CN106591013A - Biological detergent composition - Google Patents
Biological detergent composition Download PDFInfo
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- CN106591013A CN106591013A CN201611085779.7A CN201611085779A CN106591013A CN 106591013 A CN106591013 A CN 106591013A CN 201611085779 A CN201611085779 A CN 201611085779A CN 106591013 A CN106591013 A CN 106591013A
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- Prior art keywords
- extract
- biocleaner
- detergent
- compositionss
- enzyme
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Abstract
The invention relates to a biological detergent composition. The biological detergent composition is prepared from a biological surfactant, a plant surface active agent, a biological enzyme and at least one washing auxiliary material. In the biological detergent, the biological surfactant is compounded with the plant surface active agent, the biological enzyme and other adjuvant agents. The detergent is reasonable in formula, the total content of active matters is high, and through complex synergism, the washing effect can fully meet the needs of people.
Description
Technical field
The present invention relates to by biosurfactant, plant surface activating agent, enzyme and at least one washing adminicle
The composition of detergent of matter composition.
Background of invention
It is the conventional method of dirt and spot with composition of detergent laundering of textile fabrics, tableware or other host materials.
As the development of society, people are increasing to the demand of detergent, the use of synthetic detergent is also more and more extensive.Synthesis is washed
The surfactant for washing agent to synthesize, such as sodium alkyl benzene sulfonate, alkylsulfonate, alkenyl sulphonate, fatty alcohol-polyoxyethylene ether
Sulfate, alkyl sulfate, fatty alcohol-polyoxyethylene ether etc. are main component.This kind of material is mostly
Material synthesis.This kind of surfactant can rapidly dissolve in water, show good moistening, dispersion, emulsifying, lyotropy
Energy.Detergent manufacturers based on cost, income and clean result consideration, substantial amounts of and new synthetic detergent produced and
Sale.
Although synthetic detergent can reach the beneficial effect of the materials such as fabric, tableware cleaning, because people are to synthesis
There are some misgivings in the potential security risk of detergent；Or the environmental hazard risk that these synthetic detergents may bring；Make one
The biosurfactant higher to traditional cleaning ingredients from plant, safety into and green safety, environmental protection
Efficient biological effect, increasingly payes attention to and approves.These make consumers in general to safe and efficient, eco-friendly detergent
Demand it is more and more urgent.
What is be contrasted with synthetic detergent is biocleaner with Bio-surface active as primary raw material.Biological surface
Activating agent is microorganism, including antibacterial, yeast and funguses, under certain condition during fermentation culture, secretion produce with certain
The metabolite of surface activity, the such as rhamnolipid of glycolipid class, sophorolipid, and table cytokines (surfactin), the phenol of lipopeptid class
Interleukin (fengycin) etc..It is same as surfactant, these biosurfactants have reduce surface tension, solubilising,
Outside the effect of stable emulsion, also with the environmental friendliness not available for general synthetic surfactant, biodegradable, nothing
Poison, the advantages of gently stimulation.
Detergent researcher both domestic and external has also noticed that potential application of the biosurfactant in washing field.Such as
Chinese patent《A kind of preparation methoies of microbial detergent of CN103146496》Disclose a kind of system containing biosurfactant
Preparation Method：The rhamnolipid extraction, sucrose fatty acid ester, enzyme and the EDTA additions that obtain after rhamnolipid fermentation liquor will be separated
Into lipopeptid fermentation liquid, that is, obtain the microbial detergent described in it.But because the rhamnolipid in the detergent, lipopeptid have
Effect content is low, sucrose fatty acid ester scourability is not good and addition is not high, causes the active matter total amount of the detergent relatively low,
It is difficult to reach preferable clean result.
Patent application of the Unilever NV in China《CN103052703 comprising biosurfactant and
The composition of detergent of lipase》Comprising at least Glycolipids Biosurfactantss of 1wt% in disclosed cleanser compositions
And the lipase of at least one bacterial origin.The patent application equally exists the low problem of gross activity thing content, and this is washed
The clean result to fats (beef fat) spot is only illustrated in the embodiment for washing agent.
The content of the invention
For the deficiencies in the prior art, in order to solve the problems, such as that biosurfactant is washed, exploitation really is able to
The detergent of practical application, inventor has carried out deep thinking and has carried out substantial amounts of experimental work.
The technical solution used in the present invention is：
1st, the gross activity thing content in biocleaner is improved
Due to being limited by technique for gene engineering, fermentation technique and purification technique, the biology in prior art is washed
In washing agent, often it is directly added into microbial fermentation solution and wants composition as group, and the life in the fermentation liquid that fermentable is obtained
Thing surface-active contents about 0.1～1% or so, this gross activity thing content resulted in biocleaner is too low, it is difficult to reach
To the clean result of synthetic detergent.
One aspect of the present invention, inventor in biocleaner by adding vegetalitas surfactant, such as tea soap
Element, Fructus Gleditsiae Abnormalis extract, soapberry extract, the method for sterol ester, improve the content of active matter in biocleaner, break away from micro- life
The too low restriction of active matter content in thing fermentation liquid, improves the clean result of detergent.And what is added is that vegetalitas surface is lived
Property agent, environmental protection identical with the application original intention of biosurfactant is safe.
