CN106367223B - A kind of foam type kitchen duplicate removal finish and preparation method thereof - Google Patents

A kind of foam type kitchen duplicate removal finish and preparation method thereof Download PDF

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Publication number
CN106367223B
CN106367223B CN201610772784.9A CN201610772784A CN106367223B CN 106367223 B CN106367223 B CN 106367223B CN 201610772784 A CN201610772784 A CN 201610772784A CN 106367223 B CN106367223 B CN 106367223B
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duplicate removal
sodium
removal finish
foam type
type kitchen
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CN106367223A (en
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郭伊妮
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One Tian (Guangzhou) living health products Co., Ltd.
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One Tian (guangzhou) Living Health Products Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/06—Phosphates, including polyphosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/32—Amides; Substituted amides
    • C11D3/323—Amides; Substituted amides urea or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/3481—Organic compounds containing sulfur containing sulfur in a heterocyclic ring, e.g. sultones or sulfolanes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008—Polymeric surface-active agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
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  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention belongs to cleaning agent technical field, and in particular to a kind of foam type kitchen duplicate removal finish and preparation method thereof.Described foam type kitchen duplicate removal finish is made up of following preparing raw material：Sodium hydroxide, sodium carbonate, polyoxyethylene alkyl ether sulfate sodium, linear alkyl benzene sulfonic acid, triethanolamine, nine hydrated sodium metasilicates, AEO, phosphate, essence, pH adjusting agent, preservative, surplus are deionized water.Duplicate removal finish property in foam type kitchen of the present invention is gentle, and safe to the human body nontoxic, cleaning process does not stimulate skin, and dirt-removing power is stronger, rapid, easy can remove grease, while corrosivity is low, does not damage kitchen appliance.

Description

A kind of foam type kitchen duplicate removal finish and preparation method thereof
Technical field
The present invention relates to cleaning agent technical field, and in particular to a kind of foam type kitchen duplicate removal finish and preparation method thereof.
Background technology
The problem of removal of kitchen grease is always housewife's worry, its formed not only influence kitchen environment cleaning with Health, also it is unfavorable for the health of people, the grease especially on kitchen tools, is directly contacted with food, it is easier to cause food hygiene Problem.The formation of kitchen grease is mainly edible oil drippage or heated portion evaporation and polluted on apparatus, plus dust, and food With unrighted acid oxidative aggregation in oil, accumulating over a long period, it is extremely strong to form one layer of sticky adhesive force, it is difficult to the dirt of removal.
At present, people are broadly divided into three classes for removing the cleaning agent of kitchen grease：1) strong base cleaning agent, the cleaning agent Counterweight dirt removal ability is strong, but corrosivity is strong, larger corrosivity and injury be present to the skin of tool face and user.2) Leaning solvent, the active ingredient of the cleaning agent is various organic solvents, has good dissolution to grease and makes oil Dirt removes, but because organic solvent is inflammable, it is explosive and poisonous, it is poorly suitable in kitchen environment.3) surfactant type is cleaned Agent, the cleaning agent is easy to use, action temperature and, cost is low, but counterweight dirt removal effect it is poor.Therefore, efficient, safety, ring The development of the kitchen duplicate removal finish of guarantor has larger application value and development prospect.
Chinese patent application 20110456699.9 discloses a kind of non-corrosive heavy oil stain remover and its preparation side Method.Contain sodium sulfate of polyethenoxy ether of fatty alcohol, aliphatic alcohol polyethenoxy (7) ether, APG, poly- in the heavy oil stain remover PAA, 2- methyl -2,4- pentanediol, sodium hydroxide, potassium hydroxide, sodium metasilicate, MEA, essence, deionized water. The heavy oil stain remover that the invention provides is strong to heavy oil stain dirt-removing power, environmentally friendly, to metal, plastics, glass during use It is corrosion-free Deng material.
