CN107619725A - A kind of low alveolitoid liquid detergent and preparation method thereof - Google Patents
A kind of low alveolitoid liquid detergent and preparation method thereof Download PDFInfo
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- CN107619725A CN107619725A CN201710339810.3A CN201710339810A CN107619725A CN 107619725 A CN107619725 A CN 107619725A CN 201710339810 A CN201710339810 A CN 201710339810A CN 107619725 A CN107619725 A CN 107619725A
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- liquid detergent
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- low alveolitoid
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- foam
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Abstract
The invention discloses a kind of low alveolitoid liquid detergent and preparation method thereof.By the formula of liquid detergent, deionized water is added in stirred tank, and first foam in hibitors is dissolved in deionized water, is heated to 45 DEG C and is stirred；APG, sodium sulfate of polyethenoxy ether of fatty alcohol, fatty diglycollic amide are added while stirring, and adjusts pH value to 7.0 7.5 with citric acid or sodium hydrate aqueous solution, add water constant volume；Treat that solution is down to room temperature, add sodium chloride and adjust viscosity to 200 400mPa.s, continuously add preservative and essence, stir and produce product.Caused foam is appropriate in cleaning process of the present invention, saving water resource, beneficial to energy-saving and emission-reduction and green.
Description
【Technical field】
The present invention relates to liquid detergent production technical field, more particularly to a kind of low alveolitoid liquid detergent and preparation method thereof.
【Background technology】
Liquid detergent is daily life articles for use, is mainly used in washing tableware, tea set and kitchen tools etc.；It can be used for washing
Wash the clothing of water fruits and vegetables and greasy dirt weight.Surfactant is the main component of liquid detergent cleaning greasy dirt, passes through surfactant
Soak, disperse, greasy dirt is taken away surface to be cleaned by parcel ability.Caused foam is due to surfactant in cleaning process
Foam stabilizing effect caused by, appropriate foam has certain advantageous effects to decontamination, but excessive foam can give cleaning process
Unnecessary trouble is brought, especially during Machine automated cleaning tableware, cleaning inconvenience is not only caused, can also waste
Water resource, it is unfavorable for energy-saving and emission-reduction and green.Therefore, low alveolitoid liquid detergent is in the higher and higher current society of automaticity
It can will have the very big market space.
【The content of the invention】
It is a primary object of the present invention to provide a kind of low alveolitoid liquid detergent and preparation method thereof, can solve the above and ask
Topic.
To achieve the above object, the technical scheme taken of the present invention is：
A kind of low alveolitoid liquid detergent, its scheme are as follows：
The present invention is made by following component and proportioning：
Subscript g is 1~6 integer in foam controller R [(EO) m (PO) nH] g；EO is oxirane, and PO is ring
Ethylene Oxide；R is the reaction residue of polyether initiator, and initiator is C1~C10 straight or branched alkyl alcohol；M, n is the degree of polymerization,
M is 1~100 integer, and n is 0~80 integer.
Preferably, the surfactant：Mixture, specially aliphatic alcohol polyethenoxy are compounded for nonionic and anion
Ether sodium sulfate, fatty diglycollic amide, the mixture of APG (alkyl chain containing C8~10).
Preferably, the pH adjusting agent：PH value is adjusted with the citric acid of food additives.
Preferably, the preservative：For one of methyl p-hydroxybenzoate, propylparaben, phenylic acid sodium or
Its mixture.
Preferably, the viscosity modifier：With sodium chloride, regulation viscosity to 200-400mPa.s.
Preferably, the essence is essence commonly used in the art, including natural petit grain oil elite, sponge gourd essential oil, lemon
Essential oil, ginger essence oil.
Preferably, subscript g is 1~4 integer in foam controller R [(EO) m (PO) nH] g, and m is the whole of 1-40
Number, n are 0-60 integer.
Preferably, in foam controller R [(EO) m (PO) nH] g R initiator be ethylene glycol, propane diols, the third three
Any of alcohol, glycerine trimethylolpropane, pentaerythrite.
A kind of low alveolitoid liquid detergent preparation method, by the formula of liquid detergent, deionized water is added in stirred tank, first will bubble
Foam inhibitor is dissolved in deionized water, is heated to 45 DEG C and is stirred；APG, fatty alcohol polyoxy second are added while stirring
Alkene ether sodium sulfate, fatty diglycollic amide, and pH value is adjusted to 7.0-7.5 with citric acid or sodium hydrate aqueous solution, then add
Water constant volume；Treat that solution is down to room temperature, addition sodium chloride regulation viscosity to 200-400mPa.s, continuously add preservative and essence,
Stir and produce product.
Compared with prior art, the present invention has the advantages that：Caused foam is appropriate in cleaning process of the present invention,
Saving water resource, beneficial to energy-saving and emission-reduction and green.
【Embodiment】
To be easy to understand the technical means, the inventive features, the objects and the advantages of the present invention, with reference to
Embodiment, the present invention is expanded on further.
