JP2005314583A - Cleansing composition for cip - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a cleansing composition for CIP (cleaning in place), capable of removing residual flavor in a good efficiency in the CIP cleaning and almost without remaining solvent smell after the cleaning. <P>SOLUTION: This cleansing composition for the CIP contains (A) an ester compound selected from specific 4 kinds of ester compounds such as an ester of a fatty acid with an alcohol, etc., and water. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention relates to a CIP cleaning composition and a CIP cleaning method. More specifically, the present invention relates to a CIP cleaning composition and a CIP cleaning method used for cleaning manufacturing equipment and manufacturing equipment such as food and beverage factories.

  In food factories, beverage factories, etc., production facilities and equipment are cleaned when production varieties are switched or when operations are completed, etc., but CIP cleaning (stationary cleaning) is difficult for places where piping and tanks are difficult to remove and clean. )It is carried out. This CIP cleaning is a method of cleaning by flowing a cleaning agent without disassembling the apparatus with the word “Cleaning in place”.

  CIP cleaning is widely used in food factories and beverage factories. Especially in beverage factories, when switching production varieties, etc., thoroughly wash the product so that the previous product does not remain on the production line and the flavor contained in the previous product is not mixed into the next product. is important. For this reason, in food factories, etc., CIP cleaning is carried out over time. In particular, flavors tend to remain in the packing parts (seal parts) such as pipe connection parts in the production line in order to sufficiently remove the flavors. Takes a lot of effort.

In recent years, with the increase in production speed and the increase in beverage varieties, the frequency of switching is increased, and the time loss of the CIP process is a cause of remarkably reducing productivity.
Conventionally, in CIP cleaning, alkali cleaning, acid cleaning, and cleaning using a combination of these are appropriately performed in accordance with dirt inside manufacturing equipment and piping of manufacturing equipment, but in order to increase cleaning efficiency, In some cases, an oxidizing agent such as chlorate, isocyanurate, percarbonate, or perborate is used. However, a sufficient deodorizing effect is still not obtained, and damage to the device may occur depending on the use situation.

Under these circumstances, techniques for further improving the cleaning efficiency and flavor removal efficiency in CIP cleaning have been proposed. For example, Patent Document 1 discloses a technique for deodorizing and cleaning using a nonionic surfactant, but even with this method, flavor removal is not sufficient.
JP 2003-49193 A

  In view of the above situation, an object of the present invention is to provide a CIP cleaning composition and a CIP cleaning method that can efficiently remove the remaining flavor in the currently performed CIP process and hardly leave a solvent odor after cleaning. .

  The present invention relates to a CIP cleaning composition containing one or more ester compounds (A) represented by the following general formulas (1) to (4) (hereinafter referred to as the component (A)) and water.

[In the formula, R ^{11 to} R ¹⁶ may be the same or different, each having an alkyl group having 1 to 30 carbon atoms, an alkyl group having 1 to 30 carbon atoms substituted with a hydroxyl group, or 2 to 30 carbon atoms. An alkenyl group, an aryl group having 6 to 30 carbon atoms, an arylalkyl group having 7 to 30 carbon atoms, or an alkylaryl group having 7 to 30 carbon atoms is represented. R ¹⁷ represents an alkylene group having 1 to 20 carbon atoms or an alkenylene group having 2 to 20 carbon atoms. R ²¹ , R ²⁴ , and R ²⁵ may be the same or different, each having an alkyl group having 1 to 24 carbon atoms, an alkyl group having 2 to 24 carbon atoms substituted with a hydroxyl group, or an alkenyl having 2 to 24 carbon atoms. Group, an aryl group having 6 to 24 carbon atoms, an arylalkyl group having 7 to 24 carbon atoms, or an alkylaryl group having 7 to 24 carbon atoms. R ²² is an alkylene group having 2 to 24 carbon atoms, an alkenylene group having 2 to 24 carbon atoms, an arylene group having 6 to 24 carbon atoms, an arylene alkylene group having 7 to 24 carbon atoms, or an alkylarylene group having 7 to 24 carbon atoms. Represents. R ²³ represents a group obtained by removing a hydroxyl group from a trivalent alcohol having 3 to 24 carbon atoms. ]

  The present invention also relates to a CIP cleaning method including a step (1) of bringing the cleaning medium (I) containing the specific compound (A), the surfactant (B) and water into contact with an object to be cleaned.

