CN101225348B - Antibiotic cleaning agent composition using cereal fermentation liquor as main component - Google Patents
Antibiotic cleaning agent composition using cereal fermentation liquor as main component Download PDFInfo
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- CN101225348B CN101225348B CN2007100007547A CN200710000754A CN101225348B CN 101225348 B CN101225348 B CN 101225348B CN 2007100007547 A CN2007100007547 A CN 2007100007547A CN 200710000754 A CN200710000754 A CN 200710000754A CN 101225348 B CN101225348 B CN 101225348B
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Abstract
The invention relates to an antibacterial detergent composition taking grain fermentation liquid as the main body, which comprises hop extraction liquid 1 to 5wt percent, natural matter type nonionic surface-active material 15-25wt percent, and grain fermentation liquid the rest of 100wt percent. The detergent composition is a safe and healthy natural detergent added no petroleum extractant; the component of the hop extraction liquid is the reuse of the hop which is a vintage byproduct, containing natural ablastin and alexin which can prevent germs from breeding; meanwhile, the component of the alcohol in the grain fermentation liquid also has a cleaning effect.
Description
Technical field
The present invention relates to a kind of antibiotic cleaning agent composition based on cereal fermentation liquor, relate in particular to a kind of based on beer, pure mellow wine etc. by the alcoholic fermented liquid that fermented grain forms, add the antibacterial cleanser that the hops dregs of rice and natural matter class nonionic surface active agent are formed again.
Background technology
Cereal fermentation liquor mainly is to be raw material with cereal such as rice, barley, wheat, Chinese sorghum and water, adds distiller's yeast bacterium and yeast with fermentation, again through squeeze and filter or distillation form as alcoholic liquid drinks such as beer, pure mellow wine, Kaoliang spirits.For example, beer is to be raw material with Fructus Hordei Germinatus and water, and hops is a spices, and through germination, saccharification, fermentation procedure, made a kind of ethanol content is between 2 degree～5 degree, and usually by the low ethanol content fumet wine as a kind of refreshment drink.Country variant or geographic beer also can add other cereals such as rice, corn, wheat as auxiliary material, make beer produce different local flavors.
Hops (
Humulus LupulusL.) claim hops or hop again, belong to Cannabaceae, it is a kind of climing rattan property plant, kind surplus being divided into 20 according to the place of production is different with kind comprises typical fragrant hops (classic aroma hop), cultivates fragrant hops (bred aroma hop), high-quality bitter taste type hops (superior quality hop) and general quality bitter taste type hops (normalquality hop); As brewage Saaz, Styriangoldings, the Mt.Hood of Lager (" Lager formula " beer) usefulness, brewage Kent Goldings, the Fuggles that brown Ai Ershi beer uses and all be.Scientific and technical literature was once put down in writing hops and was had the function that suppresses bacterial activity, can prevent the growth (J.C.Lewis of gram positive bacterium effectively, Gordon Alderton, J.F.Carson, D.M.Reynolds, and W.D.Maclay " Lupulon and humulon-antibioticconstituents of hops ", J Clin Invest., 1949September; 28:916-919); U.S. Pat P No.6,313,178 also propose hexahydrolupulon (hexahydrolupulones) has antibiotic and but the effect of cancer.
The contained alcohol (ethanol) of cereal fermentation liquor also is broad-spectrum solvent, No. 426730 Patent publish of TaiWan, China a kind of liquid cleanser composition, it contains the alcohol of 0.01-5wt%; U.S. Pat P No.4,808,330 have also disclosed a kind of nontoxic cleanser compositions that is used to clean vegetables and fruits, and it contains the alcohol of 10-35wt%.Therefore, ethanol is a kind of known and technology of being widely used as cleanser compositions.
