CN103146506A - Dish washing detergent composition with tea stain cleaning effect - Google Patents
Dish washing detergent composition with tea stain cleaning effect Download PDFInfo
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- CN103146506A CN103146506A CN2013100697340A CN201310069734A CN103146506A CN 103146506 A CN103146506 A CN 103146506A CN 2013100697340 A CN2013100697340 A CN 2013100697340A CN 201310069734 A CN201310069734 A CN 201310069734A CN 103146506 A CN103146506 A CN 103146506A
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Abstract
The invention discloses a dish washing detergent composition with a tea stain cleaning effect. The composition comprises an anionic surfactant, a nonionic surfactant, an ampholytic surfactant, a specific chelating agent, a viscosity regulator, a sterilization antiseptic agent, a light stabilizer, an antioxidant, essence and deionized water, wherein the specific chelating agent comprises dimethyl glycine oxalic acid trisodium. The washing detergent prepared by the method has a good dirt-removing capability and the tea stain cleaning effect.
Description
Technical field
The invention belongs to the daily chemical product technical field, particularly relate to a kind of dish washing detergent compositions with removing tea stain effect and preparation method thereof.
Background technology
At present, the dish washing detergent major function is exactly the tablewares such as cleaning pot, bowl, cups and dishes, mainly is aimed at the common dirts such as protein, starch and grease, and the emulsification of dependence tensio-active agent, solubilising etc. are used for realizing clean effect.And for the tea stain spot, present domestic dish washing detergent is not almost removed effect to it, and the dishwashing detergent product that abroad can remove mainly contains following a few class: one, to contain the powder form product of sodium bicarbonate; Two, to contain the powder form product of SPC-D, be used for specially removing the stains such as red wine stain, tea stain, and need not to clean; Three, to contain the powder form product of chlorine bleach (as Surchlor GR 60); Four, the product form with enzyme-containing formulation is used for dividing heavy dirt and the tea on tea set on degrading dishware to steep.
Wang Baopin etc. disclose a kind of tea stain spot clean-out system and wet tissue and preparation method in patent (CN102703229A), be mainly to utilize the synergy of calcium carbonate rubbing effect and other tensio-active agents to realize the removing of tea stain spot.The straight preparation method that the liquid washing agent of the stains such as a kind of tea stain, bloodstain newly is provided in its patent of invention (CN101100629A), this liquid washing agent is mainly to utilize the bleaching oxygenizement of hydrogen peroxide to remove the tea stain.
Also have in addition many scholars, researchist carrying out a lot of research work aspect removing tea stain spot clean-out system.Yet what generally adopt at present is the mode of adding friction agent and SYNTHETIC OPTICAL WHITNER in order to removing the tea stain, and still belongs to blank the dish washing detergent field of removing the tea stain is domestic.Therefore, developing the dish washing detergent with removing tea stain effect is also a researchdevelopment direction.
Summary of the invention
The object of the present invention is to provide a kind of dish washing detergent compositions of removing tea stain and wash dishes spot effect that has, by the prepared dish washing detergent of the inventive method, have tea stain removing effect preferably.
A kind of dish washing detergent compositions with removing tea stain effect that the present invention proposes, the various feed composition that comprise following weight percent: tensio-active agent 0.1-50%, sequestrant 0.01-10.0%, viscosity modifier 0.1-5.0%, fungicidal preservative 0.01-0.5%, other components 0.01-0.1%, surplus is deionized water.
Described sequestrant is the MDGA trisodium.
Described tensio-active agent is at least a or two or more mixture in anion surfactant, nonionogenic tenside or amphoterics.