Another aspect of the present invention, inventor is also introduced into green surfactant in biocleaner, by green
Surfactant it is green, efficiently with biosurfactant it is safe and environment-friendly in combination with.The concept of green surfactant,
Implication etc. sees reference document (ref 1：Zhu Minghua. the preparation technology of green surfactant MES and performance study [J]. Shandong
Work, 2016,45 (2)：8-10.；ref 2：Hu Jianpin, Xia Xiongyan, Geng Erhuan, etc. the present situation of green surfactant and development
Trend [J]. Perspective of China Washing Product Industry, 2016 (2)：30-36.；ref 3：Wang Zeyun, Chen Hailan. China's washing green table
Face activating agent latest developments [J]. household chemicalss science, 2011,34 (7)：21-23.) and more documents and materials published
It is discussed in detail.
2nd, preferred compositional biological enzyme is added in biocleaner, clean result is further improved
The essence of enzyme is a kind of catalyst, and in being applied to detergent, enzyme primarily serves the spot of catalysis contamination
The effect of fast decoupled.Because enzyme has specificity, therefore different spots, different types of enzyme is needed come spot of degrading
The special protein degradation class spot of composition, such as protease, lipase is specially degraded fats spot etc..By the sieve of many experiments
Choosing, will preferably combine enzyme compounding use, can improve cleansing power of the detergent to more spots, and improve to spot
Adaptability.The relevant information such as effect of enzyme sees reference document (ref 1 in detergent：Xiong Enge. with regard to compound enzyme in liquid
Application research [J] in body detergent. chemical management, 2016 (4)：221-221.；ref2：Suzuki yujiu one, Yue Xiao (is translated). washing
The effect of agent enzyme and state-of-the-art technology [J]. Perspective of China Washing Product Industry, 2016 (6).；ref 3：Zhou Xinping. compound enzyme is in liquid
Study on decontamination [J] in detergent. household chemicalss science, 2015,38 (2) .) and more publish the detailed of documents and materials
Discuss.
3rd, improve zinc cation agent prescription, composition can commercialization biocleaner
Published biology is washed in detergent patent application, and major part is simply by biosurfactant and a few group
Divide the simple proportioning of such as chelating agent, enzyme component, it is difficult to reach the clean result of commercialization detergent.
Accordingly, as the one side of this biocleaner invention, we at least with the addition of in the zinc cation of invention
One kind washing auxiliary substance, such as builder, chelating agen, filler, foam inhibitor, antibacterial, buffer agent, cosolvent, viscosity adjustment
Agent etc..While the biocleaner that this assures invention meets people's safe and environment-friendly theory, also with green, efficiently
Characteristic, disclosure satisfy that requirement of the people to scourability.
4th, compound botanical sexual function composition, improves the added value of product of biocleaner
Synthesize development of the class detergent through decades, in addition to scourability is improved constantly, more functional characteristics
Increasingly receive publicity.And biocleaner is used as new things, at this stage used as also there are more needs in it for detergent
The problem of solution, is even more beyond example as functional detergent.On the other hand, biosurfactant nature is gentle, and more
Many functional components have more preferable compatibility, and then are easy to the feature of biocleaner to upgrade, and improve the product of biocleaner
Product added value.
5th, there is provided a kind of preparation method for preparing biocleaner
Biocleaner is a kind of compositionss containing many kinds of substance such as surfactants, in addition to kinds of surface activating agent,
Also containing compositions such as a kind of washing auxiliary substances.In order to produce meet certain requirements, the detergent of stay in grade, need corresponding
Production technology.Corresponding method should be may be selected according to the type of detergent, prepare biocleaner.
The invention has the beneficial effects as follows：
1st, a kind of biocleaner has been invented, need of the people to green, safe and efficient healthy living theory have been complied fully with
Ask, lead industry development trend.
2nd, in the biocleaner of invention, the various auxiliary agents such as biosurfactant and plant surface activating agent, enzyme
Compounding, rationally, gross activity thing content is high, and by compound synergic, clean result is fully able to meet people's for the detergent compositions
Demand.
3rd, half-life of the enzyme in biocleaner is substantially increased.Enzyme can be long-term in biocleaner
Activity is kept, the stability of biocleaner scourability is improved.
4th, functional plant extract is compounded in biocleaner, strengthens the feature of biocleaner, give life
The functions such as thing detergent whitening, skin protection, bactericidal.
Detailed description of the invention
Gross activity thing content in 1 detergent
Detergent gross activity thing content refers to that all surfaces activating agent with clean effect is in detergent in detergent
Shared mass percent.The height of gross activity thing content has much relations, Just because of this, wash with the performance of detergent performance
The index of different detergent gross activity thing contents, such as table 1 are defined in the concerned countries standard for washing agent product.
Requirement of the national standard of table 1 to gross activity thing content in detergent
*：The apparent density of concentrated washing powder, decantation test concentration are different from plain edition.Apparent density can be by production
The adjustment of technique is changed.
Therefore, the gross activity thing content in detergent need to meet corresponding standard set quota, and improve detergent
In gross activity thing content contribute to obtaining more preferable traction.
The method of testing of active matter content in detergent：
The A methods for generally specifying by the chapters of GB/T13173-2008 the 7th are determined.Ethanol is not dissolved in when containing in formula
Surface active agent composition, or require test result not aqueous cosolvent when, the B methods specified by the chapters of GB/T13173-2008 the 7th are surveyed
It is fixed.
2 biosurfactants
Biosurfactant is the surfactant produced by fermentable.The species of microorganism includes antibacterial, ferment
Female and funguses.