The content of the invention
To solve the problems, such as that prior art is present, it is an object of the invention to provide a kind of foam type kitchen duplicate removal finish and Its preparation method, described duplicate removal finish property is gentle, safe to the human body nontoxic, and cleaning process does not stimulate skin, and decontamination energy Power is stronger, rapid, easy can remove grease, while corrosivity is low, does not damage kitchen appliance.
The present invention is by following technical solution to realize above-mentioned purpose：
A kind of foam type kitchen duplicate removal finish provided by the invention, is made up of the preparing raw material of following percentage by weight meter： Sodium hydroxide 0.5~3.0%, sodium carbonate 0.5~2.0%, polyoxyethylene alkyl ether sulfate sodium 0.5~3.0%, straight chain alkane Base benzene sulfonic acid 0.5~3.0%, triethanolamine 2.5~3.0%, nine hydrated sodium metasilicates 0.5~3.0%, aliphatic alcohol polyethenoxy Ether 2.0~3.0%, phosphate 0.1~5.0%, essence 0.1~1.0%, pH adjusting agent 0.1~3.0%, preservative 0.1~ 0.5%, surplus is deionized water.
Preferably, described duplicate removal finish is made up of the preparing raw material of following percentage by weight meter：Sodium hydroxide 1.5%, Sodium carbonate 1.5%, polyoxyethylene alkyl ether sulfate sodium 2.0%, linear alkyl benzene sulfonic acid 1.8%, triethanolamine 2.5%, Nine hydrated sodium metasilicates 1.5%, AEO 2.0%, phosphate 0.8%, essence 0.4%, pH adjusting agent 1.0%th, preservative 0.3%, surplus are deionized water.
Further, described linear alkyl benzene sulfonic acid is C10-C13At least one of alkyl benzene sulphonate, as ten alkane At least one of base benzene sulfonic acid, DBSA or tridecyl benzene sulfonic acid.
Preferably, described linear alkyl benzene sulfonic acid is DBSA.
Further, described AEO is aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) at least one of ether and aliphatic alcohol polyethenoxy (10) ether.
In addition, the present invention also provides a kind of preparation method of described foam type kitchen duplicate removal finish, it includes following step Suddenly：
(1) polyoxyethylene alkyl ether sulfate sodium, linear alkyl benzene sulfonic acid, AEO are added to In ionized water, stir to system into homogeneous transparent liquid；
(2) sodium hydroxide, sodium carbonate, triethanolamine, nine hydrated sodium metasilicates, phosphate are added while stirring, until thing Material is completely dissolved；
(3) pH adjusting agent regulation pH to 10.5-11.5 is added, essence, preservative is added, stirs.
PH adjusting agent of the present invention is organic acid or inorganic acid commonly used in the art, such as citric acid, acetic acid or hydrochloric acid Deng.
Preservative of the present invention is reagent commonly used in the art, such as dimethyl OIT, imidazolidinyl urea, two Methylol dimethyl hydantion, Phenoxyethanol, iodine propilolic alcohol butyl mephenesin Carbamate or DMDMH etc..
Phosphate of the present invention is reagent commonly used in the art, such as sodium tripolyphosphate, sodium pyrophosphate, sodium tetrapolyphosphate Or polymetaphosphate sodium etc..
In above-mentioned technical scheme, polyoxyethylene alkyl ether sulfate sodium is anionic surfactant, fatty alcohol APEO is nonionic surface active agent, and both of which has infiltration well, emulsification and dirt-removing power, but poly alkyl alcohol The foaming characteristic of oxygen vinethene is weaker, and foam stability is poor, is compounded with polyoxyethylene alkyl ether sulfate sodium, can overcome this defect. When both are with 1:1 ratio carry out compounding can produce stably and enrich foam, decontamination it is better, dirt and water can be reduced Surface tension between phase, stain is gradually removed from surface by aggregation, emulsification or dissolution, and dirt can be kept In suspended state, soil redeposition is prevented on the surface, beneficial to removing dirt.