Described anion surfactant is any or two or more composition in polyoxyethylenated alcohol sodium sulfate, fatty alcohol-polyoxyethylene ether carboxylic acid sodium, sodium alkyl sulfate, alkyl sodium sulfonate, a-sodium olefin sulfonate, methyl sodiosul foaliphatate, sulfo-succinic acid ester sodium salt.Fatty Alcohol(C12-C14 and C12-C18) for the synthesis of polyoxyethylenated alcohol sodium sulfate can be that natural alcohol can be also synthol, and the alkyl chain of Fatty Alcohol(C12-C14 and C12-C18) is preferably the straight chained alkyl of 12-16 carbon atom; The average adduct number of the oxyethane of alcohol ether is 1-3.The preferred content of anion surfactant is 5.0-30%.
Described nonionogenic tenside is any or two or more mixture in fatty alcohol-polyoxyethylene ether-9, fatty alcohol-polyoxyethylene ether-7, fatty alcohol-polyoxyethylene ether-5, collateralization fatty alcohol-polyoxyethylene ether, alkylolamide, alkyl-glucoside, monoolein, sucrose ester, fatty acid methyl ester ethoxylate, polyglycerol fatty acid ester, amine oxide.The preferred content of nonionogenic tenside is 0.5-15%.
Described amphoterics is any or two or more mixture in lauryl L-Ala diethanolamine salt, lauryl Sodium L-alaninate, AMONYL 380LC, alkyl hydroxyl sulfopropyl betaine, tetrahydroglyoxaline.The preferred content of amphoterics is 0.5-10%.
In addition, sequestrant of the present invention is preferably the MDGA trisodium, and its chemical structural formula is as follows
(trisodium salt), its preferred addition is 0.01-3.0%.
Described viscosity modifier is mixture any or two or more in sodium-chlor, sodium sulfate, sodium bicarbonate, ethanol, propylene glycol, sodium xylene sulfonate, cumene sodium sulfonate.The preferred content of viscosity modifier is 0.1～2.0%.
Described fungicidal preservative has Sodium Benzoate, methylisothiazolinone, Phenoxyethanol, wherein preferable methyl isothiazolinone more; Preferred addition is 0.01-0.1%.
Other components of the present invention are photostabilizer, antioxidant, essence, and these components are the universaling component of detergent composition, and kind is not done specific restriction, and the preferred addition of other components is 0.04-0.1%.
Dish washing detergent compositions with removing tea stain effect of the present invention has following advantage and beneficial effect:
Dish washing detergent of the present invention is owing to adopting special sequestrant MDGA trisodium in its formula, compare with common dish washing detergent in the past, utilize the prepared special dish washing compositions of the inventive method, an outstanding feature is to have to remove preferably tea stain spot effect, with the multi-efficiency of wash dishes, fruits and vegetables and removing tea stain.
Embodiment
Dish washing detergent compositions of the present invention is comprised of the material component of following weight percent:
The preferred content of anion surfactant is 5.0～30.0%, the preferred content of nonionic watch active agent is 0.5～15.0%, the preferred content of amphoterics is 0.5～10%, the preferred content of sequestrant is 0.01～3.0%, the preferred content of viscosity modifier is 0.1～2.0%, and the preferred content of fungicidal preservative is 0.01～0.1%.The preferred content of other components is 0.04～0.1%, and surplus is deionized water.
The preferred special sequestrant MDGA trisodium of the present invention, also has and removes preferably tea stain spot effect when keeping the product detergency ability as the decontamination component.
In addition, the preparation method of dish washing detergent compositions of the present invention comprises following steps:
(1) first add first part's water of the 60-70% of the deionized water weight in total raw material in the ingredients pot;
(2) input table surface-active agent successively is stirred to dissolving fully;
(3) drop into sequestrant, be stirred to dissolving fully;
(4) drop into surplus, be stirred to dissolving fully;
(5) adjust the pH value to 6.2-8.5, be stirred to dissolving fully;
When (6) in the pot, temperature of charge is lower than 40 ℃, drop into other components;
(7) drop into viscosity modifier, stir; Sample examination, qualified discharging;
In above-mentioned steps (7), when adopting sodium-chlor to be viscosity modifier, before using, need sodium-chlor is mixed with the sodium chloride aqueous solution that mass concentration is 20-40%.
