CN102492571A - Detergent composition containing amino acid component for washing fruits, vegetables and dishes - Google Patents
Detergent composition containing amino acid component for washing fruits, vegetables and dishes Download PDFInfo
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Abstract
The present invention relates to a detergent composition containing an amino acid component for washing fruits, vegetables and dishes, which comprises the following components of an anionic surfactant, a non-ionic surfactant, an amphoteric surfactant, amino acid, a viscosity modifier, a chelating agent, an antiseptic, a light stabilizer, an antioxidant, a flavor and deionized water. The amino acid composition is one or a mixture with more than two of alanine, arginine, asparagine, aspartic acid, cystine, glutamine, glutamic acid, leucine, lysine, methionine, phenylalanine, prolinol acid, serine, threonine, glycine, histidine, isoleucine, tryptophan, tyrosine and valine. The detergent of the invention can maintain good decontamination capability, improve the feeling when the detergent composition is used, reduce the hands skin irritation and enhance the hand skin moisturizing ability to improve dry feeling.
Description
Technical field
The invention belongs to the daily chemical product field, be specifically related to a kind of fruits and vegetables that contain the amino acid composition, dish washing detergent compositions and preparation method thereof.
Background technology
Product form is known by people so that liquid detergent, dish detergent, the essence that washes the dishes, fruits and vegetables are clean etc. usually for fruits and vegetables, dish washing detergent.This type Betengent product is made up of tensio-active agent, washing assistant, water conditioner, reodorant, fungicidal preservative usually.Because clean various food soil residual on the tableware, particularly remove the oils spot, need product to have stronger washing force.Thereby this series products also has stronger degreasing power to human body skin, frequently contacts with people's hand skin for a long time, can cause xerosis cutis, fold, follow the string and attenuation aging, even the skin problem of seriously chapping appears.
Be particular about consciousness surging of sanitation and hygiene along with the human consumer; The usage frequency of fruits and vegetables, dish washing detergent constantly increases; These washing composition are more and more with the chance that human consumer's skin directly contacts; Sometimes can reach more than 10 times in one day, Halkier Sorensen etc. find in some long-time immersions and the crowd who contacts washing composition, if without wetting Agent for Printing Inks; Skin obviously dry (the Halkier Sorensen L that becomes; Thestrup Pedersen K.The efficacy of a moisturizer (Locobase) among cleaners and kitchen assistants during everyday exposure to water and detergents.Contact Dermatitis, 1993,29:266-271.).Therefore, increasing human consumer require to wash clean effective in, begin to pay close attention to the damage problem of washing composition to skin.
But the research emphasis of dish washing detergent is focusing more on the detergency ability aspect that promotes product at present, for reducing the irritating research of product and few.Modal reduction dish washing detergent degreasing power and irritating method are through the mode of control formula for a product potential of hydrogen or reduce the petroleum amount of surfactant and realize; Also have through adding VITAMINs and wetting Agent for Printing Inks etc. and reduce the product pungency, feel when improving washing.So-called wetting Agent for Printing Inks is exactly in order to simulate in the human body skin by oil, water, natural moisturizing factor (Natural Moisturizing Factor; NMF) the natural moisture preserving system that forms, effect is to delay loss of moist, increases corium-epidermis moisture penetration, is that skin temporarily provides protection, reduces damage, promotes repair process.Like publication number is the patent of CN 101712912A, discloses a kind of skin-care detergent that contains vitamin E and amino acid humectant.This skin-care detergent plays the effect of moist, smooth user's skin through the acting in conjunction of vitamin E and amino acid humectant.But the used amino acid humectant of patent is not human body institute inherent 20 seed amino acids, and its bio-compatibility is not as human body institute inherent 20 seed amino acids.In addition, mostly present amino acid humectant is to be present in Trimethyl glycine or the trimethyl-glycine in aquatic shellfish of animal and the plant trimethyl-glycine, though have good moisture hold facility, its biological safety and toxicity are still needed and further assessed.
Natural moisture preserving system in the human body skin mainly is made up of water, lipid, NMF.NMF is the general name of some low molecular weight substances of in the angling process, forming of epidermic cell, and its composition is through measuring, and the result sees table 1-1.(Wang Huaying. the formulating of recipe of wetting Agent for Printing Inks and insulation nursing product. Chinese outstanding Master's thesis, 2009.)
