CN106753830A - The liquid dishwashing detergent of stain can be removed - Google Patents

The liquid dishwashing detergent of stain can be removed Download PDF

Info

Publication number
CN106753830A
CN106753830A CN201611170725.0A CN201611170725A CN106753830A CN 106753830 A CN106753830 A CN 106753830A CN 201611170725 A CN201611170725 A CN 201611170725A CN 106753830 A CN106753830 A CN 106753830A
Authority
CN
China
Prior art keywords
acid
surfactant
sodium
agent
stain
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611170725.0A
Other languages
Chinese (zh)
Inventor
王小淳
石荣莹
高娟
叶霄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANGHAI WHITECAT SHAREHOLDING CO Ltd
Original Assignee
SHANGHAI WHITECAT SHAREHOLDING CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANGHAI WHITECAT SHAREHOLDING CO Ltd filed Critical SHANGHAI WHITECAT SHAREHOLDING CO Ltd
Priority to CN201611170725.0A priority Critical patent/CN106753830A/en
Publication of CN106753830A publication Critical patent/CN106753830A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C11D1/24—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds containing ester or ether groups directly attached to the nucleus
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/2034—Monohydric alcohols aromatic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2072—Aldehydes-ketones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2082—Polycarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2096—Heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/364—Organic compounds containing phosphorus containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38654—Preparations containing enzymes, e.g. protease or amylase containing oxidase or reductase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3942—Inorganic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3945—Organic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention relates to cleaning compositions field mainly with surface active cpd as base-material, specially a kind of liquid dishwashing detergent for going stain.A kind of liquid dishwashing detergent for going stain, including surfactant, it is characterized in that：Also include stain removal agent, auxiliary agent, preservative, chelating agent and essence, the mass percent concentration of each component is respectively：Surfactant：10%~30%, stain removal agent：0.1%~5%, auxiliary agent：0.05%~5%, preservative：0.001%~1%, chelating agent：0.001%~1%, essence：0.001%~5%, deionized water：Surplus.The present invention goes stain ability strong, to human temperature and.

