CN107513715A - A kind of cleaning agent for engine compression casting oil - Google Patents

A kind of cleaning agent for engine compression casting oil Download PDF

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Publication number
CN107513715A
CN107513715A CN201710777890.0A CN201710777890A CN107513715A CN 107513715 A CN107513715 A CN 107513715A CN 201710777890 A CN201710777890 A CN 201710777890A CN 107513715 A CN107513715 A CN 107513715A
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CN
China
Prior art keywords
cleaning agent
sodium
engine compression
compression casting
casting oil
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710777890.0A
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Chinese (zh)
Inventor
卢燕燕
张丽燕
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huizhou Dacheng Microelectronic Materials Co ltd
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Dongguan Dacheng Display Material Co Ltd
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Publication of CN107513715A publication Critical patent/CN107513715A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

The present invention relates to the cleaning agent for engine compression casting oil, it is made up of alkaline matter, surfactant, auxiliary agent and aqueous medium, the quality percentages of various compositions this be:Alkaline matter 3.5 4%;Surfactant 0.05 0.5%;Auxiliary agent 0.5 1%;Aqueous medium surplus.The cleaning agent is green, and cleaning performance is good, without secondary pollution.

Description

A kind of cleaning agent for engine compression casting oil
Technical field
The invention belongs to cleaning agent technical field, is related to a kind of cleaning agent, and in particular to one kind is used for engine compression casting oil Cleaning agent.
Background technology
Automobile engine is that its function is by liquid or gas by the machine that the energy conversion of a certain form is mechanical energy Chemical energy by being converted into heat energy after burning, then heat energy is converted into mechanical energy by expansion and externally exports power.Automobile Power come from engine, engine is the heart of automobile, and power is provided for the walking of automobile, be related to automobile dynamic property, Economy, the feature of environmental protection.
The processing of the preparation technology of automobile engine including each type component and assembling process, each type component processing, When being circulated using each link such as, accumulating, residue-dirt of various liquid or solids can be left in piece surface.Therefore, filling It is required for being cleaned before matching somebody with somebody, piece surface is reached certain cleannes.Cleaning is to ensure all kinds of engine components Machining, heat treatment, application, plating, antirust, the essential procedure of assembling quality.The cleaning of engine part Quality has direct relation with part processing, paint, plating and assembling quality, also directly influences the service life of engine.
It is well known that there are the parts that many products are used for automobile in die-cast product.With to environmentally friendly, light-weighted requirement Increasingly improve, many critical components in automobile, such as engine cylinder-body, be increasingly turned to Die Casting.Compression casting is modern age Develop a kind of faster few Special Processes of Metal Castings method without cutting in metal working process.It is by molten metal under high-voltage high-speed Casting mold is filled, and crystallization and freezing forms the process of casting under high pressure.In press casting procedure, die casting conduction oil, die casting can be used Particle oil, diecasting punching head oil, die casting conduction oil etc., are referred to as die casting oil.Die casting oil can remain in component surface, in order to not Subsequent operation is influenceed, does not interfere with the service life of engine, it is necessary to cleans up remnants die casting oil.
Deoiling method common at present has alkali degreasing, Solvent degreasing, electrochemical degreasing, ultrasonic wave cleaning oil removing Deng.
Cleaning agent currently used for engine compression casting oil uses Solvent degreasing more, according to rule of similarity by greasy dirt Dissolve.Solvent degreasing is used, though simple to operate, cleaning performance is preferable, organic solvent has certain toxicity, meeting mostly Operating personnel's health is endangered, it is not green, and be possible to that secondary pollution can be caused.In addition, Discarded organic solvent Processing be also a great problem.
In view of the drawbacks described above of prior art, there is an urgent need to a kind of new cleaning agent for being used for engine compression casting oil.
The content of the invention