The chemical constitution of table 1 natural moisturizing factor
In addition, what can be used as the wetting Agent for Printing Inks active ingredient also has: neural phthalein amine, indispensable fatty acid, for example linolenic and linoleic, eicosanoic acid etc., various VITAMINss, pyrrolidone sodium carboxylate, lactic acid, collagen, source amine albumen and mucinase, aloe etc.(Tabata N such as Tabata; O ' Goshi K, Zhen YX, et al.Biophysical ssessment of persistent effects of moisturizers after their daily applications:evaluation of corneotherapy.Dermatology; 2000; 200:308-313.) discover that wetting Agent for Printing Inks all can increase normal people and xerosis patient skin electric capacity, strengthen the hydration of skin surface, improve the xerosis cutis situation.(Ramsing DW such as Ramsing; Agner T.Preventive and therapeutic effects of a moisturizer.An experimental study of human skin.Acta Derm Venereol; 1997; 77:335-337.) discover that wetting Agent for Printing Inks can also prevent normal skin impaired and skin in damaged condition had therapeutic action, when the prophylactic effect of research external application wetting Agent for Printing Inks, finds that wetting Agent for Printing Inks can obviously alleviate sodium lauryl sulphate (sodium lauryl sulphate; SLS) damage, and protection skin; Behind the external preparation for skin wetting Agent for Printing Inks 5d that is damaged, barrier and hydration function are obviously improved, and have promoted the reparation of skin.(Held E such as Held; Lund H; Agner T.Effect of different moisturizers on SLS-irritated human skin.Contact Dermatitis; 2001,44:229-234.) also confirm that wetting Agent for Printing Inks can promote the reparation of the skin that SLS damages, and the effect of high fat wetting Agent for Printing Inks is more obvious.(Suarez M such as Suarez; Fulton JE Jr. A novel occlusive dressing for skin resurfacing.Dermatol Surg; 1998,24:567-570.) discover and carrying out the laser skin Resurfacing with wetting Agent for Printing Inks such as silicone, can quicken surface of a wound epithelization again; Alleviate erythema oedema and pain, promote healing.These explain that all wetting Agent for Printing Inks has not only increased skin moisture content, improve dry condition, stimulate to external world also to have provide protection, and can promote the damaged skin reparation.Yet, preferably select for use natural moisturizing factor as the wetting Agent for Printing Inks active ingredient, because they are human body inherent NMFs, can not produce untoward reaction and hormesis to human body.
Can find out from above-mentioned progress and summary; The research that has fruits and vegetables, the dish washing detergent of moisture-keeping functions at present also is in the starting stage with using; Make fruits and vegetables, dish washing detergent have performance of keeping humidity; Damage can be reduced, the material of natural moisturizing factor, particularly amino acids must be added user's skin.Amino acid is the indispensable a kind of compound of human body, is the main source of collagen protein and elastin in the skin, and it has affinity to skin and hair, and it is fit to form the meeting that is produced by carboxamido-group, also has antiacidization ability etc.On skin and hair, all have free amino acid, they combine with water, make skin and hair keep wettability equilibrium.Total free aminoacids has more cationic characteristic than polypeptide, and they are stronger to the proteinic avidity of hair and skin.In addition, they can also infiltrate through skin and hair further increases its amount of being adsorbed.Amino acid makes the skin softness not tight, moist attached to can Glycerin on the skin surface, and wrinkle is unfolded, high resilience.And temporary transient in the market fruits and vegetables, the dish washing detergent that the necessary 20 seed amino acid class materials of human body institute do not occur adding.Therefore, exploitation has moisture-keeping functions and does not hinder the fruits and vegetables of hand, the main developing direction that dish washing detergent will become fruits and vegetables, dish washing detergent.
Summary of the invention
The object of the present invention is to provide a kind of fruits and vegetables that contain aminoacid component, dish washing detergent compositions with moisture-keeping functions; This washing composition adopts necessary for human body 20 seed amino acids as the natural moisture preserving agent; Tool height bio-compatibility; Be used for fruits and vegetables, dish washing detergent can improve the moisture hold facility that skin is sent out rapidly, the activated cell vigor, make skin moist, smooth, prevent drying and obfuscation; The exploitation of this washing composition will successfully solve existing fruits and vegetables, the dish washing detergent degreasing power is strong, and human consumer's hand skin is produced pungency, cause xerodermatic problem.
A kind of fruits and vegetables of aminoacid component, each material component that dish washing detergent compositions comprises following weight percent of containing that the present invention proposes: tensio-active agent 15.0-50.0%; Amino acid 0.1-5.0%; Viscosity modifier 0.1-5.0%, sequestrant 0.01-1.0%, fungicidal preservative 0.01-0.5%; Other compositions 0.04-0.1%, surplus is a deionized water.
The preparation method of fruits and vegetables of the present invention, dish washing detergent compositions is: with random order above-mentioned tensio-active agent, viscosity modifier, sequestrant, fungicidal preservative, amino acid, pH regulator agent, photostabilizer, inhibitor and essence are joined in the deionized water, be stirred to dissolving evenly.Draw samples is also checked according to quality standard.Specification product leave standstill to basic non-foam, can be finished product fruits and vegetables, dish washing detergent compositions.
Tensio-active agent of the present invention is at least a in AS, nonionogenic tenside and the amphoterics.
AS of the present invention is an any or two or more mixture in polyoxyethylenated alcohol sodium sulfate, AEO carboxylic acid sodium, sodium alkyl sulfate, alkyl sodium sulfonate, α-sodium olefin sulfonate, methyl sodiosul foaliphatate, the sulfo-succinic acid ester sodium salt, wherein the mixture of preferred fat polyoxyethylenated alcohol sodium sulfate and methyl sodiosul foaliphatate more.The Fatty Alcohol(C12-C14 and C12-C18) that is used for the synthetic fatty alcohol polyethenoxy ether sodium sulfate can be that natural alcohol also can be a synthol, and the alkyl chain of Fatty Alcohol(C12-C14 and C12-C18) is preferably the straight chained alkyl of 12-16 carbon atom.The average adduct number of the oxyethane of alcohol ether is 1-3.The preferred content of AS is 5.0-30.0%.