Contained tensio-active agent comprises anionic, cationic and nonionic surface active agent etc. in the liquid cleaning agent composition, is divided into petroleum-type and natural matter class according to raw material sources again; Wherein, nonionic surface active agent is usually used in cleaning the sanitising agent of food or dish and kitchen tools etc. owing to have good power of impregnation, clearing power and emulsifying capacity.Nonionic surface active agent is to belong in water can not be dissociated into the ionic tensio-active agent, main hydrophilic group show this class material hydroxyl (OH) and ether (O-) on the integrated structure, therefore, assemble many more hydrophilic groups, it is water-soluble good more.If divided time-like again according to the kind of hydrophilic group, can be divided into polyethoxye alcohol type and multivalence alcohol type two classes again, polyethoxye alcohol type wherein so become main nonionic surface active agent, accounts for 80% of total amount owing to have preferable power of impregnation and clearing power.And the alkylphenol polyethoxye alcohols nonionic surface active agent of being sold on the market (alkylphenol polyethoxylate, APEO), based on nonylphenol polyethoxye alcohols nonionic surface active agent (about 80%), the waste water that this kind sanitising agent uses the back to be produced, can be produced nonylphenol (nonylphenol) by the microbiological deterioration in the water, because the female hormone of the chemical structure of nonylphenol and animal body (17 beta estradiol) structural similitude, after it enters the buck body, can the internal secretion of animal body be impacted, buck is feminized, so be listed in one of Environmental Hormone, many countries ban use of.
Beer belongs to seasonal commodity, when weather is hot, be in great demand and sell fast, but weather when changeing cold sales achievement change light at once.The production line of beer factory must keep a certain amount of production capacity on manpower and mechanical advantage, but because the dull and rush season of beer selling, the rate of capacity utilization in the time of in the dull season will be tending towards descending, terms of settlement is except that changing sales tactics, when the period of slack sales, utilize existing production line to produce other products, also help to improve the rate of capacity utilization.
Summary of the invention
Because commercially available sanitising agent contains environmentally hazardous composition more or less at present, therefore, expects a kind of cleanser compositions that does not have above-mentioned defective.Given this, the inventor is with practical experiences such as the research of engaging in the drinks related products for many years and exploitations, and for the problem of beer production line because of the rate of capacity utilization inequality that weather produced finds new outlets, and makes the present invention through studying in many ways and improveing.Therefore, primary and foremost purpose of the present invention is for providing a kind of antibacterial cleanser based on cereal fermentation liquor, it can be in beer production during dull season, on existing beer or pure mellow wine production line, prepare, keeping the production capacity of this production line, thereby solve the problem of beer production line because of the rate of capacity utilization inequality that weather produced.
Another object of the present invention provides a kind of antibacterial cleanser based on cereal fermentation liquor, it can be in beer production during dull season, on existing beer or pure mellow wine production line, the cereal fermentation liquor for preparing beer or pure mellow wine with the raw material the same and the mode of production with producing beer; Be main raw material with this cereal fermentation liquor again, add the hops dregs of rice and natural class nonionic surface active agent, forming an antibacterial cleanser, thereby solve the problem of beer production line because of the rate of capacity utilization inequality that weather produced.
A further object of the present invention provides a kind of antibacterial cleanser based on cereal fermentation liquor, it is the cleaning function that alcoholic content had that utilizes in the cereal fermentation liquors such as beer or pure mellow wine, the natural bacteriostatic effect that extraction liquid had that adds the wine brewing process by product hops dregs of rice, provide a kind of natural and have the sanitising agent of excellent cleaning antibiotic effect thus, and created the new purposes of these hops dregs of rice.
According to a kind of antibiotic cleaning agent composition based on cereal fermentation liquor of above the object of the invention, the main composition main body is a cereal fermentation liquor, through mixing suitable natural matter class nonionic surface active agent, adds hops dregs of rice extraction liquid again and constitutes.Wherein the content of hops dregs of rice extraction liquid is 1-5wt%, is preferably 3-5wt%; The content of natural matter class nonionic surface active agent is 15-25wt%, is preferably 20-25wt%; And, adding up to the cereal fermentation liquor of 100wt% with mentioned component, its content is preferably 70-80wt%.