Draw samples is also checked according to quality standard.Qualified product are standing to basic non-foam, can be the finished product dish washing detergent compositions.
Below by concrete preferred embodiment, the present invention is described in further detail, but the present invention is not limited in following embodiment.
Embodiment 1
According to the formulation content of table 1, successively tensio-active agent, sequestrant, pH adjusting agent, photostabilizer, antioxidant, essence and viscosity modifier are joined in deionized water in a certain order, be stirred to and be uniformly dissolved.Draw samples is checked according to quality standard.Qualified product are standing to basic non-foam, can be the finished product dish washing detergent compositions.
The formula of the dish washing detergent compositions of table 1 embodiment 1 forms
The dish washing detergent of embodiment 1 preparation carries out the test of tea stain soil release, found that, it is fine that this washing composition is removed tea stain effect; The tea stain soil release effect of the common dish washing detergent of while contrast test, effect is relatively poor.
Embodiment 2
According to the formulation content of table 2, successively tensio-active agent, sequestrant, pH adjusting agent, photostabilizer, antioxidant, essence and viscosity modifier are joined in deionized water in a certain order, be stirred to and be uniformly dissolved.Draw samples is checked according to quality standard.Qualified product are standing to basic non-foam, can be the finished product dish washing detergent compositions.
The formula of the dish washing detergent compositions of table 2 embodiment 2 forms
The dish washing detergent of embodiment 2 preparations carries out the test of tea stain soil release, found that, it is fine that this washing composition is removed tea stain effect; The tea stain soil release effect of the common dish washing detergent of while contrast test, effect is relatively poor.
Embodiment 3
According to the formulation content of table 3, tensio-active agent, sequestrant, pH adjusting agent, photostabilizer, antioxidant, essence and viscosity modifier are joined in deionized water in a certain order, be stirred to and be uniformly dissolved.Draw samples is checked according to quality standard.Qualified product are standing to basic non-foam, can be the finished product dish washing detergent compositions.
The formula of the dish washing detergent compositions of table 3 embodiment 3 forms
The dish washing detergent of embodiment 3 preparations carries out the test of tea stain soil release, found that, it is fine that this washing composition is removed tea stain effect; The tea stain soil release effect of the common dish washing detergent of while contrast test, effect is relatively poor.
The above, it is only preferred embodiment of the present invention, be not that the present invention is done any pro forma restriction, therefore every technical solution of the present invention content that do not break away from,, all still belong in the scope of technical solution of the present invention any simple modification, equivalent variations and modification that above embodiment does according to technical spirit of the present invention.
Claims (9)
1. one kind has the dish washing detergent compositions of removing tea stain effect, and it is characterized in that: it is formulated by the feed composition of following weight percent:
Tensio-active agent 0.1-50%, sequestrant 0.01-10.0%, viscosity modifier 0.1-5.0%, fungicidal preservative 0.01-0.5%, other components 0.01-0.1%, surplus is deionized water.
2. dish washing detergent compositions according to claim 1, it is characterized in that: described sequestrant is the MDGA trisodium.
3. dish washing detergent compositions according to claim 1, it is characterized in that: described tensio-active agent is at least a or two or more mixture in anion surfactant, nonionogenic tenside or amphoterics.
4. dish washing detergent compositions according to claim 3, is characterized in that: the anion surfactant that contains 5.0-30%; Described anion surfactant is any one or more mixture in polyoxyethylenated alcohol sodium sulfate, fatty alcohol-polyoxyethylene ether carboxylic acid sodium, sodium alkyl sulfate, alkyl sodium sulfonate, a-sodium olefin sulfonate, methyl sodiosul foaliphatate, sulfo-succinic acid ester sodium salt.
5. dish washing detergent compositions according to claim 3, is characterized in that: the nonionogenic tenside that contains 0.5-15%; Described nonionogenic tenside is any or two or more mixture in fatty alcohol-polyoxyethylene ether-9, fatty alcohol-polyoxyethylene ether-7, fatty alcohol-polyoxyethylene ether-5, collateralization fatty alcohol-polyoxyethylene ether, alkylolamide, alkyl-glucoside, monoolein, sucrose ester, fatty acid methyl ester ethoxylate, polyglycerol fatty acid ester, amine oxide.
