CN108251225A - A kind of neutrality environment-protecting clean stoste and preparation method thereof - Google Patents
A kind of neutrality environment-protecting clean stoste and preparation method thereof Download PDFInfo
- Publication number
- CN108251225A CN108251225A CN201711251843.9A CN201711251843A CN108251225A CN 108251225 A CN108251225 A CN 108251225A CN 201711251843 A CN201711251843 A CN 201711251843A CN 108251225 A CN108251225 A CN 108251225A
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- China
- Prior art keywords
- parts
- fatty acid
- protecting clean
- preparation
- polyethylene glycol
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
Abstract
The invention discloses a kind of neutral environment-protecting clean stostes and preparation method thereof, and neutral environment-protecting clean stoste is prepared by the component of following parts by weight：8 18 parts of 30 50 parts of polyglyceryl fatty acid ester, 25 38 parts of cocoanut fatty acid diethanolamide, 12 20 parts of oleoyl sarcosine sodium, fatty alcohol and ethylene oxide condensate, 0.05 2 parts of polyethylene glycol.The application on the basis of original non-ionic surface active by doing the adjustment adapted to, it is modulated by a variety of nonionic surfactants and conditioner through highly enriched, permanent accumulation can quickly be penetrated into and form the heavy oil dirt that glutinous greasy difficulty is removed, then effective rapid pin decomposes greasy dirt, is emulsified, is catalyzed, disintegrating the glutinous greasy heavy oil dirt that greasy dirt has polymerize, and achievees the effect that quickly to remove.
Description
Technical field
The present invention relates to a kind of detergent technologies more particularly to a kind of neutral environment-protecting clean stoste and preparation method thereof.
Background technology
Electric appliance in kitchen is the severely afflicated area of oil foulant, and the formula of the existing pollution cleanser that deoils is as follows：15.0 parts of sulfonic acid,
1.5 parts of potassium hydroxide, 1.5 parts of cocoanut fatty acid diethanolamide, 77.0 parts of pure water, fatty alcohol and ethylene oxide condensate
5.0 parts, 0.15 part of Kathon CG.The pollution cleanser that deoils is with following defect：(1) it is strong acid or strong base, corrosivity is strong, to object
Surface grievous injury；(2) chemical reagent, volatility are big, and smell is big, and corrosivity is strong；(3) contain preservative, as Kathon CG removes；(4)
Oily decontamination is not strong, has large effect to people and environment；(5) it is not easy to store, there is safety problem.
Invention content
For overcome the deficiencies in the prior art, one of the objects of the present invention is to provide a kind of neutral environment-protecting clean stostes.
The application on the basis of original non-ionic surface active by doing the adjustment adapted to, by a variety of nonionic surfactants and tune
Reason agent is modulated through highly enriched, can quickly be penetrated into permanent accumulation and be formed the heavy oil dirt that glutinous greasy difficulty is removed, then effective rapid pin
Greasy dirt is decomposed, is emulsified, is catalyzed, disintegrates the glutinous greasy heavy oil dirt that greasy dirt has polymerize, achievees the effect that quickly to remove.Simultaneously originally
Product pH value 5.0-7.5, to be neutral, to human skin, manual dishwashing, ceramic tile, surface, metal surface, cotton fibriia without perverse
Swash property, non-corrosive,
The second object of the present invention is to provide a kind of preparation method of neutral environment-protecting clean stoste.The preparation side of the present invention
Method is easy to operate, more preferable easy to operate, at low cost, suitable for industrialized production.
An object of the present invention adopts the following technical scheme that realization：A kind of neutrality environment-protecting clean stoste, which is characterized in that
It is prepared by the component of following parts by weight：30-50 parts of polyglyceryl fatty acid ester, cocoanut fatty acid diethanolamide 25-38
Part, 12-20 parts of oleoyl sarcosine sodium, fatty alcohol and 8-18 parts of ethylene oxide condensate, 0.05-2 parts of polyethylene glycol.
Further, the neutral environment-protecting clean stoste is prepared by the component of following parts by weight：Polyglycereol fat
35-42 parts of acid esters, 28-35 parts of cocoanut fatty acid diethanolamide, 15-18 parts of oleoyl sarcosine sodium, fatty alcohol and epoxy second
10-16 parts of alkane condensation product, 0.05-1 parts of polyethylene glycol.
Further, the neutral environment-protecting clean stoste is prepared by the component of following parts by weight：Polyglycereol fat
38 parts of acid esters, 32 parts of cocoanut fatty acid diethanolamide, 16.5 parts of oleoyl sarcosine sodium, fatty alcohol and ethylene oxide condensate
13 parts, 0.5 part of polyethylene glycol.