  The present invention also includes a step (2) of bringing the cleaning compound (II) containing the specific compound (A) and water into contact with an object to be cleaned, and a cleaning medium (S) containing a surfactant (B) and water ( The present invention relates to a CIP cleaning method including a step (3) performed after the previous step (2), wherein III) is brought into contact with an object to be cleaned.

  According to the present invention, in CIP cleaning, flavors can be efficiently removed, and there is almost no solvent odor even after cleaning, and the cleaning time can be shortened compared to the prior art.

<(A) component>
In the present invention, as the component (A), one or more ester compounds represented by the general formulas (1) to (4) are used from the viewpoints of base odor and deodorization. From the viewpoint of deodorization, an ester compound represented by the general formula (1) or an ester compound represented by the general formula (3) is preferable.

In the general formula (1), the total number of carbon atoms of R ¹¹ and R ²¹ is preferably 3-54, more preferably 5-40, particularly preferably 10 to 30.

In General formula (2), 6-84 are preferable, as for the total carbon number of R < ¹² >, R < ¹³ > and R < ²² >, 10-60 are more preferable, and 16-40 are especially preferable.

In the general formula (3), the total carbon number of R ¹⁴ , R ¹⁵ , R ¹⁶ and R ²³ is preferably 9 to 114, more preferably 15 to 80, and particularly preferably 20 to 70.

In the general formula (4), the total number of carbon atoms in R ^17, R ²⁴ and R ²⁵ is preferably 3-68, more preferably from 10 to 60, particularly preferably from 15 to 50.

  Examples of the ester compound of the general formula (1) include methyl hexanoate, hexyl acetate, ethyl butyrate, octyl acetate, isoamyl acetate, ethyl myristate, octyl stearate, isooctyl myristate, oleyl oleate, isooctyl oleate, methyl laurate , Ethyl laurate, methyl stearate, ethyl stearate, isoamyl butyrate, phenylethyl acetate, geranyl formate, citronellyl acetate, ethyl benzoate, octyldodecyl oleate, octyldodecyl stearate or octyldodecyl myristate, etc. Ethyl acrylate, octyl stearate, isooctyl myristate, oleyl oleate, isooctyl oleate, methyl laurate, ethyl laurate, methyl stearate, stearic acid Chill, octyldodecyl oleate, octyldodecyl or octyldodecyl myristate stearate are preferred.

  Examples of the ester compound of the general formula (2) include ethylene glycol diolate, ethylene glycol dilaurate, ethylene glycol distearate, propylene glycol dilaurate or propylene glycol distearate, and ethylene glycol diolate, ethylene glycol dilaurate or propylene. Glycol dilaurate is preferred.

  Examples of the ester compound represented by the general formula (3) include triglycerides, beef tallow, lard, bone oil, whale oil, and cinnamon that are present in various vegetable oils represented by rapeseed oil, olive oil, coconut oil, sesame oil, corn oil, soybean oil and the like. Examples include triglycerides, glycerin tristearate, glycerin trilaurate, or glycerin triacetate present in various animal oils such as oil and sardine oil. Triglycerides, glycerin tris present in rapeseed oil, coconut oil, and soybean oil Laurate or glycerin triacetate is preferred.

  Examples of the ester compound of the general formula (4) include dimethyl adipate, diethyl adipate, dioctyl phthalate, dimethyl azelate or diethyl azelate, and dimethyl adipate, diethyl adipate or dioctyl phthalate is preferable.

  The component (A) of the present invention preferably has a solubility in water at 25 ° C. of 10% by weight or less. The solubility here refers to the maximum concentration at which the appearance can be kept transparent in a uniform phase by adding the component (A) in water at 25 ° C. [weight (g) of the component (A) with respect to 100 g of water: unit is % By weight]. (A) As a component, since it is excellent in deodorizing property (odor removal performance), a thing whose solubility is 10 weight% or less is preferable, 8 weight% or less is more preferable, and 5 weight% or less is especially preferable.

  The component (A) of the present invention preferably has a melting point of 100 ° C. or lower, more preferably 80 ° C. or lower, from the viewpoint of base odor and deodorizing property. In particular, 65 ° C. or lower is preferable.

<(B) component>
The cleaning composition for CIP of the present invention preferably contains a surfactant (B) [hereinafter referred to as component (B)].

