CN108384655A - A kind of detergent composition and preparation method thereof - Google Patents
A kind of detergent composition and preparation method thereof Download PDFInfo
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- CN108384655A CN108384655A CN201810304294.5A CN201810304294A CN108384655A CN 108384655 A CN108384655 A CN 108384655A CN 201810304294 A CN201810304294 A CN 201810304294A CN 108384655 A CN108384655 A CN 108384655A
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
Abstract
The invention belongs to chemical technology fields, and in particular to a kind of detergent composition is mainly made of following raw material:Chitosan, phenylalanine, benzene sulfonic acid sodium salt, Dodecyl Polyoxyethylene Ether sodium sulphate, ethoxyl chitin, sodium alkyl sulfate, alkyl-glucoside, sodium citrate, dimeticone, triethanolamine and water.The preparation method of the detergent composition includes the following steps:S1, each raw material is weighed in parts by weight, triethanolamine is soluble in water, obtain solution 1;S2, dimeticone is added in solution 1, is stirred and heated to 70~85 DEG C, kept for 20~40 minutes, obtain solution 2;S3, solution 1 is uniformly mixed with solution 2, chitosan, phenylalanine, benzene sulfonic acid sodium salt, Dodecyl Polyoxyethylene Ether sodium sulphate, ethoxyl chitin, sodium alkyl sulfate, alkyl glucose base and sodium citrate are added in solution 2 again, it is stirred and heated to 60~90 DEG C, it is kept for 30~50 minutes, be cooled to 15~25 DEG C to get.The present invention improves detergency.
Description
Technical field
The invention belongs to chemical technology fields, and in particular to a kind of detergent composition and preparation method thereof.
Background technology
Articles for washing exactly chases after clean, health and fashionable life to meet people from its that time being born
It asks.With the fast development of domestic economy and society, people are higher and higher to the pursuit of quality of the life, and detergent industry obtains
Unprecedented rapid development.Currently, detergent product is dazzling on the market, the classification of product more refines, the work(of product
Can more diversification, specialized, emerging in multitude for cleaning product makes the cleanup activities of script very complicated become more convenient, fast
Prompt and safety.When people, which generate detergent, to be relied on and be accustomed to, potential hazard has but quietly been grown.It is close several
Nian Lai, the attention with people to dish washing detergent safety problem, country and various regions superintendent offices also begin to in the market, meal
Liquid detergent in shop is inspected by random samples, as a result, it has been found that, dish washing detergent that either supermarket sells or that restaurant uses, which all exists, to be permitted
Mostly underproof project.The defective item of product quality relates generally to exceeded content of formaldehyde, gross activity object content and detergency
Not up to standard, total number of bacteria and coliform group count are exceeded etc..In addition, in daily life, using liquid detergent, there is also chemical residuals
The problem of, remaining chemicals can there are certain potential hazards to animals and plants.
Invention content
One aspect of the present invention technical problems to be solved are to provide a kind of detergent composition, to improve oil cut rate.
In order to solve the above-mentioned technical problem, the technical scheme is that:
A kind of detergent composition, which is characterized in that be mainly made of following raw material:Chitosan, phenylalanine, benzene sulfonic acid
Sodium, Dodecyl Polyoxyethylene Ether sodium sulphate, ethoxyl chitin, sodium alkyl sulfate, alkyl-glucoside, sodium citrate, two
First silicone oil, triethanolamine and water.
In detergent composition provided by the invention, it is preferable that be mainly made of the raw material of following parts by weight:Shell is poly-
7~28 parts of sugar, 5~19 parts of phenylalanine, 3~9 parts of benzene sulfonic acid sodium salt, 10~31 parts of Dodecyl Polyoxyethylene Ether sodium sulphate, hydroxyl second
15~36 parts of based chitin, 4~14 parts of sodium alkyl sulfate, 2~21 parts of alkyl-glucoside, 3~16 parts of sodium citrate, diformazan
80~150 parts of 5~23 parts of silicone oil, 2~15 parts of triethanolamine and water.
In detergent composition provided by the invention, it is preferable that be mainly made of the raw material of following parts by weight:Shell is poly-
11~24 parts of sugar, 8~15 parts of phenylalanine, 3~5 parts of benzene sulfonic acid sodium salt, 10~22 parts of Dodecyl Polyoxyethylene Ether sodium sulphate, hydroxyl second
18~30 parts of based chitin, 6~11 parts of sodium alkyl sulfate, 5~18 parts of alkyl-glucoside, 7~13 parts of sodium citrate, diformazan
95~140 parts of 8~17 parts of silicone oil, 6~10 parts of triethanolamine and water.
