CN105296190B - Mechanical equipment the imperial robe cleaning agent - Google Patents
Mechanical equipment the imperial robe cleaning agent Download PDFInfo
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- CN105296190B CN105296190B CN201510808714.XA CN201510808714A CN105296190B CN 105296190 B CN105296190 B CN 105296190B CN 201510808714 A CN201510808714 A CN 201510808714A CN 105296190 B CN105296190 B CN 105296190B
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Abstract
The present invention relates to a kind of cleanser compositions, be 100 weight % by the cleanser compositions in terms of, the cleanser compositions include following components: (a) sodium alkyl sulfonate of 1-10 weight %, the sodium alkyl sulfonate include sodium cetanesulfonate；(b) liquid alkaline of 1-5 weight %, the liquid alkaline include NaOH and/or KOH；(c) alkyl polyglycoside of 2-15 weight %, the alkyl polyglycoside include the more glycosides of lauryl glucose and/or the more glycosides of decyl glucose；(d) alcohol of 1-10 weight %, the alcohol include ethyl alcohol and/or isopropanol；(e) butyl glycol ether of 1-10 weight %；And (f) disodium ethylene diamine tetraacetate of 0.1-0.5 weight %.Cleanser compositions of the invention have excellent removal the imperial robe ability, can quickly and efficiently remove the imperial robe.
Description
Technical field
This invention relates generally to a kind of cleanser compositions, more particularly, to one kind for industrial machinery oil
Dirt, the especially cleanser compositions of " the imperial robe " greasy dirt.
Background technique
In the operation of industrial machinery, due to mechanical friction campaign, generate heat in this process so that oil plant by
It thermally decomposes, under aerial oxidation, causes to gradually form greasy yellowish-brown mucous membrane (being commonly called as " the imperial robe ").The imperial robe is close
It is adsorbed in equipment list surface layer, molecular structure is secured, it is difficult to be removed.
It can be led by the long-term accumulation that each class lubricating oil, heavy engine oil, diesel oil, gasoline volatilization and dust form slightly solubility " the imperial robe "
The service life of equipment is caused to substantially reduce, some even can also seriously affect the operating of equipment, to influence to produce.
Steel, machinery, auto manufacturing, shipping industry, part processing, electromechanical equipment, war industry, agricultural machinery,
The industries such as aviation, machine maintenance maintenance all endure the puzzlement of " the imperial robe " problem to the fullest extent.How the imperial robe one on mechanical equipment surface is removed
It is directly these enterprises insoluble problem for many years.
In the prior art, gasoline, diesel oil and kerosene are generallyd use to be cleaned.But cleaning effect can only remove
Surface grease, can not remove certain greases for being difficult to emulsify, thus the imperial robe that cannot fundamentally on eliminating equipment, and can
New greasy dirt can be adsorbed again.In addition, such " oil wash oil " technique can also seriously pollute ambient enviroment.The waste oil that it is discharged is in water
In can not degrade, cause direct environmental pollution.In addition to this, gasoline, diesel oil and kerosene are all important energy oil, use
They cause apparent energy waste to remove " the imperial robe ", do not meet power conservation requirement.
Another method of the prior art scrapes to remove on machine " the imperial robe " using knife.But one scraped using knife
A distinct disadvantage is that the process is not only time-consuming and laborious, also will cause the damage of machine surface.This is precision machined for requiring
It is unacceptable especially for the high-tech mechanical equipment such as aviation for machinery.
It, sometimes can also be on mechanical equipment surface using paint or spray other than oil wash oil and knife scrape both methods
The method of paint covers the imperial robe.But this method will cause workshop stop work and production, and the smell is awful, waste a large amount of manpowers
And financial resources.Different degrees of harm can be caused to the body of people using gasoline for a long time, in production environment mainly with steam
Form suck human body through respiratory tract, by the brain of blood circulation to people, cause anesthetic effect.And Central nervous system and
Nerve ending generates toxic action, also generates adverse effect to marrow hemopoiesis function.