Sodium Hydroxide Alkaline is most strong, and sodium carbonate takes second place, and both of which can dissolve and degrease well, weaker with alkalescence Triethanolamine, nine hydrated sodium metasilicates compounding, can adjust the alkalescence of degreasing system, improve detergency, reduce the thorn to skin Swash property and reduce corrosivity.
Linear alkyl benzene sulfonic acid is organic monoacid, can be similar with the sodium hydroxide in system, sodium carbonate, triethanolamine generation The effect of saponification, sodium n-alkylbenzenesulfonate and linear alkyl benzene sulfonic acid triethanolamine are formed, further regulation system Alkalescence, reduce the excitant to skin and reduce corrosivity, and produce the excellent infiltration of anionic surfactant, emulsification and Dirt-removing power, strengthen Scavenging activity of the system to grease.
Phosphate has metal ion network and effect, can be formed water-soluble with causing the polyvalent metal ion of the water hardness to chelate Property complex compound, avoid these metal ions and anionic surfactant from acting on forming insoluble dirt deposition in washings table Face, beneficial to removing grease.
Compared with prior art, advantage of the invention is that：
(1) duplicate removal finish in kitchen provided by the invention is aided with and added using surfactant, alkaline matter as principle active component Add organic monoacid and inorganic salts, each component is mutually coordinated, mutual gain, has efficient greasy dirt cleaning force, can be rapid, easy to be clear Remove grease, preferable to the elimination effect of heavy oil stain, clearance rate can reach 90%.
(2) duplicate removal finish in kitchen provided by the invention has excellent foam performance and adhesive force, is advantageous to improve decontamination Ability.
(3) duplicate removal finish property in kitchen provided by the invention is gentle, and safe to the human body nontoxic, cleaning process does not stimulate skin Skin, while corrosivity is low, does not damage kitchen appliance.
Embodiment
The present invention is further described below by way of embodiment, but the present invention is not limited only to following examples.
Embodiment 1
The foam type kitchen duplicate removal finish of the embodiment of the present invention 1, is made up of the preparing raw material of following percentage by weight meter：
Sodium hydroxide 1.5%, sodium carbonate 1.5%, polyoxyethylene alkyl ether sulfate sodium 2.0%, detergent alkylate sulphur Acid 1.8%, triethanolamine 2.5%, nine hydrated sodium metasilicates 1.5%, aliphatic alcohol polyethenoxy (7) ether 2.0%, sodium tripolyphosphate 0.8%th, essence 0.4%, citric acid 1.0%, dimethyl OIT 0.3%, surplus are deionized water.
Preparation method：
(1) polyoxyethylene alkyl ether sulfate sodium, DBSA, aliphatic alcohol polyethenoxy (7) ether are added Into deionized water, stir to system into homogeneous transparent liquid；
(2) sodium hydroxide, sodium carbonate, triethanolamine, nine hydrated sodium metasilicates, sodium tripolyphosphate are added while stirring, directly It is completely dissolved to material；
(3) lemon acid for adjusting pH is added to 10.5, is added essence, dimethyl OIT, is stirred.
Embodiment 2
The foam type kitchen duplicate removal finish of the embodiment of the present invention 2, is made up of the preparing raw material of following percentage by weight meter：
Sodium hydroxide 3.0%, sodium carbonate 0.5%, polyoxyethylene alkyl ether sulfate sodium 3.0%, detergent alkylate sulphur Acid 3.0%, triethanolamine 3.0%, nine hydrated sodium metasilicates 3.0%, aliphatic alcohol polyethenoxy (7) ether 3.0%, sodium tripolyphosphate 2%th, essence 0.1%, citric acid 3%, dimethyl OIT 0.1%, surplus are deionized water.
Preparation method reference implementation example 1.
Embodiment 3
The foam type kitchen duplicate removal finish of the embodiment of the present invention 3, is made up of the preparing raw material of following percentage by weight meter：
Sodium hydroxide 0.5%, sodium carbonate 2.0%, polyoxyethylene alkyl ether sulfate sodium 0.5%, detergent alkylate sulphur Acid 0.5%, triethanolamine 3.0%, nine hydrated sodium metasilicates 0.5%, aliphatic alcohol polyethenoxy (7) ether 3.0%, sodium tripolyphosphate 5.0%th, essence 0.5%, citric acid 0.4%, dimethyl OIT 0.3%, surplus are deionized water.