In detergent composition provided by the invention, it is preferable that be mainly made of the raw material of following parts by weight:Shell is poly-
Sugar 16 parts, 13 parts of phenylalanine, 4 parts of benzene sulfonic acid sodium salt, 12 parts of Dodecyl Polyoxyethylene Ether sodium sulphate, 27 parts of ethoxyl chitin,
7 parts of sodium alkyl sulfate, 16 parts of alkyl-glucoside, 9 parts of sodium citrate, 13 parts of dimeticone, 7 parts of triethanolamine and water 125
Part.
The technical problem to be solved is that a kind of preparation methods of detergent composition of offer for another aspect of the present invention, including
Following steps:
S1, each raw material is weighed in parts by weight, triethanolamine is soluble in water, obtain solution 1;
S2, dimeticone is added in solution 1, is stirred and heated to 70~85 DEG C, kept for 20~40 minutes, obtain solution
2;
S3, solution 1 is uniformly mixed with solution 2, then by chitosan, phenylalanine, benzene sulfonic acid sodium salt, lauryl alcohol polyoxyethylene
Ether sodium sulfate, ethoxyl chitin, sodium alkyl sulfate, alkyl glucose base and sodium citrate are added in solution 2, stir and add
Heat to 60~90 DEG C, keep 30~50 minutes, be cooled to 15~25 DEG C to get.
In the preparation method of detergent composition provided by the invention, it is preferable that be heated to 75 DEG C in the step S2.
In the preparation method of detergent composition provided by the invention, it is preferable that be heated to 80 DEG C in the step S3.
Using above-mentioned technical proposal, since detergent composition is gathered by chitosan, phenylalanine, benzene sulfonic acid sodium salt, lauryl alcohol
Ethylene oxide ether sodium sulfate, ethoxyl chitin, sodium alkyl sulfate, alkyl-glucoside, sodium citrate, dimeticone, three second
Hydramine and water, and using rational proportioning so that its detergency improves.Chitosan and phenylalanine wash raising in the present invention
The detergency for washing agent composition has synergistic function.
Specific implementation mode
The specific implementation mode of the present invention is described further below.It should be noted that for these implementations
The explanation of mode is used to help understand the present invention, but does not constitute limitation of the invention.In addition, invention described below
Involved technical characteristic can be combined with each other as long as they do not conflict with each other in each embodiment.
Embodiment 1
A kind of detergent composition is present embodiments provided, is mainly made of the raw material of following parts by weight:Chitosan 28
Part, 5 parts of phenylalanine, 9 parts of benzene sulfonic acid sodium salt, 10 parts of Dodecyl Polyoxyethylene Ether sodium sulphate, 15 parts of ethoxyl chitin, fatty alcohol
80 parts of 14 parts of sodium sulphate, 21 parts of alkyl-glucoside, 3 parts of sodium citrate, 23 parts of dimeticone, 2 parts of triethanolamine and water.
The preparation method of the detergent composition, includes the following steps:
S1, each raw material is weighed in parts by weight, triethanolamine is soluble in water, obtain solution 1;
S2, dimeticone is added in solution 1, is stirred and heated to 85 DEG C, kept for 20 minutes, obtain solution 2;
S3, solution 1 is uniformly mixed with solution 2, then by chitosan, phenylalanine, benzene sulfonic acid sodium salt, lauryl alcohol polyoxyethylene
Ether sodium sulfate, ethoxyl chitin, sodium alkyl sulfate, alkyl glucose base and sodium citrate are added in solution 2, stir and add
Heat to 90 DEG C, keep 50 minutes, be cooled to 15 DEG C to get.
Embodiment 2
A kind of detergent composition is present embodiments provided, is mainly made of the raw material of following parts by weight:Chitosan 7
Part, 19 parts of phenylalanine, 3 parts of benzene sulfonic acid sodium salt, 31 parts of Dodecyl Polyoxyethylene Ether sodium sulphate, 36 parts of ethoxyl chitin, fat
150 parts of 4 parts of alcohol sodium sulphate, 2 parts of alkyl-glucoside, 16 parts of sodium citrate, 5 parts of dimeticone, 15 parts of triethanolamine and water.
The preparation method of the detergent composition, includes the following steps:
S1, each raw material is weighed in parts by weight, triethanolamine is soluble in water, obtain solution 1;
S2, dimeticone is added in solution 1, is stirred and heated to 70 DEG C, kept for 40 minutes, obtain solution 2;
S3, solution 1 is uniformly mixed with solution 2, then by chitosan, phenylalanine, benzene sulfonic acid sodium salt, lauryl alcohol polyoxyethylene
Ether sodium sulfate, ethoxyl chitin, sodium alkyl sulfate, alkyl glucose base and sodium citrate are added in solution 2, stir and add
Heat to 60 DEG C, keep 30 minutes, be cooled to 25 DEG C to get.