It is an object of the invention to overcome shortcoming present in prior art, there is provided a kind of for the clear of engine compression casting oil Lotion, the cleaning agent is green, and cleaning performance is good, without secondary pollution.
To achieve these goals, the present invention provides following technical scheme:
It is a kind of for engine compression casting oil cleaning agent, it is characterised in that by alkaline matter, surfactant, auxiliary agent and Aqueous medium forms, wherein, the mass percent of various compositions is:
Further, wherein, the alkaline matter is carbonate and/or silicate.
Further, wherein, the carbonate in sodium carbonate, sodium acid carbonate, potassium carbonate and saleratus extremely Few one kind.
Yet further, wherein, the silicate includes at least one of sodium metasilicate and sodium metasilicate.
On the other hand, wherein, the surfactant is nonionic surfactant.
Further, wherein, the nonionic surfactant is selected from AEO, alkylphenol-polyethenoxy In ether, alkylolamides APEO, Block polyoxyethylene-polyethenoxy ether, alkylolamides and alkyl poly glucoside At least one.
Yet another aspect, wherein, the auxiliary agent is inorganic assistant and/or organic additive.
Further, wherein, the inorganic assistant in sodium carbonate, sodium metasilicate, sodium sulphate, sodium chloride and borax extremely Few one kind.
Yet further, wherein, the organic additive be selected from sodium citrate, sodium ethylene diamine tetracetate, sodium gluconate and At least one of sodium tartrate.
Finally, wherein, the aqueous medium is deionized water.
Compared with existing cleaning agent, there is the cleaning agent for being used for engine compression casting oil of the invention following Advantageous to imitate Fruit:The cleaning agent for being used for engine compression casting oil of the present invention will not corrode workpiece while workpiece surface greasy dirt is effectively removed Surface, secondary pollution will not be caused.Meanwhile its raw material is simple and environmentally-friendly, after being cleaned to workpiece, directly can be rinsed with water, Add the action pane of workpiece rinsing.Therefore, the cleaning agent has good application prospect in engine production field.
Embodiment
With reference to embodiment, the present invention is further described, and the content of embodiment is not as to protection scope of the present invention Limitation.
It is different from existing Solvent degreasing method the present invention relates to a kind of cleaning agent for engine compression casting oil, this Invention uses alkaline degreasing method.Alkaline degreasing is a kind of chemical cleaning method using alkaline matter as host, mainly passes through soap Change, emulsification, scattered and dissolution remove degreasing.Alkali lye and sponifiable grease generate soluble aliphatic acid by saponification Salt, for not saponifiable oil fat, alkali lye disperses greasy dirt by greasy dirt from the dissociation on workpiece surface.
Alkaline degreasing method has good cleaning performance, the damage to cleaned matrix is small, usage amount is small, price is low Honest and clean, non-toxic or hypotoxicity, free from extraneous odour, waste material are disposable, will not cause environmental pollution.Provided by the present invention for engine pressure The cleaning agent of casting oil uses alkaline degreasing method, using alkaline matter as host, adds certain surfactant and auxiliary agent, then add remaining The deionized water of amount, mix in proportion to obtain at normal temperatures.
Surfactant is that have to assemble on the interface of two kinds of materials, and can significantly change surface tension of liquid and two-phase Between interfacial property a kind of material.Surfactant hydrophilic group be present simultaneously and the special construction of hydrophobic group determines that it has The fundamental propertys such as wetting, emulsification, scattered, solubilising.And in cleaning process, the basic step to be taken out stains from the surface of solids is all First to being cleaned the wetting of the surface of solids, get on dirt from substrate, recycle the peptizaiton of cleaning agent, make dirt stable Disperse in the solution.In general, some auxiliary agents are added in toward cleaning agent, auxiliary agent energy chelating metal ion, softening of water, are had Certain buffer capacity, the pH of cleaning agent can be maintained stable, and have peptizaiton to solid greasy dirt, prevent greasy dirt in workpiece surface Adhere to again.When particularly with surfactant compound, cleansing power can be significantly improved.
