CN105670830A - Cleaning agent composition - Google Patents
Cleaning agent composition Download PDFInfo
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- CN105670830A CN105670830A CN201610213252.1A CN201610213252A CN105670830A CN 105670830 A CN105670830 A CN 105670830A CN 201610213252 A CN201610213252 A CN 201610213252A CN 105670830 A CN105670830 A CN 105670830A
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- polyoxyethylene ether
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-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Abstract
The invention relates to a cleaning agent composition which comprises the following components in parts by weight: 1-9 parts of sodium dodecyl benzene sulfonate, 1-5 parts of sodium hydroxide or potassium hydroxide, 0.5-3 parts of coconutt diethanol amide, 1-9 parts of C12-C13 fatty alcohol-polyoxyethylene ether, 1-8 parts of alkyl polyglucoside, 2-10 parts of sodium metasilicate, 0.1-2 parts of citric acid, 0.1-1.7 parts of sodium ethylenediaminetetraacetate and the balance of water based on 100 parts in total. By adopting the cleaning agent composition provided by the invention, oil stains on a surface can be removed perfectly.
Description
Technical field
This invention relates generally to a kind of cleansing composition, in particular it relates to the cleansing composition cleaned for crust greasy dirt.
Background technology
Ground greasy dirt be tedious, need for a long time to be solved the technical problem that. Especially for iron and steel enterprise and the Mechanical Manufacturing Enterprises such as automobile making, shipbuilding, due to life-time service, mill floor there will be a large amount of greasy dirt, both unsightly had an effect on use, the potential hazard such as cause workshop to pollute, to slip, is urgent problem.
In the past, clean ground greasy dirt mainly through modes such as Caustic soda, wood flour, liquid detergent, gasoline and kerosene. But, requiring now at reinforcement working environment and personal safety, above-mentioned cleaning method is phased out.
Specifically, the volatile gasoline of life-time service, kerosene carry out ground greasy dirt cleaning can affect Health Status For Workers Exposed, and organic volatilization is also easy to cause haze problem. It is also to be noted that use the oils such as gasoline and kerosene to clean ground greasy dirt also introduce other new problems, for instance, the ground after being cleaned by gasoline or kerosene is generally very cunning, and can quickly adsorb dust, it is necessary to it is cleaned frequently further. Meanwhile, the greasy dirt inflow sewer after cleaning causes water oil to be layered, it is necessary to waste water is carried out pretreatment could discharge, thus considerably increasing the cost of sewage disposal.
On the other hand, adopting wood flour cleaning not only to consume a large amount of timber, too increase operation easier, after cleaning, wood flour accumulation deposit and burning also can to environments; If cleaned with Caustic soda and liquid detergent, there is also effect undesirable, the problem such as high cost.
In addition, attempts have been made to be scraped by cutter or the mode such as baking removes ground greasy dirt. It will be evident that serious damage can be caused in ground by this type of cleaning method.
Therefore, this area is in the urgent need to a kind of abluent, and it can either meet the clean environment standard of 5s and 6s of working environment, has the advantages such as efficient, safe and environment-friendly, low cost simultaneously.
Summary of the invention
Therefore, the invention provides a kind of new cleansing composition, it is remarkably productive, it is possible to quickly wipe oil, and institute's expense is few.
Additionally, the cleansing composition of the present invention avoids use gasoline and kerosene cleans the problems such as produced easily breaking out of fire, and satiny phenomenon will not be produced, human body is non-stimulated, damage without causing ground. In addition, this cleansing composition can fully dissolve emulsifying greasy dirt, reduces and cleans the water yield, and saving water resource reduces cost.
In particular it relates to a kind of cleansing composition, it comprises:
The dodecylbenzene sodium sulfonate of 1-9 parts by weight;
The sodium hydroxide of 1-5 parts by weight or potassium hydroxide;
The coco-nut oil fatty acid diacetayl amide of 0.5-3 parts by weight;
The C12-C13 fatty alcohol-polyoxyethylene ether of 1-9 parts by weight;
The alkyl polyglycoside of 1-8 parts by weight;
The sodium metasilicate of 2-10 parts by weight;
The citric acid of 0.1-2 parts by weight;
The sodium ethylene diamine tetracetate of 0.1-1.7 parts by weight; And
Add and to the water of 100 parts by weight.