Embodiment 3
A kind of detergent composition is present embodiments provided, is mainly made of the raw material of following parts by weight:Chitosan 16
Part, 13 parts of phenylalanine, 4 parts of benzene sulfonic acid sodium salt, 12 parts of Dodecyl Polyoxyethylene Ether sodium sulphate, 27 parts of ethoxyl chitin, fat
125 parts of 7 parts of alcohol sodium sulphate, 16 parts of alkyl-glucoside, 9 parts of sodium citrate, 13 parts of dimeticone, 7 parts of triethanolamine and water.
The preparation method of the detergent composition, includes the following steps:
S1, each raw material is weighed in parts by weight, triethanolamine is soluble in water, obtain solution 1;
S2, dimeticone is added in solution 1, is stirred and heated to 75 DEG C, kept for 35 minutes, obtain solution 2;
S3, solution 1 is uniformly mixed with solution 2, then by chitosan, phenylalanine, benzene sulfonic acid sodium salt, lauryl alcohol polyoxyethylene
Ether sodium sulfate, ethoxyl chitin, sodium alkyl sulfate, alkyl glucose base and sodium citrate are added in solution 2, stir and add
Heat to 80 DEG C, keep 40 minutes, be cooled to 20 DEG C to get.
Embodiment 4
A kind of detergent composition is present embodiments provided, is mainly made of the raw material of following parts by weight:Chitosan 22
Part, 13 parts of phenylalanine, 5 parts of benzene sulfonic acid sodium salt, 21 parts of Dodecyl Polyoxyethylene Ether sodium sulphate, 21 parts of ethoxyl chitin, fat
130 parts of 5 parts of alcohol sodium sulphate, 11 parts of alkyl-glucoside, 6 parts of sodium citrate, 12 parts of dimeticone, 12 parts of triethanolamine and water.
The preparation method of the detergent composition, includes the following steps:
S1, each raw material is weighed in parts by weight, triethanolamine is soluble in water, obtain solution 1;
S2, dimeticone is added in solution 1, is stirred and heated to 75 DEG C, kept for 35 minutes, obtain solution 2;
S3, solution 1 is uniformly mixed with solution 2, then by chitosan, phenylalanine, benzene sulfonic acid sodium salt, lauryl alcohol polyoxyethylene
Ether sodium sulfate, ethoxyl chitin, sodium alkyl sulfate, alkyl glucose base and sodium citrate are added in solution 2, stir and add
Heat to 65 DEG C, keep 35 minutes, be cooled to 20 DEG C to get.
Embodiment 5
A kind of detergent composition is present embodiments provided, is mainly made of the raw material of following parts by weight:Phenylalanine
19 parts, 6 parts of benzene sulfonic acid sodium salt, 15 parts of Dodecyl Polyoxyethylene Ether sodium sulphate, 22 parts of ethoxyl chitin, 7 parts of sodium alkyl sulfate,
120 parts of 14 parts of alkyl-glucoside, 8 parts of sodium citrate, 17 parts of dimeticone, 13 parts of triethanolamine and water.
The preparation method of the detergent composition, includes the following steps:
S1, each raw material is weighed in parts by weight, triethanolamine is soluble in water, obtain solution 1;
S2, dimeticone is added in solution 1, is stirred and heated to 80 DEG C, kept for 30 minutes, obtain solution 2;
S3, solution 1 is uniformly mixed with solution 2, then by chitosan, phenylalanine, benzene sulfonic acid sodium salt, lauryl alcohol polyoxyethylene
Ether sodium sulfate, ethoxyl chitin, sodium alkyl sulfate, alkyl glucose base and sodium citrate are added in solution 2, stir and add
Heat to 68 DEG C, keep 36 minutes, be cooled to 22 DEG C to get.
Embodiment 6
A kind of detergent composition is present embodiments provided, is mainly made of the raw material of following parts by weight:Chitosan 21
Part, 6 parts of benzene sulfonic acid sodium salt, 23 parts of Dodecyl Polyoxyethylene Ether sodium sulphate, 25 parts of ethoxyl chitin, 11 parts of sodium alkyl sulfate,
110 parts of 10 parts of alkyl-glucoside, 8 parts of sodium citrate, 17 parts of dimeticone, 10 parts of triethanolamine and water.
The preparation method of the detergent composition, includes the following steps:
S1, each raw material is weighed in parts by weight, triethanolamine is soluble in water, obtain solution 1;
S2, dimeticone is added in solution 1, is stirred and heated to 77 DEG C, kept for 35 minutes, obtain solution 2;
S3, solution 1 is uniformly mixed with solution 2, then by chitosan, phenylalanine, benzene sulfonic acid sodium salt, lauryl alcohol polyoxyethylene
Ether sodium sulfate, ethoxyl chitin, sodium alkyl sulfate, alkyl glucose base and sodium citrate are added in solution 2, stir and add
Heat to 68 DEG C, 40 minutes, be cooled to 23 DEG C to get.
