CN103881838B - Fructus Sapindi Mukouossi fluid composition, dish washing detergent containing Fructus Sapindi Mukouossi fluid composition - Google Patents
Fructus Sapindi Mukouossi fluid composition, dish washing detergent containing Fructus Sapindi Mukouossi fluid composition Download PDFInfo
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- CN103881838B CN103881838B CN201410084175.5A CN201410084175A CN103881838B CN 103881838 B CN103881838 B CN 103881838B CN 201410084175 A CN201410084175 A CN 201410084175A CN 103881838 B CN103881838 B CN 103881838B
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Abstract
The invention discloses a kind of Fructus Sapindi Mukouossi fluid composition, it includes the following component of weight portion: the fermentation of sapindust saponin rhamnolipid refines thing 38 parts, sapindust saponin lactate fermentation refines thing 26 parts, Gleditisia sinensis Saponin alcohol fermentation refines thing 35 parts, Lipolase lipase 0.02 0.5 parts, pectase 0.01 0.3 parts, 0.2 0.5 parts of sodium chloride, sodium citrate 0.5 3 parts, 70 90 parts of water.The present invention uses the refined thing of fermentation to substitute Fructus Sapindi Mukouossi or Fructus Gleditsia extracting solution, the impurity such as the saccharide in extracting solution, protein can be converted into the useful constituent of detergent, can increase substantially the stability of fluid product simultaneously；The refined thing of sapindust saponin rhamnolipid fermentation is the complex of Saponin and rhanolipid as biosurfactant, thus effectively overcomes the defect that sapindust saponin surface activity is poorer than synthetic surfactant.
Description
Technical field
The invention belongs to composition of detergent field, be specifically related to a kind of containing soapberry extract
Composition of detergent.
Background technology
Dish washing detergent is the light-duty detergent used in kitchen, usually liquid, is life
In indispensable article of everyday use, occupy the second largest kind in liquid detergent.Conventional cutlery is washed
Washing agent is synthetic detergent, mainly use sodium lauryl sulphate, dodecylbenzene sodium sulfonate,
Dodecyl-β-D-Maltose glycosides, lauryl dimethyl sulfoacetic acid sodium etc. are as surface activity
Agent, then add that the compositions such as some thickening agents, emulsifying agent, foaming agent and fluorescent whitening agent are compounding to be formed.
Along with renewal and progress, the growth in the living standard of people's philosophy of life, daily washing is
Become can not be default in most consumer daily life content.But for a long time, with oil
The surfactant of derivant synthesis becomes the main flow of lotion always, not only directly contributes skin mistake
Quick and damaged hair, the chemical substance of accumulation also pollutes the environment, and endangers organism in water, along with
Food chain will affect again the health of people.Additionally, industrialized large-scale production has attached in a large number
Chemical refuse, causes water clarity decline, dissolved oxygen deficit, fish and shrimp death, drinking water source to be disliked
The environmental problems such as change.
Synthesis dish washing detergent can suppress endocrine system rich in Environmental Hormone, Environmental Hormone
System, and change biological vivo immunization nerve and other physiological actions, cause all kinds of cancer and child
Grow abnormal etc..Surfactant sodium alkyl benzene sulfonate and sodium alkyl sulfonate can kill animal
Sperm, makes animal weaken or loses fertility.Therefore, various countries are concerned about natural nothing again
In the exploitation of the washing material of evil, it is whole world daily use chemicals, food in " green, nature and environmental protection "
Deng in the main flow cry of consumer nondurable goods industry, with biological preparation, plant extract as representative
Daily cleaning product, along with back to nature rise in the world, will replace people the most undoubtedly
Work sintetics.
The natural surfactant composition that plant extract such as Fructus Sapindi Mukouossi etc. extract will not bring glimmering
The negative issues such as photo etching, Environmental Hormone, rivers and creeks are oxygen enrichment.Exploitation and serviceability superior,
Ecological friendly articles for washing has become the Ecosystem Responsibility of detergent manufacturer and user.Cause
This, use reproducible plant resources, produces degradable cleaning product, will be human survival
Inexorable trend.But natural Saponin there is also some shortcomings such as some surface active property than synthesis table
Face activating agent is slightly worse, containing the impurity such as saccharide, protein in the natural extract containing Saponin, this
The purity of a little impurity effect products and stability, and remove these impurity and can increase considerably product
Production cost.