Further, the polyethylene glycol is PEG-8000.
The second object of the present invention adopts the following technical scheme that realization：A kind of preparation method of neutrality environment-protecting clean stoste,
Including,
The preparation process of raw material：Polyglyceryl fatty acid ester, coconut grease are weighed by the formula ratio of neutral environment-protecting clean stoste
Fat acid diglycollic amide, oleoyl sarcosine sodium, fatty alcohol and ethylene oxide condensate, polyethylene glycol；
The step of reaction：By polyglyceryl fatty acid ester, cocoanut fatty acid diethanolamide, oleoyl sarcosine sodium, fat
Alcohol is put into reaction pot in order with ethylene oxide condensate, polyethylene glycol, is stirred while raw material is added in；Wait own
It after raw material input reaction pot, starts to warm up while stirring, after being warming up to 75-85 DEG C, keeps the temperature 25-40min, stirring is to having reacted
Entirely；
The step of discharging：It after all raw materials are completely dissolved, begins to cool down, is cooled to 45 DEG C, discharging.
Further, in the preparation process of raw material, it is described neutrality environment-protecting clean stoste by following parts by weight component system
It is standby to form：38 parts of polyglyceryl fatty acid ester, 32 parts of cocoanut fatty acid diethanolamide, 16.5 parts of oleoyl sarcosine sodium, fat
Alcohol and 13 parts of ethylene oxide condensate, 0.5 part of polyethylene glycol.
Further, the polyethylene glycol is PEG-8000.
Further, in the step of reaction, the speed of the stirring is 300 turns/min.
Further, in the step of reaction, the temperature for starting to warm up middle heating while stirring is 80 DEG C, Ran Houbao
Hold 80 DEG C of temperature 30min.
Compared with prior art, the beneficial effects of the present invention are：
The application is lived by doing the adjustment adapted on the basis of original non-ionic surface active by a variety of non-ionic surfaces
Property agent and conditioner modulated through highly enriched, can quickly penetrate into permanent accumulation and formed and stick the heavy oil dirt that greasy difficulty is removed, Ran Houyou
Effect rapid pin decomposes greasy dirt, is emulsified, is catalyzed, disintegrating the glutinous greasy heavy oil dirt that greasy dirt has polymerize, and reaches the effect quickly removed
Fruit.
This product pH value 5.0-7.5 simultaneously, to be neutral, to human skin, manual dishwashing, ceramic tile, surface, metal watch
Face, cotton fibriia without excitatory, non-corrosive,
This product is a kind of highly enriched cleaning stoste of the nonionic of neutrality, and the decontamination that can deoil can save the environment-friendly materials of water,
It during use, is reused after dilution, dilution ratio 100：(2-15), be added to the water stir evenly i.e. can be used.
Specific embodiment
In the following, with reference to specific embodiment, the present invention is described further, it should be noted that is do not collided
Under the premise of, new embodiment can be formed between various embodiments described below or between each technical characteristic in any combination.
In the present invention, if not refering in particular to, all parts, percentage are unit of weight, used equipment and raw material etc.
It is commercially available or commonly used in the art.Method in following embodiments is the normal of this field unless otherwise instructed
Rule method.
A kind of neutrality environment-protecting clean stoste, is prepared by the component of following parts by weight：Polyglyceryl fatty acid ester 30-50
Part, 25-38 parts of cocoanut fatty acid diethanolamide, 12-20 parts of oleoyl sarcosine sodium, fatty alcohol and ethylene oxide condensate 8-
18 parts, 0.05-2 parts of polyethylene glycol.
Be formulated as a further preference, the neutral environment-protecting clean stoste by following parts by weight component prepare and
Into：35-42 parts of polyglyceryl fatty acid ester, 28-35 parts of cocoanut fatty acid diethanolamide, 15-18 parts of oleoyl sarcosine sodium, fat
Fat alcohol and 10-16 parts of ethylene oxide condensate, 0.05-1 parts of polyethylene glycol.
As best optimization formula, the neutral environment-protecting clean stoste is prepared by the component of following parts by weight：
38 parts of polyglyceryl fatty acid ester, 32 parts of cocoanut fatty acid diethanolamide, 16.5 parts of oleoyl sarcosine sodium, fatty alcohol and epoxy
13 parts of oxide condensate, 0.5 part of polyethylene glycol.
Wherein, the polyethylene glycol is preferably PEG-8000.