Description

The liquid dishwashing detergent of stain can be removed
Technical field
The present invention relates to cleaning compositions field mainly with surface active cpd as base-material, specially one kind can go stain Liquid dishwashing detergent.
Background technology
Used as daily cleaning articles for use, its main component is surfactant to liquid detergent, based on decontamination oil stain.It is existing to wash clean The degreasing result of essence is all preferable, but, such as tea stain, coffee stain etc. poor for coloured dirt removal effect.At present, The stain product that goes on the market mainly has clothing to remove stain washing powder, for the pre- stain removal agent of fabric, and can be used for dishwashing detergent and goes stain Have solid stain removal agent, a sodium hypochlorite class bleaching agent, solid needs dissolving rear can be used, and the alkali of sodium hypochlorite class stain removal agent Property and excitant it is stronger, there is larger excitant to skin and respiratory tract, long-term use produces larger harm to human body.
The content of the invention
In order to overcome the defect of prior art, there is provided it is a kind of go stain ability it is strong, to the articles for washing of human temperature sum, the present invention Disclose a kind of liquid dishwashing detergent for going stain.
The present invention reaches goal of the invention by following technical solution：
A kind of liquid dishwashing detergent for going stain, including surfactant, it is characterized in that：Also include stain removal agent, auxiliary agent, anti-corrosion Agent, chelating agent and essence, the mass percent concentration of each component are respectively：
Ingredient names mass percent concentration (%)
Surfactant 10~30
Stain removal agent 0.1~5
Auxiliary agent 0.05%~5%
Preservative 0.001~1
Chelating agent 0.001~1
Essence 0.001~5
Deionized water surplus
Wherein：Surfactant is from anion surfactant, nonionic surfactant and amphoteric surfactant Any one or at least two compounding；
Peroxide of the stain removal agent from food-grade；
Buffer selects aliphatic unitary, binary or polynary from least one in organic acid and acylate, organic acid At least one in carboxylic acid and aromatic organic acid, acylate is from organic acid and the salt or organic acid and alkaloid of inorganic base Salt；Organic acid selects tartaric acid, oxalic acid, malic acid, citric acid, ascorbic acid, benzoic acid, citric acid, salicylic acid and coffee At least one in acid；Acylate is selected in sodium acetate, sodium oxalate, sodium citrate, sodium citrate and natrium malicum at least It is a kind of.
Preservative from sorbic acid, potassium sorbate, formic acid, formaldehyde, Metagin is cruel, nipalgin second is cruel, nipalgin third is cruel, Nipalgin fourth is cruel, at least one in phenmethylol, benzoic acid, Sodium Benzoate, dehydroacetic acid and sodium dehydroacetate；
Chelating agent selects edta and its sodium salt, hydroxyethylethylene diamine tri-acetic acid and its sodium salt, N, N- from chelating agent Two (carbonyl methyl) alanine trisodium, citric acid and its sodium salts, tartaric acid and its sodium salt, gluconic acid and its sodium salt, dihydroxy ethyl Glycine and its sodium salt, glycine oxalic acid and its sodium salt, glutamic acid diacetic acid and its sodium salt, (methylene of diethylenetriamines five Base phosphonic acids) and its sodium salt, hydroxy ethylidene-diphosphate and its sodium salt and Sodium Polyacrylate in any one；
Essence selects food-grade essence or daily level essence.
The liquid dishwashing detergent of described gone to stain, it is characterized in that：
In surfactant：Anion surfactant from sodium n-alkylbenzenesulfonate, sodium sulfate of polyethenoxy ether of fatty alcohol, At least one in sodium alkyl sulfate and alkene sulfonic acid sodium, nonionic surfactant selects AEO and alkane At least one in base glucosides, amphoteric surfactant is from alkyl betaine, alkylamidopropyl betaine, alkyl oxidation At least one in amine.
Stain removal agent is from any one in hydrogen peroxide, Peracetic acid and peroxidase.
During each component sequentially added into water, stir and the present invention is can be prepared by after being completely dissolved.The present invention is as liquid Stain removal agent composition is directly added into the surfactant of body liquid detergent, active oxygen can be discharged during washing tableware, can be effectively The stains such as removal tea stain, coffee stain, stain-removing effect is good, and dishwashing detergent is used and is more convenient, and the stain removal agent for adding is food Grade, security is higher.
This product is also added into auxiliary agent simultaneously so that preferable in its stain removal agent stability in the solution, solves ozone The unstable technical problem in liquid detergent solution.
The beneficial effects of the invention are as follows：Go stain ability strong, to human temperature and.
Brief description of the drawings
Nothing.
Specific embodiment
The present invention is further illustrated below by way of specific embodiment.
Embodiment 1
A kind of liquid dishwashing detergent for going stain, including surfactant, stain removal agent, auxiliary agent, preservative, chelating agent and perfume (or spice) Essence, the mass percent concentration of each component is respectively：
Ingredient names mass percent concentration (%)
Surfactant 10
Stain removal agent 0.1
Auxiliary agent 0.05
Preservative 0.001
Chelating agent 0.001
Essence 0.001
Deionized water surplus
Wherein：Surfactant selects sodium n-alkylbenzenesulfonate, sodium sulfate of polyethenoxy ether of fatty alcohol, dodecyl sulphur successively One kind in sour sodium and alkene sulfonic acid sodium；
One kind that stain removal agent is selected in hydrogen peroxide, Peracetic acid and the peroxidase of food-grade successively；