In general, some alkaline matters also are used as auxiliary agent, and auxiliary agent can be divided into inorganic assistant and organic additive.Common Inorganic assistant has sodium tripolyphosphate, sodium carbonate, sodium sulphate, sodium metasilicate, borax, sodium chloride, sodium bisulfate etc..Organic additive root Acted on according to played in cleaning, solubilizer, chelating agent, foam modifier, anti redeposition agent etc. can be divided into.
Effect of the inorganic assistant in cleaning agent is not quite similar, and following is some industrial usual auxiliaries and its effect:
By largely studying, the raw material and its proportioning of the cleaning agent for being used for engine compression casting oil of the invention are as follows:
It should be noted that above-mentioned content is mass percentage content.
When using the engine compression casting oil cleaning agent of the present invention, it is sprayed into appropriate time on workpiece to remove Greasy dirt on workpiece, is dried up after being rinsed with water with high pure nitrogen, so that it may continues assembling process.
Therefore, engine compression casting of the invention oil is simple with cleaning agent raw material, and it is easy to prepare, easy to use, can be well Degrease, industrial production can be widely used in.
In the present invention, alkaline matter may be selected from least one of carbonate, silicate, phosphate.Phosphate is because of rich phosphorus Redization phenomenon can be caused to occur, thus preferably at least one of carbonate, silicate.
In one embodiment of invention, the example of carbonate includes sodium carbonate, sodium acid carbonate, potassium carbonate, saleratus And its mixture.The example of silicate includes sodium metasilicate, sodium metasilicate and its mixture.
Meanwhile in the present invention, surfactant selects nonionic surface active agent.Nonionic surface active agent includes AEO (AEO), APES (TX-10, OP-10,), alkylolamides polyoxy second Alkene ether, Block polyoxyethylene-polyethenoxy ether (PO-EO copolymers), alkylolamides, alkyl poly glucoside (alkyl polyglycoside APG) etc..
The in general surface of solids is negatively charged, and Electrostatic Absorption can only occur for cationic surfactant, make electroneutral Hydrophobic layer, the hydrophobic group of anion surfactant adsorbs with Van der Waals force and dirt, makes the negative electrical charge on its surface increase, increasing The strong electric repulsion of solid greasy dirt and workpiece surface, the adhesion strength of solid greasy dirt is reduced, so as to be removed.And nonionic table Face activating agent is contacted with its nonpolar moiety and dirt, and hydrophilic group gos deep into water, so as to form hydrated sheath, increase in fouled surfaces The dispersion stabilization of dirt, dirt is set to be not easy again close to each other and deposit.Therefore, nonionic surfactant is to solids foul Cleaning performance is best.
In addition, in the present invention, auxiliary agent includes inorganic assistant and organic additive.The former may be selected from sodium carbonate, sodium metasilicate, sulfuric acid Sodium, sodium chloride, borax.The latter may be selected from sodium citrate, sodium ethylene diamine tetracetate, sodium gluconate, sodium tartrate at least It is a kind of.
Finally, it is preferable that aqueous medium used is deionized water.
Below, the present invention is further described by some embodiments, but the present invention is not limited to the following example In embodiment.
Wherein, △:Cleaning performance is good;×:Cleaning performance is bad.
Also, wherein, AEO7 is a kind of AEO, using C12-C16 coconut oleyl alcohol, EO numbers are 7, shallow Yellow liquid.There are good wetability, foaminess, detergency and emulsifying ability.There are higher degreasing ability and hard water resistance power.
AEO9 is a kind of AEO, and from C12-C16 coconut oleyl alcohol, EO numbers are 9, have decontamination, emulsification, Degreasing, wetting action.
TX-10 is a kind of APES, and chemical stability is high, resistance to strong acid, highly basic, has good wetting Power, penetration, detergency and stronger emulsifying ability.There is low bubble property, antistatic behaviour, hard water resistance property in addition.
By above-described embodiment, engine compression casting oil is used for using the raw material and its mass percent of the present invention Cleaning agent cleaning performance is good, and the cleaning performance of other embodiments is bad.
The above embodiment of the present invention is only intended to clearly illustrate example of the present invention, and is not to the present invention Embodiment restriction.For those of ordinary skill in the field, can also make on the basis of the above description Other various forms of changes or variation.Here all embodiments can not be exhaustive.Every skill for belonging to the present invention Row of the obvious changes or variations that art scheme is extended out still in protection scope of the present invention.