In one preferred embodiment, described cleansing composition comprises:
The dodecylbenzene sodium sulfonate of 2-8 parts by weight;
The sodium hydroxide of 1.5-4.5 parts by weight or potassium hydroxide;
The coco-nut oil fatty acid diacetayl amide of 0.2-2.5 parts by weight;
The C12-C13 fatty alcohol-polyoxyethylene ether of 2-8 parts by weight;
The alkyl polyglycoside of 1-7 parts by weight;
The sodium metasilicate of 2-8 parts by weight;
The citric acid of 0.1-1.5 parts by weight;
The sodium ethylene diamine tetracetate of 0.1-1.5 parts by weight; And
Add and to the water of 100 parts by weight.
Another preferred embodiment in, described cleansing composition comprises:
The dodecylbenzene sodium sulfonate of 3-7 parts by weight;
The sodium hydroxide of 2-4 parts by weight or potassium hydroxide;
The coco-nut oil fatty acid diacetayl amide of 1-2.5 parts by weight;
The C12-C13 fatty alcohol-polyoxyethylene ether of 3-7 parts by weight;
The alkyl polyglycoside of 2-6 parts by weight;
The sodium metasilicate of 3-7 parts by weight;
The citric acid of 0.3-1.5 parts by weight;
The sodium ethylene diamine tetracetate of 0.1-1 parts by weight; And
Add and to the water of 100 parts by weight.
Another preferred embodiment in, described cleansing composition comprises:
The dodecylbenzene sodium sulfonate of 4-6 parts by weight;
The sodium hydroxide of 2-3.5 parts by weight or potassium hydroxide;
The coco-nut oil fatty acid diacetayl amide of 1-2 parts by weight;
The C12-C13 fatty alcohol-polyoxyethylene ether of 4-6 parts by weight;
The alkyl polyglycoside of 3-5 parts by weight;
The sodium metasilicate of 4-7 parts by weight;
The citric acid of 0.5-1.5 parts by weight;
The sodium ethylene diamine tetracetate of 0.1-0.5 parts by weight; And
Add and to the water of 100 parts by weight.
Another preferred embodiment in, described cleansing composition comprises:
The dodecylbenzene sodium sulfonate of 5 parts by weight;
The sodium hydroxide of 2.8 parts by weight or potassium hydroxide;
The coco-nut oil fatty acid diacetayl amide of 1.7 parts by weight;
The C12-C13 fatty alcohol-polyoxyethylene ether of 5 parts by weight;
The alkyl polyglycoside of 4 parts by weight;
The sodium metasilicate of 6 parts by weight;
The citric acid of 1 parts by weight;
The sodium ethylene diamine tetracetate of 0.25 parts by weight; And
Add and to the water of 100 parts by weight.
Another preferred embodiment in, described cleansing composition also comprises the oleate soap of 3-7 parts by weight.
Another preferred embodiment in, described cleansing composition comprises the oleate soap of 4-5 parts by weight.
Another preferred embodiment in, described cleansing composition comprises the oleate soap of 4.5 parts by weight.
Another preferred embodiment in, described C12-C13 fatty alcohol-polyoxyethylene ether is C12 fatty alcohol-polyoxyethylene ether.
Another preferred embodiment in, described alkyl polyglycoside includes the many glycosides of lauryl glucose and/or the many glycosides of decyl glucose.
It should be noted that above-mentioned numerical range includes the combination in any of any number and numerical range therebetween. Such as, 1-9 parts by weight include 1 parts by weight, 2 parts by weight, 3 parts by weight, 4 parts by weight, 5 parts by weight, 6 parts by weight, 7 parts by weight, 8 parts by weight and 9 parts by weight and the combination in any of the parts by weight such as such as 1-2,1-3,1-4,1-5,1-6,1-7,1-8 and 1-9.Here concrete numerical value and numerical range are as just citing, and nonrestrictive.
