CN102660399B - Fructo-oligosaccharide enzyme-containing detergent - Google Patents
Fructo-oligosaccharide enzyme-containing detergent Download PDFInfo
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- CN102660399B CN102660399B CN201210151529.4A CN201210151529A CN102660399B CN 102660399 B CN102660399 B CN 102660399B CN 201210151529 A CN201210151529 A CN 201210151529A CN 102660399 B CN102660399 B CN 102660399B
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Abstract
The invention discloses a fructo-oligosaccharide enzyme-containing detergent. The fructo-oligosaccharide enzyme-containing detergent comprises at least one conventional enzyme-containing detergent composition and fructo-oligosaccharide, wherein the mass ratio of the fructo-oligosaccharide to the conventional enzyme-containing detergent composition is less than 300:1,000. The fructo-oligosaccharide enzyme-containing detergent improves decontamination capacity, and also has the advantages of skin health protection, environment friendliness and the like.
Description
Technical field
The invention belongs to washing composition technical field, be specifically related to a kind of oligofructose enzyme-containing detergent.
Background technology
The conventional ingredient of washing composition generally comprises the chemical compositions such as tensio-active agent, washing assistant, SYNTHETIC OPTICAL WHITNER and polymkeric substance.Tensio-active agent can infiltrate blood through skin, and calcium ion concn in blood is declined, and acidification of blood, makes people easily tired, also can cause the decline of liver toxin expelling ability, reduces immunizing power, induces an illness.Phosphate compounds in washing assistant can cause phytoplankton bloom after entering water body, causes body eutrophication.SYNTHETIC OPTICAL WHITNER and hydrolysate thereof, suspension polymer can not be biodegradable completely.The washing composition such as washing powder have become people's daily life indispensable requisites, therefore, improve washing composition, use and are not detrimental to health, and do not destroy ecotope, and energy-efficient washing composition becomes problem demanding prompt solution.At present enzyme is widely used in washing composition as the fill-in of detergent component, compares with the composition such as tensio-active agent, washing assistant, SYNTHETIC OPTICAL WHITNER, and its soil-removing action is stronger, and harmless, be easily degraded, and environmentally safe.In our life, using washing composition is inevitably, therefore, improves washing composition, develops not harmful to human, the washing composition of welding does not become problem demanding prompt solution.
Oligofructose is a kind of natural active matter, and health ministry bulletin (2008 No. 16) has been ratified oligofructose and used as cosmetic material, for suppressing the growth of skin harmful bacteria, has skin care effect.Oligofructose have not been reported as detergent ingredients, and oligofructose has the advantages such as environmental protection, health as detergent ingredients.
Summary of the invention
The technical problem that the present invention mainly solves is to provide and is not a kind ofly detrimental to health, the enzyme-containing detergent of welding not, and further improve the soil removability of enzyme-containing detergent.
For this reason, the invention provides a kind of oligofructose enzyme-containing detergent, contain at least one conventional enzyme-containing detergent constituent, also contain oligofructose, evenly mix in proportion.
Preferably, described oligofructose: the weight ratio of conventional enzyme-containing detergent constituent is less than 300:1000.
Preferably, described oligofructose: the scope of the weight ratio of conventional enzyme-containing detergent constituent is 0.5:1000-300:1000.
Preferably, described oligofructose: the scope of the weight ratio of conventional enzyme-containing detergent constituent is 0.5:1000-50:1000.
Preferably, described oligofructose: the scope of the weight ratio of conventional enzyme-containing detergent constituent is 0.5:1000-25:1000.
The present invention is as a kind of oligofructose enzyme-containing detergent, also contain conventional enzyme-containing detergent constituent, comprise enzyme, tensio-active agent, SYNTHETIC OPTICAL WHITNER, white dyes, enzyme stabilizers, dispersion agent, spot suspension agent, water-softening agent, sanitas, sequestrant, spices etc.Enzyme is mainly one or more in cellulase, hemicellulase, peroxidase, proteolytic enzyme, amylase, zytase, lipase, Phospholipid hydrolase, polygalacturonase, oxydase, reductase enzyme, dextranase.
The formulation of oligofructose enzyme-containing detergent of the present invention can be block, Powdered, particulate state, paste or liquid form.