Patent CN103242976A discloses Soapberry vegetable-fruit washing-up liquid, patent
CN102935050A discloses a kind of Soapberry hand sanitizer and preparation method thereof, patent
CN102940603A discloses a kind of Soapberry bath foam, and patent CN102949318A is open
A kind of Soapberry shampoo and preparation technology thereof, patent CN102965217A discloses one
Soapberry liquid laundry detergent, patent CN102559422B discloses Fructus Sapindi Mukouossi cleaning agent and manufacturer thereof
Method, patent CN102397183A discloses Radix Ginseng, Fructus Sapindi Mukouossi fermented product extract and is making up
Application in terms of product, it is natural that patent CN102080028B discloses a kind of shield-fern, Fructus Sapindi Mukouossi
The preparation of biomass detergent and method thereof, patent CN102241725A discloses daily use chemicals nothing
The water suffering from sub-saponin obtains through refining Preparation Method, and patent CN1344537A discloses Fructus Sapindi Mukouossi dandruff-removing itching-relieve
Shampoo.The common trait of these patents is all to have employed that soapberry extract is natural, environment is friendly
Good some surface active property, but it is all to directly utilize extract, but also with the addition of synthesis table
Face activating agent, some formula also added preservative and the stabilizer etc. of synthesis.Patent
201310020396.1 disclose the natural Saponin of a kind of extraction and the compound product of biosurfactant
The method of thing, patent 201210211918.1 discloses the fermentation of a kind of sapindust saponin extract
Process for purification, patent 0510011673.8 discloses a kind of Gleditisia sinensis Saponin preparation technology and answers
With, these three patent proposes the process for purification of natural Saponin from different perspectives.
Summary of the invention
It is an object of the invention to utilize raw material based on Fructus Sapindi Mukouossi and Fructus Gleditsia extract, it is thus achieved that real
The efficient cryogenic dishwashing detergent Fructus Sapindi Mukouossi fluid composition of the pure natural of meaning, existing in order to solve
There is problem present in detergent technical field.
For realizing the purpose of the present invention, concrete technical scheme is:
A kind of Fructus Sapindi Mukouossi fluid composition, it includes the following component of weight portion:
The refined thing 3-8 part of sapindust saponin rhamnolipid fermentation, sapindust saponin lactate fermentation essence
Thing 2-6 part processed, Gleditisia sinensis Saponin alcohol fermentation refine thing 3-5 part, Lipolase lipase 0.02-0.5
Part, pectase 0.01-0.3 part, sodium chloride 0.2-0.5 part, sodium citrate 0.5-3 part, water 70-90
Part.
Preferably, described Fructus Sapindi Mukouossi fluid composition includes the following component of weight portion:
The refined thing 5-8 part of sapindust saponin rhamnolipid fermentation, sapindust saponin lactate fermentation essence
Thing 4-6 part processed, Gleditisia sinensis Saponin alcohol fermentation refine thing 3-5 part, Lipolase lipase 0.02-0.5
Part, pectase 0.1-0.3 part, sodium chloride 0.2-0.5 part, sodium citrate 0.5-3 part, water 70-90
Part.
Wherein, the preparation method of the refined thing of described sapindust saponin rhamnolipid fermentation is: without suffering from
Sub-peel is 1:8 with the weight ratio of water, and Extracting temperature is 50-60 DEG C, and extraction time is 3-5h,
Extracting solution is filtered；600-800IU cellobiase/L, 40-50 DEG C of saccharifying is added in filtrate
Hydrolysis 40-50h；In the hydrolyzed solution that hydrolysis obtains, add 20-30g/L soybean oil, be concurrently accessed
The Pseudomonas aeruginosa of 12-18% (weight ratio i.e. accounts for the weight ratio of complete soln), sends out for 30 DEG C
Ferment 72h, fermentation liquid sterilizing centrifugal filtration, filtrate is sapindust saponin rhamnolipid ferment essence
Thing processed.
Preferably, described vegetable oil is soybean oil, Semen Maydis oil or olive oil, obtains to hydrolysis
Hydrolyzed solution adds 20g/L vegetable oil.
Wherein, described Pseudomonas aeruginosa (Pseudomonas aeruginosa), belong to non-
Ferment gram negative bacilli, commercially available.