Embodiment 1
By said ratio, deionized water is added in stirred tank, first foam in hibitors is dissolved in deionized water, is added
Hot to 45 DEG C stir；APG, sodium sulfate of polyethenoxy ether of fatty alcohol, aliphatic acid diethanol acyl are added while stirring
Amine, and pH value is adjusted to 7.0-7.5 with citric acid or sodium hydrate aqueous solution, add water constant volume；Treat that solution is down to room temperature, add
Sodium chloride adjusts viscosity to 200-400mPa.s, continuously adds preservative and essence, stirs and produce product.
Embodiment 2
By said ratio, deionized water is added in stirred tank, first foam in hibitors is dissolved in deionized water, is added
Hot to 45 DEG C stir；APG, sodium sulfate of polyethenoxy ether of fatty alcohol, aliphatic acid diethanol acyl are added while stirring
Amine, and pH value is adjusted to 7.0-7.5 with citric acid or sodium hydrate aqueous solution, add water constant volume；Treat that solution is down to room temperature, add
Sodium chloride adjusts viscosity to 200-400mPa.s, continuously adds preservative and essence, stirs and produce product.
Embodiment 3
By said ratio, deionized water is added in stirred tank, first foam in hibitors is dissolved in deionized water, is added
Hot to 45 DEG C stir；APG, sodium sulfate of polyethenoxy ether of fatty alcohol, aliphatic acid diethanol acyl are added while stirring
Amine, and pH value is adjusted to 7.0-7.5 with citric acid or sodium hydrate aqueous solution, add water constant volume；Treat that solution is down to room temperature, add
Sodium chloride adjusts viscosity to 200-400mPa.s, continuously adds preservative and essence, stirs and produce product.
Surfactant described above：Mixture, specially AEO are compounded for nonionic and anion
Sodium sulphate, fatty diglycollic amide, the mixture of APG (alkyl chain containing C8~10).
The APG contains the alkyl chain of C8~10, and APG is a new generation using renewable natural material, property
Can it is gentle, safe and non-toxic, with skin-friendliness it is good, can quick and complete biodegradable " green " type non-ionic surface active
Agent, have the characteristic of conventional nonionic and anion surfactant concurrently, there is good dirt-removing power, no cloud point, show without gel
As, can with any kind of surfactant Synergistic, and with preferably thickening and stabilising system performance, be especially suitable for
Applied to liquid dishwashing detergent.
Foam controller：R [(EO) m (PO) nH] g, wherein：Subscript g be 1~6 integer, preferably 1~4 integer；EO is
Oxirane, PO are expoxy propane；R is the reaction residue of polyether initiator, and initiator is C1~C10 straight or branched alkyl
Any of alcohol, preferably ethylene glycol, propane diols, glycerine, glycerine trimethylolpropane, pentaerythrite；M, n is the degree of polymerization, m
For 1~100 integer, preferably 1~40 integer, n is 0~80 integer, preferably 0-60 integers.
The foam controller has certain foam control action, while has certain cleansing power, can be used for low
In the actual production of alveolitoid liquid detergent.
PH adjusting agent：It is used as the citric acids of food additives to adjust pH value, therefore can avoids bringing price with sulfonic acid
Height, the defects of biological degradability difference, while with the piece alkali in citric acid and in raw material, make product in neutrality, and citric acid with
Caused sodium citrate after piece alkali neutralizes, can substitute the disodium ethylene diamine tetraacetate that valency is high in existing formula, i.e. EDTA, there is softening
The effect of the heavy metal ion such as calcium, magnesium.
Preservative：For one of methyl p-hydroxybenzoate, propylparaben, phenylic acid sodium or its mixture.
Viscosity modifier：With sodium chloride, regulation viscosity to 200-400mPa.s.
Essence：The essence can be essence commonly used in the art, such as natural petit grain oil elite, sponge gourd essential oil, lemon
Lemon essential oil, ginger essence oil etc..
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (9)
- A kind of 1. low alveolitoid liquid detergent, it is characterised in that：The present invention is made by following component and proportioning：Subscript g is 1~6 integer in foam controller R [(EO) m (PO) nH] g；EO is oxirane, and PO is epoxy third Alkane；R is the reaction residue of polyether initiator, and initiator is C1~C10 straight or branched alkyl alcohol；M, n is the degree of polymerization, m 1 ~100 integer, n are 0~80 integer.
- 2. low alveolitoid liquid detergent according to claim 1, it is characterised in that：The surfactant be nonionic and it is cloudy from The mixture of son compounding mixture, specially sodium sulfate of polyethenoxy ether of fatty alcohol, fatty diglycollic amide, APG.
- 3. low alveolitoid liquid detergent according to claim 1, it is characterised in that：The pH adjusting agent：Used with food additives Citric acid adjust pH value.