The biosurfactant of 2.1 bacterial origins
The biocleaner preferably comprises rhamnolipid.Rhamnolipid is produced by pseudomonass or Burkholderia class
A kind of biosurfactant of biological metabolism property.Plant-scale rhamnolipid can be obtained by fermentation culture, such as logical
Cross patent or patent application CN103966282, CN104312942, CN103833800, CN101613725 or document (such as：Wu
Rainbow, Wang Wei, Han Shuanyan. the progress [J] of rhamnolipid biological surface activator. microbiology is circulated a notice of, and 2007,34 (1)：
Method disclosed in 148-152.) prepares rhamnolipid surfactant.Preferably, rhamnolipid in biocleaner compositionss
Addition be 1～20wt%, preferred addition be 1～15wt%, the addition being more highly preferred to be 2～10wt%.
The biocleaner preferably comprises Lipopeptide Biosurfactants.Lipopeptide Biosurfactants are usually
The metabolite of bacillus cereuss, the existing kind more than ten of the lipopeptid class Bio-surface active having now been found that, mainly includes table cytokines
(Surfactin), (ref such as phenol interleukin (Fengysin)：Lv Yingnian, Yang Shizhong, Mu Baizhong. Lipopeptide Biosurfactants
Progress [J]. biotechnology circulate a notice of, 2004 (6)：11-16.).Lipopeptide Biosurfactants can be from product lipopeptid bacterium
(ref is isolated and purified in strain fermentation liquid according to sour heavy, organic solvent extraction, fractional precipitation, decolorization adsorption：Lv Yingnian, poplar generation
Loyalty, Mu Baizhong. lipopeptid is isolated and purified and structural research [J]. and microbiology is circulated a notice of, and 2005,32 (1)：67-73.), it is also possible to
Side with reference to disclosed in patent or patent application (such as CN103059108, CN1592753, CN102325785, CN105838763)
It is prepared by method.Preferably, the addition of lipopeptide surfactant is 1～20wt% in biocleaner compositionss, preferred addition
Measure as 1～15wt%, the addition being more highly preferred to is 2～10wt%.
The biosurfactant in 2.2 non-bacterial source
The biocleaner preferably comprises sophorolipid, manna erythrose alcohol ester or their mixture.Sophorolipid can be by
The honeybee life candida mycoderma (Candida of many primary yeasts, such as mycocandida (Candida) and Torulopsiss (Torulopsis)
Apicola), the fatty candida mycoderma (Candida lipolytica) of Candida bombicola, solution, Candida
Bogoriensis etc. is produced.Sophorolipid can according to specific method (such as patent or patent application, such as CN102695796,
CN101845469, CN105593370 or document, such as ref 1：Liu Qingzhi, Guo Xueping. the Microbe synthesis of sophorolipid and its should
With progress [C] // whole nation biochemistry and biotech drug Annual Conference .2010：51-55.；ref 2：Chen Jing, Zhang Yunrui,
Song Xin. the production of sophorolipid and its applied research progress [J]. Food Science, 2007,28 (8)：525-529.) by training of fermenting
Foster sophorolipid production bacterial strain is obtained.
Mannosylerythritol lipid is usually from Pseudozyma (having previously been thought that it is mycocandida) Antarctica.It is logical
Cross patent or patent application CN103589764, CN104789619 or document (ref 1：Red legend is prosperous, Chen Jian, Hua Zhaozhe, etc. it is sweet
The micro-organisms [J] of dew erythrose alcohol ester. industrial microorganism, 1998 (1)：32-37.；ref2：Zhu Siming, Yu Shujuan, Yang Lian
It is raw. a kind of mannosylerythritol lipid -- new MICROBIAL SURFACTANT [J]. Food Additives Used in China, 2005 (1)：64-
69.) method disclosed in can obtain biosurfactant mannose erythrose alcohol ester.
3 enzyme
Disclosed composition of detergent includes enzyme.Preferably described enzyme is selected from protease, lipase, amylase, fiber
Plain enzyme, alpha-galactosidase, mannase or their mixture.The enzyme being more highly preferred to is combined as cellulase, β-manna
Dextranase, alpha-galactosidase or their mixture.
3.1 protease
Disclosed composition of detergent preferably comprises protease.Described protease is from animal (as pig or cattle come
The trypsin and reaping hook protease enzyme in source), plant (such as bromelain) or microorganism.Preferred protease comes from micro- life
Thing.Protease can also be chemical modification or for protein engineering mutant (protein engineered mutant).
It is subtilisin, especially those from bacillus cereuss from the example of the protease of microorganism.
There is multiple protein enzyme to buy on market, preferred commercial protein enzyme includes AlcalaseTM、SavinaseTM、PrimaseTM、
DuralaseTM、DyrazymTMAnd PolarzymeTM。
3.2 lipase
Disclosed composition of detergent preferably comprises lipase.Lipase-catalyzed edible fat and oil, i.e. glycerol three
The ester linkage hydrolyzing of ester is into free fatty, monoglyceride and diglyceride and glycerol.
Preferred lipase includes coming from the lipase of antibacterial or funguses, also including chemical modification or protein engineering
Mutant.Preferred commercially available lipase is that trade mark is WithLipase.
3.3 amylase
Disclosed composition of detergent preferably comprises d- amylase.Suitable d- amylase includes antibacterial or originated from fungus
D- amylase, further comprises chemical modification or protein engineering mutant.Preferred commercially available amylase is that trade mark is
Duramyl (TM), Termamyl (TM), Termamyl Ultra (TM), Natalase (TM) and Stainzyme (TM),
The α-amylase of Stainzyme Plus (TM).