Wherein, described sapindust saponin lactate fermentation refines the preparation method of thing and is: Fructus Sapindi Mukouossi fruit
The weight ratio of Pi Yushui is 1:7-9, and Extracting temperature is 45-55 DEG C, and extraction time is 3-5h, will
Extracting solution filters；500-600IU cellobiase/L, 40-50 DEG C of saccharifying water is added in filtrate
Solve 35-40h；6-8% (accounting for the weight ratio of complete soln) is accessed in the hydrolyzed solution that hydrolysis obtains
Lactic acid bacteria fermentation, fermentation liquid sterilizing centrifugal filtration, filtrate is sapindust saponin lactate fermentation
Refined thing.
Wherein, described lactic acid bacteria can be selected for the lactobacillus thermophilus of conventional commercial.
Wherein, described Gleditisia sinensis Saponin alcohol fermentation refines the preparation method of thing and is: Fructus Gleditsia peel with
The weight ratio of water is 1:6-10, and Extracting temperature is 40-60 DEG C, and extraction time is 2-4h, will extract
Liquid filters；Accessing the Angel activated yeast of 10-13% (weight ratio) in filtrate, fermentation liquid goes out
Bacterium centrifugal filtration, filtrate is Gleditisia sinensis Saponin alcohol fermentation and refines thing.
Preferably, 38 DEG C of fermentation 72h after the activated yeast of Angel are accessed.
Wherein, Angel activated yeast is high temperature resistant type distillery yeast.
The beneficial effects of the present invention is:
(1) the refined thing of fermentation is used to substitute Fructus Sapindi Mukouossi or Fructus Gleditsia extracting solution, can be by extracting solution
Saccharide, the impurity such as protein be converted into the useful constituent of detergent, can significantly carry simultaneously
The stability of high fluid product；
(2) the refined thing of sapindust saponin rhamnolipid fermentation is Saponin and biosurfactant
The complex of rhamnolipid, thus effectively overcome sapindust saponin surface activity (critical micell
Concentration, surface tension, foaming properties) defect poorer than synthetic surfactant；
(3) in sapindust saponin rhamnolipid fermentation refined thing preparation, 20g/L Semen sojae atricolor is added
Oil can promote the generation of surfactant lipophilic group, significantly reduces solution surface tension, Fructus rhamni (Rhamnus davurica Pall.)
The detersive efficiency of oil substances is also increased substantially by glycolipid.
(4) preparation of fermentation refined thing uses higher strain inoculum concentration (Pseudomonas aeruginosa
15%, lactic acid bacteria 7%, Angel activated yeast 13%), can not use minor metallic element and
Culture medium, effectively prevent heavy metal pollution, can shorten fermentation Refining times simultaneously；
(5) biocidal property of Gleditisia sinensis Saponin, the antibiotic property of sapindust saponin and Gleditisia sinensis Saponin ethanol
Ethanol in the refined thing of fermentation determines Fructus Sapindi Mukouossi fluid composition and has antibacterial activity；
(6) sapindust saponin lactate fermentation refines the lactic acid in thing and can serve as Fructus Sapindi Mukouossi liquid
The pH adjusting agent of compositions；
(7) group of sapindust saponin, Gleditisia sinensis Saponin, rhamnolipid, lipase and pectase
Close, can be easy to wash away the oils and fats of tableware, glucide and pectin substance etc., therefore this meal
Tool washing Fructus Sapindi Mukouossi fluid composition has the feature such as low temperature, efficient, nontoxic, environmental friendliness.
Detailed description of the invention
Following example are used for illustrating the present invention, but are not limited to the scope of the present invention.
In embodiment, the Pseudomonas aeruginosa (Pseudomonas aeruginosa) used
Purchased from China General Microbiological culture presevation administrative center (preserving number CGMCC1.50).
Wherein, described lactic acid bacteria is lactobacillus thermophilus, purchased from Harbin China of U.S. biotechnology share
Company limited.
Wherein, Angel activated yeast is high temperature resistant type distillery yeast, conventionally activates.
