CN113913251A - Microbial washing sheet for washing tableware - Google Patents

Microbial washing sheet for washing tableware Download PDF

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Publication number
CN113913251A
CN113913251A CN202111083882.9A CN202111083882A CN113913251A CN 113913251 A CN113913251 A CN 113913251A CN 202111083882 A CN202111083882 A CN 202111083882A CN 113913251 A CN113913251 A CN 113913251A
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China
Prior art keywords
washing
microbial
tableware
tablet
polyethylene glycol
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Pending
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CN202111083882.9A
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Chinese (zh)
Inventor
范田水
董丽巍
沈建
郑鹏
朱永平
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Anhui Keling Health Technology Co ltd
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Anhui Keling Health Technology Co ltd
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Priority to CN202111083882.9A priority Critical patent/CN113913251A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/40Products in which the composition is not well defined
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047Detergents in the form of bars or tablets
    • C11D17/0065Solid detergents containing builders
    • C11D17/0073Tablets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047Detergents in the form of bars or tablets
    • C11D17/0065Solid detergents containing builders
    • C11D17/0073Tablets
    • C11D17/0091Dishwashing tablets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • C11D7/14Silicates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/263Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/265Carboxylic acids or salts thereof

Abstract

The invention relates to a microbial washing tablet for washing tableware, which is characterized by being a tablet prepared from the following raw materials in percentage by weight: 20-30% of layer silicon, 20-25% of Marc copolymer, 30-50% of anhydrous trisodium citrate, 4-5% of polyethylene glycol and 8-10% of microorganism. The invention has the advantages that: the detergent has high-efficiency elution and decomposition capacity on vegetable oil, beef tallow, lard, protein stains, starch stains and the like on tableware; the bacteria take the food residues as nutrient substances in the growth and propagation stages, so that the COD value of the restaurant wastewater can be reduced, and the discharge of the restaurant wastewater is reduced; the product has no strong alkaline/corrosive components, contains no phosphate and surfactant, can be completely biodegraded, has no toxicity to aquatic organisms, and has no residue after cleaning, thus having no influence on human body; easy storage and long preservation time.