Therefore, it goes that " the imperial robe " ability is strong, effect is lasting there is an urgent need in the art to developing one kind, while not will cause environment dirt
Dye and human body harm and lower-cost cleanser compositions.
Summary of the invention
The present invention provides a kind of cleanser compositions, the cleanser compositions can more quick and effect preferably go
Except the imperial robe, while will not cause damages to environment and human body.In addition, the cost of the cleanser compositions is also lower, it can be preferably
It is applied in the mechanical equipment cleaning purpose of removal the imperial robe.
In one aspect of the invention, a kind of cleanser compositions are provided, with the cleanser compositions for 100 weight %
Meter, it includes:
(a) sodium alkyl sulfonate (SAS) of 1-10 weight %；
(b) liquid alkaline of 1-5 weight %；
(c) alkyl polyglycoside (APG) of 2-15 weight %；
(d) alcohol of 1-10 weight %；
(e) butyl glycol ether of 1-10 weight %；And
(f) disodium ethylene diamine tetraacetate (EDTA-2Na) of 0.1-0.5 weight %.
In one preferred embodiment, the sodium alkyl sulfonate includes sodium cetanesulfonate.
In another preferred embodiment, the content of the sodium alkyl sulfonate (or sodium cetanesulfonate) includes
2-8 weight %, 3-7 weight % or 4-6 weight %, or be for example, 2 weight %, 2.5 weight %, 3 weight %, 3.5 weights
Measure %, 4 weight %, 4.5 weight %, 5 weight %, 5.5 weight %, 6 weight %, 6.5 weight %, 7 weight %, 7.5 weight %
Or 8 weight %, any combination range including above-mentioned numerical value.
In one preferred embodiment, the liquid alkaline includes NaOH and/or KOH.
In another preferred embodiment, the content of the liquid alkaline (or NaOH and/or KOH) includes 2-5 weight
% is measured, or is for example, 2 weight %, 2.5 weight %, 3 weight %, 3.5 weight %, 4 weight %, 4.5 weight % or 5 weights
Measure %, any combination range including above-mentioned numerical value.
In one preferred embodiment, the alkyl polyglycoside includes the more glycosides of lauryl Portugal (grape) sugar and/or decyl Portugal
The more glycosides of (grape) sugar.
In another preferred embodiment, the alkyl polyglycoside (or the more glycosides of lauryl Portugal (grape) sugar and/or decyl
The more glycosides of Portugal (grape) sugar) content include 3-14 weight %, 4-13 weight %, 5-12 weight %, 6-11 weight % or 7-10 weight
% is measured, or is for example, 3 weight %, 4 weight %, 5 weight %, 6 weight %, 7 weight %, 8 weight %, 9 weight %, 10
Weight %, 11 weight %, 12 weight %, 13 weight % or 14 weight %, any combination range including above-mentioned numerical value.
In one preferred embodiment, the alcohol includes ethyl alcohol and/or isopropanol.
In another preferred embodiment, the content of the alcohol (or ethyl alcohol and/or isopropanol) includes 2-9 weight
%, 3-8 weight % or 4-7 weight % are measured, or is for example, 2 weight %, 3 weight %, 4 weight %, 5 weight %, 6 weights
Measure %, 7 weight %, 8 weight % or 9 weight %, any combination range including above-mentioned numerical value.
In one preferred embodiment, the content of the butyl glycol ether include 2-9 weight %, 3-8 weight % or
4-7 weight %, or be for example, 2 weight %, 3 weight %, 4 weight %, 5 weight %, 6 weight %, 7 weight %, 8 weights
Measure % or 9 weight %, any combination range including above-mentioned numerical value.
In one preferred embodiment, the content of the disodium ethylene diamine tetraacetate includes 0.2-0.4 weight %, again
Either for example, 0.2 weight %, 0.3 weight % or 0.4 weight %, any combination range including above-mentioned numerical value.