  Examples of the component (B) include nonionic surfactants, anionic surfactants, amphoteric surfactants, and cationic surfactants. From the viewpoint of assisting the emulsifying dispersibility of the component (A), nonionic surfactants are used. Or anionic surfactant is preferable.

  Nonionic surfactants include polyoxyalkylene alkyl ether, polyoxyalkylene alkylamine, polyoxyalkylene fatty acid ester, alkyl polyglycoside, alkyl glyceryl ether, glycerin fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, polyoxy Examples include ethylene-polyoxypropylene block polymers or polyoxyalkylene polyhydric alcohol fatty acid esters, preferably polyoxyalkylene fatty acid esters, alkyl polyglycosides, alkyl glyceryl ethers, polyoxyalkylene alkyl ethers, polyoxyalkylene alkyl amines, etc. In particular, alkyl polyglycosides, alkyl glyceryl ethers and polyoxyalkylene alkyls One or more non-ionic surfactant selected from amine are preferred. In these nonionic surfactants, the polyoxyalkylene is preferably polyoxyethylene, polyoxypropylene, or a mixture thereof, and the alkyl group preferably has 8 to 18 carbon atoms, and some can be changed to an alkenyl group. The number of carbon atoms of the fatty acid is preferably 8-18.

  In the case of nonionic surfactants, particularly polyoxyalkylene alkyl ethers, those having an HLB value of 3 or more and less than 8 according to the Griffin calculation formula are preferred.

  As alkyl polyglycoside, 3-30 are preferable, as for carbon number of an alkyl group, 4-24 are especially preferable, and 5-20 are especially preferable. Moreover, 1-10 are preferable, as for the average condensation degree of monosaccharides, such as glucose, 1-5 are especially preferable, and 1-3 are especially preferable. Among the alkylpolyglycosides, alkylpolyglucosides whose constituent sugar is glucose are preferred.

  As alkyl glyceryl ether, 3-30 are preferable, as for carbon number of an alkyl group, 4-24 are especially preferable, and 5-20 are especially preferable.

  As polyoxyalkylene alkylamine, 3-30 are preferable, as for carbon number of an alkyl group, 4-24 are especially preferable, and 5-20 are especially preferable. Moreover, as an alkylene group of polyoxyalkylene, C2-C4 is preferable, 2-3 is especially preferable, and 2 is especially preferable. Moreover, as an average addition mole number of polyoxyalkylene, 2-20 are preferable, 2-15 are especially preferable, and 2-10 are especially preferable.

  Examples of the anionic surfactant include fatty acid salts (preferably 8 to 24 carbon atoms), alkyl (preferably 8 to 24 carbon atoms) sulfonate, alkyl (preferably 8 to 18 carbon atoms) benzene sulfonate, alkyl ( Preferably 8 to 24 carbon atoms sulfate ester, alkyl (preferably 2 to 24 carbon atoms) phosphate ester salt, polyoxyalkylene (preferably polyoxyethylene) alkyl (preferably 8 to 18 carbon atoms) sulfate ester salt , Polyoxyalkylene (preferably polyoxyethylene) alkyl (preferably having 8 to 18 carbon atoms) carboxylate or alkyl (preferably having 6 to 18 carbon atoms) sulfosuccinate.

  Examples of amphoteric surfactants include alkyl (preferably 8 to 18 carbon atoms) amine oxide, alkyl (preferably 8 to 18 carbon atoms) dimethylaminoacetic acid betaine, alkyl (preferably 8 to 18 carbon atoms) amidopropyl betaine, alkyl (Preferably having 8 to 18 carbon atoms) Hydroxysulfobetaine or alkyl (preferably having 8 to 18 carbon atoms) carboxymethylhydroxyethyl imidazolinium betaine and the like can be mentioned.

  Examples of the cationic surfactant include alkyl chloride (preferably 6 to 24 carbon atoms) trimethylammonium, dialkyl chloride (preferably 6 to 18 carbon atoms) dimethylammonium chloride, and benzalkonium chloride (preferably 6 to 18 carbon atoms). Is mentioned.

<CIP cleaning composition>
Examples of the concentrated stock solution used for the CIP cleaning composition of the present invention include the component (A) alone or a mixture of organic solvents compatible with the component (A). As content of (A) component, it is 1 to 100 weight% from an economical viewpoint, Preferably it is 10 to 100 weight%. Most preferably, it is 20-100 weight%.