Oligofructose enzyme-containing detergent of the present invention can be fabric detergent, dish washing detergent, shampoo, Liquid soap, fruits and vegetables washing composition, medical clean-out system etc.
With respect to prior art, beneficial effect of the present invention is, one, oligofructose add the soil removability that has improved enzyme-containing detergent.Its two, the present invention proportionally evenly mixes common conventional enzyme-containing detergent constituent with oligofructose, without special manufacturing process, when improving soil removability, does not increase cost.Its three, newly add composition oligofructose to be all harmful to human health, also pollution-free to environment, there is the advantages such as safety, environmental protection, meanwhile, also there is skin care function.
Accompanying drawing explanation
Fig. 1 is weight ratio and the cotton decontamination proportionlity figure of different amount oligofructoses and conventional enzymatic detergent compositions D.
Embodiment
Below in conjunction with the drawings and specific embodiments, the present invention is described in further detail.
When add oligofructose composition in conventional enzyme-containing detergent, the soil removability of enzyme-containing detergent increases.
Conventional enzyme-containing detergent constituent in the present invention, can be selected from enzyme, tensio-active agent, SYNTHETIC OPTICAL WHITNER, white dyes, enzyme stabilizers, dispersion agent, spot suspension agent, water-softening agent, sanitas, sequestrant, spices etc.
The precise nature of these components and mix content by the physical form that depends on component with and the precise nature of the washing composition operation of application.
Preferred component is an enzyme, and enzyme can be selected from cellulase, hemicellulase, peroxidase, proteolytic enzyme, amylase, zytase, lipase, Phospholipid hydrolase, polygalacturonase, oxydase, reductase enzyme, dextranase or their mixture.
A kind of preferred component is tensio-active agent, it can be aniorfic surfactant, cats product, zwitterionics, nonionic surface active agent and their combination, as tensio-active agent can be selected from carboxylate fluorocarbon surfactant, linear alkyl benzene sulphonic acid (LAS), aliphatic alcohol sulfate (AS or FAS), secondary paraffin sulfonate (SAS), sulfonated α-olefin (AOS), fatty alcohol polyoxyethylene ether sulfate (AES), fatty alcohol-polyoxyethylene ether (AE), methyl ester sulfonate or alpha-sulfo fatty acid methyl ester (MES), APG (APG), N-alkyl glucose amide (AGA), alkylphenol polyoxyethylene (APE), fat alkylolamide (FAA), betanin derivative, imidazolidine derivatives etc. one or more of.
Preferred component is a sanitas, can be parabens (nipagin esters), is mainly its methyl esters, propyl ester, butyl ester etc.; And quaternary ammonium salt surface active agent, O-SyL, Imidurea; Organic acid, as de-acetic acid, M-nitro benzoic acid and its esters, Sorbic Acid and its esters, phenylformic acid and its esters, Whitfield's ointment, phenylic acid; Some fragrance component etc.
A kind of preferred component is sequestrant, heavy metal ion chelating agent is in qualitative acidity, as there is phosphoric acid or carboxylic acid functional, can contend with its acid form and positively charged ion, as the ammonium salt ion of alkalimetal ion, ammonium salt or replacement or the complex compound of its mixture, the form of salt exist.Be preferably organophosphate, as alkylidene group phosphoric acid ester, basic metal ethane, 1-hydroxyl bisphosphate and inferior amino trimethylene methyl phosphorodithioate etc.
Preferred component is a spot suspension agent, can be selected from the one or more of of Walocel MT 20.000PV (sodium), Volpo S 10, polyvinylpyrrolidone, macromolecule polyacrylic acid, Vltra tears, Type 3U, carboxyl methyl starch, natural gum etc.
Preferred component is a water-softening agent, can be selected from the one or more of of phosphoric acid salt, nitrogenous organic sequestering agent and acrylic polymers, Starso, zeolite, sodium carbonate, water glass etc.
Preferred component is a spices, mainly comprises the spices that incapsulates, fragrance precursor, pure fragrance material and composition thereof.Various chemical substances are used to the manufacture of spices as materials such as aldehyde, ketone, esters.The crude vegetal of the complex mixture of various chemical compositions and animal oil and exudate are also used as spice oil.It can be better simply that the present invention's spices used forms, and can be also more complicated, can be natural, or the chemical composition of synthetic.