3.4 mannase
Preferably, disclosed compositionss include mannase.The example of suitable mannase is included from thin
Bacterium or the mannase of originated from fungus, further comprises chemical modification or protein engineering mutant.Preferably commercially available is sweet
Reveal dextranase is for trade mark 'beta '-mannase.
3.5 cellulase
Preferably, disclosed compositionss include cellulase.Suitable cellulase includes the fibre of antibacterial or fungal source
The plain enzyme of dimension, also including chemical modification or protein engineered mutant.Preferred marketed cellulose enzyme is included from spore
Bacillus (Bacillus), Rhodopseudomonass (Pseudomonas), humicola lanuginosa (Humicola) category, fusarium
(Fusarium), Thielavia (Thielavia), the cellulase of Acremonium (Acremonium).For example by special detritus
Mould (Humicola insolens), Thielavia terrestris (Thielavia terrestris), thermophilic fungus destroyed wire
Fungin produced by (Myceliophthora thermophila) and Fusarium oxysporum (Fusarium oxyspomm)
Enzyme.Commercially available cellulase includes CelluzymeTM、CarezymeTM、EndolaseTM、RenozymeTM(Novozymes A/S)
And ClazinaseTM, wherein it is Celluzyme that preferred cellulase is trade markTMCellulase.
4 plant components
Plant component is referred to from plant, by the material of appropriate method acquisition.In the present invention, plant component is made
For one of detergent component, including functional plants extract and plant surface activating agent.
Vegetalitas surfactant is added in detergent, detergent active content can be improved, strengthen detergent
Detergency；Adding functional plants extract can more give biocleaner corresponding feature, such as antibacterial, fragrant, anthelmintic
Etc. function, the added value of cleaning product is lifted.
4.1 functional plants extracts
Plant extract refers to using appropriate method, is extracted as raw material or added with plant (plant is all or certain is a part of)
The material of work.Plant extract is to extract separation process through physical chemistry, can orient acquisition or concentrate in plant
A certain or plurality of active ingredients.
Plant extract used in the present invention is including but not limited to following extract：
Fructus cnidii extract：Fructus Cnidii is the mature fruit of umbrella section plant cnidium monnieri Cnidium monnieri (L.) Cuss.
Mainly containing pinene, isovaleric acid borneol acetate (bomyl isovalarate), osthole (osthol), Columbianetin (+)-Columbianetin.,
Bergapton (berapten), osthole (cnidiadin), isopimpinellin (isopimpinellin) etc..Fructus Cnidii is carried
Take thing and there is the function (ref such as anti-trichomonal, antifungal (Trichophyton, mycete)：Li Jinghong, Gu Jiwei, Wang Xi. Fructus cnidii extract
Antibacterial action research [J]. Heilungkiang medical science, 2013,36 (4)：87-87.).Fructus cnidii extract can be according to disclosed
Documents and materials prepare (ref 1：Deng Hong, Gu Dandan, sun is brave, etc. the optimization [J] of Osthole in Fructus Cnidii extraction process. West China
Pharmaceutical journal, 2013,28 (1)：106-107.ref2：Tension force power, Huang Jing, Zhang Qi. cnidium monnieri in Response Surface Method optimization Fructus Cnidii
The extraction process [J] of sub- element. HEILONGJIANG ANIMAL SCIENCE AND VETERINARY MEDICINE, 2014 (9) .ref3：Shi Yafang, Jia Xiaobin. Fructus Cnidii extraction process
Research [J]. R＆D of modern TCM and practice, 2000 (1)：47-47.ref 4：Zhang Changbin, Chen Xiangsheng, Zhou Wei. Fructus Cnidii is extracted
Technique preference. Chinese pharmacists, 2004,7 (9)：716-718.)
Flos Chrysanthemi Indici extract：Flos Chrysanthemi Indici extract is feverfew Herba Dendranthematis indici Chrysanthemum indicum L. HERBA CHRYSANTHEMI LAVANDULAEFOLIIs
The capitate extract of C.boreale Mak. or lavandulaleaf dendranthema herb C.lavandulaefolium (Fisch.) Mak..Flos Chrysanthemi Indici
Extract has antibiosis and antiviral functions (ref：Jiang Yu, Chen Anjun, Yu Xin, etc. Flos Chrysanthemi Indici extract bacteriostatic activity [J]. Sichuan
Agriculture university's journal, 2010,28 (3)：328-332.), Flos Chrysanthemi Indici extract can prepare (ref 1 according to disclosed documents and materials：
Zhu Lin, Li Yuxi, Qiu Yuli, etc. Flos Chrysanthemi Indici extraction process, mother chrysanthemum total flavone assay method：, CN102961427A [P]
.2013.ref 2：Ruan Jun, Huang Yonglin. mother chrysanthemum total flavone Study on Extraction Method [J]. Chinese patent medicine, 2004,26 (2)：153-
154.)
Herba Lysimachiae foenum-graeci quintessence oil：Lavandula angustifolia is Labiatae lavender platymiscium, and Herba Lysimachiae foenum-graeci quintessence oil is to extract from lavandula angustifolia and obtain,
Suppression of the Herba Lysimachiae foenum-graeci quintessence oil to microorganisms such as escherichia coli, bacillus subtilis, staphylococcus aureuses, Mucor, Hypocrea virens
Bacterium acts on.Herba Lysimachiae foenum-graeci quintessence oil can prepare (ref 1 according to disclosed documents and materials：Yang Shaoyu, Feng Lijiao, Luo Zhigang. lavandula angustifolia essence
The extraction of oil and Components identification [J]. Guangdong chemical industry, 2007,34 (9)：109-112.ref 2：Zhang Qiuxia, Jiang Ying, Zhang Zhiqiang. smoke
The progress [J] of clothing grass quintessence oil. fragrance flavor and cosmetic, 2006,2006 (6)：21-24.ref 3：Cheng Peng, Pan Qin, are apt to perhaps
Just. the biological activity [J] of Herba Lysimachiae foenum-graeci quintessence oil. modern medicines and clinic, 2008,23 (1)：7-10.)