  Moreover, when the cleaning composition for CIP of this invention contains (B) component, the weight ratio of (A) component and (B) component is (A) / (B) = 1 / 99-99 / 1. Is more preferable, 20/80 to 90/10 is more preferable, and 30/70 to 70/30 is particularly preferable. The water content is preferably more than 0 to 99% by weight, more preferably more than 0 to 90% by weight. Particularly preferably, it is more than 0 to 80% by weight. When the ratio of (A) / (B) is 99/1 or less, the stability of the dispersion system is improved and adsorption contamination to the piping and the like is eliminated. Further, when the ratio (A) / (B) is 1/99 or more, a sufficient deodorizing effect can be obtained.

  In the present invention, the component (A) is a compound or substance selected from octyl stearate, octyldodecyl myristate, triacetin, rapeseed oil, and soybean oil, and the component (B) is an alkylpolyglycoside (specifically decylglucoside). , Undecyl glucoside, lauryl glucoside, tetradecyl glucoside, etc.), alkyl glyceryl ether (specifically, iso-octyl glyceryl ether (eg, 2-ethylhexyl glyceryl ether), n-octyl glyceryl ether, iso-decyl glyceryl ether) , N-decyl glyceryl ether, dodecyl glyceryl ether, etc.], polyoxyalkylene fatty acid ester (specifically, polyoxyethylene oleate, polyoxyethylene laurate, etc.), polyoxya Xylene alkylamine (specifically, polyoxyethylene (ethylene oxide average addition mole number 10) laurylamine, polyoxyethylene (ethylene oxide average addition mole number 9) stearylamine, etc.), and polyoxyl having an HLB of 3 or more and less than 8. A combination that is a surfactant selected from alkylene alkyl ethers is more preferable in terms of cleaning effect. In these, “n-” means a straight chain, and “iso-” means a branched chain.

  In addition to the components (A) and (B), the CIP cleaning composition of the present invention includes an antifoaming agent, a rust inhibitor, a chelating agent, a water-soluble solvent, an inorganic salt, and a water-soluble solvent as necessary. It can be used by adding alcohol.

  The cleaning composition for CIP of the present invention is used for CIP cleaning as a cleaning liquid diluted with a non-aqueous solvent, an aqueous solvent, water or the like. The dilution medium is preferably water from the viewpoint of economy and safety. In the diluted cleaning solution, the concentration of the component (A) is preferably 0.01 to 20% by weight, more preferably 0.1 to 10% by weight, and particularly preferably 0.8% from the viewpoints of cleanability and economy. 5 to 5% by weight. Moreover, it is preferable that the density | concentration of (B) component in this washing | cleaning liquid is 0.01-20 weight% from a viewpoint of the emulsification dispersibility of (A) component, More preferably, it is 0.1-15 weight%, Especially preferably, 0.5 to 10% by weight.

<CIP cleaning method>
As described above, the CIP cleaning composition of the present invention is preferably used as a diluted cleaning solution for CIP cleaning. The cleaning liquid is preferably circulated and cleaned in a range of 10 ° C. to 98 ° C. so as to come into contact with the piping and various devices that are the objects to be cleaned in CIP cleaning. Further, the flow rate of the cleaning liquid flowing in the pipe is preferably 0.5 to 5 m / second, and more preferably 1 to 3 m / second.

  Moreover, in this invention, the CIP washing | cleaning method including the process (1) which makes the to-be-washed | cleaned material contact the washing | cleaning medium (I) containing (A) component, (B) component, and water can be performed. In addition, the step (2) of bringing the cleaning medium (II) containing the component (A) and water into contact with the object to be cleaned, and the cleaning medium containing the component (B) and water performed after the step (2) A CIP cleaning method including a step (3) of bringing (III) into contact with an object to be cleaned can be performed. As the component (A) and the component (B), those described above are used.

  In this case, the cleaning medium (I) and / or (II) is preferably a cleaning liquid obtained by diluting the cleaning composition of the present invention.