Preparation method reference implementation example 1.
Embodiment 4
The foam type kitchen duplicate removal finish of the embodiment of the present invention 4, is made up of the preparing raw material of following percentage by weight meter：
Sodium hydroxide 1.5%, sodium carbonate 1.5%, polyoxyethylene alkyl ether sulfate sodium 2.0%, ten alkyl benzene sulphonates 1.8%th, triethanolamine 2.5%, nine hydrated sodium metasilicates 1.5%, aliphatic alcohol polyethenoxy (9) ether 2.0%, sodium pyrophosphate 0.8%th, essence 0.4%, citric acid 1.0%, Phenoxyethanol 0.3%, surplus are deionized water.
Preparation method reference implementation example 1.
Embodiment 5
The foam type kitchen duplicate removal finish of the embodiment of the present invention 5, is made up of the preparing raw material of following percentage by weight meter：
Sodium hydroxide 1.5%, sodium carbonate 1.5%, polyoxyethylene alkyl ether sulfate sodium 2.0%, tridane sulphur Acid 1.8%, triethanolamine 2.5%, nine hydrated sodium metasilicates 1.5%, aliphatic alcohol polyethenoxy (10) ether 2.0%, four polyphosphoric acids Sodium 0.8%, essence 0.4%, citric acid 1.0%, dimethyloldimethylhydantoin 0.3%, surplus are deionized water.
Preparation method reference implementation example 1.
Comparative example 1
The foam type kitchen duplicate removal finish of comparative example 1 of the present invention, is made up of the preparing raw material of following percentage by weight meter：
Sodium hydroxide 1.5%, sodium carbonate 1.5%, polyoxyethylene alkyl ether sulfate sodium 2.0%, triethanolamine 2.5%th, nine hydrated sodium metasilicates 1.5%, aliphatic alcohol polyethenoxy (7) ether 2.0%, sodium tripolyphosphate 0.8%, essence 0.4%, Citric acid 1.0%, dimethyl OIT 0.3%, surplus are deionized water.
The formula composition of this comparative example foam type kitchen duplicate removal finish is substantially the same manner as Example 1, and difference is, does not add DBSA.
Preparation method reference implementation example 1.
Comparative example 2
The foam type kitchen duplicate removal finish of comparative example 2 of the present invention, is made up of the preparing raw material of following percentage by weight meter：
Sodium hydroxide 1.5%, sodium carbonate 1.5%, DBSA 1.8%, the hydration of triethanolamine 2.5%, nine are inclined Sodium metasilicate 1.5%, aliphatic alcohol polyethenoxy (7) ether 2.0%, sodium tripolyphosphate 0.8%, essence 0.4%, citric acid 1.0%, two Methylisothiazolinone 0.3%, surplus are deionized water.
The formula composition of this comparative example foam type kitchen duplicate removal finish is substantially the same manner as Example 1, and difference is, does not add Polyoxyethylene alkyl ether sulfate sodium.
Comparative example 3
The foam type kitchen duplicate removal finish of comparative example 3 of the present invention, is made up of the preparing raw material of following percentage by weight meter：
Sodium hydroxide 1.5%, sodium carbonate 1.5%, polyoxyethylene alkyl ether sulfate sodium 2.0%, detergent alkylate sulphur Acid 1.8%, triethanolamine 2.5%, nine hydrated sodium metasilicates 1.5%, sodium tripolyphosphate 0.8%, essence 0.4%, citric acid 1.0%th, dimethyl OIT 0.3%, surplus are deionized water.
The formula composition of this comparative example foam type kitchen duplicate removal finish is substantially the same manner as Example 1, and difference is, does not add Aliphatic alcohol polyethenoxy (7) ether.