Cereal fermentation liquor such as beer mainly are to be raw material with corn bud and water, and add hops and yeast and lead to, in composition of the present invention, cereal fermentation liquor is meant that be raw material as beer or pure mellow wine etc. by cereal such as rice, barley, wheat, Chinese sorghum and water, add the solution that distiller's yeast bacterium and saccharomycetes to make fermentation become to contain alcohol, ethanol (alcohol) in this solution has the function of cleaning, if use beer to be cereal fermentation liquor, its contained hops composition has more germ-resistant function; And cereal fermentation liquor itself also contains multiple amino acids and VITAMIN etc., can infiltrate user's skin simultaneously, and the maintenance user is provided the effect of skin; And be to strengthen the restraining and sterilizing bacteria effect of utilizing hops, though the preparation of cereal fermentation liquor of the present invention adopt be still general beer-brewing method, used as Harrar Dao Magenumu (
Hallertauer Magnum) wait the finished product bitterness value to be set at the above high-quality bitter taste type hops of 40BU.
Generally, add hops during beer brewing, make beer have bitter taste, and be in harmonious proportion the sweet taste of Fructus Hordei Germinatus, the local flavor that beer is had clearly refresh oneself; But the utilization ratio of hops only reaches about 30% in the beer brewing process, and the by product hops dregs of rice after utilizing do not have further purposes yet, so the present invention adds the hops dregs of rice in said composition, to reach the purpose that makes full use of.The employed hops dregs of rice in the cleanser compositions of the present invention, be select high-quality bitter taste type hops such as Harrar Dao Magenumu (
Hallertauer Magnum) wait the restraining and sterilizing bacteria element that contains maximum amount, obtain with extraction processs such as the supercritical co or the hot alcohol aqueous solution, and join in the cleanser compositions of the present invention, provide the present invention to have effects such as anticorrosion, antibacterial or sterilization.
Natural matter class nonionic surface active agent is meant the made tensio-active agent of renewable raw materials as refinements such as sodium soap, lipid acid potassium, Oleum Cocois and starch that utilizes animal and plant, for example, the Henkel company in Europe and Union Carbide company produce by alcohols and synthetic and next APG (the Alkyl polyglycosides of carbohydrate, APG)) with methyl glucamine (Alkyl Glucosamides, AGA); It has preferable solubleness, foaminess, can tolerate bigger temperature range and polyelectrolyte concentration, and extremely gentle to skin, Biodegradable is good, and characteristic such as nontoxicity.In composition of the present invention, use above-mentioned this natural matter class nonionic surface active agent so that the effect of cleaning and degreasing to be provided, it can form emulsification with the greasy dirt of foodstuff surface in water, and then remove pollutent on food and the utensil, but unlikely environment is worked the mischief.In addition, the biological decomposition degree of sanitising agent is meant the per-cent that its solution is digested by microbiological degradation, and the high more expression sanitising agent of resolution is easy of more biological decomposition, and the sanitising agent that residues in the water body is just few more; Therefore, above-mentioned natural matter class nonionic surface active agent used in the present invention, its biological decomposition degree preferably reaches more than 95%, to reach the security of use.
As mentioned above, cleanser compositions of the present invention, its principal feature is to be formed with natural matter fully, owing to do not use the existing contained petroleum refining material of general sanitising agent, its toxicity is low, can be used to wash the dishes, wash foods such as vegetables, fruit, the not material that can residually be detrimental to health safely; And cereal fermentation liquor itself has high Biodegradable, can not work the mischief to environment.
Less important characteristics of the present invention, be to provide a kind of based on antibiotic cleaning agent composition as the cereal fermentation liquor of beer or pure mellow wine, by natural ethanol that itself has in this cereal fermentation liquor and the cleaning efficacy of being brought into play thereof, and under the situation that need not add other industrial alcohol, just can clean dish and vegetables and fruits effectively, and it is residual not have toxic substance.
Therefore characteristics more of the present invention are to provide a kind of antibiotic cleaning agent composition based on cereal fermentation liquor, comprise the natural hops dregs of rice extraction liquid with bacteria resistance function in its composition, after cleaning dish or vegetables and fruits, and can suppress the breeding of bacterium.