- 4. low alveolitoid liquid detergent according to claim 1, it is characterised in that：The preservative：For P-hydroxybenzoic acid first One of ester, propylparaben, phenylic acid sodium or its mixture.
- 5. low alveolitoid liquid detergent according to claim 1, it is characterised in that：The viscosity modifier：With sodium chloride, regulation Viscosity is to 200-400mPa.s.
- 6. low alveolitoid liquid detergent according to claim 1, it is characterised in that：The essence is essence commonly used in the art, Including natural petit grain oil elite, sponge gourd essential oil, lemonene essential oil, ginger essence oil.
- 7. low alveolitoid liquid detergent according to claim 1, it is characterised in that：The foam controller R [(EO) m (PO) nH] Subscript g is 1~4 integer in g, and m is 1-40 integer, and n is 0-60 integer.
- 8. low alveolitoid liquid detergent according to claim 1, it is characterised in that：The foam controller R [(EO) m (PO) nH] R initiator is any of ethylene glycol, propane diols, glycerine, glycerine trimethylolpropane, pentaerythrite in g.
- 9. a kind of low alveolitoid liquid detergent preparation method, it is characterised in that by the formula of liquid detergent, deionized water is added to stirred tank In, first foam in hibitors is dissolved in deionized water, 45 DEG C is heated to and stirs；APG, fat are added while stirring Fat alcohol polyethenoxy ether sodium sulfate, fatty diglycollic amide, and adjust pH value extremely with citric acid or sodium hydrate aqueous solution 7.0-7.5 add water constant volume；Treat that solution is down to room temperature, add sodium chloride and adjust viscosity to 200-400mPa.s, continuously add anti- Rotten agent and essence, stir and produce product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710339810.3A CN107619725A (en) | 2017-05-15 | 2017-05-15 | A kind of low alveolitoid liquid detergent and preparation method thereof |
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| CN201710339810.3A CN107619725A (en) | 2017-05-15 | 2017-05-15 | A kind of low alveolitoid liquid detergent and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108624429A (en) * | 2018-06-19 | 2018-10-09 | 浙江永金生物科技有限公司 | A kind of hyperconcetration green low foam laundry liquid and preparation method thereof |
| CN112481044A (en) * | 2019-09-12 | 2021-03-12 | 焦文贺 | Laundry detergent and preparation method thereof |
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| CN1121952A (en) * | 1994-03-23 | 1996-05-08 | 安卫公司 | High actives cleaning compositions and methods of use |
| CN1560211A (en) * | 2004-03-08 | 2005-01-05 | 浙江大学 | Cleaning agent for automatic cleaning machine of tableware |
| CN1756580A (en) * | 2003-03-03 | 2006-04-05 | 考格尼斯性能化学制品英国有限公司 | Foam control agent |
| CN101760346A (en) * | 2009-12-17 | 2010-06-30 | 陈政 | Multi-component concentrated dish cleanser |
| CN103060114A (en) * | 2013-01-07 | 2013-04-24 | 洛娃科技实业集团有限公司 | Detergent with quick-drying effect |
| CN103540436A (en) * | 2013-09-27 | 2014-01-29 | 安徽华印机电股份有限公司 | Pesticide residue removing liquid detergent |
-
2017
- 2017-05-15 CN CN201710339810.3A patent/CN107619725A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1121952A (en) * | 1994-03-23 | 1996-05-08 | 安卫公司 | High actives cleaning compositions and methods of use |
| CN1756580A (en) * | 2003-03-03 | 2006-04-05 | 考格尼斯性能化学制品英国有限公司 | Foam control agent |
| CN1560211A (en) * | 2004-03-08 | 2005-01-05 | 浙江大学 | Cleaning agent for automatic cleaning machine of tableware |
| CN101760346A (en) * | 2009-12-17 | 2010-06-30 | 陈政 | Multi-component concentrated dish cleanser |
| CN103060114A (en) * | 2013-01-07 | 2013-04-24 | 洛娃科技实业集团有限公司 | Detergent with quick-drying effect |
| CN103540436A (en) * | 2013-09-27 | 2014-01-29 | 安徽华印机电股份有限公司 | Pesticide residue removing liquid detergent |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108624429A (en) * | 2018-06-19 | 2018-10-09 | 浙江永金生物科技有限公司 | A kind of hyperconcetration green low foam laundry liquid and preparation method thereof |
| CN112481044A (en) * | 2019-09-12 | 2021-03-12 | 焦文贺 | Laundry detergent and preparation method thereof |
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Address after: 230000 Peach Blossom Industrial Park, Jingkai District, Hefei City, Anhui Province Applicant after: Anhui Pu Qing Environmental Protection Technology Co., Ltd. Address before: 230000 Peach Blossom Industrial Park, Jingkai District, Hefei City, Anhui Province Applicant before: Hefei Puqing Daily Chemical Co. |
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Application publication date: 20180123 |