Those skilled in the art can be according to the applied specific field of washing composition, and actual needs is selected and adjusts.These selections and adjustment all can not produce substantial effect to the present invention.
As when being used for washing clothes, in washing composition of the present invention, also can comprise clothing whitening agent, fabric softening, dyestuff etc.
For the ease of rinsing, can in washing composition, add Yi Pao ﹑ defoamer.
When washing hand liquid ﹑ hand with dish washing detergent etc., also can add and steep ﹑ suds-stabilizing agent.
When washing the crust with firm stain as Lu Zao ﹑ Chui Ju ﹑ wall, can add friction agent, as Shi Ying Sha ﹑ Gui Zao Tu ﹑ Hua Shi Fen ﹑ calcium carbonate etc.
In order to clean coloured dirt as Se Su ﹑ Cha Gou ﹑ Ka Fei Zi ﹑ dish stain etc., can add SYNTHETIC OPTICAL WHITNER and activator, the former is as chloramines T ﹑ DICHLOROISOCYANURIC ACID and ﹑ Lv Suan Na ﹑ Piao Bai Fen ﹑ Guo Peng Suan Na ﹑ SPC-D of Yan thereof etc., and the latter is as tetraacetyl ethylene diamine (TAED) etc.
In order to increase clean bacterium effect, need to add antiseptic-germicide.Conventional antiseptic-germicide has the adjacent phenylester of: Ben Fen ﹑ Jia Fen ﹑ etc.
In order to increase the solubleness of tensio-active agent and auxiliary agent in liquid washing agent, and promote the consistency of each compatibility component to reduce cloud point, can add solubilizing agent, make surface active agent solubilization, can make solution become transparence, prevent Precipitation and be separated.Conventional solubilizing agent has Na Yan ﹑ Jia Yan ﹑ ammonium salt and the Yi Chun ﹑ Yi Bing Chun ﹑ Yi glycol Dan Ding Mi ﹑ alkyl phosphate of Jia Ben Huang Suan ﹑ xylene monosulfonic acid and isopropyl sulfonic acid, urea etc.
For higher liquid or the detergent paste relevant with human body of class, during as Liquid soap, shampoo etc., can add pearling agent, be mainly to give washing composition pearlescent gloss, also can add washing composition stickiness simultaneously, make washing composition outward appearance more beautiful.As ethylene glycol monostearate, Ethylene Glycol Distearate etc.
In addition, oligofructose enzyme-containing detergent of the present invention can, for any form easily, as the liquid of Powdered or particulate solid, bar, tablet or non-water, comprise gel and paste form.When being the enzyme-containing detergent of liquid form, in washing composition of the present invention, can comprise enzyme stabilizers composition, as boric acid etc.Enzyme stabilizers and consumption thereof for liquid washing agent are known for those skilled in the art, and those skilled in the art can select suitable enzyme stabilizers according to actual needs, and the effect of oligofructose in the present invention is not produced to materially affect.
For washing composition being made to liquid or paste, in washing composition, also can add: thickening material, as natural resin is Chenged Shu Zhi ﹑ macrogol ester class, longer chain fatty acid with He, and derivatived cellulose is as carboxymethyl cellulose (CMC), Natvosol, Type 3U, methylhydroxypropylcellulose, sodium-chlor, Repone K, magnesium chloride, ammonium chloride, saltcake etc.; Buffer reagent: have sulfonic acid, citric acid, phosphoric acid, Sodium Tetraborate, a SODIUM PHOSPHATE, MONOBASIC etc. for what regulate pH value.
Embodiment
In order to verify the enhancement of oligofructose to enzyme-containing detergent soil removability, the inventor adopts and add the oligofructose of different ratios in conventional enzyme-containing detergent constituent, and tests the washing effect of enzyme-containing detergent to cotton spot.