Test example one, toxicology test
Press《Cosmetics health specification》(version in 2007) acute oral toxicity test is tested, with tested material animal LD50 Overall merit is carried out, observes its toxic action.
Acute oral toxicity test result shows, foam type kitchen duplicate removal finish made from embodiment 1-5 and comparative example 1-3 It is nontoxic level, LD50 >=5000mg/kg.
Test example two, foam performance experiment
Using concussion method measure, 0.03g duplicate removal finishes to be measured are added in colorimetric cylinder, 10mL distilled water is added, covers lid Son, 50 times (it is as consistent as possible to shake direction, speed, intensity etc.) are shaked, lid is removed, adds 10mL water, by colorimetric tube wall Upper foam is swept away, and records foam height, foam height is recorded again after 30min, is highly risen using initial foam as duplicate removal finish Performance metric is steeped, the stability of foam is characterized with the foam height after 30min.Foam height after foam stability=30min/ Initial foam height × 100%.
As a result it see the table below 1.
The foam performance test result of the duplicate removal finish in kitchen of the present invention of table 1
As a result show, kitchen duplicate removal finish has good foaming capacity and foam steady made from 1-5 of the embodiment of the present invention It is qualitative, and with duplicate removal finish best results in kitchen made from embodiment 1.Comparative example 1 lacks DBSA, makes in system The content of anionic surfactant is reduced, and system foam performance is obviously reduced；Comparative example 2 and 3 lacks poly alkyl alcohol respectively Oxygen ethene ether sodium sulfovinate and aliphatic alcohol polyethenoxy (7) ether, system foam performance are obviously reduced, especially to lack poly alkyl alcohol Oxygen ethene ether sodium sulfovinate is more notable, shows polyoxyethylene alkyl ether sulfate sodium and aliphatic alcohol polyethenoxy in body series (7) ether complements each other, indispensable.
Test example three, detergency ability experiment
By standard intraocular's dirt even application in stainless steel test piece, washed with sample stoste by QB/T 4348, measurement is dirty The removal percentage of dirt, the results are shown in Table 2.
The detergency ability test result of the duplicate removal finish in kitchen of the present invention of table 2
Group Soil removal efficiency/%
Embodiment 1 96.2
Embodiment 2 95.6
Embodiment 3 90.4
Embodiment 4 94.2
Embodiment 5 93.8
Comparative example 1 80.5
Comparative example 2 76.4
Comparative example 3 70.2
As a result showing, kitchen duplicate removal finish made from 1-5 of the embodiment of the present invention has good dirt-removing power, and to implement Duplicate removal finish best results in kitchen made from example 1.Duplicate removal finish dirt-removing power in kitchen weakens made from comparative example 1-3, especially It is worst to lack the clean effect of nonionic surface active agent aliphatic alcohol polyethenoxy (7) ether.
Test example four, erosion test
Determined by QB/T 2117, using sample stoste 150ml, 2 blocks of LY-12 aluminium sheets and 2 blocks of No. 45 steel plates, heating water bath It is 25 ± 2 DEG C, soak time 30min to make solution temperature, and heavy oil is evaluated with the cosmetic variation and etching extent of metal testing plate Agent corrosivity.Other operations the results are shown in Table 3 with QB/T 2117.
The corrosive nature test result of the duplicate removal finish in kitchen of the present invention of table 3
As a result showing, kitchen duplicate removal finish has relatively low corrosivity made from 1-5 of the embodiment of the present invention, and with embodiment Duplicate removal finish corrosivity in kitchen is most weak made from 1.Kitchen duplicate removal finish is respectively provided with certain corrosivity made from comparative example 1-3, It is especially most strong to lack the corrosivity of DBSA.
