CN110055140A - It is a kind of to replace aqueous cleaning multiple-effect agent for carbon hydrogen detergent and preparation method thereof - Google Patents

It is a kind of to replace aqueous cleaning multiple-effect agent for carbon hydrogen detergent and preparation method thereof Download PDF

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Publication number
CN110055140A
CN110055140A CN201910449828.8A CN201910449828A CN110055140A CN 110055140 A CN110055140 A CN 110055140A CN 201910449828 A CN201910449828 A CN 201910449828A CN 110055140 A CN110055140 A CN 110055140A
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aqueous
agent
carbon hydrogen
hydrogen detergent
cleaning
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刘暘
刘长禹
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Ma'anshan Huazhijie Metal Surface Treatment Agent Co Ltd
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Ma'anshan Huazhijie Metal Surface Treatment Agent Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/2034Monohydric alcohols aromatic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2072Aldehydes-ketones
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43Solvents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/34Derivatives of acids of phosphorus
    • C11D1/345Phosphates or phosphites
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/667Neutral esters, e.g. sorbitan esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Anti-Oxidant Or Stabilizer Compositions (AREA)

Abstract

The present invention relates to cleaning agent technical fields, and disclose a kind of raw material for replacing aqueous cleaning multiple-effect agent for carbon hydrogen detergent and preparation method thereof, matching including following parts by weight: specific type surfactant 10-20%, antioxidant 0.1-0.5%, demulsifying agent 5-10% and hydrocarbon solvent 69.5-84.90%.This replaces aqueous cleaning multiple-effect agent for carbon hydrogen detergent and preparation method thereof, used raw material is cosmetics-stage, low taste is to tasteless, it is practically free of aromatic hydrocarbons and sulphur, it is harmless, easily biological-degradable, noresidue sense, it is harmless to the mankind and marine organisms, this replaces aqueous cleaning to be free of traditional alcohol ethers compound with multiple-effect agent for carbon hydrogen detergent, it simultaneously can be with the moisture on cleaning workpiece with cleaning oil-dirt, cuttings liquid, saponification liquor, aqueous grinding fluid, aqueous polishing liquid, the aqueous spot such as aqueous stamping stretch liquid and aqueous rinsing liquid, use can be distilled to recover instead of aqueous cleaning multiple-effect agent for carbon hydrogen detergent, without discharge, overall cost is low, it is produced on a large scale.

