax, 2% tetraacetyl ethylene diamine, also comprise 15% sodium bicarbonate and 5% sapindoside
According to a further aspect in the invention, provide a kind of preparation method of above-mentioned non-foaming detergent, comprise the following steps:
A. first load weighted water glass and sodium perborate are dropped into and in stirring tank, stirred 10-15 minute by filter screen;
B. sapindoside, sodium alginate, starch, Trisodium Citrate, sea salt, sodium bicarbonate, tetraacetyl ethylene diamine and borax are dropped into and in stirring tank, stirred 5-10 minute by filter screen;
C. mixture step a being made adds in the mixture that step b makes, and stirs and adds citric acid to stir 5-10 minute after 5-10 minute again, obtains described non-foaming detergent product.
In the preparation method of above-mentioned non-foaming detergent, comprise the following steps:
A. first load weighted water glass and sodium perborate are dropped in stirring tank and stirred 10 minutes by filter screen;
B. sapindoside, sodium alginate, starch, Trisodium Citrate, sea salt, sodium bicarbonate, tetraacetyl ethylene diamine and borax are dropped in stirring tank and stirred 5 minutes by filter screen;
C. mixture step a being made adds in the mixture that step b makes, and stirs after 5 minutes and adds citric acid to stir 10 minutes again, obtains described non-foaming detergent product.
Principle of design of the present invention:
Organic raw material citric acid, sapindoside, starch, Trisodium Citrate, sodium alginate are adopted, natural matter sea salt and strong oxidizer sodium perborate etc.; The performance of making washing assistant and can improve cleaning product with citric acid, precipitate metal ion rapidly, prevents that pollutent is re-attached on fabric, keep the alkalescence that washing is necessary, making dirt and ash disperse and suspend, improve the performance of tensio-active agent, is a kind of good sequestrant, sterilant; Sapindoside is the extract of wild deciduous tree Seed of Chinese Soapberry (Sapindus mukorossi Gareth.) pericarp, it is a kind of natural nonionic surface active agent, all-natural product, without adding any artificial synthetic detergent, essence, pigment and sanitas.There is the capillary effect of very strong reduction, for skin clean (take a shower, wash one's face, wash one's hands, have one's hair wash) and clothes washing, wash clean performance good, effectively take out stains, free from extraneous odour, antibacterial beauty treatment, brightens, nti-freckle, anti-acne, prevents and treats tetter.100% degraded, gentle non-stimulated, can not produce the residue that is harmful to HUMAN HEALTH and hostile environment.Sodium perborate can be used as additive, the washing assistant of washing composition, can effectively bring into play good bleaching, sterilization, germicidal action, and can not produce corrosion to fabric, household articles, can be widely used in washing of cotton goods, chemical fibre, artificial silk, short fiber, flax and woollen fabrics floats, make it not yellowing, do not affect fabric, the flexibility of energy reinforced fabric and wear resistance and effectively antistatic property yet; Tetraacetyl ethylene diamine (TAED) is the activator of strong oxidizer, improves the washing functions of strong oxidizer in water at low temperature and sterilization, sterilizing function.
The use range of non-foaming detergent of the present invention: comprise the washing of various cotton goods, chemical fibre, artificial silk, short fiber, flax and woollen fabrics, also can be used for metal brightener, cabinet sanitising agent, food utensil sanitising agent, vegetables and fruits sanitising agent, denture cleanser, cleaning agent for mouth cavity, ceramic sanitising agent, antibacterial sanitising agent, feeding bottle sanitising agent, hand cleaner, pet cleaning agent, shampoo, bath shampoo etc.
The consumption standard of non-foaming detergent of the present invention: per kilogram clothing is 7-10 gram, if during for metal brightener, cabinet sanitising agent, food utensil sanitising agent, vegetables and fruits sanitising agent, denture cleanser, cleaning agent for mouth cavity, ceramic sanitising agent, antibacterial sanitising agent, feeding bottle sanitising agent, hand cleaner, pet cleaning agent, shampoo, bath shampoo: by non-foaming detergent by 1: 1000 (water) dilution.