  In the cleaning medium (I), the concentration of the component (A) is 0.01 to 20% by weight, more preferably 0.1 to 10% by weight, and particularly 0.5 to 5% by weight. 01 to 20% by weight, more preferably 0.1 to 15% by weight, and particularly 0.5 to 10% by weight. The total of the component (A) and the component (B) is 0.01 to 50% by weight, more preferably 0.1 to 30% by weight, particularly preferably 0.2 to 10% by weight.

  In the cleaning medium (II), the concentration of the component (A) is preferably 0.01 to 50% by weight, more preferably 0.05 to 30% by weight, and particularly preferably 0.1 to 10% by weight. The component (A) used in the cleaning medium (II) may be the same as or different from that used in the cleaning medium (I).

  In the cleaning medium (III), the concentration of the component (B) is preferably 0.01 to 30% by weight, more preferably 0.1 to 20% by weight, and particularly preferably 0.2 to 10% by weight. The cleaning medium (III) may contain the component (A), but from the viewpoint of deodorization, the concentration of the component (A) in the cleaning medium (III) is less than 0.5% by weight. Further, it is preferably 0.3% by weight or less, more preferably 0.2% by weight or less, and particularly preferably less than 0.1% by weight. The component (B) used in the cleaning medium (III) may be the same as or different from that used in the cleaning medium (I).

  The component (B) used in the step (1) or the component (B) used in the step (3) is preferably one or more selected from nonionic surfactants. As the nonionic surfactant, those described above are preferably used.

  For example, CIP washing in a beverage plant is performed by (a) hot water washing → (b) alkali washing → (c) hot water washing → (d) acid washing → (e) hot water washing. Later, if necessary, further washing with hypochlorite and hot water may be performed. The step (1) may be carried out in any of these washing steps, specifically, before and / or after any of the steps (a) to (d), or any step. It can be performed with substitution or simultaneously with any step. The step (1) can be performed alone or simultaneously with each step as long as it is between the steps (a) to (e), but considering the total CIP time, simultaneously with any of the steps (a) to (e) Preferably it is done. In order to further improve the deodorizing property, it is preferable to perform the step (2) and the step (3), and the step (2) is performed before any of the above steps (a) to (d) and It can be carried out after, or after, or replaced with any step or simultaneously with any step. Moreover, this process (3) should just be after the said process (2), and may interpose another process immediately after a process (2). Note that a plurality of steps (1) to (3) may be performed.

In the examples, “%” and “parts” are respectively “% by weight” and “parts by weight” unless otherwise specified.
Example 1
A cleaning composition for CIP was prepared with the composition shown in Table 1. Using them, the deodorizing property and the base odor were tested by the following method. The results are shown in Table 1. As comparative product 1-1, the result of performing the cleaning steps (a) to (e) described later without using the cleaning medium (I) is shown.

(1) Test object An EPDM (ethylene / propylene / diene / rubber) sheet (Osaka Sanitary Metal Industry Cooperative) made of the same material as the packing was cut into 5 cm × 0.5 cm (thickness 2 mm) to obtain a test piece. A test sample was obtained by immersing the test piece in a commercial beverage (peach natural water: manufactured by JT) at 70 ° C. for 2 hours.

(2) Test method When the composition shown in Table 1 (cleaning medium (I): 2.0 g in terms of effective component) is put into a 100 cc screw tube and then used in step (a) or step (c). Prepare water with a total amount of 100 g each by adding a predetermined amount of NaOH and water when used in step (b) and a predetermined amount of HNO ₃ and water when using in step (d). Keep it. The contents in the screw tube were stirred at 80 ° C. with a magnetic stirrer.

In the case of using the composition in the step (a), one test piece was put into a screw tube containing a diluent containing the composition prepared above, and the following steps were performed. Moreover, when using a composition at a process (b), the screw pipe | tube which put the diluted liquid containing the composition prepared above and NaOH for one to-be-tested body which finished the process (a) by the hot water washing 1 The following steps were performed. When using a composition in the step (c), a diluted solution containing the composition prepared above is prepared for one specimen to be tested after the step (a) by hot water washing 1 and the step (b) by alkali washing. The following process was performed by putting in the screw tube. When using the composition in the step (d), one test object after the step (a) by the hot water washing 1, the step (b) by the alkaline washing, and the step (c) by the hot water washing 2 is as described above. The following steps were performed by feeding the prepared composition and a screw tube containing a diluent containing HNO ₃ . One test piece after a series of washing steps is dipped for 30 seconds in a 100 cc screw tube containing 50 g of ion exchange water at 80 ° C. and then pulled up. This water was used as a sample for evaluation.