Description

Microbial washing sheet for washing tableware
Technical Field
The invention belongs to the technical field of daily chemicals, and particularly relates to a microbial washing sheet for washing tableware.
Background
With the continuous improvement of the living standard and environmental protection consciousness of people, tableware washing products are continuously pushed out and become new, and iteration is carried out in the direction of environmental protection and health.
Most of the active ingredients of the traditional tableware washing products are chemically synthesized cationic, anionic or neutral surfactants which have good deoiling effect, but the chemically synthesized surfactants can not be completely biodegraded in natural environment and can be accumulated in the nature for a long time, so that the water quality can be polluted, the growth and the propagation of aquatic organisms can be influenced, and the harmful substances to human bodies can be enriched.
The bleaching agent in the traditional tableware washing product generally selects peroxide and an activating agent thereof, the peroxide has excellent bacteriostatic effect on bacteria on the surface of tableware, but the peroxide is inflammable and explosive, has potential safety hazards in the production and transportation processes, and can partially remain on the surface of the tableware after the tableware is cleaned, thereby affecting the human health.
Disclosure of Invention
The invention aims to solve the defects of the prior art and provides a microbial washing sheet for washing tableware, which does not contain a surfactant, phosphorus or peroxide in a formula, has long shelf life, is suitable for various adverse environments, cleans tableware by microorganisms, is environment-friendly, green and environment-friendly, has excellent cleaning effect, and has certain practical value and market prospect.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows:
a microbial washing tablet for washing tableware is characterized in that the tablet is prepared from the following raw materials in percentage by weight: 20-30% of laminated silicon, 20-25% of Marc copolymer, 30-50% of anhydrous trisodium citrate, 4-5% of polyethylene glycol (PEG 8000) and 8-10% of microorganism.
Furthermore, the microbial washing sheet for washing tableware is characterized by being a tablet prepared from the following raw materials in percentage by weight: 24-28% of laminated silicon, 22-23% of Marc copolymer, 35-40% of anhydrous trisodium citrate, 4.5-5% of polyethylene glycol (PEG 8000) and 8-9% of microorganism.
Further, the microorganism is one or a mixture of bacillus licheniformis and bacillus subtilis.
Furthermore, the microbial washing sheet for washing tableware is mainly used for removing artificial dirt (containing beef tallow, vegetable oil, lard, wheat flour, milk powder, egg liquid, tomato sauce and mustard), oat stains, tea stains and the like.
According to the invention, bacillus licheniformis and/or bacillus subtilis are/is selected as an active agent, wherein the bacillus licheniformis has high propagation speed (10 ten thousand times of the bacillus licheniformis can be propagated in 4 hours), is strong in vitality, strong in acid resistance, strong in alkali resistance, high in oxygen resistance (aerobic propagation), low in oxygen resistance (anaerobic propagation) and the like, can quickly occupy space advantages through propagation, and can inhibit the growth and propagation of harmful bacteria; the reproduction speed of the bacillus subtilis is 8-12 times higher than that of other fungi; the strain has the characteristics of good stability, oxidation resistance, extrusion resistance, high temperature resistance and the like, can resist the high temperature of 60 ℃ for a long time, can survive for 20 minutes at the temperature of 120 ℃, and is the fungus with the best adaptability of the current beneficial microbial strains; the antibacterial agent can inhibit the growth and the propagation of other bacteria by quickly propagating and generating antibacterial substances, has excellent antibacterial performance, and is a completely nontoxic and pollution-free biological agent; the microorganism is in dormant state in tablet, and can be rapidly activated and proliferated after dissolving in water to rapidly decompose food residue on tableware.
In the invention, the polyethylene glycol 8000 is used as a tabletting auxiliary agent, so that the tablet is non-powdery and is not easy to break; the layer silicon is used as a buffering agent/corrosion inhibitor, so that dirt is loosened, emulsified and hydrolyzed, and the surface of the porcelain or stainless steel tableware is prevented from being corroded; the Marylac copolymer is used as a chelating agent/masking agent to soften water quality, so that no water stain is left on the tableware after washing is finished; the anhydrous sodium citrate is used as chelating agent/masking agent, and has water softening effect.
Compared with the prior art, the invention has the following beneficial effects:
1. excellent cleaning ability: the product can wash tableware with fermentation liquid formed by bacteria after dissolving tablet, and has high-efficiency elution and decomposition capability on vegetable oil, beef tallow, lard, protein stain, starch stain, etc. on tableware;
2. green and environment-friendly: the bacteria take the food residues as nutrient substances in the growth and propagation stages, so that the COD value of the restaurant wastewater can be reduced, and the discharge of the restaurant wastewater is reduced;
3. high-efficiency bacteriostasis: the bacteria in the product can inhibit the growth and reproduction of harmful bacteria on the surface of tableware in a biological competitive mode, so as to protect the health of human body;