Test example five, adhesive force test
Its pulling force is tested using universal testing machine, adhesive force is calculated by pulling force.Respectively with injection mist and foam liquid side Between duplicate removal finish in kitchen made from embodiment 1 is sprayed on two parallel upper and lower templates by formula respectively, gradually increase the weight of weight Amount, until cope plate setting in motion, the reading of record pulling force (F).Pulling force reading is bigger, and adhesive force (f) is better.Wherein, f=F/ A, in formula, f is adhesive force (Pa), and F is pulling force (N), and A is contact area (m2)。
It the results are shown in Table 4.
The adhesive force test result of the duplicate removal finish in kitchen of the present invention of table 4
As a result show, duplicate removal finish in kitchen made from the embodiment of the present invention 1 with foam-like use caused by adhesive force be better than With vaporific use.
In summary, the kitchen duplicate removal finish property of foam-like of the present invention is gently safe, and foam performance is excellent, adhesive force By force, clean effect is good, and corrosivity is low.

Claims (5)

  1. A kind of 1. foam type kitchen duplicate removal finish, it is characterised in that described duplicate removal finish by following percentage by weight meter system Standby raw material forms：
    It is sodium hydroxide 0.5~3.0%, sodium carbonate 0.5~2.0%, polyoxyethylene alkyl ether sulfate sodium 0.5~3.0%, straight Alkyl group benzene sulfonic acid 0.5~3.0%, triethanolamine 2.5~3.0%, nine hydrated sodium metasilicates 0.5~3.0%, fatty alcohol polyoxy Vinethene 2.0~3.0%, phosphate 0.1~5.0%, essence 0.1~1.0%, pH adjusting agent 0.1~3.0%, preservative 0.1 ~0.5%, surplus is deionized water；
    Described linear alkyl benzene sulfonic acid is C10-C13At least one of alkyl benzene sulphonate.
  2. 2. foam type kitchen duplicate removal finish according to claim 1, it is characterised in that described duplicate removal finish is by following heavy Measure the preparing raw material composition of percentages：
    Sodium hydroxide 1.5%, sodium carbonate 1.5%, polyoxyethylene alkyl ether sulfate sodium 2.0%, linear alkyl benzene sulfonic acid 1.8%th, triethanolamine 2.5%, nine hydrated sodium metasilicates 1.5%, AEO 2.0%, phosphate 0.8%, perfume Essence 0.4%, pH adjusting agent 1.0%, preservative 0.3%, surplus is deionized water.
  3. 3. foam type kitchen duplicate removal finish according to claim 1, it is characterised in that described linear alkyl benzene sulfonic acid is DBSA.
  4. 4. foam type kitchen duplicate removal finish according to claim 1 or 2, it is characterised in that described fatty alcohol polyoxy second Alkene ether is at least one in aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether and aliphatic alcohol polyethenoxy (10) ether Kind.
  5. A kind of 5. method for preparing the foam type kitchen duplicate removal finish as described in claim 1-4 is any, it is characterised in that including Following steps：
    (1) polyoxyethylene alkyl ether sulfate sodium, linear alkyl benzene sulfonic acid, AEO are added to deionization In water, stir to system into homogeneous transparent liquid；
    (2) sodium hydroxide, sodium carbonate, triethanolamine, nine hydrated sodium metasilicates, phosphate are added while stirring, until material is complete Fully dissolved；
    (3) pH adjusting agent regulation pH to 10.5-11.5 is added, essence, preservative is added, stirs.
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CN111849647A (en) * 2020-08-13 2020-10-30 程坤 Oil removing agent
CN113201416B (en) * 2021-05-20 2022-02-01 中山市迈微环保科技有限公司 Alkaline multifunctional cleaning agent, preparation method and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102864037A (en) * 2012-10-12 2013-01-09 苏州谷力生物科技有限公司 Heavy-duty liquid composite detergent
CN105670830A (en) * 2016-04-07 2016-06-15 上海斯麦尔日化有限公司 Cleaning agent composition

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102864037A (en) * 2012-10-12 2013-01-09 苏州谷力生物科技有限公司 Heavy-duty liquid composite detergent
CN105670830A (en) * 2016-04-07 2016-06-15 上海斯麦尔日化有限公司 Cleaning agent composition

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