Embodiment 1
The preparation method of the refined thing of sapindust saponin rhamnolipid fermentation is:
The weight ratio of peel of Fructus Sapindi Mukouossi and water is 1:8, and Extracting temperature is 55 DEG C, and extraction time is
4h, filters extracting solution；700IU cellobiase/L, 45 DEG C of saccharifying water are added in filtrate
Solve 48h；In the hydrolyzed solution that hydrolysis obtains, add 20g/L soybean oil, be concurrently accessed 15% and (account for
The weight ratio of complete soln) Pseudomonas aeruginosa, 30 DEG C fermentation 72h, fermentation liquid sterilizing from
The heart filters, and filtrate is the refined thing of sapindust saponin rhamnolipid fermentation.
Sapindust saponin lactate fermentation refines the preparation method of thing:
The weight ratio of peel of Fructus Sapindi Mukouossi and water is 1:8, and Extracting temperature is 50 DEG C, and extraction time is
4h, filters extracting solution；500IU cellobiase/L, 45 DEG C of saccharifying water are added in filtrate
Solve 36h；In the hydrolyzed solution that hydrolysis obtains, access the lactic acid bacteria of 7% (weight ratio), send out for 42 DEG C
Ferment 60h, fermentation liquid sterilizing centrifugal filtration, filtrate is sapindust saponin lactate fermentation and refines thing.
Gleditisia sinensis Saponin alcohol fermentation refines the preparation method of thing:
Fructus Gleditsia peel is 1:8 with the weight ratio of water, and Extracting temperature is 50 DEG C, and extraction time is 2h,
Extracting solution is filtered；The Angel activated yeast of access 13% (weight ratio) in filtrate, 38
DEG C fermentation 72h, fermentation liquid sterilizing centrifugal filtration, filtrate be Gleditisia sinensis Saponin alcohol fermentation refine
Thing.
Embodiment 2
The fermentation of sapindust saponin rhamnolipid refined thing 8kg, the Fructus Sapindi Mukouossi that embodiment 1 is prepared
Saponin lactate fermentation refines thing 6kg, Gleditisia sinensis Saponin alcohol fermentation refines thing 5kg, and
Lipolase lipase 0.5kg, pectase 0.3kg, sodium chloride 0.5kg and sodium citrate 3kg
Join in water 76.7kg deionized water, be heated to 45 DEG C, mix homogeneously, it is cooled to room temperature,
I.e. prepare this dishwashing detergent Fructus Sapindi Mukouossi fluid composition.
Rate method of deoiling in measuring by GB9985 2000 Appendix B detergency records detergency and is
68.4%；The Fructus Sapindi Mukouossi fluid composition prepared is made into the solution of 10%, uses JZHY-
It is 34.5mN/m that 180 interfacial tensimeters record its surface tension.
Embodiment 3
The fermentation of sapindust saponin rhamnolipid refined thing 5kg, the Fructus Sapindi Mukouossi that embodiment 1 is prepared
Saponin lactate fermentation refines thing 4kg, Gleditisia sinensis Saponin alcohol fermentation refines thing 3kg, and
Lipolase lipase 0.02kg, pectase 0.01kg, sodium chloride 0.2kg and sodium citrate 0.5kg
Join in water 87.27kg deionized water, be heated to 45 DEG C, mix homogeneously, it is cooled to room temperature,
I.e. prepare this dishwashing detergent Fructus Sapindi Mukouossi fluid composition.
Rate method of deoiling in measuring by GB9985 2000 Appendix B detergency records detergency and is
53.0%；The Fructus Sapindi Mukouossi fluid composition prepared is made into the solution of 10%, uses JZHY-
It is 42.7mN/m that 180 interfacial tensimeters record its surface tension.
Embodiment 4
The fermentation of sapindust saponin rhamnolipid refined thing 7kg, the Fructus Sapindi Mukouossi that embodiment 1 is prepared
Saponin lactate fermentation refines thing 5kg, Gleditisia sinensis Saponin alcohol fermentation refines thing 4kg, and
Lipolase lipase 0.3kg, pectase 0.1kg, sodium chloride 0.3kg and sodium citrate 1kg
Join in water 82.3kg deionized water, be heated to 45 DEG C, mix homogeneously, it is cooled to room temperature,
I.e. prepare this dishwashing detergent Fructus Sapindi Mukouossi fluid composition.
Rate method of deoiling in measuring by GB9985 2000 Appendix B detergency records detergency and is
62.5%；The Fructus Sapindi Mukouossi fluid composition prepared is made into the solution of 10%, uses JZHY-
It is 36.9mN/m that 180 interfacial tensimeters record its surface tension.