The technique effect that the present invention is useful is:
The raw materials used mutual compatibility of the present invention, has good solvability, has extremely strong activity under cold condition, and washing force is high, goes stain completely, still tasteless, the effectively biological degradation of water of discharging after washing.Washing process is not hindered fabric and human body skin, can effectively suppress staphylococcus aureus, intestinal bacteria, Candida albicans etc., has deodorant to taste effect, and water saving power saving, meets energy-saving and emission-reduction, environmental protection low-carbon (LC) category.
Embodiment
Embodiment 1:
The non-foaming detergent of embodiment 1 is made up of following weight percent raw material:
Figure BDA00002380300300041
The preparation of the non-foaming detergent of embodiment 1 comprises the following steps:
Step a, first load weighted water glass and sodium perborate are dropped in stirring tank and stirred 10 minutes by filter screen; Step b, sapindoside, sodium alginate, starch, Trisodium Citrate, sea salt, sodium bicarbonate, tetraacetyl ethylene diamine and borax are dropped in stirring tank and stirred 5 minutes by filter screen; Step c, the mixture that step a is made add in the mixture that b makes, and stir and add citric acid after 5 minutes, then stir 10 minutes; Steps d, sample examination analyze qualified after, blowing packing, obtains non-foaming detergent product.
Embodiment 2:
The non-foaming detergent of embodiment 2 is made up of following weight percent raw material:
Figure BDA00002380300300042
Figure BDA00002380300300051
The preparation of the non-foaming detergent of embodiment 2 comprises the following steps:
Step a, first load weighted water glass and sodium perborate are dropped in stirring tank and stirred 15 minutes by filter screen; Step b, sapindoside, sodium alginate, starch, Trisodium Citrate, sea salt, sodium bicarbonate, tetraacetyl ethylene diamine and borax are dropped in stirring tank and stirred 7 minutes by filter screen; Step c, the mixture that step a is made add in the mixture that b makes, and stir and add citric acid after 7 minutes, then stir 5 minutes; Steps d, sample examination analyze qualified after, blowing packing, obtains non-foaming detergent product.
Embodiment 3:
The non-foaming detergent of embodiment 3 is made up of following weight percent raw material:
Figure BDA00002380300300052
The preparation of the non-foaming detergent of embodiment 3 comprises the following steps:
Step a, first load weighted water glass and sodium perborate are dropped in stirring tank and stirred 12 minutes by filter screen; Step b, sapindoside, sodium alginate, starch, Trisodium Citrate, sea salt, sodium bicarbonate, tetraacetyl ethylene diamine and borax are dropped in stirring tank and stirred 10 minutes by filter screen; Step c, the mixture that step a is made add in the mixture that b makes, and stir and add citric acid after 7 minutes, then stir 7 minutes; Steps d, sample examination analyze qualified after, blowing packing, obtains non-foaming detergent product.
Embodiment 4:
The non-foaming detergent of embodiment 4 is made up of following weight percent raw material:
Embodiment 5:
The non-foaming detergent of embodiment 5 is made up of following weight percent raw material:
Figure BDA00002380300300062
Embodiment 6:
The non-foaming detergent of embodiment 6 is made up of following weight percent raw material:
Figure BDA00002380300300071
Embodiment 7:
The non-foaming detergent of embodiment 7 is made up of following weight percent raw material:
Figure BDA00002380300300072
Above content is in conjunction with concrete embodiment further description made for the present invention, can not assert that specific embodiment of the invention is confined to these explanations.For general technical staff of the technical field of the invention; make without departing from the inventive concept of the premise some alternative or obvious modification that are equal to; and performance or purposes identical, should be considered as belonging to the present invention by the definite protection domain of submitted to claims.