6. dish washing detergent compositions according to claim 3, is characterized in that: the amphoterics that contains 0.5-5.0%; Described amphoterics is any or two or more mixture in lauryl L-Ala diethanolamine salt, lauryl Sodium L-alaninate, AMONYL 380LC, alkyl hydroxyl sulfopropyl betaine, tetrahydroglyoxaline.
7. dish washing detergent compositions according to claim 1, it is characterized in that: described viscosity modifier is mixture any one or more in sodium-chlor, sodium sulfate, sodium bicarbonate, ethanol, propylene glycol, sodium xylene sulfonate, cumene sodium sulfonate.
8. dish washing detergent compositions according to claim 1 is characterized in that: described fungicidal preservative is any or two or more mixture in Sodium Benzoate, methylisothiazolinone, Phenoxyethanol.
9. according to claim 1-8 described dish washing detergent compositions of any one, it is characterized in that: described other components comprise photostabilizer, antioxidant, essence, and these components are the universaling component of detergent composition, and kind is not done specific restriction.
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Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103320240A (en) * | 2013-07-05 | 2013-09-25 | 宋子奎 | Bleaching agent composition and detergent composition |
| CN103333749A (en) * | 2013-07-02 | 2013-10-02 | 武汉理工大学 | Near neutral environment-friendly water-based cleaning agent and preparation method thereof |
| CN103340584A (en) * | 2013-07-17 | 2013-10-09 | 深圳市妍倩科技有限公司 | Wet tissue for kitchen cleaning and disinfection |
| CN104651081A (en) * | 2013-11-18 | 2015-05-27 | 青岛锦涟鑫商贸有限公司 | Novel cleaning agent |
| CN106701337A (en) * | 2016-12-29 | 2017-05-24 | 上海和黄白猫有限公司 | Viscous nonionic system liquid detergent composition |
| CN106753830A (en) * | 2016-12-16 | 2017-05-31 | 上海和黄白猫有限公司 | The liquid dishwashing detergent of stain can be removed |
| CN107099394A (en) * | 2017-05-30 | 2017-08-29 | 山东黄河三角洲纺织科技研究院有限公司 | A kind of cleaning fluid for removing dyestuff and preparation method thereof |
| CN107922890A (en) * | 2015-08-10 | 2018-04-17 | 狮王株式会社 | Wash up washes agent by liquid |
| CN108034520A (en) * | 2017-12-29 | 2018-05-15 | 广州馨香日用化工有限公司 | One kind machine washing cleaning agent for dinnerware |
| CN108165376A (en) * | 2017-12-05 | 2018-06-15 | 山东泰和水处理科技股份有限公司 | A kind of detergent |
| CN108251225A (en) * | 2017-12-01 | 2018-07-06 | 广州佰信生物科技有限公司 | A kind of neutrality environment-protecting clean stoste and preparation method thereof |
| CN109234064A (en) * | 2018-09-06 | 2019-01-18 | 山西涑涑净商贸有限公司 | One kind disappears cleaning and preparation method thereof |
| CN109439456A (en) * | 2018-11-28 | 2019-03-08 | 山东海天生物化工有限公司 | A kind of sodium bicarbonate lotion dish washing detergent |
| CN109593614A (en) * | 2018-11-28 | 2019-04-09 | 山东海天生物化工有限公司 | A kind of fruits and vegetables cleaning agent |
| CN109593615A (en) * | 2018-11-28 | 2019-04-09 | 山东海天生物化工有限公司 | A kind of preparation method of sodium bicarbonate detergent |
| CN114634845A (en) * | 2022-03-23 | 2022-06-17 | 广州蓝月亮实业有限公司 | Dishwashing composition |