The characteristics that the present invention is last, be to provide a kind of antibiotic cleaning agent composition based on cereal fermentation liquor, the cereal fermentation liquor in this cleanser compositions wherein, can on original beer or pure mellow wine brew production line, make, therefore, can solve drinks low problem of the rate of capacity utilization during period of slack sales.
Hereinafter, will describe the characteristics and the effect thereof of antibiotic cleaning agent composition of the present invention in detail by preferred embodiment.
Embodiment
The preparation of hops dregs of rice extraction liquid
Get the dried hops dregs of rice of beer brewing by product, after grinding to form powdery, ratio concussion extraction 1 hour and filtration with solvent: the hops dregs of rice=2:1 (W/W) make hops dregs of rice extraction liquid; Wherein, described solvent is respectively 70 ℃ of hot water, 70 ℃ of 50% alcohol and propylene glycol (monopropolene glycol).
The antibacterial power of hops dregs of rice extraction liquid
The bacterial strain that is used to test is Bacillus subtilus (B.subtilis), faecalis (E.faecalis), intestinal bacteria (E.coli), Pseudomonas aeruginosa (P.aeruginosa) and streptococcus aureus (S.aureus).Testing method is as follows:
1. the preparation of test bacterium liquid: with 0.5% sterile physiological salt solution (pH=7.2) preparation 1.0 * 10
6The above bacteria strain suspension of respectively testing of cfu/mL.
2. fungistatic effect test: get above-mentioned hops dregs of rice extraction liquid 0.3mL, thin up adds test bacterium liquid 0.1mL to 10mL.After mixing, left standstill 10 minutes.Get the 0.1mL mixed solution coat tryptic soy agar (Tryptic soy agar, TSA), every processing repeats five times, place 37 ℃ of incubators, count colony number after 24 hours, and compare, try to achieve its inhibiting rate with the colony number of control group (sterilized water).Result such as following table one.
The antibacterial power evaluation of table one, hops dregs of rice extraction liquid
By the result of table one as can be known, with the hops dregs of rice extraction liquid that 70 ℃ of 50% alcoholic extract makes, its bacteriostasis the best; Inferior good hops dregs of rice extraction liquid for making with the propylene glycol extraction; The hops dregs of rice extraction liquid that other makes with 70 ℃ of water hot extractions reaches other solvent that does not contain hops dregs of rice extraction liquid composition, and its antibacterial power is all not good.
The antibacterial power of sanitising agent
The sanitising agent of embodiment one is formed and is comprised:
70 ℃ of 50% alcoholic extract liquid of the hops dregs of rice of 3wt%; The cocinin of 22wt%; The cereal fermentation liquor of 75wt%.
Antibacterial power test:
Carry out the test as the inhibition microbial reproduction hyperplasia ability of above-mentioned hops dregs of rice extraction liquid, test strain is the same, and testing method is as follows: get 0.1mL bacterium liquid, join by the 0.3mL thin up to become in the sanitising agent of 10mL to mix, left standstill 10 minutes; Get above-mentioned mixed solution 0.1mL and coat tryptic soy agar, every processing repeats five times, places 37 ℃ of incubators, counts colony number after 24 hours.Result such as following table two.
The antibacterial power evaluation of table two, sanitising agent.
By the result of table two as can be known, contain the sanitising agent of the embodiment one of hops dregs of rice extraction liquid in the composition, can reach and analogy of commercially available sanitising agent even better antibacterial power; Though commercially available product one also has the good sterilization effect, it contains the antiseptic-germicide of triclosan (Triclosan), and this material confirms after deliberation, after the water with the process chlorine disinfectant contacts, can produce the chloroform gas (trichloromethane) that is commonly called as chloroform.If this gas sees through skin and sucks, the user that gets off for a long time may cause melancholia, hepatic dysfunction, even cancer; And this additive also may bring harm to environment, as problems such as the excellent oxidations in rivers and creeks.The result of table two shows simultaneously, does not add 100% cereal fermentation liquor sanitising agent of the hops dregs of rice, and its fungistatic effect is obviously poor than embodiment one; Therefore, the cereal fermentation liquor of susceptible of proof such as beer or pure mellow wine etc. should not be used as the sanitising agent use separately.