Embodiment 5
The fermentation of sapindust saponin rhamnolipid refined thing 3kg, the Fructus Sapindi Mukouossi that embodiment 1 is prepared
Saponin lactate fermentation refines thing 5kg, Gleditisia sinensis Saponin alcohol fermentation refines thing 4kg, and
Lipolase lipase 0.3kg, pectase 0.1kg, sodium chloride 0.3kg and sodium citrate 1kg
Join in water 82.3kg deionized water, be heated to 45 DEG C, mix homogeneously, it is cooled to room temperature,
I.e. prepare this dishwashing detergent Fructus Sapindi Mukouossi fluid composition.
Rate method of deoiling in measuring by GB9985 2000 Appendix B detergency records detergency and is
50.5%；The Fructus Sapindi Mukouossi fluid composition prepared is made into the solution of 10%, uses JZHY-
It is 43.9mN/m that 180 interfacial tensimeters record its surface tension
Embodiment 7:
The fermentation of sapindust saponin rhamnolipid refined thing 5kg, the Fructus Sapindi Mukouossi that embodiment 1 is prepared
Saponin lactate fermentation refines thing 2kg, Gleditisia sinensis Saponin alcohol fermentation refines thing 4kg, and
Lipolase lipase 0.3kg, pectase 0.1kg, sodium chloride 0.3kg and sodium citrate 1kg
Join in water 82.3kg deionized water, be heated to 45 DEG C, mix homogeneously, it is cooled to room temperature,
I.e. prepare this dishwashing detergent Fructus Sapindi Mukouossi fluid composition.
Rate method of deoiling in measuring by GB9985 2000 Appendix B detergency records detergency and is
52.3%；The Fructus Sapindi Mukouossi fluid composition prepared is made into the solution of 10%, uses JZHY-
It is 43.0mN/m that 180 interfacial tensimeters record its surface tension.
Comparative example:
By Fructus Sapindi Mukouossi aqueous extract, (peel of Fructus Sapindi Mukouossi is 1:6 with the weight ratio of water, 55 DEG C of extractions
Time is 4h, is filtrated to get Fructus Sapindi Mukouossi aqueous extract) 9kg, Fructus Gleditsia aqueous extract (Fructus Gleditsia fruit
The weight ratio of Pi Yushui is 1:8, and 50 DEG C of extraction times are 2h, are filtrated to get Fructus Gleditsia aqueous extract)
3kg, Lipolase lipase 0.02kg, pectase 0.01kg, sodium chloride 0.2kg and citric acid
Sodium 0.5kg joins in water 87.27kg deionized water, is heated to 45 DEG C, and mix homogeneously is cold
But to room temperature, this dishwashing detergent Fructus Sapindi Mukouossi fluid composition is i.e. prepared.
Rate method of deoiling in measuring by GB9985 2000 Appendix B detergency records detergency and is
42.2%；The Fructus Sapindi Mukouossi fluid composition prepared is made into the solution of 10%, uses JZHY-
It is 45.3mN/m that 180 interfacial tensimeters record its surface tension.
Above embodiment is only to be described the preferred embodiment of the present invention, the most right
The scope of the present invention is defined, on the premise of designing spirit without departing from the present invention, and this area
Various modification that technical scheme is made by ordinary skill technical staff and improvement, all should
Fall in the protection domain that claims of the present invention determines.
Claims (5)
1. a Fructus Sapindi Mukouossi fluid composition, is made up of the following component of weight portion:
The refined thing 3-8 part of sapindust saponin rhamnolipid fermentation, sapindust saponin lactate fermentation essence
Thing 2-6 part processed, Gleditisia sinensis Saponin alcohol fermentation refine thing 3-5 part, Lipolase lipase 0.02-0.5
Part, pectase 0.01-0.3 part, sodium chloride 0.2-0.5 part, sodium citrate 0.5-3 part, water 70-90
Part；
Wherein, the preparation method of the refined thing of described sapindust saponin rhamnolipid fermentation is: without suffering from
Sub-peel is 1:8 with the weight ratio of water, and Extracting temperature is 50-60 DEG C, and extraction time is 3-5h,
Extracting solution is filtered；600-800IU cellobiase/L, 40-50 DEG C of saccharifying is added in filtrate
Hydrolysis 40-50h；In the hydrolyzed solution that hydrolysis obtains, add 20-30g/L soybean oil, be concurrently accessed
Weight ratio is the Pseudomonas aeruginosa of 12-18%, and 30 DEG C of fermentation 72h, fermentation liquid sterilizing was centrifuged
Filter, filtrate is the refined thing of sapindust saponin rhamnolipid fermentation；
Described Gleditisia sinensis Saponin alcohol fermentation refines the preparation method of thing: Fructus Gleditsia peel and the weight of water
Amount ratio is 1:6-10, and Extracting temperature is 40-60 DEG C, and extraction time is 2-4h, is filtered by extracting solution；
Accessing the Angel activated yeast that weight ratio is 10-13% in filtrate, fermentation liquid sterilizing was centrifuged
Filter, filtrate is Gleditisia sinensis Saponin alcohol fermentation and refines thing.