Tartaric acid, oxalic acid, malic acid, citric acid, ascorbic acid, benzoic acid, citric acid, salicylic acid and coffee are selected in auxiliary agent choosing successively At least one in coffee acid and its esters.
Preservative successively from sorbic acid, potassium sorbate, formic acid, formaldehyde, Metagin is cruel, nipalgin second is cruel, nipalgin Third is cruel, nipalgin fourth is cruel, the one kind in phenmethylol, benzoic acid, Sodium Benzoate, dehydroacetic acid and sodium dehydroacetate；
Chelating agent successively from chelating agent from edta and its sodium salt, hydroxyethylethylene diamine tri-acetic acid and its sodium salt, N, N- bis- (carbonyl methyl) alanine trisodium, citric acid and its sodium salt, tartaric acid and its sodium salt, gluconic acid and its sodium salt, dihydroxy Ethyl glycine and its sodium salt, glycine oxalic acid and its sodium salt, glutamic acid diacetic acid and its sodium salt, diethylenetriamines five One kind in (methylene phosphonic acid) and its sodium salt, hydroxy ethylidene-diphosphate and its sodium salt and Sodium Polyacrylate；
Essence selects food-grade essence and daily level essence successively.
Embodiment 2
A kind of liquid dishwashing detergent for going stain, including surfactant, stain removal agent, auxiliary agent, preservative, chelating agent and perfume (or spice) Essence, the mass percent concentration of each component is respectively：
Ingredient names mass percent concentration (%)
Surfactant 14
Stain removal agent 1
Auxiliary agent 1
Preservative 0.2
Chelating agent 0.2
Essence 1
Deionized water surplus
Wherein：The selection material of stain removal agent, auxiliary agent, preservative, chelating agent and essence is all with embodiment 1；
Surfactant selects sodium sulfate of polyethenoxy ether of fatty alcohol and APG successively.
Embodiment 3
A kind of liquid dishwashing detergent for going stain, including surfactant, stain removal agent, auxiliary agent, preservative, chelating agent and perfume (or spice) Essence, the mass percent concentration of each component is respectively：
Ingredient names mass percent concentration (%)
Surfactant 18
Stain removal agent 2
Auxiliary agent 2
Preservative 0.4
Chelating agent 0.4
Essence 2
Deionized water surplus
Wherein：The selection material of stain removal agent, auxiliary agent, preservative, chelating agent and essence is all with embodiment 1；
Surfactant is from the alkyl dimethyl betaine that carbochain is 12 to 14.
Embodiment 4
A kind of liquid dishwashing detergent for going stain, including surfactant, stain removal agent, auxiliary agent, preservative, chelating agent and perfume (or spice) Essence, the mass percent concentration of each component is respectively：
Ingredient names mass percent concentration (%)
Surfactant 22
Stain removal agent 3
Auxiliary agent 3
Preservative 0.6
Chelating agent 0.6
Essence 3
Deionized water surplus
Wherein：The selection material of stain removal agent, auxiliary agent, preservative, chelating agent and essence is all with embodiment 1；
The content of surfactant selects anion surfactant and non-ionic surface active with embodiment 1, surfactant Agent is with mass ratio 10:1 compounding, anion surfactant selects sodium n-alkylbenzenesulfonate, lauryl sodium sulfate successively With the one kind in alkene sulfonic acid sodium, nonionic surfactant is successively from AEO and APG.
Embodiment 5
A kind of liquid dishwashing detergent for going stain, including surfactant, stain removal agent, auxiliary agent, preservative, chelating agent and perfume (or spice) Essence, the mass percent concentration of each component is respectively：
Ingredient names mass percent concentration (%)
Surfactant 26
Stain removal agent 4
Auxiliary agent 4
Preservative 0.8
Chelating agent 0.8
Essence 4
Deionized water surplus
Wherein：The selection material of stain removal agent, auxiliary agent, preservative, chelating agent and essence is all with embodiment 1；
The content of surfactant selects anion surfactant and amphoteric surfactant with embodiment 2, surfactant With mass ratio 10:1 compounding, anion surfactant successively from sodium n-alkylbenzenesulfonate, lauryl sodium sulfate and One kind in alkene sulfonic acid sodium, amphoteric surfactant is from the alkyl dimethyl betaine that carbochain is 12 to 14.
Embodiment 6
A kind of liquid dishwashing detergent for going stain, including surfactant, stain removal agent, auxiliary agent, preservative, chelating agent and perfume (or spice) Essence, the mass percent concentration of each component is respectively：
Ingredient names mass percent concentration (%)
Surfactant 30
Stain removal agent 5
Auxiliary agent 5
Preservative 1
Chelating agent 1
Essence 5
Deionized water surplus
Wherein：The selection material of stain removal agent, auxiliary agent, preservative, chelating agent and essence is all with embodiment 1；
The content of surfactant selects nonionic surfactant and amphoteric surfactant with embodiment 3, surfactant With mass ratio 3:1 compounding, nonionic surfactant selects AEO or APG, amphoteric surface successively Activating agent is successively from the one kind in alkyl betaine, alkylamidopropyl betaine, alkyl amine oxide.
Embodiment 7
A kind of liquid dishwashing detergent for going stain, including surfactant, stain removal agent, auxiliary agent, preservative, chelating agent and perfume (or spice) Essence, wherein：The selection material and content of stain removal agent, auxiliary agent, preservative, chelating agent and essence are all with embodiment 1；Surfactant Content with embodiment 1, surfactant selects anion surfactant, nonionic surfactant and amophoteric surface active Agent is with mass ratio 4:2:1 compounding, anion surfactant selects sodium n-alkylbenzenesulfonate, fatty alcohol polyoxy second successively One kind in alkene ether sodium sulfate, lauryl sodium sulfate and alkene sulfonic acid sodium, nonionic surfactant selects fatty alcohol successively APEO and APG, amphoteric surfactant select alkyl betaine, alkylamidopropyl betaine, alkane successively One kind in base amine oxide.