Nonionogenic tenside of the present invention has any or two or more mixture in AEO-9, AEO-7, polyoxyethylene glycol, alkyl-glucoside, monoolein, sucrose ester, fatty acid methyl ester ethoxylate, polyglycerol fatty acid ester, the amine oxide.The preferred content of nonionic watch active agent is 5.0-15.0%.
Amphoterics of the present invention is an any or two or more mixture in lauryl L-Ala diethanolamine salt, lauryl Sodium L-alaninate, AMONYL 380LC, alkyl hydroxyl sulfopropyl betaine, the tetrahydroglyoxaline.The preferred content of amphoterics is 1.0-5.0%.
Amino acid of the present invention is any or two or more amino acid whose mixtures in the table 2.Preferred addition is 0.1-5.0%.
Kind that table 2 human body is amino acid contained and the solubleness in water thereof (25 ℃, g/100g)
| Amino acid | Abbreviation | Solubleness | Amino acid | Abbreviation | Solubleness |
| L-Ala | Ala | 16.65 | Glycocoll | Gly | 25 |
| L-arginine | Arg | 14.8 | Histidine | His | 4.29 |
| L-asparagine | Asn | 3.0 | Isoleucine | Ile | 4.12 |
| Aspartic acid | Asp | 0.50 | Tryptophane | Trp | 1.14 |
| Gelucystine | Cys | 0.011 | Tyrosine | Tyr | 0.05 |
| Proline(Pro) | Pro | 162.3 | Xie Ansuan | Val | 8.85 |
| Leucine | Leu | 2.426 | Stimulina | Gln | 4.25 |
| Methionin | Lys | 89 (hydrochlorides) | L-glutamic acid | Glu | 0.864 |
| Methionine(Met) | Met | 5.92 | Serine | Ser | 5.02 |
| Phenylalanine(Phe) | Phe | 2.97 | Threonine | Thr | 10.6 |
Viscosity modifier of the present invention has sodium-chlor, sodium sulfate, ethanol, Ucar 35, sodium xylene sulfonate, cumene sodium sulfonate, wherein more preferred alcohol or sodium xylene sulfonate.Alcoholic acid adds the low-temperature stability that can stop the generation of mesomorphic phase and improve product, and preferred content is 0.5-5.0%, and preferred especially content is 3.0-5.0%.Sodium xylene sulfonate can promote the dissolving of tensio-active agent, and its content is below 5.0%, preferred 0.1-1.5%.
Sequestrant of the present invention has tetrasodium ethylenediamine tetraacetate, EDTA Disodium, Hydrocerol A, wherein more preferred EDTA Disodium; Preferred addition is 0.01-0.5%.
Fungicidal preservative of the present invention has Sodium Benzoate, methylisothiazolinone, phenoxyethyl alcohol, wherein preferable methyl RH-893 more; Preferred addition is 0.01-0.1%.
Other components of the present invention are photostabilizer, inhibitor, essence, and these components are the universaling component of detergent composition, and kind is not done specific restriction, and the preferred addition of other components is 0.04-0.1%.
Fruits and vegetables according to the invention, dish washing detergent compositions have following advantage and beneficial effect than prior art:
1) the gentle tensio-active agent that the preferred pungency of the present invention is low relatively reduces the pungency and the degreasing power of product self as the decontamination component when keeping the product detergency ability; These tensio-active agent biological degradabilities are good, more environmental protection.
2) the low and safer fungicidal preservative of the preferred pungency of the present invention improves the xerosis cutis state; Wetting Agent for Printing Inks can obviously improve the water cut of skin, increases skin elasticity, prevention skin damage and the reparation of promotion damaged skin.
Embodiment
The performance test methods of fruits and vegetables of the present invention, dish washing detergent compositions is following:
1, Determination of Amino Acids Content method in fruits and vegetables, the dish washing detergent compositions
In the presence of 2 mercapto ethanol, amino acid and O-phthalic aldehyde reaction generate the verivate of high fluorescence, when 380nm excites, have the highest fluorescent emission at 450nm, are used for quantitative analysis amino acid.Reaction equation is following:
2, the measuring method of fruits and vegetables, dish washing detergent compositions detersive power
The detersive power of fruits and vegetables, dish washing detergent compositions adopts the foam position method among the GB 9985-2000 (manual dishwashing is used washing composition) to measure.Measure the result and disappear to half terminal point as washing with fruits and vegetables, dish washing detergent compositions surfactant foam layer, the number of dishwashing is as the evaluation of soil removability.Wherein, described dish is white porcelain vegetable dish, and divide large, medium and small three kinds: the deep bid external diameter is about 250mm, and the section diameter of defiling of trying to get to the heart of a matter is about 190mm, and the mid-game external diameter is about 200mm, and the section diameter of defiling of trying to get to the heart of a matter is about 140mm; The shallow bid external diameter is about 160mm, and the section diameter of defiling of trying to get to the heart of a matter is about 100mm.
3, the measuring method of fruits and vegetables, dish washing detergent compositions stability
The detersive power of fruits and vegetables, dish washing detergent compositions adopts the requirement among the GB 9985-2000 (manual dishwashing is used washing composition) to measure.Stability is placed 24h in-3 ℃～-10 ℃ refrigerator, take out and observe no crystallization when returning to room temperature, does not have deposition; Place 24h in the insulation can of (40 ± 1) ℃, take out and observe not stratifiedly, haze-free immediately, and do not change smell.