| CN114921293A (en) * | 2022-06-13 | 2022-08-19 | 西安优露清科技股份有限公司 | Abrasive cleaner for immediately removing clothes stains and preparation method thereof |
| CN114989904A (en) * | 2022-05-11 | 2022-09-02 | 山西焦煤运城盐化集团有限责任公司 | Ultra-low viscosity tableware detergent composition |
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Cited By (22)
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|---|---|---|---|---|
| CN103333749A (en) * | 2013-07-02 | 2013-10-02 | 武汉理工大学 | Near neutral environment-friendly water-based cleaning agent and preparation method thereof |
| CN103333749B (en) * | 2013-07-02 | 2015-12-09 | 武汉理工大学 | Environment protection water-based clean-out system of Near neutral and preparation method thereof |
| CN103320240A (en) * | 2013-07-05 | 2013-09-25 | 宋子奎 | Bleaching agent composition and detergent composition |
| CN103320240B (en) * | 2013-07-05 | 2014-12-24 | 宋子奎 | Bleaching agent composition and detergent composition |
| CN103340584A (en) * | 2013-07-17 | 2013-10-09 | 深圳市妍倩科技有限公司 | Wet tissue for kitchen cleaning and disinfection |
| CN104651081A (en) * | 2013-11-18 | 2015-05-27 | 青岛锦涟鑫商贸有限公司 | Novel cleaning agent |
| CN107922890A (en) * | 2015-08-10 | 2018-04-17 | 狮王株式会社 | Wash up washes agent by liquid |
| CN107922890B (en) * | 2015-08-10 | 2021-01-26 | 狮王株式会社 | Liquid detergent for washing tableware |
| CN106753830A (en) * | 2016-12-16 | 2017-05-31 | 上海和黄白猫有限公司 | The liquid dishwashing detergent of stain can be removed |
| CN106701337A (en) * | 2016-12-29 | 2017-05-24 | 上海和黄白猫有限公司 | Viscous nonionic system liquid detergent composition |
| CN107099394A (en) * | 2017-05-30 | 2017-08-29 | 山东黄河三角洲纺织科技研究院有限公司 | A kind of cleaning fluid for removing dyestuff and preparation method thereof |
| CN108251225A (en) * | 2017-12-01 | 2018-07-06 | 广州佰信生物科技有限公司 | A kind of neutrality environment-protecting clean stoste and preparation method thereof |
| CN108165376A (en) * | 2017-12-05 | 2018-06-15 | 山东泰和水处理科技股份有限公司 | A kind of detergent |
| CN108165376B (en) * | 2017-12-05 | 2021-03-12 | 山东泰和水处理科技股份有限公司 | Detergent |
| CN108034520A (en) * | 2017-12-29 | 2018-05-15 | 广州馨香日用化工有限公司 | One kind machine washing cleaning agent for dinnerware |
| CN109234064A (en) * | 2018-09-06 | 2019-01-18 | 山西涑涑净商贸有限公司 | One kind disappears cleaning and preparation method thereof |
| CN109593614A (en) * | 2018-11-28 | 2019-04-09 | 山东海天生物化工有限公司 | A kind of fruits and vegetables cleaning agent |
| CN109593615A (en) * | 2018-11-28 | 2019-04-09 | 山东海天生物化工有限公司 | A kind of preparation method of sodium bicarbonate detergent |
| CN109439456A (en) * | 2018-11-28 | 2019-03-08 | 山东海天生物化工有限公司 | A kind of sodium bicarbonate lotion dish washing detergent |
| CN114634845A (en) * | 2022-03-23 | 2022-06-17 | 广州蓝月亮实业有限公司 | Dishwashing composition |
| CN114989904A (en) * | 2022-05-11 | 2022-09-02 | 山西焦煤运城盐化集团有限责任公司 | Ultra-low viscosity tableware detergent composition |
| CN114921293A (en) * | 2022-06-13 | 2022-08-19 | 西安优露清科技股份有限公司 | Abrasive cleaner for immediately removing clothes stains and preparation method thereof |
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Application publication date: 20130612 |