Claims (2)

1. a kind of liquid dishwashing detergent for going stain, including surfactant, it is characterized in that：Also include stain removal agent, auxiliary agent, Preservative, chelating agent and essence, the mass percent concentration of each component are respectively：
Ingredient names mass percent concentration (%)
Surfactant 10~30
Stain removal agent 0.1~5
Auxiliary agent 0.05~5
Preservative 0.001~1
Chelating agent 0.001~1
Essence 0.001~5
Deionized water surplus
Wherein：Surfactant is from anion surfactant, nonionic surfactant and amphoteric surfactant Any one or at least two compounding；
Peroxide of the stain removal agent from food-grade；
At least one in selection of auxiliary sodium metasilicate, magnesium silicate, fatty acid magnesium, polyacrylamide, phosphonates and polyhydric carboxylic acid；
Preservative is from sorbic acid, potassium sorbate, formic acid, formaldehyde, Metagin is cruel, nipalgin second is cruel, nipalgin third is cruel, Ni Bo Golden fourth is cruel, at least one in phenmethylol, benzoic acid, Sodium Benzoate, dehydroacetic acid and sodium dehydroacetate；
Chelating agent selects edta and its sodium salt, hydroxyethylethylene diamine tri-acetic acid and its sodium salt, N, N- bis- (carbonyl methyl) Alanine trisodium, citric acid and its sodium salt, tartaric acid and its sodium salt, gluconic acid and its sodium salt, bicine N- and its Sodium salt, glycine oxalic acid and its sodium salt, glutamic acid diacetic acid and its sodium salt, diethylene triamine penta(methylene phosphonic acid) and its Any one in sodium salt, hydroxy ethylidene-diphosphate and its sodium salt and Sodium Polyacrylate；
Essence selects food-grade essence or daily level essence.
2. the liquid dishwashing detergent of stain can be removed as claimed in claim 1, it is characterized in that：
In surfactant：Anion surfactant from sodium n-alkylbenzenesulfonate, sodium sulfate of polyethenoxy ether of fatty alcohol, At least one in sodium alkyl sulfate and alkene sulfonic acid sodium, nonionic surfactant selects AEO and alkane At least one in base glucosides, amphoteric surfactant is from alkyl betaine, alkylamidopropyl betaine, alkyl oxidation At least one in amine；
Stain removal agent is from any one in hydrogen peroxide, Peracetic acid and peroxidase.
CN201611170725.0A 2016-12-16 2016-12-16 The liquid dishwashing detergent of stain can be removed Pending CN106753830A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611170725.0A CN106753830A (en) 2016-12-16 2016-12-16 The liquid dishwashing detergent of stain can be removed

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611170725.0A CN106753830A (en) 2016-12-16 2016-12-16 The liquid dishwashing detergent of stain can be removed

Publications (1)

Publication Number Publication Date
CN106753830A true CN106753830A (en) 2017-05-31

Family

ID=58891953

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611170725.0A Pending CN106753830A (en) 2016-12-16 2016-12-16 The liquid dishwashing detergent of stain can be removed

Country Status (1)

Country Link
CN (1) CN106753830A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110157554A (en) * 2019-04-19 2019-08-23 上海和黄白猫有限公司 A kind of foam type removes stain dish washing detergent and preparation method thereof
CN110423653A (en) * 2019-08-12 2019-11-08 深圳市耀星实业有限公司 A kind of tableware dipping powder
CN111394200A (en) * 2019-12-31 2020-07-10 纳爱斯浙江科技有限公司 Liquid tableware detergent composition without dioxane and preparation method thereof
CN112011414A (en) * 2020-09-15 2020-12-01 海南热带海洋学院 Areca nut oral vomit juice cleaning composition and preparation method thereof
CN113913251A (en) * 2021-09-16 2022-01-11 安徽克菱保健科技有限公司 Microbial washing sheet for washing tableware