4, fruits and vegetables, the dish washing detergent compositions measuring method of rate % of preserving moisture
With saturated potassium carbonate [K
2CO
3] solution and saturated ammonium sulphate [(NH
4)
2SO
4] solution places respectively in the different moisture eliminators; Moisture eliminator is put in 20 ℃ the thermostatic chamber; Stablize 24h, then the fixedly humidity in the moisture eliminator be respectively RH 43% and RH 81% (Miyazaki fortunately practises, flat wooden lucky husband. the present situation of wetting Agent for Printing Inks, performance of keeping humidity makeup and future expectation .Fragance Jounral; 1990, (2): 30-36).With these two humidity is ambient moisture, and the rate of the preserving moisture % of test fruits and vegetables, dish washing detergent compositions (Du Xiaohao, Xu Wei, Du Xuejie. the performance of keeping humidity evaluation of skin-protection product. daily chemical industry, 2000,3 (6): 47-51).
Take by weighing fruits and vegetables, the dish washing detergent compositions of 18～22g, be designated as M
1, evenly be applied in the watch-glass that diameter is 8cm, watch-glass is put into moisture eliminator, behind 24h, take by weighing its weight again, be designated as M
2The rate of preserving moisture % is according to computes:
5, fruits and vegetables, dish washing detergent compositions are to the measuring method of skin moisture-keeping effect
Fruits and vegetables, dish washing detergent compositions adopt SKICON 200 type high frequency conductance determinators to measure to the humidity-holding effect of skin.Testing method is following: selected totally 10 of tested volunteer men and women (22～65 years old age).Previous day on-test, the volunteer requires can not use any washing or skin care item series products at hand.At first let the volunteer be 25 ℃ in temperature, relative humidity RH is that 40～45% environment adapts to 15 minutes down; Then; 10 volunteers' of picked at random the left hand or the right hand; It is soaked in the fruits and vegetables, the dish washing detergent compositions aqueous solution of 1wt%; The another hand is soaked in the fruits and vegetables that do not add amino acid whose 1wt%, the dish washing detergent compositions aqueous solution, after 15 minutes both hands taken out, and clean with flushing with clean water.The specific conductivity of test volunteer palm butt skin behind the 4h.Measure the result with specific conductivity (Ω
-1) expression.There is the polar biofilm structure that skin is become in the skin and has the highly tissue of compartment, be equivalent to electric capacity as the small anatomical structure that the border forms by microbial film.When skin injury, destroyed these micro-structures, can cause that the electricimpedance that can reflect skin injury descends, the corresponding increase of specific conductivity.
6, the measuring method that moisture of skin scatters and disappears behind use fruits and vegetables, the dish washing detergent compositions
After using fruits and vegetables, dish washing detergent compositions, the lost employing Tewameter TM210 type moisture of skin of the moisture of skin tester that scatters and disappears.Testing method is following: selected totally 10 of tested volunteer men and women (22～65 years old age).Previous day on-test, the volunteer requires can not use any washing or skin care item series products at hand.At first let the volunteer be 25 ℃ in temperature, relative humidity RH is that 40～45% environment adapts to 15 minutes down; Then; 10 volunteers' of picked at random the left hand or the right hand; It is soaked in the fruits and vegetables, the dish washing detergent compositions aqueous solution of 1wt%; The another hand is soaked in the fruits and vegetables that do not add amino acid whose 1wt%, the dish washing detergent compositions aqueous solution, after 15 minutes both hands taken out, and clean with flushing with clean water.The interior moisture of test volunteer palm butt skin is through epidermis evaporation or forfeiture (TEWL) speed behind the 1h.Detect the index result and represent TEWL (g/m
2H).Under the normal circumstances, because effective skin barrier, the TEWL increase shows barrier injury, the effect of skin irriate.
Below in conjunction with embodiment the present invention is carried out concrete description, it is pointed out that cited embodiment only is used for the present invention is further explained, can not be interpreted as restriction protection domain of the present invention.These those skilled in the art can content according to the present invention make some nonessential improvement and adjustment, also belong in protection scope of the present invention.
Embodiment 1
According to the formulation content of table 3, tensio-active agent, viscosity modifier, sequestrant, fungicidal preservative, amino acid, pH regulator agent, photostabilizer, inhibitor and essence are joined in the deionized water with random order, be stirred to dissolving evenly.Draw samples is also checked according to quality standard.Specification product leave standstill to basic non-foam, can be finished product fruits and vegetables, dish washing detergent compositions.
The fruits and vegetables of table 3 embodiment 1, the prescription of dish washing detergent compositions are formed
To the mensuration of the mensuration of the fruits and vegetables of embodiment 1, mensuration that the dish washing detergent compositions sample carries out Determination of Amino Acids Content, detersive power, stability, the rate of preserving moisture %, to the mensuration of skin moisture-keeping effect and the mensuration that moisture of skin scatters and disappears after using the fruits and vegetables, dish washing detergent compositions of embodiment 1, test result is seen table 4.Comparison sample does not add amino acid, and its addition is replaced by water.