4. the safety is high: the product has no strong alkaline/corrosive components, contains no phosphate and surfactant, can be completely biodegraded, has no toxicity to aquatic organisms, and has no influence on human bodies after being cleaned;
5. easy storage and long preservation time: the shelf life of the enzyme-containing cleaning products is generally 6-12 months, strict requirements are imposed on the storage environment, and the enzyme activity is gradually reduced along with the prolonging of the storage time; the activity of the bacillus licheniformis and the bacillus subtilis in the strain is not reduced along with the time extension, and the bacillus licheniformis and the bacillus subtilis can adapt to various adverse environments in a dormant state, thereby effectively solving the problems that the quality guarantee period of enzyme-containing products is short, and the enzyme-containing products are sensitive to temperature and acid-base environments and are difficult to store.
Drawings
FIG. 1 is a photograph of an artificial soil before washing;
FIG. 2 is a photograph of an artificial soil after washing;
FIG. 3 is a photograph of oat wash before washing;
FIG. 4 is a photograph of oat smut after washing;
FIG. 5 is a photograph of tea before washing;
FIG. 6 is a photograph of a tea stain after washing.
Detailed Description
The invention is further illustrated, but not limited, by the following examples. The invention is protected by the following simple alternatives and modifications within the scope of the invention.
Preparation of artificial stains: preparing artificial dirt, oat stain and tea stain according to GB/T24692 household machine dishwashing detergent performance comparison test guide (ISO 7573:1984 MOD) appendix B4.4; dishes to be cleaned were wiped clean with absolute ethanol, dried and weighed recording weight M1, stained dishes were weighed, and weight M2 was recorded.
Stain wash test: dividing tableware coated with stains into 2 groups, and performing a washing experiment according to the 2 groups; adding 1 microbial washing piece into an 8L plastic barrel, adding 3L tap water to prepare a detergent solution, controlling the water temperature at 35 +/-2 ℃, soaking 1 group of tableware coated with stains (comprising 3 round dishes coated with artificial dirt, 3 rice bowls coated with oat stains and 1 tea cup with tea stains) in the solution for 10h while continuously stirring, placing the washed tableware into a constant-temperature drying box at 60 ℃ for drying for 6h, cooling at room temperature, weighing, recording the weight M3, and calculating the stain removal rate of each tableware.
A microorganism washing sheet for washing tableware comprises the following specific implementation steps:
example 1
1. Preparation of tablets: accurately weighing 25kg of layer silicon, 22kg of a propylene copolymer, 40kg of anhydrous citric acid, 4.5kg of polyethylene glycol (PEG 8000) and 8kg of microorganisms, sequentially feeding the weighed materials into a lifting hopper mixer through a vacuum feeder, mixing for 60min, and controlling the mixing speed to be 10 r/min; the mixture is fed into a tablet press to adjust the rotating speed of the tablet press to be 2r/min, the pressure is under 60MIPa, the weight of the tablet is controlled to be 15 g/tablet, the production efficiency is 60 tablets/min, and the microbial washing tablet for washing tableware, which is smooth in surface and excellent in hardness, is obtained.
Example 2
1. Preparation of tablets: accurately weighing 27kg of layer silicon, 25kg of propylene-maleic copolymer, 38kg of anhydrous citric acid, 4.5kg of polyethylene glycol (PEG 8000) and 8.5kg of microorganism, sequentially feeding the weighed materials into a lifting hopper mixer through a vacuum feeder, mixing for 60min, and controlling the mixing speed to be 12 r/min; the mixture is fed into a tablet press to adjust the rotating speed of the tablet press to be 2.5r/min, the pressure is under 65MIPa, the weight of the tablet is controlled to be 15 g/tablet, the production efficiency is 75 tablets/min, and the microbial washing tablet for washing the tableware, which is smooth in surface and excellent in hardness, is obtained.
Example 3
1. Preparation of tablets: accurately weighing 28kg of layer silicon, 22kg of propylene copolymer, 37kg of anhydrous citric acid, 5kg of polyethylene glycol (PEG 8000) and 9kg of microorganisms, sequentially entering a lifting hopper mixer through a vacuum feeder after weighing, mixing for 60min, and controlling the mixing speed to be 10 r/min; the mixture is fed into a tablet press to adjust the rotating speed of the tablet press to be 2r/min, the pressure is 67MIPa, the weight of the tablet is controlled to be 15 g/tablet, the production efficiency is 60 tablets/min, and the microbial washing tablet for washing tableware, which is smooth in surface and excellent in hardness, is obtained.
Example 4
1. Preparation of tablets: accurately weighing 28kg of layer silicon, 23kg of propylene-maleic copolymer, 38kg of anhydrous citric acid, 5kg of polyethylene glycol (PEG 8000) and 9kg of microorganism, sequentially feeding the weighed materials into a lifting hopper mixer through a vacuum feeder, mixing for 65min, and controlling the rotating speed of the mixed materials to be 11 r/min; the mixture is fed into a tablet press to adjust the rotating speed of the tablet press to be 2.5r/min, the pressure is under 65MIPa, the weight of the tablet is controlled to be 15 g/tablet, the production efficiency is 75 tablets/min, and the microbial washing tablet for washing the tableware, which is smooth in surface and excellent in hardness, is obtained.
Figure RE-615246DEST_PATH_IMAGE001