Tea tree ethereal oil：Tea tree ethereal oil originates in Australia, is the extract of Camellia sinensis, the function with sterilization.Tea tree ethereal oil can
(ref 1 is prepared according to disclosed documents and materials：Zhu Cuibang. a kind of extracting method of tea tree ethereal oil：, CN105062691A [P]
.2015.ref2：Liu Xiangyi, Ling Qinghua, period-luminosity is put down. while the method for extracting Australia tea tree essential oil and flavonoid glycoside：CN, CN
103146473A[P].2013.)
Folium Artemisiae Argyi extract：Folium Artemisiae Argyi extract is to be with the leaf of feverfew Chinese mugwort Artemisia argyi L6vl.etVant.
Raw material is extracted.Containing abundant volatile oil, flavonoid, triterpeness, Folium eucalypti globueli (Eucalyptus globulus Labill.) alkanes with chemical combination such as, trace element and tannin, polysaccharide
Thing, its active component is mainly volatile oil and flavonoid, with antibacterial, antiviral functions (ref 1：Chen Yu, Xu Wei, Xu Shiyi.
The bactericidal effect [J] of Folium Artemisiae Argyi extract. JOURNAL OF MICROBIOLOGY, 2014,34 (6)：107-109.).In vitro tests proves Oleum Folium Artemisiae Argyi
To coccus (white and staphylococcus aureuses, A type and group B streptococcus, Diplococcus pneumoniae and Neisseria) and great majority leather
Lan Shi negative bacillus (influenza, deformation, typhoid fever, paratyphoid fever, large intestine, secondary large intestine and dysentery bacterium) have inhibitory action.Folium Artemisiae Argyi carries
Taking thing can prepare (ref 1 according to disclosed documents and materials：Yuan Huihui, Yin Xiang, Lu Dongying, etc. Folium Artemisiae Argyi extraction process and antioxygen
Change the research [J] of activity. East China University of Science's journal (natural science edition), 2005,31 (6)：768-771.)
Rhizoma Zingiberis Recens extract：Rhizoma Zingiberis Recens are the subterraneous stems of plant Zingiber officinale or claim root stock, Rhizoma Zingiberis Recens extract pair
Microorganism has obvious inhibiting effect, and its MIC value is respectively flavous Fructus Vitis viniferae ball, bacillus subtilis, aspergillus niger, penicillium sp and is
0.25%, escherichia coli 0.5%, (the ref 1 of cereuisiae fermentum 0.125%：Yan Zankai. the bacteriostatic test [J] of Rhizoma Zingiberis Recens extract.
Food Additives Used in China, 2005 (1)：74-76.).Rhizoma Zingiberis Recens extract can prepare (ref 1 according to disclosed documents and materials：Xin Li,
Yellow Guidong, clock pioneer, etc. Rhizoma Zingiberis Recenss total flavone extracting process studies [J]. Chinese crude drug, 2008,31 (5)：766-768.ref2：
Comply with one's wishes, Zhu Jing. Rhizoma Zingiberis Recenss total flavone extracting process studies [J]. food and fermentation science and technology, 2010,46 (1)：89-92.)
Herba Schizonepetae extract：Herba Schizonepetae extract is with labiate Herba Schizonepetae Schizonepeta tenuifolia (Benth.)
Briq. herb is the product that raw material is extracted, containing volatile oil.Herba Schizonepetae extract is to anthrax bacillus, group B streptococcus, typhoid fever bar
Bacterium, dysentery bacterium, bacillus pyocyaneus and mycobacterium hominis also have certain inhibitory action.Herba Schizonepetae extract can be according to disclosed document
Data prepares (ref 1：Fang Ru, Chen Guiqian, money Yushan. the extraction [J] of Chemical Constituents From Schizonepeta. Fuyang Teachers College's journal：It is natural
Science version, 2006,23 (1)：48-50.ref 2：Luan Weili, Xiao Jianmou, Shang Xili, etc. grinding for. Herba Schizonepetae volatile oil extracting method
Study carefully example. Jiangxi chemical industry, 2006 (2)：7-9.)
Herba Cymbopogonis Citrari extract：Herba Cymbopogonis Citrari (Citronella) is grass tree section thatch category (Cymbopogon) about 55 kinds of fragment plants
It is referred to as, is one of common Rhizoma et radix valerianae.Herba Cymbopogonis Citrari extract has antibacterial, anthelmintic action.Herba Cymbopogonis Citrari extract can be according to disclosed document
Data prepares (ref 1：Jia Yuan, Hu Tie, Tan Yun, etc. oil of Cymbopogon winterianus optimal extraction technology and its component analyses [J]. Central-South forestry
University of Science and Technology's journal, 2015 (4)：130-134.ref2：Wang Hongtao, He Xiaodong, Meng Qinghua. the extraction and its suppression of Herba Cymbopogonis Citrari volatile oil
Bacterium acts on [J]. Tonghua Teachers College's journal, 2013,34 (6)：44-45.ref 3：Zhao Jianfen, Wei Shoulian, Chen Zichong. Herba Cymbopogonis Citrari
The extraction of volatile oil and its chemical composition analysis [J]. food research and development, 2015 (19)：55-58.)