Detailed description of the invention
The present inventor finds after having carried out extensive and deep research, by adopting dodecylbenzene sodium sulfonate, C12-C13 fatty alcohol-polyoxyethylene ether, alkyl polyglycoside and sodium metasilicate as important activity composition, it is simultaneously introduced appropriate sodium hydroxide or potassium hydroxide, coco-nut oil fatty acid diacetayl amide, citric acid, sodium ethylene diamine tetracetate, water, and optional oleate soap, the performance of the good wipe oil of cleansing composition can be given so that cleansing composition can quickly and well wipe oil.
Dodecylbenzene sodium sulfonate
Dodecylbenzene sodium sulfonate is the important activity composition of the present invention, belongs to new nonionic surfactant, and it has excellent surface or interface performance, has good dissolubility in water. At the dissolubility of 25 degrees Celsius more than 30%, there is efficient emulsifying capacity. Dodecylbenzene sodium sulfonate energy complete biodegradable, having chemical stability and low-temperature stability, the toxicity for human body and environment is only small, has good oily waste degradation and wettability.
For the consumption of dodecylbenzene sodium sulfonate, if consumption is less than 1 parts by weight, then do not reach effective oily waste degradation effect; If consumption is more than 9 parts by weight, then the effect change of wipe oil is little, also results in cost and dramatically increases.
Preferably, the consumption of dodecylbenzene sodium sulfonate is 1-9 parts by weight, more preferably 2-8 parts by weight, 3-7 parts by weight or 4-6 parts by weight, or 4 parts by weight, 5 parts by weight or 6 parts by weight.
Sodium hydroxide or potassium hydroxide
The cleansing composition of the present invention also comprises NaOH or KOH, its content is preferably 1-5 parts by weight, it is more preferably 1.5-4.5 parts by weight, 2-4 parts by weight or 2-3.5 parts by weight or 2 parts by weight, 2.1 parts by weight, 2.2 parts by weight, 2.3 parts by weight, 2.4 parts by weight, 2.5 parts by weight, 2.6 parts by weight, 2.7 parts by weight, 2.8 parts by weight, 2.9 parts by weight, 3 parts by weight, 3.1 parts by weight, 3.2 parts by weight, 3.3 parts by weight, 3.4 parts by weight or 3.5 parts by weight.
Coco-nut oil fatty acid diacetayl amide
The cleansing composition of the present invention also comprises coco-nut oil fatty acid diacetayl amide, and being commonly called as in this area is 6501 (1:1.5).
For the consumption of coco-nut oil fatty acid diacetayl amide, if consumption is less than 0.5 parts by weight, then do not reach effective oily waste degradation effect; If consumption is more than 3 parts by weight, then the effect change of wipe oil is little, also results in cost and dramatically increases.
Preferably, the consumption of coco-nut oil fatty acid diacetayl amide is 0.5-3 parts by weight, it is more preferably 0.5-2.5 parts by weight, 1-2.5 parts by weight or 1-2 parts by weight or 1 parts by weight, 1.1 parts by weight, 1.2 parts by weight, 1.3 parts by weight, 1.4 parts by weight, 1.5 parts by weight, 1.6 parts by weight, 1.7 parts by weight, 1.8 parts by weight, 1.9 parts by weight or 2 parts by weight.
C12-C13 fatty alcohol-polyoxyethylene ether
C12-C13 fatty alcohol-polyoxyethylene ether is also called 23E9 in this area, it it is the important activity composition of the present invention, it is easily dispersed or dissolved in water, can use composite with multiple cation, anion and nonionic surfactant, there is good lubricity, permeability, emulsibility, hard water resistance property, and its chemical stability and Environmental compatibility in broad pH value range are good.
For the consumption of C12-C13 fatty alcohol-polyoxyethylene ether, if consumption is less than 1 parts by weight, then do not reach effective oily waste degradation effect; If consumption is more than 9 parts by weight, then the effect change of wipe oil is little, also results in cost and dramatically increases.