In another preferred embodiment, the cleanser compositions also include: the water of (g) surplus is preferably gone
Ionized water.
In another preferred embodiment, the cleanser compositions also include: the fragrance of (h) 1-10 weight %.
In another preferred embodiment, the cleanser compositions also include: the wool of (i) 1-10 weight %
Rouge.
In another aspect of the invention, a kind of use that the cleanser compositions are used for mechanical device cleaning is provided
On the way, the mechanical device includes but is not limited to the machine of the mechanical device of shipbuilding industry, the mechanical device of railway industry, aircraft industry
Tool device, lathe and steel etc..
Above-mentioned preferred embodiment of the invention can be using arbitrary form individualism or as depositing in the form of any combination
?.
Specific embodiment
The present inventor has found after having made extensive and intensive studies, by using sodium alkyl sulfonate
(SAS), alkyl polyglycoside (APG) is used as main active, while liquid alkaline, alcohols, butyl glycol ether and EDTA-2Na, energy is added
Assign the performance that preferably degreases of cleanser compositions so that the speed that cleanser compositions degrease faster, effect
More preferably.
Sodium alkyl sulfonate (SAS)
Sodium alkyl sulfonate (SAS) is important activity ingredient of the invention, belongs to new nonionic surfactant, molecule
Structural formula is R1CH(SO3Na)R2, the average carbon number of alkyl chain is 14-16.Since sulfonic group is connected with secondary carbon, thus its
With excellent surface or interface performance, there is preferable dissolubility in water.It is greater than 30% in 25 degrees Celsius of solubility, tool
There is efficient emulsifying capacity.
SAS can complete biodegradable, have chemical stability and low-temperature stability, for human body and environment toxicity very
It is small, there is good the imperial robe removal and wettability.
Common SAS is sodium cetanesulfonate.
Compared with cleaning component neopelex (LAS) common in industry, SAS or sodium cetanesulfonate tool
There is identical decontamination, go the imperial robe ability, but there is better biological degradability.SAS or sodium cetanesulfonate can prepare low
The detergent of viscosity, high concentration can add less or solubilizer is not added, and the foam booster for not needing alkanolamide etc has
There is a good foamability, and also with fabulous fat dissolving, does not need oily using adding rouge agent i.e. and can dissolve a large amount of " the imperial robes "
It is dirty.On the contrary, LAS needs to improve solubility using alkanolamine, cost and complexity are increased.
For the dosage of SAS or sodium cetanesulfonate, if it is yellow that removal is not achieved less than 1 weight % in dosage
The effect of robe；If dosage is greater than 10 weight %, the effect variation for removing the imperial robe less, also results in increased costs.
Liquid alkaline
Cleanser compositions of the invention also include liquid alkaline, are selected from NaOH and/or KOH.The content of liquid alkaline is 1-5 weight
Measure %, preferably 2 weight %.
Alkyl polyglycoside (APG)
Alkyl polyglycoside (APG) is also important activity ingredient of the invention, is belonged to natural oils such as renewable raw materials coconut oil
Fatty alcohol caused by rouge synthesizes new non-ionic type surfactant obtained with corn kind of starch hydrolysate glucose.
APG is by fatty alcohol and carbohydrate under acid catalysis, using made from Fischer glycosidation method.The structural formula of alkyl polyglycoside
It is as follows:
In formula, n is the number of glucose unit, and R is alkyl.General molecular formula can be expressed as RO (G)m, wherein G indicates to contain
The sugar unit of 5 or 6 carbon atoms, R are usually the straight chain saturated alkyl containing 8-18 carbon atom.Glycosides of the m greater than 2 is generally referred to as
For the more glycosides of alkyl glucose (APG), or referred to as alkyl polyglycoside.
Common APG is the more glycosides of lauryl glucose and the more glycosides of decyl glucose.
APG and its oligomer have both the property of anionic surfactant and nonionic surface active agent.APG molecule
Hydrophilic segment neutral when being dissolved in water, without plastic range when being diluted with water.APG is good foaming agent and detergent, is belonged to
In " easily biological-degradable class " surfactant.