4.2 plant surface activating agents
Plant surface activating agent refers to source and the whole strain of plant or part, such as flower, stem and leaf, fruit, seed or root part,
By specific technological means or combination technique means, such as crushed, extraction, distillation, concentration, filter, the operation such as crystallization is obtained
Extract with surface activity.
Plant surface activating agent used in the present invention is including but not limited to following surfactant：
Tea saponin also known as TS, be by the class candy glycoside compound extracted in Camellia sinensis seed (camellia oleosa seed, tea-seed),
It is a kind of natural surfactant of good performance, with various biologies such as the surface activitys such as emulsifying, dispersion and antibacterial, antiinflammatory
Activity (ref：Deng Guilan. the extraction of tea saponin and purifying research [J]. food research and development, 2016,37 (8) .).
Fructus Gleditsiae Abnormalis extract：Also known as Fructus Gleditsia extract, the saponin for containing is a kind of natural surfactant (ref：Zhao Feng,
Hu Guanfang, Liu Minyan, etc. the extraction and its potentiation research [J] to pesticide of Fructus Gleditsia surfactant. agriculture of gansu section
Skill, 2011 (9)：3-6.).
Soapberry extract：The sapindoside that Fructus Sapindi Mukouossi contains is a kind of natural nonionic surfactant, energy
The surface tension of water is reduced, with foaming abundancy, feel is fine and smooth, strong detergency, and with antibacterial functions (ref：Cui Li, Yang Wei
It is red, Mei Jiaqi. research and progress [C] of the soapberry extract in hair washing industry, national fragrance flavor and cosmetic special topic is academic to be discussed
Altar .2013.).
The source of 4.3 plant components and effect
Plant component of the present invention can include the component in following table, but be not limited to material described in table.
The plant component information table of table 2
Plant extract of the present invention can also be prepared according to disclosed documents and materials, and the plant for being used carries
Take thing can at businessman very advantageously from table purchase or or e-commerce platform, other markets at be commercially available.
5 washing auxiliary substances
Disclosed biocleaner compositionss can be comprising washing auxiliary substance or washing assisant, the washing auxiliary substance
Selected from builder, chelating agen, filler, foam inhibitor, colour fixative, antibacterial, cosolvent, viscosity modifier and their mixing
Thing.Washing auxiliary substance of the present invention includes, but are not limited to the material described in following table.
The auxiliary substance added in the detergent of table 3 and amount ranges
When preparing liquid detergent, wherein without or water can be added as solvent.
This is enumerated and is not meant to be limit, those skilled in the art can according to published information in field,
By simple permutation and combination, the test of finite number of time, suitable washing auxiliary substance can be selected or filtered out.
The preparation method of 6 biocleaners
The preparation method of 6.1 liquid detergents
It is preferred that it is low, using conventional high shear mixing arrangement, the method for being capable of achieving to prepare the present composition.This guarantees own
Composition suitably dispersing or dissolving in the final composition.
Basic step is illustrated below：
1) deionized water is added in preparing tank；
2) stirring is started ,～50 DEG C are warming up to, plant surface activating agent is added in preparing tank, stir complete to dissolving
(such as having glycerol or triethanolamine cosolvent in formula, appropriate cosolvent can be added to promote dissolving)；
3) heating, Temperature fall are stopped；Continue to stir, at the same add in preparing tank green surfactant (by it is cloudy from
Son, nonionic and amphoteric surfactant) order addition, stir complete to dissolving；
4) biosurfactant is added in preparing tank, stirs complete to dissolving；
5) if it has, adding functional plants extract, stir to being completely dissolved or disperse；
6) after adding the cosolvent of (remainder), qs pH adjuster, such as citric acid are added, adjusts pH for neutrality；
7) enzyme or biological enzymatic compositions are added, is stirred to being completely dissolved or disperse；
8) viscosity modifier adjustment fine setting system viscosity is added, and supplements the deionized water of surplus.
The production technology of 6.2 detergent powders
The production of detergent powder can be carried out by following 2 kinds of technique：
High tower powder injection process：By green surfactant (MES, fatty acid distribution of coconut oil soap potassium, anion surfactant), plant
Thing surfactant, biosurfactant and washing assisant (such as carboxymethyl cellulose, sodium sulfate, sodium carbonate) etc. add from
Sub- water makes slip, is then spray-dried, and cool aging, then enzyme and nonionic surfactant are added, stirring system
Grain can obtain detergent granules, and the grain density of powdery biocleaner can be adjusted by the addition of auxiliary agent.
The attached polymer molding production technology：By green surfactant (MES, fatty acid distribution of coconut oil soap potassium, anion surface active
Agent), plant surface activating agent, biosurfactant and washing assisant (such as carboxymethyl cellulose, sodium sulfate, sodium carbonate),
Nonionic surfactant etc. is directly mixed by Recipe requirement, is sufficiently mixed uniform rear addition enzyme, and stirring granulation can
Detergent granules are obtained, the grain density of powdery biocleaner can pass through addition and granulation mixing speed and the time of auxiliary agent
Adjustment.
The form of the enzyme for using can be liquid, or solid, preferably use the biology of solid form
Enzyme.
Description of the drawings
The detergency comparison diagram of the biological liquid detergent of Fig. 1 formula 4 and certain commodity liquid detergent.
Specific embodiment
Following non-limiting examples describe the present invention.Unless otherwise stated, all percentage ratios in embodiment
It is by weight.