Preferably, the consumption of C12-C13 fatty alcohol-polyoxyethylene ether is 1-9 parts by weight, more preferably 2-8 parts by weight, 3-7 parts by weight or 4-6 parts by weight, or 4 parts by weight, 5 parts by weight or 6 parts by weight.
Alkyl polyglycoside
Alkyl polyglycoside (APG) is also the important activity composition of the present invention, belongs to the new non-ionic type surfactant prepared with fatty alcohol produced by renewable raw materials Cortex cocois radicis wet goods natural oil with the synthesis of Semen Maydis kind of starch hydrolyzate glucose. APG is by fatty alcohol and carbohydrate under acid catalysis, adopts Fischer glycosidation method to prepare. The structural formula of alkyl polyglycoside is as follows:
In formula, n is the number of glucose unit, and R is alkyl. General molecular formula can be expressed as RO (G) m, and wherein G represents the sugar unit containing 5 or 6 carbon atoms, and R is usually the straight chain saturated alkyl containing 8-18 carbon atom. The m glycosides more than 2 is commonly referred to collectively as the many glycosides of alkyl glucose (APG), or referred to as alkyl polyglycoside.
Common APG is the many glycosides of lauryl glucose and the many glycosides of decyl glucose.
APG and oligomer thereof have the character of anionic surfactant and nonionic surfactant concurrently. The hydrophilic segment of APG molecule is dissolved in neutral during water, without plastic scope when being diluted with water. APG is good foaming agent and detergent, belongs to " easily biological-degradable class " surfactant.
APG has foam enhancing in anionic surfactant, and alkali resistance is strong, and Efficient Adhesive Promotion is obvious, good with various surfactant compatibilities, it is possible to replace LAS, AEO, AES etc. as main active component. APG is different from conventional nonionic type surfactant, and the hydrophobic and hydrophilic segment in its molecule all derives from reproducible natural material, has the ability of very strong wipe oil.
For the consumption of APG, if consumption is less than 1 parts by weight, then do not reach effective oily waste degradation effect; If consumption is more than 8 parts by weight, then the effect change of wipe oil is little, also results in cost and dramatically increases.
Preferably, the consumption of APG is 1-8 parts by weight, more preferably 1-7 parts by weight, 2-6 parts by weight or 3-5 parts by weight, or 3 parts by weight, 4 parts by weight or 5 parts by weight.
Sodium metasilicate
Sodium metasilicate is also the important activity component of the present invention, and it is used as heavy duty detergent, it is possible to forms precipitation with heavy metal ion, makes water software, and prevent soil redeposition, also have rust inhibition, wettability and emulsibility etc.
For the consumption of sodium metasilicate, if consumption is less than 2 parts by weight, then do not reach effective oily waste degradation effect; If consumption is more than 10 parts by weight, then the effect change of wipe oil is little, also results in cost and dramatically increases.
Preferably, the consumption of sodium metasilicate is 2-10 parts by weight, more preferably 2-8 parts by weight, 3-7 parts by weight or 4-7 parts by weight, or 4 parts by weight, 5 parts by weight, 6 parts by weight or 7 parts by weight.
Citric acid
The cleansing composition of the present invention also comprises citric acid, its content is preferably 0.1-2 parts by weight, 0.1-1.5 parts by weight, 0.3-1.5 parts by weight or 0.5-1.5 parts by weight or 0.5 parts by weight, 0.6 parts by weight, 0.7 parts by weight, 0.8 parts by weight, 0.9 parts by weight, 1.0 parts by weight, 1.1 parts by weight, 1.2 parts by weight, 1.3 parts by weight, 1.4 parts by weight or 1.5 parts by weight.
Sodium ethylene diamine tetracetate
Sodium ethylene diamine tetracetate is also referred to as EDETATE SODIUM, its content is preferably 0.1-1.7 parts by weight, it is more preferably 0.1-1.5 parts by weight, 0.1-1 parts by weight or 0.1-0.5 parts by weight or 0.1 parts by weight, 0.15 parts by weight, 0.2 parts by weight, 0.25 parts by weight, 0.3 parts by weight, 0.35 parts by weight, 0.4 parts by weight, 0.45 parts by weight or 0.5 parts by weight.