Description

It is a kind of to replace aqueous cleaning multiple-effect agent for carbon hydrogen detergent and preparation method thereof
Technical field
The present invention relates to cleaning agent technical fields, specially a kind of to replace aqueous cleaning multiple-effect agent for carbon hydrogen detergent and its system Preparation Method
Background technique
It is required generally to use cuttings liquid, saponification liquor, aqueous grinding fluid, aqueous grinding according to processing technology in machining As cutter and die lubricant, aqueous machining fluid has cooling and anti-the aqueous machining fluids such as liquid and aqueous stamping stretch liquid simultaneously The functions such as rust extend the service life of knife and mold, improve the precision of workpiece, the workpiece after processing generally uses aqueous cleaning Agent is cleaned, and the spot in process is removed, and aqueous cleaning is generally using acid or alkaline cleaner, rinsing water amount Greatly, general components are rinsed and has been not thorough the discoloration easy to oxidize of corrosion risk, especially non-ferrous metal, and high-accuracy electricity The industries such as sub and micro- electricity are higher for purity requirements, and the residual and watermark mark of aqueous cleaning influence its performance and reliability, are It is entirely unacceptable.
High using aqueous cleaning water consumption, wastewater discharge is big, and qualified discharge processing cost is high, and the solvent that cleaning force is good Because explicit order is forbidden to use, alkanes cleaning agent is current green solvent, nothing for type cleaning agent such as toluene, chlorohydrocarbon and fluoride solvent Discharge, noresidue, retortable recycling uses the agent for carbon hydrogen detergent main wash oil-dirt of the existing market m, to the water on workpiece Point, cuttings liquid, saponification liquor, aqueous grinding fluid, aqueous polishing liquid, the aqueous spot such as aqueous stamping stretch liquid and aqueous rinsing liquid it is clear It washes that power is poor, is not able to satisfy requirement of the client to noble and unsullied resulting net force, cleaning field is narrow, a kind of replaces aqueous cleaning use more so proposing Agent for carbon hydrogen detergent and preparation method thereof is imitated to solve the problems, such as above-mentioned propose.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, aqueous cleaning multiple-effect agent for carbon hydrogen detergent and its system are replaced the present invention provides a kind of Preparation Method, oil-dirt can not only be cleaned by having, can be with the moisture on cleaning workpiece, cuttings liquid, saponification liquor, aqueous grinding The advantages of aqueous spots such as liquid, aqueous polishing liquid, aqueous stamping stretch liquid and aqueous rinsing liquid, solves current agent for carbon hydrogen detergent Cleaning force is poor and cleans the narrow problem in field.
(2) technical solution
Oil-dirt can be cleaned for realization is above-mentioned, it can be with moisture, cuttings liquid, saponification liquor, the aqueous mill on cleaning workpiece The aqueous spot purpose such as liquid, aqueous polishing liquid, aqueous stamping stretch liquid and aqueous rinsing liquid is cut, the present invention provides following technical side Case: a kind of to replace aqueous cleaning multiple-effect agent for carbon hydrogen detergent, the raw material including following parts by weight proportion: surfactant 10- 20%, antioxidant 0.1-0.5%, demulsifying agent 5-10% and hydrocarbon solvent 69.5-84.9%.
Preferably, antioxidant 2,6 di-tert-butylphenols or 2, one or two kinds of combinations of 6 di-tert-butyl p-cresol Object.
Preferably, surfactant is vinyl pyrrolidone-Methacrylamide-vinyl imidazol copolymer, vitamin E The combination of acetate, vitamin C phosphoric ester salt, polyoxyethylene ether PO-EO block copolymer.
Preferably, demulsifying agent is the nonionic surfactant that o-alkylation phenolic resin is compounded with polyamines polyene.
Preferably, hydrocarbon solvent is Isopars, and using the Synthin product of height collateralization, carbochain is The distribution of C9-12.
Another technical problem to be solved by the present invention is that providing a kind of system instead of aqueous cleaning multiple-effect agent for carbon hydrogen detergent Preparation Method, comprising the following steps:
1) hydrocarbon solvent is added in reaction kettle, then is separately added into vinyl pyrrolidone-Methacrylamide-ethylene miaow Azoles copolymer sodium 5%-10% and Vitwas E 2%-5% and vitamin C phosphoric ester salt 1%-2%, under stiring into Row is warming up to 80-90 degree;
2) when temperature reaches 80-90 and spends, polyoxyethylene ether PO-EO block copolymer 2%-3% is added, continues stirring 2 Start to cool down after hour;
3) when temperature, which drops to 40-50, to be spent, antioxidant 0.1-0.5% and demulsifying agent 5-10% insulated and stirred 1 is added Hour;
4) temperature drops to 30 degree or so and can discharge, and whole preparation process terminates, hydrocarbon instead of aqueous cleaning multiple-effect Cleaning agent completes.
(3) beneficial effect
Compared with prior art, aqueous cleaning multiple-effect agent for carbon hydrogen detergent and its preparation side are replaced the present invention provides a kind of Method, have it is following the utility model has the advantages that
1, this replaces aqueous cleaning multiple-effect agent for carbon hydrogen detergent and preparation method thereof, is by using isomery C9-C12 alkane Hydrocarbon solvent, the solvent are the Synthin product of height collateralization, and low taste is practically free of aromatic hydrocarbons and sulphur, to human body to tasteless It is harmless, and easily biological-degradable, noresidue, it is harmless to the mankind and marine organisms, and retortable recycling uses, no waste liquid discharge.
2, this replaces aqueous cleaning multiple-effect agent for carbon hydrogen detergent and preparation method thereof, passes through vinyl pyrrolidone-methyl Acrylamide-vinyl imidazol copolymer, Vitwas E, vitamin C phosphoric ester salt, polyoxyethylene ether PO-EO block copolymerization The addition of the combined surfactant of object, play infiltration, removing, disperse aqueous spot purpose.
3, this replaces aqueous cleaning multiple-effect agent for carbon hydrogen detergent and preparation method thereof, is realized by the addition of demulsifying agent Water-oil phase is completely separated, and has been achieved the purpose that cleaning solution is used for a long time and has not been had to change liquid.
4, this replaces aqueous cleaning with multiple-effect agent for carbon hydrogen detergent and preparation method thereof, using 2,6 di-tert-butylphenols and 2,6 two The mixture of both Butylated Hydroxytoluenes is antioxidant, has the function of extending the service life of cleaning agent.
5, this replaces aqueous cleaning with multiple-effect agent for carbon hydrogen detergent and preparation method thereof, and when cleaning will not destroy original processing fluidity Can, it can continue to use as working fluid after separation discharge, no waste liquid excludes.
6, this replaces aqueous cleaning with multiple-effect agent for carbon hydrogen detergent and preparation method thereof, the simple science of the mechanism of action, safety and Environmental protection, smell is low, nonflammable, raw materials used to use cosmetic grade, securely and reliably, the not pollution of waste water and emission problem, Preparation method is simple, and raw material is extensive, is suitble to scale industrial production, by being added to the surfactant of specific type, significantly The cleaning force of hydrocarbon solvent is improved, can not only clean oil-dirt but also can be with moisture, cuttings liquid, the soap on cleaning workpiece Changing the aqueous spots such as liquid, aqueous grinding fluid, aqueous polishing liquid, aqueous stamping stretch liquid and aqueous rinsing liquid has cleaning well Effect has widened the field of hydrocarbon cleaning, has obtained the effect of environmental protection.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical solution in the embodiment of the present invention is clearly and completely retouched It states, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the present invention In embodiment, every other implementation obtained by those of ordinary skill in the art without making creative efforts Example, shall fall within the protection scope of the present invention.