Embodiment 1：The biological liquid detergent for dress material washing of invention and preparation
By taking formula 1 as an example (the biological laundry liquid formulation of other citings is shown in Table 4), the preparation method of biological liquid detergent is illustrated.
The preparation of other formula, by those skilled in the art through the test of limited number of time, can obtain described biology and wash according to this example
Clothing liquid.
1) will be furnished with the 250mL there-necked flasks (heating in water bath) of agitator, recirculated water cooling condenser and add 35.0g deionizations
Water；Stirring is started, 50 ± 0.5 DEG C are warming up to, tea saponin 10.0g is added in flask, stir complete to dissolving；
2) heater is closed；Continue stir, in flask add sequentially add MES, fatty acid distribution of coconut oil soap potassium, FMEE and
CAB35 (adds next component) after dissolving completely, stirs complete to dissolving；
3) 10.0g table cytokines fermentation liquids, stirring and dissolving are added in flask；
4) add after 1g triethanolamine and 1.0g glycerol, add 1.0g citric acids, adjust pH for neutral (6.5～7.5)；
5) enzyme (1.0g 'beta '-mannases, 0.1g protease and 0.3g cellulase) is sequentially added, is stirred to complete
CL or dispersion；
6) 2.0g NaCl fine setting system viscosities, and the 6.1g deionized waters of supplementary surplus are added, stir to obtain formula 1
Biological liquid detergent.
The test of active matter content：Contain cosolvent (glycerol, triethanolamine) in the detergent invented in the present embodiment, therefore
The test of active matter content is determined by the B methods that the chapters of GB/T13173-2008 the 7th specify.
Table 4 is used for the biological laundry liquid formulation citing of dress material washing
Embodiment 2：Biological liquid detergent is contrasted with the clean result of commodity liquid detergent
Biological liquid detergent is prepared according to formula, with certain brand article liquid detergent contrast clean result.Method of testing according to
《GB/T 13174-2008 dress materials detergent detergency and the measure of circulation scourability》Carry out.Scourability contrast is shown in Table
5。
The biological liquid detergent of table 5 is contrasted with the detergency of certain commodity liquid detergent
*：According to the method for testing of GB/T 13174-2008, the test concentrations of plain edition liquid detergent are 0.2%, concentrated type
The test concentrations of liquid detergent are 0.1%.
Embodiment 3：Clean result of the biological liquid detergent to various spots
Liquid detergent is prepared according to formula 4, the decantation test of dress material spot is carried out.Soiled cotton is GB/T 13174-2008 regulations
JB-01 standard cotton cloths Jing difference spot smear, place 1 day and obtain (edible oil is dyeed with Sudan IV).According to conventional clothing
Thing washing methods, the washing flow for soak, wash by rubbing with the hands, rinsing cleans spot.Wash temperature：Room temperature (～20 DEG C)；Water: fabric weight
Than for 5: 1；Drying mode：Drier.
Fig. 1 gives, the detergency comparison diagram of the biological liquid detergent of formula 4 and certain commodity liquid detergent.
Embodiment 4：The detergent granules and preparation method for dress material washing of invention.
(the particular biological detergent compositions of other citings are shown in Table 6 by taking formula 11 and 12 as an example
), illustrate the preparation method of detergent granules.The preparation of other formula can be according to this example, by the technology of this area
Personnel obtain described particular biological detergent through the test of limited number of time.
High tower powder injection process (by taking formula 11 as an example)：By green surfactant (MES, fatty acid distribution of coconut oil soap potassium, anion
Surfactant), plant surface activating agent, biosurfactant and washing assisant (carboxymethyl cellulose, sodium sulfate, carbonic acid
Sodium etc.) etc. add appropriate amount of deionized water (consumption can be adjusted according to mixture state, water content ranges 10～60%, such as 50%) be made
Slip, is then spray-dried, and cool aging, then by enzyme and nonionic surfactant, stirring granulation can obtain graininess
Biocleaner.
The attached polymer molding production technology (by taking formula 12 as an example)：By green surfactant (MES, fatty acid distribution of coconut oil soap potassium, the moon
Ionic surface active agent), plant surface activating agent, biosurfactant and washing assisant (carboxymethyl cellulose, sodium sulfate,
Sodium carbonate etc.), nonionic surfactant etc. directly mix by Recipe requirement, be sufficiently mixed it is uniform after add enzyme,
Stirring granulation can obtain detergent granules.
Table 6 is used for the detergent granules formula examples of dress material washing
Embodiment 5：For the detergency test of the detergent granules of dress material washing
Biological liquid detergent is prepared according to formula, with certain brand article liquid detergent contrast clean result.Method of testing according to
《GB/T 13174-2008 dress materials detergent detergency and the measure of circulation scourability》Carry out.Scourability contrast is shown in Table
7。
The detergency test of the detergent granules of table 7
Embodiment 6：For the liquid detergent composition and preparation method of dishwashing detergent
The present embodiment provides the biocleaner compositionss for the manual/auto washing of tableware.
With reference to the preparation method of embodiment 1, carry out by taking formula 16 as an example that (biological laundry liquid formulations of other citings are shown in Table
8) preparation method for dishwashing detergent, is illustrated.The preparation of other formula can be passed through according to this example by those skilled in the art
The test of limited number of time, obtains described biocleaner.