Claims (4)

1. a non-foaming detergent, comprises the raw material of following weight percent:
Figure FDA00002380300200011
It is characterized in that: also comprise following weight percent raw material:
Sodium bicarbonate 13-25%
Sapindoside 3-17%.
2. non-foaming detergent according to claim 1, is characterized in that, the weight percent of contained raw material is:
Figure FDA00002380300200012
It is characterized in that: also comprise following weight percent raw material:
Sodium bicarbonate 15%
Sapindoside 5%.
3. a preparation method for the non-foaming detergent of claim 1, is characterized in that, comprises the following steps:
A. first load weighted water glass and sodium perborate are dropped into and in stirring tank, stirred 10-15 minute by filter screen;
B. sapindoside, sodium alginate, starch, Trisodium Citrate, sea salt, sodium bicarbonate, tetraacetyl ethylene diamine and borax are dropped into and in stirring tank, stirred 5-10 minute by filter screen;
C. mixture step a being made adds in the mixture that step b makes, and stirs and adds citric acid to stir 5-10 minute after 5-10 minute again, obtains described non-foaming detergent product.
4. the preparation method of non-foaming detergent according to claim 3, is characterized in that, comprises the following steps:
A. first load weighted water glass and sodium perborate are dropped in stirring tank and stirred 10 minutes by filter screen;
B. sapindoside, sodium alginate, starch, Trisodium Citrate, sea salt, sodium bicarbonate, tetraacetyl ethylene diamine and borax are dropped in stirring tank and stirred 5 minutes by filter screen;
C. mixture step a being made adds in the mixture that step b makes, and stirs after 5 minutes and adds citric acid to stir 10 minutes again, obtains described non-foaming detergent product.
CN201210448205.7A 2012-11-09 2012-11-09 Foamless detergent and preparation method thereof Pending CN103805351A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104017661A (en) * 2014-06-16 2014-09-03 湖南农业大学 Tea saponin dishwashing liquid and preparation method thereof
CN104498013A (en) * 2014-09-18 2015-04-08 成都孚吉科技有限责任公司 Self-foaming-type foaming drainage agent and preparation method thereof
CN104974862A (en) * 2015-06-15 2015-10-14 马建剑 Novel bactericidal and insect-repelling detergent for wool clothing and preparation method therefor
CN111454792A (en) * 2020-04-24 2020-07-28 谷雨河生物科技有限公司 Production process and formula of efficient detergent for removing pesticide residues
CN111454788A (en) * 2020-04-24 2020-07-28 谷雨河生物科技有限公司 Energy-saving water-saving low-foam pregnant woman and infant laundry detergent production process and formula

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CN101993788A (en) * 2010-11-05 2011-03-30 深圳市七叶红生物科技有限公司 Healthy zero-carbon washing powder and preparation method thereof
CN102517170A (en) * 2011-12-07 2012-06-27 王爽 Natural plant environment-friendly washing product

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US20070244026A1 (en) * 2004-10-22 2007-10-18 Wolfgang Barthel Detergent or cleaning agent
CN101993788A (en) * 2010-11-05 2011-03-30 深圳市七叶红生物科技有限公司 Healthy zero-carbon washing powder and preparation method thereof
CN102517170A (en) * 2011-12-07 2012-06-27 王爽 Natural plant environment-friendly washing product

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104017661A (en) * 2014-06-16 2014-09-03 湖南农业大学 Tea saponin dishwashing liquid and preparation method thereof
CN104017661B (en) * 2014-06-16 2015-06-17 湖南农业大学 Tea saponin dishwashing liquid and preparation method thereof
CN104498013A (en) * 2014-09-18 2015-04-08 成都孚吉科技有限责任公司 Self-foaming-type foaming drainage agent and preparation method thereof
CN104498013B (en) * 2014-09-18 2017-10-24 成都孚吉科技有限责任公司 It is a kind of from foaming type foaming water discharge agent and preparation method thereof
CN104974862A (en) * 2015-06-15 2015-10-14 马建剑 Novel bactericidal and insect-repelling detergent for wool clothing and preparation method therefor
CN111454792A (en) * 2020-04-24 2020-07-28 谷雨河生物科技有限公司 Production process and formula of efficient detergent for removing pesticide residues
CN111454788A (en) * 2020-04-24 2020-07-28 谷雨河生物科技有限公司 Energy-saving water-saving low-foam pregnant woman and infant laundry detergent production process and formula

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Application publication date: 20140521