APG has foam enhancing in anionic surfactant, and alkali resistance is strong, and Efficient Adhesive Promotion is obvious, with various surfaces
Active ingredient performance is good, can replace LAS, AEO, AES etc. as main active component.
APG is different from conventional nonionic type surfactant, and the hydrophobic and hydrophilic segment in molecule all derives from can be again
Raw natural material, the ability with very strong removal the imperial robe.
For the dosage of APG, if the effect of removal the imperial robe is not achieved less than 2 weight % in dosage；If dosage
Greater than 15 weight %, then the effect variation for removing the imperial robe less, also results in increased costs.
Alcohols
Cleanser compositions of the invention also include alcohols, are selected from ethyl alcohol and/or isopropanol.Alcohols has certain wave
Hair property, can preferably remove the imperial robe.The content of alcohol is 1-10 weight %, preferably 2-5 weight %.
Butyl glycol ether
Cleanser compositions of the invention also include butyl glycol ether.The content of butyl glycol ether is 1-10 weight %, excellent
It is selected as 3-6 weight %.
Disodium ethylene diamine tetraacetate (EDTA-2Na)
Cleanser compositions of the invention also include disodium ethylene diamine tetraacetate.The content of disodium ethylene diamine tetraacetate is
0.1-0.5 weight %, preferably 0.2 weight %.
Optionally, cleanser compositions of the invention also may include fragrance.The dosage of the fragrance is 1-10 weight %, excellent
It is selected as 3-7 weight %, more preferably 5 weight %.
Optionally, cleanser compositions of the invention also may include lanolin.The dosage of the lanolin is 1-10 weight
Measure %, preferably 3-7 weight %, more preferably 5 weight %.
Optionally, cleanser compositions of the invention also may include enough water, preferably deionized water.
Selected all mentioned components in cleanser compositions of the invention, such as sodium cetanesulfonate, lauryl
The more glycosides of glucose, the more glycosides of decyl glucose etc. are all substances well known in the art, can be prepared with conventional method, can also be directly from city
It is bought on, such as can be purchased from such as Japanese Kao company, Henkel KGaA Ke Lin company, German Klein company.Especially
Preferred ingredient is all those in the common type in detergent field.
Cleanser compositions of the invention can be made into various dosage forms, such as lotion, detergent, detergent etc..
The major advantage of cleanser compositions of the invention is as follows:
(1) ability for removing the imperial robe is strong；
(2) speed for removing the imperial robe is fast；
(3) duration of effect is long after removal the imperial robe；
(4) environmental pollution is small, non-hazardous to human body；And
(5) at low cost.
Embodiment
The present invention is further explained combined with specific embodiments below.It should be understood that these embodiments are merely to illustrate this hair
It is bright and be not meant to limit the scope of the invention.In the following examples, the experimental methods for specific conditions are not specified, usually according to normal
Rule condition, or according to the normal condition proposed by manufacturer.Unless otherwise indicated, all percentage and number press composition gross weight
Meter.