test materials
Cotton calico, is cut into 8 cm * 8 cm cloths in test;
Conventional enzyme-containing detergent constituent D: Sodium dodecylbenzene sulfonate 20 wt/%, polyoxyethylenated alcohol sodium sulfate 10wt/%, trolamine 1 wt/%, white dyes 0.3 wt/%, spices 0.2 wt/%, Xylo-Mucine 1 wt/%, water glass 8 wt/%, sodium carbonate 12wt/%, sodium sulfate 10%, 4A zeolite 29.5 wt/%, Sumizyme MP 2 wt/%, alkaline lipase 2 wt/%, cellulase 2 wt/%, amylase 2 wt/%;
Conventional enzyme-containing detergent constituent T: sodium alkyl benzene sulfonate 30 wt/%, tripoly phosphate sodium STPP 17 wt/%, water glass 8 wt/%, sodium carbonate 6 wt/%, Xylo-Mucine 1 wt/%, sodium sulfate 34 wt/%, Sumizyme MP 1 wt/%, alkaline lipase 1 wt/%, cellulase 1 wt/%, amylase 1 wt/%;
Mixing oil spot Ye – presses mass ratio mixing soy sauce and the edible oil preparation of 1:1;
Tomato-sauce spot Ye – tomato-sauce;
Fresh orange-juice spot Ye – shreds orange, mash, and filters.
testing sequence
One, stain the making of stain cloth
Spot is poured in pallet, got after cloth compregnate one time, then by the reverse compregnate of stained cloth one time, naturally dry.
Two, washing process
Take the conventional enzyme-containing detergent constituent of 1 g in large beaker, add the tap water of 200 mL, glass stick stirs enzyme-containing detergent composition is dissolved completely;
Arrange and do not add the control group of oligofructose, and the sample sets that adds 0.0005g, 0.005g, 0.01g, 0.025g, 0.05g, 0.3 g oligofructose, stir, dissolve completely;
In embodiment 1-6, be wherein different ratios oligofructose and the mixing of conventional enzyme-containing detergent constituent D; In embodiment 7-11, be different ratios oligofructose and the mixing of conventional enzyme-containing detergent constituent T.
Put into the cloth with spot prepared by step 1, soaking at room temperature 30 minutes, during every 5 minutes, with glass stick, stir once, each churning time approximately 20 seconds;
Take out cloth, with 2 dehydrations afterwards of the RB50-3012G of Rongshida type automatic washing machine tap water rinsing, under room temperature, naturally dry.
Three, detergency test
Instrument: DATACOLORSF600X blancometer, D65 light source, 10Deg.
Method: the whiteness value by test white cloth before and after washing, evaluate washing effect, whiteness value is higher, illustrates that washing effect is better.At every soiled cotton pros and cons, get 5 tests and average as whiteness value, and be calculated as follows decontamination value R(%):
R(%)=(A2-A1)/(A0-A1) * 100%, wherein A0 is that cloth specimen stains front whiteness value; Al is that cloth specimen stains rear whiteness value; A2 is for staining the rear whiteness value of cloth specimen washing.
According to formula F=R1/R0, calculate decontamination ratio F, wherein R1 is the decontamination value that adds the enzyme-containing detergent of oligofructose; R0 is not for adding the decontamination value of the enzyme-containing detergent of oligofructose.
That is during F > 1, detersive power is stronger than former enzyme-containing detergent; During F=1, detersive power is suitable with former enzyme-containing detergent; During F < 1, detersive power than former enzyme-containing detergent a little less than
The sensory evaluation of four, decontamination effect
The judgement criteria of decontamination effect, is made as five grades, is respectively 1,2,3,4 and 5.1 is that detersive power is the poorest, and 5 is that detersive power is best, and 3 is medium, and 2,4 detersive power is respectively between 1 and 3,3 and 5.5 for loseing spot liquid vestige completely; 4 for substantially loseing spot liquid vestige; 3 is remaining light stains only, and stains area is less than original 50%; 2 is more shallow stains, and stains area does not reduce; 1 for there being darker stains.Each sample has six repetitions, and detersive power effect is passed judgment on by three non-experimenters, to each repeat samples, all will mark, and each appraises for six times cumulatively must to be divided into three judge personnel, and total points is 90 minutes.
test result
Table 1 different ratios oligofructose and conventional enzyme-containing detergent constituent D decontamination value and with conventional enzyme-containing detergent constituent D decontamination ratio
Fig. 1 is the oligofructose of different ratios and the weight ratio of conventional enzymatic detergent compositions and cotton decontamination value variation diagram, the data of associative list 1, visible, added after oligofructose, the weight ratio scope of oligofructose and conventional enzymatic detergent compositions, when 0.5:1000-300:1000, all can make the soil removability of enzyme-containing detergent increase.When scope at 0.5:1000-10:1000 of the weight ratio of oligofructose and conventional enzymatic detergent compositions, soil removability increases gradually, when the weight ratio of oligofructose and conventional enzymatic detergent compositions is 10:1000(embodiment 3) reach maximum value R=87.10, F=1.22, when scope at 10:1000-300:1000 of the weight ratio of oligofructose and conventional enzymatic detergent compositions, decontamination ratio declines to some extent.