1) will be furnished with the 250mL there-necked flasks (heating in water bath) of agitator, recirculated water cooling condenser and add 55.0g deionizations
Water；Stirring is started, 50 ± 0.5 DEG C are warming up to, sophorolipid 5.0g is added in flask, stir complete to dissolving；
2) heater is closed；Continue to stir, add that to sequentially add MES, APG0810, FMEE and CAB35 (molten in flask
Next component is added after solution is complete), stir complete to dissolving；
3) 5.0g table cytokines fermentation liquids, soapberry extract 5.0g, Fructus Gleditsiae Abnormalis extract 5.0g are sequentially added in flask, is stirred
Mix dissolving；
4) citrate trisodium dihydrate, 1,2-PD, potassium sorbate and stirring and dissolving are sequentially added；
5) sequentially add enzyme (0.3g 'beta '-mannases, 0.3g α-amylase and 0.1g protease), stir to
It is completely dissolved or disperses；
6) 2.0g sodium tripolyphosphates fine setting system viscosity, and the 6.0g deionized waters of supplementary surplus are added, is stirred
The liquid detergent for dishwashing detergent of formula 16.
Table 8 is used for the detergent compositions of dishwashing detergent and illustrates
Embodiment 7：For the detergency test of the liquid detergent composition of dishwashing detergent
Dish washing detergent is prepared according to formula, its detergency is tested.Method of testing according to《GB9985-2000 Appendix B decontaminations
Power determines (method one)》In go oil cut rate measure represent dish washing detergent detergency.
The detergency of the dish washing detergent of table 9
Detergency contrast is shown in Table 9.
Claims (8)
1. a kind of biocleaner compositionss, the compositionss are included：
(A) biosurfactant, is the surfactant produced by antibacterial, yeast or fungi fermentation, and the biological surface is lived
Property one or two or more kinds mixture of the agent in table cytokines, phenol interleukin, rhamnolipid, the sophorolipid, Bio-surface active
The addition of agent is 1～20wt%, and preferred addition is 1～15wt%, and the addition being more highly preferred to is 2～10wt%；
(B) plant surface activating agent, the plant surface activating agent refer to tea saponin, Fructus Gleditsiae Abnormalis extract, soapberry extract,
The mixture of one or two or more kinds in sterol ester；The addition of plant surface activating agent is 1 in biocleaner compositionss
～20wt%, preferred addition is 1～15wt%, and the addition being more highly preferred to is 2～10wt%；
(C) enzyme or biological enzymatic compositions, the enzyme or biological enzymatic compositions be by protease, cellulase, β-
One kind in mannonase α-amylase, lipase, pectin lyase, alpha-galactosidase, saccharifying enzyme, oxidoreductase
Or two or more enzymes is combined；In biocleaner compositionss the addition of enzyme living organism enzymatic compositions be 0.1～
5wt%, preferred addition is 0.1～2wt%, and the addition being more highly preferred to is 0.5～2wt%；
And at least one of balance of (D) washs auxiliary substance, the washing auxiliary substance is selected from washing synergist, helps and wash
One or two or more kinds in agent, chelating agen, filler, foam inhibitor, anti-deposition agent, antibacterial, cosolvent or viscosity modifier
Mixture.
2. biocleaner compositionss according to claim 1, it is characterised in that：Contain in biocleaner compositionss
Enzyme preferably is selected from one or two or more kinds in protease, cellulase, 'beta '-mannase, lipase, alpha-galactosidase
Mixture；The enzyme being more highly preferred to is combined as cellulase：'beta '-mannase：The mass ratio of alpha-galactosidase is 2～3:1.5
～3:1.
3. biocleaner compositionss according to claim 1, it is characterised in that：Described washing synergist is lived for green surface
Property agent, described green surfactant is selected from alkyl-glucoside, MES, fatty acid methyl ester ethoxylation
Live on the mixture of one or two or more kinds in thing, Polyglycerol ester of fatty acids, coco-nut oil fatty acid soap potassium, preferred green surface
Property one or two or more kinds mixing of the agent in alkyl-glucoside, Polyglycerol ester of fatty acids, the coco-nut oil fatty acid soap potassium
Thing.
4. biocleaner compositionss according to claim 3, it is characterised in that：Described green surfactant content is 1
～20wt%, preferred scope is 5～20wt%.
5. biocleaner compositionss according to claim 1-4, it is characterised in that：The gross activity thing contained in compositionss
Content range be 10～80wt%, preferred scope be 15～80wt%, the addition being more highly preferred to be 20～70wt%；It is described
Gross activity thing content refers to the matter percentage for playing decontamination.
6. biocleaner compositionss according to any one of claim 1-5, it is characterised in that：Wherein also containing functional
Property plant extract, described feature extract extracts selected from Herba Lysimachiae foenum-graeci quintessence oil, Flos Camelliae Japonicae quintessence oil, rosemary ethereal oil, Fructus Cnidii
Thing, Rhizoma Zingiberis Recens extract, Folium Artemisiae Argyi extract, Flos Chrysanthemi Indici extract, Herba Cymbopogonis Citrari extract, Herba Schizonepetae extract, Aloe extract, Fructus Corni
The mixture of one or two or more kinds in extract, Flos Lonicerae extract, Radix Ginseng extract.
7. biocleaner compositionss according to claim 6, it is characterised in that：Described functional plants extractive content is
0.1～10wt%, preferred scope is 0.5～5wt%.
8. biocleaner compositionss according to any one of claim 1-7, it is characterised in that：Wherein described combination
Thing is the form or granule of the fluid composition (wherein without or can add water as solvent) for medicated clothing or dishwashing detergent
The form of shape compositionss.
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Application publication date: 20170426 |