(Washing process)
(A) Hot water washing 1: 80 ° C., 20 minutes immersion stirring (b) Alkaline cleaning: 2% NaOH aqueous solution, 80 ° C., 20 minutes immersion stirring (c) Hot water washing 2: 80 ° C., 20 minutes immersion stirring (d) Acid Cleaning: 0.6% HNO ₃ aqueous solution, 20 minutes immersion stirring (e) Hot water washing 3: 80 ° C., 20 minutes immersion stirring

(3) Evaluation method Five-stage evaluation was performed about the flavor odor and base odor of the test piece by six panelists. It can be said that the smaller the score, the better the deodorizing effect. The average value of the evaluation points by the six panelists was evaluated as “odor residual”. Judgment criteria are as follows.

(Evaluation points and criteria)
5: Strong smell 4: Strong smell 3: Slight smell 2: Slight smell 1: No smell

* 1 Octyl stearate: manufactured by Kao Corporation, Exepal EH-S, solubility (water, 25 ° C) 1 wt% or less, number of ester groups, melting point 25 ° C or less * 2 octyldodecyl myristate: Kao Corporation ), Exepearl OD-M, Solubility (to water, 25 ° C) 1 wt% or less, Number of ester groups, melting point 25 ° C or less * 3 Rapeseed oil: Reagent, Solubility (to water, 25 ° C) 1 wt% or less , Number of ester groups of triglyceride, the main component, melting point 25 ° C. or lower * 4 Soybean oil: Reagent, solubility (with water, 25 ° C.) 1 wt% or less, Number of ester groups of triglyceride, the main component, melting point 25 ° C. or lower * 5 Triacetin: manufactured by Cognis Co., Ltd., Edenoa GTA, solubility (with water, 25 ° C.) 7% by weight, number of ester groups 3, melting point 25 ° C. or lower * 6 Nonionic surfactant A: polyoxyethylene Al Triethanolamine [Kao Co., Ltd., AMIET 308]
* 7 Nonionic surfactant B: alkylpolyglucoside [manufactured by Kao Corporation, Mydol 12]
* 8 Nonionic surfactant C: alkyl glyceryl ether [manufactured by Kao Corporation, 2-ethylhexyl glyceryl ether]
* 9 Anionic surfactant A: sodium dialkylsulfosuccinate (manufactured by Kao Corporation, PELEX OT-P)
* 10 Cationic Surfactant A: Lauryltrimethylammonium chloride [manufactured by Kao Corporation, Coatamine 24P]
* 11 Amphoteric surfactant A: lauryl betaine [manufactured by Kao Corporation, Amphitol 24B]

Example 2
With the composition shown in Table 2, a composition 2 for the washing step (2) and a composition 3 for the washing step (3) were prepared. Using them in any of the following washing steps (a) to (d), deodorizing properties and base odor were tested by the following methods. At that time, in each step, the contents in the screw tube were stirred at 80 ° C. with a magnetic stirrer. The results are shown in Table 2. The components in Table 2 are the same as those in Example 1. As Comparative Method 2-1, the results of performing the cleaning steps (a) to (e) described below without using the cleaning medium (II) and the cleaning medium (III) are shown.

(Washing process)
(A) Hot water washing 1: 80 ° C., 20 minutes immersion stirring (b) Alkaline cleaning: 2% NaOH aqueous solution, 80 ° C., 20 minutes immersion stirring (c) Hot water washing 2: 80 ° C., 20 minutes immersion stirring (d) Acid Cleaning: 0.6% HNO ₃ aqueous solution, 20 minutes immersion stirring (e) Hot water washing 3: 80 ° C., 20 minutes immersion stirring

(1) Device to be tested A sample to be tested was prepared in the same manner as in Example 1.

(2) Test method After putting composition 2 of Table 2 (cleaning medium (II): 2.0 g in terms of effective amount) into a 100 cc screw tube, it is used in step (a) or step (c). In this case, water is used, and when used in step (b), a predetermined amount of NaOH and water are added to prepare a total of 100 g. The contents in the screw tube were stirred at 80 ° C. with a magnetic stirrer.