The preparation method of the neutrality environment-protecting clean stoste, including,
The preparation process of raw material：Polyglyceryl fatty acid ester, coconut grease are weighed by the formula ratio of neutral environment-protecting clean stoste
Fat acid diglycollic amide, oleoyl sarcosine sodium, fatty alcohol and ethylene oxide condensate, polyethylene glycol；
The step of reaction：By polyglyceryl fatty acid ester, cocoanut fatty acid diethanolamide, oleoyl sarcosine sodium, fat
Alcohol is put into reaction pot in order with ethylene oxide condensate, polyethylene glycol, is stirred while raw material is added in, stirring
Speed is 300 turns/min；After all raw materials put into reaction pot, start to warm up while stirring, after being warming up to 75-85 DEG C, heat preservation
25-40min, stirring is to the reaction was complete；Preferably, in the step of reaction, the temperature for starting to warm up middle heating while stirring
It is 80 DEG C to spend, and then keeps 80 DEG C of temperature 30min.
The step of discharging：It after all raw materials are completely dissolved, begins to cool down, is cooled to 45 DEG C, discharging.
It is specific embodiment of the present invention below, used raw material, equipment etc. remove special limit in the following embodiments
It can be obtained outside fixed by buying pattern.
Embodiment 1-5 and comparative example
The proportioning according to the form below 1 weighs raw material respectively, is prepared in accordance with the following steps, the difference lies in what is added
Raw material proportioning is different, prepares product, specifically refers to table 1：
The formula of comparative example is 15.0 parts of sulfonic acid, 1.5 parts of potassium hydroxide, 1.5 parts of cocoanut fatty acid diethanolamide, pure
5.0 parts of 77.0 parts of water, fatty alcohol and ethylene oxide condensate, 0.15 part of Kathon CG.
Table 1：The raw material proportioning table of embodiment 1-5
Effect assessment and performance detection
The dirt-removing power of the cleaning stoste of embodiment 1-5 is detected
Detection method is as follows：It takes and the bowl of 3 months has been placed in certain restaurant kitchen as cleaning object, be covered on the bowl same
The thick and heavy greasy dirt of sample, then by the cleaning stoste of embodiment 1-5 with 100:2 ratio is diluted, and is packed into 5 beakers
The dilution of 500ml, is respectively labeled as A, B, C, D, E, the formula 500ml of comparative example is added in the 6th beaker, labeled as F.So
Bowl is respectively put into A, B, C, D, E, F beaker afterwards and impregnates 10s, removes, the heavy oil stain in each bowl is observed, as a result referring to table
2。
2 embodiment 1-5 of table and comparative example cleaning test result
As known from Table 2, (10s) quickly penetrates into length to the obtained neutral Environment protection cleaning stostes of embodiment 1-5 in a short time
Accumulation long, which is formed, sticks the heavy oil dirt that greasy difficulty is removed, and then effective rapid pin decomposes greasy dirt, emulsifies, is catalyzed, disintegrates greasy dirt
The glutinous greasy heavy oil having polymerize is dirty, achievees the effect that quickly to remove.The especially formula of embodiment 1 is optimal formula, cleans
Speed is up to 5s.
The above embodiment is only the preferred embodiment of the present invention, it is impossible to the scope of protection of the invention is limited with this,
The variation and replacement for any unsubstantiality that those skilled in the art is done on the basis of the present invention belong to institute of the present invention
Claimed range.
Claims (9)
1. a kind of neutrality environment-protecting clean stoste, which is characterized in that be prepared by the component of following parts by weight：Polyglycerol fatty acid
30-50 parts of ester, 25-38 parts of cocoanut fatty acid diethanolamide, 12-20 parts of oleoyl sarcosine sodium, fatty alcohol and ethylene oxide
8-18 parts of condensation product, 0.05-2 parts of polyethylene glycol.
2. neutrality environment-protecting clean stoste as described in claim 1, which is characterized in that by the component preparation of following parts by weight
Into：35-42 parts of polyglyceryl fatty acid ester, 28-35 parts of cocoanut fatty acid diethanolamide, 15-18 parts of oleoyl sarcosine sodium, fat
Fat alcohol and 10-16 parts of ethylene oxide condensate, 0.05-1 parts of polyethylene glycol.
3. neutrality environment-protecting clean stoste as described in claim 1, which is characterized in that by the component preparation of following parts by weight
Into：38 parts of polyglyceryl fatty acid ester, 32 parts of cocoanut fatty acid diethanolamide, 16.5 parts of oleoyl sarcosine sodium, fatty alcohol with
13 parts of ethylene oxide condensate, 0.5 part of polyethylene glycol.