Embodiment one: a kind of to replace aqueous cleaning multiple-effect agent for carbon hydrogen detergent, the raw material including following parts by weight proportion: Surfactant 10%, antioxidant 0.1, demulsifier 5% and hydrocarbon solvent 84.9%, surfactant are that vinylpyridine presses against alkane Ketone-Methacrylamide-vinyl imidazol copolymer, Vitwas E, vitamin C phosphoric ester salt, polyoxyethylene ether PO-EO The combination of block copolymer, demulsifier are the nonionic surfactant that o-alkylation phenolic resin is compounded with polyamines polyene, are resisted Oxidant is 2,6 di-tert-butylphenols or 2, and one or two kinds of compositions of 6 di-tert-butyl p-cresol, hydrocarbon solvent is isomeric alkane Hydrocarbon solvent, using the Synthin product of height collateralization, carbochain is the distribution of C9.
Another technical problem to be solved by the present invention is that providing a kind of system instead of aqueous cleaning multiple-effect agent for carbon hydrogen detergent Preparation Method the following steps are included:
1) hydrocarbon solvent is added in reaction kettle, then is separately added into vinyl pyrrolidone-Methacrylamide-ethylene miaow Azoles copolymer sodium 5% and Vitwas E 2% and vitamin C phosphoric ester salt 1%, carry out being warming up to 80 degree under stiring;
2) when temperature reaches 80 degree, polyoxyethylene ether PO-EO block copolymer 2% is added, is opened after continuing stirring 2 hours Begin to cool down;
3) when temperature drops to 40 degree, antioxidant 0.1% and 5% insulated and stirred of demulsifying agent 1 hour is added;
4) temperature drops to 30 degree or so and can discharge, and whole preparation process terminates, hydrocarbon instead of aqueous cleaning multiple-effect Cleaning agent completes.
Note: agent for carbon hydrogen detergent is for 100 kilograms.
Embodiment two: a kind of to replace aqueous cleaning multiple-effect agent for carbon hydrogen detergent, the raw material including following parts by weight proportion: Surfactant 15%, antioxidant 0.2, demulsifier 8% and hydrocarbon solvent 76.8%, surfactant are that vinylpyridine presses against alkane Ketone-Methacrylamide-vinyl imidazol copolymer, Vitwas E, vitamin C phosphoric ester salt, polyoxyethylene ether PO-EO The combination of block copolymer, demulsifier are the nonionic surfactant that o-alkylation phenolic resin is compounded with polyamines polyene, are resisted Oxidant is 2,6 di-tert-butylphenols or 2, and one or two kinds of compositions of 6 di-tert-butyl p-cresol, hydrocarbon solvent is N-alkanes Hydrocarbon solvent, using high-purity hydrocarbon products, carbochain is the distribution of C10.
Another technical problem to be solved by the present invention is that providing a kind of system instead of aqueous cleaning multiple-effect agent for carbon hydrogen detergent Preparation Method the following steps are included:
1) hydrocarbon solvent is added in reaction kettle, then is separately added into vinyl pyrrolidone-Methacrylamide-ethylene miaow Azoles copolymer sodium 6% and Vitwas E 4% and vitamin C phosphoric ester salt 2%, carry out being warming up to 85 degree under stiring;
2) when temperature reaches 85 degree, polyoxyethylene ether PO-EO block copolymer 3% is added, is opened after continuing stirring 2 hours Begin to cool down;
3) when temperature drops to 45 degree, antioxidant 0.2% and 8% insulated and stirred of demulsifying agent 1 hour is added;
4) temperature drops to 30 degree or so and can discharge, and whole preparation process terminates, hydrocarbon instead of aqueous cleaning multiple-effect Cleaning agent completes.
Note: agent for carbon hydrogen detergent is for 100 kilograms.
Embodiment three: a kind of to replace aqueous cleaning multiple-effect agent for carbon hydrogen detergent, the raw material including following parts by weight proportion: Surfactant 20%, antioxidant 0.5, demulsifier 10% and hydrocarbon solvent 69.5%, surfactant is pressed against for vinylpyridine Alkanone-Methacrylamide-vinyl imidazol copolymer, Vitwas E, vitamin C phosphoric ester salt, polyoxyethylene ether PO- The combination of EO block copolymer, demulsifier are the nonionic surfactant that o-alkylation phenolic resin is compounded with polyamines polyene, Antioxidant is 2,6 di-tert-butylphenols or 2, and one or two kinds of compositions of 6 di-tert-butyl p-cresol, hydrocarbon solvent is isomery Alkane solvent, using high-purity hydrocarbon products, carbochain is the distribution of C12.
Another technical problem to be solved by the present invention is that providing a kind of system instead of aqueous cleaning multiple-effect agent for carbon hydrogen detergent Preparation Method the following steps are included:
1) hydrocarbon solvent is added in reaction kettle, then is separately added into vinyl pyrrolidone-Methacrylamide-ethylene miaow Azoles copolymer sodium 10% and Vitwas E 5% and vitamin C phosphoric ester salt 3%, carry out being warming up to 90 under stiring Degree;
2) when temperature reaches 90 degree, polyoxyethylene ether PO-EO block copolymer 2% is added, is opened after continuing stirring 2 hours Begin to cool down;
3) when temperature drops to 50 degree, antioxidant 0.5% and 10% insulated and stirred of demulsifying agent 1 hour is added;
4) temperature drops to 30 degree or so and can discharge, and whole preparation process terminates, hydrocarbon instead of aqueous cleaning multiple-effect Cleaning agent completes.
Note: agent for carbon hydrogen detergent is for 100 kilograms.
The beneficial effects of the present invention are: being hydrocarbon solvent by using isomery C9-C12 alkane and ten alkane of positive structure, low taste is extremely It is tasteless, it is practically free of aromatic hydrocarbons and sulphur, it is harmless, and easily biological-degradable, noresidue, it is harmless to the mankind and marine organisms, Retortable recycling uses, no waste liquid discharge.
Also, pass through vinyl pyrrolidone-Methacrylamide-vinyl imidazol copolymer, Vitwas E, dimension Raw element C phosphate ester salt, polyoxyethylene ether PO-EO block copolymer combined surfactant addition, play infiltration, remove With the purpose of disperse aqueous spot.
Also, water-oil phase is realized by the addition of demulsifying agent to be completely separated, has reached cleaning solution and has been used for a long time not With the purpose for changing liquid.
Also, 2,6 di-tert-butylphenols and 2 are used, the mixture of both 6 di-tert-butyl p-cresol is antioxidant, is had Extend the effect of the service life of cleaning agent.
Also, original processing fluidity energy will not be destroyed when cleaning, can continue to use as working fluid after separation discharge, without useless Liquid excludes.
Also, the simple science of the mechanism of action, safety and environmental protection, smell is low, nonflammable, raw materials used using cosmetics etc. Grade, securely and reliably, the not pollution of waste water and emission problem, preparation method is simple, and raw material is extensive, is suitble to large-scale industrial raw It produces, by being added to the surfactant of specific type, significantly improves the cleaning force of hydrocarbon solvent, can not only clean oiliness dirt Stain but also can be with moisture, cuttings liquid, saponification liquor, aqueous grinding fluid, the aqueous polishing liquid, aqueous stamping stretch on cleaning workpiece The aqueous spot such as liquid and aqueous rinsing liquid has good cleaning effect, has widened the field of hydrocarbon cleaning, has obtained environmental protection Effect.
It is a kind of that aqueous cleaning is replaced to use technique with multiple-effect agent for carbon hydrogen detergent:
Illustrate:
1-2 slot is rinse bath, using a kind of replacement aqueous cleaning multiple-effect agent for carbon hydrogen detergent of the invention;
3-7 slot, as rinsing liquid, is washed by vacuum ultrasonic cleaning with what gas phase cleaning made using Isopars Resulting net force significantly improves, and meets high clean and requires, while it is low to be distilled to recover use cost online.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (6)