Can draw thus, the interpolation of a small amount of oligofructose can significantly increase the soil removability of enzyme-containing detergent, and its clean effect is improved.
Table 2 different ratios oligofructose is evaluated the different spot liquid of cotton soil removability from conventional enzyme-containing detergent constituent D
Detersive power scoring (each 6 are repeated samples, 3 people's scorings add and, full marks 90 minutes)
Table 3 different ratios oligofructose is evaluated the different spot liquid of cotton soil removability from conventional enzyme-containing detergent constituent T
Detersive power scoring (each 6 are repeated samples, 3 people's scorings add and, full marks 90 minutes)
After the oligofructose of different ratios mixes with conventional enzyme-containing detergent constituent, soil removability evaluation is in Table 2 and table 3.As can be seen here, enzyme-containing detergent provided by the present invention is compared with the conventional enzyme-containing detergent constituent that does not contain oligofructose composition, has stronger soil removability.Conventional enzyme-containing detergent constituent D compares and has improved 8.9%-20%(embodiment 2-embodiment 4 with conventional enzyme-containing detergent constituent D with the soil removability of the different ratios mixture mixing oil of oligofructose), the soil removability of tomato-sauce has been improved to 12.8%-33.3%(embodiment 1-embodiment 5).Conventional enzyme-containing detergent constituent T compares and has improved 11%-26%(embodiment 8-embodiment 11 with conventional enzyme-containing detergent constituent T with the soil removability of the different ratios mixture mixing oil of oligofructose), the soil removability of tomato-sauce has been improved to 12.8%-25.6%(embodiment 8-embodiment 11).The mixture of two kinds of conventional enzyme-containing detergent constituents and oligofructose is less to the soil removability increase of orange juice.
Yet, it will be understood by those skilled in the art that, in actual applications, due to needs, consider other factors such as cost, in enzyme-containing detergent of the present invention, the relative content of oligofructose can suitably be chosen within the scope of this, and the amount of the oligofructose that enzyme-containing detergent composition as conventional in every 1000 g is corresponding is less than 300 g, as being 0.5-300 g, or the scope of 0.5-50 g, or 0.5-25 g.Concrete selection foundation and scope can be definite according to practical situation by those skilled in the art, and can therefore not limit the scope of the invention.
Simultaneously, owing to having added the oligofructose composition with multi-biological functional in enzyme-containing detergent, therefore enzyme-containing detergent provided by the present invention is except having high-effective cleansing ability, also there is the multi-biological activity that oligofructose has, as suppress the growth of skin harmful bacteria, this also makes enzyme-containing detergent provided by the present invention have skin care function, has expanded its effect.
In addition, the present invention proportionally evenly mixes common conventional enzyme-containing detergent constituent with oligofructose, without special manufacturing process, does not significantly increase cost when obviously improving soil removability.
The detersive power that can significantly strengthen conventional enzyme-containing detergent constituent about the interpolation of the oligofructose of small amount, contriver thinks that possible reason comprises, oligofructose can strengthen the activity of zymin in conventional enzyme-containing detergent constituent.So, in common conventional enzyme-containing detergent composition, add a small amount of oligofructose, just can reach the effect that strengthens decontamination, have wide range of applications.
About to different sorts spot, the performance difference of the decontamination enhancement of oligofructose, applicant's supposition, this may be because oligofructose causes the difference of heterogeneity spot soil removability the difference of the enzymic activity enhancement of different zymins and washing composition itself.
The above the specific embodiment of the present invention, does not form limiting the scope of the present invention.Various other corresponding changes and distortion that any technical conceive according to the present invention is made, all should be included in the protection domain of the claims in the present invention.