The clearing power of sanitising agent
The sanitising agent of embodiment two is formed and is comprised:
Any hops dregs of rice extraction liquid 3wt% in the table one; Cocinin 22wt%; Cereal fermentation liquor 75wt%.
The sanitising agent of reference examples is formed and is comprised:
Any hops dregs of rice extraction liquid 3wt% in the table one; Cocinin 22wt%; Water 75wt%.
The test of clearing power:
Get sanitising agent and each 3mL of commercially available sanitising agent of embodiment two, reference examples, be diluted to 50mL with water, wash the disk that was stained with butter at 14 o'clock respectively, until the foam completely dissolve, the disk number that counting can be cleaned is as the test of its clearing power.Result such as following table three.
Table three, clearing power evaluation.
| Specimen | The disk number (individual) that can clean |
| Embodiment two | 31 |
| Reference examples | 28 |
| Commercially available product one | 22 |
| Commercially available product two | 23 |
By the result of table three as can be known, have the embodiment two of cereal fermentation liquor during sanitising agent is formed, the clearing power of obviously not adding the reference examples of cereal fermentation liquor and other commercially available two kinds of sanitising agents is good.
Although the present invention has disclosed preferred embodiment of the present invention for reaching above-mentioned each purpose, it does not limit the present invention.It will be understood by those skilled in the art that under the situation of the scope of the invention that does not depart from the claims qualification, can make various changes and variation the present invention.
Claims (8)
1. antibiotic cleaning agent composition based on cereal fermentation liquor, it comprises:
The hops dregs of rice extraction liquid of 1-5wt%;
The natural matter class nonionic surface active agent of 15-25wt%;
Add up to the cereal fermentation liquor of 100wt% with mentioned component,
Wherein, described hops dregs of rice extraction liquid is the by product hops dregs of rice that utilize beer brewing, gets with 70 ℃ of 50% ethanol aqueous solution extraction, perhaps gets with the propylene glycol solution extraction;
Described natural matter class nonionic surface active agent is a cocinin;
Described cereal fermentation liquor comprises that with various cereal be raw material, through the general prepared alcoholic solution of excise law.
2. composition as claimed in claim 1, the content of wherein said hops dregs of rice extraction liquid is 3-5wt%.
3. composition as claimed in claim 1, the content of wherein said natural matter class nonionic surface active agent is 20-25wt%.
4. composition as claimed in claim 1, the content of wherein said cereal fermentation liquor are 70-80wt%.
5. composition as claimed in claim 1, wherein said cereal fermentation liquor are pure mellow wine.
6. composition as claimed in claim 1, wherein said cereal fermentation liquor are beer.
7. composition as claimed in claim 6, the brewing process of wherein said beer are that adding finished product bitterness value is the above bitter taste type hops of 40BU.
8. composition as claimed in claim 7, wherein said bitter taste type hops are Harrar Dao Magenumu (Hallertauer Magnum).
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| CN101225348B true CN101225348B (en) | 2010-12-08 |
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| ES2675204T3 (en) | 2013-09-20 | 2018-07-09 | Equator Global Limited | Fermented fruit solutions for cleaning compositions |
| CN104498207A (en) * | 2014-11-28 | 2015-04-08 | 桂林市和胤祥新型材料有限公司 | Environment-friendly sterilizing dish washing detergent |
| CN106176358B (en) * | 2016-07-18 | 2020-04-24 | 益盛汉参化妆品有限公司 | Skin cleaning product containing grain and herba Ixeritis Sonchifoliae fermentation product and its preparation method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1352238A (en) * | 2000-11-13 | 2002-06-05 | 王海根 | Dry cleaning power for cleaning carpet |
| CN1670154A (en) * | 2005-04-16 | 2005-09-21 | 王浩贵 | Wild chrysanthemum flower cleaning products |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1352238A (en) * | 2000-11-13 | 2002-06-05 | 王海根 | Dry cleaning power for cleaning carpet |
| CN1670154A (en) * | 2005-04-16 | 2005-09-21 | 王浩贵 | Wild chrysanthemum flower cleaning products |
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