Fructus Sapindi Mukouossi fluid composition the most according to claim 1, it is characterised in that by weight
The following component composition of amount part:
The refined thing 5-8 part of sapindust saponin rhamnolipid fermentation, sapindust saponin lactate fermentation essence
Thing 4-6 part processed, Gleditisia sinensis Saponin alcohol fermentation refine thing 3-5 part, Lipolase lipase 0.02-0.5
Part, pectase 0.1-0.3 part, sodium chloride 0.2-0.5 part, sodium citrate 0.5-3 part, water 70-90
Part.
Fructus Sapindi Mukouossi fluid composition the most according to claim 1, it is characterised in that described
In the preparation method of the refined thing of sapindust saponin rhamnolipid fermentation, the hydrolyzed solution obtained to hydrolysis
Middle addition 20g/L soybean oil.
Fructus Sapindi Mukouossi fluid composition the most according to claim 1 and 2, it is characterised in that
Described sapindust saponin lactate fermentation refines the preparation method of thing: peel of Fructus Sapindi Mukouossi and the weight of water
Amount ratio is 1:7-9, and Extracting temperature is 45-55 DEG C, and extraction time is 3-5h, is filtered by extracting solution；
500-600IU cellobiase/L, 40-50 DEG C of saccharification 35-40h is added in filtrate；To
Accessing weight ratio in the hydrolyzed solution that obtains of hydrolysis is the lactic acid bacteria fermentation of 6-8%, fermentation liquid sterilizing from
The heart filters, and filtrate is sapindust saponin lactate fermentation and refines thing.
Fructus Sapindi Mukouossi fluid composition the most according to claim 1, it is characterised in that access
38 DEG C of fermentation 72h after the activated yeast of Angel.
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| CN105861201B (en) * | 2016-04-19 | 2018-04-27 | 和和实业股份有限公司 | It is the method that part material prepares cleaning supplies with soapberry pulp |
| CN106010807B (en) * | 2016-06-08 | 2018-05-18 | 大连莱恩医疗工业有限公司 | A kind of multienzyme cleaning agent for stain on medical instrument |
| CN106190651A (en) * | 2016-07-20 | 2016-12-07 | 福州喜自然生物科技有限公司 | A kind of zinc cation liquid and preparation method thereof |
| CN106214557A (en) * | 2016-08-25 | 2016-12-14 | 吴留香 | The preparation method of purely-natural liquid shampoo |
| CN106591013A (en) * | 2016-11-30 | 2017-04-26 | 大连百奥泰科技有限公司 | Biological detergent composition |
| CN109464377B (en) * | 2018-12-29 | 2021-06-08 | 泉州市倍斯豪日用品有限公司 | Biological antibacterial shower gel and preparation method thereof |
| CN109536296B (en) * | 2018-12-29 | 2021-02-02 | 广东居美日用品有限公司 | Antibacterial biological detergent for infants and preparation method thereof |
| CN113583065B (en) * | 2021-07-30 | 2023-02-28 | 广州德谷个人护理用品有限公司 | Natural saponin stabilization method |
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| CN101649258A (en) * | 2009-08-31 | 2010-02-17 | 广州立白企业集团有限公司 | Tableware detergent with enzyme and preparation method thereof |
| CN102719491B (en) * | 2012-06-21 | 2014-07-16 | 北京林业大学 | Fermentation and refining method for sapindus mukurossi saponin extract |
| CN103088101B (en) * | 2013-01-18 | 2014-12-10 | 北京林业大学 | Method for extracting natural saponin and biosurfactant composite product |
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