Claims (4)
1. oligofructose enzyme-containing detergent, contains at least one conventional enzyme-containing detergent constituent, it is characterized in that, also contains oligofructose, described oligofructose: the scope of the weight ratio of conventional enzyme-containing detergent constituent is 0.5:1000-50:1000;
Described conventional enzyme-containing detergent constituent is conventional enzyme-containing detergent constituent D or conventional enzyme-containing detergent constituent T;
Described conventional enzyme-containing detergent constituent D is: Sodium dodecylbenzene sulfonate 20wt%, polyoxyethylenated alcohol sodium sulfate 10wt%, trolamine 1wt%, white dyes 0.3wt%, spices 0.2wt%, Xylo-Mucine 1wt%, water glass 8wt%, sodium carbonate 12wt%, sodium sulfate 10wt%, 4A zeolite 29.5wt%, Sumizyme MP 2wt%, alkaline lipase 2wt%, cellulase 2wt%, amylase 2 wt%;
Described conventional enzyme-containing detergent constituent T is: sodium alkyl benzene sulfonate 30wt%, tripoly phosphate sodium STPP 17wt%, water glass 8wt%, sodium carbonate 6wt%, Xylo-Mucine 1wt%, sodium sulfate 34wt%, Sumizyme MP 1wt%, alkaline lipase 1wt%, cellulase 1wt%, amylase 1wt%.
2. oligofructose enzyme-containing detergent according to claim 1, is characterized in that, described oligofructose: the scope of the weight ratio of conventional enzyme-containing detergent constituent is 0.5:1000-25:1000.
3. oligofructose enzyme-containing detergent according to claim 1, is characterized in that, its formulation is block, Powdered, particulate state, paste or liquid form.
4. oligofructose enzyme-containing detergent according to claim 1, is characterized in that, described enzyme-containing detergent is fabric detergent, dish washing detergent, shampoo, Liquid soap, fruits and vegetables washing composition, medical clean-out system.
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| CN102871921A (en) * | 2012-10-15 | 2013-01-16 | 金红叶纸业集团有限公司 | Hand cleaner composition |
| CN103897884A (en) * | 2012-12-26 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Modified washing agent |
| CN103897864A (en) * | 2012-12-26 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Tableware cleaning compound |
| CN103897822A (en) * | 2012-12-27 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Novel daily detergent |
| CN103897850A (en) * | 2012-12-27 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Efficient detergent |
| CN103315921B (en) * | 2013-06-28 | 2014-10-22 | 广州丹奇日用化工厂有限公司 | Shower gel |
| CN104629918A (en) * | 2013-11-14 | 2015-05-20 | 青岛锦涟鑫商贸有限公司 | Improved powerful cloth detergent |
| CN104629960A (en) * | 2013-11-15 | 2015-05-20 | 青岛锦涟鑫商贸有限公司 | Cleaning agent with stable performance |
| CN103695192A (en) * | 2013-11-28 | 2014-04-02 | 南通市通州区大达麻纺织有限公司 | Bactericidal disinfectant for sheet and preparation method thereof |
| CN104120042A (en) * | 2014-06-26 | 2014-10-29 | 济南伟传信息技术有限公司 | Composition for preparing washing powder |
| CN104789396B (en) * | 2015-05-12 | 2017-11-28 | 保山市新华肥皂有限责任公司 | The method that fragrant fruit oil soap powder is prepared using high tower spray drying |
| CN105368613A (en) * | 2015-11-19 | 2016-03-02 | 骆雪琦 | Bio-enzyme liquid laundry detergent |
| CN107982135A (en) * | 2017-12-25 | 2018-05-04 | 深圳市芭格美生物科技有限公司 | A kind of shampoo and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1332787A (en) * | 1998-10-23 | 2002-01-23 | 宝洁公司 | Fabrid care composition and method |
| CN102260607A (en) * | 2011-07-13 | 2011-11-30 | 广州市正阳工业科技有限公司 | Food detergent |
-
2012
- 2012-05-16 CN CN201210151529.4A patent/CN102660399B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1332787A (en) * | 1998-10-23 | 2002-01-23 | 宝洁公司 | Fabrid care composition and method |
| CN102260607A (en) * | 2011-07-13 | 2011-11-30 | 广州市正阳工业科技有限公司 | Food detergent |
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