4. neutrality environment-protecting clean stoste as described in claim 1, which is characterized in that the polyethylene glycol is PEG-8000.
5. a kind of preparation method of neutrality environment-protecting clean stoste, it is characterised in that including,
The preparation process of raw material：Polyglyceryl fatty acid ester, coco-nut oil fatty acid are weighed by the formula ratio of neutral environment-protecting clean stoste
Diglycollic amide, oleoyl sarcosine sodium, fatty alcohol and ethylene oxide condensate, polyethylene glycol；
The step of reaction：By polyglyceryl fatty acid ester, cocoanut fatty acid diethanolamide, oleoyl sarcosine sodium, fatty alcohol with
Ethylene oxide condensate, polyethylene glycol are put into reaction pot in order, are stirred while raw material is added in；Treat all raw materials
It after putting into reaction pot, starts to warm up while stirring, after being warming up to 75-85 DEG C, keeps the temperature 25-40min, stirring is to the reaction was complete；
The step of discharging：It after all raw materials are completely dissolved, begins to cool down, is cooled to 45 DEG C, discharging.
6. the preparation method of neutrality environment-protecting clean stoste as claimed in claim 5, which is characterized in that in the preparation process of raw material
In, the neutrality environment-protecting clean stoste is prepared by the component of following parts by weight：38 parts of polyglyceryl fatty acid ester, coconut grease
32 parts of fat acid diglycollic amide, 16.5 parts of oleoyl sarcosine sodium, fatty alcohol and 13 parts of ethylene oxide condensate, polyethylene glycol 0.5
Part.
7. the preparation method of neutrality environment-protecting clean stoste as claimed in claim 6, which is characterized in that the polyethylene glycol is
PEG-8000。
8. the preparation method of neutrality environment-protecting clean stoste as claimed in claim 5, which is characterized in that in the step of reaction,
The speed of the stirring is 300 turns/min.
9. the preparation method of neutrality environment-protecting clean stoste as claimed in claim 5, which is characterized in that in the step of reaction,
The temperature for starting to warm up middle heating while stirring is 80 DEG C, then keeps 80 DEG C of temperature 30min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711251843.9A CN108251225A (en) | 2017-12-01 | 2017-12-01 | A kind of neutrality environment-protecting clean stoste and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711251843.9A CN108251225A (en) | 2017-12-01 | 2017-12-01 | A kind of neutrality environment-protecting clean stoste and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN108251225A true CN108251225A (en) | 2018-07-06 |
Family
ID=62722347
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711251843.9A Pending CN108251225A (en) | 2017-12-01 | 2017-12-01 | A kind of neutrality environment-protecting clean stoste and preparation method thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103045400A (en) * | 2012-12-18 | 2013-04-17 | 广州立白企业集团有限公司 | Liquid tableware detergent composition containing natural antibacterial components |
| CN103146506A (en) * | 2013-03-05 | 2013-06-12 | 广州立白企业集团有限公司 | Dish washing detergent composition with tea stain cleaning effect |
| CN105062712A (en) * | 2015-07-29 | 2015-11-18 | 广州立白企业集团有限公司 | Foam type fruit-vegetable and tableware detergent composition |
| CN105754752A (en) * | 2016-04-11 | 2016-07-13 | 广州立白企业集团有限公司 | Method for giving gel property to detergent composition and high water content gel-type detergent composition |
| CN106701337A (en) * | 2016-12-29 | 2017-05-24 | 上海和黄白猫有限公司 | Viscous nonionic system liquid detergent composition |
-
2017
- 2017-12-01 CN CN201711251843.9A patent/CN108251225A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103045400A (en) * | 2012-12-18 | 2013-04-17 | 广州立白企业集团有限公司 | Liquid tableware detergent composition containing natural antibacterial components |
| CN103146506A (en) * | 2013-03-05 | 2013-06-12 | 广州立白企业集团有限公司 | Dish washing detergent composition with tea stain cleaning effect |
| CN105062712A (en) * | 2015-07-29 | 2015-11-18 | 广州立白企业集团有限公司 | Foam type fruit-vegetable and tableware detergent composition |
| CN105754752A (en) * | 2016-04-11 | 2016-07-13 | 广州立白企业集团有限公司 | Method for giving gel property to detergent composition and high water content gel-type detergent composition |
| CN106701337A (en) * | 2016-12-29 | 2017-05-24 | 上海和黄白猫有限公司 | Viscous nonionic system liquid detergent composition |
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Application publication date: 20180706 |