Claims (10)

1. a kind of cleaning agent for engine compression casting oil, it is characterised in that by alkaline matter, surfactant, auxiliary agent and water Property medium composition, wherein, the mass percent of various compositions is:
2. the cleaning agent according to claim 1 for engine compression casting oil, it is characterised in that the alkaline matter is carbon Hydrochlorate and/or silicate.
3. the cleaning agent according to claim 2 for engine compression casting oil, it is characterised in that the carbonate is selected from carbon At least one of sour sodium, sodium acid carbonate, potassium carbonate and saleratus.
4. the cleaning agent according to claim 2 for engine compression casting oil, it is characterised in that the silicate includes silicon At least one of sour sodium and sodium metasilicate.
5. the cleaning agent according to claim 1 for engine compression casting oil, it is characterised in that the surfactant is Nonionic surfactant.
6. the cleaning agent according to claim 5 for engine compression casting oil, it is characterised in that the non-ionic surface is lived Property agent be selected from AEO, APES, alkylolamides APEO, Block polyoxyethylene- At least one of polyethenoxy ether, alkylolamides and alkyl poly glucoside.
7. the cleaning agent according to claim 1 for engine compression casting oil, it is characterised in that the auxiliary agent is without machine aided Agent and/or organic additive.
8. the cleaning agent according to claim 7 for engine compression casting oil, it is characterised in that the inorganic assistant is selected from At least one of sodium carbonate, sodium metasilicate, sodium sulphate, sodium chloride and borax.
9. the cleaning agent according to claim 7 for engine compression casting oil, it is characterised in that the organic additive is selected from At least one of sodium citrate, sodium ethylene diamine tetracetate, sodium gluconate and sodium tartrate.
10. the cleaning agent according to claim 1 for engine compression casting oil, it is characterised in that the aqueous medium is Deionized water.
CN201710777890.0A 2017-06-01 2017-08-31 A kind of cleaning agent for engine compression casting oil Pending CN107513715A (en)

Applications Claiming Priority (2)

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CN2017104054305 2017-06-01
CN201710405430 2017-06-01

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109531045A (en) * 2018-12-29 2019-03-29 瑞安市得力标准件制造有限公司 Engine cylinder body spindle hole restorative procedure
CN110565104A (en) * 2019-09-03 2019-12-13 湖南德莱恩新材料科技有限公司 Environment-friendly spray cleaning agent and preparation method thereof
CN110713865A (en) * 2019-10-24 2020-01-21 党育锋 Automobile engine cleaning agent and preparation method and application thereof
CN112410797A (en) * 2019-08-20 2021-02-26 富泰华精密电子(郑州)有限公司 Cleaning method, cleaning apparatus and cleaned substrate
CN112725096A (en) * 2020-12-28 2021-04-30 广东月福汽车用品有限公司 Engine cabin cleaning agent and preparation method thereof
CN114621826A (en) * 2022-03-30 2022-06-14 苏州科锐德节能环境科技有限公司 Environment-friendly oil-separating type battery shell heavy oil stain cleaning agent
CN115852381A (en) * 2022-10-19 2023-03-28 广州市联诺化工科技有限公司 High-pressure spray cleaning agent for automatic line spraying and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4597888A (en) * 1985-06-19 1986-07-01 Parker Chemical Company Cleaner for steel cans
CN1056904A (en) * 1990-05-30 1991-12-11 李洪耀 High efficiency clening agent for engine of vehicle
CN1106864A (en) * 1994-11-11 1995-08-16 开封空分设备厂 Cleaning agent
CN106835166A (en) * 2016-12-02 2017-06-13 湖南德莱恩新材料科技有限公司 Low-temperature environment-friendly cleaning agent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4597888A (en) * 1985-06-19 1986-07-01 Parker Chemical Company Cleaner for steel cans
CN1056904A (en) * 1990-05-30 1991-12-11 李洪耀 High efficiency clening agent for engine of vehicle
CN1106864A (en) * 1994-11-11 1995-08-16 开封空分设备厂 Cleaning agent
CN106835166A (en) * 2016-12-02 2017-06-13 湖南德莱恩新材料科技有限公司 Low-temperature environment-friendly cleaning agent