The fruits and vegetables of table 4 embodiment 1, the performance of dish washing detergent compositions
Can find out that from table 4 the pH value of the fruits and vegetables of embodiment 1, dish washing detergent compositions is 6.5 (recording with PHS-3C numeral pH acidometer), the pH value the same (the pH value of normal skin is between 5.5-6.5) with human epidermal all presents slightly acidic.The Determination of Amino Acids Content value of embodiment 1 is consistent with actual addition.Compare with comparison sample, the dishwashing number of embodiment 1 is 5 deep bids.Well heat-resisting, cold-resistant and centrifugal stability that embodiment 1 has.With do not add amino acid whose comparison sample relatively, embodiment 1 scatters and disappears at the rate % that preserves moisture, to skin moisture-keeping effect and moisture of skin and is superior to comparison sample on the TEWL, under the prerequisite of identical washability, the protection of 1 pair of skin of embodiment is more obvious.
Therefore, under the situation of life-time service, the fruits and vegetables of embodiment 1, dish washing detergent compositions can improve the water cut of skin, and prevention skin damage and the reparation of promotion damaged skin.
Embodiment 2
According to the formulation content of table 5, tensio-active agent, viscosity modifier, sequestrant, fungicidal preservative, amino acid, pH regulator agent, photostabilizer, inhibitor and essence are joined in the deionized water with random order.Draw samples is also checked according to quality standard.Specification product leave standstill to basic non-foam, can be finished product fruits and vegetables, dish washing detergent compositions.
The fruits and vegetables of table 5 embodiment 2, the prescription of dish washing detergent compositions are formed
To the mensuration of the mensuration of the fruits and vegetables of embodiment 2, mensuration that the dish washing detergent compositions sample carries out Determination of Amino Acids Content, detersive power, stability, the rate of preserving moisture %, to the mensuration of skin moisture-keeping effect and the mensuration that moisture of skin scatters and disappears after using the fruits and vegetables, dish washing detergent compositions of embodiment 2, test result is seen table 6.Comparison sample does not add amino acid, and its addition is replaced by water.
The fruits and vegetables of table 6 embodiment 2, the performance of dish washing detergent compositions
Can find out that from table 6 the pH value of the fruits and vegetables of embodiment 2, dish washing detergent compositions is 6.5 (recording with PHS-3C numeral pH acidometer), the pH value the same (the pH value of normal skin is between 5.5-6.5) with human epidermal all presents slightly acidic.The Determination of Amino Acids Content value of embodiment 2 is consistent with actual addition.Compare with comparison sample, the dishwashing number of embodiment 2 is 10 deep bids.Well heat-resisting, cold-resistant and centrifugal stability that embodiment 2 has.With do not add amino acid whose comparison sample relatively; Embodiment 2 scatters and disappears at the rate % that preserves moisture, to skin moisture-keeping effect and moisture of skin and obviously is superior to comparison sample on the TEWL; Under the prerequisite of identical washability, the fruits and vegetables of embodiment 2, dish washing detergent compositions are more obvious to the protection of skin.
Therefore, under the situation of life-time service, the fruits and vegetables of embodiment 2, dish washing detergent compositions can obviously improve the water cut of skin, and prevention skin damage and the reparation of promotion damaged skin.
Embodiment 3
According to the formulation content of table 7, tensio-active agent, viscosity modifier, sequestrant, fungicidal preservative, amino acid, pH regulator agent, photostabilizer, inhibitor and essence are joined in the deionized water with random order.Draw samples is also checked according to quality standard.Specification product leave standstill to basic non-foam, can be finished product fruits and vegetables, dish washing detergent compositions.
The fruits and vegetables of table 7 embodiment 3, the prescription of dish washing detergent compositions are formed
To the mensuration of the mensuration of the fruits and vegetables of embodiment 3, mensuration that dish washing detergent compositions carries out Determination of Amino Acids Content, detersive power, stability, the rate of preserving moisture %, to the mensuration of skin moisture-keeping effect and the mensuration that moisture of skin scatters and disappears after using the fruits and vegetables, dish washing detergent compositions of embodiment 3, test result is seen table 8.Comparison sample does not add amino acid, and its addition is replaced by water.
The fruits and vegetables of table 8 embodiment 3, the performance of dish washing detergent compositions
Can find out that from table 8 the pH value of the fruits and vegetables of embodiment 3, dish washing detergent compositions is 6.5 (recording with PHS-3C numeral pH acidometer), the pH value the same (the pH value of normal skin is between 5.5-6.5) with human epidermal all presents slightly acidic.The Determination of Amino Acids Content value of embodiment 3 is consistent with actual addition.Compare with comparison sample, the dishwashing number of embodiment 3 is 9 deep bids.Well heat-resisting, cold-resistant and centrifugal stability that embodiment 3 has.With do not add amino acid whose comparison sample relatively, embodiment 3 scatters and disappears at the rate % that preserves moisture, to skin moisture-keeping effect and moisture of skin and obviously is superior to comparison sample on the TEWL, under the prerequisite of identical washability, the protection of 3 pairs of skins of embodiment is more obvious.
Therefore, under the situation of life-time service, the fruits and vegetables of embodiment 3, dish washing detergent compositions can obviously improve the water cut of skin, and prevention skin damage and the reparation of promotion damaged skin.