Embodiment 1
Using methods known in the art, the cleanser compositions of various formulas listed in Table are prepared:
Table 1
| Component | Dosage (weight %) |
| Sodium cetanesulfonate | 2.0 |
| NaOH | 2.0 |
| The more glycosides of lauryl glucose | 4.0 |
| Ethyl alcohol | 5.0 |
| Butyl glycol ether | 3.0 |
| EDETATE SODIUM | 0.2 |
| Deionized water | Surplus |
Embodiment 2
Using methods known in the art, the cleanser compositions of various formulas listed in Table are prepared:
Table 2
| Component | Dosage (weight %) |
| Sodium cetanesulfonate | 2.0 |
| NaOH | 2.0 |
| The more glycosides of lauryl glucose | 4.0 |
| Isopropanol | 5.0 |
| Butyl glycol ether | 3.0 |
| EDETATE SODIUM | 0.2 |
| Deionized water | Surplus |
Embodiment 3
Using methods known in the art, the cleanser compositions of various formulas listed in Table are prepared:
Table 3
Embodiment 4
Using methods known in the art, the cleanser compositions of various formulas listed in Table are prepared:
Table 4
| Component | Dosage (weight %) |
| Sodium cetanesulfonate | 5.0 |
| NaOH | 4.5 |
| The more glycosides of lauryl glucose | 12.0 |
| Isopropanol | 2.0 |
| Butyl glycol ether | 3.0 |
| EDETATE SODIUM | 0.2 |
| Deionized water | Surplus |
Embodiment 5
Using methods known in the art, the cleanser compositions of various formulas listed in Table are prepared:
Table 5
| Component | Dosage (weight %) |
| Sodium cetanesulfonate | 2.5 |
| NaOH | 2.5 |
| The more glycosides of lauryl glucose | 5.0 |
| Ethyl alcohol | 2.0 |
| Butyl glycol ether | 4.0 |
| EDETATE SODIUM | 0.2 |
| Deionized water | Surplus |
Embodiment 6
Using methods known in the art, the cleanser compositions of various formulas listed in Table are prepared:
Table 6
| Component | Dosage (weight %) |
| Sodium cetanesulfonate | 3.0 |
| NaOH | 3.0 |
| The more glycosides of lauryl glucose | 6.0 |
| Ethyl alcohol | 3.0 |
| Butyl glycol ether | 5.0 |
| EDETATE SODIUM | 0.2 |
| Deionized water | Surplus |
Comparative example 1
Use commercially available 93# gasoline as the imperial robe remover.
Comparative example 2
Use commercially available 0# diesel oil as the imperial robe remover.
Embodiment 3
Using methods known in the art, the cleanser compositions of various formulas listed in Table are prepared:
Table 7
| Component | Dosage (parts by weight) |
| Trihydroxy ethylamine oleate soap | 5 |
| Coconut oil alkylolamides | 5 |
| Dodecyl benzene sulfonic acid | 15 |
| KOH | 5 |
| Glycerine | 7 |
| Citric acid | 12 |
| AEO-7 | 4 |
| Deionized water | Surplus |
Evaluation method
(1) the imperial robe removal effect
The industrial machine tool component sample that surface is covered with the imperial robe greasy dirt is immersed respectively by embodiment 1-6 and comparative example 1-3
In the bath of preparation, it is aided with ultrasonic vibration to remove the imperial robe greasy dirt.The imperial robe removal effect is evaluated using following evaluation criterion:
◎: the imperial robe removal effect is fine；
O: the imperial robe removal effect is preferable；
Δ: the imperial robe removal effect is general；
X: the imperial robe poor removal effect.
(2) the imperial robe removes speed
The industrial machine tool component sample that surface is covered with the imperial robe greasy dirt is immersed respectively by embodiment 1-6 and comparative example 1-3
In the bath of preparation.The imperial robe removal speed is evaluated using following evaluation criterion:
◎: the imperial robe removes speed quickly；
O: the imperial robe removes fast speed；
Δ: it is general that the imperial robe removes speed；
X: it is slow that the imperial robe removes speed.
(3) the imperial robe removes persistence
After the aptitude tests of (1) removal the imperial robe described above, industrial machine tool component is clean by obtained
Continue in equipment, to 2 weeks, visual observations the imperial robe situation again after 4 weeks.It is gone using following evaluation criterion to evaluate the imperial robe
Except persistence:
◎: the imperial robe is not observed；
O: slightly the imperial robe is observed；
Δ: there are a large amount of the imperial robes；
X: it is almost covered by the imperial robe.
Table 7
As can be seen that cleanser compositions of the invention have excellent the imperial robe removal ability from upper table 7, can quickly,
It is effectively removed the imperial robe, and also preferable for the lasting effect of the imperial robe removal.Moreover, because cleanser compositions of the invention
In each component cost it is lower, therefore, the price of cleanser compositions of the invention is relatively low.