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109531045A (en) * 2018-12-29 2019-03-29 瑞安市得力标准件制造有限公司 Engine cylinder body spindle hole restorative procedure
CN112410797A (en) * 2019-08-20 2021-02-26 富泰华精密电子(郑州)有限公司 Cleaning method, cleaning apparatus and cleaned substrate
CN110565104A (en) * 2019-09-03 2019-12-13 湖南德莱恩新材料科技有限公司 Environment-friendly spray cleaning agent and preparation method thereof
CN110713865A (en) * 2019-10-24 2020-01-21 党育锋 Automobile engine cleaning agent and preparation method and application thereof
CN112725096A (en) * 2020-12-28 2021-04-30 广东月福汽车用品有限公司 Engine cabin cleaning agent and preparation method thereof
CN114621826A (en) * 2022-03-30 2022-06-14 苏州科锐德节能环境科技有限公司 Environment-friendly oil-separating type battery shell heavy oil stain cleaning agent
CN115852381A (en) * 2022-10-19 2023-03-28 广州市联诺化工科技有限公司 High-pressure spray cleaning agent for automatic line spraying and preparation method thereof

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PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right
TA01 Transfer of patent application right

Effective date of registration: 20180202

Address after: 518000 Guangdong Shenzhen city Baoan District Songgang Street Yan Chuan community Ring Road No. 54

Applicant after: SHENZHEN DACHENG ABLUENT CO.,LTD.

Address before: 523378 Guangdong province Dongguan City Chashan Nanshe village of Castle Peak Road dry pit

Applicant before: DONGGUAN DACHENG DISPLAY MATERIAL Co.,Ltd.

TA01 Transfer of patent application right
TA01 Transfer of patent application right

Effective date of registration: 20190312

Address after: 516265 West of Maintenance Workshop of McCort Science and Technology Industrial Park, Weilong Management Zone, Liangjing Town, Huiyang District, Huizhou City, Guangdong Province

Applicant after: Huizhou Dacheng Microelectronic Materials Co.,Ltd.

Address before: 518000 No. 54 Huansheng Avenue, Yanchuan Community, Songgang Street, Baoan District, Shenzhen City, Guangdong Province

Applicant before: SHENZHEN DACHENG ABLUENT CO.,LTD.

CI02 Correction of invention patent application
CI02 Correction of invention patent application

Correction item: Applicant|Address

Correct: Huizhou Dacheng Microelectronic Materials Co., Ltd.|516265 West of Maintenance Workshop of McCort Science and Technology Industrial Park, Weilong Management Zone, Liangjing Town, Huiyang District, Huizhou City, Guangdong Province

False: Huizhou Dacheng Microelectronic Materials Co., Ltd.|516265 West of Maintenance Workshop of McCort Science and Technology Industrial Park, Weilong Management Zone, Liangjing Town, Huiyang District, Huizhou City, Guangdong Province

Number: 13-02

Volume: 35

WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20171226