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1075161A (en) * 1992-01-10 1993-08-11 普罗格特-甘布尔公司 Colorless detergent compositions with enhanced stability
CN102492571A (en) * 2011-11-28 2012-06-13 广州立白企业集团有限公司 Detergent composition containing amino acid component for washing fruits, vegetables and dishes
CN103146506A (en) * 2013-03-05 2013-06-12 广州立白企业集团有限公司 Dish washing detergent composition with tea stain cleaning effect
CN104862086A (en) * 2015-04-14 2015-08-26 青岛康泰鑫环保科技有限公司 Dishwashing detergent
CN105695159A (en) * 2016-03-25 2016-06-22 中国日用化学工业研究院 Solvent-free high-enriched tableware scouring agent and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1075161A (en) * 1992-01-10 1993-08-11 普罗格特-甘布尔公司 Colorless detergent compositions with enhanced stability
CN102492571A (en) * 2011-11-28 2012-06-13 广州立白企业集团有限公司 Detergent composition containing amino acid component for washing fruits, vegetables and dishes
CN103146506A (en) * 2013-03-05 2013-06-12 广州立白企业集团有限公司 Dish washing detergent composition with tea stain cleaning effect
CN104862086A (en) * 2015-04-14 2015-08-26 青岛康泰鑫环保科技有限公司 Dishwashing detergent
CN105695159A (en) * 2016-03-25 2016-06-22 中国日用化学工业研究院 Solvent-free high-enriched tableware scouring agent and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110157554A (en) * 2019-04-19 2019-08-23 上海和黄白猫有限公司 A kind of foam type removes stain dish washing detergent and preparation method thereof
CN110423653A (en) * 2019-08-12 2019-11-08 深圳市耀星实业有限公司 A kind of tableware dipping powder
CN111394200A (en) * 2019-12-31 2020-07-10 纳爱斯浙江科技有限公司 Liquid tableware detergent composition without dioxane and preparation method thereof
CN111394200B (en) * 2019-12-31 2021-06-25 纳爱斯浙江科技有限公司 Liquid tableware detergent composition without dioxane and preparation method thereof
CN112011414A (en) * 2020-09-15 2020-12-01 海南热带海洋学院 Areca nut oral vomit juice cleaning composition and preparation method thereof
CN113913251A (en) * 2021-09-16 2022-01-11 安徽克菱保健科技有限公司 Microbial washing sheet for washing tableware

Similar Documents

Publication Publication Date Title
CN106753830A (en) The liquid dishwashing detergent of stain can be removed
EP3284808B1 (en) Method for low temperature washing and disinfection of laundry
JP5207162B2 (en) Neutral liquid detergent composition for automatic dishwashers
JP4181727B2 (en) Liquid detergent composition for automatic dishwashers
JP5025097B2 (en) Liquid detergent composition for automatic washing machine
JP2009149777A (en) Detergent composition for dish washer and method for producing the same
JPH0288700A (en) Composition for automatic dish washer
CN101880605B (en) Detergent for removing stubborn spots in textiles
JP5950557B2 (en) Liquid detergent composition
JP5364396B2 (en) Cleaning composition for wiping and cleaning method
CN111534388A (en) Low-foam easy-to-bleach sterilization laundry detergent and preparation method thereof
US20110315168A1 (en) Acid Compositions for Removing Oxalates
CN103468422A (en) Anti-static color-protecting laundry detergent
CN110157554A (en) A kind of foam type removes stain dish washing detergent and preparation method thereof
WO2013038750A1 (en) Liquid detergent composition
CN108034519A (en) A kind of multifuctional cleaning agent
WO2015098265A1 (en) Powder cleaning agent composition
JP6598356B2 (en) Liquid detergent for textile products
US20090099054A1 (en) Method for formulating a reduced phosphorus branded cleaning product or cleaning system
JP2908892B2 (en) Liquid detergent composition
JP2009019130A (en) Detergent composition and deterging method of dishes using the same
JP6862035B2 (en) Neutral cleaning agent composition
JP4994608B2 (en) Cleaning composition for beverage dispenser
JP4017940B2 (en) Foam-coated laundry pretreatment agent
JP6253403B2 (en) Detergent composition for clothing

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20170531

RJ01 Rejection of invention patent application after publication