Embodiment 4
According to the formulation content of table 9, tensio-active agent, viscosity modifier, sequestrant, fungicidal preservative, amino acid, pH regulator agent, photostabilizer, inhibitor and essence are joined in the deionized water with random order.Draw samples is also checked according to quality standard.Specification product leave standstill to basic non-foam, can be finished product fruits and vegetables, dish washing detergent compositions.
The prescription of table 9 embodiment 4 fruits and vegetables, dish washing detergent compositions is formed
To the mensuration of the mensuration of the fruits and vegetables of embodiment 4, mensuration that dish washing detergent compositions carries out Determination of Amino Acids Content, detersive power, stability, the rate of preserving moisture %, to the mensuration of skin moisture-keeping effect and the mensuration that moisture of skin scatters and disappears after using the fruits and vegetables, dish washing detergent compositions of embodiment 4, test result is seen table 10.Comparison sample does not add amino acid, and its addition is replaced by water.
The fruits and vegetables of table 10 embodiment 4, the performance of dish washing detergent compositions
Can find out that from table 10 the pH value of the fruits and vegetables of embodiment 4, dish washing detergent compositions is 6.5 (recording with PHS-3C numeral pH acidometer), the pH value the same (the pH value of normal skin is between 5.5-6.5) with human epidermal all presents slightly acidic.The Determination of Amino Acids Content value of embodiment 4 is consistent with actual addition.Compare with comparison sample, the dishwashing number of embodiment 4 is 8 deep bids.Well heat-resisting, cold-resistant and centrifugal stability that embodiment 4 has.With do not add amino acid whose comparison sample relatively, embodiment 4 scatters and disappears at the rate % that preserves moisture, to skin moisture-keeping effect and moisture of skin and obviously is superior to comparison sample on the TEWL, under the prerequisite of identical washability, the protection of 4 pairs of skins of embodiment is more obvious.
Therefore, under the situation of life-time service, the fruits and vegetables of embodiment 4, dish washing detergent compositions can obviously improve the water cut of skin, and prevention skin damage and the reparation of promotion damaged skin.
Embodiment 5
According to the formulation content of table 11, tensio-active agent, viscosity modifier, sequestrant, fungicidal preservative, amino acid, pH regulator agent, photostabilizer, inhibitor and essence are joined in the deionized water with random order.Draw samples is also checked according to quality standard.Specification product leave standstill to basic non-foam, can be finished product fruits and vegetables, dish washing detergent compositions.
The prescription of table 11 embodiment 5 fruits and vegetables, dish washing detergent compositions is formed
To the mensuration of the mensuration of the fruits and vegetables of embodiment 5, mensuration that dish washing detergent compositions carries out Determination of Amino Acids Content, detersive power, stability, the rate of preserving moisture %, to the mensuration of skin moisture-keeping effect and the mensuration that moisture of skin scatters and disappears after using the fruits and vegetables, dish washing detergent compositions of embodiment 5, test result is seen table 12.Comparison sample does not add amino acid, and its addition is replaced by water.
The fruits and vegetables of table 12 embodiment 5, the performance of dish washing detergent compositions
Can find out that from table 12 the pH value of the fruits and vegetables of embodiment 5, dish washing detergent compositions is 6.5 (recording with PHS-3C numeral pH acidometer), the pH value the same (the pH value of normal skin is between 5.5-6.5) with human epidermal all presents slightly acidic.The Determination of Amino Acids Content value of embodiment 5 is consistent with actual addition.Compare with comparison sample, the dishwashing number of embodiment 5 is 9 deep bids.Well heat-resisting, cold-resistant and centrifugal stability that embodiment 5 has.With do not add amino acid whose comparison sample relatively, embodiment 5 scatters and disappears at the rate % that preserves moisture, to skin moisture-keeping effect and moisture of skin and obviously is superior to comparison sample on the TEWL, under the prerequisite of identical washability, the protection of 5 pairs of skins of embodiment is more obvious.
Therefore, under the situation of life-time service, the fruits and vegetables of embodiment 5, dish washing detergent compositions can obviously improve the water cut of skin, and prevention skin damage and the reparation of promotion damaged skin.
Embodiment 6
According to the formulation content of table 13, tensio-active agent, viscosity modifier, sequestrant, fungicidal preservative, amino acid, pH regulator agent, photostabilizer, inhibitor and essence are joined in the deionized water with random order.Draw samples is also checked according to quality standard.Specification product leave standstill to basic non-foam, can be finished product fruits and vegetables, dish washing detergent compositions.
The fruits and vegetables of table 13 embodiment 6, the prescription of dish washing detergent compositions are formed
To the mensuration of the mensuration of the fruits and vegetables of embodiment 6, mensuration that dish washing detergent compositions carries out Determination of Amino Acids Content, detersive power, stability, the rate of preserving moisture %, to the mensuration of skin moisture-keeping effect and the mensuration that moisture of skin scatters and disappears after using the fruits and vegetables, dish washing detergent compositions of embodiment 6, test result is seen table 14.Comparison sample does not add amino acid, and its addition is replaced by water.