  When using the composition 2 in the step (a), one test piece was put into a screw tube containing a diluent containing the composition 2 prepared above, and the following steps were performed. Moreover, when using the composition 2 by the process (b), the diluted solution containing the composition 2 prepared above and NaOH was put into one to-be-tested body which finished the process (a) by the hot water washing 1. The following process was performed by putting in the screw tube. In the case of using the composition 2 in the step (c), a test piece that has finished the step (a) by the hot water washing 1 and the step (b) by the alkali washing is diluted with the composition 2 prepared above. It poured into the screw tube which put the liquid, and the following processes were performed.

Next, after putting the composition 3 of Table 2 (cleaning medium (III): 3.0 g in terms of effective amount) into a 100 cc screw tube, and using it in step (b), a predetermined amount of NaOH and When water is used in step (c), water is added, and when used in step (d), a predetermined amount of HNO ₃ and water are added to prepare a total of 100 g. The contents in the screw tube were stirred at 80 ° C. with a magnetic stirrer.

When using the composition 3 in the step (b), a screw tube containing the composition 3 prepared above and a diluted solution containing NaOH is used for one specimen to be tested after the step (a) by the hot water washing 1. The following steps were performed. In the case of using the composition 3 in the step (c), one test object which has finished the step (a) by the hot water washing 1 and the step (b) by the alkali washing is diluted with the composition 3 prepared above. It poured into the screw tube which put the liquid, and the following processes were performed. Also, when using the composition 3 in step (d), step (a) ~ Step a single test object having been subjected to (c), diluted solution containing a composition 3 and HNO ₃ prepared above The following process was carried out. One test piece after a series of washing steps is dipped for 30 seconds in a 100 cc screw tube containing 50 g of ion exchange water at 80 ° C. and then pulled up. This water was used as a sample for evaluation.

(3) Evaluation method The same evaluation method and standard as in Example 1 were used.

Claims (6)

A cleaning composition for CIP containing one or more ester compounds (A) represented by the following general formulas (1) to (4) and water.

[In the formula, R ^{11 to} R ¹⁶ may be the same or different, each having an alkyl group having 1 to 30 carbon atoms, an alkyl group having 1 to 30 carbon atoms substituted with a hydroxyl group, or 2 to 30 carbon atoms. An alkenyl group, an aryl group having 6 to 30 carbon atoms, an arylalkyl group having 7 to 30 carbon atoms, or an alkylaryl group having 7 to 30 carbon atoms is represented. R ¹⁷ represents an alkylene group having 1 to 20 carbon atoms or an alkenylene group having 2 to 20 carbon atoms. R ²¹ , R ²⁴ , and R ²⁵ may be the same or different, each having an alkyl group having 1 to 24 carbon atoms, an alkyl group having 2 to 24 carbon atoms substituted with a hydroxyl group, or an alkenyl having 2 to 24 carbon atoms. Group, an aryl group having 6 to 24 carbon atoms, an arylalkyl group having 7 to 24 carbon atoms, or an alkylaryl group having 7 to 24 carbon atoms. R ²² is an alkylene group having 2 to 24 carbon atoms, an alkenylene group having 2 to 24 carbon atoms, an arylene group having 6 to 24 carbon atoms, an arylene alkylene group having 7 to 24 carbon atoms, or an alkylarylene group having 7 to 24 carbon atoms. Represents. R ²³ represents a group obtained by removing a hydroxyl group from a trivalent alcohol having 3 to 24 carbon atoms. ] The CIP cleaning composition according to claim 1, wherein the solubility of the compound (A) in water at 25 ° C is 10% by weight or less. Furthermore, the detergent composition for CIP of Claim 1 or 2 containing surfactant (B). The CIP cleaning according to any one of claims 1 to 3, wherein the surfactant (B) is at least one nonionic surfactant selected from alkyl polyglycosides, alkyl glyceryl ethers, and polyoxyalkylene alkyl amines. Agent. A CIP cleaning method comprising a step (1) of bringing a cleaning medium (I) containing the compound (A) according to claim 1, a surfactant (B) and water into contact with an object to be cleaned. A step (2) of bringing the cleaning medium (II) containing the compound (A) and water according to claim 1 into contact with an object to be cleaned, and a cleaning medium (III) containing a surfactant (B) and water A CIP cleaning method including a step (3) performed after the previous step (2), which is brought into contact with a cleaning object.