Test example
In order to verify beneficial effects of the present invention, by GB 9985-2000《Manual dishwashing detergent》Appendix B detergency
Measurement in method one carry out detergency measurement, the results are shown in Table 1.
The detergency result of detergent composition obtained by 1. each embodiment of table
As can be seen from the above table, the dynamic strong detergency of the detergent composition of 1 to 4 gained of embodiment is in embodiment 5 and 6 institutes
Obtain the detergency of detergent.Component lacks chitosan in embodiment 5, and component lacks phenylalanine in embodiment 6, it is seen then that
Chitosan and phenylalanine have synergistic function to the detergency for improving detergent composition.
Embodiments of the present invention are explained in detail above, but the present invention is not limited to described embodiments.It is right
For those skilled in the art, in the case where not departing from the principle of the invention and spirit, these embodiments are carried out more
Kind change, modification, replacement and modification, still fall in protection scope of the present invention.
Claims (7)
1. a kind of detergent composition, which is characterized in that be mainly made of following raw material:Chitosan, phenylalanine, benzene sulfonic acid
Sodium, Dodecyl Polyoxyethylene Ether sodium sulphate, ethoxyl chitin, sodium alkyl sulfate, alkyl-glucoside, sodium citrate, two
First silicone oil, triethanolamine and water.
2. detergent composition according to claim 1, which is characterized in that mainly by the raw material group of following parts by weight
At:7~28 parts of chitosan, 5~19 parts of phenylalanine, 3~9 parts of benzene sulfonic acid sodium salt, Dodecyl Polyoxyethylene Ether sodium sulphate 10~31
Part, 15~36 parts of ethoxyl chitin, 4~14 parts of sodium alkyl sulfate, 2~21 parts of alkyl-glucoside, sodium citrate 3~16
Part, 5~23 parts of dimeticone, 2~15 parts of triethanolamine and 80~150 parts of water.
3. detergent composition according to claim 2, which is characterized in that mainly by the raw material group of following parts by weight
At:11~24 parts of chitosan, 8~15 parts of phenylalanine, 3~5 parts of benzene sulfonic acid sodium salt, Dodecyl Polyoxyethylene Ether sodium sulphate 10~22
Part, 18~30 parts of ethoxyl chitin, 6~11 parts of sodium alkyl sulfate, 5~18 parts of alkyl-glucoside, sodium citrate 7~13
Part, 8~17 parts of dimeticone, 6~10 parts of triethanolamine and 95~140 parts of water.
4. detergent composition according to claim 3, which is characterized in that mainly by the raw material group of following parts by weight
At:16 parts of chitosan, 13 parts of phenylalanine, 4 parts of benzene sulfonic acid sodium salt, 12 parts of Dodecyl Polyoxyethylene Ether sodium sulphate, ethoxy crust
27 parts of element, 7 parts of sodium alkyl sulfate, 16 parts of alkyl-glucoside, 9 parts of sodium citrate, 13 parts of dimeticone, 7 parts of triethanolamine
With 125 parts of water.
5. a kind of preparation method based on Claims 1 to 4 any one of them detergent composition, which is characterized in that including
Following steps:
S1, each raw material is weighed in parts by weight, triethanolamine is soluble in water, obtain solution 1;
S2, dimeticone is added in solution 1, is stirred and heated to 70~85 DEG C, kept for 20~40 minutes, obtain solution 2;
S3, solution 1 is uniformly mixed with solution 2, then by chitosan, phenylalanine, benzene sulfonic acid sodium salt, Dodecyl Polyoxyethylene Ether sulphur
Sour sodium, ethoxyl chitin, sodium alkyl sulfate, alkyl glucose base and sodium citrate are added in solution 2, are stirred and heated to
60~90 DEG C, keep 30~50 minutes, be cooled to 15~25 DEG C to get.
6. the preparation method of detergent composition according to claim 5, which is characterized in that be heated in the step S2
75℃。
7. the preparation method of detergent composition according to claim 5, which is characterized in that be heated in the step S3
80℃。
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Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102492571A (en) * | 2011-11-28 | 2012-06-13 | 广州立白企业集团有限公司 | Detergent composition containing amino acid component for washing fruits, vegetables and dishes |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN102492571A (en) * | 2011-11-28 | 2012-06-13 | 广州立白企业集团有限公司 | Detergent composition containing amino acid component for washing fruits, vegetables and dishes |
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