1. a kind of replace aqueous cleaning multiple-effect agent for carbon hydrogen detergent, which is characterized in that the raw material including following parts by weight proportion: Specific type surfactant 10-20%, antioxidant 0.1-0.5%, demulsifying agent 5-10 and hydrocarbon solvent 69.5- 84.9%.
2. the aqueous cleaning multiple-effect agent for carbon hydrogen detergent of a kind of replacement according to claim 1, which is characterized in that the antioxygen Agent is one or two kinds of compositions of 2,6 di-tert-butylphenols or 2,6 di-tert-butyl p-cresol.
3. the aqueous cleaning multiple-effect agent for carbon hydrogen detergent of a kind of replacement according to claim 1, which is characterized in that described special Classes of surfactant is vinyl pyrrolidone-Methacrylamide-vinyl imidazol copolymer, Vitwas E, dimension life The combination of plain C phosphate ester salt and polyoxyethylene ether PO-EO block copolymer.
4. the aqueous cleaning multiple-effect agent for carbon hydrogen detergent of a kind of replacement according to claim 1, which is characterized in that described hydrocarbon Solvent is n-alkane or Isopars, and using the Synthin product of height collateralization, carbochain is the distribution of C9-12 Or its carbochain of decane hydrocarbon is C10.
5. the aqueous cleaning multiple-effect agent for carbon hydrogen detergent of a kind of replacement according to claim 1, which is characterized in that the anti-cream Agent is the nonionic surfactant that o-alkylation phenolic resin is compounded with polyamines polyene.
6. a kind of instead of the aqueous cleaning preparation method of multiple-effect agent for carbon hydrogen detergent, which comprises the following steps:
1) hydrocarbon solvent is added in reaction kettle, then to be separately added into vinyl pyrrolidone-Methacrylamide-vinyl imidazol total Polymers sodium 5%-10% and Vitwas E 2%-5% and vitamin C phosphoric ester salt 1%-2%, is risen under stiring Temperature is to 80-90 degree;
2) when temperature reaches 80-90 and spends, polyoxyethylene ether PO-EO block copolymer 2%-3% is added, continues stirring 2 hours After start to cool down;
3) when temperature, which drops to 40-50, to be spent, antioxidant 0.1-0.5% and demulsifying agent 5-10% insulated and stirred 1 hour is added;
4) temperature drops to 30 degree or so and can discharge, and whole preparation process terminates, and environment protection type multifunctional agent for carbon hydrogen detergent is made It completes.
CN201910449828.8A 2019-05-28 2019-05-28 It is a kind of to replace aqueous cleaning multiple-effect agent for carbon hydrogen detergent and preparation method thereof Pending CN110055140A (en)