Oleate soap
The cleansing composition of the present invention also optionally comprises oleate soap, and its content is preferably 3-7 parts by weight, more preferably 4-5 parts by weight, or 4 parts by weight, 4.5 parts by weight or 5 parts by weight.
All mentioned components selected in the cleansing composition of the present invention, such as dodecylbenzene sodium sulfonate, the many glycosides of lauryl glucose, the decyl many glycosides of glucose etc. are all materials well known in the art, can prepare by conventional method, can also directly buy from the market, for instance can purchased from such as Japanese Kao company, Henkel KGaA Ke Lin company, Lay benefactor department of Germany gram etc. Particularly preferred composition is all the kind that those are conventional in cleaning agent field.
The cleansing composition of the present invention can be made into various dosage form, for instance emulsion, cleaning agent, detergent etc.
Embodiment
The present invention is expanded on further below in conjunction with specific embodiment. Should be understood that these embodiments are merely to illustrate the present invention and are not meant to limit the scope of the invention. The experimental technique of unreceipted actual conditions in the following example, generally conventionally condition, or according to manufacturer it is proposed that condition. Except as otherwise noted, all of percentage ratio and number are by composition total weight.
Embodiment 1
Adopt methods known in the art, the cleansing composition of the preparation various formula listed by table 1 below:
| Component | Consumption (parts by weight) |
| Dodecylbenzene sodium sulfonate | 5 |
| NaOH | 2.8 |
| Coco-nut oil fatty acid diacetayl amide | 1.7 |
| C12 fatty alcohol-polyoxyethylene ether | 5 |
| The many glycosides of lauryl glucose | 4 |
| Sodium metasilicate | 6 |
| Citric acid | 1 |
| EDETATE SODIUM | 0.25 |
| Water | Add and to the surplus of 100 parts by weight |
Embodiment 2
Adopt methods known in the art, the cleansing composition of the preparation various formula listed by table 2 below:
Embodiment 3
Adopt methods known in the art, the cleansing composition of the preparation various formula listed by table 3 below:
| Component | Consumption (parts by weight) |
| Dodecylbenzene sodium sulfonate | 6 |
| NaOH | 3.5 |
| Coco-nut oil fatty acid diacetayl amide | 2 |
| C12 fatty alcohol-polyoxyethylene ether | 6 |
| The many glycosides of lauryl glucose | 5 |
| Sodium metasilicate | 7 |
| Citric acid | 1.5 |
| EDETATE SODIUM | 0.5 |
| Water | Add and to the surplus of 100 parts by weight |
Embodiment 4
Adopt methods known in the art, the cleansing composition of the preparation various formula listed by table 4 below:
Embodiment 5
Adopt methods known in the art, the cleansing composition of the preparation various formula listed by table 5 below:
| Component | Consumption (parts by weight) |
| Dodecylbenzene sodium sulfonate | 5.3 |
| NaOH | 3 |
| Coco-nut oil fatty acid diacetayl amide | 1.7 |
| C12 fatty alcohol-polyoxyethylene ether | 5 |
| The many glycosides of lauryl glucose | 4.5 |
| Sodium metasilicate | 6 |
| Citric acid | 1 |
| EDETATE SODIUM | 0.3 |
| Oleate soap | 4.5 |
| Water | Add and to the surplus of 100 parts by weight |
Comparative example 6
Adopt methods known in the art, the cleansing composition of the preparation various formula listed by table 6 below:
| Component | Consumption (parts by weight) |
| Dodecylbenzene sodium sulfonate | 5 |
| NaOH | 2.5 |
| Coco-nut oil fatty acid diacetayl amide | 0 |
| C12 fatty alcohol-polyoxyethylene ether | 4 |
| The many glycosides of lauryl glucose | 5 |
| Sodium metasilicate | 6.5 |
| Citric acid | 2.5 |
| EDETATE SODIUM | 0.25 |
| Water | Add and to the surplus of 100 parts by weight |
Comparative example 7
Adopt methods known in the art, the cleansing composition of the preparation various formula listed by table 7 below:
| Component | Consumption (parts by weight) |
| Dodecylbenzene sodium sulfonate | 4.5 |
| NaOH | 3 |
| Coco-nut oil fatty acid diacetayl amide | 2 |
| C12 fatty alcohol-polyoxyethylene ether | 0 |
| The many glycosides of lauryl glucose | 4 |
| Sodium metasilicate | 6 |
| Citric acid | 3 |
| EDETATE SODIUM | 0.1 |
| Water | Add and to the surplus of 100 parts by weight |
Comparative example 8
Adopt methods known in the art, the cleansing composition of the preparation various formula listed by table 8 below:
| Component | Consumption (parts by weight) |
| Dodecylbenzene sodium sulfonate | 8 |
| NaOH | 4 |
| Coco-nut oil fatty acid diacetayl amide | 2.5 |
| C12 fatty alcohol-polyoxyethylene ether | 5.5 |
| The many glycosides of lauryl glucose | 3.7 |
| Sodium metasilicate | 0 |
| Citric acid | 3 |
| EDETATE SODIUM | 0.1 |
| Water | Add and to the surplus of 100 parts by weight |
Comparative example 9
Use commercially 93# gasoline.
Comparative example 10
Use commercially white cat board liquid detergent.
Comparative example 11
Use commercially Caustic soda.
Evaluation methodology
(1) oily waste degradation effect
Clean greasy dirt ground, steel workshop by the embodiment 1-5 compositions prepared and comparative example 6-11, adopt following evaluation criterion to evaluate oily waste degradation effect:
◎: oily waste degradation effect is fine;
O: oily waste degradation effect is better;
Δ: oily waste degradation effect is general;
X: oily waste degradation weak effect.
(2) oily waste degradation speed
Clean greasy dirt ground, steel workshop by the embodiment 1-5 compositions prepared and comparative example 6-11, adopt following evaluation criterion to evaluate oily waste degradation speed:
◎: oily waste degradation speed is fine;
O: oily waste degradation speed is better;
Δ: oily waste degradation speed is general;
X: oily waste degradation speed difference.
(3) oily waste degradation persistency
After the aptitude tests of (1) wipe oil mentioned above, visual observations greasy dirt situation again after treating 2 weeks, 4 weeks. Adopt following evaluation criterion to evaluate oily waste degradation persistency:
◎: do not observe greasy dirt;
O: observe slightly greasy dirt;
Δ: a large amount of greasy dirt occurs;
X: almost covered by greasy dirt completely.
Referring to table 9, the effect of the cleansing composition of the present invention is evaluated below.
Table 9
It can be seen that the cleansing composition of the present invention has excellent oily waste degradation ability from upper table 9, can wipe oil quickly and efficiently, and the lasting effect for oily waste degradation is also better. The cost being additionally, since in the cleansing composition of the present invention each component is all relatively low, and therefore, the price of the cleansing composition of the present invention is relatively low.
Although for the purpose being aware and understand, the present invention is described in detail, but after having read present specification, those skilled in the art will be appreciated that, under the premise of the spirit and essence that not necessarily depart from the present invention, the present invention can carry out various amendment and change, and these amendments and change each fall within the scope included by appended claims and equivalents thereto thereof.
Claims (10)
1. a cleansing composition, it comprises:
The dodecylbenzene sodium sulfonate of 1-9 parts by weight;
The sodium hydroxide of 1-5 parts by weight or potassium hydroxide;
The coco-nut oil fatty acid diacetayl amide of 0.5-3 parts by weight;
The C12-C13 fatty alcohol-polyoxyethylene ether of 1-9 parts by weight;
The alkyl polyglycoside of 1-8 parts by weight;
The sodium metasilicate of 2-10 parts by weight;
The citric acid of 0.1-2 parts by weight;
The sodium ethylene diamine tetracetate of 0.1-1.7 parts by weight; And
Add and to the water of 100 parts by weight.