Claims (6)

1. A microbial washing tablet for washing tableware is characterized in that the tablet is prepared from the following raw materials in percentage by weight: 20-30% of layer silicon, 20-25% of Marc copolymer, 30-50% of anhydrous trisodium citrate, 4-5% of polyethylene glycol and 8-10% of microorganism.
2. A microbial detergent tablet for washing tableware according to claim 1 which is a tablet made from the following raw materials in percentage by weight: 24-28% of laminated silicon, 22-23% of Marc copolymer, 35-40% of anhydrous trisodium citrate, 4.5-5% of polyethylene glycol and 8-9% of microorganism.
3. The microbial detergent tablet of claim 1, wherein said microorganisms are selected from the group consisting of Bacillus licheniformis and Bacillus subtilis.
4. A microbial washing sheet according to any of claims 1 to 3, wherein: the molecular weight of the polyethylene glycol is 8000.
5. A microbial wash pad for use in washing dishes according to claim 1, wherein: the microbial washing sheet for washing tableware is mainly used for removing artificial dirt, oat stains and tea stains.
6. A microbial washing sheet according to claim 5, wherein: the artificial dirt mainly comprises: beef tallow, vegetable oil, lard, wheat flour, milk powder, egg liquid, tomato sauce and mustard.
CN202111083882.9A 2021-09-16 2021-09-16 Microbial washing sheet for washing tableware Pending CN113913251A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202111083882.9A CN113913251A (en) 2021-09-16 2021-09-16 Microbial washing sheet for washing tableware

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202111083882.9A CN113913251A (en) 2021-09-16 2021-09-16 Microbial washing sheet for washing tableware

Publications (1)

Publication Number Publication Date
CN113913251A true CN113913251A (en) 2022-01-11

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007009024A (en) * 2005-06-29 2007-01-18 Adeka Corp Detergent composition for automatic dishwasher
EP1967578A1 (en) * 2007-02-23 2008-09-10 Bolton Manitoba SpA Composition for water closets with a continuous action
CN101475882A (en) * 2009-01-19 2009-07-08 浙江大学 Cleanser containing microorganism and preparation thereof
CN103146496A (en) * 2013-03-11 2013-06-12 广州舒国生物科技有限公司 Preparation method of microbial detergent
WO2014107111A1 (en) * 2013-01-07 2014-07-10 Savon Group B.V. Mechanical dishwashing agent and method of mechanical dishwashing
CN106753830A (en) * 2016-12-16 2017-05-31 上海和黄白猫有限公司 The liquid dishwashing detergent of stain can be removed
EP3342846A1 (en) * 2016-12-31 2018-07-04 Grupa Inco S.A. Self-dissoluble capsule for preparation of washing solutions
CN110184129A (en) * 2019-06-24 2019-08-30 东莞市水卫仕日化有限公司 Detergent composition and its preparation method and application
CN111187678A (en) * 2020-02-18 2020-05-22 佛山市顺德区美的洗涤电器制造有限公司 Detergent composition and cleaning solution

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007009024A (en) * 2005-06-29 2007-01-18 Adeka Corp Detergent composition for automatic dishwasher
EP1967578A1 (en) * 2007-02-23 2008-09-10 Bolton Manitoba SpA Composition for water closets with a continuous action
CN101475882A (en) * 2009-01-19 2009-07-08 浙江大学 Cleanser containing microorganism and preparation thereof
WO2014107111A1 (en) * 2013-01-07 2014-07-10 Savon Group B.V. Mechanical dishwashing agent and method of mechanical dishwashing
CN103146496A (en) * 2013-03-11 2013-06-12 广州舒国生物科技有限公司 Preparation method of microbial detergent
CN106753830A (en) * 2016-12-16 2017-05-31 上海和黄白猫有限公司 The liquid dishwashing detergent of stain can be removed
EP3342846A1 (en) * 2016-12-31 2018-07-04 Grupa Inco S.A. Self-dissoluble capsule for preparation of washing solutions
CN110184129A (en) * 2019-06-24 2019-08-30 东莞市水卫仕日化有限公司 Detergent composition and its preparation method and application
CN111187678A (en) * 2020-02-18 2020-05-22 佛山市顺德区美的洗涤电器制造有限公司 Detergent composition and cleaning solution

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