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CN110923727A (en) * 2019-12-12 2020-03-27 广东红日星实业有限公司 Grinding fluid cleaning agent and preparation method thereof
CN112760663A (en) * 2021-01-22 2021-05-07 宁波莱昂德尔化工科技有限公司 Special hydrocarbon cleaning agent with strong cleaning power for environment-friendly heat exchanger parts
CN112899089A (en) * 2021-01-28 2021-06-04 郭振河 Hydrocarbon cleaning agent for cleaning HW49 waste packaging materials and preparation method thereof

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CN108531314A (en) * 2018-04-20 2018-09-14 广东红日星实业有限公司 Aqua and preparation method thereof is cut in environmental protection

Cited By (4)

* Cited by examiner, † Cited by third party
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CN110628524A (en) * 2019-10-10 2019-12-31 江苏电卫能源科技有限公司 Composite cleaning agent for electrified insulating equipment
CN110923727A (en) * 2019-12-12 2020-03-27 广东红日星实业有限公司 Grinding fluid cleaning agent and preparation method thereof
CN112760663A (en) * 2021-01-22 2021-05-07 宁波莱昂德尔化工科技有限公司 Special hydrocarbon cleaning agent with strong cleaning power for environment-friendly heat exchanger parts
CN112899089A (en) * 2021-01-28 2021-06-04 郭振河 Hydrocarbon cleaning agent for cleaning HW49 waste packaging materials and preparation method thereof

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Application publication date: 20190726