2. cleansing composition as claimed in claim 1, it is characterised in that described cleansing composition comprises:
The dodecylbenzene sodium sulfonate of 2-8 parts by weight;
The sodium hydroxide of 1.5-4.5 parts by weight or potassium hydroxide;
The coco-nut oil fatty acid diacetayl amide of 0.2-2.5 parts by weight;
The C12-C13 fatty alcohol-polyoxyethylene ether of 2-8 parts by weight;
The alkyl polyglycoside of 1-7 parts by weight;
The sodium metasilicate of 2-8 parts by weight;
The citric acid of 0.1-1.5 parts by weight;
The sodium ethylene diamine tetracetate of 0.1-1.5 parts by weight; And
Add and to the water of 100 parts by weight.
3. cleansing composition as claimed in claim 2, it is characterised in that described cleansing composition comprises:
The dodecylbenzene sodium sulfonate of 3-7 parts by weight;
The sodium hydroxide of 2-4 parts by weight or potassium hydroxide;
The coco-nut oil fatty acid diacetayl amide of 1-2.5 parts by weight;
The C12-C13 fatty alcohol-polyoxyethylene ether of 3-7 parts by weight;
The alkyl polyglycoside of 2-6 parts by weight;
The sodium metasilicate of 3-7 parts by weight;
The citric acid of 0.3-1.5 parts by weight;
The sodium ethylene diamine tetracetate of 0.1-1 parts by weight; And
Add and to the water of 100 parts by weight.
4. cleansing composition as claimed in claim 3, it is characterised in that described cleansing composition comprises:
The dodecylbenzene sodium sulfonate of 4-6 parts by weight;
The sodium hydroxide of 2-3.5 parts by weight or potassium hydroxide;
The coco-nut oil fatty acid diacetayl amide of 1-2 parts by weight;
The C12-C13 fatty alcohol-polyoxyethylene ether of 4-6 parts by weight;
The alkyl polyglycoside of 3-5 parts by weight;
The sodium metasilicate of 4-7 parts by weight;
The citric acid of 0.5-1.5 parts by weight;
The sodium ethylene diamine tetracetate of 0.1-0.5 parts by weight; And
Add and to the water of 100 parts by weight.
5. cleansing composition as claimed in claim 4, it is characterised in that described cleansing composition comprises:
The dodecylbenzene sodium sulfonate of 5 parts by weight;
The sodium hydroxide of 2.8 parts by weight or potassium hydroxide;
The coco-nut oil fatty acid diacetayl amide of 1.7 parts by weight;
The C12-C13 fatty alcohol-polyoxyethylene ether of 5 parts by weight;
The alkyl polyglycoside of 4 parts by weight;
The sodium metasilicate of 6 parts by weight;
The citric acid of 1 parts by weight;
The sodium ethylene diamine tetracetate of 0.25 parts by weight; And
Add and to the water of 100 parts by weight.
6. the cleansing composition as according to any one of claim 1-5, it is characterised in that described cleansing composition also comprises the oleate soap of 3-7 parts by weight.
7. cleansing composition as claimed in claim 6, it is characterised in that described cleansing composition comprises the oleate soap of 4-5 parts by weight.
8. cleansing composition as claimed in claim 7, it is characterised in that described cleansing composition comprises the oleate soap of 4.5 parts by weight.
9. the cleansing composition as according to any one of claim 1-5, it is characterised in that described C12-C13 fatty alcohol-polyoxyethylene ether is C12 fatty alcohol-polyoxyethylene ether.
10. the cleansing composition as according to any one of claim 1-5, it is characterised in that described alkyl polyglycoside includes the many glycosides of lauryl glucose and/or the many glycosides of decyl glucose.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610213252.1A CN105670830A (en) | 2016-04-07 | 2016-04-07 | Cleaning agent composition |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610213252.1A CN105670830A (en) | 2016-04-07 | 2016-04-07 | Cleaning agent composition |
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| CN106700715B (en) * | 2016-11-15 | 2020-08-28 | 姚佑灿 | Cleaning agent for removing paint on plastic surface and preparation method thereof |
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