The fruits and vegetables of table 14 embodiment 6, the performance of dish washing detergent compositions
Can find out that from table 14 the pH value of the fruits and vegetables of embodiment 6, dish washing detergent compositions is 6.5 (recording with PHS-3C numeral pH acidometer), the pH value the same (the pH value of normal skin is between 5.5-6.5) with human epidermal all presents slightly acidic.The Determination of Amino Acids Content value of embodiment 6 is consistent with actual addition.Compare with comparison sample, the dishwashing number of embodiment 6 is 14 deep bids.Well heat-resisting, cold-resistant and centrifugal stability that embodiment 6 has.With do not add amino acid whose comparison sample relatively, embodiment 6 scatters and disappears at the rate % that preserves moisture, to skin moisture-keeping effect and moisture of skin and obviously is superior to comparison sample on the TEWL, under the prerequisite of identical washability, the protection of 6 pairs of skins of embodiment is more obvious.
Therefore, under the situation of life-time service, the fruits and vegetables of embodiment 6, dish washing detergent compositions can obviously improve the water cut of skin, and prevention skin damage and the reparation of promotion damaged skin.
Embodiment 7
According to the formulation content of table 15, tensio-active agent, viscosity modifier, sequestrant, fungicidal preservative, amino acid, pH regulator agent, photostabilizer, inhibitor and essence are joined in the deionized water with random order.Draw samples is also checked according to quality standard.Specification product leave standstill to basic non-foam, can be finished product fruits and vegetables, dish washing detergent compositions.
The fruits and vegetables of table 15 embodiment 7, the prescription of dish washing detergent compositions are formed
To the mensuration of the mensuration of the fruits and vegetables of embodiment 7, mensuration that dish washing detergent compositions carries out Determination of Amino Acids Content, detersive power, stability, the rate of preserving moisture %, to the mensuration of skin moisture-keeping effect and the mensuration that moisture of skin scatters and disappears after using the fruits and vegetables, dish washing detergent compositions of embodiment 7, test result is seen table 16.Comparison sample does not add amino acid, and its addition is replaced by water.
The fruits and vegetables of table 16 embodiment 7, the performance of dish washing detergent compositions
Can find out that from table 16 the pH value of the fruits and vegetables of embodiment 7, dish washing detergent compositions is 6.5 (recording with PHS-3C numeral pH acidometer), the pH value the same (the pH value of normal skin is between 5.5-6.5) with human epidermal all presents slightly acidic.The Determination of Amino Acids Content value of embodiment 7 is consistent with actual addition.Compare with comparison sample, the dishwashing number of embodiment 7 is 11 deep bids.Well heat-resisting, cold-resistant and centrifugal stability that embodiment 7 has.With do not add amino acid whose comparison sample relatively, embodiment 7 scatters and disappears at the rate % that preserves moisture, to skin moisture-keeping effect and moisture of skin and obviously is superior to comparison sample on the TEWL, under the prerequisite of identical washability, the protection of 7 pairs of skins of embodiment is more obvious.
Therefore, under the situation of life-time service, the fruits and vegetables of embodiment 7, dish washing detergent compositions can obviously improve the water cut of skin, and prevention skin damage and the reparation of promotion damaged skin.
Embodiment 8
According to the formulation content of table 17, tensio-active agent, viscosity modifier, sequestrant, fungicidal preservative, amino acid, pH regulator agent, photostabilizer, inhibitor and essence are joined in the deionized water with random order.Draw samples is also checked according to quality standard.Specification product leave standstill to basic non-foam, can be finished product fruits and vegetables, dish washing detergent compositions.
The prescription of table 17 embodiment 8 fruits and vegetables, dish washing detergent compositions is formed
To the mensuration of the mensuration of the fruits and vegetables of embodiment 8, mensuration that dish washing detergent compositions carries out Determination of Amino Acids Content, detersive power, stability, the rate of preserving moisture %, to the mensuration of skin moisture-keeping effect and the mensuration that moisture of skin scatters and disappears after using the fruits and vegetables, dish washing detergent compositions of embodiment 8, test result is seen table 18.Comparison sample does not add amino acid, and its addition is replaced by water.
The fruits and vegetables of table 18 embodiment 8, the performance of dish washing detergent compositions
Can find out that from table 18 the pH value of the fruits and vegetables of embodiment 8, dish washing detergent compositions is 6.5 (recording with PHS-3C numeral pH acidometer), the pH value the same (the pH value of normal skin is between 5.5-6.5) with human epidermal all presents slightly acidic.The Determination of Amino Acids Content value of embodiment 8 is consistent with actual addition.Compare with comparison sample, the dishwashing number of embodiment 8 is 8 deep bids.Well heat-resisting, cold-resistant and centrifugal stability that embodiment 8 has.With do not add amino acid whose comparison sample relatively, embodiment 8 scatters and disappears at the rate % that preserves moisture, to skin moisture-keeping effect and moisture of skin and obviously is superior to comparison sample on the TEWL, under the prerequisite of identical washability, the protection of 8 pairs of skins of embodiment is more obvious.
Therefore, under the situation of life-time service, the fruits and vegetables of embodiment 8, dish washing detergent compositions can obviously improve the water cut of skin, and prevention skin damage and the reparation of promotion damaged skin.
Embodiment 9
According to the formulation content of table 19, tensio-active agent, viscosity modifier, sequestrant, fungicidal preservative, amino acid, pH regulator agent, photostabilizer, inhibitor and essence are joined in the deionized water with random order.Draw samples is also checked according to quality standard.Specification product leave standstill to basic non-foam, can be finished product fruits and vegetables, dish washing detergent compositions.