It should be understood that above-mentioned specific embodiment just to the purpose of explanation, is not construed as limiting the invention.?
Under the premise of spirit and substance of the present invention, those skilled in the art can carry out various modifications and change to the present invention
Become, these modifications and changes are each fallen within the scope of the appended claims.
Claims (10)
1. a kind of the imperial robe cleansing composition, be 100 weight % by the imperial robe cleansing composition in terms of, the detergent combination
Object includes following components:
(a) sodium alkyl sulfonate of 1-10 weight %, the sodium alkyl sulfonate include sodium cetanesulfonate；
(b) liquid alkaline of 1-5 weight %, the liquid alkaline include NaOH and/or KOH；
(c) alkyl polyglycoside of 2-15 weight %, the alkyl polyglycoside include the more glycosides of lauryl glucose and/or the more glycosides of decyl glucose；
(d) alcohol of 1-10 weight %, the alcohol include ethyl alcohol and/or isopropanol；
(e) butyl glycol ether of 1-10 weight %；And
(f) disodium ethylene diamine tetraacetate of 0.1-0.5 weight %.
2. the imperial robe cleansing composition as described in claim 1, which is characterized in that the content of the sodium alkyl sulfonate is 2-5
Weight %.
3. the imperial robe cleansing composition as described in claim 1, which is characterized in that the content of the liquid alkaline is 2-4.5 weight
Measure %.
4. the imperial robe cleansing composition as described in claim 1, which is characterized in that the content of the alkyl polyglycoside is 4-12 weight
Measure %.
5. the imperial robe cleansing composition as described in claim 1, which is characterized in that the content of the alcohol is 2-5 weight %.
6. the imperial robe cleansing composition as described in claim 1, which is characterized in that the content of the butyl glycol ether is 3-6
Weight %.
7. the imperial robe cleansing composition as described in claim 1, which is characterized in that the content of the disodium ethylene diamine tetraacetate
For 0.2 weight %.
8. the imperial robe cleansing composition as described in claim 1, which also includes:
(g) deionized water of surplus.
9. the imperial robe cleansing composition as described in claim 1, which also includes:
(h) fragrance of 1-10 weight % and/or (i) lanolin of 1-10 weight %.
10. the imperial robe cleansing composition as described in claim 1 is used for the purposes of mechanical device cleaning, the mechanical device packet
Include the mechanical device of shipbuilding industry, the mechanical device of railway industry, the mechanical device of aircraft industry, lathe and steel.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105670830A (en) * | 2016-04-07 | 2016-06-15 | 上海斯麦尔日化有限公司 | Cleaning agent composition |
| CN106947979B (en) * | 2017-03-22 | 2020-08-14 | 广州亦盛环保科技有限公司 | Magnesium-aluminum alloy cleaning agent |
| CN107574026A (en) * | 2017-08-22 | 2018-01-12 | 无锡市永兴金属软管有限公司 | A kind of lathe cleaning agent and preparation method thereof |
| CN113201416B (en) * | 2021-05-20 | 2022-02-01 | 中山市迈微环保科技有限公司 | Alkaline multifunctional cleaning agent, preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1339579A (en) * | 2001-10-10 | 2002-03-13 | 常耀辉 | Water base micro emulsion cleaning agent for heavy oil pollution and its prepn |
| CN101538512A (en) * | 2009-03-11 | 2009-09-23 | 上海九盛实业有限公司 | Water-based cleaner |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9911818D0 (en) * | 1999-05-21 | 1999-07-21 | Reckitt & Colman Inc | Improvements in or relating to organic compositions |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1339579A (en) * | 2001-10-10 | 2002-03-13 | 常耀辉 | Water base micro emulsion cleaning agent for heavy oil pollution and its prepn |
| CN101538512A (en) * | 2009-03-11 | 2009-09-23 | 上海九盛实业有限公司 | Water-based cleaner |
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