The prescription of table 19 embodiment 9 fruits and vegetables, dish washing detergent compositions is formed
To the mensuration of the mensuration of the fruits and vegetables of embodiment 9, mensuration that dish washing detergent compositions carries out Determination of Amino Acids Content, detersive power, stability, the rate of preserving moisture %, to the mensuration of skin moisture-keeping effect and the mensuration that moisture of skin scatters and disappears after using the fruits and vegetables, dish washing detergent compositions of embodiment 9, test result is seen table 20.Comparison sample does not add amino acid, and its addition is replaced by water.
The fruits and vegetables of table 20 embodiment 9, the performance of dish washing detergent compositions
Can find out that from table 20 the pH value of the fruits and vegetables of embodiment 9, dish washing detergent compositions is 6.5 (recording with PHS-3C numeral pH acidometer), the pH value the same (the pH value of normal skin is between 5.5-6.5) with human epidermal all presents slightly acidic.The Determination of Amino Acids Content value of embodiment 9 is consistent with actual addition.Compare with comparison sample, the dishwashing number of embodiment 9 is 7 deep bids.Well heat-resisting, cold-resistant and centrifugal stability that embodiment 9 has.With do not add amino acid whose comparison sample relatively, embodiment 9 scatters and disappears at the rate % that preserves moisture, to skin moisture-keeping effect and moisture of skin and obviously is superior to comparison sample on the TEWL, under the prerequisite of identical washability, the protection of 9 pairs of skins of embodiment is more obvious.
Therefore, under the situation of life-time service, the fruits and vegetables of embodiment 9, dish washing detergent compositions can obviously improve the water cut of skin, and prevention skin damage and the reparation of promotion damaged skin.
The above; It only is preferred embodiment of the present invention; Be not that the present invention is done any pro forma restriction; Former every technical scheme content of the present invention that do not break away from, all still belongs in the scope of technical scheme of the present invention any simple modification, equivalent variations and modification that above embodiment did according to technical spirit of the present invention.
Claims (10)
1. fruits and vegetables, dish washing detergent compositions that contains the amino acid composition is characterized in that containing each feed composition of following weight percent:
Tensio-active agent 15.0-50.0%, amino acid 0.1-5.0%, viscosity modifier 0.1-5.0%, sequestrant 0.01-1.0%, fungicidal preservative 0.01-0.5%, other components 0.04-0.1%, surplus is a deionized water.
2. detergent composition according to claim 1 is characterized in that: said amino acid is mixtures any or two or more in L-Ala, l-arginine, l-asparagine, aspartic acid, Gelucystine, Stimulina, L-glutamic acid, leucine, Methionin, methionine(Met), phenylalanine(Phe), proline(Pro), Serine, Threonine, glycocoll, Histidine, Isoleucine, tryptophane, tyrosine, the Xie Ansuan.
3. detergent composition according to claim 1 is characterized in that: said tensio-active agent is at least a or two above mixtures in AS, nonionogenic tenside or the amphoterics.
4. detergent composition according to claim 3 is characterized in that: the AS that contains 5.0-30.0%; Said AS is an any or two or more mixture in polyoxyethylenated alcohol sodium sulfate, AEO carboxylic acid sodium, sodium alkyl sulfate, alkyl sodium sulfonate, α-sodium olefin sulfonate, methyl sodiosul foaliphatate, the sulfo-succinic acid ester sodium salt.
5. detergent composition according to claim 4 is characterized in that: the Fatty Alcohol(C12-C14 and C12-C18) that is used for the synthetic fatty alcohol polyethenoxy ether sodium sulfate can be that natural alcohol also can be a synthol, and the alkyl chain of Fatty Alcohol(C12-C14 and C12-C18) is preferably the straight chained alkyl of 12-16 carbon atom; The average adduct number of the oxyethane of alcohol ether is 1-3.
6. detergent composition according to claim 3 is characterized in that: the nonionic watch active agent that contains 5.0-15.0%; Said nonionogenic tenside is an any or two or more mixture in AEO-9, AEO-7, polyoxyethylene glycol, alkyl-glucoside, monoolein, sucrose ester, fatty acid methyl ester ethoxylate, polyglycerol fatty acid ester, the amine oxide.
7. detergent composition according to claim 3 is characterized in that: the amphoterics that contains 1.0-5.0%; Said amphoterics is an any or two or more mixture in lauryl L-Ala diethanolamine salt, lauryl Sodium L-alaninate, AMONYL 380LC, alkyl hydroxyl sulfopropyl betaine, the tetrahydroglyoxaline.
8. detergent composition according to claim 1 is characterized in that: said viscosity modifier is a mixture any or two or more in sodium-chlor, sodium sulfate, ethanol, Ucar 35, sodium xylene sulfonate, the cumene sodium sulfonate.
9. detergent composition according to claim 1 is characterized in that: said sequestrant is a mixture any or two or more in tetrasodium ethylenediamine tetraacetate, EDTA Disodium, the Hydrocerol A; Said fungicidal preservative is a mixture any or two or more in Sodium Benzoate, methylisothiazolinone, the phenoxyethyl alcohol.
10. according to each described detergent composition among the claim 1-9, it is characterized in that: said other components are photostabilizer, inhibitor, essence, and these components are the universaling component of detergent composition, and kind is not done specific restriction.
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Application publication date: 20120613 |